JPH01139659A - Marking ink - Google Patents
Marking inkInfo
- Publication number
- JPH01139659A JPH01139659A JP62297470A JP29747087A JPH01139659A JP H01139659 A JPH01139659 A JP H01139659A JP 62297470 A JP62297470 A JP 62297470A JP 29747087 A JP29747087 A JP 29747087A JP H01139659 A JPH01139659 A JP H01139659A
- Authority
- JP
- Japan
- Prior art keywords
- water
- ink
- parts
- oil
- mark
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002904 solvent Substances 0.000 claims abstract description 17
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 15
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 15
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 15
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims abstract description 10
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims abstract description 10
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims abstract description 10
- 229920000896 Ethulose Polymers 0.000 claims abstract description 9
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 claims abstract description 9
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 claims abstract description 9
- 239000001023 inorganic pigment Substances 0.000 claims description 4
- 238000004043 dyeing Methods 0.000 claims description 3
- 239000012860 organic pigment Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 26
- 229910000831 Steel Inorganic materials 0.000 abstract description 13
- 239000000975 dye Substances 0.000 abstract description 13
- 239000010959 steel Substances 0.000 abstract description 13
- 239000003960 organic solvent Substances 0.000 abstract description 7
- 238000001035 drying Methods 0.000 abstract description 6
- 239000000463 material Substances 0.000 abstract description 6
- 239000000049 pigment Substances 0.000 abstract description 6
- 238000007689 inspection Methods 0.000 abstract description 5
- 230000001988 toxicity Effects 0.000 abstract description 3
- 231100000419 toxicity Toxicity 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract 2
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 239000007850 fluorescent dye Substances 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 34
- 239000000976 ink Substances 0.000 description 30
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 21
- 229910052742 iron Inorganic materials 0.000 description 17
- 239000007864 aqueous solution Substances 0.000 description 12
- 238000005507 spraying Methods 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 238000009472 formulation Methods 0.000 description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000001514 detection method Methods 0.000 description 6
- 230000002378 acidificating effect Effects 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000007822 coupling agent Substances 0.000 description 3
- 239000011324 bead Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000006249 magnetic particle Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
に関するものであって、主として角ビレットやパイプの
如き各種鋼材の探傷検査ラインにおける目印し付けに利
用される。DETAILED DESCRIPTION OF THE INVENTION This invention relates to [industrial application field] and is mainly used for marking in flaw detection inspection lines of various steel materials such as square billets and pipes.
周知の通シ、各種鋼材の探傷検査ラインにおいては、白
色や赤色の鮮明な色彩のインク又はブラックライト（紫
外線灯）の照射下で鮮明に発光する螢光インクによって
鋼材表面の検出された傷の部分に目印しか付けられてい
るが、探傷検査ラインの自動化にともない上記の目印し
を付けるに当っても、上記インクをノズル噴射によって
吹付けるというマーキング手段が採られており、このマ
ーキング手段に用いられるインクは、一般ｋ「スプレー
ミーキングインク」或いは単に「マーキングインク」と
呼ばれている。As is well known, in flaw detection inspection lines for various steel materials, flaws detected on the surface of steel materials are detected using brightly colored ink such as white or red, or fluorescent ink that clearly emits light under black light (ultraviolet light). Only marks are placed on the parts, but with the automation of flaw detection inspection lines, a marking method has been adopted in which the above-mentioned marks are sprayed by a nozzle jet. The ink used is generally called "spray marking ink" or simply "marking ink."
また、最近では、上記マーキング手段を利用して工場内
の各種部品や製品に、整理、分類、保証等の為の記号等
を付ける・ことも行われている。Furthermore, recently, the above-mentioned marking means have been used to attach symbols and the like to various parts and products in a factory for organizing, classifying, guaranteeing, etc.
そして、上記マーキング手段に用いられる上記インク（
以下、「マーキングインク」という。）としては、■速
乾性であること（通常、対象物に吹付は後１０〜６０秒
程度で乾燥すること。）、■乾燥後、比較的強い被膜面
が形成されること及び■吹付は面が水で濡れていても■
、■が満されること（通常、鋼材等の探傷検査には磁粉
液を用いた湿式磁粉探傷法−、Ｔ工Ｓ Ｇ○５６５−１
９７４−が用いられており、この探傷法による場合には
検査直後の鋼材面一マーキングインクを吹付ける面一は
水で濡れている）等の性能が要求されることもよく知ら
れている。The ink used in the marking means (
Hereinafter, it will be referred to as "marking ink." ): ■ It dries quickly (normally, it dries in about 10 to 60 seconds after spraying on the object.) ■ After drying, a relatively strong coating is formed, and ■ It can be sprayed on a surface. Even if it is wet with water■
,■ must be satisfied (Usually, wet magnetic particle testing method using magnetic particle liquid is used for flaw detection of steel materials, etc.) T Engineering SG○565-1
974- is used, and it is well known that this flaw detection method requires performance such as (the surface of the steel material where the marking ink is sprayed immediately after inspection is wet with water).
