JPH011798A - cleaning composition - Google Patents
cleaning compositionInfo
- Publication number
- JPH011798A JPH011798A JP62-156510A JP15651087A JPH011798A JP H011798 A JPH011798 A JP H011798A JP 15651087 A JP15651087 A JP 15651087A JP H011798 A JPH011798 A JP H011798A
- Authority
- JP
- Japan
- Prior art keywords
- sodium
- chlorine dioxide
- cleaning composition
- surfactant
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims description 13
- 238000004140 cleaning Methods 0.000 title claims description 12
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims description 42
- 239000004155 Chlorine dioxide Substances 0.000 claims description 21
- 235000019398 chlorine dioxide Nutrition 0.000 claims description 21
- 150000003839 salts Chemical class 0.000 claims description 11
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 6
- XOAAWQZATWQOTB-UHFFFAOYSA-N Taurine Natural products NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 claims description 5
- 229960003080 taurine Drugs 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 4
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 description 24
- 125000000217 alkyl group Chemical group 0.000 description 10
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 8
- 239000000460 chlorine Substances 0.000 description 8
- 229910052801 chlorine Inorganic materials 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- 125000002947 alkylene group Chemical group 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000004659 sterilization and disinfection Methods 0.000 description 6
- 239000003205 fragrance Substances 0.000 description 5
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- -1 aliphatic carboxylate Chemical class 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- BACYUWVYYTXETD-UHFFFAOYSA-N N-Lauroylsarcosine Chemical compound CCCCCCCCCCCC(=O)N(C)CC(O)=O BACYUWVYYTXETD-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004332 deodorization Methods 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 108700004121 sarkosyl Proteins 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- BZXMNFQDWOCVMU-UHFFFAOYSA-N 2-[dodecanoyl(methyl)amino]acetic acid;sodium Chemical compound [Na].CCCCCCCCCCCC(=O)N(C)CC(O)=O BZXMNFQDWOCVMU-UHFFFAOYSA-N 0.000 description 1
- QWYVYEYZQCJFJI-UHFFFAOYSA-N 2-[methyl(tetradecanoyl)amino]acetic acid;sodium Chemical compound [Na].CCCCCCCCCCCCCC(=O)N(C)CC(O)=O QWYVYEYZQCJFJI-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- OTTPFCJTQXRWHO-UHFFFAOYSA-N 3-(2,3-dichloroanilino)cyclohex-2-en-1-one Chemical compound ClC1=CC=CC(NC=2CCCC(=O)C=2)=C1Cl OTTPFCJTQXRWHO-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- DIOYAVUHUXAUPX-KHPPLWFESA-N Oleoyl sarcosine Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CC(O)=O DIOYAVUHUXAUPX-KHPPLWFESA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- GWVPJQDUGPKIOI-UQKRIMTDSA-N [Na].CCCCCCCCCCCC(=O)CN[C@@H](C)C(O)=O Chemical compound [Na].CCCCCCCCCCCC(=O)CN[C@@H](C)C(O)=O GWVPJQDUGPKIOI-UQKRIMTDSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- JEMLSRUODAIULV-UHFFFAOYSA-M potassium;2-[dodecanoyl(methyl)amino]acetate Chemical compound [K+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O JEMLSRUODAIULV-UHFFFAOYSA-M 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- PWWJJDVDTKXWOF-UHFFFAOYSA-M sodium;2-[hexadecanoyl(methyl)amino]ethanesulfonate Chemical compound [Na+].CCCCCCCCCCCCCCCC(=O)N(C)CCS([O-])(=O)=O PWWJJDVDTKXWOF-UHFFFAOYSA-M 0.000 description 1
- HJXBXTZDPSSEST-UHFFFAOYSA-M sodium;2-[methyl(tetradecanoyl)amino]ethanesulfonate Chemical compound [Na+].CCCCCCCCCCCCCC(=O)N(C)CCS([O-])(=O)=O HJXBXTZDPSSEST-UHFFFAOYSA-M 0.000 description 1
- VYPDUQYOLCLEGS-UHFFFAOYSA-M sodium;2-ethylhexanoate Chemical compound [Na+].CCCCC(CC)C([O-])=O VYPDUQYOLCLEGS-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は二酸化塩素の水溶液に特定の２種類の界面活性
剤を配合してなる漂白ならびに消毒、殺菌作用を有し、
長期に亙って二酸化塩素の分解が防止された安定な洗浄
剤組成物を提供するものである。Detailed Description of the Invention (Industrial Application Field) The present invention has bleaching, disinfection, and sterilization effects by blending two specific types of surfactants into an aqueous solution of chlorine dioxide,
The present invention provides a stable cleaning composition in which decomposition of chlorine dioxide is prevented over a long period of time.
