JP7484705B2 - Wastewater treatment system and wastewater treatment method - Google Patents

Wastewater treatment system and wastewater treatment method Download PDF

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JP7484705B2
JP7484705B2 JP2020217640A JP2020217640A JP7484705B2 JP 7484705 B2 JP7484705 B2 JP 7484705B2 JP 2020217640 A JP2020217640 A JP 2020217640A JP 2020217640 A JP2020217640 A JP 2020217640A JP 7484705 B2 JP7484705 B2 JP 7484705B2
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茉莉恵 植村
明恵 手嶋
元 高橋
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Oji Holdings Corp
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Description

本開示は、排出水量及び汚濁濃度の変動の大きな排水を、安定して省資源で適切に処理できる排水処理システム及び排水処理方法に関する。 This disclosure relates to a wastewater treatment system and method that can stably and appropriately treat wastewater with large fluctuations in discharge volume and pollutant concentration while conserving resources.

段ボール製造工場では、貼合機由来の糊洗浄水と製函機由来のインキ洗浄水が排水として発生する。水質汚濁防止法や廃棄物処理法に適した処理水質及び廃棄物となるように、これらの排水を処理することが必要である。これらの排水は洗浄水であることから、発生頻度や発生量、汚濁濃度の変動等の負荷変動が大きく、安定な処理水質を得ることが難しい。
このような大きな負荷変動に対応するための装置として、一次処理を凝集沈殿処理法、二次処理を生物処理として組み合わせて処理する方法が広く導入されている。生物処理に膜分離活性汚泥を使用する場合、膜の閉塞を防ぐために、凝集沈殿処理で汚濁物質を十分に低減させる必要がある。
また、大きな負荷変動のため、汚濁物質低減に必要な凝集剤添加量の変動が大きく、凝集剤添加量の自動制御においても、変動に対応することが必要である。凝集沈殿処理法として、被処理水の電気伝導度及び流量に応じて凝集剤添加量を調整する手段が記載されている(例えば、特許文献1~3)。
特許文献3では、電気伝導度の異なる2種類の原水の混合水の電気伝導度を測定し、混合比率と電気伝導度の関係に基づいて、凝集剤添加量を処理水のMFFが1.1以下になるよう制御する手段が記載されている。
In corrugated cardboard manufacturing plants, wastewater is generated from glue washing water from laminating machines and ink washing water from box making machines. It is necessary to treat these wastewaters so that the treated water quality and wastewater comply with the Water Pollution Prevention Law and the Waste Management Law. Since these wastewaters are washing waters, there are large load fluctuations such as fluctuations in generation frequency, generation volume, and pollutant concentration, making it difficult to obtain stable treated water quality.
As a device to deal with such large load fluctuations, a method that combines coagulation-sedimentation treatment for primary treatment and biological treatment for secondary treatment has been widely introduced. When using membrane separation activated sludge for biological treatment, it is necessary to sufficiently reduce pollutants by coagulation-sedimentation treatment to prevent clogging of the membrane.
In addition, because of the large load fluctuations, the amount of flocculant required to reduce pollutants fluctuates greatly, and it is necessary to respond to the fluctuations even in the automatic control of the amount of flocculant added. As a coagulation and sedimentation treatment method, a means for adjusting the amount of flocculant added depending on the electrical conductivity and flow rate of the water to be treated has been described (for example, Patent Documents 1 to 3).
Patent Document 3 describes a method for measuring the electrical conductivity of a mixture of two types of raw water with different electrical conductivities, and controlling the amount of coagulant added based on the relationship between the mixing ratio and electrical conductivity so that the MFF of the treated water is 1.1 or less.

特開平5-103910号公報Japanese Patent Application Laid-Open No. 5-103910 特開平6-304412号公報Japanese Patent Application Laid-Open No. 6-304412 特開2017-77513号公報JP 2017-77513 A

しかし、凝集剤の最適な添加量は電気伝導度に依存しない場合もある。糊洗浄水とインキ洗浄水のように、電気伝導度は同程度であるが、電荷密度が異なる複数の排水を処理する場合、混合水の電気伝導度のみに基づいて計算された凝集剤添加量では、過剰添加になるなど適切な凝集剤添加量で制御できない場合があることがわかった。
本開示は、電荷密度が異なる複数の排水の処理において、適切な凝集剤添加量を自動制御する排水処理システム及び排水処理方法を提供する。
However, the optimal amount of flocculant to be added does not always depend on the electrical conductivity. When treating multiple wastewaters with similar electrical conductivity but different charge densities, such as glue washing water and ink washing water, it was found that the amount of flocculant to be added calculated based only on the electrical conductivity of the mixed water may not be adequate and may result in excessive addition.
The present disclosure provides a wastewater treatment system and a wastewater treatment method that automatically controls an appropriate amount of flocculant to be added when treating multiple wastewaters with different charge densities.

[1] 2種類以上の排水を混合して凝集沈殿処理する排水処理システムであって、
該2種類以上の排水の中で最も電荷密度の絶対値が高い排水を排水Aとし、
該2種類以上の排水のうち該排水A以外の排水を他の排水としたとき、
該排水処理システムは、混合水を凝集沈殿処理するものであり、該混合水は該排水Aと該他の排水とを混合して得られたものであり、
該排水処理システムは、
該排水Aの電気伝導度、該他の排水の電気伝導度及び該混合水の電気伝導度のうちの少なくとも二つの電気伝導度を測定する電気伝導度計、
該排水Aの量、該他の排水の量及び該混合水の量のうちの少なくとも二つの水量を測定す
る水量測定装置、
該混合水を凝集沈殿処理する凝集沈殿処理装置、並びに
該凝集沈殿処理装置に凝集剤を添加する凝集剤添加装置を備え、
該排水処理システムは、該少なくとも二つの電気伝導度及び該少なくとも二つの水量から、
予め準備した、該排水Aの電気伝導度、該他の排水の電気伝導度、該混合水の量及び該混合水中の該排水Aと該他の排水との混合割合と、
凝集剤添加量と、
該凝集剤の添加及び沈殿処理後の該混合水の汚濁物質の指標と、の関係に基づき、
該混合水の汚濁物質の指標が予め設定した適正値以下となる適正凝集剤添加量を算出する演算部を有し、
該凝集沈殿処理において、該算出された該適正凝集剤添加量で、該凝集剤添加装置により該凝集沈殿処理装置に該凝集剤を添加することを特徴とする排水処理システム。
[2] 2種類以上の排水を混合して凝集沈殿処理する排水処理システムであって、
該2種類以上の排水のうち電荷密度の絶対値が100μeq/Lを超える排水を排水Aとし、
該2種類以上の排水のうち電荷密度の絶対値が0μeq/L~100μeq/Lの排水を他の排水としたとき、
該排水処理システムは、混合水を凝集沈殿処理するものであり、該混合水は該排水Aと該他の排水とを混合して得られたものであり、
該排水処理システムは、
該排水Aの電気伝導度、該他の排水の電気伝導度及び該混合水の電気伝導度のうちの少なくとも二つの電気伝導度を測定する電気伝導度計、
該排水Aの量、該他の排水の量及び該混合水の量のうちの少なくとも二つの水量を測定する水量測定装置、
該混合水を凝集沈殿処理する凝集沈殿処理装置、並びに
該凝集沈殿処理装置に凝集剤を添加する凝集剤添加装置を備え、
該排水処理システムは、該少なくとも二つの電気伝導度及び該少なくとも二つの水量から、
予め準備した、該排水Aの電気伝導度、該他の排水の電気伝導度、該混合水の量及び該混合水中の該排水Aと該他の排水との混合割合と、
凝集剤添加量と、
該凝集剤の添加及び沈殿処理後の該混合水の汚濁物質の指標と、の関係に基づき、
該混合水の汚濁物質の指標が予め設定した適正値以下となる適正凝集剤添加量を算出する演算部を有し、
該凝集沈殿処理において、該算出された該適正凝集剤添加量で、該凝集剤添加装置により該凝集沈殿処理装置に該凝集剤を添加することを特徴とする排水処理システム。
[3] 前記汚濁物質の指標が、濁度、浮遊物質量、紫外線吸光度及び化学的酸素要求量からなる群から選択される少なくとも一である[1]又は[2]に記載の排水処理システム。
[4] 前記汚濁物質の指標が、濁度である[1]又は[2]に記載の排水処理システム。
[1] A wastewater treatment system for mixing two or more types of wastewater and subjecting them to coagulation and sedimentation treatment,
The wastewater having the highest absolute value of the charge density among the two or more types of wastewater is designated as wastewater A;
When the wastewater other than the wastewater A among the two or more types of wastewater is regarded as the other wastewater,
The wastewater treatment system performs coagulation and sedimentation treatment on mixed water, the mixed water being obtained by mixing the wastewater A with the other wastewater,
The wastewater treatment system comprises:
an electrical conductivity meter for measuring at least two electrical conductivities of the drainage water A, the other drainage water, and the mixed water;
a water amount measuring device for measuring at least two water amounts among the amount of the wastewater A, the amount of the other wastewater, and the amount of the mixed water;
The method includes a coagulation and sedimentation treatment device for coagulating and sedimenting the mixed water, and a coagulant adding device for adding a coagulant to the coagulation and sedimentation treatment device,
The wastewater treatment system comprises:
The electrical conductivity of the wastewater A, the electrical conductivity of the other wastewater, the amount of the mixed water, and the mixing ratio of the wastewater A and the other wastewater in the mixed water, which have been prepared in advance,
The amount of flocculant added;
Based on the relationship between the addition of the coagulant and the indicator of the pollutants in the mixed water after the sedimentation treatment,
A calculation unit is provided for calculating an appropriate amount of flocculant to be added so that the pollutant index of the mixed water is equal to or less than a predetermined appropriate value,
The wastewater treatment system is characterized in that in the coagulation sedimentation treatment, the coagulant is added to the coagulation sedimentation treatment device by the coagulant adding device in the calculated appropriate coagulant addition amount.
[2] A wastewater treatment system for mixing two or more types of wastewater and subjecting them to coagulation and sedimentation treatment,
Among the two or more types of wastewater, wastewater having an absolute value of charge density exceeding 100 μeq/L is designated as wastewater A;
Among the two or more types of wastewater, wastewater having an absolute value of charge density of 0 μeq/L to 100 μeq/L is taken as the other wastewater,
The wastewater treatment system performs coagulation and sedimentation treatment on mixed water, the mixed water being obtained by mixing the wastewater A with the other wastewater,
The wastewater treatment system comprises:
an electrical conductivity meter for measuring at least two electrical conductivities of the drainage water A, the other drainage water, and the mixed water;
a water amount measuring device for measuring at least two water amounts among the amount of the wastewater A, the amount of the other wastewater, and the amount of the mixed water;
The method includes a coagulation and sedimentation treatment device for coagulating and sedimenting the mixed water, and a coagulant adding device for adding a coagulant to the coagulation and sedimentation treatment device,
The wastewater treatment system comprises:
The electrical conductivity of the wastewater A, the electrical conductivity of the other wastewater, the amount of the mixed water, and the mixing ratio of the wastewater A and the other wastewater in the mixed water, which have been prepared in advance,
The amount of flocculant added;
Based on the relationship between the addition of the coagulant and the indicator of the pollutants in the mixed water after the sedimentation treatment,
A calculation unit is provided for calculating an appropriate amount of flocculant to be added so that the pollutant index of the mixed water is equal to or less than a predetermined appropriate value,
The wastewater treatment system is characterized in that in the coagulation sedimentation treatment, the coagulant is added to the coagulation sedimentation treatment device by the coagulant adding device in the calculated appropriate coagulant addition amount.
[3] The wastewater treatment system according to [1] or [2], wherein the indicator of pollutants is at least one selected from the group consisting of turbidity, suspended solids, ultraviolet absorbance, and chemical oxygen demand.
[4] The wastewater treatment system according to [1] or [2], wherein the indicator of pollutants is turbidity.

[5] 前記排水処理システムは、
前記排水Aを貯留する貯留槽A、
前記排水A以外の前記他の排水を貯留する他の貯留槽、
該貯留槽Aから送水された前記排水Aと該他の貯留槽から送水された前記他の排水とを混合して前記混合水を得る混和槽、並びに
該混和槽から送水された前記混合水を凝集沈殿処理する連続式の凝集沈殿処理装置を備え、
前記排水処理システムは、
前記排水Aの電気伝導度Aを測定する電気伝導度計A及び該貯留槽Aから該混和槽に送水された前記排水Aの流量Aを測定する流量計A、
前記他の排水の電気伝導度を測定する他の電気伝導度計、並びに
該混和槽から凝集沈殿処理装置に送水された前記混合水の流量を測定する混合水流量計を備え、
前記演算部は、前記混合水の該流量、該電気伝導度A、該流量A、及び前記他の排水の電気伝導度から、前記関係に基づいて前記適正凝集剤添加量を算出する[1]~[4]のいずれかに記載の排水処理システム。
[6] 前記排水処理システムは、
前記排水Aを貯留する貯留槽A、
前記排水A以外の前記他の排水を貯留する他の貯留槽、並びに
該貯留槽Aから送水された前記排水A及び該他の貯留槽から送水された前記他の排水を混合し、得られた前記混合水を凝集沈殿処理する回分式の凝集沈殿処理装置を備え、
前記排水処理システムは、
前記排水Aの電気伝導度Aを測定する電気伝導度計A及び該貯留槽Aから前記凝集沈殿処理装置に送水された前記排水Aの流量Aを測定する流量計A、
前記他の排水の電気伝導度を測定する他の電気伝導度計、並びに
前記凝集沈殿処理装置に送水された前記混合水の量及び送水時間を測定する水位計を備え、
該演算部は、該電気伝導度A、該流量A、前記他の排水の電気伝導度、並びに前記混合水の量及び該送水時間から、前記関係に基づいて前記適正凝集剤添加量を算出する[1]~[4]のいずれかに記載の排水処理システム。
[7] 前記排水処理システムは、
前記排水A以外の前記他の排水を貯留する他の貯留槽、
前記排水Aが送水され、且つ、該他の貯留槽から前記他の排水が送水されることで、前記排水A及び前記他の排水が混合され前記混合水が得られ、前記混合水が貯留される混合水貯留槽、並びに
該混合水貯留槽から送水された前記混合水を凝集沈殿処理する前記凝集沈殿処理装置を備え、
前記排水処理システムは、
前記他の排水の電気伝導度を測定する他の電気伝導度計、該他の貯留槽から該混合水貯留槽に送水された前記他の排水の流量Bを測定する流量計B、
該混合水貯留槽中の前記混合水の電気伝導度Cを測定する電気伝導度計C、
該混合水貯留槽から前記凝集沈殿処理装置に送水された前記混合水の流量を測定する混合水流量計を備え、
前記演算部は、前記他の排水の電気伝導度、該流量B、該電気伝導度C及び前記混合水の流量から、前記関係に基づいて前記適正凝集剤添加量を算出する[1]~[4]のいずれかに記載の排水処理システム。
[5] The wastewater treatment system comprises:
A storage tank A for storing the wastewater A;
Another storage tank for storing the other wastewater other than the wastewater A;
a mixing tank for mixing the wastewater A sent from the storage tank A with the other wastewater sent from the other storage tank to obtain the mixed water, and a continuous coagulation and sedimentation treatment device for coagulating and sedimenting the mixed water sent from the mixing tank,
The wastewater treatment system comprises:
an electrical conductivity meter A for measuring the electrical conductivity A of the wastewater A and a flow meter A for measuring the flow rate A of the wastewater A conveyed from the storage tank A to the mixing tank;
another electrical conductivity meter for measuring the electrical conductivity of the other wastewater, and a mixed water flow meter for measuring the flow rate of the mixed water sent from the mixing tank to a coagulation sedimentation treatment device;
The calculation unit calculates the appropriate amount of coagulant to be added based on the relationship from the flow rate of the mixed water, the electrical conductivity A, the flow rate A, and the electrical conductivity of the other wastewater. Wastewater treatment system described in any of [1] to [4].
[6] The wastewater treatment system comprises:
A storage tank A for storing the wastewater A;
a second storage tank for storing the wastewater other than the wastewater A, and a batch-type coagulation and sedimentation treatment device for mixing the wastewater A sent from the storage tank A and the second storage tank for treating the mixed water by coagulation and sedimentation,
The wastewater treatment system comprises:
an electric conductivity meter A for measuring the electric conductivity A of the wastewater A and a flow meter A for measuring the flow rate A of the wastewater A conveyed from the storage tank A to the coagulation sedimentation treatment device;
Another electrical conductivity meter for measuring the electrical conductivity of the other wastewater, and a water level meter for measuring the amount and water supply time of the mixed water supplied to the coagulation sedimentation treatment device,
The calculation unit calculates the appropriate amount of coagulant to be added based on the relationship from the electrical conductivity A, the flow rate A, the electrical conductivity of the other wastewater, as well as the amount of the mixed water and the water supply time. Wastewater treatment system according to any one of [1] to [4].
[7] The wastewater treatment system comprises:
Another storage tank for storing the other wastewater other than the wastewater A;
The wastewater A is delivered and the other wastewater is delivered from the other storage tank, so that the wastewater A and the other wastewater are mixed to obtain the mixed water, and the mixed water is stored in a mixed water storage tank, and the coagulation sedimentation treatment device is provided for coagulating and sedimenting the mixed water delivered from the mixed water storage tank,
The wastewater treatment system comprises:
Another electrical conductivity meter for measuring the electrical conductivity of the other wastewater; a flow meter B for measuring the flow rate B of the other wastewater sent from the other storage tank to the mixed water storage tank;
an electrical conductivity meter C for measuring the electrical conductivity C of the mixed water in the mixed water storage tank;
a mixed water flow meter for measuring a flow rate of the mixed water sent from the mixed water storage tank to the coagulation sedimentation treatment device;
The wastewater treatment system according to any one of [1] to [4], wherein the calculation unit calculates the appropriate amount of coagulant to be added based on the relationship from the electrical conductivity of the other wastewater, the flow rate B, the electrical conductivity C, and the flow rate of the mixed water.

