JPH0119205B2 - - Google Patents
Info
- Publication number
- JPH0119205B2 JPH0119205B2 JP18482180A JP18482180A JPH0119205B2 JP H0119205 B2 JPH0119205 B2 JP H0119205B2 JP 18482180 A JP18482180 A JP 18482180A JP 18482180 A JP18482180 A JP 18482180A JP H0119205 B2 JPH0119205 B2 JP H0119205B2
- Authority
- JP
- Japan
- Prior art keywords
- silver
- contact
- nickel
- contacts
- welding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 26
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 16
- 229910052709 silver Inorganic materials 0.000 claims description 16
- 239000004332 silver Substances 0.000 claims description 16
- 229910052759 nickel Inorganic materials 0.000 claims description 13
- MOFOBJHOKRNACT-UHFFFAOYSA-N nickel silver Chemical compound [Ni].[Ag] MOFOBJHOKRNACT-UHFFFAOYSA-N 0.000 claims description 11
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 8
- 229910052738 indium Inorganic materials 0.000 claims description 7
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 7
- 229910003437 indium oxide Inorganic materials 0.000 claims description 2
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 claims description 2
- IVQODXYTQYNJFI-UHFFFAOYSA-N oxotin;silver Chemical compound [Ag].[Sn]=O IVQODXYTQYNJFI-UHFFFAOYSA-N 0.000 claims 1
- 238000003466 welding Methods 0.000 description 22
- PSCIKKFYFNJDPV-UHFFFAOYSA-N [O-2].[In+3].[Sn+2]=O.[Ag+].[O-2].[O-2] Chemical compound [O-2].[In+3].[Sn+2]=O.[Ag+].[O-2].[O-2] PSCIKKFYFNJDPV-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 3
- 229910001887 tin oxide Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000004663 powder metallurgy Methods 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- QCEUXSAXTBNJGO-UHFFFAOYSA-N [Ag].[Sn] Chemical compound [Ag].[Sn] QCEUXSAXTBNJGO-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical group [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
Landscapes
- Contacts (AREA)
Description
本発明は組合せ電気接点の改良に関する。
近時、電気、電子技術の発展に伴い各種電気、
電子機器が小型化され、それに応じてブレーカ
ー、マグネツトスイツチ等も小型化されている。
然し乍ら、ブレーカー、マグネツトスイツチ等
が小型化され、開閉容量が増加すると、これに伴
い接点の消耗や溶着が増加する。これに対抗する
ためには接点の体積を増加したり、開離力を増加
させる必要がある。しかしこれでは機器は大型に
なつてしまい初期の目的に沿わなくなる。
この為、耐消耗性が良く、耐溶着性に優れた組
合せ電気接点が要望され、種々の組合せ電気接点
の開発なされているが、今だ満足すべきものがな
い。
従来、組合せ電気接点には銀中に金属酸化物が
分散した銀−酸化物より成る接点が用いられ、そ
の中でも銀−酸化すず−酸化インジウムより成る
接点同志を対向させた組合せ電気接点が高濃度銀
−ニツケルより成る接点同志を対向させた組合せ
電気接点に比し耐消耗性が優れているが、銀−酸
化すず−酸化インジウム中の酸化すずや酸化イン
ジウムが接点閉成の度毎に接点表面に凝集してい
き、耐溶着性に不安定が生じ、溶着した場合の溶
着力が高くなる。また、高濃度銀−ニツケルより
成る接点同志を対向させた組合せ電気接点の場合
は、熱的に安定なニツケルの効果により耐溶着性
にはある程度富むが、開閉中にニツケルが酸化す
るため接触抵抗が高くなり、溶着した場合の溶着
力が高くなる。
このように従来の組合せ電気接点は、相対向す
る固定接点と可動接点を同じ電気接点材料を用い
ていたので、溶着した場合の溶着力が高くなる等
の問題があつた。そこで、本発明者は小型化され
たブレーカー、マグネツトスイツチ等に於いても
耐溶着性に優れた組合せ電気接点を開発すべく鋭
意攻究の結果、相対向する固定接点と可動接点に
所定の異なる接点材料を用いることにより耐溶着
性が向上し得ることを見い出した。
本発明はこの点に着目してなされたものであ
り、耐消耗性をある程度犠牲にしても耐溶着性を
確実に向上させることのできる組合せ電気接点と
して銀−酸化すず−酸化インジウム系の接点を高
濃度銀−ニツケルの接点とを相対向させて成る組
合せ電気接点を提供せんとするものである。
本発明による組合せ電気接点は、相対向する接
点にすず2重量%(以下「w/o」という。)〜
15w/o、インジウム1w/o〜7w/o及び残部
銀から成る銀−酸化すず−酸化インジウム系の接
点と、ニツケル20w/oを超え50w/o以下及び
残部銀から成る高濃度銀−ニツケル系の接点を用
いたことを特徴とするものである。
本発明の組合せ電気接点に於いて上記の如く相
対向する接点の材料を限定した理由は、高濃度銀
−ニツケル系の消耗のしやすさを利用して小形接
点に大電流を投じたときでも、溶着回数が少な
く、しかも溶着力の低い組合せ電気接点を得る為
である。また銀−酸化ずず−酸化インジウム系の
すずの含有量を2w/o〜15w/oと限定した理
由は、2w/o未満では高濃度銀−ニツケル系電
気接点と組み合わせた場合の耐消耗量が不十分で
あり、15w/oを超えると、接点表面に凝集する
酸化すずの量が多くなつて接触抵抗が増大し、溶
着した場合の溶着力が高くなるからである。イン
ジウムの含有量を1w/o〜7w/oと限定した理
由は、1w/o未満ではすずの内部酸化が困難で
