JPH01131300A - Jojoba oil and jojoba oil derivative lubricant composition - Google Patents
Jojoba oil and jojoba oil derivative lubricant compositionInfo
- Publication number
- JPH01131300A JPH01131300A JP63207994A JP20799488A JPH01131300A JP H01131300 A JPH01131300 A JP H01131300A JP 63207994 A JP63207994 A JP 63207994A JP 20799488 A JP20799488 A JP 20799488A JP H01131300 A JPH01131300 A JP H01131300A
- Authority
- JP
- Japan
- Prior art keywords
- jojoba oil
- oil
- adduct
- phosphite
- jojoba
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229940119170 jojoba wax Drugs 0.000 title claims abstract description 90
- 239000000314 lubricant Substances 0.000 title claims abstract description 62
- 239000000203 mixture Substances 0.000 title claims abstract description 45
- 230000001050 lubricating effect Effects 0.000 claims abstract description 20
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003921 oil Substances 0.000 claims description 26
- 239000007788 liquid Substances 0.000 claims description 22
- 239000002480 mineral oil Substances 0.000 claims description 16
- 235000010446 mineral oil Nutrition 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 11
- 150000002430 hydrocarbons Chemical class 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 150000002148 esters Chemical class 0.000 claims description 10
- 150000008301 phosphite esters Chemical class 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 9
- 239000004215 Carbon black (E152) Substances 0.000 claims description 8
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 7
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 239000010687 lubricating oil Substances 0.000 claims description 3
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims 3
- 239000007795 chemical reaction product Substances 0.000 claims 2
- 239000004615 ingredient Substances 0.000 abstract description 2
- 238000010348 incorporation Methods 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 18
- 241000221095 Simmondsia Species 0.000 description 12
- 235000004433 Simmondsia californica Nutrition 0.000 description 12
- 239000012530 fluid Substances 0.000 description 8
- 238000005555 metalworking Methods 0.000 description 5
- 239000010705 motor oil Substances 0.000 description 5
- 239000002173 cutting fluid Substances 0.000 description 4
- 239000012208 gear oil Substances 0.000 description 4
- -1 monocarboxylic acid esters Chemical class 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 238000005461 lubrication Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 241001125281 Eubalaena glacialis Species 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000010727 cylinder oil Substances 0.000 description 2
- BVXOPEOQUQWRHQ-UHFFFAOYSA-N dibutyl phosphite Chemical compound CCCCOP([O-])OCCCC BVXOPEOQUQWRHQ-UHFFFAOYSA-N 0.000 description 2
- 239000010720 hydraulic oil Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000010698 whale oil Substances 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical class CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical class CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000005069 Extreme pressure additive Substances 0.000 description 1
- 241000221096 Simmondsia chinensis Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000007866 anti-wear additive Substances 0.000 description 1
- 239000010692 aromatic oil Substances 0.000 description 1
- SAOKZLXYCUGLFA-UHFFFAOYSA-N bis(2-ethylhexyl) adipate Chemical compound CCCCC(CC)COC(=O)CCCCC(=O)OCC(CC)CCCC SAOKZLXYCUGLFA-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000010724 circulating oil Substances 0.000 description 1
- 238000000641 cold extrusion Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- HTMDHERCQUESGS-UHFFFAOYSA-N didecyl decanedioate Chemical compound CCCCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCCCC HTMDHERCQUESGS-UHFFFAOYSA-N 0.000 description 1
- HCQHIEGYGGJLJU-UHFFFAOYSA-N didecyl hexanedioate Chemical compound CCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCC HCQHIEGYGGJLJU-UHFFFAOYSA-N 0.000 description 1
- VJHINFRRDQUWOJ-UHFFFAOYSA-N dioctyl sebacate Chemical compound CCCCC(CC)COC(=O)CCCCCCCCC(=O)OCC(CC)CCCC VJHINFRRDQUWOJ-UHFFFAOYSA-N 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000003879 lubricant additive Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000010690 paraffinic oil Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229940113116 polyethylene glycol 1000 Drugs 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 231100000241 scar Toxicity 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 208000011117 substance-related disease Diseases 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000008093 supporting effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/045—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
- C10M101/04—Fatty oil fractions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/02—Sulfurised compounds
- C10M135/06—Esters, e.g. fats
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- C—CHEMISTRY; METALLURGY
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/02—Natural products
- C10M159/08—Fatty oils
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
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- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/06—Well-defined aromatic compounds
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
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- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
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- C10M2207/283—Esters of polyhydroxy compounds
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- C10M2207/286—Esters of polymerised unsaturated acids
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- C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/402—Castor oils
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
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- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
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- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/042—Metal salts thereof
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- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/12—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy
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- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/02—Bearings
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
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- C10N2040/042—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for automatic transmissions
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/08—Hydraulic fluids, e.g. brake-fluids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/135—Steam engines or turbines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/241—Manufacturing joint-less pipes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/242—Hot working
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/243—Cold working
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/247—Stainless steel
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/251—Alcohol fueled engines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/252—Diesel engines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/252—Diesel engines
- C10N2040/253—Small diesel engines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/255—Gasoline engines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/255—Gasoline engines
- C10N2040/28—Rotary engines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/46—Textile oils
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B1/00—Engines characterised by fuel-air mixture compression
- F02B1/02—Engines characterised by fuel-air mixture compression with positive ignition
- F02B1/04—Engines characterised by fuel-air mixture compression with positive ignition with fuel-air mixture admission into cylinder
Abstract
Description
【発明の詳細な説明】
発明の分野
本発明はホホバ油およびホホバ油ＢＭ ｍ体を活性潤滑
性物質として含む、潤滑剤ベース組成物および減摩性を
有する潤滑剤組成物に関する。より詳しくは本発明は活
性潤滑剤の形成に組合せて使用されるホホバ油およびホ
ホバ油の亜リン酸エステルアダクト並びに（または）硫
化ホホバ油の組成物に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to lubricant base compositions and lubricant compositions with antifriction properties comprising jojoba oil and jojoba oil BM m-form as active lubricating substances. More particularly, the present invention relates to compositions of jojoba oil and phosphite adducts of jojoba oil and/or sulfurized jojoba oil used in combination to form active lubricants.
