JPH01110926A - Molding die - Google Patents

Molding die

Info

Publication number
JPH01110926A
JPH01110926A JP27003087A JP27003087A JPH01110926A JP H01110926 A JPH01110926 A JP H01110926A JP 27003087 A JP27003087 A JP 27003087A JP 27003087 A JP27003087 A JP 27003087A JP H01110926 A JPH01110926 A JP H01110926A
Authority
JP
Japan
Prior art keywords
molding
mold
mirror surface
molding die
large number
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP27003087A
Other languages
Japanese (ja)
Inventor
Junji Fujii
淳司 藤井
Kazuyuki Fukuda
和幸 福田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Idemitsu Petrochemical Co Ltd
Original Assignee
Idemitsu Petrochemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Idemitsu Petrochemical Co Ltd filed Critical Idemitsu Petrochemical Co Ltd
Priority to JP27003087A priority Critical patent/JPH01110926A/en
Publication of JPH01110926A publication Critical patent/JPH01110926A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To obtain a mold capable of molding at favorable mold release conditions, by forming the planar part of the die from a metallic mirror surface body possessing a large number of fine vent holes. CONSTITUTION:This die 10 forms a planar part comprised of a vast area on its cavity part 11. A molding surface of the planer part is provided with a metallic mirror body 12. The mirror surface body 12 is provided on the cavity part 11 so as to cover the surface of a suction and exhaustion hole 13 bored in the cavity part 11. The mirror surface body 12 is formed of an electroformed plate having a large number of fine vent holes 12a. With this construction, molding of a product superior in transparency and gloss properties becomes possible.

Description

【発明の詳細な説明】 [産業上の利用分野コ 本発明は、比較的広い平面部を有する製品の成形に用い
る成形用金型に関し、特に、ポリプロピレンシートを用
いて融点以下の温度で成形を行なう際に有効な成形用金
型に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a molding die used for molding a product having a relatively wide flat area, and in particular, a mold for molding a product using a polypropylene sheet at a temperature below the melting point. The present invention relates to a mold for molding that is effective when performing such molding.

[従来の技術〕 従来、圧空および/もしくは真空式等の成形機を用いて
、熱可塑性樹脂シートから容器や蓋材等の各種製品が成
形されている。
[Prior Art] Conventionally, various products such as containers and lids have been molded from thermoplastic resin sheets using compressed air and/or vacuum molding machines.

これら各種成形品のうち、例えば容器類は、食品、医薬
品等の包装用として利用されるため、その商品価値を高
めるために透明性を良くすることが望まれている。また
、製品の成形サイクルを早めるため、成形後における製
品の冷却を良くする必要もある。一方、平面部面積の大
きい金型を用いて成形する製品にあっては、製品の平面
部に波打ちを生じないようにして、製品の商品価値を高
めるようにしなければならない。
Among these various molded products, for example, containers are used for packaging foods, medicines, etc., and therefore, it is desired that they have good transparency in order to increase their commercial value. Furthermore, in order to speed up the molding cycle of the product, it is also necessary to improve cooling of the product after molding. On the other hand, when a product is molded using a mold with a large flat area, it is necessary to prevent the flat area of the product from undulating in order to increase the commercial value of the product.

しかしながら、熱可塑性樹脂シート、特にポリプロピレ
ンシートを用いて融点以下の温度で成形を行なう場合、
平面部面積の大きい金型を用いて大きな平面部を有する
容器や蓋材を波打ちのない良好な形状に成形することは
困難である。すなわち、シートと金型の間に残留する空
気が断熱層となり、金型による冷却固化にむらを生じる
ため。
However, when molding a thermoplastic resin sheet, especially a polypropylene sheet, at a temperature below its melting point,
It is difficult to use a mold with a large flat area to mold a container or lid material having a large flat area into a good shape without undulations. In other words, the air remaining between the sheet and the mold acts as a heat insulating layer, causing uneven cooling and solidification by the mold.

成形品平面部に歪が残り、その結果波打ちを生じて良製
品が得られない。
Distortion remains on the flat surface of the molded product, resulting in waving and making it impossible to obtain a good product.