[8] 前記関係が、下記関係式(1)であり、
前記演算部が、下記関係式(1)により前記適正凝集剤添加量を算出する[5]~[7]のいずれかに記載の排水処理システム。
F=αEA×VA+βEB(VC-VA) ・・・(1)
(式中、F(L/h)は前記適正凝集剤添加量である。EA(μS/cm)は前記排水Aの電気伝導度であり、VA(m/h)は前記排水Aの流量Aである。EB(μS/cm)は前記他の排水の電気伝導度であり、VC(m/h)は前記混合水の流量である。α及びβは係数(cm/μS・L/m)であり、αは1.0×10-3~1.0×10-2の値を示し、βは1.0×10-4~1.0×10-3の値を示す。)
[9] 前記凝集剤添加装置による前記凝集剤の添加後、高分子凝集剤を前記混合水1m
につき固形分で0.1g~10g添加する[1]~[8]のいずれかに記載の排水処理システム。
[10] 前記排水Aの電荷密度が、-10000μeq/L以上-100μeq/L未満であり、
前記他の排水の電荷密度が、-100μeq/L~0μeq/Lである[1]~[9]のいずれかに記載の排水処理システム。
[11] 前記2種類以上の排水が、段ボール工場で発生する排水であり、
前記排水Aが、インキ洗浄水であり、前記排水A以外の前記他の排水が、糊洗浄水である[1]~[10]のいずれかに記載の排水処理システム。
[12] 前記排水処理システムは、前記凝集沈殿処理装置の処理水を生物学的に処理する生物反応槽を備える[1]~[11]のいずれかに記載の排水処理システム。
[13] 前記生物反応槽が膜分離活性汚泥処理装置である[12]に記載の排水処理システム。
[8] The relationship is the following relational formula (1):
The wastewater treatment system according to any one of [5] to [7], wherein the calculation unit calculates the appropriate amount of flocculant to be added by the following relational formula (1).
F = αEA × VA + βEB (VC - VA) ... (1)
(In the formula, F (L/h) is the appropriate amount of flocculant to be added. EA (μS/cm) is the electrical conductivity of wastewater A, VA (m 3 /h) is the flow rate A of wastewater A, EB (μS/cm) is the electrical conductivity of the other wastewater, and VC (m 3 /h) is the flow rate of the mixed water. α and β are coefficients (cm/μS·L/m 3 ), α is a value of 1.0×10 -3 to 1.0×10 -2 , and β is a value of 1.0×10 -4 to 1.0×10 -3 .)
[9] After the flocculant is added by the flocculant adding device, the polymer flocculant is added to 1 m of the mixed water.
The wastewater treatment system according to any one of [1] to [8], wherein 0.1 g to 10 g of solids are added per 3 .
[10] The charge density of the wastewater A is -10,000 μeq/L or more and less than -100 μeq/L,
The wastewater treatment system according to any one of [1] to [9], wherein the charge density of the other wastewater is −100 μeq/L to 0 μeq/L.
[11] The two or more types of wastewater are wastewater generated in a cardboard factory,
The wastewater treatment system according to any one of [1] to [10], wherein the wastewater A is ink washing water, and the other wastewater other than the wastewater A is glue washing water.
[12] The wastewater treatment system according to any one of [1] to [11], further comprising a biological reaction tank for biologically treating treated water from the coagulation sedimentation treatment device.
[13] The wastewater treatment system according to [12], wherein the biological reaction tank is a membrane separation activated sludge treatment device.

[14] 2種類以上の排水を混合して得られた混合水を凝集沈殿処理する凝集沈殿処理装置を備えた排水処理システムによる排水処理方法であって、
該排水処理方法は、
該2種類以上の排水の中で最も電荷密度の絶対値が高い排水である排水Aと、
該2種類以上の排水のうち該排水A以外の他の排水と、を混合して該混合水を得る混合工程、
該排水Aの電気伝導度、該他の排水の電気伝導度及び該混合水の電気伝導度のうちの少なくとも二つの電気伝導度、並びに該排水Aの量、該他の排水の量及び該混合水の量のうちの少なくとも二つの水量から、
予め準備した、該排水Aの電気伝導度、該他の排水の電気伝導度、該混合水の量及び該混合水中の該排水Aと該他の排水との混合割合と、
凝集剤添加量と、
該凝集剤の添加及び沈殿処理後の該混合水の汚濁物質の指標と、の関係に基づき、
該混合水の汚濁物質の指標が予め設定した適正値以下となる適正凝集剤添加量を算出する算出工程、並びに
得られた該混合水を凝集沈殿処理する凝集沈殿処理工程を有し、
該凝集沈殿処理工程において、該算出された該適正凝集剤添加量で、該凝集沈殿処理装置に該凝集剤を添加することを特徴とする排水処理方法。
[15] 2種類以上の排水を混合して得られた混合水を凝集沈殿処理する凝集沈殿処理装置を備えた排水処理システムによる排水処理方法であって、
該排水処理方法は、
該2種類以上の排水のうち電荷密度の絶対値が100μeq/Lを超える排水である排水Aと、
該2種類以上の排水のうち電荷密度の絶対値が0μeq/L~100μeq/Lの排水である他の排水と、を混合して該混合水を得る混合工程、
該排水Aの電気伝導度、該他の排水の電気伝導度及び該混合水の電気伝導度のうちの少なくとも二つの電気伝導度、並びに該排水Aの量、該他の排水の量及び該混合水の量のうちの少なくとも二つの水量から、
予め準備した、該排水Aの電気伝導度、該他の排水の電気伝導度、該混合水の量及び該混合水中の該排水Aと該他の排水との混合割合と、
凝集剤添加量と、
該凝集剤の添加及び沈殿処理後の該混合水の汚濁物質の指標と、の関係に基づき、
該混合水の汚濁物質の指標が予め設定した適正値以下となる適正凝集剤添加量を算出する算出工程、並びに
得られた該混合水を凝集沈殿処理する凝集沈殿処理工程を有し、
該凝集沈殿処理工程において、該算出された該適正凝集剤添加量で、該凝集沈殿処理装
置に該凝集剤を添加することを特徴とする排水処理方法。
[14] A wastewater treatment method using a wastewater treatment system equipped with a coagulation sedimentation treatment device that performs coagulation sedimentation treatment on mixed water obtained by mixing two or more types of wastewater, comprising:
The wastewater treatment method comprises:
Wastewater A is a wastewater having the highest absolute value of charge density among the two or more types of wastewater;
A mixing step of mixing the two or more types of wastewater with other wastewater than the wastewater A to obtain the mixed water;
From at least two electrical conductivities of the drainage A, the other drainage, and the mixed water, and the amount of at least two waters of the amount of the drainage A, the amount of the other drainage, and the amount of the mixed water,
The electrical conductivity of the wastewater A, the electrical conductivity of the other wastewater, the amount of the mixed water, and the mixing ratio of the wastewater A and the other wastewater in the mixed water, which have been prepared in advance,
The amount of flocculant added;
Based on the relationship between the addition of the coagulant and the indicator of the pollutants in the mixed water after the sedimentation treatment,
The method includes a calculation step of calculating an appropriate amount of flocculant to be added so that the pollutant index of the mixed water is equal to or less than a predetermined appropriate value, and a coagulation and sedimentation treatment step of subjecting the obtained mixed water to coagulation and sedimentation treatment,
The wastewater treatment method, wherein in the coagulation sedimentation treatment step, the calculated appropriate amount of coagulant to be added is added to the coagulation sedimentation treatment device.
[15] A wastewater treatment method using a wastewater treatment system equipped with a coagulation sedimentation treatment device that performs coagulation sedimentation treatment on mixed water obtained by mixing two or more types of wastewater, comprising:
The wastewater treatment method comprises:
Among the two or more types of wastewater, wastewater A is wastewater having an absolute value of charge density exceeding 100 μeq/L;
A mixing step of mixing the two or more types of wastewater with another wastewater having an absolute value of charge density of 0 μeq/L to 100 μeq/L to obtain the mixed water;
From at least two electrical conductivities of the drainage A, the other drainage, and the mixed water, and the amount of at least two waters of the amount of the drainage A, the amount of the other drainage, and the amount of the mixed water,
The electrical conductivity of the wastewater A, the electrical conductivity of the other wastewater, the amount of the mixed water, and the mixing ratio of the wastewater A and the other wastewater in the mixed water, which have been prepared in advance,
The amount of flocculant added;
Based on the relationship between the addition of the coagulant and the indicator of the pollutants in the mixed water after the sedimentation treatment,
The method includes a calculation step of calculating an appropriate amount of flocculant to be added so that the pollutant index of the mixed water is equal to or less than a predetermined appropriate value, and a coagulation and sedimentation treatment step of subjecting the obtained mixed water to coagulation and sedimentation treatment,
The wastewater treatment method, wherein in the coagulation and sedimentation treatment step, the calculated appropriate amount of coagulant to be added is added to the coagulation and sedimentation treatment device.

本開示により、電荷密度が異なる複数の排水の処理において、適切な凝集剤添加量を自動制御する排水処理システム及び排水処理方法を提供できる。 This disclosure provides a wastewater treatment system and method that automatically controls the appropriate amount of flocculant to be added when treating multiple wastewaters with different charge densities.

排水処理システムの概念図Conceptual diagram of wastewater treatment system 排水処理システムの一態様の概略図Schematic diagram of one embodiment of a wastewater treatment system. 排水処理システムの一態様の概略図Schematic diagram of one embodiment of a wastewater treatment system. 排水処理システムの一態様の概略図Schematic diagram of one embodiment of a wastewater treatment system. 排水処理システムの一態様の概略図Schematic diagram of one embodiment of a wastewater treatment system.

数値範囲を表す「XX以上YY以下」や「XX~YY」の記載は、特に断りのない限り、端点である下限及び上限を含む数値範囲を意味する。
数値範囲が段階的に記載されている場合、各数値範囲の上限及び下限は任意に組み合わせることができる。
The expressions "XX to YY" and "XX to YY" representing a numerical range mean a numerical range including the endpoints, that is, the lower limit and the upper limit, unless otherwise specified.
When numerical ranges are stated in stages, the upper and lower limits of each numerical range can be combined in any way.

本開示は、2種類以上の排水を混合して凝集沈殿処理する排水処理システムであって、
該2種類以上の排水の中で最も電荷密度の絶対値が高い排水を排水Aとし、
該2種類以上の排水のうち該排水A以外の排水を他の排水としたとき、
該排水処理システムは、混合水を凝集沈殿処理するものであり、該混合水は該排水Aと該他の排水とを混合して得られたものであり、
該排水処理システムは、
該排水Aの電気伝導度、該他の排水の電気伝導度及び該混合水の電気伝導度のうちの少なくとも二つの電気伝導度を測定する電気伝導度計、
該排水Aの量、該他の排水の量及び該混合水の量のうちの少なくとも二つの水量を測定する水量測定装置、
該混合水を凝集沈殿処理する凝集沈殿処理装置、並びに
該凝集沈殿処理装置に凝集剤を添加する凝集剤添加装置を備え、
該排水処理システムは、該少なくとも二つの電気伝導度及び該少なくとも二つの水量から、予め準備した、該排水Aの電気伝導度、該他の排水の電気伝導度、該混合水の量及び該混合水中の該排水Aと該他の排水との混合割合と、凝集剤添加量と、該凝集剤の添加及び沈殿処理後の該混合水の汚濁物質の指標と、の関係に基づき、該混合水の汚濁物質の指標が予め設定した適正値以下となる適正凝集剤添加量を算出する演算部を有し、
該凝集沈殿処理において、該算出された該適正凝集剤添加量で、該凝集剤添加装置により該凝集沈殿処理装置に該凝集剤を添加する排水処理システムに関する。
The present disclosure relates to a wastewater treatment system for mixing two or more types of wastewater and subjecting them to coagulation and sedimentation treatment,
The wastewater having the highest absolute value of the charge density among the two or more types of wastewater is designated as wastewater A;
When the wastewater other than the wastewater A among the two or more types of wastewater is regarded as the other wastewater,
The wastewater treatment system performs coagulation and sedimentation treatment on mixed water, the mixed water being obtained by mixing the wastewater A with the other wastewater,
The wastewater treatment system comprises:
an electrical conductivity meter for measuring at least two electrical conductivities of the drainage water A, the other drainage water, and the mixed water;
a water amount measuring device for measuring at least two water amounts among the amount of the wastewater A, the amount of the other wastewater, and the amount of the mixed water;
The method includes a coagulation and sedimentation treatment device for coagulating and sedimenting the mixed water, and a coagulant adding device for adding a coagulant to the coagulation and sedimentation treatment device,
The wastewater treatment system has a calculation unit that calculates an appropriate amount of flocculant to be added, which makes the index of the pollutant in the mixed water equal to or lower than a predetermined appropriate value, based on a relationship between the electrical conductivity of the wastewater A, the electrical conductivity of the other wastewater, the amount of the mixed water, and the mixing ratio of the wastewater A and the other wastewater in the mixed water, the amount of flocculant to be added, and an index of the pollutant in the mixed water after the addition of the flocculant and precipitation treatment, which is prepared in advance, from the at least two electrical conductivities and the at least two water volumes,
The present invention relates to a wastewater treatment system in which, in the coagulation sedimentation treatment, the coagulant is added to the coagulation sedimentation treatment device by the coagulant adding device in the calculated appropriate amount of coagulant to be added.

本開示の他の態様は、2種類以上の排水を混合して凝集沈殿処理する排水処理システムであって、
該2種類以上の排水のうち電荷密度の絶対値が100μeq/Lを超える排水を排水Aとし、
該2種類以上の排水のうち電荷密度の絶対値が0μeq/L~100μeq/Lの排水を他の排水としたとき、
該排水処理システムは、混合水を凝集沈殿処理するものであり、該混合水は該排水Aと該他の排水とを混合して得られたものであり、
該排水処理システムは、
該排水Aの電気伝導度、該他の排水の電気伝導度及び該混合水の電気伝導度のうちの少なくとも二つの電気伝導度を測定する電気伝導度計、
該排水Aの量、該他の排水の量及び該混合水の量のうちの少なくとも二つの水量を測定する水量測定装置、
該混合水を凝集沈殿処理する凝集沈殿処理装置、並びに
該凝集沈殿処理装置に凝集剤を添加する凝集剤添加装置を備え、
該排水処理システムは、該少なくとも二つの電気伝導度及び該少なくとも二つの水量から、予め準備した、該排水Aの電気伝導度、該他の排水の電気伝導度、該混合水の量及び該混合水中の該排水Aと該他の排水との混合割合と、凝集剤添加量と、該凝集剤の添加及び沈殿処理後の該混合水の汚濁物質の指標と、の関係に基づき、該混合水の汚濁物質の指標が予め設定した適正値以下となる適正凝集剤添加量を算出する演算部を有し、
該凝集沈殿処理において、該算出された該適正凝集剤添加量で、該凝集剤添加装置により該凝集沈殿処理装置に該凝集剤を添加する排水処理システムに関する。
Another aspect of the present disclosure is a wastewater treatment system for mixing two or more types of wastewater and subjecting them to coagulation and sedimentation treatment,
Among the two or more types of wastewater, wastewater having an absolute value of charge density exceeding 100 μeq/L is designated as wastewater A;
When wastewater having an absolute value of charge density of 0 μeq/L to 100 μeq/L among the two or more types of wastewater is the other wastewater,
The wastewater treatment system performs coagulation and sedimentation treatment on mixed water, the mixed water being obtained by mixing the wastewater A with the other wastewater,
The wastewater treatment system comprises:
an electrical conductivity meter for measuring at least two electrical conductivities of the drainage water A, the other drainage water, and the mixed water;
a water amount measuring device for measuring at least two water amounts among the amount of the wastewater A, the amount of the other wastewater, and the amount of the mixed water;
The method includes a coagulation and sedimentation treatment device for coagulating and sedimenting the mixed water, and a coagulant adding device for adding a coagulant to the coagulation and sedimentation treatment device,
The wastewater treatment system has a calculation unit that calculates an appropriate amount of flocculant to be added, which makes the index of the pollutant in the mixed water equal to or lower than a predetermined appropriate value, based on a relationship between the electrical conductivity of the wastewater A, the electrical conductivity of the other wastewater, the amount of the mixed water, and the mixing ratio of the wastewater A and the other wastewater in the mixed water, the amount of flocculant to be added, and an index of the pollutant in the mixed water after the addition of the flocculant and precipitation treatment, which is prepared in advance, from the at least two electrical conductivities and the at least two water volumes,
The present invention relates to a wastewater treatment system in which, in the coagulation sedimentation treatment, the coagulant is added to the coagulation sedimentation treatment device by the coagulant adding device in the calculated appropriate amount of coagulant to be added.

図1は、排水処理システムの概念図である。
排水処理システムは、2種類以上の排水を混合して凝集沈殿処理する。すなわち、排水処理システムは、該2種類以上の排水の中で最も電荷密度の絶対値が高い排水である排水A、及び該2種類以上の排水のうち該排水A以外の他の排水、を混合して得られた混合水を、凝集沈殿処理装置により凝集沈殿処理する。
他の態様においては、該2種類以上の排水のうち電荷密度の絶対値が100μeq/Lを超える排水である排水A、及び該2種類以上の排水のうち電荷密度の絶対値が0μeq/L~100μeq/Lの排水である他の排水、を混合して得られた混合水を、凝集沈殿処理装置により凝集沈殿処理する。他の態様においては、排水Aは複数存在してもよい。
FIG. 1 is a conceptual diagram of a wastewater treatment system.
The wastewater treatment system mixes two or more types of wastewater and performs coagulation and sedimentation treatment on the mixed water obtained by mixing wastewater A, which is wastewater having the highest absolute value of charge density among the two or more types of wastewater, and other wastewater among the two or more types of wastewater other than wastewater A, using a coagulation and sedimentation treatment device.
In another embodiment, mixed water obtained by mixing wastewater A, which is wastewater having an absolute value of charge density exceeding 100 μeq/L among the two or more types of wastewater, and other wastewater, which is wastewater having an absolute value of charge density of 0 μeq/L to 100 μeq/L among the two or more types of wastewater, is subjected to coagulation precipitation treatment by a coagulation precipitation treatment device. In another embodiment, there may be a plurality of wastewaters A.

排水処理システムは、排水Aの電気伝導度、他の排水の電気伝導度及び混合水の電気伝導度のうちの少なくとも二つの電気伝導度を測定する電気伝導度計、並びに排水Aの量、他の排水の量及び混合水の量のうちの少なくとも二つの水量を測定する水量測定装置を備える。また、排水処理システムは、凝集沈殿処理装置に凝集剤を添加する凝集剤添加装置を備える。排水処理システムは、及び凝集沈殿処理装置への凝集剤の添加量を算出(演算)する演算部を備える。
演算部は、測定された少なくとも二つの電気伝導度及び少なくとも二つの水量から、予め準備した、排水Aの電気伝導度、他の排水の電気伝導度、混合水の量及び該混合水中の該排水Aと該他の排水との混合割合、凝集剤添加量並びに凝集剤の添加及び沈殿処理後(凝集沈殿処理後)の混合水の汚濁物質の指標の関係に基づき、混合水の汚濁物質の指標が予め設定した適正値以下となる適正凝集剤添加量を算出する。
そして、排水処理システムは、算出された適正凝集剤添加量で、凝集剤添加装置により凝集沈殿処理装置に凝集剤を添加する。
The wastewater treatment system includes an electrical conductivity meter that measures at least two electrical conductivities of wastewater A, other wastewater, and mixed water, and a water volume measuring device that measures at least two water volumes of the amount of wastewater A, other wastewater, and mixed water. The wastewater treatment system also includes a flocculant addition device that adds a flocculant to the coagulation sedimentation treatment device. The wastewater treatment system also includes a calculation unit that calculates (calculates) the amount of flocculant to be added to the coagulation sedimentation treatment device.
The calculation unit calculates, from the at least two measured electrical conductivities and at least two water volumes, an appropriate amount of coagulant to be added that will make the index of the pollutants in the mixed water below a predetermined appropriate value, based on the relationship between the electrical conductivity of wastewater A, the electrical conductivity of the other wastewater, the volume of the mixed water and the mixing ratio of wastewater A and the other wastewater in the mixed water, the amount of coagulant to be added, and the index of the pollutants in the mixed water after the addition of the coagulant and the precipitation treatment (after the coagulation and precipitation treatment), which have been prepared in advance.
Then, the wastewater treatment system adds the calculated appropriate amount of flocculant to the flocculating sedimentation treatment device by the flocculant adding device.