（従来技術及び発明が解決しようとする問題点）二酸化
塩素は漂白、殺菌、消毒および防臭等の目的で広く使用
されている。最近では、界面活性剤を配合して浸透力を
付与することにより、衣類の漂白剤、カビ取り剤、防カ
ビ剤など住宅用の洗浄剤として使用することも検討され
ている。しかしながら、一般に二酸化塩素は強力な酸化
剤であるため、セッケンに代表される一般の界面活性剤
を配合した場合には、該界面活性剤がいずれも塩析また
は分解され、かつ二酸化塩素の安定性も著しく阻害され
る。この傾向は二酸化゛塩素−界面活性剤の系に、特に
塩素臭をマスキングする目的で香料を添加した場合に顕
著である。したがって、従来、二酸化塩素に界面活性剤
及び香料を配合した洗浄剤は市販されていない、そのた
め、特に界面活性剤による二酸化塩素の分解が少なく、
長期に亙って安定な洗浄剤が要求されている。(Prior Art and Problems to be Solved by the Invention) Chlorine dioxide is widely used for purposes such as bleaching, sterilization, disinfection and deodorization. Recently, by incorporating surfactants to impart penetrating power, it has been considered to be used as a cleaning agent for clothes, as a bleaching agent for mold, as a mold remover, and as a mold preventive agent for household use. However, since chlorine dioxide is generally a strong oxidizing agent, if a general surfactant such as soap is added, the surfactant will be salted out or decomposed, and the stability of chlorine dioxide will increase. is also significantly inhibited. This tendency is particularly noticeable when a fragrance is added to the chlorine dioxide-surfactant system for the purpose of masking the odor of chlorine. Therefore, conventionally, there are no commercially available cleaning agents that contain chlorine dioxide, surfactants, and fragrances.
There is a need for cleaning agents that are stable over a long period of time.
（課題を解決するための手段）
本発明者等は上記した課題に鑑み鋭意研究の結果、二酸
化塩素の水溶液に２種類の特定の界面活性剤を組合わせ
て配合することにより、上記した問題が解決され、所期
の目的が達成されることを見い出し、本発明を提案する
に至った。(Means for Solving the Problems) In view of the above-mentioned problems, the present inventors have conducted intensive research and found that the above-mentioned problems can be solved by blending a combination of two specific surfactants into an aqueous solution of chlorine dioxide. The inventors have found that the problem can be solved and the intended purpose can be achieved, and have come to propose the present invention.
即ち、本発明は二酸化塩素の水溶液に、（ａ）Ｎ−アシ
ルアミノ酸、Ｎ−アシルタウリン及びこれらの塩よりな
る群から選ばれた少なくとも一種の化合物
及び
（ｂ）脂肪族カルボン酸塩及び／又は脂肪族スルホン酸
塩
を配合してなる洗浄剤組成物である。That is, the present invention provides an aqueous solution of chlorine dioxide containing (a) at least one compound selected from the group consisting of N-acyl amino acids, N-acyl taurine, and salts thereof, and (b) an aliphatic carboxylate and/or This is a cleaning composition containing an aliphatic sulfonate.
本発明に用いられる二酸化塩素の水溶液は、公知ものも
が特に制限なく用いられる。一般には、炭酸ナトリウム
、炭酸水素ナトリウム、水酸化ナトリウム、ペルオクソ
炭酸アルカリ、及び過酸化アルカリ等の公知の安定剤が
配合された安定化二酸化塩素の水溶液が好ましい。二酸
化塩素水ｆｌｉ液の有効塩素量は、漂白、殺菌、消毒、
防カビ及び防臭等の効果を勘案すると、一般に１．５〜
１５重量％、好ましくは、２〜８％の範囲であることが
好適である。As the aqueous solution of chlorine dioxide used in the present invention, any known aqueous solution can be used without particular limitation. Generally, stabilized aqueous solutions of chlorine dioxide containing known stabilizers such as sodium carbonate, sodium bicarbonate, sodium hydroxide, alkali peroxocarbonate, and alkali peroxide are preferred. The amount of available chlorine in chlorine dioxide solution is for bleaching, sterilization, disinfection,
Considering the effects of mold prevention and deodorization, it is generally 1.5~
A suitable amount is 15% by weight, preferably in the range from 2 to 8%.