これらの諸条件および問題点にかんがみ、従来は、残留
空気を排除するためセラミックを用しまた多孔質金型、
ポリテトラフィルオロエチレン(商品名:テフロン)樹
脂によって成形面をコーティングした金型、成形面を粗
面化した金型などが用いられている。
In view of these conditions and problems, conventionally ceramic molds were used to eliminate residual air, porous molds,
Molds with molding surfaces coated with polytetrafiloethylene (trade name: Teflon) resin, molds with roughened molding surfaces, etc. are used.

[解決すべき問題点] しかしながら、上述した各種金型を平面部面積の大きい
製品の成形用として用いるときには、次のような問題が
あった。
[Problems to be Solved] However, when the above-mentioned various molds are used for molding products having a large planar area, the following problems occur.

すなわち、セラミック多孔質金型は、成形品の波打ちを
解消するものの、粗面転写による成形品の透明不良を生
じるとともに、熱伝導性が悪く冷却が不充分となること
による成形サイクルの低下および、#天性の点で問題が
あった。
In other words, although ceramic porous molds eliminate the waving of molded products, they also cause poor transparency of molded products due to rough surface transfer, as well as a reduction in molding cycles due to poor thermal conductivity and insufficient cooling. # There was a problem with nature.

また、成形面をテフロン樹脂でコーティングした金型は
、離型性には優れているものの、粗面化およびシートと
金型の滑り改善による波打ちの解消は不十分で、粗面転
写により透明性も低下するという問題があった。
In addition, although molds whose molding surfaces are coated with Teflon resin have excellent mold releasability, it is insufficient to eliminate waviness due to roughening the surface and improving slippage between the sheet and the mold, and transparency due to rough surface transfer. There was also the problem that the

さらに、成形面をショツトブラスト、ペーパ掛は等で粗
面化した金型(広い平面部を有する成形品の波打ち防止
用として、最も一般的に採用されている金型)は、波打
ちの解消にある程度の効果を示すものの未だ十分でなく
、また、離型性が余り良くないとともに、粗面転写によ
り透明性を低下させるといった問題があった。
Furthermore, molds whose molding surfaces have been roughened by shot blasting, paper coating, etc. (the molds most commonly used to prevent waviness in molded products with wide flat areas) are effective at eliminating waviness. Although it shows some effect, it is still not sufficient, and there are also problems in that the mold releasability is not very good and transparency is reduced due to rough surface transfer.

なお、多孔通気性を有する電鋳板を用いた金型として特
開昭60−152692号、同61−104820号。
In addition, JP-A-60-152692 and JP-A-61-104820 are examples of molds using electroformed plates having porous air permeability.

同61−104849号などがあるが、これらはいずれ
も、曲面の多い複雑な形状で、表面の微細模様(凹凸)
を転写した製品を成形するための金型であり、広い平面
部を有する金型については何も記載がない。
No. 61-104849, etc., but all of these have complicated shapes with many curved surfaces and fine patterns (irregularities) on the surface.
This is a mold for molding a product that has been transferred, and there is no mention of a mold with a wide flat surface.

本発明は、従来技術における上記事情にかんがみてなさ
れたもので、比較的広い平面部を有する容器、蓋材など
の製品を、透明性の低下をもたらすことなく、しかも平
面部の波打ち不良を解消し、離型性良く成形できるよう
にした成形用金型の提供を目的とする。
The present invention was made in view of the above-mentioned circumstances in the prior art, and eliminates the problem of waviness in the flat surface of products such as containers and lids that have a relatively wide flat surface without reducing transparency. The object of the present invention is to provide a molding die that can perform molding with good mold releasability.

[問題点の解決手段] 本発明の成形用金型は、上記目的を達成するため、金型
成形面に比較的広い面積の平面部を有する金型において
、少なくとも上記平面部を、微細通気孔を多数有する金
属鏡面体によって形成した構成としてあり、好ましくは
金属鏡面体を電鋳体で構成しである。
[Means for Solving Problems] In order to achieve the above-mentioned object, the molding die of the present invention has a flat part with a relatively large area on the molding surface, and at least the flat part is provided with fine ventilation holes. The metal mirror surface body is preferably formed of an electroformed body.