背景技術
ホホバ油は主にｃｕｅ〜Ｃ２４モノ不飽和酸でエステル
化されたＣＩ８〜Ｃ２４モノ不胞和アルコールを含む直
鎖不飽和モノカルボン酸エステルの天然混合物である。BACKGROUND OF THE INVENTION Jojoba oil is a natural mixture of linear unsaturated monocarboxylic acid esters containing primarily CI8-C24 monounsaturated alcohols esterified with cue-C24 monounsaturated acids.
二重結合はエステルのアルコールおよび酸両部分中の０
９位置に主に位置する。ホホバ油は通常シモンドシア・
シネンシス（ＳｉｍｍｏｎｄｓｉａＣｈｉｎｅｎｓｉｓ
） 、カリフォルニア、アリシナおよびメキシコに自
生する荒地低木、の種子から常温圧搾される。The double bond is 0 in both the alcohol and acid portions of the ester.
It is mainly located in the 9th position. Jojoba oil is usually simmondsia
Simmondsia Chinensis
), a wasteland shrub native to California, Alicina, and Mexico, is cold-pressed from the seeds.
ホホバ油およびその多くの誘導体が文献に開示された。Jojoba oil and its many derivatives have been disclosed in the literature.
ホホバ油は主に化粧品およびヘアシャンプーに使用され
たが、しかしまた潤滑剤として有用であることが開示さ
れた。アーン） （Ａｒｎｄｔ）米国特許束４．５５７
．８４１号にはホホバ油が潤滑性添加剤として、標準モ
ーター油配合でモーター油中に０、１〜１０％（Ｗ／Ｗ
）の範囲内で有用であることが示されている。クープル
（Ｋｕｂｌｅ）の米国特許束２．９２１．８７４号には
金属の冷間押出に用いる冷開成形潤滑剤としてのホホバ
油の１吏用が示されている。さらに、ブラウン（Ｂｒｏ
ｖ＋ｎ）ほかの米国特許束４、３６０．３８７号にはホ
ホバ油のトランス異性化物の同形組成物の使用が食品機
械潤滑剤として有用であることが示されている。ホリン
シェッド（Ｈｏｌｌｉｎｓｈｅａｄ）の米国特許束３．
８４９．３２３号には天然油例えばホホバ油、を含む潤
滑用配合石油製品が示されている。Jojoba oil has been primarily used in cosmetics and hair shampoos, but has also been disclosed to be useful as a lubricant. (Arndt) US Patent Bundle 4.557
．． No. 841 contains jojoba oil as a lubricating additive at 0.1 to 10% (W/W) in motor oil in standard motor oil formulations.
) have been shown to be useful within the range of Kuble, US Pat. No. 2,921,874, discloses the use of jojoba oil as a cold-open forming lubricant for cold extrusion of metals. Furthermore, Brown (Bro
v+n) et al., U.S. Pat. No. 4,360,387, discloses the use of isomorphic compositions of trans-isomers of jojoba oil to be useful as food machine lubricants. Hollinhead US Patent Bundle 3.
No. 849.323 discloses a lubricating formulated petroleum product containing natural oils such as jojoba oil.
潤滑剤例えば切削液、プレコート油、金属加工油、自動
変速液（ＡＴＦ）、ギヤ油、ウェイ油（ｗａｙ ｏｉｌ
）、並びに自動車および船、舶用油の摩擦特性の改善に
対し新規かつ改善された潤滑剤および潤滑剤添加剤系に
対する大きな満たされない要求が存在する。種々のホホ
バ油誘導体が単独で潤滑油組成物として示唆された。例
えばドイツ国特許第３，３０９，２１１号にはホホバ油
とＰ２Ｓ５との高温窒素雰囲気下の反応が示されている
。ドイツ国特許第３，３２７．１２７号には耐食または
耐摩耗性を改良するためのスルホクロリネーション化混
合物におけるホホバ油の使用が示されている。ミワ（Ｍ
ｉｗａ）はか〔「ホホバおよびまっこう鯨油に対する極
圧潤滑試験」、ジャーナル・オブ、アメリカンオイル・
ケミスツ・ソサイエティー（Ｊ、Ａｍｅｒ、ＯｉＩＣｈ
ｅｍｉｓｔｓ’ Ｓｏｃ、） 、５６．７６５〜７０．
１９７９）はモーター油、ギヤ潤滑剤および自動変速液
に対する極圧添加剤としての硫化ホホバ油に対する潤滑
試験を示している。ミワ（Ｍｉｗａ）ほかは潤滑剤に対
する耐摩耗添加剤としての硫化ホホバ油が硫化まっこう
鯨油と少くとも等価で、若干の場合にそれより優れてい
ることを認めた。Lubricants such as cutting fluid, pre-coat oil, metal working oil, automatic transmission fluid (ATF), gear oil, way oil
), and there is a significant unmet need for new and improved lubricants and lubricant additive systems for improving the friction properties of automotive and marine oils. Various jojoba oil derivatives have been suggested alone as lubricating oil compositions. For example, German Patent No. 3,309,211 describes the reaction of jojoba oil and P2S5 under a high temperature nitrogen atmosphere. German Patent No. 3,327,127 discloses the use of jojoba oil in sulfochlorination mixtures to improve corrosion or wear resistance. Miwa (M
iwa) Haka [“Extreme pressure lubrication test on jojoba and black whale oil”, Journal of American Oil
Chemistry Society (J, Amer, OiICh
emists' Soc, ), 56.765-70.
(1979) present lubrication tests on sulfurized jojoba oil as an extreme pressure additive to motor oils, gear lubricants, and automatic transmission fluids. Miwa et al. found that sulfurized jojoba oil is at least equivalent to, and in some cases superior to, sulfurized black whale oil as an antiwear additive to lubricants.