従来、上記■〜■の性能要求を満たすマーキングインク
として種々の処方のものが実用されているが、代表的な
ものとしては、特公昭５４−２２１４５ベースとしたマ
ーキングインクが挙げられる。Hitherto, various formulations of marking inks have been put into practical use that meet the above-mentioned performance requirements (1) to (3), and a typical marking ink is a marking ink based on Japanese Patent Publication No. 54-22145.
従来のマーキングインクは、いづれも前記■〜■の性能
要求を満たしておシマーキング自体には問題はないが、
マーキングしたマーク（被膜）を除去するに当っては有
機溶剤を使用しなければ容易に除去できないという問題
点をもっている。All of the conventional marking inks meet the performance requirements listed above (■ to ■), and there is no problem with the marking itself.
There is a problem in that the marked mark (coating) cannot be easily removed without using an organic solvent.
即ち、例えばマーキングインクを施用してマークを付け
た後、当該マークを除去して置かないと商品価値が下が
ってしまう場合にはマークを除去して置かなければなら
ないが、この場合、有機溶剤の使用が必須であると、火
気、毒性等の点で種々の問題が発生してくるのである。That is, for example, if a mark is applied by applying marking ink and the product value will decrease unless the mark is removed, the mark must be removed.In this case, the mark must be removed. If its use is essential, various problems arise in terms of fire, toxicity, etc.
本発明者は、有機溶剤を使用せずに水、温水、弱アルカ
リ性水溶液又は弱酸性水溶液で容易に除去できるマーキ
ングインクを求めて、数多くの市販品及び前掲公報を始
めとする本発明者が調査し得た限シの公知処方について
除去試験を行ったが、前記■〜■の性能要求を満たして
いながら水、温水、弱アルカリ性水溶液又は酸性水溶液
で容易に除去できるものを見出すことができ外かった。In search of a marking ink that can be easily removed with water, hot water, a weakly alkaline aqueous solution, or a weakly acidic aqueous solution without using an organic solvent, the present inventor has researched many commercially available products and the above-mentioned publication. We conducted a removal test on the limited number of known formulations that could be used, but we were unable to find one that satisfies the performance requirements listed above but can be easily removed with water, hot water, a weakly alkaline aqueous solution, or an acidic aqueous solution. Ta.
本発明者は、上記現況に鑑み、前記■〜■の要求を満た
し、且つ有機溶剤を使用しなくとも水等によって容易に
除去できるマーキングインクを提供することを技術的課
題として研究を重ねた結果、本発明を完成したものであ
る。In view of the above-mentioned current situation, the present inventor has conducted repeated research on the technical issue of providing a marking ink that satisfies the above-mentioned requirements (1) to (3) and can be easily removed with water or the like without using an organic solvent. , has completed the present invention.
即ち、１本発明け、ヒドロキシグロビルセルロース又ハ
エチルピドロキシエチルセルロースヲ０．１〜５重量部
と無機顔料、有機顔料、染色油溶性染料又は畳光油溶性
染料を０．１〜５重量部と炭化水素系溶剤を８０〜９９
重量部とを含む水う先住マーキングインクである。That is, according to the present invention, 0.1 to 5 parts by weight of hydroxyglobil cellulose or haethyl pidroxyethyl cellulose and 0.1 to 5 parts by weight of an inorganic pigment, an organic pigment, a dyeing oil-soluble dye or a light oil-soluble dye. and hydrocarbon solvents from 80 to 99
An indigenous marking ink containing parts by weight.