[実施例] 以下、本発明の実施例を図面にもとづいて説明する。[Example] Embodiments of the present invention will be described below based on the drawings.

第1図および第2図は本発明金型の一実施例であり、第
1図は全体の縦断面図、第2図は要部の拡大断面図を示
す。
1 and 2 show an embodiment of the mold of the present invention, with FIG. 1 showing a longitudinal sectional view of the whole, and FIG. 2 showing an enlarged sectional view of the main parts.

これら図面において、10は成形用金型であり、熱板式
あるいは前加熱式等の圧空および/もしくは真空成形機
における金型として用いられる。この金型10は、比較
的広い平面部を有する容器、蓋材等の製品を成形すべく
、そのキャビティ部11に広い面積からなる平面部を形
成しである。平面部の熱可塑性樹脂シートと接触する成
形面には、金属鏡面体12が設けである。この金属鏡面
体12は、成形面に向ってキャビティ部11に穿設され
た吸排気孔13の表面を覆うようにして設けである。な
お、14は冷却管である。
In these drawings, 10 is a molding die, which is used as a mold in a hot plate type or preheating type compressed air and/or vacuum forming machine. This mold 10 has a cavity portion 11 formed with a flat portion having a relatively wide area in order to mold products such as containers and lids having a relatively wide flat portion. A metal mirror body 12 is provided on the molding surface that comes into contact with the flat thermoplastic resin sheet. This metal mirror body 12 is provided so as to cover the surface of the air intake and exhaust hole 13 formed in the cavity portion 11 toward the molding surface. Note that 14 is a cooling pipe.

上記金属鏡面体12は、多数の微細通気孔12aを有す
る金属、例えば電鋳板(体)で形成しである。この電鋳
板のシート接触面、すなわち、微細通気孔を除いた面の
表面粗度は13以下、好ましくは0.8S以下、より好
ましくは0.5S以下の鏡面とする。このようにすると
、透明性、光沢性に優れた製品の成形が可能となる。
The metal mirror body 12 is made of a metal, for example, an electroformed plate (body), having a large number of fine ventilation holes 12a. The sheet contacting surface of this electroformed plate, that is, the surface excluding the fine ventilation holes, has a mirror surface roughness of 13 or less, preferably 0.8S or less, more preferably 0.5S or less. In this way, it becomes possible to mold a product with excellent transparency and gloss.

また、微細通気孔の大きさは、通常5〜300ル、必要
に応じ10〜150ル程度とすることが好ましく、通気
孔の数は、通常10〜1000個/cm2、必要に応じ
30〜500個/C■2程度とすることが好ましい。
Further, the size of the fine ventilation holes is usually 5 to 300 l, preferably about 10 to 150 l if necessary, and the number of ventilation holes is usually 10 to 1000 pieces/cm2, and 30 to 500 if necessary. It is preferable that the number of particles/C is about 2.

さらに、この電鋳板(金属鏡面体12)は、必要に応じ
、通気性、熱伝導性の良好な金属粉、金属繊維の焼結体
などの材料によって裏打することもできる。
Furthermore, this electroformed plate (metal mirror surface body 12) can be lined with a material having good air permeability and thermal conductivity, such as metal powder or a sintered body of metal fiber, if necessary.

このよ・うな微細通気孔を有する電鋳板の製造方法は、
公知の方法によることができる(例えば、特開昭60−
152692号、同61−253392号)、これら公
知の方法は、いずれも、成形用金型の形成を目的とする
ものであり、電鋳加工法(本発明では広義の意味でメツ
キと云う)により、各種複雑な形状の金型を得ているが
、本発明は、広い平面部を形成するものを得る点で異な
る。
The manufacturing method for electroformed plates with such minute ventilation holes is as follows:
This can be done by a known method (for example, Japanese Patent Application Laid-open No. 1986-
No. 152692, No. 61-253392), these known methods are all aimed at forming a mold for molding, and are based on the electroforming method (referred to as "metsuki" in a broad sense in the present invention). Although molds with various complicated shapes have been obtained, the present invention is different in that a mold with a wide flat surface is obtained.

