JPH01138099A - Production of ag-cu-ti alloy brazing filler metal for joining ceramics - Google Patents
Production of ag-cu-ti alloy brazing filler metal for joining ceramicsInfo
- Publication number
- JPH01138099A JPH01138099A JP29837387A JP29837387A JPH01138099A JP H01138099 A JPH01138099 A JP H01138099A JP 29837387 A JP29837387 A JP 29837387A JP 29837387 A JP29837387 A JP 29837387A JP H01138099 A JPH01138099 A JP H01138099A
- Authority
- JP
- Japan
- Prior art keywords
- filler metal
- alloy
- brazing filler
- mold
- specified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005219 brazing Methods 0.000 title claims abstract description 16
- 239000002184 metal Substances 0.000 title claims abstract description 15
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 15
- 239000000945 filler Substances 0.000 title claims abstract description 11
- 239000000919 ceramic Substances 0.000 title claims abstract description 10
- 238000005304 joining Methods 0.000 title claims abstract description 4
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 229910001069 Ti alloy Inorganic materials 0.000 title description 4
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 17
- 239000000956 alloy Substances 0.000 claims abstract description 17
- 229910017945 Cu—Ti Inorganic materials 0.000 claims abstract description 16
- 238000005266 casting Methods 0.000 claims abstract description 12
- 238000002844 melting Methods 0.000 claims abstract description 9
- 230000008018 melting Effects 0.000 claims abstract description 9
- 229910052802 copper Inorganic materials 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 5
- 229910052709 silver Inorganic materials 0.000 claims abstract description 4
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 4
- 239000000779 smoke Substances 0.000 claims description 4
- 239000006082 mold release agent Substances 0.000 claims description 3
- 238000005491 wire drawing Methods 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000004071 soot Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 229910000765 intermetallic Inorganic materials 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229910001141 Ductile iron Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
Landscapes
- Ceramic Products (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、電子部品用のセラミックスの接合に用いるＡ
ｇ−Ｃｕ−Ｔｉ合金ろう材の製造方法の改良に関する。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to an A
The present invention relates to improvements in the manufacturing method of g-Cu-Ti alloy brazing filler metal.
（従来の技術とその問題点）
従来よりセラミックスの接合にはＡｇＣｕ−Ｔｉ合金よ
り成るろう材が用いられているが、このろう材はＡｇＣ
ｕＴｉマトリクスが軟らかい（Ｈｖ １５０）のに硬い
（Ｈｖ３５０） Ｃｕ Ｔ ｉ相が大きな粒状となって
点在する為、加工時に応力が不均一にかかり、線径の細
い線材に加工した際には、伸線中にＣｕＴｉ相の部分で
破断し、薄板に加工した際には圧延中にＣｕＴｉ相の部
分で凹凸が発生したり、割れたり、穴が明いたりして甚
だ加工性が悪く、歩留りも悪かった。またろう付は強度
が低く、ばらつきが大きくて不安定であった。(Conventional technology and its problems) Conventionally, a brazing filler metal made of AgCu-Ti alloy has been used for joining ceramics, but this brazing filler metal is made of AgC
The uTi matrix is soft (Hv 150) but hard (Hv 350). Because the CuTi phase is scattered in large particles, stress is applied unevenly during processing, and when processed into a wire with a small diameter, The wire broke at the CuTi phase part during wire drawing, and when it was processed into a thin plate, the CuTi phase part became uneven, cracked, or holed during rolling, resulting in extremely poor workability and low yield. It was bad. In addition, brazing had low strength, large variations, and was unstable.
（発明の目的）
本発明は、上記問題点を解決すべくなされたもので、加
工性に優れ、且つセラミックスのろう付は強度が高く安
定したセラミックス接合用Ａｇ−Ｃｕ−Ｔｉ合金ろう材
の製造方法を提供することを目的とするものである。(Object of the Invention) The present invention has been made to solve the above-mentioned problems, and is to produce an Ag-Cu-Ti alloy brazing filler metal for ceramic bonding which has excellent workability and is highly strong and stable when brazing ceramics. The purpose is to provide a method.