上記の二酸化塩素の水′？ｉｇ液には、次の２種類の界
面活性剤が配合される。The above chlorine dioxide water′? The following two types of surfactants are blended into the ig liquid.
（ａ） Ｎ−アシルアミノ酸、Ｎ−アシルタウリン及び
これらの塩よりなる群から選ばれた少なくとも１種の化
合物（以下、界面活性剤Ａともいう。）（ｂ）脂肪族カ
ルボン酸塩及び／又は脂肪族スルホン酸塩（以下、界面
活性剤Ｂともいう。）上記の特定の２種の界面活性剤を
配合することにより該界面活性剤が塩析または分解され
ることはなく、また、二酸化塩素の分解も防止される。(a) at least one compound selected from the group consisting of N-acyl amino acids, N-acyl taurine, and salts thereof (hereinafter also referred to as surfactant A) (b) aliphatic carboxylate and/or Aliphatic sulfonate (hereinafter also referred to as surfactant B) By blending the above two specific surfactants, the surfactant will not be salted out or decomposed, and chlorine dioxide will not be salted out or decomposed. decomposition is also prevented.
本発明で用いられる界面活性剤の一秤であるＮ−アシル
アミノ酸及びその塩としては、公知の化合物が何ら制限
なく使用される。一般には、下記式で示されるＮ−アシ
ルアミノ酸及びその塩が好適に使用される。As the N-acylamino acid and its salt, which are one of the surfactants used in the present invention, known compounds can be used without any restriction. Generally, N-acylamino acids represented by the following formulas and salts thereof are preferably used.
Ｒ＋ −Ｃ−Ｎ−Ｒ３−Ｃ００Ｍ
但し、Ｒ１はアルキル基であり、Ｒ２は水素原子又はア
ルキル基であり、Ｒ３はアルキレン基であり、Ｍは水素
原子又はアルカリ金属である。R+ -C-N-R3-C00M However, R1 is an alkyl group, R2 is a hydrogen atom or an alkyl group, R3 is an alkylene group, and M is a hydrogen atom or an alkali metal.
上記式中、Ｒ１及びＲ２のアルキル基並びにＲのアルキ
レン基の炭素数は特に制限されるものではないが、界面
活性剤の効果を発揮させ、また、安定な洗浄剤組成物を
得るためには、Ｒ１のアルキル基は５〜１４の範囲、Ｒ
２のアルキル基は１〜５の範回、Ｒ３のアルキレン基は
】〜５の範囲であることが好ましい。また、Ｍで示され
るアルカリ金属としては、リチウム、ナトリウム、カリ
ウ、ム等が制限されずに用い得る。In the above formula, the number of carbon atoms in the alkyl groups of R1 and R2 and the alkylene group of R is not particularly limited, but in order to exert the effect of the surfactant and obtain a stable cleaning composition, , the alkyl group of R1 is in the range of 5 to 14, R
The alkyl group of 2 is preferably in the range of 1 to 5, and the alkylene group of R3 is preferably in the range of 1 to 5. Moreover, as the alkali metal represented by M, lithium, sodium, potassium, mu, etc. can be used without limitation.
本発明に於いて好適に使用されるＮ−アシルアミノ酸及
びその塩を具体的に例示すると次のとおりである０例え
ば、Ｎ−ココイルサルコシンナトリウム、Ｎ−ラウロイ
ルサルコシン、Ｎ−ラウロイルサルコシンナトリウム、
Ｎ−ラウロイルサルコシンカリウム、Ｎ−ミリストイル
サルコシンナトリウム、Ｎ−バルミトイルサルコシンナ
トリウム、Ｎ−オレオイルサルコシン、Ｎ−ラウロイル
メチルアラニンナトリウム等で、中でもＮ−ラウロイル
サルコシン、Ｎ−ラウロイルサルコシンンナトリウムが
好適である。Specific examples of N-acyl amino acids and salts thereof preferably used in the present invention are as follows. For example, N-cocoylsarcosine sodium, N-lauroylsarcosine, N-lauroylsarcosine sodium,
Potassium N-lauroylsarcosine, sodium N-myristoylsarcosine, sodium N-balmitoylsarcosine, N-oleoylsarcosine, sodium N-lauroylmethylalanine, etc., of which N-lauroylsarcosine and sodium N-lauroylsarcosine are preferred. be.