あり7w/oを超えると酸化すずが凝集しやすく
なるからである。
銀−ニツケル系のニツケルの含有量を20w/o
を超え50w/o以下とした理由は、20w/o以下
では銀−酸化すず−酸化インジウム系の耐溶着性
を補うことができず、50w/oを超えると表面に
酸化ニツケルの厚い膜を作り接触抵抗が極端に悪
くなるからである。
次に本発明による組合せ電気接点の効果を明瞭
ならしめる為にその具体的な実施例と従来例につ
いて説明する。
実施例 1
すず8w/o、インジウム3w/o及び残部銀の
銀−酸化すず−酸化インジウムより成る直径5mm
固定接点と、ニツケル40w/o及び残部銀の銀−
ニツケルより成る直径5mmの可動接点とを相対向
させて組合せ電気接点を構成した。
実施例 2
すず6w/o、インジウム2w/o及び残部銀の
銀−酸化すず−酸化イジウムより成る直径5mmの
固定接点と、ニツケル25w/o及び残部銀の銀−
ニツケルより成る直径5mmの可動接点とを相対向
させて組合せ電気接点を構成した。
従来例 1
すず8w/o、インジウム3w/o及び残部銀の
銀−酸化すず−酸化インジウムより成る直径5mm
固定接点と直径5mmの可動接点とを相対向させて
組合せ電気接点を構成した。
従来例 2
ニツケル10w/o及び残部銀の銀−ニツケルよ
り成る5φmmの固定接点と5φmmの可動接点とを相
対向させて組合せ電気接点を構成した。
比較例 1
すず8w/o、インジウム3w/o及び残部銀の
銀−酸化すず−酸化インジウムより成る直径5mm
の固定接点と、ニツケル10w/o及び残部銀の銀
−ニツケルより成る直径5mmの可能接点とを相対
向させて組合せ電気接点を構成した。然してこれ
ら各組合せ電気接点を下記の試験条件にて耐溶着
試験を測定したところ下表の右欄に示すような結
果を得た。
耐溶着試験条件
A C 100V 50Hz
電 流 2230A
開閉回数 20回 開−閉−閉のくり返し
開閉頻度 1回/2分
接触力 500g
開離力 150g
The present invention relates to improvements in combination electrical contacts. Recently, with the development of electrical and electronic technology, various electrical
As electronic devices have become smaller, breakers, magnetic switches, etc. have also become smaller. However, as breakers, magnetic switches, etc. become smaller and their switching capacity increases, wear and welding of contacts increases. In order to counter this, it is necessary to increase the volume of the contact point or increase the separation force. However, this would make the equipment too large and would no longer meet its initial purpose. For this reason, there is a demand for a combination electrical contact that has good wear resistance and excellent welding resistance, and various combination electrical contacts have been developed, but so far none has been satisfactory. Conventionally, contacts made of silver-oxide, in which metal oxide is dispersed in silver, have been used for combination electrical contacts, and among these, combination electrical contacts, in which contacts made of silver-tin oxide-indium oxide are placed facing each other, are highly concentrated. It has superior wear resistance compared to a combination electrical contact made of silver and nickel, which has contacts facing each other, but tin oxide and indium oxide in silver-tin oxide-indium oxide are deposited on the contact surface each time the contact is closed. As it aggregates, the welding resistance becomes unstable and the welding force increases when welded. In addition, in the case of a combination electrical contact in which contacts made of high concentration silver and nickel face each other, they have some degree of adhesion resistance due to the thermally stable effect of nickel, but since the nickel oxidizes during opening and closing, the contact resistance becomes higher, and the welding force when welding increases. As described above, in the conventional combination electric contact, the same electric contact material was used for the opposing fixed contact and movable contact, which caused problems such as increased welding force when welded. Therefore, as a result of intensive research to develop a combination electrical contact with excellent welding resistance even in miniaturized breakers, magnetic switches, etc., the inventors of the present invention have found that a fixed contact and a movable contact facing each other have a fixed contact and a