JPH01188595A - Cleaning agent composition for dry cleaning - Google Patents
Cleaning agent composition for dry cleaningInfo
- Publication number
- JPH01188595A JPH01188595A JP1206188A JP1206188A JPH01188595A JP H01188595 A JPH01188595 A JP H01188595A JP 1206188 A JP1206188 A JP 1206188A JP 1206188 A JP1206188 A JP 1206188A JP H01188595 A JPH01188595 A JP H01188595A
- Authority
- JP
- Japan
- Prior art keywords
- water
- dry cleaning
- cleaning
- organic amine
- sulfotricarballylic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 32
- 238000005108 dry cleaning Methods 0.000 title claims description 29
- 239000012459 cleaning agent Substances 0.000 title abstract description 7
- -1 ester salt Chemical class 0.000 claims abstract description 10
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 9
- 150000001412 amines Chemical class 0.000 claims abstract description 9
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 8
- 239000003599 detergent Substances 0.000 claims description 25
- 239000002253 acid Substances 0.000 claims description 11
- 229910052783 alkali metal Inorganic materials 0.000 claims description 7
- 150000001340 alkali metals Chemical class 0.000 claims description 7
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 7
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims 2
- 239000002904 solvent Substances 0.000 abstract description 20
- 239000003208 petroleum Substances 0.000 abstract description 17
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 239000003513 alkali Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 29
- 239000007788 liquid Substances 0.000 description 15
- 238000005063 solubilization Methods 0.000 description 9
- 230000007928 solubilization Effects 0.000 description 9
- 239000004094 surface-active agent Substances 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- KQTIIICEAUMSDG-UHFFFAOYSA-N tricarballylic acid Chemical compound OC(=O)CC(C(O)=O)CC(O)=O KQTIIICEAUMSDG-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- 239000004808 2-ethylhexylester Substances 0.000 description 1
- YEYKMVJDLWJFOA-UHFFFAOYSA-N 2-propoxyethanol Chemical compound CCCOCCO YEYKMVJDLWJFOA-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 229960000956 coumarin Drugs 0.000 description 1
- 235000001671 coumarin Nutrition 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、ドライクリーニング用洗浄剤組成物に関し、
更に詳しくは石油系溶剤を用いるドライクリーニングに
適したドライクリーニング用洗浄剤組成物に関する。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a detergent composition for dry cleaning,
More specifically, the present invention relates to a dry cleaning detergent composition suitable for dry cleaning using petroleum solvents.
〔従来の技術及び発明が解決しようとする課題〕パラフ
ィン、ナフテン、芳香族炭化水素などからなる石油系溶
剤を用いるドライクリーニングにおける洗浄剤は、水の
可溶化能（抱水能）を向上させること、及び除去された
汚れの再汚染を防ぐことが必須の条件であり、水溶性汚
れ、個体汚れの除去及び再汚染の防止の為に種々の界面
活性剤が用いられている。[Prior art and problems to be solved by the invention] Cleaning agents used in dry cleaning that use petroleum-based solvents made of paraffin, naphthene, aromatic hydrocarbons, etc. should improve water solubilization ability (water-holding ability). It is an essential condition to prevent recontamination of the removed dirt and soil, and various surfactants are used to remove water-soluble dirt and solid soil and prevent recontamination.
従来のドライクーニング用洗浄剤組成物は、一般に５〜
８０重量％の界面活性剤、ドライクリーニング溶剤、粘
度低下剤及び防錆剤等が配合された液状洗浄剤組成物で
あって、ドライクリーニングに際しては、この洗浄剤組
成物をドライクリーニング溶剤に対して０．１〜５重量
％の割合で使用している。しかしながら、石油系溶剤を
用いるドライクリーニングにおいては、ドライ機での洗
浄に先立って、洗浄では落ちにくい水溶性汚れやじみを
除去する為に処理液にてスプレー又はブラッシング処理
後、洗浄するのが一般的である。−船釣な処理液の処方
は以下の通りである。Conventional dry cleaning detergent compositions generally have a
A liquid cleaning composition containing 80% by weight of a surfactant, a dry cleaning solvent, a viscosity reducer, a rust preventive, etc. When dry cleaning, this cleaning composition is mixed with a dry cleaning solvent. It is used in a proportion of 0.1 to 5% by weight. However, in dry cleaning that uses petroleum-based solvents, it is common to spray or brush with a treatment liquid and then wash before washing with a dry machine to remove water-soluble dirt and stains that are difficult to remove with washing. It is true. - The formulation of the treatment solution for boat fishing is as follows.