本発明に係る水洗性マーキングインクは、対象物の吹付
は面が乾燥状態であるときは勿論、湿った状態であって
も吹付は後１０〜６０秒程度ですみやかに乾燥し、乾燥
後は指で触ったシ振動が加わったシした程度では剥離し
ない被膜面が形成されるものであるにもか＼わらず、有
機溶剤を用いなくとも水、温水、弱アルカリ性水溶液又
は弱酸性水溶液によって容易に洗浄除去することができ
る。The water-washable marking ink according to the present invention can be sprayed not only when the surface is dry, but even when the surface is wet, it dries quickly in about 10 to 60 seconds, and after drying, it can be used with the fingertips. Although a coating surface is formed that does not peel off even when exposed to vibrations, it can be easily removed with water, hot water, weakly alkaline aqueous solution, or weakly acidic aqueous solution without using an organic solvent. Can be removed by washing.
上記作用は、被膜形成樹脂としてヒドロキシプロピルセ
ルロース、エチルヒドロキシエチルセルロースを用い、
溶媒として炭化水素系溶剤を用いるとともに配合割合を
特定した結果のものであって、ヒドロキシプロピルセル
ロース、エチルヒドロキシエチルセルロースによって形
成される樹脂被膜が水溶性であることと炭化水素系溶剤
が疎水性であることによって水等による洗浄性並びに被
膜の速乾性の両特性が満されているのである。The above action uses hydroxypropylcellulose and ethylhydroxyethylcellulose as the film-forming resin,
This is the result of using a hydrocarbon solvent as a solvent and specifying the blending ratio, and the resin coating formed by hydroxypropyl cellulose and ethyl hydroxyethyl cellulose is water-soluble, and the hydrocarbon solvent is hydrophobic. As a result, both the properties of cleaning with water and the quick drying properties of the film are satisfied.
次に、本発明を実施するに当っての諸条件を説明する。Next, various conditions for implementing the present invention will be explained.
ヒドロキシプロピルセルロース、エチルヒドロキシエチ
ルセルロースは市販の粉末状又はベレット状製品を用い
ればよい。As for hydroxypropyl cellulose and ethyl hydroxyethyl cellulose, commercially available powder or pellet products may be used.
炭化水素系溶剤としては、塩化メチレン、１゜１．１−
トリクロルエタン、イソプロピルアルコール、メタノー
ルを用いればよい。Examples of hydrocarbon solvents include methylene chloride, 1°1.1-
Trichloroethane, isopropyl alcohol, and methanol may be used.
着色剤としては、無機顔料、有機顔料、染色油溶性染料
、螢光油溶性染料のいずれでも用いることができる。As the coloring agent, any of inorganic pigments, organic pigments, dyeing oil-soluble dyes, and fluorescent oil-soluble dyes can be used.
ヒドロキシプロピルセルロース又はエチルヒドロキシエ
チルセルロースは、少くとも０．１重量部以上が必要で
あシ、これ以下では形成される被膜が弱くなってしまい
実用できない。含量を多くすればするはど強い被膜とな
るが、５重量部以上とすると洗浄時の除去性が悪くなっ
てしまう。Hydroxypropylcellulose or ethylhydroxyethylcellulose must be used in an amount of at least 0.1 part by weight; if it is less than this, the film formed will be too weak to be practical. If the content is increased, the film will be stronger, but if the content exceeds 5 parts by weight, the removability during washing will be poor.
着色剤は、少くとも０．１重量部以上が必要であシ、こ
れ以下では着色度合又は螢光輝度が薄く目印しとしての
役目かはたせなくなってしまう。５重量部までの含量に
よって実用上充分な指示が得られ、また油溶性染料を用
いる場合には５重量部以上とすると完全、に溶解しない
ことがある。The coloring agent must be used in an amount of at least 0.1 part by weight; if the amount is less than this, the degree of coloring or fluorescence brightness will be too weak to serve as a marker. A content of up to 5 parts by weight provides sufficient indication for practical use, and when oil-soluble dyes are used, they may not be completely dissolved if the content exceeds 5 parts by weight.
炭化水素系溶剤を８０〜９９重量部とするのは、上記二
者の溶剤としての必要量であるとともに速乾性並びにノ
ズルによる噴射性を満足させるための好２ｉ１景である
からである。尚、前掲の各炭化水素系溶剤を適宜組合せ
て用いるが、塩化メチレンを６０重量部以上用いる必要
がある。The reason why the amount of the hydrocarbon solvent is 80 to 99 parts by weight is because it is the necessary amount of the above-mentioned two solvents, and is also favorable for satisfying quick drying properties and jetting performance by a nozzle. In addition, although the above-mentioned hydrocarbon solvents are used in appropriate combinations, it is necessary to use 60 parts by weight or more of methylene chloride.