movable contact. It has been found that welding resistance can be improved by using different contact materials. The present invention has been made with attention to this point, and uses a silver-tin oxide-indium oxide type contact as a combination electrical contact that can reliably improve welding resistance even if it sacrifices wear resistance to some extent. It is an object of the present invention to provide a combination electrical contact formed by opposing highly concentrated silver-nickel contacts. The combination electrical contact according to the present invention has a tin content of 2% by weight (hereinafter referred to as "w/o") in opposing contacts.
A silver-tin oxide-indium oxide system contact consisting of 15 w/o, indium 1 w/o to 7 w/o and the balance silver, and a high concentration silver-nickel system consisting of nickel exceeding 20 w/o and 50 w/o or less and the balance silver. This is characterized by the use of contacts. In the combination electrical contact of the present invention, the reason why the materials for the opposing contacts are limited as described above is that by taking advantage of the ease of wear of the high-concentration silver-nickel system, even when a large current is applied to the small contact, This is to obtain a combination electrical contact that requires fewer welding times and has a lower welding force. In addition, the reason why the content of tin in the silver-tin oxide-indium oxide system was limited to 2w/o to 15w/o is that if it is less than 2w/o, the wear resistance when combined with a high concentration silver-nickel electrical contact is This is insufficient, and if it exceeds 15 w/o, the amount of tin oxide that aggregates on the contact surface will increase, resulting in increased contact resistance and increased welding force when welded. The reason why the indium content is limited to 1 w/o to 7 w/o is that if it is less than 1 w/o, internal oxidation of tin is difficult, and if it exceeds 7 w/o, tin oxide tends to aggregate. The content of nickel in the silver-nickel system is 20w/o.
The reason for setting it above 50w/o is that below 20w/o, it is not possible to compensate for the adhesion resistance of the silver-tin oxide-indium oxide system, and when it exceeds 50w/o, a thick film of nickel oxide forms on the surface. This is because contact resistance becomes extremely poor. Next, in order to clarify the effects of the combined electrical contact according to the present invention, specific examples and conventional examples thereof will be described. Example 1 5 mm diameter made of silver-tin oxide-indium oxide with 8 w/o tin, 3 w/o indium and the balance silver
Fixed contacts, nickel 40w/o and balance silver -
A movable contact made of nickel and having a diameter of 5 mm was placed facing each other to form a combination electric contact. Example 2 A fixed contact with a diameter of 5 mm made of silver-tin oxide-idium oxide with 6 w/o tin, 2 w/o indium and the balance silver, and a fixed contact with a diameter of 5 mm made of nickel 25 w/o and the balance silver.
A movable contact made of nickel and having a diameter of 5 mm was placed facing each other to form a combination electric contact. Conventional example 1 5 mm diameter made of silver-tin oxide-indium oxide with 8 w/o tin, 3 w/o indium, and the balance silver.