ドライクリーニング用洗浄剤組成物 １容量部水
１容量部石油系溶剤
８容量部通常、この液をササラ液と
呼ぶ。Detergent composition for dry cleaning 1 volume part water
1 part by volume petroleum solvent
8 parts by volume This liquid is usually called Sasara liquid.
石油系溶剤を用いるドライクリーニング用洗浄剤は、均
一なササラ液を作る為に水の可溶化能が大であることが
要求される。併しながらドライクリーニングに用いる石
油系溶剤は、石油メーカーの原産地、精製法等によりパ
ラフィン、ナフテン、芳香族炭化水素等の成分が異なる
。Dry cleaning detergents that use petroleum-based solvents are required to have a high ability to solubilize water in order to produce a uniform liquid. However, petroleum solvents used for dry cleaning have different components, such as paraffins, naphthenes, and aromatic hydrocarbons, depending on the oil manufacturer's country of origin, refining method, etc.
この為、各種溶剤を用いて均一なササラ液を作る為に洗
浄剤の界面活性剤に工夫がされている。For this reason, improvements have been made to surfactants in detergents in order to create uniform sasara liquid using various solvents.
併しながら全ての溶剤で均一なササラが出来ないのが現
状である。均一なササラが出来ない場合は水の配合量を
少なくして使用しており、水溶性汚れの除去効果が小さ
いという問題がある。However, the current situation is that uniform thinning cannot be achieved with all solvents. If uniform drying cannot be achieved, a reduced amount of water is used, which poses the problem of low effectiveness in removing water-soluble stains.
ササラ液の作り方はドライクリーニング用洗浄剤と水と
を容量で同量を良く混合し、混合物の８倍量の石油系溶
剤で希釈する。この時にドライクリーニング用洗浄剤と
水との混合物が均一透明な液状となれば、石油系溶剤で
希釈する時に容易に溶解するが、水の可溶化能（抱水能
）の小さいドライクリーニング用洗浄剤を用いると、水
の量を少なくしないと乳化状態となり均一なササラ液が
作れず、水溶性汚れやじみの除去効果が小さい。従って
、水の可溶化能（抱水能）の大きなドライクリーニング
用洗浄剤が必要である。To make Sasara liquid, mix equal amounts of dry cleaning detergent and water, then dilute with 8 times the amount of petroleum solvent. At this time, if the mixture of dry cleaning detergent and water becomes a uniform and transparent liquid, it will be easily dissolved when diluted with petroleum solvent, but dry cleaning detergent has low water solubilization ability (water holding ability). When using an agent, unless the amount of water is reduced, it becomes emulsified and a uniform sasara liquid cannot be produced, and the effect of removing water-soluble stains and stains is small. Therefore, a dry cleaning detergent with a high water solubilizing ability (water holding ability) is required.
上述の様に石油メーカー各社の石油系溶剤の何れに対し
ても十分な水の可溶化能（抱水能）を有し、均一なササ
ラ液が出来るドライクリーニング用洗浄剤が望まれてい
た。As mentioned above, there has been a desire for a dry cleaning detergent that has sufficient water solubilization ability (water-holding ability) for all petroleum-based solvents from petroleum manufacturers and can produce a uniform liquid.
本発明者らは、石油系溶剤の種類に関係なく十分な水可
溶化能（抱水能）を有し、均一なササラ液を作成し得る
ドライクリーニング用洗浄剤組成物について鋭意研究の
結果、特定のスルホトリカルバリル酸エステル塩を含有
する組成物がこの目的に適うことを見出し、本発明を完
成するに至った。As a result of intensive research by the present inventors on a dry cleaning detergent composition that has sufficient water solubilization ability (water-holding ability) regardless of the type of petroleum solvent and can create a uniform sasara liquid, The present inventors have discovered that a composition containing a specific sulfotricarballylic acid ester salt is suitable for this purpose, and have completed the present invention.
