JPH01170651A - Joint compound of normal temperature type and packing thereof - Google Patents

Joint compound of normal temperature type and packing thereof

Info

Publication number
JPH01170651A
JPH01170651A JP33112387A JP33112387A JPH01170651A JP H01170651 A JPH01170651 A JP H01170651A JP 33112387 A JP33112387 A JP 33112387A JP 33112387 A JP33112387 A JP 33112387A JP H01170651 A JPH01170651 A JP H01170651A
Authority
JP
Japan
Prior art keywords
weight
cement
joint material
joints
asphalt emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP33112387A
Other languages
Japanese (ja)
Inventor
Takayuki Kobayashi
孝行 小林
Masaaki Takahashi
正明 高橋
Mineo Oshita
大下 峰生
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Showa Shell Sekiyu KK
Original Assignee
Showa Shell Sekiyu KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Showa Shell Sekiyu KK filed Critical Showa Shell Sekiyu KK
Priority to JP33112387A priority Critical patent/JPH01170651A/en
Publication of JPH01170651A publication Critical patent/JPH01170651A/en
Pending legal-status Critical Current

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  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Sealing Material Composition (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

PURPOSE:To obtain a joint compound of normal temperature type maintaining excellent fluidity, permeability and workability, having precuring properties and displacement follow-up properties, blending asphalt emulsion containing a specific diamine as an emulsifying material with cement. CONSTITUTION:100 pts.wt. asphalt emulsion containing 40-75wt.% calculated as solid content of a diamine shown by the formula (R is 11-20C saturated or unsaturated aliphatic hydrocarbon; RI and RII are 1-4C lower alkyl) as an emulsifying material is blended with 1-30 pts.wt. cement and, if necessary, 1-30 pts.wt. cement just before packing into joints and impregnated into the joints.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、コンクリート舗装、床等目地を必要とする構
築物、または剛性舗装の接合部上に充填する常温型目地
材、およびその充填方法に関する。
[Detailed Description of the Invention] [Field of Industrial Application] The present invention relates to a room-temperature type joint material to be filled onto joints of concrete pavements, structures requiring joints such as floors, or rigid pavements, and a method for filling the same. .

〔従来の技術〕[Conventional technology]

−aに目地とは、第4図に示すようなコンクリート舗装
、床等の構築物、または剛性舗装の接合部のことをいう
が、目地材はその目地内に充填され、接合部を強化する
と共に、コンクリート舗装、床または剛性舗装の膨張、
収縮に対応する機能をも要求されるものである。
-a Joints refer to joints between concrete pavements, structures such as floors, or rigid pavements as shown in Figure 4, and joint material is filled into the joints to strengthen the joints and , expansion of concrete pavements, floors or rigid pavements,
A function to cope with contraction is also required.

従来目地材としては、常温型としてウレタン系のもの、
アスファルトエマルジョンと系のもの、アスファルトを
使用する加熱型のもの、溶剤カットバンク型のものが知
られている。
Conventional joint materials include urethane-based joint materials that are room temperature type,
There are known asphalt emulsion type, heating type using asphalt, and solvent cut bank type.

(発明が解決しようとする問題点〕 しかしながら、従来の常温型のアスファルトエマルジョ
ン系のものは硬化するまで時間がかかり、またウレタン
系のものは、施工性が悪(、耐久性にしても弾性率が高
すぎて、ひび割れ等の現象も起きる。また加熱型は充填
率が悪く、溶剤カットバンク型は硬化時間が相当必要で
道路等の目地材としては不適当である。
(Problems to be solved by the invention) However, conventional room-temperature asphalt emulsion-based products take a long time to harden, and urethane-based products have poor workability (and, even in terms of durability, elastic modulus is too high, causing phenomena such as cracking.Furthermore, the heating type has a poor filling rate, and the solvent-cut bank type requires considerable curing time, making it unsuitable as a joint material for roads, etc.