排水処理方法においては、2種類以上の排水を混合して得られた混合水を凝集沈殿処理する凝集沈殿処理装置を備えた排水処理システムを用いる。
そして、排水処理方法は、
該2種類以上の排水の中で最も電荷密度の絶対値が高い排水である排水Aと、
該2種類以上の排水のうち該排水A以外の他の排水と、を混合して混合水を得る混合工程、
該排水Aの電気伝導度、該他の排水の電気伝導度及び該混合水の電気伝導度のうちの少なくとも二つの電気伝導度、並びに該排水Aの量、該他の排水の量及び該混合水の量のうちの少なくとも二つの水量から、予め準備した、排水Aの電気伝導度、他の排水の電気伝導度、混合水の量及び該混合水中の排水Aと他の排水との混合割合と、凝集剤添加量と、凝集剤の添加及び沈殿処理後の混合水の汚濁物質の指標と、の関係に基づき、混合水の汚濁物質の指標が予め設定した適正値以下となる適正凝集剤添加量を算出する算出工程、並びに
得られた混合水を凝集沈殿処理する凝集沈殿処理工程を有し、
凝集沈殿処理工程において、算出された適正凝集剤添加量で、凝集沈殿処理装置に凝集剤を添加する。
In the wastewater treatment method, a wastewater treatment system is used that is equipped with a coagulation sedimentation treatment device that performs coagulation sedimentation treatment on mixed water obtained by mixing two or more types of wastewater.
And the wastewater treatment method is
Wastewater A is a wastewater having the highest absolute value of charge density among the two or more types of wastewater;
A mixing step of mixing the two or more types of wastewater with other wastewater than the wastewater A to obtain mixed water;
a calculation step of calculating an appropriate amount of flocculant to be added, based on at least two electrical conductivities of the wastewater A, the other wastewater, and the mixed water, and at least two water volumes of the wastewater A, the other wastewater, and the mixed water, based on a previously prepared relationship between the electrical conductivity of the wastewater A, the electrical conductivity of the other wastewater, the volume of the mixed water, and the mixing ratio of the wastewater A and the other wastewater in the mixed water, the amount of flocculant to be added, and the indicator of the pollutant of the mixed water after the addition of the flocculant and the sedimentation treatment; and a coagulation and sedimentation treatment step of performing coagulation and sedimentation treatment on the resulting mixed water,
In the coagulation sedimentation treatment step, the calculated appropriate amount of coagulant is added to the coagulation sedimentation treatment device.

また、該排水処理方法の他の態様は、
該2種類以上の排水のうち電荷密度の絶対値が100μeq/Lを超える排水である排水Aと、
該2種類以上の排水のうち電荷密度の絶対値が0μeq/L~100μeq/Lの排水である他の排水と、を混合して該混合水を得る混合工程、
該排水Aの電気伝導度、該他の排水の電気伝導度及び該混合水の電気伝導度のうちの少なくとも二つの電気伝導度、並びに該排水Aの量、該他の排水の量及び該混合水の量のうちの少なくとも二つの水量から、予め準備した、排水Aの電気伝導度、他の排水の電気伝導度、混合水の量及び該混合水中の排水Aと他の排水との混合割合と、凝集剤添加量と、凝集剤の添加及び沈殿処理後の混合水の汚濁物質の指標と、の関係に基づき、混合水の汚濁物質の指標が予め設定した適正値以下となる適正凝集剤添加量を算出する算出工程、並びに
得られた該混合水を凝集沈殿処理する凝集沈殿処理工程を有し、
凝集沈殿処理工程において、算出された適正凝集剤添加量で、凝集沈殿処理装置に該凝集剤を添加する。
Another aspect of the wastewater treatment method is
Among the two or more types of wastewater, wastewater A is wastewater having an absolute value of charge density exceeding 100 μeq/L;
A mixing step of mixing the two or more types of wastewater with another wastewater having an absolute value of charge density of 0 μeq/L to 100 μeq/L to obtain the mixed water;
a calculation step of calculating an appropriate amount of flocculant to be added, based on at least two electrical conductivities of the wastewater A, the other wastewater, and the mixed water, and at least two water volumes of the wastewater A, the other wastewater, and the mixed water, based on a previously prepared relationship between the electrical conductivity of the wastewater A, the electrical conductivity of the other wastewater, the volume of the mixed water, and the mixing ratio of the wastewater A and the other wastewater in the mixed water, the amount of flocculant to be added, and the indicator of the pollutant of the mixed water after the addition of the flocculant and the sedimentation treatment; and a coagulation and sedimentation treatment step of subjecting the resulting mixed water to coagulation and sedimentation treatment,
In the coagulation sedimentation treatment step, the calculated appropriate amount of the coagulant is added to the coagulation sedimentation treatment device.

前述のとおり、電荷密度が異なる複数の排水を処理する場合、これらの混合水の電気伝導度に基づいて計算された凝集剤添加量では、過剰添加になる場合がある。例えば、排水AとBの電気伝導度は同等であっても、排水Aの電荷密度の絶対値が高い場合、排水A及びBの混合水の電気伝導度から算出した凝集剤添加量を採用すると、過剰添加になる場合がある。
一方で、凝集沈殿処理の自動制御を考慮すると、連続測定が困難な排水の電荷密度を、適切な凝集剤添加量を決定するための指標として用いることは困難である。
As described above, when treating multiple wastewaters with different charge densities, the amount of flocculant added calculated based on the electrical conductivity of the mixed water may result in excessive addition. For example, even if the electrical conductivities of wastewaters A and B are the same, if the absolute value of the charge density of wastewater A is high, the amount of flocculant added calculated from the electrical conductivity of the mixed water of wastewaters A and B may result in excessive addition.
On the other hand, when considering automatic control of the coagulation and sedimentation treatment, it is difficult to use the charge density of the wastewater, which is difficult to measure continuously, as an index for determining an appropriate amount of coagulant to be added.

そこで、本発明者らが検討したところ、このような排水A及びBの混合水に等量の凝集剤を添加した際、Bの混合比が高いほど処理水の濁度などの汚濁物質の指標が低くなる(すなわち、凝集剤の最適添加量が低くなる)ことがわかった。これは、電荷密度の絶対値が高い排水の方が、荷電中和に必要な凝集剤添加量が多くなるためと考えられる。
そして本発明者らは、電荷密度が異なる複数の排水を混合した混合水を処理する場合、電荷密度の絶対値の大きい排水Aの電気伝導度、他の排水の電気伝導度、混合水の量及び混合水中の複数の排水の混合割合に着目することで、過剰添加とならない凝集剤の最適添加量を制御しうることを見出した。
The inventors have studied and found that when equal amounts of flocculant are added to a mixture of wastewater A and B, the higher the mixing ratio of B, the lower the pollutant index such as turbidity of the treated water (i.e., the lower the optimal amount of flocculant to be added). This is thought to be because wastewater with a higher absolute value of charge density requires a larger amount of flocculant to be added for charge neutralization.
The inventors have discovered that when treating mixed water containing multiple wastewaters with different charge densities, it is possible to control the optimal amount of coagulant to be added without excessive addition by focusing on the electrical conductivity of wastewater A, which has a large absolute value of charge density, the electrical conductivity of the other wastewaters, the amount of mixed water, and the mixing ratio of the multiple wastewaters in the mixed water.

排水Aの電気伝導度、他の排水の電気伝導度、混合水の量及び混合水中の排水Aと他の排水との混合割合と、凝集剤添加量と、該凝集剤の添加及び沈殿処理後の該混合水の汚濁物質の指標と、の関係を取得する手段は特に制限されない。
例えば、あらかじめ、凝集沈殿処理に供する複数の排水のそれぞれの電気伝導度及び量と、それぞれの排水の汚濁物質の指標を適正値以下にするために必要な凝集剤の添加量と、のデータを取得する。より具体的には、排水Aに対する適正な凝集剤添加量と、他の排水に対する適正な凝集剤添加量とを予め凝集試験によって求めておく。電気伝導度の異なるそれぞれの排水について、凝集剤添加量と、凝集剤を添加し沈殿処理を行った後の汚濁物質の指標と、の検量関係を取得する。
混合水中の排水Aと他の排水との混合割合及び上記のようにして求めた各排水に対する適正な凝集剤添加量に基づいて、混合水に対する適正な凝集剤注入量を算出することができる。
これらのデータから、各排水の電気伝導度、混合水の量及び混合水中の各排水の混合割合と、凝集剤を添加し凝集沈殿処理を行った後の混合水における汚濁物質の指標を適正に
するための凝集剤添加量との関係を得ることができる。
There are no particular limitations on the means for acquiring the relationship between the electrical conductivity of wastewater A, the electrical conductivity of the other wastewater, the amount of mixed water and the mixing ratio of wastewater A to the other wastewater in the mixed water, the amount of coagulant added, and the indicator of pollutants in the mixed water after the addition of the coagulant and precipitation treatment.
For example, data on the electrical conductivity and amount of each of a plurality of wastewaters to be subjected to coagulation and sedimentation treatment, and the amount of flocculant required to reduce the pollutant index of each wastewater to an appropriate value or less are obtained in advance. More specifically, the appropriate amount of flocculant to be added for wastewater A and the appropriate amount of flocculant to be added for the other wastewaters are determined in advance by a coagulation test. For each wastewater with a different electrical conductivity, a calibration relationship is obtained between the amount of flocculant to be added and the pollutant index after the coagulant is added and the sedimentation treatment is performed.
An appropriate amount of coagulant to be injected into the mixed water can be calculated based on the mixing ratio of wastewater A to other wastewater in the mixed water and the appropriate amount of coagulant to be added to each wastewater determined as described above.
From these data, it is possible to obtain the relationship between the electrical conductivity of each wastewater, the amount of mixed water, and the mixing ratio of each wastewater in the mixed water, and the amount of coagulant to be added to adjust the indicator of pollutants in the mixed water after adding a coagulant and performing coagulation and sedimentation treatment.

排水Aの電気伝導度AをEAとし、排水Aの量をVAとし、
他の排水を排水Bとしたときの該排水Bの電気伝導度をEBとし、排水Bの量をVBとし、
混合水の電気伝導度をECとし、混合水の量をVCとしたとき、
近似的に以下の関係式(A)が成り立つ。
EA×VA + EB×VB = EC×VC ・・・(A)
また、混合水中の排水Aの混合割合をrとしたとき、近似的に以下の関係式(B)が成り立つ。
EC = EA×r + EB×(1-r) ・・・(B)
排水A以外の排水が2以上の場合でも、それらを混合して得た他の排水(すなわち、排水B)を測定し、式A、式Bに適用することができる。
The electrical conductivity A of wastewater A is EA, and the volume of wastewater A is VA.
When another wastewater is wastewater B, the electrical conductivity of the wastewater B is EB, and the amount of the wastewater B is VB.
When the electrical conductivity of the mixed water is EC and the volume of the mixed water is VC,
The following relational expression (A) approximately holds true:
EA x VA + EB x VB = EC x VC ... (A)
In addition, when the mixing ratio of wastewater A in the mixed water is r, the following relational expression (B) approximately holds.
EC = EA × r + EB × (1-r) ... (B)
Even when there are two or more wastewaters other than wastewater A, the other wastewater obtained by mixing them (i.e., wastewater B) can be measured and applied to formulas A and B.

したがって、排水Aの電気伝導度、他の排水の電気伝導度及び混合水の電気伝導度のうちの少なくとも二つと、排水Aの量、他の排水の量及び混合水の量のうちの少なくとも二つを測定することができれば、これらすべての値を算出しうる。自動制御の観点から、電荷密度の絶対値が大きく凝集剤添加量に影響しやすい、排水Aの電気伝導度及び排水Aの量を測定することが好ましい。
よって、排水処理システムは、排水Aの電気伝導度、他の排水の電気伝導度及び混合水の電気伝導度のうちの少なくとも二つ(例えば二つ)の電気伝導度を測定する電気伝導度計を備える。また、排水処理システムは、排水Aの量、他の排水の量及び混合水の量のうちの少なくとも二つ(例えば二つ)の水量を測定する水量測定装置を備える。少ない測定装置で適切な凝集剤添加量を算出することができる。水量測定装置は、例えば、流量計又は水位計などが挙げられる。
Therefore, if at least two of the electrical conductivity of wastewater A, the electrical conductivity of the other wastewater, and the electrical conductivity of the mixed water, and at least two of the amount of wastewater A, the amount of the other wastewater, and the amount of the mixed water can be measured, all of these values can be calculated. From the viewpoint of automatic control, it is preferable to measure the electrical conductivity of wastewater A and the amount of wastewater A, which have a large absolute value of charge density and are likely to affect the amount of flocculant added.
Therefore, the wastewater treatment system includes an electrical conductivity meter that measures at least two (e.g., two) electrical conductivities of the wastewater A, the other wastewater, and the mixed water. The wastewater treatment system also includes a water volume measuring device that measures at least two (e.g., two) water volumes of the wastewater A, the other wastewater, and the mixed water. An appropriate amount of flocculant to be added can be calculated with a small number of measuring devices. Examples of the water volume measuring device include a flow meter or a water level gauge.

排水の量とは、排水の体積であってもよいし、排水の流量(単位時間当たりの排水の体積)であってもよい。排水処理システムに適用する凝集沈殿処理装置の種類に応じて、適宜選択すればよい。排水の流量と流入時間から排水の体積を計算でき、排水の体積と送水時間から排水の流量を計算できる。
例えば、凝集沈殿処理装置が連続式の場合、排水の流量を選択しうる。すなわち、排水Aの流量、他の排水の流量、及び混合水の流量を用いて、凝集剤添加量との関係を設定し、単位時間当たりの適正凝集剤添加量を算出すればよい。
また、凝集沈殿処理装置が回分式の場合、排水の体積を選択しうる。すなわち、凝集沈殿槽における排水Aの体積、他の排水の体積、及び混合水の体積を用いて、凝集剤添加量との関係を設定し、適正凝集剤添加量を算出すればよい。凝集沈殿処理装置が回分式の場合、排水の流量を選択してもよい。排水の流量及び送水時間に基づいて、単位時間当たりの適正凝集剤添加量を算出し、回分式の凝集沈殿槽への排水の送水時間に応じた量の凝集剤を添加すればよい。
The amount of wastewater may be the volume of the wastewater or the flow rate of the wastewater (volume of the wastewater per unit time). It may be appropriately selected depending on the type of coagulation sedimentation treatment device applied to the wastewater treatment system. The volume of the wastewater can be calculated from the flow rate of the wastewater and the inflow time, and the flow rate of the wastewater can be calculated from the volume of the wastewater and the water conveyance time.
For example, when the coagulation and sedimentation treatment device is a continuous type, the flow rate of the wastewater can be selected. That is, the relationship with the amount of flocculant to be added can be set using the flow rate of wastewater A, the flow rate of other wastewater, and the flow rate of mixed water, and the appropriate amount of flocculant to be added per unit time can be calculated.
In addition, when the coagulation sedimentation treatment device is a batch type, the volume of the wastewater can be selected. That is, the volume of the wastewater A in the coagulation sedimentation tank, the volume of the other wastewater, and the volume of the mixed water can be used to set the relationship with the amount of coagulant to be added, and the appropriate amount of coagulant to be added can be calculated. In the case of the coagulation sedimentation treatment device is a batch type, the flow rate of the wastewater can be selected. The appropriate amount of coagulant to be added per unit time can be calculated based on the flow rate and water supply time of the wastewater, and the amount of coagulant corresponding to the water supply time of the wastewater to the batch type coagulation sedimentation tank can be added.

各排水の電気伝導度及び各排水の量の測定には、特に制限されず、公知の電気伝導度計、流量計及び水位計を用いることができる。自動制御の観点から、連続測定可能なものが好ましい。
排水処理システムにおける、電気伝導度計や流量計などの測定装置の位置は特に制限されない。使用する排水の貯留槽や混合槽の構成、使用する凝集沈殿処理装置の構成に応じて適宜選択すればよい。排水処理システムは、排水Aの電気伝導度、他の排水の電気伝導度又は混合水の電気伝導度を測定できる位置に電気伝導度計を有していればよい。また、排水処理システムは、排水Aの量、他の排水の量又は混合水の量を測定できる位置に流量計又は水位計を有していればよい。
The measurement of the electrical conductivity and the amount of each wastewater is not particularly limited, and a known electrical conductivity meter, flow meter, and water level meter can be used. From the viewpoint of automatic control, those capable of continuous measurement are preferable.
The positions of measuring devices such as electrical conductivity meters and flow meters in the wastewater treatment system are not particularly limited. They may be appropriately selected depending on the configuration of the wastewater storage tank and mixing tank used and the configuration of the coagulation sedimentation treatment device used. The wastewater treatment system may have an electrical conductivity meter at a position where it can measure the electrical conductivity of wastewater A, the electrical conductivity of other wastewater, or the electrical conductivity of the mixed water. In addition, the wastewater treatment system may have a flow meter or a water level gauge at a position where it can measure the amount of wastewater A, the amount of other wastewater, or the amount of the mixed water.

なお、2種類以上の排水のうち、排水A以外の排水が一つの場合はその一つが、排水A以外の排水が複数の場合はそれらを混合した排水が、他の排水である。
排水A以外の排水が複数存在する場合、他の排水の電気伝導度及び他の排水の量とは、排水A以外の排水を混合した排水の電気伝導度及び量を意味する。他の排水の電気伝導度及び他の排水の量は、複数の排水A以外の排水を混合した後に測定してもよいし、複数の排水A以外の排水のそれぞれの値から計算した値でもよい。
また、排水Aが複数存在する場合、排水Aの電気伝導度及び排水Aの量とは、複数の排水Aを混合したときの電気伝導度及び量を意味する。排水Aの電気伝導度及び排水Aの量は、複数の排水Aを混合した後に測定してもよいし、複数の排水Aのそれぞれの値から計算した値でもよい。
In addition, when there is one wastewater other than wastewater A among two or more kinds of wastewater, that one is the other wastewater, and when there are multiple kinds of wastewater other than wastewater A, a mixture of these wastewaters is the other wastewater.
When multiple wastewaters other than wastewater A are present, the electrical conductivity of the other wastewaters and the amount of the other wastewaters refer to the electrical conductivity and amount of wastewater mixed with wastewaters other than wastewater A. The electrical conductivity of the other wastewaters and the amount of the other wastewaters may be measured after mixing multiple wastewaters other than wastewater A, or may be values calculated from the values of each of the multiple wastewaters other than wastewater A.
In addition, when a plurality of wastewaters A are present, the electrical conductivity of wastewater A and the amount of wastewater A refer to the electrical conductivity and amount when a plurality of wastewaters A are mixed. The electrical conductivity of wastewater A and the amount of wastewater A may be measured after a plurality of wastewaters A are mixed, or may be values calculated from the values of each of the plurality of wastewaters A.