A fixed contact and a movable contact with a diameter of 5 mm were made to face each other to form a combination electric contact. Conventional Example 2 A fixed contact of 5 φ mm and a movable contact of 5 φ mm made of nickel 10 w/o and silver-nickel with the balance being silver were made to face each other to form a combination electric contact. Comparative Example 1 5 mm diameter made of silver-tin oxide-indium oxide with 8 w/o tin, 3 w/o indium and the balance silver
A fixed contact and a flexible contact of 5 mm in diameter made of nickel 10 w/o and silver-nickel with the balance being silver were placed opposite each other to form a combination electrical contact. However, when each of these combinations of electrical contacts was subjected to a welding resistance test under the following test conditions, the results shown in the right column of the table below were obtained. Welding resistance test conditions A C 100V 50Hz Current 2230A Number of openings and closings 20 times Open-close-close repetitions Opening and closing frequency 1 time/2 minutes Contact force 500g Breaking force 150g
【表】
上記表で明らかなように銀−酸化すず−酸化イ
ンジウム系の接点と高濃度銀−ニツケル系の接点
を相対向させた本発明の組合せ電気接点は、耐溶
着性が良いと言われている従来の銀−ニツケルの
接点同志を相対向させた組合せ電気接点よりも耐
溶着性に優れ、溶着した場合の溶着力も低い。ま
た、類似の組合せである低濃度銀−ニツケル系の
接点と銀−酸化すず−酸化インジウム系の接点を
相対向させた比較例1の組合せ電気接点よりも、
高電流ノーヒユーズブレーカ試験において溶着し
た場合の溶着力が低い。
尚、本発明における銀−酸化すず−酸化インジ
ウムは、内部酸化法、粉末冶金法、内部酸化法と
粉末冶金法の併用等によつて作られるもので、銀
中に金属酸化物が細かく分散しているものであれ
ばよいものである。
以上詳記した通り本発明の組合せ電気接点は、
耐溶着性に格別に優れているので、小型化された
ブレーカー、マグネツトスイツチ等に使用して単
位面積当たりに流れる電流量が大きくなつても、
溶着の発生を抑えることができ、しかも低い溶着
力で済み、機器の信頼性と寿命の向上をはかるこ
とができる等の効果がある。[Table] As is clear from the table above, the combination electrical contact of the present invention, in which a silver-tin oxide-indium oxide contact and a highly concentrated silver-nickel contact are placed opposite each other, is said to have good welding resistance. It has better welding resistance than the conventional combination electrical contacts in which silver-nickel contacts are opposed to each other, and the welding force when welded is also lower. Furthermore, compared to the electrical contact combination of Comparative Example 1, in which a similar combination of low-concentration silver-nickel-based contacts and silver-tin oxide-indium oxide contacts were made to face each other,
Welding force is low when welding in high current no fuse breaker test. The silver-tin oxide-indium oxide used in the present invention is produced by an internal oxidation method, a powder metallurgy method, a combination of an internal oxidation method and a powder metallurgy method, etc., and the metal oxide is finely dispersed in silver. It is good as long as it is true. As detailed above, the combination electrical contact of the present invention is
It has exceptional adhesion resistance, so even when used in miniaturized breakers, magnetic switches, etc., and the amount of current flowing per unit area increases,
It has the effect of suppressing the occurrence of welding, requiring only a low welding force, and improving the reliability and life of equipment.
Claims (1)
%〜7重量%及び残部銀から成る銀−酸化すず−
酸化インジウム系の接点と、ニツケル20重量%を
超え、50重量%以下及び残部銀から成る銀−ニツ
ケル系の接点とを相対向させて成る組合せ電気接
点。1 Silver - tin oxide - consisting of 2% to 15% by weight of tin, 1% to 7% by weight of indium, and the balance silver
A combination electrical contact consisting of an indium oxide-based contact and a silver-nickel-based contact consisting of more than 20% by weight but not more than 50% by weight of nickel, and the balance being silver, facing each other.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP18482180A JPS57107517A (en) | 1980-12-25 | 1980-12-25 | Combination electric contact |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP18482180A JPS57107517A (en) | 1980-12-25 | 1980-12-25 | Combination electric contact |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS57107517A JPS57107517A (en) | 1982-07-05 |
JPH0119205B2 true JPH0119205B2 (en) | 1989-04-11 |
Family
ID=16159872
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP18482180A Granted JPS57107517A (en) | 1980-12-25 | 1980-12-25 | Combination electric contact |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS57107517A (en) |
-
1980
- 1980-12-25 JP JP18482180A patent/JPS57107517A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS57107517A (en) | 1982-07-05 |
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