JPH01179756A - Oxide magnetic material - Google Patents
Oxide magnetic materialInfo
- Publication number
- JPH01179756A JPH01179756A JP63002401A JP240188A JPH01179756A JP H01179756 A JPH01179756 A JP H01179756A JP 63002401 A JP63002401 A JP 63002401A JP 240188 A JP240188 A JP 240188A JP H01179756 A JPH01179756 A JP H01179756A
- Authority
- JP
- Japan
- Prior art keywords
- oxide
- weight
- magnetic material
- oxide magnetic
- excepting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000696 magnetic material Substances 0.000 title claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 7
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 7
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims abstract 5
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 6
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 3
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 2
- 230000035699 permeability Effects 0.000 abstract description 13
- 239000000470 constituent Substances 0.000 abstract 3
- 229910052681 coesite Inorganic materials 0.000 abstract 2
- 229910052906 cristobalite Inorganic materials 0.000 abstract 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 229910052682 stishovite Inorganic materials 0.000 abstract 2
- 229910052905 tridymite Inorganic materials 0.000 abstract 2
- 239000000292 calcium oxide Substances 0.000 abstract 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 5
- 229910001935 vanadium oxide Inorganic materials 0.000 description 5
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical class [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 3
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 229910000859 α-Fe Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- KFAFTZQGYMGWLU-UHFFFAOYSA-N oxo(oxovanadiooxy)vanadium Chemical compound O=[V]O[V]=O KFAFTZQGYMGWLU-UHFFFAOYSA-N 0.000 description 2
- VASIZKWUTCETSD-UHFFFAOYSA-N oxomanganese Chemical compound [Mn]=O VASIZKWUTCETSD-UHFFFAOYSA-N 0.000 description 2
- 229910052815 sulfur oxide Inorganic materials 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 238000009740 moulding (composite fabrication) Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Magnetic Ceramics (AREA)
- Soft Magnetic Materials (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は高初透磁率かつ低損失を有する通信用の変成器
磁心に使用するに適した酸化物磁性材料に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to an oxide magnetic material having high initial permeability and low loss and suitable for use in transformer cores for communications.
近年、酸化物磁性材料は小型化かつ高性能化がますます
要求されてきている。In recent years, there has been an increasing demand for smaller size and higher performance of oxide magnetic materials.
そのため、初透磁率を大きくする必要があるが。 Therefore, it is necessary to increase the initial magnetic permeability.
初透磁率を大きくすると、相対的に損失が大きくなり、
高透磁率を維持したまま損失特性を改善することは困難
である。When the initial permeability is increased, the loss becomes relatively large,
It is difficult to improve loss characteristics while maintaining high magnetic permeability.
そこで本発明の技術的課題は、前記の緒特性を満足する
酸化物磁性材料を提供することである。Therefore, a technical object of the present invention is to provide an oxide magnetic material that satisfies the above characteristics.
本発明によれば、２０〜３０モルチの酸化マンガン（Ｍ
ｎＯ） 、 ２０〜２５モルチの酸化亜鉛、残分として
、酸化第二鉄を主成分とし、又、副成分として、０．０
１０重量％以下（０％を含まず）の二酸化ケイ素（Ｓｉ
Ｏ２）と０．０２０重量襲以下（０％を含まず）の酸化
カルシウム（ＣａＯ）を含むＭｎ−Ｚｎ系フェライトで
ある酸化物磁性材料に、酸化イオウ（ＳＯ３）を０．１
０−０．５０重量％と０１０重量重量下（０％を含まず
）の酸化バナジウム（Ｖ２Ｏ３）とを添加することによ
り、高透磁率かつ低損失係数を有する酸化物磁性材料を
提供するものである。According to the invention, 20 to 30 molty manganese oxide (M
nO), 20 to 25 molti of zinc oxide, with ferric oxide as the main component and 0.0 as a minor component.
10% by weight or less (excluding 0%) of silicon dioxide (Si
0.1 sulfur oxide (SO3) is added to an oxide magnetic material which is Mn-Zn ferrite containing calcium oxide (CaO) of 0.020% by weight or less (excluding 0%).