排水処理後の処理水の汚濁物質の指標は特に制限されず、例えば、濁度、浮遊物質量(SS)、紫外線吸光度(UV)、化学的酸素要求量(COD)などが挙げられる。凝集沈殿処理の後段の装置や放流の水質基準に応じて適宜選択すればよい。汚濁物質の指標は、好ましくは濁度、浮遊物質量、紫外線吸光度及び化学的酸素要求量からなる群から選択される少なくとも一である。これらの指標を低減するのに必要な凝集剤添加量が電荷密度と相関しており、上記排水処理システム及び排水処理方法により、より適正な凝集剤注入量を算出しうる。
汚濁物質の指標は、より好ましくは濁度である。濁度は、連続測定及び1点測定のどちらも可能である。濁度の適正値は、好ましくは0.0度~100.0度であり、より好ましくは8.0度~60.0度であり、さらに好ましくは10.0度~15.0度である。
濁度の測定は、JISK0101「工業用水試験方法」又は「JISK0801 濁度自動計測器」に規定される濁度に応じた濁度計による測定を行う。測定方法は、連続測定でもよく、定期的な1点測定でもよい。
連続測定では、「JISK0801 濁度自動計測器」に規定される透過散乱光方式あるいは表面散乱光方式を用いる。1点測定では、JISK0101「工業用水試験方法」に規定される視覚法、透過光法、散乱光法、積分球法を用いる。濁度は凝集沈殿処理による上澄みを用いて測定する。
The indicator of pollutants in the treated water after wastewater treatment is not particularly limited, and examples thereof include turbidity, suspended solids (SS), ultraviolet absorbance (UV), and chemical oxygen demand (COD). It may be appropriately selected according to the downstream equipment of the coagulation and sedimentation treatment and the water quality standard of the discharge. The indicator of pollutants is preferably at least one selected from the group consisting of turbidity, suspended solids, ultraviolet absorbance, and chemical oxygen demand. The amount of flocculant added required to reduce these indicators is correlated with the charge density, and the above-mentioned wastewater treatment system and wastewater treatment method can calculate a more appropriate amount of flocculant to be injected.
The indicator of pollutants is more preferably turbidity. Turbidity can be measured either continuously or at one point. The appropriate value of turbidity is preferably 0.0 to 100.0 degrees, more preferably 8.0 to 60.0 degrees, and even more preferably 10.0 to 15.0 degrees.
The turbidity is measured using a turbidimeter according to the turbidity specified in JIS K0101 "Industrial Water Testing Method" or "JIS K0801 Automatic Turbidity Meter." The measurement method may be continuous measurement or periodic single-point measurement.
For continuous measurements, the transmitted light scattering method or the surface scattered light method specified in "JIS K0801 Automatic Turbidity Meter" is used. For single point measurements, the visual method, transmitted light method, scattered light method, and integrating sphere method specified in JIS K0101 "Industrial Water Testing Method" are used. Turbidity is measured using the supernatant obtained by coagulation and sedimentation treatment.

凝集沈殿処理装置は、回分式でもよいし、連続式でもよい。
凝集沈殿処理では、混合水に凝集剤を添加する。凝集剤が添加されることで、被処理水中の微細粒子が凝集する。
凝集剤としては、特に制限されず、公知の凝集剤を用いることができる。例えば、硫酸バンド(硫酸アルミニウム)、ポリ鉄(ポリ硫酸第二鉄)、ポリ塩化アルミニウム、塩化第二鉄、硫酸第一鉄などの無機凝集剤が挙げられる。
凝集剤は、カチオン系の凝集剤が好ましく、金属系無機凝集剤として鉄系又はアルミ系の凝集剤がより好ましく、ポリ鉄、硫酸バンド及びポリ塩化アルミニウムからなる群から選択される少なくとも一である鉄系又はアルミ系の凝集剤がさらに好ましい。硫酸バンド及びポリ塩化アルミニウムからなる群から選択される少なくとも一であるアルミ系の凝集剤がもっとも好ましい。
凝集剤が硫酸バンドの場合、その硫酸アルミニウム濃度は5質量%~15質量%(より好ましくは6質量%~10質量%)のものを用いることが好ましい。その他、凝集助剤を併用してもよい。凝集助剤としては、珪藻土、カオリン、タルクなどが挙げられる。
The coagulation and sedimentation treatment device may be of a batch type or a continuous type.
In the coagulation and sedimentation treatment, a coagulant is added to the mixed water, which causes fine particles in the water to coagulate.
The flocculant is not particularly limited, and any known flocculant can be used, including, for example, inorganic flocculants such as aluminum sulfate (aluminum sulfate), polyiron (polyferric sulfate), polyaluminum chloride, ferric chloride, and ferrous sulfate.
The flocculant is preferably a cationic flocculant, more preferably an iron- or aluminum-based flocculant as a metal-based inorganic flocculant, even more preferably an iron- or aluminum-based flocculant selected from the group consisting of polyiron, aluminum sulfate, and polyaluminum chloride, and most preferably an aluminum-based flocculant selected from the group consisting of aluminum sulfate and polyaluminum chloride.
When the flocculant is aluminum sulfate, it is preferable to use one having an aluminum sulfate concentration of 5% by mass to 15% by mass (more preferably 6% by mass to 10% by mass). Other flocculant aids may be used in combination. Examples of flocculant aids include diatomaceous earth, kaolin, and talc.

凝集に適したpHに制御するため、公知の酸又はアルカリ剤などのpH調整剤を添加してもよい。凝集沈殿処理では、好ましくは凝集剤及びアルカリ剤を添加する。
凝集の際のpHは、アルミ系凝集剤の場合は、好ましくは5.0~8.0程度、より好ましくは6.0~7.5程度、さらに好ましくは6.5~7.0程度に制御すればよい。鉄系凝集剤の場合、該pHは、好ましくは4.0以上、より好ましくは6.5~7.0程度に制御すればよい。
In order to adjust the pH to a level suitable for coagulation, a pH adjuster such as a known acid or alkali agent may be added. In the coagulation precipitation treatment, a coagulant and an alkali agent are preferably added.
The pH during flocculation is preferably controlled to about 5.0 to 8.0 in the case of an aluminum-based flocculant, more preferably about 6.0 to 7.5, and even more preferably about 6.5 to 7.0. In the case of an iron-based flocculant, the pH is preferably controlled to 4.0 or more, more preferably about 6.5 to 7.0.

続いて、凝集剤が添加された混合水に、高分子凝集剤を添加してもよい。高分子凝集剤は、凝集剤により凝集した微細粒子の凝集物同士をさらに凝集させ、大きなフロックを形成させる(フロック化)。形成されたフロックは沈殿しやすくなるため、固液分離しやすくなる。
高分子凝集剤は、特に制限されず、公知の高分子凝集剤を用いることができる。例えば、ポリアクリルアミド系、2-アクリロイルアミノ-2-メチルプロパンスルホン酸(AMPS)などが挙げられる。高分子凝集剤には、アニオン性高分子凝集剤、カチオン性高分子凝集剤、ノニオン性高分子凝集剤などがあり、混合水の荷電状態に応じて適宜選択すればよい。
Next, a polymer flocculant may be added to the mixed water to which the flocculant has been added. The polymer flocculant further flocculates the fine particles that have been flocculated by the flocculant, forming larger flocs (flocculation). The formed flocs are more likely to settle, facilitating solid-liquid separation.
The polymer flocculant is not particularly limited, and any known polymer flocculant can be used. For example, polyacrylamide, 2-acryloylamino-2-methylpropanesulfonic acid (AMPS), etc. Polymer flocculants include anionic polymer flocculants, cationic polymer flocculants, nonionic polymer flocculants, etc., and may be appropriately selected depending on the charge state of the mixed water.

高分子凝集剤の添加量は処理する混合水1mにつき固形分で0.1g~10g程度であることが好ましい。
高分子凝集剤が添加され、フロックが形成された混合水(凝集沈殿処理による処理物)は、例えば、沈降分離などにより、上澄み液(処理水)とフロックを含む沈殿物(汚泥スラリー)とに分離される。
The amount of polymer flocculant added is preferably about 0.1 g to 10 g in terms of solid content per cubic meter of mixed water to be treated.
The mixed water to which the polymer flocculant has been added and in which flocs have been formed (the treated product of the coagulation-sedimentation treatment) is separated, for example, by sedimentation separation into a supernatant liquid (treated water) and a sediment containing flocs (sludge slurry).

排水処理システムにおいて、2種類以上の排水は、好ましくは2種類の排水である。
2種類以上の排水は、食品工場又は段ボール工場で発生する排水であることが好ましい。より好ましくは段ボール工場で発生する排水である。2種類の排水が、段ボール工場で発生する排水の場合、(最も電荷密度の絶対値が高い排水又は電荷密度の絶対値が100μeq/Lを超える排水である)排水Aは、好ましくは製函機由来のインキ洗浄水であり、排水A以外の他の排水は、好ましくは貼合機由来の糊洗浄水である。
製函機由来のインキ洗浄水とは、段ボール印刷用のインキ(フレキソインキ等)を少なくとも含む排水である。
貼合機由来の糊洗浄水とは、段ボール接着用の糊(デンプン等)を少なくとも含む排水である。
In the wastewater treatment system, the two or more types of wastewater are preferably two types of wastewater.
The two or more types of wastewater are preferably wastewater generated in a food factory or a cardboard factory. More preferably, the two types of wastewater are wastewater generated in a cardboard factory. When the two types of wastewater are wastewater generated in a cardboard factory, the wastewater A (the wastewater having the highest absolute value of charge density or the absolute value of charge density exceeding 100 μeq/L) is preferably ink washing water from a box making machine, and the other types of wastewater other than the wastewater A are preferably glue washing water from a laminating machine.
Ink wash water from box making machines is wastewater that contains at least ink (such as flexographic ink) used for printing on corrugated board.
The glue washing water from the laminating machine is wastewater that contains at least glue (starch, etc.) for gluing cardboard.

電荷密度とは、排水中にコロイドとして存在する汚濁物質の表面電荷を中和するのに要するカチオン物質もしくはアニオン物質の排水容積あたりの原単位であり、1Lあたりの電荷のモル等量を1eq/Lとし、以下のように定義されている。
1μeq/L=1μmol/L×電荷数=96.5C/m
排水Aの電荷密度は、好ましくは-10000μeq/L~-100μeq/Lであり、より好ましくは-10000μeq/L以上-100μeq/L未満であり、さらに好ましくは-1000μeq/L~-200μeq/Lであり、さらにより好ましくは-600μeq/L~-300μeq/Lである。2種類以上の排水のうち該排水A以外の排水(排水A以外の排水が複数ある場合はこれらを混合した排水、すなわち、前記他の排水)の電荷密度は、好ましくは-100μeq/L~0μeq/Lであり、より好ましくは-50μeq/L~-5μeq/Lであり、さらに好ましくは-30μeq/L~-10μeq/Lである。
また、排水Aの電荷密度と他の排水の電荷密度との絶対差は、好ましくは300μeq/L~10000μeq/Lであり、より好ましくは350μeq/L~1000μeq/Lであり、さらに好ましくは350μeq/L~500μeq/Lである。
The charge density is the unit of cationic or anionic substance required per volume of wastewater to neutralize the surface charge of pollutants present as colloids in the wastewater, and is defined as follows, with the molar equivalent of charge per 1 L being 1 eq/L:
1 μeq/L = 1 μmol/L × number of charges = 96.5 C/ m3
The charge density of wastewater A is preferably -10000 μeq/L to -100 μeq/L, more preferably -10000 μeq/L or more and less than -100 μeq/L, even more preferably -1000 μeq/L to -200 μeq/L, and even more preferably -600 μeq/L to -300 μeq/L. The charge density of wastewater other than wastewater A among two or more kinds of wastewater (if there are multiple wastewaters other than wastewater A, the wastewaters obtained by mixing these, i.e., the other wastewaters) is preferably -100 μeq/L to 0 μeq/L, more preferably -50 μeq/L to -5 μeq/L, and even more preferably -30 μeq/L to -10 μeq/L.
In addition, the absolute difference between the charge density of wastewater A and the charge density of other wastewater is preferably 300 μeq/L to 10,000 μeq/L, more preferably 350 μeq/L to 1,000 μeq/L, and even more preferably 350 μeq/L to 500 μeq/L.

排水Aの電荷密度の絶対値は、好ましくは100μeq/L以上であり、より好ましくは100μeq/Lを超え、さらに好ましくは100μeq/Lを超え10000μeq/L以下であり、さらにより好ましくは200μeq/L~1000μeq/Lであり、特に好ましくは300μeq/L~600μeq/Lである。他の排水の電荷密度の絶対値は、好ましくは0μeq/L~100μeq/Lであり、より好ましくは5μeq/L~50μeq/Lであり、さらに好ましくは10μeq/L~30μeq/Lである。
本開示における排水処理システム及び排水処理方法は、電荷密度の絶対値が、好ましくは10000μeq/L以下、より好ましくは1000μeq/L以下、さらに好ましくは600μeq/L以下の排水に適用しうる。
The absolute value of the charge density of the wastewater A is preferably 100 μeq/L or more, more preferably more than 100 μeq/L, even more preferably more than 100 μeq/L and not more than 10,000 μeq/L, even more preferably 200 μeq/L to 1,000 μeq/L, and particularly preferably 300 μeq/L to 600 μeq/L. The absolute value of the charge density of the other wastewater is preferably 0 μeq/L to 100 μeq/L, more preferably 5 μeq/L to 50 μeq/L, and even more preferably 10 μeq/L to 30 μeq/L.
The wastewater treatment system and wastewater treatment method disclosed herein can be applied to wastewater having an absolute value of charge density of preferably 10,000 μeq/L or less, more preferably 1,000 μeq/L or less, and even more preferably 600 μeq/L or less.

電荷密度の測定方法
本開示において、複数の排水の電荷密度の絶対値により、排水Aと、排水A以外の他の排水に分類する。複数の排水に対し、電荷密度を測定し、比較する方法は以下の通りである。
複数の排水の中の1種の排水に対し、3時間おきに、0.1Lの排水をサンプリングする。これを4回繰り返してすべてを混合し、複数回の累積サンプル排水を得る。なお、工場等の排水の都合により、排水が3時間おきにサンプリングできない場合、頻度及びサンプリング量を適宜調整する。総サンプルリング回数が4回以上、総サンプルリング体積が0.4L以上となるようにし、排水の水質のばらつきの影響を最小限にする。
複数回の累積サンプル排水に対し、チャージアナライザー(THE RANK BROTHERS CHARGE ANARYZER)等を用いて、電荷密度を測定する。
In the present disclosure, wastewaters are classified into wastewater A and wastewaters other than wastewater A based on the absolute value of the charge density of the wastewaters. The method for measuring and comparing the charge density of the multiple wastewaters is as follows.
For one of the multiple wastewaters, 0.1 L of wastewater is sampled every 3 hours. This is repeated 4 times and all the samples are mixed to obtain multiple cumulative wastewater samples. If it is not possible to sample the wastewater every 3 hours due to the wastewater conditions of the factory, etc., the frequency and sampling amount are adjusted appropriately. The total number of samplings is set to 4 or more, and the total sampling volume is set to 0.4 L or more to minimize the influence of variations in wastewater quality.
The charge density of the accumulated wastewater samples is measured using a charge analyzer (THE RANK BROTHERS CHARGE ANALYZER) or the like.

また、排水A(排水Aが複数ある場合はこれらを混合した排水)の電気伝導度は、好ましくは0μS/cm~5000μS/cmであり、より好ましくは100μS/cm~1000μS/cmである。2種類以上の排水のうち該排水A以外の他の排水(他の排水が複数ある場合はこれらを混合した排水)の電気伝導度は、好ましくは0μS/cm~5000μS/cmであり、より好ましくは100μS/cm~1000μS/cmである。 The electrical conductivity of wastewater A (or a mixture of wastewaters when there are multiple wastewaters A) is preferably 0 μS/cm to 5000 μS/cm, more preferably 100 μS/cm to 1000 μS/cm. The electrical conductivity of the other wastewaters (or a mixture of other wastewaters when there are multiple other wastewaters) other than wastewater A among the two or more types of wastewater is preferably 0 μS/cm to 5000 μS/cm, more preferably 100 μS/cm to 1000 μS/cm.

図2は、排水処理システムの一態様の概略図である。排水処理システム100は、2種類以上の排水の中で最も電荷密度の絶対値が高い排水である排水Aを貯留する貯留槽1、2種類以上の排水のうち該排水A以外の他の排水(排水B)を貯留する他の貯留槽2、貯留槽1から送水された排水A及び他の貯留槽2から送水された他の排水を混合し混合水を得る混和槽3、並びに混和槽3から送水された混合水を凝集沈殿処理する連続式の凝集沈殿処理装置10を備える。
排水Aが複数の場合は、複数の排水Aを貯留槽1に送水して混合し、排水Aとすればよい。他の排水が複数の場合は、複数の他の排水を貯留槽2に送水して混合し、他の排水とすればよい。
2 is a schematic diagram of one embodiment of a wastewater treatment system. The wastewater treatment system 100 includes a storage tank 1 for storing wastewater A, which is wastewater having the highest absolute value of charge density among two or more types of wastewater, another storage tank 2 for storing another type of wastewater (wastewater B) other than the wastewater A among the two or more types of wastewater, a mixing tank 3 for mixing the wastewater A sent from the storage tank 1 with the other wastewater sent from the other storage tank 2 to obtain mixed water, and a continuous coagulation sedimentation treatment device 10 for coagulating and sedimenting the mixed water sent from the mixing tank 3.
When there are multiple wastewaters A, the multiple wastewaters A may be sent to storage tank 1 and mixed to obtain wastewater A. When there are multiple other wastewaters, the multiple other wastewaters may be sent to storage tank 2 and mixed to obtain other wastewater.

排水処理システム100は、排水Aの電気伝導度Aを測定する電気伝導度計EM1及び貯留槽1から混和槽3に送水された排水Aの流量Aを測定する流量計FT1、他の排水の電気伝導度を測定する他の電気伝導度計EM2、並びに混和槽3から送水された混合水の流量を測定する混合水流量計FT2を備える。
また、排水処理システム100は、凝集沈殿処理装置10の反応槽11に凝集剤を添加する凝集剤添加装置5を備える。
The wastewater treatment system 100 includes an electrical conductivity meter EM1 that measures the electrical conductivity A of wastewater A, a flow meter FT1 that measures the flow rate A of wastewater A transported from a storage tank 1 to a mixing tank 3, another electrical conductivity meter EM2 that measures the electrical conductivity of another wastewater, and a mixed water flow meter FT2 that measures the flow rate of mixed water transported from the mixing tank 3.
The wastewater treatment system 100 also includes a flocculant adding device 5 that adds a flocculant to the reaction tank 11 of the coagulation sedimentation treatment device 10 .