（問題点を解決するための手段）
上記問題点を解決するための本発明のセラミックス接合
用Ａｇ−Ｃｕ−Ｔｉ合金ろう材の製造方法は、Ａ ｇ
ＸＣｕ ＸＴ １を、１０４Ｔｏｒｒの真空度を持つ高
周波溶解炉にて溶解し、次に約４ ｋｇのＡｇ−Ｃｕ−
Ｔｉ合金溶湯を、１００℃に予熱した１ｗｔ％Ｃｒ−Ｃ
ｕより成る鋳型に、離型剤として油煙とホワイトガソリ
ン混合液を塗布し、然る後約４ｋｇのＡｇ−Ｃｕ−Ｔｉ
合金溶湯を、５〜６秒の鋳込スピードで前記鋳型に鋳込
むことを特徴とするものである。(Means for Solving the Problems) The method for producing an Ag-Cu-Ti alloy brazing filler metal for ceramic bonding of the present invention to solve the above-mentioned problems includes the following steps:
XCu XT 1 was melted in a high frequency melting furnace with a vacuum level of 104 Torr, and then approximately 4 kg of Ag-Cu-
1wt%Cr-C molten Ti alloy preheated to 100℃
A mixture of oil smoke and white gasoline is applied as a mold release agent to the mold made of u, and then about 4 kg of Ag-Cu-Ti is applied.
The molten alloy is poured into the mold at a casting speed of 5 to 6 seconds.
（作用）
上述の如く本発明の製造方法では、Ａｇ、Ｃｕ、Ｔｉを
１０−’Ｔ ｏ ｒ ｒの真空度の持つ高周波溶解炉に
て溶解するので、Ｔｉが酸化しにくいものである。また
Ａｇ−Ｃｕ−Ｔｉ合金溶湯を、１００℃に予熱した１ｗ
ｔ％Ｃｒ−Ｃｕより成る鋳型に鋳込むので、鋳型反応が
比較的おだやかである。即ち、鋳型表面にＣｒの若干の
酸化被膜がある為、鋳型とのなじみが良好で、鋳込み始
めの飛び散りが無（、それにより粒々の発生も無い。さ
らに鋳型に溶湯を鋳込む前に、離型剤として油煙とホワ
イトガソリンの混合液を塗布するので、鋳型反応がゆっ
くり行われ、鋳肌に凹凸が発生せずきれいで、内部に大
きな巣が発生することが無い。また約４ｋｇの溶湯を５
〜６秒早い鋳込スピードで鋳込むので、冷却速度が早く
、融点の高いＣｕ−Ｔｉの金属間化合物は偏析すること
がなく、しかも遊離することがないので、大きく粒状に
成長することがなく、均一微細に分散し、巣も生じない
。(Function) As described above, in the manufacturing method of the present invention, Ag, Cu, and Ti are melted in a high frequency melting furnace with a degree of vacuum of 10-' Torr, so that Ti is difficult to oxidize. In addition, 1W of Ag-Cu-Ti alloy molten metal preheated to 100℃
Since it is cast into a mold made of t%Cr-Cu, the mold reaction is relatively mild. In other words, since there is a slight Cr oxide film on the mold surface, it fits well with the mold, and there is no scattering at the beginning of pouring (therefore, no particles are generated.Furthermore, before pouring the molten metal into the mold, there is no separation). Since a mixture of oil smoke and white gasoline is applied as a molding agent, the molding reaction takes place slowly, the casting surface is clean without any unevenness, and there are no large cavities inside.Also, approximately 4 kg of molten metal is 5
Since the casting speed is ~6 seconds faster, the cooling rate is faster, and the Cu-Ti intermetallic compound with a high melting point does not segregate or become liberated, so it does not grow into large particles. , it is uniformly and finely dispersed, and no nests are formed.
（実施例）
本発明によるセラミックス接合用Ａｇ−Ｃｕ−Ｔｉ合金
ろう材の製造方法の一実施例と従来例について説明する
。(Example) An example of the method for manufacturing an Ag-Cu-Ti alloy brazing material for ceramic bonding according to the present invention and a conventional example will be described.