目地材としては、変位追随性、即ち目地幅の伸収縮は、
主に温度変化によって発生するが温度変化により生じる
歪の歪み速度は非常に小さいが、目地材の引っ張り強度
が小さければ、コンクリート等の本体への影響が小さい
、また自動車等、振動等の歪み速度の早い荷重等が作用
する場合には、目地材に相応した引っ張り強度が要求さ
れる。また常温で施工でき、浸透性が高く、しかも早期
硬化性が要求される。
As a joint material, displacement followability, that is, expansion and contraction of joint width, is
This is mainly caused by temperature changes, but the strain rate of strain caused by temperature changes is very small, but if the tensile strength of the joint material is small, the effect on the main body of concrete etc. is small. When fast loads are applied, tensile strength suitable for the joint material is required. In addition, it must be able to be applied at room temperature, have high permeability, and have early curing properties.

〔問題点を解決するための手段〕[Means for solving problems]

そのため、本発明は一般式 (式中、RH炭素数11ないし20の飽和または不飽和
脂肪族炭化水素基、R′およびR”は同種または異種の
炭素数1ないし4の低級アルキル基である)で示される
ジアミンを乳化材とした固形分40〜75重景%有重量
アスファルトエマルジョン100重量部に対して、セメ
ント1〜30重量部、必要に応じて水を加えてなる常温
型目地材、およびその充填方法を提供することを特徴と
する。
Therefore, the present invention is directed to the general formula (wherein RH is a saturated or unsaturated aliphatic hydrocarbon group having 11 to 20 carbon atoms, and R' and R'' are the same or different lower alkyl groups having 1 to 4 carbon atoms). A room-temperature type joint material made by adding 1 to 30 parts by weight of cement and water as necessary to 100 parts by weight of a weighted asphalt emulsion with a solid content of 40 to 75% by weight using diamine as an emulsifying agent, and The present invention is characterized by providing a method for filling the same.

本発明で使用する乳化剤は、本出願人による特願昭62
−162476号に記載されているジアミンを使用する
が、特に上記一般式におけるRがラウリル基、ミリスチ
ル基、パルミチル基、ステアリル基、オレイル基、リノ
ール基、リルイン基のもの、R’ 、Rゝがメチル基、
エチル基、プロピル基、ブチル基のものが好適である。
The emulsifier used in the present invention is
The diamine described in No. 162476 is used, especially when R in the above general formula is a lauryl group, myristyl group, palmityl group, stearyl group, oleyl group, linole group, or lyluine group, and R′ and R′ are methyl group,
Ethyl, propyl, and butyl groups are preferred.

尚、上記乳化剤として、ジアミンにゴムラテックス、例
えばスチレンブタジェンゴム、ネオプレンゴム、スチレ
ンイソプレンゴム、ブチルゴム、ブタジェンアクリロニ
トリルゴム等を10重量%以下の使用量で加えて使用し
てもよい。
As the emulsifier, a rubber latex such as styrene-butadiene rubber, neoprene rubber, styrene-isoprene rubber, butyl rubber, butadiene-acrylonitrile rubber, etc. may be added to the diamine in an amount of 10% by weight or less.

アスファルトの配合量は、通常40〜75重景%、重量
しくは55〜70重量%が使用される。
The amount of asphalt used is usually 40 to 75% by weight, or 55 to 70% by weight.

また本発明のアスファルトエマルジョンは上記ジアミン
の中和当量以上の燐酸水溶液を添加することにより、ジ
アミンの混和性を促進させることができる。該中和剤の
配合量は0.30〜5重量%、好ましくは0. 8〜4
.5重量%が適当である。
Further, in the asphalt emulsion of the present invention, the miscibility of the diamine can be promoted by adding an aqueous phosphoric acid solution in an amount equal to or more than the neutralization equivalent of the diamine. The amount of the neutralizing agent blended is 0.30 to 5% by weight, preferably 0.30% to 5% by weight. 8-4
.. 5% by weight is suitable.