排水処理システム100は、予め準備した、排水Aの電気伝導度、他の排水の電気伝導度、混合水の量及び混合水中の排水Aと他の排水との混合割合と、凝集剤添加量と、凝集剤の添加及び沈殿処理後の混合水の汚濁物質の指標と、の関係に基づき、混合水の汚濁物質の指標が予め設定した適正値以下となる適正凝集剤添加量を算出する演算部4を有する。
混合水の量や、排水の混合割合を正確に把握するために、排水処理システム100は、貯留槽2から混和槽3に送水される他の排水の流量を測定する流量計及び/又は混和槽3中の混合水の量を測定する水位計を備えていてもよい。排水処理システム100は、貯留槽2から混和槽3に送水される他の排水の流量を測定する流量計及び/又は混和槽3中の混合水の量を測定する水位計を備えなくてもよい。
The wastewater treatment system 100 has a calculation unit 4 that calculates an appropriate amount of coagulant to be added so that the index of pollutants in the mixed water will be equal to or lower than a predetermined appropriate value, based on the relationship between the electrical conductivity of wastewater A, the electrical conductivity of other wastewaters, the amount of mixed water, and the mixing ratio of wastewater A and other wastewaters in the mixed water, the amount of coagulant to be added, and the index of pollutants in the mixed water after addition of the coagulant and sedimentation treatment, which have been prepared in advance.
In order to accurately grasp the amount of mixed water and the mixing ratio of the wastewater, the wastewater treatment system 100 may be provided with a flow meter that measures the flow rate of other wastewater sent from the storage tank 2 to the mixing tank 3 and/or a water level meter that measures the amount of mixed water in the mixing tank 3. The wastewater treatment system 100 does not necessarily have to be provided with a flow meter that measures the flow rate of other wastewater sent from the storage tank 2 to the mixing tank 3 and/or a water level meter that measures the amount of mixed water in the mixing tank 3.

排水A及び他の排水(排水B)がそれぞれ貯留槽1及び2から、例えばポンプPなどにより混和槽3に供給され混合されて、混合水が得られる。混和槽3には、撹拌装置21が備えられていてもよい。混合水は、例えばポンプPなどにより連続式に凝集沈殿処理装置10の反応槽11に供給される。
排水A及び他の排水の電気伝導度が電気伝導度計EM1及びEM2により測定される。また、排水A及び混合水の流量が、流量計FT1及びFT2により測定される。これらの測定値が演算部4に入力される。
Wastewater A and another wastewater (wastewater B) are supplied from storage tanks 1 and 2, respectively, to a mixing tank 3 by, for example, a pump P, and mixed to obtain mixed water. The mixing tank 3 may be equipped with an agitator 21. The mixed water is continuously supplied to a reaction tank 11 of a coagulation sedimentation treatment device 10 by, for example, a pump P.
The electrical conductivities of wastewater A and the other wastewater are measured by electrical conductivity meters EM1 and EM2. The flow rates of wastewater A and the mixed water are measured by flow meters FT1 and FT2. These measured values are input to the calculation unit 4.

演算部4は、混合水の流量、電気伝導度A、流量A、及び他の排水の電気伝導度から、凝集沈殿処理装置10で処理される混合水について、適正凝集剤添加量を算出する。算出の際、演算部4は必要に応じて、混合水の流量、電気伝導度A、流量A、及び他の排水の電気伝導度から、混合水の量及び混合水中の排水Aと他の排水との混合割合を算出する。凝集剤添加装置は連続式であるため、好ましくは適正凝集剤添加量が単位時間当たりの凝集剤量として算出される。演算部4で算出された適正凝集剤添加量が、凝集剤添加装置5に出力されると、凝集剤添加装置5は適正凝集剤添加量の凝集剤を反応槽11に添加する。 The calculation unit 4 calculates the appropriate amount of flocculant to be added for the mixed water to be treated by the coagulation and sedimentation treatment device 10 from the flow rate, electrical conductivity A, flow rate A, and electrical conductivity of the other wastewater. When calculating, the calculation unit 4 calculates the amount of mixed water and the mixing ratio of wastewater A and other wastewater in the mixed water from the flow rate, electrical conductivity A, flow rate A, and electrical conductivity of the other wastewater, as necessary. Since the flocculant addition device is a continuous type, the appropriate amount of flocculant to be added is preferably calculated as the amount of flocculant per unit time. When the appropriate amount of flocculant to be added calculated by the calculation unit 4 is output to the flocculant addition device 5, the flocculant addition device 5 adds the appropriate amount of flocculant to the reaction tank 11.

凝集沈殿処理装置10においては、公知の方法で凝集沈殿処理を行えばよい。凝集沈殿処理装置10は、反応槽11、凝集槽12及び沈殿槽13を有する。
凝集沈殿処理装置10において、凝集剤添加装置5により、反応槽11中の混合水に凝集剤及び必要に応じてさらにpH調整剤が添加され、混合水中の微細粒子を凝集させる。凝集剤が添加された混合水は、凝集槽12に送られ、凝集槽12で混合水に高分子凝集剤が添加され、微細粒子をフロック化する。高分子凝集剤の添加は、反応槽11での凝集剤の添加と同様に、演算部4及び凝集剤添加装置5により自動制御可能である。
そして、混合水は、沈殿槽13に送られ、沈殿処理に供される。混合水は上澄み液である処理水とフロックを含む汚泥スラリーとに分離される。
A known method may be used for the coagulation and sedimentation treatment in the coagulation and sedimentation treatment device 10. The coagulation and sedimentation treatment device 10 includes a reaction tank 11, a coagulation tank 12, and a sedimentation tank 13.
In the coagulation and sedimentation treatment device 10, a coagulant and, if necessary, a pH adjuster are added to the mixed water in the reaction tank 11 by the coagulant adding device 5, thereby coagulating fine particles in the mixed water. The mixed water to which the coagulant has been added is sent to the coagulation tank 12, where a polymer coagulant is added to the mixed water to flocculate the fine particles. The addition of the polymer coagulant can be automatically controlled by the calculation unit 4 and the coagulant adding device 5, similar to the addition of the coagulant in the reaction tank 11.
The mixed water is then sent to the settling tank 13 for settling treatment. The mixed water is separated into treated water, which is a supernatant liquid, and a sludge slurry containing flocs.

図3は、排水処理システムの他の一態様の概略図である。
排水処理システム100は、排水Aを貯留する貯留槽1、排水A以外の他の排水を貯留する他の貯留槽2、並びに貯留槽1から送水された排水A及び他の貯留槽2から送水された他の排水を混合し、得られた混合水を凝集沈殿処理する回分式の凝集沈殿処理装置30を備える。
排水Aが複数の場合は、複数の排水Aを貯留槽1に送水して混合し、排水Aとすればよい。他の排水が複数の場合は、複数の他の排水を貯留槽2に送水して混合し、他の排水とすればよい。
FIG. 3 is a schematic diagram of another embodiment of a wastewater treatment system.
The wastewater treatment system 100 includes a storage tank 1 for storing wastewater A, another storage tank 2 for storing wastewater other than wastewater A, and a batch-type coagulation and sedimentation treatment device 30 that mixes the wastewater A delivered from the storage tank 1 with the other wastewater delivered from the other storage tank 2 and performs coagulation and sedimentation treatment on the resulting mixed water.
When there are multiple wastewaters A, the multiple wastewaters A may be sent to storage tank 1 and mixed to obtain wastewater A. When there are multiple other wastewaters, the multiple other wastewaters may be sent to storage tank 2 and mixed to obtain other wastewater.

また、排水処理システム100は、排水Aの電気伝導度Aを測定する電気伝導度計EM1及び貯留槽1から凝集沈殿処理装置30に送水された排水Aの流量Aを測定する流量計FT、他の排水の電気伝導度を測定する他の電気伝導度計EM2、並びに凝集沈殿処理装置30に送水された混合水の量及び送水時間を測定する水位計LTを備える。
混合水の量や、排水の混合割合を正確に把握するために、排水処理システム100は、貯留槽2から凝集沈殿処理装置30に送水される他の排水の流量を測定する流量計を備えていてもよい。排水処理システム100は、貯留槽2から凝集沈殿処理装置30に送水される他の排水の流量を測定する流量計を備えなくてもよい。
The wastewater treatment system 100 also includes an electrical conductivity meter EM1 that measures the electrical conductivity A of wastewater A, a flow meter FT that measures the flow rate A of wastewater A transported from the storage tank 1 to the coagulation sedimentation treatment device 30, another electrical conductivity meter EM2 that measures the electrical conductivity of other wastewater, and a water level meter LT that measures the amount of mixed water transported to the coagulation sedimentation treatment device 30 and the transport time.
In order to accurately grasp the amount of mixed water and the mixing ratio of the wastewater, the wastewater treatment system 100 may be provided with a flow meter that measures the flow rate of the other wastewater sent from the storage tank 2 to the coagulation sedimentation treatment device 30. The wastewater treatment system 100 does not need to be provided with a flow meter that measures the flow rate of the other wastewater sent from the storage tank 2 to the coagulation sedimentation treatment device 30.

また、排水処理システム100は、凝集沈殿処理装置30に凝集剤を添加する凝集剤添加装置5を備える。
排水処理システム100は、予め準備した、排水Aの電気伝導度A、他の排水の電気伝導度、混合水の量及び混合水中の排水Aと他の排水との混合割合と、凝集剤添加量と、凝集剤の添加及び沈殿処理後の混合水の汚濁物質の指標と、の関係に基づき、混合水の汚濁
物質の指標が予め設定した適正値以下となる適正凝集剤添加量を算出する演算部4を有する。
The wastewater treatment system 100 also includes a flocculant adding device 5 that adds a flocculant to the coagulation sedimentation treatment device 30 .
The wastewater treatment system 100 has a calculation unit 4 that calculates an appropriate amount of coagulant to be added so that the index of pollutants in the mixed water is below a predetermined appropriate value, based on the relationship between the electrical conductivity A of wastewater A, the electrical conductivity of the other wastewaters, the amount of mixed water and the mixing ratio of wastewater A and the other wastewaters in the mixed water, the amount of coagulant to be added, and the index of pollutants in the mixed water after the addition of the coagulant and precipitation treatment, which have been prepared in advance.

排水A及び他の排水(排水B)がそれぞれ貯留槽1及び2から回分式に、例えばポンプPなどにより凝集沈殿処理装置30に供給される。混合水は、例えば水位計LTの上限まで供給される。
排水A及び他の排水の電気伝導度、排水Aの流量Aが測定され、演算部4に入力される。凝集沈殿処理装置30の水量(水位)及び混合水の送水時間が演算部4に入力される。演算部4は、必要に応じて、電気伝導度A、流量A、他の排水の電気伝導度、並びに混合水の量及び送水時間から、凝集沈殿処理装置30に含まれる混合水について、混合水の量及び混合水中の排水Aと他の排水との混合割合を算出する。
そして、演算部4は、これらの入力値から適正凝集剤添加量を算出する。算出された適正凝集剤添加量が、凝集剤添加装置5に出力されると、凝集剤添加装置5は適正凝集剤添加量の凝集剤を凝集沈殿処理装置30に添加する。
Wastewater A and another wastewater (wastewater B) are supplied batchwise from storage tanks 1 and 2, respectively, to a coagulation sedimentation treatment device 30 by, for example, a pump P. Mixed water is supplied, for example, up to the upper limit of a water level gauge LT.
The electrical conductivity of wastewater A and the other wastewater, and the flow rate A of wastewater A are measured and input to the calculation unit 4. The water volume (water level) of the coagulation sedimentation treatment device 30 and the water supply time of the mixed water are input to the calculation unit 4. The calculation unit 4 calculates, as necessary, the amount of mixed water and the mixing ratio of wastewater A to the other wastewater in the mixed water for the mixed water contained in the coagulation sedimentation treatment device 30 from the electrical conductivity A, the flow rate A, the electrical conductivity of the other wastewater, and the amount and water supply time of the mixed water.
The calculation unit 4 then calculates the appropriate amount of flocculant to be added from these input values. When the calculated appropriate amount of flocculant to be added is output to the flocculant addition device 5, the flocculant addition device 5 adds the appropriate amount of flocculant to the coagulation and sedimentation treatment device 30.

凝集沈殿処理装置30は、回分式の凝集沈殿処理装置である。凝集沈殿処理装置30においては、公知の方法で凝集沈殿処理を行えばよい。
凝集沈殿処理装置30では、まず、凝集剤添加装置5により、凝集剤及び必要に応じてpH調整剤が混合水に添加され、混合水中の微細粒子を凝集させる。凝集沈殿処理装置30には、撹拌装置21が備えられていてもよい。次に、高分子凝集剤を被処理水に添加し、凝集させた微細粒子をフロック化する。高分子凝集剤の添加も、演算部4及び凝集剤添加装置5により自動制御可能である。そして、混合水を所定時間静置し、混合水は上澄み液である処理水とフロックを含む汚泥スラリーとに分離される。
The coagulation and sedimentation treatment device 30 is a batch-type coagulation and sedimentation treatment device. In the coagulation and sedimentation treatment device 30, the coagulation and sedimentation treatment may be performed by a known method.
In the coagulation sedimentation treatment device 30, first, a coagulant and, if necessary, a pH adjuster are added to the mixed water by the coagulant adding device 5 to coagulate fine particles in the mixed water. The coagulation sedimentation treatment device 30 may be equipped with a stirring device 21. Next, a polymer coagulant is added to the water to be treated, and the coagulated fine particles are flocculated. The addition of the polymer coagulant can also be automatically controlled by the calculation unit 4 and the coagulant adding device 5. Then, the mixed water is left to stand for a predetermined time, and the mixed water is separated into treated water, which is a supernatant liquid, and a sludge slurry containing flocs.

図4は、排水処理システムの他の一態様の概略図である。
排水処理システム100は、排水A以外の他の排水を貯留する他の貯留槽2、排水Aが送水されるとともに、他の貯留槽2から他の排水が送水されることで、排水A及び他の排水が混合されて混合水が得られ、該混合水が貯留される混合水貯留槽6、並びに混合水貯留槽6から送水された混合水を凝集沈殿処理する凝集沈殿処理装置10を備える。
排水Aが複数の場合は、複数の排水Aを混合水貯留槽6に送水すればよい。他の排水が複数の場合は、複数の他の排水を貯留槽2に送水して混合し、他の排水とすればよい。
FIG. 4 is a schematic diagram of another embodiment of a wastewater treatment system.
The wastewater treatment system 100 includes another storage tank 2 for storing wastewater other than wastewater A, a mixed water storage tank 6 into which wastewater A is pumped and other wastewater is pumped from the other storage tank 2 to obtain mixed water by mixing the wastewater A and the other wastewater, and a coagulation and sedimentation treatment device 10 for performing coagulation and sedimentation treatment of the mixed water pumped from the mixed water storage tank 6.
When there are multiple wastewaters A, the multiple wastewaters A may be sent to the mixed water storage tank 6. When there are multiple other wastewaters, the multiple other wastewaters may be sent to the storage tank 2 and mixed to produce the other wastewater.

排水処理システム100は、他の排水の電気伝導度を測定する他の電気伝導度計EM2、他の貯留槽2から混合水貯留槽6に送水された他の排水の流量Bを測定する流量計FT2、混合水貯留槽6中の混合水の電気伝導度Cを測定する電気伝導度計EM3、混合水貯留槽6から送水された混合水の流量を測定する混合水流量計FT3を備える。
また、排水処理システム100は、凝集沈殿処理装置10の反応槽11に凝集剤を添加する凝集剤添加装置5を備える。
The wastewater treatment system 100 is equipped with another electrical conductivity meter EM2 that measures the electrical conductivity of the other wastewater, a flow meter FT2 that measures the flow rate B of the other wastewater sent from the other storage tank 2 to the mixed water storage tank 6, an electrical conductivity meter EM3 that measures the electrical conductivity C of the mixed water in the mixed water storage tank 6, and a mixed water flow meter FT3 that measures the flow rate of the mixed water sent from the mixed water storage tank 6.
The wastewater treatment system 100 also includes a flocculant adding device 5 that adds a flocculant to the reaction tank 11 of the coagulation sedimentation treatment device 10 .

排水処理システム100は、予め準備した、排水Aの電気伝導度、他の排水の電気伝導度、混合水の量及び混合水中の排水Aと他の排水との混合割合と、凝集剤添加量と、凝集剤の添加及び沈殿処理後の混合水の汚濁物質の指標と、の関係に基づき、混合水の汚濁物質の指標が予め設定した適正値以下となる適正凝集剤添加量を算出する演算部4を有する。
混合水の量や、排水の混合割合を正確に把握するために、排水処理システム100は、排水Aの流量を測定する流量計及び/又は混合水貯留槽6中の混合水の量を測定する水位計を備えていてもよい。排水処理システム100は、排水Aの流量を測定する流量計及び/又は混合水貯留槽6中の混合水の量を測定する水位計を備えなくてもよい。
The wastewater treatment system 100 has a calculation unit 4 that calculates an appropriate amount of coagulant to be added so that the index of pollutants in the mixed water will be equal to or lower than a predetermined appropriate value, based on the relationship between the electrical conductivity of wastewater A, the electrical conductivity of other wastewaters, the amount of mixed water, and the mixing ratio of wastewater A and other wastewaters in the mixed water, the amount of coagulant to be added, and the index of pollutants in the mixed water after addition of the coagulant and sedimentation treatment, which have been prepared in advance.
In order to accurately grasp the amount of mixed water and the mixing ratio of the wastewater, the wastewater treatment system 100 may be provided with a flow meter that measures the flow rate of the wastewater A and/or a water level meter that measures the amount of mixed water in the mixed water storage tank 6. The wastewater treatment system 100 does not necessarily have to be provided with a flow meter that measures the flow rate of the wastewater A and/or a water level meter that measures the amount of mixed water in the mixed water storage tank 6.

他の排水(排水B)が他の貯留槽2から、例えばポンプPなどにより排水Aとともに混
合水貯留槽6に供給され、混合されて、混合水が得られる。混合水貯留槽6には、撹拌装置21が備えられていてもよい。混合水は、例えばポンプPなどにより連続式に凝集沈殿処理装置10の反応槽11に供給される。
Another wastewater (wastewater B) is supplied from another storage tank 2 to the mixed water storage tank 6 together with the wastewater A by, for example, a pump P, and mixed to obtain mixed water. The mixed water storage tank 6 may be equipped with an agitator 21. The mixed water is continuously supplied to the reaction tank 11 of the coagulation sedimentation treatment device 10 by, for example, a pump P.

他の排水の電気伝導度、混合水の電気伝導度C、他の排水の流量B及び混合水の流量が測定され、これらの測定値が演算部4に入力される。演算部4は、必要に応じて、他の排水の電気伝導度、流量B、電気伝導度C及び混合水の流量から、凝集沈殿処理装置10に含まれる混合水について、排水Aの電気伝導度A並びに混合水の量及び混合水中の排水Aと他の排水との混合割合を算出する。
そして、演算部4は、これらの入力値から適正凝集剤添加量を算出する。算出された適正凝集剤添加量が、凝集剤添加装置5に出力されると、凝集剤添加装置5は適正凝集剤添加量の凝集剤を凝集沈殿処理装置10の反応槽11に添加する。
凝集沈殿処理装置10については、図2と同様である。
The electrical conductivity of the other wastewater, the electrical conductivity C of the mixed water, the flow rate B of the other wastewater, and the flow rate of the mixed water are measured, and these measured values are input to the calculation unit 4. The calculation unit 4 calculates, as necessary, the electrical conductivity A of wastewater A, the amount of the mixed water, and the mixing ratio of wastewater A to the other wastewater in the mixed water, for the mixed water contained in the coagulation and sedimentation treatment device 10, from the electrical conductivity, flow rate B, electrical conductivity C of the other wastewater, and the flow rate of the mixed water.
The calculation unit 4 then calculates the appropriate amount of flocculant to be added from these input values. When the calculated appropriate amount of flocculant to be added is output to the flocculant addition device 5, the flocculant addition device 5 adds the appropriate amount of flocculant to the reaction tank 11 of the coagulation and sedimentation treatment device 10.
The coagulation and sedimentation treatment device 10 is the same as that shown in FIG.