また、Ｎ−アシルタウリン及びその塩としては、公知の
化合物が何ら制限なく使用される。一般には下記式で示
されるＮ−アシルタウリン及びその塩が好適に使用され
る。Moreover, as N-acyl taurine and its salt, known compounds can be used without any restrictions. Generally, N-acyltaurine and its salts represented by the following formula are preferably used.
〒゛
Ｒａ−Ｃ−Ｎ−Ｒ５−５０３Ｍ
但し、Ｒ４はアルキル基であり、Ｒ５は水素原子又はア
ルキル基であり、Ｒ６はアルキレン基であり、Ｍは水素
原子又はアルカリ金属である。゛Ra-C-N-R5-503M However, R4 is an alkyl group, R5 is a hydrogen atom or an alkyl group, R6 is an alkylene group, and M is a hydrogen atom or an alkali metal.
上記式中、Ｒ４及びＲ５のアルキル基並びにＲ６のアル
キレン基の炭素数は特に制限されるものではないが、界
面活性剤の効果を発揮させ、また、安定な洗浄剤組成物
を得るためには、Ｒ４のアルキル基は５〜１４の範囲、
Ｒ５のアルキル基は１〜５の範囲、Ｒ６のアルキレン基
は１〜５の範囲であることが好ましい、また、Ｍで示さ
れるアルカリ金属としては、リチウム、ナトリウム、カ
リウム等が制限されずに用い得る。In the above formula, the number of carbon atoms in the alkyl groups of R4 and R5 and the alkylene group of R6 are not particularly limited, but in order to exert the effect of the surfactant and obtain a stable cleaning composition, , the alkyl group of R4 is in the range of 5 to 14,
The alkyl group of R5 is preferably in the range of 1 to 5, and the alkylene group of R6 is preferably in the range of 1 to 5.Also, as the alkali metal represented by M, lithium, sodium, potassium, etc. can be used without limitation. obtain.
乙４２−
本発明に於いて好適に使用されるＮ−アシルタウリン及
びその塩を具体的に例示すると次のとおりである。例え
ば、Ｎ−ココイルメチルタウリンナトリウム、Ｎ−ラウ
ロイルメチルタウリンナトリウム、Ｎ−ミリストイルメ
チルタウリンナトリウム、Ｎ−パルミトイルメチルタウ
リンナトリム。Otsu 42 - Specific examples of N-acyl taurine and its salts preferably used in the present invention are as follows. For example, sodium N-cocoylmethyltaurate, sodium N-lauroylmethyltaurate, sodium N-myristoylmethyltaurate, sodium N-palmitoylmethyltaurate.
Ｎ−ステアロイルメチルタウリンナトリウム等である。N-stearoylmethyl taurine sodium and the like.
次に本発明で用いられる脂肪族カルボン酸塩及び脂肪族
スルホン酸塩としては、公知の化合物が何ら制限されず
用い得る。一般には炭素数が１２〜１日の飽和酸が好ま
しい。具体的にはラウリン酸、ミリスチン酸、パルミチ
ン酸、ステアリン酸。Next, as the aliphatic carboxylate and aliphatic sulfonate used in the present invention, known compounds can be used without any restriction. Generally, saturated acids having 12 to 1 carbon atoms are preferred. Specifically, lauric acid, myristic acid, palmitic acid, and stearic acid.
オレイン酸のナトリウム塩やカリウム塩、あるいは２−
エチレンヘキサン酸ナトリウム、２−エチレンヘキシル
硫酸ナトリウム、ネオデカン酸ナトリウム等が特に制限
なく用いられるが、特に２−エチルヘキサン酸ナトリウ
ムが好適である。Sodium salt or potassium salt of oleic acid, or 2-
Sodium ethylenehexanoate, sodium 2-ethylenehexyl sulfate, sodium neodecanoate, etc. can be used without particular limitation, but sodium 2-ethylhexanoate is particularly preferred.