尚、ＤＯＰやＴＣＰの如き可塑剤やカップリング剤等の
所要の添加剤の必要量（通常、１〜２Ｍ量部程度）を配
合してもよい。In addition, necessary amounts (usually about 1 to 2 M parts) of necessary additives such as plasticizers and coupling agents such as DOP and TCP may be blended.
上述の通シの処方によれば、前記■〜■の要求を満たし
、且つ有機溶剤を使用しなくとも水等によって容易に除
去できる水洗性マーキングインクが得られることが保証
できる。According to the above-mentioned formula, it can be guaranteed that a water-washable marking ink that satisfies the requirements (1) to (4) above and can be easily removed with water or the like without using an organic solvent can be obtained.
次に、本発明に係る水洗性マーキングインクの製造法を
説明する。Next, a method for producing a water-washable marking ink according to the present invention will be explained.
製造法は極めて容易であシ、上述の通シの処方に各成分
を秤取し、ヒドロキシプロピルセルロース、エチルヒド
ロキシエチルセルロースが溶解スるとともに顔料を用い
る場合には該顔料が充分に分散するまで、染料を用いる
場合には該染料が溶解するまで攪拌混合すれば、目的と
する水洗性マーキングインクを調製することができる。The manufacturing method is extremely easy, and each component is weighed out according to the above-mentioned recipe, and the process is carried out until hydroxypropylcellulose and ethylhydroxyethylcellulose are dissolved and, if a pigment is used, the pigment is sufficiently dispersed. When a dye is used, the intended water-washable marking ink can be prepared by stirring and mixing until the dye is dissolved.
尚、顔料を用いる場合には、ビーズ玉を使用するペイン
トミキサーを用いて約３０分根度撹拌混合すればよく、
染料を用いる場合には攪拌機付の容器を用いて１〜２時
間程度攪拌混合すればよい。In addition, when using pigments, it is sufficient to stir and mix thoroughly for about 30 minutes using a paint mixer that uses beads.
When a dye is used, it may be stirred and mixed for about 1 to 2 hours using a container equipped with a stirrer.
次に、本発明に係る水洗性マーキングインクを用いてマ
ーキングしたマークの洗浄除去は、水、温水、弱アルカ
リ性水溶液、弱酸性水溶液を用い、浸漬又はスプレーに
よって容易に行える。浸漬の場合には完全に除去するた
めに約１０〜２０分が必要であるが、スプレーによれば
１〜５分程度でよい。また水蒸気スプレーによれば殆ん
ど瞬間的に除去することができる。Next, the marks made using the washable marking ink according to the present invention can be easily removed by immersion or spraying using water, warm water, a weakly alkaline aqueous solution, or a weakly acidic aqueous solution. In the case of immersion, about 10 to 20 minutes are required for complete removal, but in the case of spraying, about 1 to 5 minutes is sufficient. Also, water vapor spray can remove the particles almost instantly.
次に、本発明の実施例を挙げる。尚、各実施例における
「部」は重量部を意味する。Next, examples of the present invention will be given. Note that "parts" in each example mean parts by weight.
実施例 １゜
無機顔料：酸化チタン ５ 部 づヒ
ドロキシプロピルセルロース ０．５〃炭化
水素系溶剤：塩化メチレン ６５〃１．１．１
−）リクロルエタン２２．５ クイングロビルアルコー
ル ５ 〃
ＤＯＰ １
／／ＡＬ−Ｍ（商品名ニアルミニウム系カップリング剤
：味の素社製）１部
上記処方の水洗性マーキングインクを用いて、水平に置
いた表面が乾燥している鉄板Ａと表面が水で濡れている
鉄板Ｂの各表面に向けて約３００朋上方から加圧したイ
ンクをノズル噴射し、白線状にマーキングして、巾ＩＮ
ｇ、長さ５０ＷＩＮのマークを描いた。Example 1 Inorganic pigment: Titanium oxide 5 parts Hydroxypropyl cellulose 0.5 Hydrocarbon solvent: Methylene chloride 65 1.1.1
-) Lichloroethane 22.5 Quinglovir alcohol 5 DOP 1
//AL-M (trade name: Nialuminum-based coupling agent: manufactured by Ajinomoto Co., Ltd.) 1 part Using the water-washable marking ink of the above formulation, iron plate A placed horizontally with a dry surface and iron plate A whose surface is wet with water. A nozzle sprays pressurized ink from about 300 mm above each surface of the iron plate B, marking it in the shape of a white line.
g, I drew a mark with a length of 50 WIN.