図5は、排水処理システムの他の一態様の概略図である。
排水処理システム100は、排水A以外の他の排水を貯留する他の貯留槽2、排水Aが送水されるとともに、他の貯留槽2から他の排水が送水されることで、排水A及び他の排水が混合されて混合水が得られ、該混合水が貯留される混合水貯留槽6、並びに混合水貯留槽6から送水された混合水を凝集沈殿処理する回分式の凝集沈殿処理装置30を備える。
排水Aが複数の場合は、複数の排水Aを混合水貯留槽6に送水すればよい。他の排水が複数の場合は、複数の他の排水を貯留槽2に送水して混合し、他の排水とすればよい。
FIG. 5 is a schematic diagram of another embodiment of a wastewater treatment system.
The wastewater treatment system 100 includes another storage tank 2 for storing wastewater other than wastewater A, a mixed water storage tank 6 into which wastewater A is pumped and the other wastewater is pumped from the other storage tank 2 to obtain mixed water, and in which the mixed water is stored, and a batch-type coagulation and sedimentation treatment device 30 for coagulating and sedimenting the mixed water pumped from the mixed water storage tank 6.
When there are multiple wastewaters A, the multiple wastewaters A may be sent to the mixed water storage tank 6. When there are multiple other wastewaters, the multiple other wastewaters may be sent to the storage tank 2 and mixed to produce the other wastewater.

排水処理システム100は、他の排水の電気伝導度を測定する他の電気伝導度計EM2、他の貯留槽2から混合水貯留槽6に送水された他の排水の流量Bを測定する流量計FT2、混合水貯留槽6中の混合水の電気伝導度Cを測定する電気伝導度計EM3、混合水貯留槽6から凝集沈殿処理装置30に送水された混合水の流量を測定する混合水流量計FT3を備える。
また、排水処理システム100は、凝集沈殿処理装置30に凝集剤を添加する凝集剤添加装置5を備える。
The wastewater treatment system 100 is equipped with another electrical conductivity meter EM2 that measures the electrical conductivity of the other wastewater, a flow meter FT2 that measures the flow rate B of the other wastewater sent from the other storage tank 2 to the mixed water storage tank 6, an electrical conductivity meter EM3 that measures the electrical conductivity C of the mixed water in the mixed water storage tank 6, and a mixed water flow meter FT3 that measures the flow rate of the mixed water sent from the mixed water storage tank 6 to the coagulation sedimentation treatment device 30.
The wastewater treatment system 100 also includes a flocculant adding device 5 that adds a flocculant to the coagulation sedimentation treatment device 30 .

排水処理システム100は、予め準備した、排水Aの電気伝導度A、他の排水の電気伝導度、混合水の量及び混合水中の排水Aと他の排水との混合割合と、凝集剤添加量と、凝集剤の添加及び沈殿処理後の混合水の汚濁物質の指標と、の関係に基づき、混合水の汚濁物質の指標が予め設定した適正値以下となる適正凝集剤添加量を算出する演算部4を有する。
混合水の量や、排水の混合割合を正確に把握するために、排水処理システム100は、排水Aの流量を測定する流量計、混合水貯留槽6中の混合水の量を測定する水位計並びに/又は凝集沈殿処理装置30中の混合水の量及び混合水の送水時間を測定する水位計LTを備えていてもよい。排水処理システム100は、排水Aの流量を測定する流量計、混合水貯留槽6中の混合水の量を測定する水位計並びに/又は凝集沈殿処理装置30中の混合水の量及び混合水の送水時間を測定する水位計LTを備えなくてもよい。
The wastewater treatment system 100 has a calculation unit 4 that calculates an appropriate amount of coagulant to be added so that the index of pollutants in the mixed water is below a predetermined appropriate value, based on the relationship between the electrical conductivity A of wastewater A, the electrical conductivity of the other wastewaters, the amount of mixed water and the mixing ratio of wastewater A and the other wastewaters in the mixed water, the amount of coagulant to be added, and the index of pollutants in the mixed water after the addition of the coagulant and precipitation treatment, which have been prepared in advance.
In order to accurately grasp the amount of mixed water and the mixing ratio of the wastewater, the wastewater treatment system 100 may be provided with a flow meter that measures the flow rate of wastewater A, a water level gauge that measures the amount of mixed water in the mixed water storage tank 6, and/or a water level gauge LT that measures the amount of mixed water and the water transport time of the mixed water in the coagulation sedimentation treatment device 30. The wastewater treatment system 100 does not have to be provided with a flow meter that measures the flow rate of wastewater A, a water level gauge that measures the amount of mixed water in the mixed water storage tank 6, and/or a water level gauge LT that measures the amount of mixed water and the water transport time of the mixed water in the coagulation sedimentation treatment device 30.

他の排水(排水B)が他の貯留槽2から、例えばポンプPなどにより排水Aとともに混合水貯留槽6に供給され、混合されて、混合水が得られる。混合水貯留槽6には、撹拌装置21が備えられていてもよい。混合水は、例えばポンプPなどにより回分式に凝集沈殿処理装置30に供給される。混合水は、例えば水位計LTの上限まで供給される。 Another wastewater (wastewater B) is supplied from another storage tank 2 to the mixed water storage tank 6 together with wastewater A by, for example, a pump P, and mixed to obtain mixed water. The mixed water storage tank 6 may be equipped with an agitator 21. The mixed water is supplied to the coagulation and sedimentation treatment device 30 in batches by, for example, a pump P. The mixed water is supplied, for example, up to the upper limit of the water level gauge LT.

他の排水の電気伝導度、混合水の電気伝導度、他の排水の流量B及び混合水の流量が測定される。また、凝集沈殿処理装置30に混合水が供給された送水時間の積算測定値が演
算部4に入力される。演算部4は、必要に応じて、他の排水の電気伝導度、流量B、電気伝導度C及び混合水の流量から、凝集沈殿処理装置30に含まれる混合水について、排水Aの電気伝導度A並びに混合水の量及び混合水中の排水Aと他の排水との混合割合を算出する。
そして、演算部4は、これらの入力値から適正凝集剤添加量を算出する。算出された適正凝集剤添加量が、凝集剤添加装置5に出力されると、凝集剤添加装置5は適正凝集剤添加量の凝集剤を凝集沈殿処理装置30に添加する。
凝集沈殿処理装置30については、図3と同様である。
The electrical conductivity of the other wastewater, the electrical conductivity of the mixed water, the flow rate B of the other wastewater, and the flow rate of the mixed water are measured. In addition, an integrated measurement value of the water supply time during which the mixed water is supplied to the coagulation sedimentation treatment device 30 is input to the calculation unit 4. The calculation unit 4 calculates, as necessary, the electrical conductivity A of wastewater A, the amount of the mixed water, and the mixing ratio of wastewater A to the other wastewater in the mixed water for the mixed water contained in the coagulation sedimentation treatment device 30 from the electrical conductivity, flow rate B, electrical conductivity C of the other wastewater, and the flow rate of the mixed water.
The calculation unit 4 then calculates the appropriate amount of flocculant to be added from these input values. When the calculated appropriate amount of flocculant to be added is output to the flocculant addition device 5, the flocculant addition device 5 adds the appropriate amount of flocculant to the coagulation and sedimentation treatment device 30.
The coagulation and sedimentation treatment device 30 is the same as that shown in FIG.

排水Aの電気伝導度、他の排水の電気伝導度、混合水の量及び混合水中の排水Aと該他の排水との混合割合と、凝集剤添加量と、該凝集剤の添加及び沈殿処理後の該混合水の汚濁物質の指標と、の関係は、例えば、下記関係式(1)で表すこともできる。そして、演算部4が、下記関係式(1)により適正凝集剤添加量を算出することが好ましい。
F=αEA×VA+βEB(VC-VA) ・・・(1)
(式(1)中、F(L/h)は適正凝集剤添加量である。EA(μS/cm)は排水Aの電気伝導度であり、VA(m/h)は排水Aの流量Aである。EB(μS/cm)は他の排水の電気伝導度であり、VC(m/h)は混合水の流量である。
α及びβは係数(cm/μS・L/m)であり、αは1.0×10-3~1.0×10-2の値を示し、βは1.0×10-4~1.0×10-3(好ましくは3.0×10-4~7.0×10-4)の値を示す。)
The relationship between the electrical conductivity of wastewater A, the electrical conductivity of the other wastewater, the amount of mixed water and the mixing ratio of wastewater A and the other wastewater in the mixed water, the amount of flocculant to be added, and the index of the pollutants in the mixed water after the addition of the flocculant and the precipitation treatment can be expressed, for example, by the following relational formula (1). It is preferable that the calculation unit 4 calculates the appropriate amount of flocculant to be added by the following relational formula (1).
F = αEA × VA + βEB (VC - VA) ... (1)
(In formula (1), F (L/h) is the appropriate amount of flocculant to be added, EA (μS/cm) is the electrical conductivity of wastewater A, VA (m 3 /h) is the flow rate A of wastewater A, EB (μS/cm) is the electrical conductivity of the other wastewater, and VC (m 3 /h) is the flow rate of mixed water.
α and β are coefficients (cm/μS·L/m 3 ), α is a value of 1.0×10 −3 to 1.0×10 −2 , and β is a value of 1.0×10 −4 to 1.0×10 −3 (preferably 3.0×10 −4 to 7.0×10 −4 ).

排水処理システムにおける、各種測定装置においては、上記EA、VA、EB及びVCを直接得られない場合もあるが、その場合は、前述した関係式(A)及び(B)並びに混合水の体積、流量及び送水時間に基づいて、EA、VA、EB及びVCを算出すればよい。
例えば、混合水の流量をVC(m/h)とし、混合水の電気伝導度をEC(μS/cm)とし、他の排水の電気伝導度をEB(μS/cm)とし、流量BをVB(m/h)としたとき、前述の関係式(A)に基づくと、式(1)は、下記式(2)とすることもできる。
F=α(EC×VC-EB×VB)+βEB×VB ・・・(2)
(式(2)中、α及びβは係数(cm/μS・L/m)であり、αは1.0×10-3~1.0×10-2の値を示し、βは1.0×10-4~1.0×10-3(好ましくは3.0×10-4~7.0×10-4)の値を示す。)
In the various measuring devices in a wastewater treatment system, it may not be possible to directly obtain the above EA, VA, EB, and VC. In such cases, EA, VA, EB, and VC may be calculated based on the above-mentioned relational expressions (A) and (B) and the volume, flow rate, and water supply time of the mixed water.
For example, when the flow rate of the mixed water is VC ( m3 /h), the electrical conductivity of the mixed water is EC (μS/cm), the electrical conductivity of the other wastewater is EB (μS/cm), and the flow rate B is VB ( m3 /h), based on the above-mentioned relational formula (A), formula (1) can also be expressed as the following formula (2).
F = α (EC × VC - EB × VB) + βEB × VB ... (2)
(In formula (2), α and β are coefficients (cm/μS·L/m 3 ), α is a value of 1.0×10 −3 to 1.0×10 −2 , and β is a value of 1.0×10 −4 to 1.0×10 −3 (preferably 3.0×10 −4 to 7.0×10 −4 ).)

凝集剤添加量Fの単位は、用いる凝集剤の種類、形態、濃度などに応じて適宜選択すればよい。凝集剤添加量Fは、L/hで表したが、例えば、凝集剤が粉体などの場合はg/hとすればよい。
凝集沈殿処理が回分式の場合は、前述の通り、排水の流量に基づいて、単位時間当たりの適正凝集剤添加量を算出し、回分式の凝集沈殿槽への排水の流入時間に応じた量の凝集剤を添加すればよい。また、回分式の場合、各流量を、水量(体積)として計算してもよい。その場合、VA(m/h)を排水Aの量VA(m)とし、VC(m/h)を混合水の量VC(m)として、適正凝集剤添加量F(L又はg)を式(1)から算出できる。
The unit of the flocculant addition amount F may be appropriately selected depending on the type, form, concentration, etc. of the flocculant used. Although the flocculant addition amount F is expressed in L/h, for example, when the flocculant is a powder, it may be expressed in g/h.
When the coagulation and sedimentation treatment is a batch type, as described above, the appropriate amount of coagulant to be added per unit time is calculated based on the flow rate of the wastewater, and the amount of coagulant corresponding to the inflow time of the wastewater into the batch type coagulation and sedimentation tank is added. In addition, in the case of a batch type, each flow rate may be calculated as a water amount (volume). In that case, the appropriate amount of coagulant to be added F (L or g) can be calculated from formula (1) by assuming that VA (m 3 /h) is the amount VA (m 3 ) of wastewater A and VC (m 3 /h) is the amount VC (m 3 ) of mixed water.

係数α及びβは、凝集剤の添加量を決めるための排水の電気伝導度及び電荷密度に関係する係数である。前述した、排水Aの電気伝導度、他の排水の電気伝導度、混合水の量及び混合水中の排水Aと他の排水との混合割合と、凝集剤添加量と、該凝集剤の添加及び沈殿処理後の該混合水の汚濁物質の指標と、の関係を取得する手段と同様にして、それぞれの排水の電気伝導度と適正な凝集剤添加量との検量関係から、α及びβを得ることができる。
なお、係数α及びβは、凝集剤の種類、形態、濃度などに応じて検量関係の測定値によりにより変動しうる。凝集剤がアルミ系の凝集剤の場合はアルミナ換算の凝集剤添加量により、係数α及びβを算出することができる。
式(1)において、αEA×VAは、混合水中の排水Aに対する凝集剤の添加量に相当する。また、βEB(VC-VA)は、混合水中の排水Bに対する凝集剤の添加量に相当する。排水の電気伝導度及び電荷密度が大きいほど、α及びβは大きくなる。
The coefficients α and β are coefficients related to the electrical conductivity and charge density of the wastewater to determine the amount of flocculant to be added. In the same manner as the above-mentioned means for obtaining the relationship between the electrical conductivity of wastewater A, the electrical conductivity of other wastewaters, the amount of mixed water, the mixing ratio of wastewater A and other wastewaters in the mixed water, the amount of flocculant to be added, and the indicator of the pollutants in the mixed water after the addition of the flocculant and the precipitation treatment, α and β can be obtained from the calibration relationship between the electrical conductivity of each wastewater and the appropriate amount of flocculant to be added.
The coefficients α and β may vary depending on the measured values of the calibration relationship depending on the type, form, concentration, etc. of the flocculant. When the flocculant is an aluminum-based flocculant, the coefficients α and β can be calculated from the amount of flocculant added converted to alumina.
In formula (1), αEA×VA corresponds to the amount of flocculant added to wastewater A in the mixed water. Also, βEB(VC-VA) corresponds to the amount of flocculant added to wastewater B in the mixed water. The higher the electrical conductivity and charge density of the wastewater, the larger α and β become.

排水処理システムは、凝集沈殿処理装置の処理水を生物学的に処理する生物反応槽を備えていてもよい。生物反応槽は、特に制限されず、公知の生物反応槽を採用しうる。生物処理槽では、生物学的処理(生物処理)が行われる。
生物学的処理は、浮遊汚泥を用いる活性汚泥処理装置と汚泥を担体に担持させる生物膜処理装置に大別され、排水処理システムにおいてはどちらの装置も適用可能である。
The wastewater treatment system may include a biological reactor that biologically treats the treated water from the coagulation sedimentation treatment device. The biological reactor is not particularly limited, and a known biological reactor may be used. In the biological treatment tank, biological treatment (biological treatment) is carried out.
Biological treatment is roughly divided into activated sludge treatment apparatuses that use suspended sludge and biofilm treatment apparatuses that support sludge on a carrier, and either type of apparatus can be applied to wastewater treatment systems.

活性汚泥処理装置では、曝気槽及び汚泥返送用の沈殿槽を備えた標準活性汚泥処理装置、一つの槽で曝気と沈殿を交互に行う回分式活性汚泥処理装置、並びに曝気槽内に浸漬させた分離膜で汚泥と処理水を分離する膜分離活性汚泥処理装置(MBR装置)が好ましい。
より好ましくは膜分離活性汚泥処理装置(MBR装置)である。上記排水処理システムでは、凝集剤添加量の変動が起きやすい場合でも、濁度など汚濁物質の指標を良好に低減させる凝集剤添加量を容易に算出できる。そのため、凝集沈殿処理装置の後に膜分離活性汚泥処理装置を設けても、膜の閉塞を防ぎやすくなる。
Preferred activated sludge treatment devices are standard activated sludge treatment devices equipped with an aeration tank and a settling tank for returning sludge, batch-type activated sludge treatment devices which alternate between aeration and settling in one tank, and membrane separation activated sludge treatment devices (MBR devices) which separate sludge from treated water using a separation membrane immersed in the aeration tank.
More preferably, it is a membrane separation activated sludge treatment device (MBR device). In the above wastewater treatment system, even if the amount of coagulant added is likely to fluctuate, it is easy to calculate the amount of coagulant added that satisfactorily reduces indicators of pollutants such as turbidity. Therefore, even if a membrane separation activated sludge treatment device is provided after the coagulation sedimentation treatment device, it is easy to prevent membrane clogging.

以下、実施例により本発明を具体的に説明する。以下の実施例は、本発明を何ら限定するものではない。 The present invention will be specifically explained below with reference to examples. The following examples are not intended to limit the present invention in any way.

以下の実施例において、排水Aの電気伝導度AをEA(μS/cm)とし、排水Aの流量AをVA(m/h)とし、排水Bの電気伝導度をEB(μS/cm)とし、排水Bの流量BをVB(m/h)とし、混合水の電気伝導度をEC(μS/cm)とし、混合水の流量をVC(m/h)とする。
以下の実施例において、濁度は、透過光法により測定した。
In the following examples, the electrical conductivity A of wastewater A is EA (μS/cm), the flow rate A of wastewater A is VA (m 3 /h), the electrical conductivity of wastewater B is EB (μS/cm), the flow rate B of wastewater B is VB (m 3 /h), the electrical conductivity of the mixed water is EC (μS/cm), and the flow rate of the mixed water is VC (m 3 /h).
In the following examples, turbidity was measured by a transmitted light method.