By adding vanadium oxide (V2O3) of 0-0.50% by weight and less than 0.10% (excluding 0%), an oxide magnetic material with high magnetic permeability and low loss coefficient is provided. be.
以下２本発明の詳細な説明する。 Two aspects of the present invention will be described in detail below.
丑ず、主成分として５２．０モル％の酸化第二鉄（Ｆｅ
２０３） 、 ２５モル％の一酸化マンガン（ＭｎＯ）
及び２３０モル係の酸化亜鉛（ＺｎＯ）を含有し、副成
分として、０．００５重量係の二酸化ケイ素（ＳｉＯ２
）と００１０重量饅重量化カルシウム（ＣａＯ）を含有
する従来組成のＭｎ−Ｚｎ系フェライトに酸化イオウ（
ｓｏ３） ｏ〜０６０重量係、酸化バナゾウム（Ｖ２Ｏ
３）０〜０１５重量％それぞれ、単独あるいは複合添加
し、混合、予備焼成造粒し、成形プレスした後。52.0 mol% of ferric oxide (Fe
203), 25 mol% manganese monoxide (MnO)
and 230 molar mass of zinc oxide (ZnO), and 0.005 molar mass of silicon dioxide (SiO2) as a subcomponent.
) and sulfur oxide (
so3) o~060 weight, vanazium oxide (V2O
3) After adding 0 to 015% by weight individually or in combination, mixing, pre-calcination and granulation, and forming and pressing.
窒素ガス雰囲気中に於て所定の酸素分圧を保ち。Maintains a specified oxygen partial pressure in a nitrogen gas atmosphere.
１３５０℃〜１４００°Ｃの温度範囲で焼成した。It was fired at a temperature range of 1350°C to 1400°C.
その場合の１０ ｋＨｚでの初透磁率μ。、相対損失係
数ｔａｎδ／μ、ヒステリシス損失係数ｈｌｏを第１表
に示す。Initial permeability μ at 10 kHz in that case. , relative loss coefficient tanδ/μ, and hysteresis loss coefficient hlo are shown in Table 1.
第 １ 表 ※本発明の範囲外のもの 以下余日 その結果、酸化イオウ（ＳＯ３）の単独添加では。Table 1 *Things outside the scope of the present invention Remaining days below As a result, when sulfur oxide (SO3) is added alone.
０．１０〜０５００〜０５０重量％透磁率μ０の１０〜
１５％の向上、相対損失係数ｔａｎδ／μ及びヒステリ
シス損失系数ｈｌｏの改善が認められる。0.10-0500-050% by weight Magnetic permeability μ0 10-
An improvement of 15%, relative loss coefficient tan δ/μ, and hysteresis loss coefficient hlo are observed.
一方、酸化バナジウム（Ｖ２Ｏ３）の単独添加では。On the other hand, when vanadium oxide (V2O3) is added alone.
０．０５〜０．１０重量係の範囲で相対損失係数ｔａｎ
δ／μ及びヒステリシス損失ｈｌｏの改善は認められる
が、初透磁率が低下している。Relative loss coefficient tan in the range of 0.05 to 0.10 weight coefficient
Improvements in δ/μ and hysteresis loss hlo are recognized, but the initial permeability is reduced.
酸化イオウ（ＳＯｓ）及び酸化バナジウム（Ｖ２Ｏ３）
を同時に添加したところ、前記それぞれの単独効果が認
められる範囲内で初透磁率μ０ 、相対損失係数ｔａｎ
δ／μ及びヒステリシス損失ｈｌｏの顕著な改善がみら
れる。Sulfur oxides (SOs) and vanadium oxides (V2O3)
When added at the same time, the initial permeability μ0 and the relative loss coefficient tan decreased within the range where the independent effects of each of the above were recognized.
A significant improvement in δ/μ and hysteresis loss hlo is seen.