従来技術における潤滑性誘導体または物質としてのホホ
バ油の使用は単一物質使用に限定され、すなわち、ホホ
バ油およびホホバ油の硫化誘導体が個別に単一物質とし
て使用された。しかし自動車および船舶用油、切削液、
プレコート油、金属加工油、ＡＴＦ、ギヤ油、並びにウ
ェイ潤滑剤に対する潤滑特性の改良に対する多くの余地
が残っている。本発明は多くの周知用途における使用に
対する従来技術の潤滑剤より優れた新規組成物を意味す
る。The use of jojoba oil as a lubricating derivative or substance in the prior art is limited to single substance use, ie jojoba oil and sulfurized derivatives of jojoba oil were used individually as a single substance. However, automotive and marine oils, cutting fluids,
There remains much room for improvements in lubricating properties for precoat oils, metalworking fluids, ATF, gear oils, and way lubricants. The present invention represents a new composition that is superior to prior art lubricants for use in many known applications.
発明の開示
本発明は次の３化合物、ホホバ油、硫化ホホバ油および
ホホバ油の亜リン酸エステルアダクト、の少くとも２つ
の混合物を含む潤滑剤ベースおよび潤滑性組成物を提供
する。本発明の組成物は１つの化合物単独よりも優れた
減耗特性並びに耐摩耗および負荷支持性を有する優れた
潤滑特性を提供する。改良された減摩特性は内燃機関に
対する低燃料消費量およびエンジンおよび他の工業機械
に用いたときの低い運転温度を生ずることができる。さ
らに、本発明は、活性潤滑性物質として本発明の潤滑剤
ベースを混合した切削液、プレコート油、金属加工油、
ＡＴＦ、ギヤ油、ウニ・イ潤滑剤、グリース、航空潤滑
油、繊維潤滑剤、作動油、循環油、蒸気シリンダーオイ
ル、スピンドル油、難燃性液、並びに自動車および船舶
用油を提供する。Disclosure of the Invention The present invention provides lubricant bases and lubricant compositions comprising mixtures of at least two of the following three compounds: jojoba oil, sulfurized jojoba oil, and phosphite adducts of jojoba oil. The compositions of the present invention provide superior lubrication properties with anti-wear properties as well as anti-wear and load-carrying properties that are superior to one compound alone. Improved antifriction properties can result in lower fuel consumption for internal combustion engines and lower operating temperatures when used in engines and other industrial machinery. Furthermore, the present invention provides cutting fluids, precoat oils, metalworking oils, etc. mixed with the lubricant base of the present invention as an active lubricating substance.
The Company provides ATF, gear oils, sea lubricants, greases, aviation lubricants, textile lubricants, hydraulic oils, circulating oils, steam cylinder oils, spindle oils, flame retardant fluids, and automotive and marine oils.
発明を実施する最良の形態
前記のように、本発明は潤滑剤ベース並びに、潤滑剤ベ
ースおよびベース液からなり、耐摩耗および負荷支持性
を含めて減摩性を有する潤滑性組成物を含む。潤滑剤ベ
ースはホホバ油、ホホバ油の亜リン酸エステルアダクト
および硫化ホホバ油からなる群から選ばれる成分の２つ
または３つの混合物を含む。本発明の組成物に使用され
る成分の量は最終潤滑性組成物を基にする。潤滑剤ベー
スは約０．１〜約２０％（Ｗ／Ｗ）のホホバ油および約
０．１〜約５％（Ｗ／Ｗ）の硫化ホホバ油を含むことが
できる。あるいは潤滑剤ベースは約０．１〜約２０％（
Ｗ／Ｗ）のホホバ油、約０．１〜約５％（Ｗ／Ｗ）の硫
化ホホバ油および約０．１〜約５％（Ｗ／Ｗ）のホホバ
油の亜リン酸エステルアダクトを含むことができる。他
の潤滑剤ベース組合せは約０．１〜約２０％（Ｗ／Ｗ）
のホホバ油および約０．１〜約０．５％＜Ｗ／Ｗ）のホ
ホバ油の亜リン酸エステルアダクトを含むことができる
。潤滑剤ベースはホホバ油、ホホバ油の亜リン酸エステ
ルアダクトおよび硫化ホホバ油からなる群から選ばれる
３成分の少くとも２つの混合物、できればこれらの成分
の３つすべての混合物を含まねばならない。BEST MODE FOR CARRYING OUT THE INVENTION As noted above, the present invention includes a lubricant base and a lubricant composition comprising a lubricant base and a base liquid having antifriction properties, including wear resistance and load support properties. The lubricant base comprises a mixture of two or three components selected from the group consisting of jojoba oil, phosphite adducts of jojoba oil, and sulfurized jojoba oil. The amounts of ingredients used in the compositions of this invention are based on the final lubricating composition. The lubricant base can include about 0.1 to about 20% (W/W) jojoba oil and about 0.1 to about 5% (W/W) sulfurized jojoba oil. Or the lubricant base is about 0.1 to about 20% (
W/W) jojoba oil, about 0.1 to about 5% (W/W) sulfurized jojoba oil, and about 0.1 to about 5% (W/W) phosphite ester adducts of jojoba oil. be able to. Other lubricant base combinations are about 0.1 to about 20% (W/W)
of jojoba oil and about 0.1 to about 0.5% (w/w) phosphite ester adducts of jojoba oil. The lubricant base must contain a mixture of at least two of the three components selected from the group consisting of jojoba oil, phosphite adducts of jojoba oil, and sulfurized jojoba oil, preferably a mixture of all three of these components.
潤滑剤ベースはベース液と混合して耐摩耗および負荷支
持性を含めた減摩性を有する潤滑性組成物になされる。The lubricant base is mixed with a base liquid to form a lubricating composition having antifriction properties, including antiwear and load supporting properties.