セメントとしては、通常の水硬性セメント、例えばポル
トランドセメント、早強ポルトランドセメント、アルミ
ナセメント、ジェットセメント、フライアッシュセメン
ト、白色ポルトランドセメント、超早強セメント等を使
用できる。
As the cement, common hydraulic cements such as Portland cement, early strength Portland cement, alumina cement, jet cement, fly ash cement, white Portland cement, and ultra early strength cement can be used.

水は、施工現場で気温に応じて適宜、添加水を加減する
ことで適度の流動性が得られるようにする。
The amount of water added at the construction site is adjusted according to the temperature so that appropriate fluidity can be obtained.

セメント量の加減で硬化時間が調整できる。Curing time can be adjusted by adjusting the amount of cement.

〔作用〕[Effect]

目地材は、コンクリート舗装、床等目地を必要とする構
築物、または剛性舗装の定形状接合部に充填され、接合
部を強化すると共に、コンクリート舗装、床または剛性
舗装の膨張、収縮を吸収する&i街材としての機能をも
要求される。
Joint fillers are filled into fixed-shaped joints of concrete pavements, floors, and other structures that require joints, or rigid pavements, to strengthen the joints and absorb expansion and contraction of concrete pavements, floors, or rigid pavements. It is also required to function as a street material.

本発明で使用するアスファルトエマルジョンは、貯蔵安
定性(J l5K−2208) 、フルイ残留物(J 
l5K−2208) 、付着面積(J[5K−2208
)、蒸発残留物(JISK−2208)、可使用時間(
スラリーシールの攪拌可能時間)、貫入量、耐摩耗性、
耐流動抵抗性がすぐれている。本発明は硬化材としての
セメントを、アスファルトエマルジョンに対して1〜3
0重四%混合することにより、良好な流動性、浸透性と
作業性を維持しながらも、目地材として必要な早期硬化
性、変位追従性をも同時に有することを見出したもので
あり、目地材として適した組成物である。
The asphalt emulsion used in the present invention has storage stability (J 15K-2208), sieve residue (J
l5K-2208), adhesion area (J[5K-2208
), evaporation residue (JISK-2208), pot life (
slurry seal agitation time), penetration amount, wear resistance,
Excellent flow resistance. In the present invention, cement as a hardening agent is added to an asphalt emulsion in an amount of 1 to 3.
It was discovered that by mixing 0x4%, while maintaining good fluidity, permeability and workability, it also has the early hardening properties and displacement followability required as a joint material. The composition is suitable as a material.

〔実施例〕〔Example〕

(アスファルトエマルジョンの製法) N(3−ジメチルアミノプロピル)ミリスチルアミド8
0gを燐酸水溶液(燐酸80g、水1455g)に加え
て乳化液を作製した。一方、140〜150℃に加熱熔
融したアスファルト3300gを上記乳化液1700g
に添加し、溶融混練し、本発明で使用するアスファルト
エマルジョンを作製した。
(Production method of asphalt emulsion) N (3-dimethylaminopropyl) myristylamide 8
0 g was added to a phosphoric acid aqueous solution (phosphoric acid 80 g, water 1455 g) to prepare an emulsion. On the other hand, 3300 g of asphalt heated and melted at 140 to 150°C was added to 1700 g of the above emulsion.
The asphalt emulsion used in the present invention was prepared by adding the asphalt to the solution and melting and kneading it.

(目地材の充填方法) 上記アスファルトエマルジョン400g、水30g、ポ
ルトランドセメント40gを別々に用意し、施工現場に
おいてまず、セメントと水を混合し、アスファルトエマ
ルジョンに加え、充分に混合する(約30秒)。混合が
不充分であると硬化しないことがある。この混合物を模
擬目地(幅1Qmm、深さ50mm、長さ200mm)
に流し込んだ。
(Method of filling joint material) Separately prepare 400 g of the above asphalt emulsion, 30 g of water, and 40 g of Portland cement. At the construction site, first mix the cement and water, add it to the asphalt emulsion, and mix thoroughly (about 30 seconds). . If mixing is insufficient, curing may not occur. Use this mixture as a mock joint (width 1Qmm, depth 50mm, length 200mm)
poured into.