噴射直後から指触乾燥に到るまでの時間は、鉄板Ａでは
約２０秒、鉄板Ｂでは約５５秒であった。The time from immediately after spraying to dryness to the touch was approximately 20 seconds for Iron Plate A and approximately 55 seconds for Iron Plate B.
上記のマークが描れている各鉄板をｐＨ１３の弱アルカ
リ性水溶液に浸漬すると、約１５分後にマークは除去さ
れた。When each iron plate on which the above marks were drawn was immersed in a slightly alkaline aqueous solution with a pH of 13, the marks were removed after about 15 minutes.
実施例 ２゜
有機顔料：シシロイ七カラーＦＺ−２００１（商品名：
色：シンロイヒ社製） ３部エチ
ルヒドロキシエチルセルロース ０．３部炭化水素系溶
剤：塩化メチレン ６５〃：１．１．１−）リフ貝
ルエタン２６．７ 〃：エチルアルコール ３ 〃
ＴＯＰ １ 〃ＡＬ−
Ｍ（商品名ニアルミニウム系カップリング剤：味の素社
製） １部
上記処方の水洗性マーキングインクを用いて、水平に置
いた表面が乾燥している銅管Ａと表面が水で濡れている
銅管Ｂの各表面に向けて約２０Ｏｎ上方から加圧したイ
ンクをノズル噴射し、丸印をマーキングして、直径５ｍ
のマークを描いた。このマークは、スーパーライトＣ−
１０ＡＩ型紫外線探傷灯（マークチック社製）の照射下
で赤色に明瞭に目視できた。Example 2゜Organic pigment: Shishiroi Shichicolor FZ-2001 (Product name:
Color: Shinroihi Co., Ltd.) 3 parts Ethyl hydroxyethyl cellulose 0.3 parts Hydrocarbon solvent: Methylene chloride 65〃: 1.1.1-) Rifle shell ethane 26.7 〃: Ethyl alcohol 3 〃 TOP 1 〃AL-
M (trade name: Nialuminum-based coupling agent: manufactured by Ajinomoto Co., Ltd.) 1 part Using the water-washable marking ink of the above formulation, prepare copper pipe A with a dry surface placed horizontally and copper pipe with a wet surface with water. A nozzle sprays ink under pressure of about 20 On from above toward each surface of tube B, marking a circle with a diameter of 5 m.
I drew a mark. This mark is Super Light C-
It was clearly visible in red under irradiation with a 10AI ultraviolet flaw detection lamp (manufactured by Marktic Co., Ltd.).
噴射直後から指触乾燥に到るまでの時間は、鋼管Ａでは
約２０秒、鋼管Ｂでは約６０秒であった。The time from immediately after spraying to dryness to the touch was approximately 20 seconds for steel pipe A and approximately 60 seconds for steel pipe B.
上記のマークが描れている各銅管に温度約４０℃、ｐＨ
１５の弱アルカリ性水溶液を約１分間スプレーするとマ
ークは除去された。Each copper tube with the mark above has a temperature of approximately 40°C and a pH of approximately 40°C.
The marks were removed by spraying a weakly alkaline aqueous solution of No. 15 for about 1 minute.
実施例 ３゜
赤色油溶性染料：Ｃ，エツジシトレッド２７ １．５部
ヒドロキシプロピルセルロース ０．５〃炭化水
素系溶剤：塩化メチレン ６５〃：１．１．１−）
リクロ卿７ ２８ 〃：イソグロピルア、ルコ
ール ５ 〃上記処方の水洗性マーキングインク
を用いて、実施例１と同様にして、表面が乾燥している
鉄板Ａと表面が水で濡れている鉄板Ｂとに、それぞれ線
状にマーキングして、巾１ｆｆ、長さ５０ｍ’ｌｌの赤
色マークを描いた。Example 3〃Red oil-soluble dye: C, Edge Citrud 27 1.5 parts Hydroxypropyl cellulose 0.5〃Hydrocarbon solvent: Methylene chloride 65〃: 1.1.1-)
Rikuro Sir 7 28 〃: Isoglopyrua, Rucor 5 〃Using the water-washable marking ink with the above formulation, apply it to iron plate A whose surface is dry and iron plate B whose surface is wet with water in the same manner as in Example 1. , and a red mark with a width of 1 ff and a length of 50 m'll was drawn in a linear manner.