潤滑性組成物の例には切削液、プレコート油、金属加工
油、ＡＴＦ、ギヤ油、ウェイ潤滑剤、グリース、航空潤
滑油、繊維潤滑剤、作動油、循環油、蒸気シリンダーオ
イル、スピンドル油、難燃性液、並びに自動車および船
舶用油が含まれる。ベース液の例には炭化水素油；合成
炭化水素；エステル基潤滑剤；鉱油；鉱油とエステル基
潤滑剤との混合物；鉱油、合成炭化水素およびエステル
基潤滑剤の混合物；鉱油基グリース；並びに合成炭化水
素基グリースが含まれる。特定的にはベース液は、
ａ、ｔＪ２．油例えばパラフィン系ニュートラル１００
”、フルフラール精製パラフィン系油、溶剤精製ナフテ
ン系油および溶剤精製芳香族油；
ｂ１合成炭化水素油例えば水素化または部分水素化した
ポリデセンおよび他のオレフィン、水素化ヘキセンオリ
ゴマー、水素化オクテンオリゴマー、水素化デセンオリ
ゴマー、水素化０６〜．。Examples of lubricating compositions include cutting fluids, precoat oils, metalworking oils, ATF, gear oils, way lubricants, greases, aviation lubricants, textile lubricants, hydraulic oils, circulation oils, steam cylinder oils, spindle oils, Includes flame retardant fluids and automotive and marine oils. Examples of base fluids include hydrocarbon oils; synthetic hydrocarbons; ester-based lubricants; mineral oils; mixtures of mineral oils and ester-based lubricants; mixtures of mineral oils, synthetic hydrocarbons, and ester-based lubricants; mineral oil-based greases; and synthetic Contains hydrocarbon-based grease. Specifically, the base liquid is a, tJ2. Oil such as paraffin neutral 100
”, furfural-refined paraffinic oils, solvent-refined naphthenic oils and solvent-refined aromatic oils; b1 synthetic hydrocarbon oils such as hydrogenated or partially hydrogenated polydecene and other olefins, hydrogenated hexene oligomers, hydrogenated octene oligomers, hydrogen Hydrogenated decene oligomer, hydrogenated 06~.
オリゴマー、並びに水素化Ｃ１］〜１０オリゴマー；Ｃ
，エステル液、例えば構造：
１］
および
（式中、ＲはＣ４１１９、Ｃ６１１１３、Ｃａｔｌ＋７
またはそれらの混合物である）
を有するペンタエリトリトールエステル類、および構造
：
Ｃ１１□−〇−Ｃ−Ｒ
および
（式中、Ｒは前記のとおりである）
のトリメチロプロパンおよびジペンタエリトリトールの
エステル類、アジピン酸ジー２−エチルへキシル、セバ
シン酸ジー２−エチルヘキシル、アジピン酸ジデシル並
びにセバシン酸ジデシル；
ｄ、ジアルキルベンゼン類例えばジドセシルベンゼン；
ｅ、ポリグリコール類例えばＵ ＣＯＮ液、分子量１０
００〜３０００のポリプロピレングリコール類および分
子ｆｆ１ｌｏｏｏ〜３０００のポリエチレングリコール
類；
ｆ、アルキルアロマティックス；並びにｇ、ジカルボン
酸類、
である。oligomers, and hydrogenated C1]-10 oligomers; C
, ester liquid, for example structure: 1] and (wherein R is C4119, C61113, Catl+7
or mixtures thereof), and esters of trimethylopropane and dipentaerythritol having the structure C11□-〇-C-R and where R is as defined above; Di-2-ethylhexyl adipate, di-2-ethylhexyl sebacate, didecyl adipate and didecyl sebacate; d. Dialkylbenzenes such as didocetylbenzene; e. Polyglycols such as U CON liquid, molecular weight 10.
Polypropylene glycols having a molecular weight of 00 to 3,000 and polyethylene glycols having a molecular weight of ff1loooo to 3,000; f, alkyl aromatics; and g, dicarboxylic acids.
ホホバ油は次の構造式： ％式％ （式中、ｊ＝７．９．１１または１３ に＝６．８．１０または１２である） を有する。Jojoba oil has the following structural formula: %formula% (where j=7.9.11 or 13 = 6.8.10 or 12) has.
他の硫化ホホバ油を本発明に使用できるけれども、好ま
しい硫化ホホバ油は次のもの：（式中、ｎ＝１〜３であ
り、Ａはホホバ油の構造を示す）
並びに両方の混合物を生ずるホホバ油と１０〜２０％の
硫黄との反応の生成物である。Although other sulfurized jojoba oils can be used in the present invention, preferred sulfurized jojoba oils are: (where n=1-3 and A represents the structure of the jojoba oil) as well as jojoba that yields a mixture of both. It is the product of the reaction of oil with 10-20% sulfur.
他のホホバ油の亜リン酸エステルアダクトを本発明に使
用できるけれども、好ましいホホバ油の亜リン酸エステ
ルアダクトはホホバ油と式：％式％
（式中、Ｒ＝Ｈ，Ｃ，〜Ｉ□アルキル、Ｃ１〜Ｉ□アリ
ール、Ｃ１〜ｌ□アルカリール、Ｃ１〜１□アラルキル
およびシクロ０１〜１□アルキルである）の化合物との
反応により形成される。好ましくはＲ＝Ｃ，〜８アルキ
ル、Ｃ１〜８アルカリール、Ｃ４〜８アラルキルおよび
シクロ０４〜８アルキルである。最も好ましくはＲはｎ
−ブチルである。Although other jojoba oil phosphite adducts can be used in the present invention, the preferred jojoba oil phosphite adducts are jojoba oil and the formula: , C1-I□aryl, C1-1□alkaryl, C1-1□aralkyl and cyclo01-1□alkyl). Preferably R=C, ~8 alkyl, C1-8 alkaryl, C4-8 aralkyl and cyclo04-8 alkyl. Most preferably R is n
-Butyl.
構造式から知見できるように、ホホバ油は２つの炭素−
炭素二重結合を有する。従って、亜リン酸エステルアダ
クトはホホバ油のシアダクトまたはモノアダクトである
ことができる。従って、ホホバ油の亜リン酸エステルア
ダクトの４例は、Ｒがブチルであるときに次のとおりで
ある。As can be seen from the structural formula, jojoba oil has two carbon atoms.
Contains carbon double bonds. Thus, the phosphite adduct can be a sheaduct or a monoadduct of jojoba oil. Thus, four examples of phosphite adducts of jojoba oil are as follows when R is butyl.