ここで、itM板の形成手順の一例を、模式的に示すと
次のようになる。
Here, an example of the procedure for forming the itM board is schematically shown as follows.

すなわち、ガラス、樹脂被覆研磨金属板、エポキシ樹脂
等の基材を用意しく第3図(a))、この基材の光沢面
(鏡面)に、導電性の良い金属と、導電性の悪い素材を
ある比率で混合したものを塗布する0例えば、ペースト
状銀ラッカー、酢酸ブチル、塩化ビニルラッカーの混合
物を基材にスプレーして10数ルの層を形成し、これを
乾燥させることによって基材処理を行なう、ここで塩化
ビニルラッカーの配合量を変更することにより、基材表
面の導電性を自由に設定し、結果的に、微細通気孔の大
きさと数を自由にコントロールすることができる。
That is, prepare a base material such as glass, resin-coated polished metal plate, epoxy resin, etc. (Fig. 3(a)), and coat the shiny surface (mirror surface) of this base material with a metal with good conductivity and a material with poor conductivity. For example, spray a mixture of pasty silver lacquer, butyl acetate, and vinyl chloride lacquer onto a substrate to form a layer of more than 10 layers, and dry this to coat the substrate. By changing the amount of vinyl chloride lacquer used during the treatment, the conductivity of the substrate surface can be freely set, and as a result, the size and number of microporous holes can be freely controlled.

次いで、メツキ素材は、ニッケル、クロム。Next, the metal materials are nickel and chrome.

鉄、銅などのメツキ材料とともにメツキ液槽で電解され
、多数の微細通気孔を有するメツキ層を形成させる(第
3図(b))、この場合、メツキ液には界面活性剤を添
加しないで、通気孔の形成を容易にする。また通気孔は
、メツキの進行にともなってその径が大きくなり通気性
1表面光沢の点からも優れたものとなる。メツキ面の厚
さは、通常2〜2ha程度である。
It is electrolyzed in a plating liquid bath together with plating materials such as iron and copper to form a plating layer with many microscopic vents (Fig. 3 (b)). In this case, no surfactant is added to the plating liquid. , facilitating the formation of vent holes. Further, the diameter of the ventilation holes increases as the plating progresses, resulting in excellent air permeability and surface gloss. The thickness of the plated surface is usually about 2 to 2 ha.

その後、このメツキ層はスプレー層を介して基材から容
易に剥離し、電鋳板となる。
Thereafter, this plating layer is easily peeled off from the base material via the spray layer, forming an electroformed plate.

メツキ材料としては、ニッケルを用いることが好ましい
、これにより1表面が平滑で、光沢があり、しかも多数
の微細通気孔を有する電鋳板を得ることができる。
As the plating material, it is preferable to use nickel. This makes it possible to obtain an electroformed plate that has one surface that is smooth and glossy, and that has a large number of fine ventilation holes.

上記実施例では、微細通気孔を多数有する金属鏡面体1
2として、電鋳板を用いる例について説明したが、電鋳
板以外のものを使用するとも勿論可能である0例えば、
金属板にレーザー等で穿設加工を行なって多数の微細孔
を穿設し、かつ、その前および/もしくは後で表面を研
磨したもの、焼結金属等の多連気性金属板の表面を研磨
したものなどがある。
In the above embodiment, a metal mirror surface body 1 having a large number of fine ventilation holes is used.
2, an example using an electroformed plate has been described, but it is of course possible to use something other than an electroformed plate. For example,
Polishing of the surface of a metal plate with multiple holes such as sintered metal, etc., where a large number of micro holes are drilled by drilling with a laser etc. on a metal plate, and the surface is polished before and/or after. There are things that have been done.

なお、本発明の成形用金型における、金属鏡面体12で
形成する平面部とは、完全なる平面のものと、大きな曲
面で実質上平面的なものを含む概念である。また、部分
的に文字や数字、さらには図形、模様などを形成しであ
るものであってもよい、このような形状の金属鏡面体1
2は、上述したいずれの材料、製造方法を採用するにし
ても、その加工が非常に簡単である。
In addition, in the molding die of the present invention, the flat part formed by the metal mirror surface body 12 is a concept that includes a completely flat part and a substantially flat part with a large curved surface. In addition, a metal mirror body 1 having such a shape may be partially formed with letters, numbers, or even figures or patterns.
No. 2 is very easy to process, regardless of which of the materials and manufacturing methods described above are used.