本発明の洗浄剤組成物は、二酸化塩素の水溶液に対して
上記した界面活性剤Ａを０．０４〜５重改％、好ましく
は０．５〜２重量％と界面活性剤Ｂを０．０６〜４重量
％、好ましくは０．５〜２重改％の割合で含有すること
が好ましい。また、界面活性剤Ａと界面活性剤Ｂとの割
合は、重量比で１：１．５〜１：２．５が好適である。The cleaning composition of the present invention contains 0.04 to 5%, preferably 0.5 to 2% by weight of the surfactant A and 0.06% by weight of the surfactant B based on the aqueous solution of chlorine dioxide. It is preferably contained in a proportion of 4% by weight, preferably 0.5% to 2% by weight. Further, the ratio of surfactant A to surfactant B is preferably 1:1.5 to 1:2.5 by weight.
本発明の洗浄剤組成物を調製する方法は特に制限されず
、一般に予め所定の界面活性剤を調整した後、該界面活
性剤と所定濃度の二酸化塩素の水溶液を混合する方法が
用いられる。この際、上記成分の他に水、香料及び悪影
響を及ぼさない範囲で他の公知の界面活性剤を使用する
ことも可能である。特に本発明では香料を含む系におい
ても、二酸化塩素の分解が抑制されることも大きな特徴
の一つである。The method for preparing the cleaning composition of the present invention is not particularly limited, and generally a method is used in which a predetermined surfactant is prepared in advance and then the surfactant is mixed with an aqueous solution of chlorine dioxide at a predetermined concentration. At this time, in addition to the above-mentioned components, it is also possible to use water, fragrance, and other known surfactants to the extent that they do not have an adverse effect. In particular, one of the major features of the present invention is that the decomposition of chlorine dioxide is suppressed even in systems containing fragrances.
（効 果）
以上に記載の如く、特定した２種類の界面活性剤を組合
せて配合することにより得られる本発明の洗浄剤組成物
は、長期に亙って二酸化塩素の分解が抑制され、また界
面活性剤が塩析或いは分解することのない安定な洗浄剤
組成物である。従つて、本発明の洗浄剤組成物は、衣類
の漂白剤、殺菌剤、消毒剤、カビ取り剤及び防カビ剤等
として有効である。(Effects) As described above, the cleaning composition of the present invention obtained by combining the two specified surfactants suppresses the decomposition of chlorine dioxide over a long period of time, and It is a stable detergent composition in which the surfactant does not salt out or decompose. Therefore, the cleaning composition of the present invention is effective as a clothing bleach, a disinfectant, a disinfectant, a mold remover, a mold preventive agent, and the like.
（実施例）
以下、本発明を実施例に基づき詳細に説明するが、本発
明は以下の実施例に限定されるものではない。(Examples) Hereinafter, the present invention will be described in detail based on Examples, but the present invention is not limited to the following Examples.
実施例１
第１表に示す組成の洗浄剤組成物をそれぞれ密封容器中
に５０℃の温度でｌケ月問保存したのち、有効塩素濃度
を測定した。その結果を第１表に示した。Example 1 Each of the cleaning compositions shown in Table 1 was stored in a sealed container at a temperature of 50° C. for one month, and then the effective chlorine concentration was measured. The results are shown in Table 1.
尚、第１表に示した二酸化塩素の水溶液の種類を示す記
号は、Ａ；オスロン（商品名：大阪曹達−製、有効塩素
６％）、Ｂ；ビオトーク（商品名：助用化学■製、有効
塩素６％）である。また、香料は、ＰｅｒｆｕｍｅＳＨ
１７１７，ＲＡ７Ｆ１３９６９及び、ＢＡ７８３７ （
いずれも高砂香料■製）を用いた。The symbols indicating the types of aqueous solutions of chlorine dioxide shown in Table 1 are A: Oslon (product name: Osaka Soda Co., Ltd., available chlorine 6%), B: Biotalk (product name: Souyo Kagaku ■ Co., Ltd., available chlorine 6%); 6% effective chlorine). In addition, the fragrance is PerfumeSH
1717, RA7F13969 and BA7837 (
Both products were manufactured by Takasago Kogyo ■.