即ち、本発明は、下記の一般式（Ｉ）、又は（ＩＩ）Ｃ
）１２ＣＯＯＲＩ Ｘ０３Ｓ ＣＨＣＯ
ＯＲ＋ｌ
Ｘ０３Ｓ−Ｃ−ＣＯＯＲ２（１） ＣＩ（Ｃ
ＯＯＲ２（ＩＩ）１ ’
ＩＣＨｚＣＯＯＲ３Ｃ）ＩｚＣＯＯ
Ｒ８
（式中Ｒ，，Ｒ２及びＲ３は、互いに同一であっても異
なっていてもよい直鎖又は分岐鎖を有する炭素数１〜２
０のアルキル基又はアルケニル基、又は水素原子、アル
カリ金属、アルカリ土類金属、有機アミンを表す。但し
、Ｒ，、Ｒ２及びＲ３のうち少なくとも２つはアルキル
基又はアルケニル基である。Ｘは、アルカリ金属、アル
カリ土類金属又は有機アミンを示す）
で表されるスルホトリカルバリル酸エステル塩の１種又
はそれ以上の混合物を界面活性剤として含有することを
特徴とするドライクリーニング用洗浄剤組成物を提供す
るものである。That is, the present invention provides the following general formula (I) or (II)C
)12COORI X03S CHCO
OR+l X03S-C-COOR2(1) CI(C
OOR2(II)1'
ICHzCOOR3C)IzCOO
R8 (in the formula, R, , R2 and R3 are linear or branched carbon atoms having 1 to 2 carbon atoms, which may be the same or different from each other)
0 alkyl group or alkenyl group, or a hydrogen atom, an alkali metal, an alkaline earth metal, or an organic amine. However, at least two of R, R2 and R3 are an alkyl group or an alkenyl group. X represents an alkali metal, an alkaline earth metal, or an organic amine. The present invention provides a drug composition.
本発明における前記−殺伐（１）、 （ＩＩ）で表され
るスルホトリカルバリル酸エステル塩系界面活性剤は、
ドライクリーニング用洗浄剤組成物の主剤として従来使
用されてきたスルホコハク酸ジアルキルエステル塩に比
べ優れた水の可溶化能（抱水能）を示す。The sulfotricarballylic acid ester salt surfactant represented by the above-mentioned -killing (1) and (II) in the present invention is:
It exhibits superior water solubilization ability (water holding ability) compared to sulfosuccinic acid dialkyl ester salts that have been conventionally used as the main ingredient in dry cleaning detergent compositions.
前記−殺伐（１）、 （ＩＩ）で示される化合物におい
て、Ｒ１，’Ｒ２及びＲ８は互いに同一であっても異な
っていてもよい直鎖又は分岐鎖を有する炭素数１〜２０
のアルキル基又はアルケニル基、又は水素原子、アルカ
リ金属、アルカリ土類金属、有機アミンを表す。但し、
Ｒ＋、 Ｒｚ及びＲ３のうち少なくとも２つはアルキル
基又はアルケニル基である。これら、Ｒ１，Ｒ２及びＲ
３の炭素数の合計は、１２〜２４である化合物が好まし
い。これより炭素数の合計が少ないと、十分な水の可溶
化能（抱水能）が得られにくく、また２４を越えると組
成物にした場合の粘度、濁り等の物性に悪影響を及ぼす
ことがある。In the compounds represented by the above-mentioned -Katsu (1) and (II), R1, 'R2 and R8 have a linear or branched chain and have 1 to 20 carbon atoms, which may be the same or different from each other.
represents an alkyl group or alkenyl group, or a hydrogen atom, an alkali metal, an alkaline earth metal, or an organic amine. however,
At least two of R+, Rz and R3 are an alkyl group or an alkenyl group. These, R1, R2 and R
A compound in which the total number of carbon atoms in 3 is 12 to 24 is preferable. If the total carbon number is less than this, it will be difficult to obtain sufficient water solubilization ability (water-holding ability), and if it exceeds 24, it may have an adverse effect on the physical properties such as viscosity and turbidity when made into a composition. be.
また、Ｘは、アルカリ金属、アルカリ土類金属又は有機
アミンであり、アルカリ金属としてはナトリウム、カリ
ウム等、アルカリ土類金属としてはマグネシウム等、有
機アミンとしてはモノ、ジ、トリエタノールアミン等が
挙げられる。In addition, X is an alkali metal, an alkaline earth metal, or an organic amine; examples of the alkali metal include sodium, potassium, etc., examples of the alkaline earth metal include magnesium, etc., and examples of the organic amine include mono-, di-, and triethanolamine. It will be done.