噴射直後から指触乾燥に到るまでの時間は、鉄板Ａでは
約１０秒、鉄板Ｂでは約３０秒であった。The time from immediately after spraying to dryness to the touch was approximately 10 seconds for Iron Plate A and approximately 30 seconds for Iron Plate B.
上記のマークが捕れている各鉄板に温度約４０ｔ′の温
水を約３分間スプレーするとマークは除去された。The marks were removed by spraying hot water at a temperature of about 40 t' for about 3 minutes on each iron plate on which the above marks were captured.
実施例 ４゜
螢光油溶性染料： Ｃ，エフルオレセント プライトニ
ングエージェント７５
１．５ 部エチルヒドロキシエチルセルロース ０．
５〃炭化水素系溶剤：塩化メチレン ６５〃：
１．１．１−）リフはル鳳タン ２７ 〃：メタ
ノール ４．２〃
ＤＯＰ １ ／＞上
記処方の水溶性マーキングインクを用いて、実施例２と
同様にして、表面が乾燥している鋼管Ａと表面が水で濡
れている鋼管Ｂとに、それぞれ丸印をマーキングして直
径５Ｈのマークを描い九。Example 4 Fluorescent oil-soluble dye: C, fluorescent lightening agent 75
1.5 parts ethylhydroxyethyl cellulose 0.
5〃Hydrocarbon solvent: Methylene chloride 65〃:
1.1.1-) Riff is Lehotan 27 〃: Methanol 4.2〃 DOP 1 // Using the water-soluble marking ink of the above formulation, a steel pipe with a dry surface was prepared in the same manner as in Example 2. Mark both A and steel pipe B, whose surface is wet with water, with a circle and draw a mark with a diameter of 5H.9.
このマークは実施例２と同様にして紫外線を照射すると
螢光青色に明瞭に目視できた。When this mark was irradiated with ultraviolet rays in the same manner as in Example 2, it was clearly visible as a fluorescent blue color.
噴射直後から指触乾燥に到るまでの時間は、鋼管Ａでは
約２０秒、鋼管Ｂでは約６０秒であった。The time from immediately after spraying to dryness to the touch was approximately 20 seconds for steel pipe A and approximately 60 seconds for steel pipe B.
上記のマークが描れている各鋼管に水蒸気スプレーする
とマークが殆んど瞬間的に消滅したことを紫外線照射下
で確認できた。When steam was sprayed onto each steel pipe bearing the above mark, it was confirmed that the mark disappeared almost instantaneously under ultraviolet irradiation.
実施例 ５゜
螢光油溶性染料： Ｃ０工フルオレセントプライトニン
グエージエント５２ １ 部ヒト
ロキシグロビルセルロース ０．５り炭化水素系溶
剤：塩化メチレン ６６．５／／： １．１．１−
）リフはｂ；タン ３０ 〃：イソプロビルアルコ
ール ２ ／／上記処方の水洗性マーキングインクを
用いて、実施例１と同様にして、表面が乾燥している鉄
板Ａと表面が水で濡れている鉄板Ｂと釦、それぞれ線状
にマーキングして、巾りｎ、長さ５０Ｈのマークを描い
念。このマークは実施例２と同様にして紫外線を照射す
ると螢光青色に明瞭に目視できた。Example 5 Fluorescent oil-soluble dye: CO fluorescent brightening agent 52 1 part hydroxyglobil cellulose 0.5% hydrocarbon solvent: methylene chloride 66.5//: 1.1.1-
) Riff is b; Tan 30 〃: Isopropyl alcohol 2 // Using the water-washable marking ink of the above formulation, prepare iron plate A whose surface is dry and iron plate A whose surface is wet with water in the same manner as in Example 1. Mark the iron plate B and the button in a linear manner, and draw a mark with a width of n and a length of 50H. When this mark was irradiated with ultraviolet rays in the same manner as in Example 2, it was clearly visible as a fluorescent blue color.
噴射直後から指触乾燥忙到るまでの時間は、鉄板Ａでは
約１０秒、鉄板Ｂでは約３０秒であった。The time from immediately after spraying to when it was completely dry to the touch was about 10 seconds for iron plate A and about 30 seconds for iron plate B.