(実施例1)
図2に示す態様の排水処理システムを使用して、以下の通り排水処理を行った。
排水Aとしてインキ洗浄排水、排水Bとして糊洗浄排水、凝集剤として金属系無機凝集剤の硫酸バンド(硫酸アルミニウム濃度8質量%(硫酸アルミニウム・旭洋(株)))を使用した。全排水量VC(=VA+VB)が1.00m/hのときの、排水Aの電気伝導度EA及び流量VA、排水Bの電気伝導度EB、並びに混和槽出口の混合水の流量VCを測定した。
なお、排水Aは電荷密度-437μeq/Lであり、排水Bは電荷密度-17μeq/Lであった。
下記式(X)において、処理水の濁度が15度以下となる適正凝集剤添加量F(L/h)を求めるための係数αを検討したところ、表1の通りになった。また、同様に係数βを検討したところ、β=5.0×10-4となった。
F=α・EA・VA + β・EB・(VC-VA) …(X)
1.0×10-3≦α≦1.0×10-2
Example 1
Using the wastewater treatment system of the embodiment shown in FIG. 2, wastewater treatment was carried out as follows.
Ink washing wastewater was used as wastewater A, glue washing wastewater was used as wastewater B, and a metallic inorganic flocculant, aluminum sulfate (aluminum sulfate concentration 8 mass% (aluminum sulfate, Kyokuyo Co., Ltd.)), was used as the flocculant. The electrical conductivity EA and flow rate VA of wastewater A, the electrical conductivity EB of wastewater B, and the flow rate VC of mixed water at the mixing tank outlet were measured when the total wastewater volume VC (= VA + VB) was 1.00 m3 /h.
The charge density of wastewater A was −437 μeq/L, and the charge density of wastewater B was −17 μeq/L.
In the following formula (X), the coefficient α for determining the appropriate flocculant addition amount F (L/h) for making the turbidity of the treated water 15 degrees or less was examined, and the result is shown in Table 1. Similarly, the coefficient β was examined, and the result was β = 5.0 × 10-4 .
F = α EA VA + β EB (VC-VA) ... (X)
1.0× 10-3 ≦α≦1.0× 10-2

Figure 0007484705000001

上記表は、EA・VAの各範囲に対応した、係数αの値を示す。
Figure 0007484705000001

The above table shows the value of the coefficient α corresponding to each range of EA and VA.

図2に示す排水処理システムを用いて、EA=364μS/cm、VA=0.67m/h、EB=321μS/cm、VC=1.00m/hのとき、式(X)及び表1に基づいて硫酸バンドの最適な添加量を求めたところ、1.03L/hであった。当該添加量で排水処理を行ったところ、処理水の濁度が11度となり、基準を満たし、凝集剤添加量は過剰ではなかった。 Using the wastewater treatment system shown in Figure 2, when EA = 364 µS/cm, VA = 0.67 m 3 /h, EB = 321 µS/cm, and VC = 1.00 m 3 /h, the optimal amount of aluminum sulfate to be added was determined to be 1.03 L/h based on formula (X) and Table 1. When wastewater treatment was performed with this amount to be added, the turbidity of the treated water was 11 degrees, which satisfied the standard, and the amount of flocculant to be added was not excessive.

(比較例1)
図2に示す排水処理システムにおいて、実施例1と同様の排水を用いて排水処理を行った。混和槽中の混合水の電気伝導度EC及び混和槽出口の混合水の流量VCを測定したところ、EC=370μS/cm、VC=1.00m/hであった。
EC=EA、VC=VAとして、実施例1と同様に式(X)及び表1に基づいて硫酸バンドの最適な添加量を求めたところ、2.22L/hであった。当該添加量で排水処理を行ったところ、処理水濁度が5度となり、基準を満たしたが、実施例1と比べて、必要添加量が多くなり、過剰量であった。
(Comparative Example 1)
In the wastewater treatment system shown in Fig. 2, wastewater treatment was carried out using the same wastewater as in Example 1. The electrical conductivity EC of the mixed water in the mixing tank and the flow rate VC of the mixed water at the outlet of the mixing tank were measured, and EC was 370 µS/cm and VC was 1.00 m 3 /h.
The optimum amount of aluminum sulfate added was determined based on formula (X) and Table 1 in the same manner as in Example 1, assuming EC=EA and VC=VA, and was found to be 2.22 L/h. When wastewater treatment was performed with this amount added, the turbidity of the treated water reached 5 degrees, which met the standard, but the necessary amount was greater than in Example 1 and was an excessive amount.

(参考例1)
図2に示す排水処理システムを用いて、式(X)のαを5.0×10-4(表1のαの範囲外)とする以外は実施例1と同様に硫酸バンドの最適な添加量を求めたところ、0.17L/hであった。当該添加量で排水処理を行ったところ処理水濁度が60度となり、基準を満さなかった。
(Reference Example 1)
2, the optimum amount of aluminum sulfate added was determined in the same manner as in Example 1, except that α in formula (X) was set to 5.0×10 −4 (outside the range of α in Table 1), and was found to be 0.17 L/h. When wastewater treatment was performed with this amount added, the turbidity of the treated water was 60 degrees, which did not satisfy the standard.

(参考例2)
図2に示す排水処理システムを用いて、式(X)のαを2.0×10-2(表1のαの範囲外)とする以外は実施例1と同様に硫酸バンドの最適な添加量を求めたところ、4.93L/hであった。当該添加量で排水処理を行ったところ処理水濁度が3.6度となり、基準を満たしたが、実施例1と比べて、必要添加量が多くなり、過剰量であった。
(Reference Example 2)
2, the optimum amount of aluminum sulfate to be added was determined in the same manner as in Example 1, except that α in formula (X) was set to 2.0×10 -2 (outside the range of α in Table 1), and was found to be 4.93 L/h. When wastewater treatment was performed with this amount to be added, the turbidity of the treated water was 3.6 degrees, which satisfied the standard, but the amount required to be added was greater than that in Example 1, being an excessive amount.

実施例1において、排水AのEA・VAと排水BのEB・(VC-VA)を用いることで、比較例1のように混合水CのEC・VCを用いるときと比べて凝集剤の必要添加量が少なくなるという結果であった。 In Example 1, by using EA and VA from wastewater A and EB and (VC-VA) from wastewater B, the amount of flocculant required to be added was less than when EC and VC from mixed water C were used as in Comparative Example 1.

混合水の電気伝導度及び流量のみに基づいて凝集剤添加量を決定すると、凝集剤添加量が過剰量になる。一方、排水Aの電気伝導度及び流量、並びに混合水の電気伝導度及び流量を測定し、これらを指示値に凝集剤添加量を決定することで、最適な凝集剤添加量を求められた。 If the amount of flocculant to be added were determined based solely on the electrical conductivity and flow rate of the mixed water, an excessive amount of flocculant would be added. On the other hand, by measuring the electrical conductivity and flow rate of wastewater A, as well as the electrical conductivity and flow rate of the mixed water, and using these as the indicated values to determine the amount of flocculant to be added, the optimal amount of flocculant to be added was obtained.

(実施例2)
図4に示す排水処理システムを用いて、実施例1と同様の排水の処理を行った。EC=370μS/cm、VC=1.00m/h、EB=321μS/cm、VB=0.33
/hであった。実施例1と同様に表1、式(X)及び下記式(Y)に基づいて硫酸バンドの最適な添加量を求めたところ、1.11L/hとなった。当該添加量で排水処理を行ったところ処理水濁度が11度となり、基準を満たし、凝集剤添加量は過剰ではなかった。
EA・VA=EC・VC-EB・VB …(Y)
Example 2
Using the wastewater treatment system shown in Fig. 4, wastewater was treated in the same manner as in Example 1. EC = 370 µS/cm, VC = 1.00 m 3 /h, EB = 321 µS/cm, VB = 0.33
m3 /h. The optimum amount of aluminum sulfate added was calculated based on Table 1, formula (X) and the following formula (Y) in the same manner as in Example 1, and was found to be 1.11 L/h. When wastewater treatment was performed with this amount added, the turbidity of the treated water was 11 degrees, which satisfied the standard, and the amount of flocculant added was not excessive.
EA·VA=EC·VC-EB·VB ... (Y)

(比較例2)
図4に示す排水処理システムにおいて、実施例1と同様の排水を用いて排水処理を行った。混合水貯留槽6の出口の電気伝導度と流量を測定したところ、EC=370μS/cm、VC=1.00m/hであった。
EC=EA、VC=VAとして、実施例2と同様に表1及び式(X)に基づいて硫酸バンドの最適な添加量を求めたところ、2.22L/hであった。当該添加量で排水処理を行ったところ処理水濁度が5度となり、基準を満たしたが、実施例2と比べて、必要添加量が多くなり、過剰量であった。
(Comparative Example 2)
4, wastewater treatment was carried out using the same wastewater as in Example 1. The electrical conductivity and flow rate at the outlet of the mixed water storage tank 6 were measured, and the results were EC = 370 μS/cm and VC = 1.00 m 3 /h.
The optimum amount of aluminum sulfate added was determined based on Table 1 and formula (X) in the same manner as in Example 2, assuming EC=EA and VC=VA, and was found to be 2.22 L/h. When wastewater treatment was performed with this amount added, the turbidity of the treated water reached 5 degrees, which met the standard, but the amount required to be added was greater than in Example 2, being an excessive amount.

(参考例3)
図4に示す排水処理システムを用いて、式(X)のαを5.0×10-4(表1のαの範囲外)とする以外は実施例2と同様に硫酸バンドの最適な添加量を求めたところ、0.19L/hであった。当該添加量で排水処理を行ったところ処理水濁度が60度となり、基準を満さなかった。
(Reference Example 3)
4, the optimum amount of aluminum sulfate added was determined in the same manner as in Example 2, except that α in formula (X) was set to 5.0×10 −4 (outside the range of α in Table 1), and the result was 0.19 L/h. When wastewater treatment was performed with this amount added, the turbidity of the treated water was 60 degrees, which did not satisfy the standard.

(比較例3)
図4に示す排水処理システムを用いて、式(X)のαを2.0×10-2(表1のαの範囲外)とする以外は実施例2と同様に硫酸バンドの最適な添加量を求めたところ、5.33L/hであった。当該添加量で排水処理を行ったところ処理水濁度が3.6度となり、基準を満たしたが、実施例2と比べて、必要添加量が多くなり、過剰量であった。
(Comparative Example 3)
4, the optimum amount of aluminum sulfate to be added was determined in the same manner as in Example 2, except that α in formula (X) was set to 2.0×10 -2 (outside the range of α in Table 1), and was found to be 5.33 L/h. When wastewater treatment was performed with this amount to be added, the turbidity of the treated water was 3.6 degrees, which satisfied the standard, but the amount required to be added was greater than that in Example 2, being an excessive amount.

実施例2において、混合水CのEC及びVC、並びに排水BのEB及びVBを用いることで、比較例2における、混合水CのEC及びVCのみを用いるときと比べて、凝集剤の必要添加量が少なくなるという結果であった。 In Example 2, by using EC and VC from mixed water C and EB and VB from wastewater B, the amount of flocculant required to be added was less than that required in Comparative Example 2, when only EC and VC from mixed water C was used.

混合水の電気伝導度及び流量のみに基づいて凝集剤添加量を決定すると、凝集剤添加量が過剰量になる。一方、排水Bの電気伝導度及び流量、並びに混合水の電気伝導度及び流量を測定し、これらを指示値に凝集剤添加量を決定することで、最適な凝集剤添加量が求められた。 If the amount of flocculant to be added were determined based solely on the electrical conductivity and flow rate of the mixed water, an excessive amount of flocculant would be added. On the other hand, by measuring the electrical conductivity and flow rate of wastewater B, as well as the electrical conductivity and flow rate of the mixed water, and using these as the indicated values to determine the amount of flocculant to be added, the optimal amount of flocculant to be added was obtained.

100:排水処理システムは、1:貯留槽、2:他の貯留槽、3:混和槽、4:演算部、5:凝集剤添加装置、6:混合水貯留槽、10:連続式の凝集沈殿処理装置、11:反応槽、12:凝集槽、13:沈殿槽、21:撹拌装置、30:回分式の凝集沈殿処理装置
100: wastewater treatment system, 1: storage tank, 2: other storage tank, 3: mixing tank, 4: calculation unit, 5: flocculant addition device, 6: mixed water storage tank, 10: continuous type coagulation sedimentation treatment device, 11: reaction tank, 12: coagulation tank, 13: sedimentation tank, 21: agitation device, 30: batch type coagulation sedimentation treatment device

Claims (15)