本発明に係わる前記−殺伐（Ｉ）、 （ＩＩ）で表され
る化合物の好ましい具体例としては、スルホトリカルバ
リル酸トリー２−エチルブチルエステルＮａ塩、スルホ
トリカルバリル酸トリヘキシルエステルＮａ塩、スルホ
トリカルバリル酸トリー２−エチルヘキシルエステルＮ
ａ塩、スルホトリカルバリル酸トリオクチルエステルに
塩、スルホトリカルバリル酸トリブチルエステルに塩等
が挙げられる。Preferred specific examples of the compounds represented by (I) and (II) in the present invention include sulfotricarballylic acid tri-2-ethylbutyl ester Na salt, sulfotricarballylic acid trihexyl ester Na salt, and sulfotricarballylic acid trihexyl ester Na salt. Tricarballylic acid tri-2-ethylhexyl ester N
a salt, a salt of sulfotricarballylic acid trioctyl ester, a salt of sulfotricarballylic acid tributyl ester, and the like.
前記−殺伐（Ｉ）、 （ＩＩ）で表されるスルホトリカ
ルバリル酸エステル塩系界面活性剤は、通常本発明の洗
浄剤組成物中に５〜２０重量％（以下％と略記する）配
合される。The sulfotricarballylic acid ester salt surfactant represented by the above-mentioned -killing (I) and (II) is usually blended in the cleaning composition of the present invention in an amount of 5 to 20% by weight (hereinafter abbreviated as %). Ru.
前記−殺伐（Ｉ）、 （ＩＩ）で表されるスルホトリカ
ルバリル酸エステル塩系界面活性剤を配合した本発明の
ドライクリーニング用洗浄剤組成物の好ましい処方例は
次の通りである。A preferred formulation example of the detergent composition for dry cleaning of the present invention containing the sulfotricarballylic acid ester salt surfactant represented by the above-described (I) and (II) is as follows.
■ スルホトリカルバリル酸エステル塩５〜２０％、好
ましくは１０〜１５％
■ 非イオン性界面活性剤
３０〜５０％、好ましくは３５〜４５％■ 石油系溶剤
２０〜６０％、好ましくは３０〜５０％■ 水 １
〜２０％、好ましくは２〜ｌＯ％■成分の非イオン性界
面活性剤としては、ポリオキシアルキレンアルキルエー
テル、ポリオキシアルキレンアルキルフェニルエーテル
等が使用される。これらの中でもＨＬＢが７，５〜１０
の範囲のものが特に好ましい。■ Sulfotricarballylic acid ester salt 5-20%, preferably 10-15% ■ Nonionic surfactant 30-50%, preferably 35-45% ■ Petroleum solvent 20-60%, preferably 30-50% %■ Water 1
~20%, preferably 2~10% (2) As the nonionic surfactant component, polyoxyalkylene alkyl ether, polyoxyalkylene alkylphenyl ether, etc. are used. Among these, HLB is 7.5-10
Particularly preferred are those within the range of .
また、本発明のドライクリーニング用洗浄剤組成物には
これらの成分の他に、貯蔵時の溶液安定化剤及び粘度低
下剤として、通常のドライクリーニング用洗浄剤組成物
に配合されるメチルアルコール、エチルアルコール、イ
ソプロピルアルコール、ブチルアルコールのような低級
アルコールを添加することが出来る。また、エチルセロ
ソルブ、プロピルセルソルブ、ブチルセルソルブ等の低
級アルキルモノエーテルを添加することも可能であり、
これら低級アルキルモノエーテル等は十分に効果的であ
る。更に必要であれば、ベンゾトリアゾールのような金
属腐食防止剤、ビフェニル系又はクマリン系の螢光剤や
香料の添加も可能である。In addition to these components, the dry cleaning detergent composition of the present invention also contains methyl alcohol, which is added to ordinary dry cleaning detergent compositions, as a solution stabilizer and viscosity reducing agent during storage. Lower alcohols such as ethyl alcohol, isopropyl alcohol, butyl alcohol can be added. It is also possible to add lower alkyl monoethers such as ethyl cellosolve, propyl cellosolve, butyl cellosolve, etc.