(試験方法) ■ 引っ張り強度 歪み制御による引っ張り試験で測定される目地材の破壊
応力。
(Test method) ■ Fracture stress of joint material measured by tensile strength strain control tensile test.

■ 許容歪 引っ張り試験における破壊にいたるまでの歪。■ Allowable strain Strain leading to failure in a tensile test.

■ 充填率(%) 同一の容積、形状を有する目地を作製し、目地容積に対
する目地材の注入容積の比。
■Filling rate (%) Joints with the same volume and shape are prepared, and the ratio of the volume of joint material injected to the joint volume.

■ 硬化時間 注入後、充分に供用に耐える状態にいたるまでに要する
時間。
■ Curing time: The time required to reach a state that can be used sufficiently after injection.

■ 目減り沈下量、はだわかれ隙間幅 上記充填率についての1年後のデータ。■ Amount of sinkage, separation gap width Data regarding the above filling rate after one year.

まず、引っ張り強度についての試験結果を第1図に示す
First, the test results regarding tensile strength are shown in FIG.

第1図に示すごとく、本発明の目地材が従来の樹脂系の
ものに比較して変位追従性に優れていることを示してい
る。
As shown in FIG. 1, it is shown that the joint material of the present invention has excellent displacement followability compared to the conventional resin-based material.

即ち、目地幅の伸収縮は、主に温度変化によって発生す
るが、温度変化により生じる伸収縮時の歪み速度は非常
に小さいが、目地材の引っ張り強度が小さければ、コン
クリート等の本体への影響が小さい。自動車等、振動等
の歪み速度の早い荷重等が作用する場合には、目地材に
相応した引っ張り強度が要求され、歪み速度に応じた変
位追随性は、目地材にとって重要な性質である。
In other words, expansion and contraction of the joint width mainly occurs due to temperature changes, but the strain rate during expansion and contraction caused by temperature changes is very small, but if the tensile strength of the joint material is small, it will have a negative impact on the main body of the concrete etc. is small. When a load with a high strain rate such as vibration is applied, such as in an automobile, the joint material is required to have tensile strength corresponding to the strain rate, and the ability to follow displacement according to the strain rate is an important property for the joint material.

次ぎに、許容歪についての試験結果を第2図に示す。Next, FIG. 2 shows test results regarding allowable strain.

本発明の目地材は、ウレタン系目地材に比較して許容歪
が大きいことがわかる。
It can be seen that the joint material of the present invention has a larger allowable strain than the urethane joint material.

本発明の目地材を、従来のウレタン系目地材、アスファ
ルトエマルジョン、加熱型のストレートアスファルト、
ゴム入りアスファルト、ブローンンアスファルト、溶剤
カットバック型のストレートアスファルト、ゴム入りア
スファルト、ブローンンアスファルトと、充填率、硬化
時間、施工性、目減り沈下量、はだわかれ隙間幅、1年
後の状況の各項目についての結果を、第3図に示す。
The joint material of the present invention can be used as a conventional urethane joint material, asphalt emulsion, heated straight asphalt,
Rubber-containing asphalt, blown asphalt, solvent cutback straight asphalt, rubber-containing asphalt, and blown asphalt, filling rate, curing time, workability, loss of settlement, separation gap width, and status after one year. The results for each item are shown in Figure 3.

本発明の目地材は、従来の目地材と比較して、総合的に
見て優れた性質を示した。
The joint material of the present invention exhibited overall superior properties compared to conventional joint materials.