上記のマークが捕れている各鉄板に温度約５０℃の温水
を約５分間スプレーするとマークが消滅したことを紫外
線照射下で確認できた。When hot water at a temperature of about 50°C was sprayed for about 5 minutes on each iron plate with the above marks, it was confirmed that the marks disappeared under ultraviolet irradiation.
尚、実施例１．２の処方の水溶性マーキングインクの調
製は、ビーズ玉を使用するペイントミキサーを用い、約
３０分間の攪拌混合によって行ない、実施例３〜５の処
方の水溶性マーキングインクの調製は、攪拌機付の容器
を用いて約９０分間の攪拌混合によって行なった。゛
〔発明の効果〕
本発明に係る水洗性マーキングインクは、当業界におい
て要求されている前記■〜■の性能を満たしておシ、前
出各実施例に示した通シ繊細なマ−クも容易に描けるも
のであって、しかも有機溶剤を使用しなくとも水、温水
、弱アルカリ性水溶液又は弱酸性水溶液によって容易に
洗浄除去することができるので火気、毒性等による問題
の発生がないという格別の効果を奏するものである。The water-soluble marking ink having the formulation of Example 1.2 was prepared by stirring and mixing for about 30 minutes using a paint mixer using beads. The preparation was carried out by stirring and mixing for about 90 minutes using a container equipped with a stirrer. [Effects of the Invention] The water-washable marking ink according to the present invention satisfies the above-mentioned performances required in the industry, and is capable of producing delicate marks as shown in the above-mentioned examples. It is also easy to draw, and can be easily washed away with water, hot water, weakly alkaline aqueous solution, or weakly acidic aqueous solution without using organic solvents, so there are no problems with fire, toxicity, etc. It has the following effects.
Claims (1)
シエチルセルロースを０．１〜５重量部と無機顔料、有
機顔料、染色油溶性染料又は螢光油溶性染料を０．１〜
５重量部と炭化水素系溶剤を８０〜９９重量部とを含む
ことを特徴とする水洗性マーキングインク。1. 0.1 to 5 parts by weight of hydroxypropyl cellulose or ethyl hydroxyethyl cellulose and 0.1 to 5 parts by weight of inorganic pigment, organic pigment, dyeing oil-soluble dye or fluorescent oil-soluble dye
5 parts by weight of a hydrocarbon solvent and 80 to 99 parts by weight of a hydrocarbon solvent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62297470A JPH0794626B2 (en) | 1987-11-27 | 1987-11-27 | Marking ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62297470A JPH0794626B2 (en) | 1987-11-27 | 1987-11-27 | Marking ink |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01139659A true JPH01139659A (en) | 1989-06-01 |
| JPH0794626B2 JPH0794626B2 (en) | 1995-10-11 |
Family
ID=17846911
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62297470A Expired - Fee Related JPH0794626B2 (en) | 1987-11-27 | 1987-11-27 | Marking ink |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0794626B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998042794A1 (en) * | 1997-03-26 | 1998-10-01 | Hans Michael Hangleiter | Composition, especially in the form of a spray can filling |
| JP2005336379A (en) * | 2004-05-28 | 2005-12-08 | Marktec Corp | Paint for steel plate printing and method for steel plate printing |
| JP2010106153A (en) * | 2008-10-30 | 2010-05-13 | Fuji Xerox Co Ltd | Perimidine-based squarylium coloring matter, dispersion medium, detection medium and image-forming material |
| JP2019210355A (en) * | 2018-06-01 | 2019-12-12 | マークテック株式会社 | Coating for marking iron steel material for acid cleaning |
-
1987
- 1987-11-27 JP JP62297470A patent/JPH0794626B2/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998042794A1 (en) * | 1997-03-26 | 1998-10-01 | Hans Michael Hangleiter | Composition, especially in the form of a spray can filling |
| JP2005336379A (en) * | 2004-05-28 | 2005-12-08 | Marktec Corp | Paint for steel plate printing and method for steel plate printing |
| JP4586964B2 (en) * | 2004-05-28 | 2010-11-24 | マークテック株式会社 | Steel plate printing paint and steel plate printing method |
| JP2010106153A (en) * | 2008-10-30 | 2010-05-13 | Fuji Xerox Co Ltd | Perimidine-based squarylium coloring matter, dispersion medium, detection medium and image-forming material |
| JP2019210355A (en) * | 2018-06-01 | 2019-12-12 | マークテック株式会社 | Coating for marking iron steel material for acid cleaning |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0794626B2 (en) | 1995-10-11 |
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