These lower alkyl monoethers are sufficiently effective. Furthermore, if necessary, it is also possible to add a metal corrosion inhibitor such as benzotriazole, a biphenyl-based or coumarin-based fluorescent agent, and a fragrance.
本発明のドライクリーニング用洗浄剤組成物は相安定性
に優れ、しかも優れた水可溶化能（抱水能）を有する為
、市販の石油系溶剤の何れに対しても均一なササラ液を
作ることができ、しかもササラ液が作りやすい洗浄剤で
ある。The dry cleaning detergent composition of the present invention has excellent phase stability and excellent water solubilization ability (water-holding ability), so it can form a uniform liquid with any commercially available petroleum solvent. It is a cleaning agent that can be used as a detergent, and the sasara liquid is easy to make.
以下、実施例を挙げ本発明の詳細な説明するが、本発明
はこれらの実施例に制約されるものではない。EXAMPLES Hereinafter, the present invention will be described in detail with reference to Examples, but the present invention is not limited to these Examples.
実施例−１
表−１に示す各種ドライクリーニング用洗浄剤組成物を
調製し、洗浄剤／水−１／１ （容量比）の混合時の状
態及び水可溶化能を下記試験法により評価した。Example-1 Various dry cleaning detergent compositions shown in Table-1 were prepared, and the state and water solubilization ability at the time of mixing of detergent/water-1/1 (volume ratio) were evaluated by the following test method. .
結果を併せて表−１に示した。The results are also shown in Table-1.
〈洗浄剤／水−１／１混合時の状態〉
ドライクリーニング用洗浄剤５Ｑ＋ｎｌと水５０−を２
００ ｍｌビーカーに取り、良く混合し、状態を判定す
る。混合時透明であることがササラ液の作りやすさの条
件となる。判定は以下の通りである。<Cleaning agent/water - 1/1 mixing condition> 2 parts of dry cleaning detergent 5Q+nl and water 50-
00 ml beaker, mix well, and judge the condition. Being transparent during mixing is a condition for making sasara liquid easily. The judgment is as follows.
○・・・混合時透明
△・・・混合時半透明
×・・・混合時不透明
く水可溶化能〉
１００ ｍ／乳化試験管に石油系溶剤４０ｍ／とドライ
クリーニング用洗浄剤５−を混合後、水をシリンジで０
．５ ｍ７ずつ添加し良く振盪する。溶液が白濁するま
での水の添加量（ｍりを水の可溶化能とする。○...Transparent when mixed △...Transparent during half of mixing ×...opaque when mixed, water solubilizable> 100 m/Mix petroleum solvent 40 m/and dry cleaning detergent 5- in an emulsification test tube After that, add water with a syringe.
．． Add 5 m7 each and shake well. The amount of water added until the solution becomes cloudy (the solubilization capacity of water is defined as the amount of water added until the solution becomes cloudy).
実施例−２
市販の石油系溶剤を用いて、表−２に示すドライクリー
ニング用洗浄剤組成物を調製し、洗浄剤／水−１／１混
合時の状態を調べた。Example 2 Using a commercially available petroleum solvent, a dry cleaning detergent composition shown in Table 2 was prepared, and the state at the time of 1/1 mixing of detergent/water was investigated.
結果も表−２に示した。The results are also shown in Table-2.
また、この組成物を用いて洗浄剤／水／各社石油系溶剤
−１／１／８ （容量比）からなるササラ液を調製し、
その状態を調べた。In addition, using this composition, a sasara liquid consisting of cleaning agent/water/manufacturer's petroleum solvent - 1/1/8 (volume ratio) was prepared,
I investigated its condition.
結果を表−３に示した。The results are shown in Table-3.
表 −２
＊ ニューソールデラックス（日本石油■製）芳香族炭
化水素含量 １９．９％
表 −３
ルＢ
本 実施例１の洗浄剤／水−１／１混合時の状態評価と
同基準により評価した。Table -2 * New Sole Deluxe (manufactured by Nippon Oil) Aromatic hydrocarbon content 19.9% Table -3 LeB Book Evaluation based on the same criteria as in Example 1 when the cleaning agent/water was mixed 1/1 did.