ＩＩ ＩＩＣ１ｌ ｘ （
ＣＨｚ） ７ｃｔｌ。ＣＨ−（ＣＨｚ） ；−Ｃ−０−
（ＣＨＩ□）ｋｃｔｌ−Ｃｔｌｚ（ＣＨｚ）、ｃｔｌ＊
（ｎ−Ｃ４１１，Ｏ） ２Ｐ ＯＰ （０
−ｎ−Ｃ４Ｈ１）ｚＣ１１：１（Ｃ１１２）７Ｃ）１２
−ＣＩ（（Ｃ１１□）７−Ｃ−０−（Ｃ１ｌｚ） ｂｃ
Ｈ＝ｃＨ（ＣＨｚ） ７ＣＨ３＋ １１
（ｎ−Ｃｔｌｌ、０） ２Ｐ Ｏ（式中、
ｊおよびｋは前記のとおりである）本発明はさらに次の
実施例により例示され、それらの実施例は例示として提
供され、本発明の限定ではない。II IIC1l x (
CHz) 7ctl. CH-(CHz) ;-C-0-
(CHI□) kctl-Ctlz (CHz), ctl*
(n-C411, O) 2P OP (0
-n-C4H1)zC11:1(C112)7C)12
-CI((C11□)7-C-0-(C1lz) bc
H=cH(CHz) 7CH3+ 11 (n-Ctll, 0) 2P O (in the formula,
The invention is further illustrated by the following examples, which are offered by way of illustration and not as a limitation of the invention.
潤滑剤ベースおよび潤滑性組成物の例が表１および２中
に与えられる。表にはまた低速度摩擦装置、４球摩耗試
験およびファレックス（Ｆａｌｅｘ）試験を含む標準試
験の実施結果が与えられる。各試験の操作は次のとおり
である。Examples of lubricant bases and lubricant compositions are given in Tables 1 and 2. The table also provides the results of standard tests performed including low speed friction device, 4 ball wear test and Falex test. The operations for each test are as follows.
極圧特性を評価する４球試験
圧延、引抜および他の金属加工操作に関する摩擦の測定
は工具および工作物の表面並びに潤滑剤の粘度および化
学組成、並びに加工中に生ずる圧力および温度に依存す
る。４球摩耗試験機は制御試験条件下に摩擦を測定する
方法を与える。機械は、互いに接触させ水平面内で一緒
にクランプした３つの球からなる。第４球は３つの間に
配置することにより３つのクランプした球に接触し、モ
ーターにより回転されるのでクランプ球に接触して回転
する。回転は試験潤滑剤を容れた溜め中で生ずる。温度
測定装置、およびヒーターが試験液の温度を制御する方
法を与える。回転球は荷重され、次いで特定速度で特定
時間回転される。試験が終ると球上に生じた傷あとパタ
ーンを測定する。Four Ball Tests to Evaluate Extreme Pressure Properties Friction measurements for rolling, drawing and other metalworking operations depend on the viscosity and chemical composition of the tool and workpiece surfaces and lubricants, as well as the pressures and temperatures encountered during processing. A four-ball abrasion tester provides a way to measure friction under controlled test conditions. The machine consists of three balls in contact with each other and clamped together in a horizontal plane. The fourth ball contacts the three clamped balls by being placed between the three, and is rotated by the motor so that it contacts the clamped balls and rotates. The rotation occurs in a reservoir containing the test lubricant. A temperature measuring device and a heater provide a way to control the temperature of the test liquid. The rotating ball is loaded and then rotated at a specific speed for a specific time. Once the test is complete, measure the scar pattern created on the ball.
汚点を観察し、傷の直径を測定し、摩擦係数を、球表面
における接線力を垂直力により除することにより計算す
る。The stain is observed, the diameter of the scratch is measured, and the coefficient of friction is calculated by dividing the tangential force on the sphere surface by the normal force.
低速度摩擦装置
低速度摩擦装置（Ｌ Ｖ Ｆ Ａ）を用いて試験潤滑剤
の摩擦を種々の荷重、温度およびすべり速度下に測定す
る。ＬＶＦＡは、動輪に取付けられ、固定突出状環状鋼
表面（面積０．０８インチ２）上で回転される平らな鋼
表面（直径１．５インチ）からなる。両表面は試験潤滑
剤中に浸される。鋼表面間の摩擦が２５０°Ｆの潤滑剤
温度におけるすべり速度の関数として測定される。摩擦
表面間の摩擦はトルクアーム／ひずみ針糸を用いて測定
する。Low Velocity Friction Device A low velocity friction device (L V F A) is used to measure the friction of the test lubricant under various loads, temperatures and sliding speeds. The LVFA consists of a flat steel surface (1.5 inches in diameter) that is mounted on a driving wheel and rotated on a fixed protruding annular steel surface (area 0.08 inches2). Both surfaces are immersed in the test lubricant. Friction between steel surfaces is measured as a function of sliding rate at a lubricant temperature of 250°F. Friction between friction surfaces is measured using a torque arm/strain needle thread.
ひずみ計出力（摩擦係数に等しくなるように校正される
）はＸ−ＹプロッターのＹ軸に供給される。The strain gauge output (calibrated to equal the coefficient of friction) is fed to the Y axis of an X-Y plotter.
タコメーター−発生器からの速度信号がＸ軸に供給され
る。A speed signal from a tachometer-generator is provided on the X-axis.
ファレソクス試験
ファレソクス試験は２つの固定■ブロック間のピンの回
転間に生じたトルクおよび摩擦を測定する方法からなる
。ピンおよび■プロ・７りは種々の材料で作ることがで
きる。ピンおよびＶブロックが中に置かれる潤滑油の温
度もまた変えることができる。荷重はラチェット装置に
より適用される。Faresox Test The Faresox test consists of measuring the torque and friction produced during the rotation of a pin between two fixed blocks. The pins and ■Pro-7ri can be made from a variety of materials. The temperature of the lubricating oil in which the pin and V-block are placed can also be varied. The load is applied by a ratchet device.
転移圧、すなわち潤滑剤膜が破壊される荷重、以上でな
された摩擦測定値は実際運転に匹敵する条件のもとで行
なわれれば有用なパラメーターであることができる。The friction measurements made at the transfer pressure, ie the load at which the lubricant film breaks down, can be a useful parameter if performed under conditions comparable to actual operation.