また、本発明の成形用金型における非平面部は、平面部
と同様に形成してもよいが1通常は金型に用いられる一
般的材料、例えばアルミニウム等で形成することが望ま
しい、そして、成形後の離型性をよくするため、fa型
剤を用いた処理を施すことも可能である。
Furthermore, although the non-planar portion in the molding die of the present invention may be formed in the same manner as the planar portion, it is preferable that it is made of a general material normally used for molds, such as aluminum, and In order to improve the mold releasability after molding, it is also possible to perform treatment using an fa type agent.

上記のような構成からなる本発明の成形用金型は、透明
性、光沢性に優れたシート、特にポリプロピレンなどの
透明な結晶性樹脂シートから、容器、蓋材等を成形する
場合に適している。また、厚さが 1001L〜3+a
+s、通常 120uL〜2■程度のシートの成形に適
している。
The molding die of the present invention having the above configuration is suitable for molding containers, lid materials, etc. from sheets with excellent transparency and gloss, especially transparent crystalline resin sheets such as polypropylene. There is. Also, the thickness is 1001L ~ 3+a
+s, usually suitable for forming sheets of about 120 μL to 2 cm.

次に、本発明の成形用金型による成形例と、従来の金型
による成形例を示す。
Next, a molding example using the molding die of the present invention and a molding example using a conventional mold will be shown.

0 本発明金型による成形例 ■ シート 出光ヒュアレイ FG−100(高透明ポリプロピレン
シート)200g/EVA系シーラン)  50 gノ
ラミネートシート:ヘイズ 12% ■ 成形品 容器の蓋材、平面部100mmφ、高さ8■■  金 
 型 キャビティ平面部をiltM板で形成し、それ以外の部
分を、表面にテフロン樹脂コーティングを施したアルミ
ニウムで形成。
0 Example of molding using the mold of the present invention ■ Sheet Idemitsu Furayray FG-100 (highly transparent polypropylene sheet) 200 g/EVA sealant) 50 g Nora laminate sheet: Haze 12% ■ Lid material for molded product container, flat part 100 mmφ, height 8■■ Gold
The flat surface of the mold cavity is made of iltM board, and the other parts are made of aluminum with a Teflon resin coating on the surface.

■ 熟成形機 熱板圧空成形機、真空圧空成形機 ■結果 (金型と接する側をシーラント面として成形)1金型平
面と同一形状 ■  考  察 上記結果より、透明性が低下せず、レインドロップのな
い、平面部に波打ちを生じない蓋材を成形できることが
判明した。また、離型性も良好であった。これにより、
金型面低融点シーラント層の成形が可能となった。
■ Aging mold machine Hot plate air pressure forming machine, Vacuum pressure forming machine It has been found that it is possible to mold a lid material that does not have drops and does not cause undulation on the flat surface. Moreover, the mold releasability was also good. This results in
It is now possible to form a low melting point sealant layer on the mold surface.

さらに、冷却が十分で成形サイクルも早いことから、生
産性の向上を図れることが判明した。
Furthermore, it was found that productivity could be improved because cooling was sufficient and the molding cycle was quick.

0 従来金型による成形例 ■ キャビティ全体(平面部を含む)を、表面にテフロ
ン樹脂コーティングを施したアルミニウムで形成した金
型を用いたほかは、本発明成形条件と同じとした。
0 Molding Example Using Conventional Mold ■ The molding conditions were the same as those of the present invention except that a mold in which the entire cavity (including the plane part) was made of aluminum whose surface was coated with Teflon resin was used.

■結果 ・串第4図 参照 ■  考  察 離型性は良いものの、透明性が低下し、平面部に高さ(
h)2mmの波打ちの有る蓋材が成形され、商品として
使用できなくなるといった問題の残ることが判明した。
■Results/See Fig. 4■ Discussion Although the mold releasability is good, the transparency is reduced and the height (
h) It was found that there remained a problem in that the lid material was molded with 2 mm undulations, making it unusable as a product.