手続補正書
昭和６２年 ７月 ８日
昭和６２年６月２５日提出の特許願
２、発明の名称
洗浄剤組成物
３、補正をする者
π件との関係 特許出願人
郵便番号 ７４５
住 所 １１１０県徳山市御影町１番１号連絡先
東京都港区西新橋１−４−５”徳１１１曹達株式会社
東京本部 特許情報部
ＴＥｌ、 Ｏ：（−５９７−５１１１
゛〜＼。Procedural amendment document July 8, 1988 Patent application 2 filed on June 25, 1988, name of invention Cleaning composition 3, person making the amendment Relationship with the item π Patent applicant Postal code 745 Address 1110 1-1 Mikage-cho, Tokuyama City, Prefecture Contact information
1-4-5 Nishi-Shinbashi, Minato-ku, Tokyo Toku 111 Soda Co., Ltd. Tokyo Headquarters Patent Information Department TEL: (-597-5111 ゛〜＼.
４、補正の対象 明細書の「発明の詳細な説明」の欄 ５、補正の内容 （１）明細有第３頁１２行目 「ものも」を「のもの」に訂正する。4. Subject of correction “Detailed description of the invention” column in the specification 5. Contents of correction (1) With details, page 3, line 12 Correct "monomo" to "mono".
（２）明細臀第３頁２０行目
「これは、二酸化塩素の濃度で表示すると０゜６〜６重
量％、好ましくは０．８〜３重竜％となる。」を挿入す
る。(2) On page 3, line 20 of the specification, insert the following line: ``When expressed as a concentration of chlorine dioxide, it is 0.6 to 6% by weight, preferably 0.8 to 3% by weight.''
（３）明細書第５頁２行目 「Ｒ」を「Ｒ３」に訂正する。(3) Line 2 of page 5 of the specification Correct "R" to "R3".
（４）明細書第９頁１５行目、１６行目「有効塩素６％
」を「二酸化塩素濃度６％」に訂正する。(4) Page 9, lines 15 and 16 of the specification “6% available chlorine
" should be corrected to "chlorine dioxide concentration 6%."
（５）明細書第９頁１７行目
ｒＰｅｒｆｕｍｅｓＨ１７１７Ｊを「パーフユーム ５
Ｈ１７１７」に訂正する。(5) Perfumes H1717J on page 9, line 17 of the specification
H1717”.
以上that's all
Claims (1)
れらの塩よりなる群から選ばれた少なくとも一種の化合
物及び （ｂ）脂肪族カルボン酸塩及び／又は脂肪族スルホン酸
塩 を配合してなる洗浄剤組成物[Claims] 1) In an aqueous solution of chlorine dioxide, (a) at least one compound selected from the group consisting of N-acyl amino acids, N-acyl taurine, and salts thereof, and (b) an aliphatic carboxylic acid. Cleaning composition containing salt and/or aliphatic sulfonate
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15651087A JPH07119436B2 (en) | 1987-06-25 | 1987-06-25 | Cleaning composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15651087A JPH07119436B2 (en) | 1987-06-25 | 1987-06-25 | Cleaning composition |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPH011798A true JPH011798A (en) | 1989-01-06 |
| JPS641798A JPS641798A (en) | 1989-01-06 |
| JPH07119436B2 JPH07119436B2 (en) | 1995-12-20 |
Family
ID=15629347
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15651087A Expired - Lifetime JPH07119436B2 (en) | 1987-06-25 | 1987-06-25 | Cleaning composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH07119436B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9021798B2 (en) | 2008-10-10 | 2015-05-05 | Norrhydro Oy | Digital hydraulic system |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5837670A (en) * | 1995-04-18 | 1998-11-17 | Hartshorn; Richard Timothy | Detergent compositions having suds suppressing properties |
| EP1566100A1 (en) * | 2004-02-20 | 2005-08-24 | Erich Dr. Schmid | Bleaching, disinfectant, deodorant and/or oxidizing agents based on chlorine dioxide |
| WO2007107898A2 (en) * | 2006-03-17 | 2007-09-27 | The Procter & Gamble Company | Process of bleaching fabric |
| EP1835016A1 (en) * | 2006-03-17 | 2007-09-19 | The Procter and Gamble Company | Process of bleaching fabric |
| EP1837395A3 (en) * | 2006-03-17 | 2007-10-03 | The Procter and Gamble Company | Process of bleaching fabric |
| JP4986888B2 (en) * | 2008-03-05 | 2012-07-25 | 株式会社ヤクルト本社 | Growth inhibitor for heat-resistant acidophilic bacteria and method for inhibiting growth of heat-resistant acidophilic bacteria |
-
1987
- 1987-06-25 JP JP15651087A patent/JPH07119436B2/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9021798B2 (en) | 2008-10-10 | 2015-05-05 | Norrhydro Oy | Digital hydraulic system |
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