Claims (1)
学式、表等があります▼（II） （式中Ｒ＿１、Ｒ＿２及びＲ＿３は、互いに同一であっ
ても異なっていてもよい直鎖又は分岐鎖を有する炭素数
１〜２０のアルキル基又はアルケニル基、又は水素原子
、アルカリ金属、アルカリ土類金属、有機アミンを表す
。但し、Ｒ＿１、Ｒ＿２及びＲ＿３のうち少なくとも２
つはアルキル基又はアルケニル基である。Ｘは、アルカ
リ金属、アルカリ土類金属又は有機アミンを示す） で表されるスルホトリカルバリル酸エステル塩の１種又
はそれ以上の混合物を含有することを特徴とするドライ
クリーニング用洗浄剤組成物。[Claims] The following general formula (I) or (II): ▲There are mathematical formulas, chemical formulas, tables, etc.▼(I)▲There are mathematical formulas, chemical formulas, tables, etc.▼(II) (In the formula, R_1, R_2 and R_3 are a linear or branched alkyl group or alkenyl group having 1 to 20 carbon atoms, which may be the same or different from each other, or a hydrogen atom, an alkali metal, an alkaline earth metal, or an organic amine. However, at least 2 of R_1, R_2 and R_3
One is an alkyl group or an alkenyl group. A detergent composition for dry cleaning, characterized in that it contains one or more mixtures of sulfotricarballylic acid ester salts (X represents an alkali metal, an alkaline earth metal, or an organic amine).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1206188A JPH01188595A (en) | 1988-01-22 | 1988-01-22 | Cleaning agent composition for dry cleaning |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1206188A JPH01188595A (en) | 1988-01-22 | 1988-01-22 | Cleaning agent composition for dry cleaning |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01188595A true JPH01188595A (en) | 1989-07-27 |
Family
ID=11795084
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1206188A Pending JPH01188595A (en) | 1988-01-22 | 1988-01-22 | Cleaning agent composition for dry cleaning |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01188595A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6706076B2 (en) | 2000-06-05 | 2004-03-16 | Procter & Gamble Company | Process for separating lipophilic fluid containing emulsions with electric coalescence |
| US6706677B2 (en) | 2000-06-05 | 2004-03-16 | Procter & Gamble Company | Bleaching in conjunction with a lipophilic fluid cleaning regimen |
| US6818021B2 (en) | 2000-06-05 | 2004-11-16 | Procter & Gamble Company | Domestic fabric article refreshment in integrated cleaning and treatment processes |
| US6840069B2 (en) | 2000-06-05 | 2005-01-11 | Procter & Gamble Company | Systems for controlling a drying cycle in a drying apparatus |
| US6930079B2 (en) | 2000-06-05 | 2005-08-16 | Procter & Gamble Company | Process for treating a lipophilic fluid |
| US7345016B2 (en) | 2003-06-27 | 2008-03-18 | The Procter & Gamble Company | Photo bleach lipophilic fluid cleaning compositions |
-
1988
- 1988-01-22 JP JP1206188A patent/JPH01188595A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6706076B2 (en) | 2000-06-05 | 2004-03-16 | Procter & Gamble Company | Process for separating lipophilic fluid containing emulsions with electric coalescence |
| US6706677B2 (en) | 2000-06-05 | 2004-03-16 | Procter & Gamble Company | Bleaching in conjunction with a lipophilic fluid cleaning regimen |
| US6818021B2 (en) | 2000-06-05 | 2004-11-16 | Procter & Gamble Company | Domestic fabric article refreshment in integrated cleaning and treatment processes |
| US6828292B2 (en) | 2000-06-05 | 2004-12-07 | Procter & Gamble Company | Domestic fabric article refreshment in integrated cleaning and treatment processes |
| US6840069B2 (en) | 2000-06-05 | 2005-01-11 | Procter & Gamble Company | Systems for controlling a drying cycle in a drying apparatus |
| US6930079B2 (en) | 2000-06-05 | 2005-08-16 | Procter & Gamble Company | Process for treating a lipophilic fluid |
| US6998377B2 (en) | 2000-06-05 | 2006-02-14 | Procter & Gamble Company | Process for treating a lipophilic fluid |
| US7345016B2 (en) | 2003-06-27 | 2008-03-18 | The Procter & Gamble Company | Photo bleach lipophilic fluid cleaning compositions |
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