〔発明の効果〕〔Effect of the invention〕

セメント分をアスファルトエマルジョンに対して1〜3
0重量%とする組成となるように、施工現場で作製して
使用することにより、目地材としての使用に適した、良
好な流動性、浸透性と作業性を維持しつつ、早期硬化性
、変位追従性をも可能としうる目地材となしえた。
The cement content is 1 to 3 to the asphalt emulsion.
By preparing and using it at the construction site so that it has a composition of 0% by weight, it maintains good fluidity, permeability and workability suitable for use as a joint material, and has early hardening properties. It was possible to create a joint material that can also follow displacement.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明目地材の歪速度と応力との関係の説明図
、第2図は本発明目地材の歪速度と許容歪との関係の説
明図、第3図は従来の目地材と本発明目地材との、充填
率、硬化時間、施工性、目減り沈下量、はだわかれ隙間
幅、1年後の状況の各項目についての比較図、第4図は
各種接合部と目地との関係を断面図で示す説明図である
Figure 1 is an explanatory diagram of the relationship between the strain rate and stress of the joint material of the present invention, Figure 2 is an explanatory diagram of the relationship between the strain rate and allowable strain of the joint material of the present invention, and Figure 3 is an explanatory diagram of the relationship between the strain rate and the allowable strain of the joint material of the present invention. A comparison diagram of the filling rate, curing time, workability, amount of loss and settlement, separation gap width, and status after one year with the joint material of the present invention. Figure 4 shows the comparison between various joints and joints. FIG. 3 is an explanatory diagram showing the relationship in a cross-sectional view.

Claims (2)

【特許請求の範囲】[Claims] (1)一般式 ▲数式、化学式、表等があります▼ (式中、Rは炭素数11ないし20の飽和または不飽和
脂肪族炭化水素基、R’およびR”は同種または異種の
炭素数1ないし4の低級アルキル基である)で示される
ジアミンを乳化材とした固形分40〜75重量%有する
アスファルトエマルジョン100重量部に対して、セメ
ント1〜30重量部と、必要に応じて水を加えてなる常
温型目地材。
(1) General formula ▲ Numerical formula, chemical formula, table, etc. ▼ (In the formula, R is a saturated or unsaturated aliphatic hydrocarbon group having 11 to 20 carbon atoms, and R' and R'' are the same or different 1-carbon group. 1 to 30 parts by weight of cement and, if necessary, water are added to 100 parts by weight of an asphalt emulsion having a solid content of 40 to 75% by weight using a diamine represented by 4 to 4 lower alkyl groups as an emulsifying agent. Room temperature type joint material.
(2)一般式 ▲数式、化学式、表等があります▼ (式中、Rは炭素数11ないし20の飽和または不飽和
脂肪族炭化水素基、R’およびR”は同種または異種の
炭素数1ないし4の低級アルキル基である)で示される
ジアミンを乳化材とした固形分40〜75重量%有する
アスファルトエマルジョン100重量部に対して、セメ
ント1〜30重量部を、目地への充填直前に、必要に応
じて水を加えて混合し、目地に注入することからなる常
温型目地材の充填方法。
(2) General formula ▲ There are mathematical formulas, chemical formulas, tables, etc. Immediately before filling the joints, 1 to 30 parts by weight of cement is added to 100 parts by weight of an asphalt emulsion having a solid content of 40 to 75% by weight using a diamine represented by 4 to 4 lower alkyl groups as an emulsifying agent, A method of filling room-temperature joint material, which consists of adding water as needed, mixing, and injecting it into the joint.
JP33112387A 1987-12-26 1987-12-26 Joint compound of normal temperature type and packing thereof Pending JPH01170651A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP33112387A JPH01170651A (en) 1987-12-26 1987-12-26 Joint compound of normal temperature type and packing thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP33112387A JPH01170651A (en) 1987-12-26 1987-12-26 Joint compound of normal temperature type and packing thereof

Publications (1)

Publication Number Publication Date
JPH01170651A true JPH01170651A (en) 1989-07-05

Family

ID=18240126

Family Applications (1)

Application Number Title Priority Date Filing Date
JP33112387A Pending JPH01170651A (en) 1987-12-26 1987-12-26 Joint compound of normal temperature type and packing thereof

Country Status (1)

Country Link
JP (1) JPH01170651A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0665194A1 (en) * 1994-01-19 1995-08-02 Jean-Louis Chardonnens Process for the production of a building material, building material thus obtained, and use of this material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0665194A1 (en) * 1994-01-19 1995-08-02 Jean-Louis Chardonnens Process for the production of a building material, building material thus obtained, and use of this material

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