表１および２はＬＶＦＡ試験、ファレックス摩耗試験お
よび４球摩耗試験に対するベース液、ペース液中のホホ
バ油、ホホバ油と亜リン酸ジブチルアダクトプラスペー
ス液、ホホバ油プラス亜リン酸ジブチルアダクトおよび
硫化ホホバ油プラスベース液を示す。２つの表は本発明
の組成物の改良された潤滑特性を示す。Tables 1 and 2 show base liquid, jojoba oil in pace liquid, jojoba oil plus dibutyl phosphite adduct plus space liquid, jojoba oil plus dibutyl phosphite adduct and sulfide for the LVFA test, Farex abrasion test and 4-ball abrasion test. Showing jojoba oil plus base liquid. Two tables show the improved lubricating properties of the compositions of the invention.
表−１
ベース液” １００．０ ０
０ホホバ油 １．０ ２１
２０ホホバ油 ５．０ ２４
２８ホホバ油 ５．０ １５
１９＊ベース液は１００“パラフィン系ニュー
トラル鉱油である。Table-1 Base liquid” 100.0 0
0 Jojoba oil 1.0 21
20 Jojoba oil 5.0 24
28 Jojoba oil 5.0 15
19*Base liquid is 100" paraffinic neutral mineral oil.
麦−一医
ベース液 ０．９４ １２０
７５０ベ一スン夜＋１％ホホバ ０．７８ １
６０ −ベースン夜＋２％ホホバ ０．７５
１６０ ２９００ベ一ス液＋５％ホホバ
０．７２ １８０ ’ベース液＋５
％ホホバ ０．６８ １６０ ３０００
ベ一ス液＋１％硫化ホホバ ０．５８ ２２０
３５００ベ一ス液＋２％硫化ホホバ ０．５０
２３０ ４２００ベ一ス液＋５％硫化ホホバ
０．５１ ２５０ ４２００ベース液＋１０
χ硫化ホホバ ０．５０ ２８０ ４５００
潤滑剤ベースを異なるベース液に加えて種々の最終用途
を有する組成物を得ることができる。種々のベース液に
よる最終用途の例が表３に示される。Mugi-ichii base liquid 0.94 120
750 basis night + 1% jojoba 0.78 1
60 - Basin night + 2% jojoba 0.75
160 2900 base liquid + 5% jojoba
0.72 180' Base liquid +5
%Jojoba 0.68 160 3000
Base liquid + 1% sulfurized jojoba 0.58 220
3500 base liquid + 2% sulfurized jojoba 0.50
230 4200 base liquid + 5% sulfurized jojoba
0.51 250 4200 base liquid +10
χ sulfide jojoba 0.50 280 4500
The lubricant base can be added to different base fluids to obtain compositions with a variety of end uses. Examples of end uses with various base fluids are shown in Table 3.
金属加工 鉱油 １００〜２
００潤滑剤
ギヤ潤滑剤 鉱油 ３００〜３０
００繊維潤滑剤 ポリエチレングリコール １０００
〜３０００ポリプロピレングリコール
ガスエンジン油 鉱 油
合成炭化水素 ３５０〜６００デイーゼル
鉱油、エステルおよびエンジン油 合成炭化水素
６００〜１０００蒸気シリンダー 鉱 油
オイル １８００〜１９０
０難燃性液 鉱油（水）４００〜５００スピンド
ル油 鉱油 ５０〜１３０本発明
の原理、好ましい態様および操作の形態が明細書に記載
された。しかし、これらは制限よりはむしろ例示とみな
されるべきであるので、こ−に保護されることを意図す
る発明は開示された特定形態に限定されると解すべきで
はない。変形および変更が本発明の精神から逸脱するこ
となく当業者によりなされることができる。Metal processing mineral oil 100-2
00 Lubricant Gear Lubricant Mineral Oil 300~30
00 Textile lubricant Polyethylene glycol 1000
~3000 Polypropylene Glycol Gas Engine Oil Mineral Oil Synthetic Hydrocarbon 350~600 Diesel
Mineral oils, esters and engine oils Synthetic hydrocarbons
600~1000 Steam cylinder Mineral oil 1800~190
0 Flame Retardant Liquid Mineral Oil (Water) 400-500 Spindle Oil Mineral Oil 50-130 The principles, preferred embodiments and mode of operation of the invention have been described in the specification. However, these are to be considered illustrative rather than limiting, and the inventions herein intended to be protected should not be construed as limited to the specific forms disclosed. Variations and modifications can be made by those skilled in the art without departing from the spirit of the invention.
Claims (20)
および硫化ホホバ油からなる群から選ばれる少くとも２
つの成分の混合物を含む潤滑剤ベース成分。(1) At least two selected from the group consisting of jojoba oil, phosphite ester adduct of jojoba oil, and sulfurized jojoba oil.
A lubricant base component containing a mixture of two components.
約０．１〜約５％（Ｗ／Ｗ）の硫化ホホバ油を含む、請
求項（１）記載の潤滑剤ベース。(2) The lubricant base of claim (1) comprising about 0.1 to about 20% (W/W) jojoba oil and about 0.1 to about 5% (W/W) sulfurized jojoba oil. .
．１〜約５％（Ｗ／Ｗ）の硫化ホホバ油、および約０．
１〜約５％（Ｗ／Ｗ）のホホバ油の亜リン酸エステルア
ダクトを含む、請求項（１）記載の潤滑剤ベース。(3) About 0.1 to about 20% (W/W) jojoba oil, about 0
．． 1 to about 5% (W/W) sulfurized jojoba oil, and about 0.
The lubricant base of claim 1, comprising 1 to about 5% (w/w) phosphite adduct of jojoba oil.
約０．１〜約５％（Ｗ／Ｗ）のホホバ油の亜リン酸エス
テルアダクトを含む、請求項（１）記載の潤滑剤ベース
。Claim (1) comprising: (4) about 0.1 to about 20% (W/W) jojoba oil and about 0.1 to about 5% (W/W) phosphite adduct of jojoba oil. Lubricant base as described.