先ず実施例について説明すると、Ａ ｇ ７０．５ｗｔ
％、Ｃｕ ２７．５ｔｎｔ％、Ｔｉ２ｗｔ％を、１０−
’Ｔ ｏ ｒ ｒの真空度を持つ高周波溶解炉にて溶解
する。次に１００℃に予熱した１ｗｔ％Ｃｒ−Ｃｕより
成る鋳型（縦１５＋＋＋＋ｎ、横１２０ｍｍ、深さ２０
０顛の鋳込ピットを有する鋳型）に、離型剤として油煙
とホワイトガソリンを１０：１の割合で混合した混合液
を塗布する。First, to explain the example, A g 70.5wt
%, Cu 27.5tnt%, Ti2wt%, 10-
Melt in a high frequency melting furnace with a vacuum degree of 'T o r r. Next, a mold made of 1wt% Cr-Cu preheated to 100°C (length 15+++n, width 120mm, depth 20mm)
A liquid mixture of oil smoke and white gasoline mixed at a ratio of 10:1 is applied as a mold release agent to a mold having a casting pit of 0.05 mm.
然る後４ ｋｇのＡｇ−Ｃｕ−Ｔｉ合金溶湯を、１３０
０℃の鋳込温度、５秒の鋳込スピードで前記鋳型に鋳込
んで、縦１５ｍｍ、横１２０ｍｍ、厚さ１■のＡｇ−Ｃ
ｕ−Ｔｉ合金の板材を得た。After that, 4 kg of molten Ag-Cu-Ti alloy was heated to 130 kg.
Ag-C with a length of 15 mm, a width of 120 mm, and a thickness of 1 cm was poured into the mold at a casting temperature of 0°C and a casting speed of 5 seconds.
A u-Ti alloy plate material was obtained.
次に従来例について説明すると、Ａ ｇ ７０．５ｗｔ
％、Ｃｕ ２７．５ｗｔ％、Ｔｉ２ｗｔ％を、１０−”
Ｔ ｏ ｒ ｒの真空度を持つ高周波溶解炉にて溶解す
る。次にダクタイル鋳鉄より成る鋳型（縦１５１１、横
１２０ｍｍ、深さ２００鰭の鋳込ピットを有する鋳型）
に、４ ｋｇのＡｇ−Ｃｕ−Ｔｉ合金溶湯を、１１００
℃の鋳込温度、１０秒の鋳込スピードで鋳込んで、縦１
５鰭、横１２０１１、厚さ１顛のＡｇ−Ｃｕ−Ｔｉ合金
の板材を得た。Next, to explain the conventional example, A g 70.5wt
%, Cu 27.5wt%, Ti2wt%, 10-”
Melt in a high frequency melting furnace with a vacuum degree of T o r r. Next, a mold made of ductile cast iron (a mold with a casting pit measuring 1511 mm long, 120 mm wide, and 200 mm deep).
4 kg of Ag-Cu-Ti alloy molten metal was heated to 1100 kg.
℃ casting temperature, 10 seconds casting speed, vertical 1
An Ag-Cu-Ti alloy plate having 5 fins, 12011 mm in width, and 1 inch in thickness was obtained.
こうして得られた実施例及び従来例のＡｇ Ｃｕ〜Ｔ
ｉ合金の板材を、圧延、熱処理（水素雰囲気、６００℃
１３０分）を繰返し行った処、実施例の板材は厚さ０．
０５＋ｎｉ＋まで圧延でき、穴明き、割れ等が全く発生
しなかったのに対し、従来例の板材は厚さ０．１５１Ｗ
ｌまでしか圧延できず、穴明き、割れ等が発生した。Ag Cu~T of the example and conventional example thus obtained
Rolling and heat treatment (hydrogen atmosphere, 600℃) of i-alloy plate material
130 minutes) was repeated, the plate material of the example had a thickness of 0.
It was possible to roll the plate to 0.05+ni+ without any holes or cracks, whereas the conventional plate had a thickness of 0.151W.
It could only be rolled up to 1, and holes, cracks, etc. occurred.