[発明の効果] 以上のように本発明の成形用金型によれば、透明性を低
下させることなく、かつ平面部の波打ち不良を生じさせ
ない良質の成形品を得ることができ、しかも、離型性も
良好に保てるといった効果を有する。
[Effects of the Invention] As described above, according to the molding die of the present invention, it is possible to obtain a high-quality molded product without reducing transparency and causing no waviness defects in the plane part, and moreover, It also has the effect of maintaining good moldability.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明第一実例金型の縦断面図、第2図は第1
図の要部拡大断面図、第3図(a)。 (b)、(C)は電鋳板を形成する際の説明図、第4図
は従来の金型を用いた成形品の断面図を示す。 1:金型       ll:キャビティ部12:金属
鏡面体   12a:微細通気孔13:吸排気孔   
 14:冷却管
Fig. 1 is a vertical cross-sectional view of the first example mold of the present invention, and Fig. 2 is a longitudinal cross-sectional view of the first example mold of the present invention.
FIG. 3(a) is an enlarged sectional view of the main part of the figure. (b) and (C) are explanatory views when forming an electroformed plate, and FIG. 4 shows a cross-sectional view of a molded product using a conventional mold. 1: Mold ll: Cavity part 12: Metal mirror surface body 12a: Micro ventilation hole 13: Intake and exhaust hole
14: Cooling pipe

Claims (2)

【特許請求の範囲】[Claims] (1)金型成形面に比較的広い面積の平面部を有する金
型において、少なくとも上記平面部を、微細通気孔を多
数有する金属鏡面体によって形成したことを特徴とする
成形用金型。
(1) A mold having a relatively wide flat area on its molding surface, wherein at least the flat area is formed of a mirrored metal body having a large number of fine ventilation holes.
(2)金属鏡面体が、電鋳体であることを特徴とした特
許請求の範囲第1項記載の成形用金型。
(2) The molding die according to claim 1, wherein the mirror-finished metal body is an electroformed body.
JP27003087A 1987-10-26 1987-10-26 Molding die Pending JPH01110926A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP27003087A JPH01110926A (en) 1987-10-26 1987-10-26 Molding die

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP27003087A JPH01110926A (en) 1987-10-26 1987-10-26 Molding die

Publications (1)

Publication Number Publication Date
JPH01110926A true JPH01110926A (en) 1989-04-27

Family

ID=17480554

Family Applications (1)

Application Number Title Priority Date Filing Date
JP27003087A Pending JPH01110926A (en) 1987-10-26 1987-10-26 Molding die

Country Status (1)

Country Link
JP (1) JPH01110926A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0396320A (en) * 1989-09-08 1991-04-22 Dainippon Printing Co Ltd Heating device for sheet
JP2006088669A (en) * 2004-09-27 2006-04-06 Toyo Seikan Kaisha Ltd Flange molding method for flanged container, flanged container and easily-unsealable container
US7287975B2 (en) * 2003-06-12 2007-10-30 Towa Corporation Resin mold material and resin mold

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60152692A (en) * 1984-01-20 1985-08-10 Konan Tokushu Sangyo Kk Metallic mold for forming
JPS62292408A (en) * 1986-06-12 1987-12-19 Konan Tokushu Sangyo Kk Electroformed mold

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60152692A (en) * 1984-01-20 1985-08-10 Konan Tokushu Sangyo Kk Metallic mold for forming
JPS62292408A (en) * 1986-06-12 1987-12-19 Konan Tokushu Sangyo Kk Electroformed mold

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0396320A (en) * 1989-09-08 1991-04-22 Dainippon Printing Co Ltd Heating device for sheet
US7287975B2 (en) * 2003-06-12 2007-10-30 Towa Corporation Resin mold material and resin mold
JP2006088669A (en) * 2004-09-27 2006-04-06 Toyo Seikan Kaisha Ltd Flange molding method for flanged container, flanged container and easily-unsealable container
JP4599966B2 (en) * 2004-09-27 2010-12-15 東洋製罐株式会社 Flange molding method for flanged container, flanged container, and easy-open container

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