、化学式、表等があります▼ （式中、Ｒは水素、Ｃ＿１＿〜＿１＿２アルキル、Ｃ＿
１＿〜＿１＿２アリール、Ｃ＿１＿〜＿１＿２アルカリ
ール、Ｃ＿１＿〜＿１＿２アラルキルおよびシクロＣ＿
１＿〜＿１＿２アルキルからなる群から選ばれる） とホホバ油との反応生成物のモノ−またはジ−アダクト
である、請求項（１）記載の潤滑剤ベース。(5) Phosphite ester adduct of jojoba oil has ▲mathematical formula, chemical formula, table, etc.▼ (In the formula, R is hydrogen, C_1_ to_1_2 alkyl, C_
1_~_1_2 aryl, C_1_~_1_2 alkaryl, C_1_~_1_2 aralkyl and cycloC_
The lubricant base according to claim 1, wherein the lubricant base is a mono- or di-adduct of the reaction product of jojoba oil and jojoba oil.
ース。(6) The lubricant base according to claim (5), wherein R is butyl.
合点が炭素−炭素二重結合である、請求項（５）記載の
潤滑剤ベース。(7) The lubricant base according to claim (5), wherein the point of attachment of the phosphite adduct on the jojoba oil portion is a carbon-carbon double bond.
−Ａ （式中、ｘは１〜３であり、Ａはホホバ油である）およ
びそれら両者の組合せからなる群から選ばれる、請求項
（１）記載の潤滑剤ベース。(8) ▲There are mathematical formulas, chemical formulas, tables, etc.▼, A-S_x
-A (wherein x is 1-3 and A is jojoba oil) and a combination of both.
エステルアダクトおよび硫化ホホバ油からなる群から選
ばれる少くとも２つの成分の混合物を含む潤滑油ベース
を含む、耐摩耗および負荷支持性を含めて減摩性を有す
る潤滑性組成物。(9) a base liquid and a lubricating oil base comprising a mixture of at least two components selected from the group consisting of jojoba oil, phosphite ester adducts of jojoba oil, and sulfurized jojoba oil; A lubricating composition having anti-friction properties.
ル基潤滑剤、鉱油、鉱油とエステル基潤滑剤との混合物
、鉱油と合成炭化水素とエステル基潤滑剤との混合物、
鉱油基グリース、および合成炭化水素基グリースからな
る群から選ばれる、請求項（９）記載の潤滑性組成物。(10) The base liquid is a hydrocarbon oil, a synthetic hydrocarbon, an ester-based lubricant, a mineral oil, a mixture of mineral oil and an ester-based lubricant, a mixture of mineral oil, a synthetic hydrocarbon, and an ester-based lubricant,
The lubricating composition according to claim 9, which is selected from the group consisting of mineral oil-based greases and synthetic hydrocarbon-based greases.
Ｗ）のホホバ油および約０．１〜約０．５％（Ｗ／Ｗ）
の硫化ホホバ油を含む、請求項（９）記載の潤滑性組成
物。(11) Lubricant base component is about 0.1 to about 20% (W/
W) jojoba oil and about 0.1 to about 0.5% (W/W)
The lubricating composition according to claim 9, comprising sulfurized jojoba oil.
Ｗ）のホホバ油、約０．１〜約５％（Ｗ／Ｗ）の硫化ホ
ホバ油および約０．１〜約５％（Ｗ／Ｗ）のホホバ油の
亜リン酸エステルアダクトを含む、請求項（９）記載の
潤滑性組成物。(12) Lubricant base component is about 0.1 to about 20% (W/
W) jojoba oil, comprising about 0.1 to about 5% (W/W) sulfurized jojoba oil and about 0.1 to about 5% (W/W) phosphite ester adduct of jojoba oil. The lubricating composition according to item (9).
Ｗ）のホホバ油および約０．１〜約５％（Ｗ／Ｗ）のホ
ホバ油の亜リン酸エステルアダクトを含む、請求項（９
）記載の潤滑性組成物。(13) Lubricant base component is about 0.1 to about 20% (W/
Claim (9) comprising W) of jojoba oil and about 0.1 to about 5% (W/W) of a phosphite adduct of jojoba oil.
) The lubricating composition described.
、化学式、表等があります▼ （式中、Ｒは水素、Ｃ＿１＿〜＿１＿２アルキル、Ｃ＿
１＿〜＿１＿２アリール、Ｃ＿１＿〜＿１＿２アルカリ
ール、Ｃ＿１＿〜＿１＿２アラルキルおよびシクロＣ＿
１＿〜＿１＿２アルキルからなる群から選ばれる） とホホバ油との反応生成物のモノ−またはジ−アダクト
である、請求項（９）記載の潤滑性組成物。(14) Phosphite ester adduct of jojoba oil has ▲ mathematical formula, chemical formula, table, etc. ▼ (In the formula, R is hydrogen, C_1_ to_1_2 alkyl, C_
1_~_1_2 aryl, C_1_~_1_2 alkaryl, C_1_~_1_2 aralkyl and cycloC_
1_ to_1_2 alkyl) and jojoba oil.
アルカリール、Ｃ＿４＿〜＿８アラルキルおよびシクロ
Ｃ＿４＿〜＿８アルキルからなる群から選ばれる、請求
項（１４）記載の潤滑性組成物。(15) R is C_4_~_8 alkyl, C_4_~_8
The lubricating composition according to claim 14, wherein the lubricating composition is selected from the group consisting of alkaryl, C_4_-_8 aralkyl, and cycloC_4_-_8 alkyl.
性組成物。(16) The lubricating composition according to claim (15), wherein R is butyl.
分の結合点が炭素−炭素二重結合である、請求項（１４
）記載の潤滑性組成物。(17) Claim (14) wherein the bonding point of the phosphite adduct moiety on the jojoba oil moiety is a carbon-carbon double bond.
) The lubricating composition described.