尚、上記実施例は板材を製造した場合である場合である
が、細線を製造した場合は伸線加工中に破断することが
無いものである。In addition, although the above-mentioned example is a case where a plate material is manufactured, when a thin wire is manufactured, it will not break during the wire drawing process.
（発明の効果）
以上の説明で判るように本発明のセラミックス接合用Ａ
ｇ−Ｃｕ−Ｔｉ合金ろう材の製造方法によれば、ＡｇＣ
ｕＴ ｉマトリクスにＣｕＴｉの金属間化合物を偏析さ
せることなく、しかも遊離させることもなく、従って大
きく粒状に成長させることなく均一微細に分散させるこ
とができるので、伸線中破断したり、圧延中凹凸が発生
したり、割れたり、穴が明いたりすることの無いセラミ
ックス接合用Ａｇ−Ｃｕ−Ｔｉ合金ろう材が得られると
いう効果がある。(Effect of the invention) As can be seen from the above explanation, the A for ceramic bonding of the present invention
According to the method for producing g-Cu-Ti alloy brazing filler metal, AgC
CuTi intermetallic compounds are not segregated or liberated in the uTi matrix, and can be uniformly and finely dispersed without growing into large particles, so they do not break during wire drawing or have irregularities during rolling. This has the effect of providing an Ag-Cu-Ti alloy brazing material for ceramic bonding that does not cause cracks, cracks, or holes.
出願人 田中貴金属工業株式会社Applicant: Tanaka Kikinzoku Kogyo Co., Ltd.
Claims (1)
持つ高周波溶解炉にて溶解し、次に１００℃に予熱した
１ｗｔ％Ｃｒ−Ｃｕより成る鋳型に、離型剤として油煙
とホワイトガソリンの混合液を塗布し、然る後約４ｋｇ
のＡｇ−Ｃｕ−Ｔｉ合金溶湯を、５〜６秒の鋳込スピー
ドで前記鋳型に鋳込むことを特徴とするセラミックス接
合用Ａｇ−Ｃｕ−Ｔｉ合金ろう材の製造方法。Ag, Cu, and Ti were melted in a high-frequency melting furnace with a vacuum level of 10^-^4 Torr, and then oil smoke and white gasoline were added as mold release agents to a mold made of 1wt% Cr-Cu preheated to 100°C. After applying the mixture, about 4 kg
A method for producing an Ag-Cu-Ti alloy brazing filler metal for joining ceramics, characterized in that a molten Ag-Cu-Ti alloy is poured into the mold at a casting speed of 5 to 6 seconds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29837387A JPH01138099A (en) | 1987-11-26 | 1987-11-26 | Production of ag-cu-ti alloy brazing filler metal for joining ceramics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29837387A JPH01138099A (en) | 1987-11-26 | 1987-11-26 | Production of ag-cu-ti alloy brazing filler metal for joining ceramics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01138099A true JPH01138099A (en) | 1989-05-30 |
Family
ID=17858848
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP29837387A Pending JPH01138099A (en) | 1987-11-26 | 1987-11-26 | Production of ag-cu-ti alloy brazing filler metal for joining ceramics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01138099A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005097376A2 (en) | 2004-04-01 | 2005-10-20 | Saint-Gobain Pam | Mould for casting a liquid metal and associated method |
| CN106493443A (en) * | 2016-10-25 | 2017-03-15 | 哈尔滨工业大学 | A kind of composite interlayer ceramic soldering or the method for ceramic matric composite and metal |
-
1987
- 1987-11-26 JP JP29837387A patent/JPH01138099A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005097376A2 (en) | 2004-04-01 | 2005-10-20 | Saint-Gobain Pam | Mould for casting a liquid metal and associated method |
| WO2005097376A3 (en) * | 2004-04-01 | 2006-05-26 | Saint Gobain Pont A Mousson | Mould for casting a liquid metal and associated method |
| CN106493443A (en) * | 2016-10-25 | 2017-03-15 | 哈尔滨工业大学 | A kind of composite interlayer ceramic soldering or the method for ceramic matric composite and metal |
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