すなわち、酸化イオウ（８０３） ０．１０〜０．５０
重量係、酸化バナゾウム（Ｖ２Ｏ３） ０．０５〜０１
０重量％の範囲で、初透磁率μＯば、酸化イオウ（ＳＯ
３）の単独添加にみられた１０〜１５％の向上のままで
相対損失係数ｔａｎδ／μは約１／２〜２／３に、ヒス
テリシス損失係数ｈｌｏについても約１／２〜２／３に
改善された。That is, sulfur oxide (803) 0.10-0.50
Weight, vanazium oxide (V2O3) 0.05-01
In the range of 0% by weight, the initial magnetic permeability μO, sulfur oxide (SO
While maintaining the 10-15% improvement seen in the single addition of 3), the relative loss coefficient tan δ/μ is reduced to approximately 1/2 to 2/3, and the hysteresis loss coefficient hlo is also reduced to approximately 1/2 to 2/3. Improved.
尚、酸化イオウ及び酸化バナゾウムの前記以外の添加範
囲では、初透磁率の低下、相対損失係数及びヒステリシ
ス損失係数の増大を来たすので好ましくない。It should be noted that addition of sulfur oxide and vanadium oxide in a range other than the above is not preferable because it causes a decrease in the initial magnetic permeability and an increase in the relative loss coefficient and hysteresis loss coefficient.
以上の説明のとおシ１本発明によれば、０１０〜０５０
重量％の酸化イオウ（ＳＯ３）と０〜０１０重量％（Ｏ
は含まず）の酸化バナジウムとを同時に添加することに
より、従来のＭｎ−Ｚｎ系フェライトに関して、初透磁
率を向上させかつ相対損失係数、ヒステリシス損失係数
を大幅に改良することができる。According to the above explanation 1, according to the present invention, 010 to 050
% by weight of sulfur oxide (SO3) and 0-010% by weight (O
By simultaneously adding vanadium oxide (excluding Mn--Zn ferrite), it is possible to improve the initial permeability and significantly improve the relative loss coefficient and hysteresis loss coefficient with respect to conventional Mn--Zn ferrite.
Claims (1)
（ＭｎＯ），２０〜２５モル％の酸化亜鉛（ＺｎＯ），
残部として酸化第二鉄（Ｆｅ＿２Ｏ＿３）を含み，副成
分として０．０１０重量％以下（０％を含まず）の二酸
化ケイ素（ＳｉＯ＿２）と，０．０２０重量％以下（０
％を含まず）の酸化カルシウム（ＣａＯ）とを含む酸化
物磁性材料において，０．１０〜０．５０重量％の酸化
イオウ（ＳＯ＿３）と０．１０重量％以下（０％を含ま
ず）の酸化バナジウム（Ｖ＿２Ｏ＿５）とが添加されて
いることを特徴とする酸化物磁性材料。(1) Main components: 20-30 mol% manganese oxide (MnO), 20-25 mol% zinc oxide (ZnO),
Contains ferric oxide (Fe_2O_3) as the remainder, silicon dioxide (SiO_2) of 0.010% by weight or less (excluding 0%) as accessory components, and 0.020% by weight or less (0%) of silicon dioxide (SiO_2) as accessory components.
In an oxide magnetic material containing 0.10 to 0.50% by weight of sulfur oxide (SO_3) and 0.10% by weight or less (excluding 0%) of calcium oxide (CaO), An oxide magnetic material characterized in that vanadium oxide (V_2O_5) is added.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63002401A JPH01179756A (en) | 1988-01-11 | 1988-01-11 | Oxide magnetic material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63002401A JPH01179756A (en) | 1988-01-11 | 1988-01-11 | Oxide magnetic material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01179756A true JPH01179756A (en) | 1989-07-17 |
Family
ID=11528219
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63002401A Pending JPH01179756A (en) | 1988-01-11 | 1988-01-11 | Oxide magnetic material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01179756A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6402979B1 (en) * | 1999-08-26 | 2002-06-11 | Tdk Corporation | Magnetic ferrite material and manufacture method thereof |
-
1988
- 1988-01-11 JP JP63002401A patent/JPH01179756A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6402979B1 (en) * | 1999-08-26 | 2002-06-11 | Tdk Corporation | Magnetic ferrite material and manufacture method thereof |
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