Ｃ＿１＿〜＿１＿２アラルキルおよびシクロＣ＿１＿〜
＿１＿２アルキルからなる群から選ばれる） とホホバ油との反応生成物のモノ−またはジ−アダクト
である、ホホバ油の亜リン酸エステルアダクト。(18)▲There are mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R is hydrogen, C_1_～_1_2 alkaryl,
C_1_~_1_2 aralkyl and cycloC_1_~
A phosphite ester adduct of jojoba oil, which is a mono- or di-adduct of the reaction product of _1_2alkyl) with jojoba oil.
＿８アラルキル、およびシクロＣ＿４＿〜＿８アルキル
からなる群から選ばれる、請求項（１８）記載のホホバ
油の亜リン酸エステルアダクト。(19) R is C_4_~_8 alkaryl, C_4_~
The jojoba oil phosphite adduct according to claim 18, which is selected from the group consisting of _8 aralkyl, and cycloC_4_-_8 alkyl.
分の結合点が炭素−炭素二重結合である、請求項（１８
）記載のホホバ油の亜リン酸エステルアダクト。(20) Claim (18) wherein the bonding point of the phosphite adduct moiety on the jojoba oil moiety is a carbon-carbon double bond.
) Phosphite ester adduct of jojoba oil.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8818687A | 1987-08-21 | 1987-08-21 | |
| US088186 | 1987-08-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01131300A true JPH01131300A (en) | 1989-05-24 |
Family
ID=22209875
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63207994A Pending JPH01131300A (en) | 1987-08-21 | 1988-08-22 | Jojoba oil and jojoba oil derivative lubricant composition |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0308651B1 (en) |
| JP (1) | JPH01131300A (en) |
| AT (1) | ATE78865T1 (en) |
| AU (1) | AU602422B2 (en) |
| CA (1) | CA1313180C (en) |
| DE (1) | DE3873237T2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02311529A (en) * | 1989-05-26 | 1990-12-27 | Ube Ind Ltd | Metal-containing aromatic polycyclic polymer and its preparation |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4970010A (en) * | 1988-07-19 | 1990-11-13 | International Lubricants, Inc. | Vegetable oil derivatives as lubricant additives |
| DE3906759C2 (en) * | 1989-03-03 | 1997-01-30 | Fuchs Petrolub Ag Oel & Chemie | Method and device for lubricating an internal combustion engine |
| CN1037113C (en) * | 1993-10-12 | 1998-01-21 | 中国石油化工总公司石油化工科学研究院 | Lubricating grease for recording machine core and its preparing method |
| EP1544279B1 (en) | 2002-08-27 | 2016-09-28 | Nippon Oil Corporation | Lubricating composition |
| ES2396282B1 (en) * | 2010-06-24 | 2014-02-05 | Luis Carlos SÁNCHEZ HERRERA | EMPLOYMENT OF JOJOBA OIL AS CALO-CARRIER FLUID (HTF). |
| US10294405B2 (en) | 2015-10-29 | 2019-05-21 | King Fahd University Of Petroleum And Minerals | Oil-based drilling fluid employing jojoba oil |
| US11286412B2 (en) | 2019-11-04 | 2022-03-29 | Saudi Arabian Oil Company | Water-based drilling fluid compositions and methods for drilling subterranean wells |
| US11760919B2 (en) | 2020-07-07 | 2023-09-19 | Saudi Arabian Oil Company | Foams for hydrocarbon recovery, wells including such, and methods for use of such |
| US11840908B2 (en) | 2020-10-01 | 2023-12-12 | Saudi Arabian Oil Company | Acidizing fluid and method of improving hydrocarbon recovery using the same utilizing a surfactant consisting of an oil mixture |
| US11359134B2 (en) | 2020-10-19 | 2022-06-14 | Saudi Arabian Oil Company | Treatment fluids and methods for recovering hydrocarbons from a subterranean formation |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2212899A (en) * | 1937-09-20 | 1940-08-27 | Union Oil Co | Sulphurized lubricating oil |
| US3723314A (en) * | 1971-03-24 | 1973-03-27 | Mobil Oil Corp | Lubricant for metalworking |
| US3849323A (en) * | 1972-04-24 | 1974-11-19 | Weiner T | Friction-reducing petroleum mixtures and method of making same |
| US3956154A (en) * | 1974-02-11 | 1976-05-11 | Stauffer Chemical Company | Hydraulic fluid system |
| IL48585A (en) * | 1975-12-02 | 1979-01-31 | Univ Ben Gurion | Liquid jojoba oil derivatives |
| US4152278A (en) * | 1978-05-19 | 1979-05-01 | The United States Of America As Represented By The Secretary Of Agriculture | Wax esters of vegetable oil fatty acids useful as lubricants |
| IL65317A0 (en) * | 1982-03-23 | 1982-05-31 | Univ Ben Gurion | Liquid jojoba oil derivatives,process for the preparation thereof and lubricant compositions containing them |
| US4557841A (en) * | 1984-11-13 | 1985-12-10 | Wynn Oil Company | Lubricant additive concentrate |
-
1988
- 1988-08-17 AU AU21046/88A patent/AU602422B2/en not_active Ceased
- 1988-08-18 EP EP88113441A patent/EP0308651B1/en not_active Expired - Lifetime
- 1988-08-18 DE DE8888113441T patent/DE3873237T2/en not_active Expired - Lifetime
- 1988-08-18 AT AT88113441T patent/ATE78865T1/en not_active IP Right Cessation
- 1988-08-19 CA CA000575297A patent/CA1313180C/en not_active Expired - Fee Related
- 1988-08-22 JP JP63207994A patent/JPH01131300A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02311529A (en) * | 1989-05-26 | 1990-12-27 | Ube Ind Ltd | Metal-containing aromatic polycyclic polymer and its preparation |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0308651A3 (en) | 1989-07-12 |
| DE3873237D1 (en) | 1992-09-03 |
| EP0308651A2 (en) | 1989-03-29 |
| DE3873237T2 (en) | 1992-12-10 |
| EP0308651B1 (en) | 1992-07-29 |
| CA1313180C (en) | 1993-01-26 |
| ATE78865T1 (en) | 1992-08-15 |
| AU602422B2 (en) | 1990-10-11 |
| AU2104688A (en) | 1989-02-23 |
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