2種類以上の排水を混合して凝集沈殿処理する排水処理システムであって、
該2種類以上の排水の中で最も電荷密度の絶対値が高い排水を排水Aとし、
該2種類以上の排水のうち該排水A以外の排水を他の排水としたとき、
該排水処理システムは、混合水を凝集沈殿処理するものであり、該混合水は該排水Aと該他の排水とを混合して得られたものであり、
該排水処理システムは、
該排水Aの電気伝導度、該他の排水の電気伝導度及び該混合水の電気伝導度のうちの少なくとも二つの電気伝導度を測定する電気伝導度計、
該排水Aの量、該他の排水の量及び該混合水の量のうちの少なくとも二つの水量を測定する水量測定装置、
該混合水を凝集沈殿処理する凝集沈殿処理装置、並びに
該凝集沈殿処理装置に凝集剤を添加する凝集剤添加装置を備え、
該排水処理システムは、該少なくとも二つの電気伝導度及び該少なくとも二つの水量から、
予め準備した、該排水Aの電気伝導度、該他の排水の電気伝導度、該混合水の量及び該混合水中の該排水Aと該他の排水との混合割合と、
凝集剤添加量と、
該凝集剤の添加及び沈殿処理後の該混合水の汚濁物質の指標と、の関係に基づき、
該混合水の汚濁物質の指標が予め設定した適正値以下となる適正凝集剤添加量を算出する演算部を有し、
該関係が、
該排水Aに対する適正な凝集剤添加量と、該他の排水に対する適正な凝集剤添加量とを予め凝集試験によって求めておき、
該排水A及び該他の排水について、凝集剤添加量と、凝集剤を添加し沈殿処理を行った後の汚濁物質の指標と、の検量関係を取得したときの、
該検量関係から得られる、該排水Aの電気伝導度、該他の排水の電気伝導度、該混合水の量及び該混合水中の各排水の混合割合と、凝集剤添加量との関係であり、
該凝集沈殿処理において、該算出された該適正凝集剤添加量で、該凝集剤添加装置により該凝集沈殿処理装置に該凝集剤を添加することを特徴とする排水処理システム。
A wastewater treatment system that mixes two or more types of wastewater and performs coagulation and sedimentation treatment,
The wastewater having the highest absolute value of the charge density among the two or more types of wastewater is designated as wastewater A;
When the wastewater other than the wastewater A among the two or more types of wastewater is regarded as the other wastewater,
The wastewater treatment system performs coagulation and sedimentation treatment on mixed water, the mixed water being obtained by mixing the wastewater A with the other wastewater,
The wastewater treatment system comprises:
an electrical conductivity meter for measuring at least two electrical conductivities of the drainage water A, the other drainage water, and the mixed water;
a water amount measuring device for measuring at least two water amounts among the amount of the wastewater A, the amount of the other wastewater, and the amount of the mixed water;
The method includes a coagulation and sedimentation treatment device for coagulating and sedimenting the mixed water, and a coagulant adding device for adding a coagulant to the coagulation and sedimentation treatment device,
The wastewater treatment system comprises:
The electrical conductivity of the wastewater A, the electrical conductivity of the other wastewater, the amount of the mixed water, and the mixing ratio of the wastewater A and the other wastewater in the mixed water, which have been prepared in advance,
The amount of flocculant added;
Based on the relationship between the addition of the coagulant and the indicator of the pollutants in the mixed water after the sedimentation treatment,
A calculation unit is provided for calculating an appropriate amount of flocculant to be added so that the pollutant index of the mixed water is equal to or less than a predetermined appropriate value,
The relationship is
A suitable amount of flocculant to be added to the wastewater A and a suitable amount of flocculant to be added to the other wastewater are determined in advance by a flocculation test,
When the calibration relationship between the amount of flocculant added and the indicator of pollutants after the flocculant was added and the precipitation treatment was performed for the wastewater A and the other wastewater was obtained,
The relationship between the electrical conductivity of the wastewater A, the electrical conductivity of the other wastewater, the amount of the mixed water, and the mixing ratio of each wastewater in the mixed water, and the amount of flocculant to be added, which is obtained from the calibration relationship;
The wastewater treatment system is characterized in that in the coagulation sedimentation treatment, the coagulant is added to the coagulation sedimentation treatment device by the coagulant adding device in the calculated appropriate coagulant addition amount.
2種類以上の排水を混合して凝集沈殿処理する排水処理システムであって、
該2種類以上の排水のうち電荷密度の絶対値が100μeq/Lを超える排水を排水Aとし、
該2種類以上の排水のうち電荷密度の絶対値が0μeq/L~100μeq/Lの排水を他の排水としたとき、
該排水処理システムは、混合水を凝集沈殿処理するものであり、該混合水は該排水Aと該他の排水とを混合して得られたものであり、
該排水処理システムは、
該排水Aの電気伝導度、該他の排水の電気伝導度及び該混合水の電気伝導度のうちの少なくとも二つの電気伝導度を測定する電気伝導度計、
該排水Aの量、該他の排水の量及び該混合水の量のうちの少なくとも二つの水量を測定する水量測定装置、
該混合水を凝集沈殿処理する凝集沈殿処理装置、並びに
該凝集沈殿処理装置に凝集剤を添加する凝集剤添加装置を備え、
該排水処理システムは、該少なくとも二つの電気伝導度及び該少なくとも二つの水量から、
予め準備した、該排水Aの電気伝導度、該他の排水の電気伝導度、該混合水の量及び該混合水中の該排水Aと該他の排水との混合割合と、
凝集剤添加量と、
該凝集剤の添加及び沈殿処理後の該混合水の汚濁物質の指標と、の関係に基づき、
該混合水の汚濁物質の指標が予め設定した適正値以下となる適正凝集剤添加量を算出する演算部を有し、
該関係が、
該排水Aに対する適正な凝集剤添加量と、該他の排水に対する適正な凝集剤添加量とを予め凝集試験によって求めておき、
該排水A及び該他の排水について、凝集剤添加量と、凝集剤を添加し沈殿処理を行った後の汚濁物質の指標と、の検量関係を取得したときの、
該検量関係から得られる、該排水Aの電気伝導度、該他の排水の電気伝導度、該混合水の量及び該混合水中の各排水の混合割合と、凝集剤添加量との関係であり、
該凝集沈殿処理において、該算出された該適正凝集剤添加量で、該凝集剤添加装置により該凝集沈殿処理装置に該凝集剤を添加することを特徴とする排水処理システム。
A wastewater treatment system that mixes two or more types of wastewater and performs coagulation and sedimentation treatment,
Among the two or more types of wastewater, wastewater having an absolute value of charge density exceeding 100 μeq/L is designated as wastewater A;
When wastewater having an absolute value of charge density of 0 μeq/L to 100 μeq/L among the two or more types of wastewater is the other wastewater,
The wastewater treatment system performs coagulation and sedimentation treatment on mixed water, the mixed water being obtained by mixing the wastewater A with the other wastewater,
The wastewater treatment system comprises:
an electrical conductivity meter for measuring at least two electrical conductivities of the drainage water A, the other drainage water, and the mixed water;
a water amount measuring device for measuring at least two water amounts among the amount of the wastewater A, the amount of the other wastewater, and the amount of the mixed water;
The method includes a coagulation and sedimentation treatment device for coagulating and sedimenting the mixed water, and a coagulant adding device for adding a coagulant to the coagulation and sedimentation treatment device,
The wastewater treatment system comprises:
The electrical conductivity of the wastewater A, the electrical conductivity of the other wastewater, the amount of the mixed water, and the mixing ratio of the wastewater A and the other wastewater in the mixed water, which have been prepared in advance,
The amount of flocculant added;
Based on the relationship between the addition of the coagulant and the indicator of the pollutants in the mixed water after the sedimentation treatment,
A calculation unit is provided for calculating an appropriate amount of flocculant to be added so that the pollutant index of the mixed water is equal to or less than a predetermined appropriate value,
The relationship is
A suitable amount of flocculant to be added to the wastewater A and a suitable amount of flocculant to be added to the other wastewater are determined in advance by a flocculation test,
When the calibration relationship between the amount of flocculant added and the indicator of pollutants after the flocculant was added and the precipitation treatment was performed for the wastewater A and the other wastewater was obtained,
The relationship between the electrical conductivity of the wastewater A, the electrical conductivity of the other wastewater, the amount of the mixed water, and the mixing ratio of each wastewater in the mixed water, and the amount of flocculant to be added, which is obtained from the calibration relationship;
The wastewater treatment system is characterized in that in the coagulation sedimentation treatment, the coagulant is added to the coagulation sedimentation treatment device by the coagulant adding device in the calculated appropriate coagulant addition amount.
前記汚濁物質の指標が、濁度、浮遊物質量、紫外線吸光度及び化学的酸素要求量からなる群から選択される少なくとも一である請求項1又は2に記載の排水処理システム。 The wastewater treatment system according to claim 1 or 2, wherein the indicator of pollutants is at least one selected from the group consisting of turbidity, suspended solids, ultraviolet absorbance, and chemical oxygen demand. 前記汚濁物質の指標が、濁度である請求項1又は2に記載の排水処理システム。 The wastewater treatment system according to claim 1 or 2, wherein the indicator of pollutants is turbidity. 前記排水処理システムは、
前記排水Aを貯留する貯留槽A、
前記排水A以外の前記他の排水を貯留する他の貯留槽、
該貯留槽Aから送水された前記排水Aと該他の貯留槽から送水された前記他の排水とを混合して前記混合水を得る混和槽、並びに
該混和槽から送水された前記混合水を凝集沈殿処理する連続式の凝集沈殿処理装置を備え、
前記排水処理システムは、
前記排水Aの電気伝導度Aを測定する電気伝導度計A及び該貯留槽Aから該混和槽に送水された前記排水Aの流量Aを測定する流量計A、
前記他の排水の電気伝導度を測定する他の電気伝導度計、並びに
該混和槽から凝集沈殿処理装置に送水された前記混合水の流量を測定する混合水流量計を
備え、
前記演算部は、前記混合水の該流量、該電気伝導度A、該流量A、及び前記他の排水の電気伝導度から、前記関係に基づいて前記適正凝集剤添加量を算出する請求項1~4のいずれか一項に記載の排水処理システム。
The wastewater treatment system comprises:
A storage tank A for storing the wastewater A;
Another storage tank for storing the other wastewater other than the wastewater A;
a mixing tank for mixing the wastewater A sent from the storage tank A with the other wastewater sent from the other storage tank to obtain the mixed water, and a continuous coagulation and sedimentation treatment device for coagulating and sedimenting the mixed water sent from the mixing tank,
The wastewater treatment system comprises:
an electrical conductivity meter A for measuring the electrical conductivity A of the wastewater A and a flow meter A for measuring the flow rate A of the wastewater A conveyed from the storage tank A to the mixing tank;
another electrical conductivity meter for measuring the electrical conductivity of the other wastewater, and a mixed water flow meter for measuring the flow rate of the mixed water sent from the mixing tank to a coagulation sedimentation treatment device;
The calculation unit calculates the appropriate amount of coagulant to be added based on the relationship from the flow rate of the mixed water, the electrical conductivity A, the flow rate A, and the electrical conductivity of the other wastewater. The wastewater treatment system according to any one of claims 1 to 4.
前記排水処理システムは、
前記排水Aを貯留する貯留槽A、
前記排水A以外の前記他の排水を貯留する他の貯留槽、並びに
該貯留槽Aから送水された前記排水A及び該他の貯留槽から送水された前記他の排水を混合し、得られた前記混合水を凝集沈殿処理する回分式の凝集沈殿処理装置を備え、
前記排水処理システムは、
前記排水Aの電気伝導度Aを測定する電気伝導度計A及び該貯留槽Aから前記凝集沈殿処理装置に送水された前記排水Aの流量Aを測定する流量計A、
前記他の排水の電気伝導度を測定する他の電気伝導度計、並びに
前記凝集沈殿処理装置に送水された前記混合水の量及び送水時間を測定する水位計を備え、
該演算部は、該電気伝導度A、該流量A、前記他の排水の電気伝導度、並びに前記混合水の量及び該送水時間から、前記関係に基づいて前記適正凝集剤添加量を算出する請求項1~4のいずれか一項に記載の排水処理システム。
The wastewater treatment system comprises:
A storage tank A for storing the wastewater A;
a second storage tank for storing the wastewater other than the wastewater A, and a batch-type coagulation and sedimentation treatment device for mixing the wastewater A sent from the storage tank A with the other wastewater sent from the second storage tank, and performing coagulation and sedimentation treatment on the resulting mixed water,
The wastewater treatment system comprises:
an electric conductivity meter A for measuring the electric conductivity A of the wastewater A and a flow meter A for measuring the flow rate A of the wastewater A conveyed from the storage tank A to the coagulation sedimentation treatment device;
Another electrical conductivity meter for measuring the electrical conductivity of the other wastewater, and a water level meter for measuring the amount and water supply time of the mixed water supplied to the coagulation sedimentation treatment device,
The wastewater treatment system according to any one of claims 1 to 4, wherein the calculation unit calculates the appropriate amount of coagulant to be added based on the relationship from the electrical conductivity A, the flow rate A, the electrical conductivity of the other wastewater, and the amount of the mixed water and the water delivery time.
前記排水処理システムは、
前記排水A以外の前記他の排水を貯留する他の貯留槽、
前記排水Aが送水され、且つ、該他の貯留槽から前記他の排水が送水されることで、前記排水A及び前記他の排水が混合され前記混合水が得られ、前記混合水が貯留される混合水貯留槽、並びに
該混合水貯留槽から送水された前記混合水を凝集沈殿処理する前記凝集沈殿処理装置を備え、
前記排水処理システムは、
前記他の排水の電気伝導度を測定する他の電気伝導度計、該他の貯留槽から該混合水貯留槽に送水された前記他の排水の流量Bを測定する流量計B、
該混合水貯留槽中の前記混合水の電気伝導度Cを測定する電気伝導度計C、
該混合水貯留槽から前記凝集沈殿処理装置に送水された前記混合水の流量を測定する混合水流量計を備え、
前記演算部は、前記他の排水の電気伝導度、該流量B、該電気伝導度C及び前記混合水の流量から、前記関係に基づいて前記適正凝集剤添加量を算出する請求項1~4のいずれか一項に記載の排水処理システム。
The wastewater treatment system comprises:
Another storage tank for storing the other wastewater other than the wastewater A;
The wastewater A is delivered and the other wastewater is delivered from the other storage tank, so that the wastewater A and the other wastewater are mixed to obtain the mixed water, and the mixed water is stored in a mixed water storage tank, and the coagulation sedimentation treatment device is provided for coagulating and sedimenting the mixed water delivered from the mixed water storage tank,
The wastewater treatment system comprises:
Another electrical conductivity meter for measuring the electrical conductivity of the other wastewater; a flow meter B for measuring the flow rate B of the other wastewater sent from the other storage tank to the mixed water storage tank;
an electrical conductivity meter C for measuring the electrical conductivity C of the mixed water in the mixed water storage tank;
a mixed water flow meter for measuring a flow rate of the mixed water sent from the mixed water storage tank to the coagulation sedimentation treatment device;
The wastewater treatment system according to any one of claims 1 to 4, wherein the calculation unit calculates the appropriate amount of coagulant to be added based on the relationship from the electrical conductivity of the other wastewater, the flow rate B, the electrical conductivity C, and the flow rate of the mixed water.
前記関係が、下記関係式(1)であり、
前記演算部が、下記関係式(1)により前記適正凝集剤添加量を算出する請求項5~7のいずれか一項に記載の排水処理システム。
F=αEA×VA+βEB(VC-VA) ・・・(1)
(式中、F(L/h)は前記適正凝集剤添加量である。EA(μS/cm)は前記排水Aの電気伝導度であり、VA(m/h)は前記排水Aの流量Aである。EB(μS/cm)は前記他の排水の電気伝導度であり、VC(m/h)は前記混合水の流量である。α及びβは係数(cm/μS・L/m)であり、αは1.0×10-3~1.0×10-2の値を示し、βは1.0×10-4~1.0×10-3の値を示す。)
The relationship is the following relational formula (1):
The wastewater treatment system according to any one of claims 5 to 7, wherein the calculation unit calculates the appropriate amount of flocculant to be added by the following relational expression (1):
F = αEA × VA + βEB (VC - VA) ... (1)
(In the formula, F (L/h) is the appropriate amount of flocculant to be added. EA (μS/cm) is the electrical conductivity of wastewater A, VA (m 3 /h) is the flow rate A of wastewater A, EB (μS/cm) is the electrical conductivity of the other wastewater, and VC (m 3 /h) is the flow rate of the mixed water. α and β are coefficients (cm/μS·L/m 3 ), α is a value of 1.0×10 -3 to 1.0×10 -2 , and β is a value of 1.0×10 -4 to 1.0×10 -3 .)
前記凝集剤添加装置による前記凝集剤の添加後、高分子凝集剤を前記混合水1mにつき固形分で0.1g~10g添加する請求項1~8のいずれか一項に記載の排水処理システム。 The wastewater treatment system according to any one of claims 1 to 8, wherein after the addition of the flocculant by the flocculant adding device, 0.1 g to 10 g of polymer flocculant is added per 1 m3 of the mixed water in terms of solid content. 前記排水Aの電荷密度が、-10000μeq/L以上-100μeq/L未満であり、
前記他の排水の電荷密度が、-100μeq/L~0μeq/Lである請求項1~9のいずれか一項に記載の排水処理システム。
The charge density of the wastewater A is -10,000 μeq/L or more and less than -100 μeq/L,
The wastewater treatment system according to any one of claims 1 to 9, wherein the charge density of the other wastewater is -100 μeq/L to 0 μeq/L.
前記2種類以上の排水が、段ボール工場で発生する排水であり、
前記排水Aが、インキ洗浄水であり、前記排水A以外の前記他の排水が、糊洗浄水である請求項1~10のいずれか一項に記載の排水処理システム。
The two or more types of wastewater are wastewater generated in a cardboard factory,
The wastewater treatment system according to any one of claims 1 to 10, wherein the wastewater A is ink washing water, and the other wastewater other than the wastewater A is glue washing water.
前記排水処理システムは、前記凝集沈殿処理装置の処理水を生物学的に処理する生物反応槽を備える請求項1~11のいずれか一項に記載の排水処理システム。 The wastewater treatment system according to any one of claims 1 to 11, further comprising a biological reaction tank for biologically treating the treated water from the coagulation and sedimentation treatment device. 前記生物反応槽が膜分離活性汚泥処理装置である請求項12に記載の排水処理システム。 The wastewater treatment system according to claim 12, wherein the biological reactor is a membrane separation activated sludge treatment device. 2種類以上の排水を混合して得られた混合水を凝集沈殿処理する凝集沈殿処理装置を備えた排水処理システムによる排水処理方法であって、
該排水処理方法は、
該2種類以上の排水の中で最も電荷密度の絶対値が高い排水である排水Aと、
該2種類以上の排水のうち該排水A以外の他の排水と、を混合して該混合水を得る混合工程、
該排水Aの電気伝導度、該他の排水の電気伝導度及び該混合水の電気伝導度のうちの少なくとも二つの電気伝導度、並びに該排水Aの量、該他の排水の量及び該混合水の量のうちの少なくとも二つの水量から、
予め準備した、該排水Aの電気伝導度、該他の排水の電気伝導度、該混合水の量及び該混合水中の該排水Aと該他の排水との混合割合と、
凝集剤添加量と、
該凝集剤の添加及び沈殿処理後の該混合水の汚濁物質の指標と、の関係に基づき、
該混合水の汚濁物質の指標が予め設定した適正値以下となる適正凝集剤添加量を算出する算出工程、並びに
得られた該混合水を凝集沈殿処理する凝集沈殿処理工程を有し、
該関係が、
該排水Aに対する適正な凝集剤添加量と、該他の排水に対する適正な凝集剤添加量とを予め凝集試験によって求めておき、
該排水A及び該他の排水について、凝集剤添加量と、凝集剤を添加し沈殿処理を行った後の汚濁物質の指標と、の検量関係を取得したときの、
該検量関係から得られる、該排水Aの電気伝導度、該他の排水の電気伝導度、該混合水の量及び該混合水中の各排水の混合割合と、凝集剤添加量との関係であり、
該凝集沈殿処理工程において、該算出された該適正凝集剤添加量で、該凝集沈殿処理装置に該凝集剤を添加することを特徴とする排水処理方法。
A wastewater treatment method using a wastewater treatment system equipped with a coagulation sedimentation treatment device that performs coagulation sedimentation treatment on mixed water obtained by mixing two or more types of wastewater,
The wastewater treatment method comprises:
Wastewater A is a wastewater having the highest absolute value of charge density among the two or more types of wastewater;
A mixing step of mixing the two or more types of wastewater with other wastewater than the wastewater A to obtain the mixed water;
From at least two electrical conductivities of the drainage A, the other drainage, and the mixed water, and the amount of at least two waters of the amount of the drainage A, the amount of the other drainage, and the amount of the mixed water,
The electrical conductivity of the wastewater A, the electrical conductivity of the other wastewater, the amount of the mixed water, and the mixing ratio of the wastewater A and the other wastewater in the mixed water, which have been prepared in advance,
The amount of flocculant added;
Based on the relationship between the addition of the coagulant and the indicator of the pollutants in the mixed water after the sedimentation treatment,
The method includes a calculation step of calculating an appropriate amount of flocculant to be added so that the pollutant index of the mixed water is equal to or less than a predetermined appropriate value, and a coagulation and sedimentation treatment step of subjecting the obtained mixed water to coagulation and sedimentation treatment,
The relationship is
A proper amount of flocculant to be added to the wastewater A and a proper amount of flocculant to be added to the other wastewater are determined in advance by a flocculation test,
When the calibration relationship between the amount of flocculant added and the indicator of pollutants after the flocculant was added and the precipitation treatment was performed for the wastewater A and the other wastewater was obtained,
The relationship between the electrical conductivity of the wastewater A, the electrical conductivity of the other wastewater, the amount of the mixed water, and the mixing ratio of each wastewater in the mixed water, and the amount of flocculant to be added, which is obtained from the calibration relationship;
The wastewater treatment method, wherein in the coagulation and sedimentation treatment step, the calculated appropriate amount of coagulant to be added is added to the coagulation and sedimentation treatment device.
2種類以上の排水を混合して得られた混合水を凝集沈殿処理する凝集沈殿処理装置を備えた排水処理システムによる排水処理方法であって、
該排水処理方法は、
該2種類以上の排水のうち電荷密度の絶対値が100μeq/Lを超える排水である排水Aと、
該2種類以上の排水のうち電荷密度の絶対値が0μeq/L~100μeq/Lの排水である他の排水と、を混合して該混合水を得る混合工程、
該排水Aの電気伝導度、該他の排水の電気伝導度及び該混合水の電気伝導度のうちの少
なくとも二つの電気伝導度、並びに該排水Aの量、該他の排水の量及び該混合水の量のうちの少なくとも二つの水量から、
予め準備した、該排水Aの電気伝導度、該他の排水の電気伝導度、該混合水の量及び該混合水中の該排水Aと該他の排水との混合割合と、
凝集剤添加量と、
該凝集剤の添加及び沈殿処理後の該混合水の汚濁物質の指標と、の関係に基づき、
該混合水の汚濁物質の指標が予め設定した適正値以下となる適正凝集剤添加量を算出する算出工程、並びに
得られた該混合水を凝集沈殿処理する凝集沈殿処理工程を有し、
該関係が、
該排水Aに対する適正な凝集剤添加量と、該他の排水に対する適正な凝集剤添加量とを予め凝集試験によって求めておき、
該排水A及び該他の排水について、凝集剤添加量と、凝集剤を添加し沈殿処理を行った後の汚濁物質の指標と、の検量関係を取得したときの、
該検量関係から得られる、該排水Aの電気伝導度、該他の排水の電気伝導度、該混合水の量及び該混合水中の各排水の混合割合と、凝集剤添加量との関係であり、
該凝集沈殿処理工程において、該算出された該適正凝集剤添加量で、該凝集沈殿処理装置に該凝集剤を添加することを特徴とする排水処理方法。
A wastewater treatment method using a wastewater treatment system equipped with a coagulation sedimentation treatment device that performs coagulation sedimentation treatment on mixed water obtained by mixing two or more types of wastewater,
The wastewater treatment method comprises:
Among the two or more types of wastewater, wastewater A is wastewater having an absolute value of charge density exceeding 100 μeq/L;
A mixing step of mixing the two or more types of wastewater with another wastewater having an absolute value of charge density of 0 μeq/L to 100 μeq/L to obtain the mixed water;
From at least two electrical conductivities of the drainage A, the other drainage, and the mixed water, and the amount of at least two waters of the amount of the drainage A, the amount of the other drainage, and the amount of the mixed water,
The electrical conductivity of the wastewater A, the electrical conductivity of the other wastewater, the amount of the mixed water, and the mixing ratio of the wastewater A and the other wastewater in the mixed water, which have been prepared in advance,
The amount of flocculant added;
Based on the relationship between the addition of the coagulant and the indicator of the pollutants in the mixed water after the sedimentation treatment,
The method includes a calculation step of calculating an appropriate amount of flocculant to be added so that the pollutant index of the mixed water is equal to or less than a predetermined appropriate value, and a coagulation and sedimentation treatment step of subjecting the obtained mixed water to coagulation and sedimentation treatment,
The relationship is
A proper amount of flocculant to be added to the wastewater A and a proper amount of flocculant to be added to the other wastewater are determined in advance by a flocculation test,
When the calibration relationship between the amount of flocculant added and the indicator of pollutants after the flocculant was added and the precipitation treatment was performed for the wastewater A and the other wastewater was obtained,
The relationship between the electrical conductivity of the wastewater A, the electrical conductivity of the other wastewater, the amount of the mixed water, and the mixing ratio of each wastewater in the mixed water, and the amount of flocculant to be added, which is obtained from the calibration relationship;
The wastewater treatment method, wherein in the coagulation and sedimentation treatment step, the calculated appropriate amount of coagulant to be added is added to the coagulation and sedimentation treatment device.
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004223357A (en) 2003-01-21 2004-08-12 Toshiba Corp Flocculant injecting/controlling apparatus
JP2017077525A (en) 2015-10-20 2017-04-27 株式会社東芝 Flocculant injection support device and control method
JP2017077513A (en) 2015-10-19 2017-04-27 栗田工業株式会社 Production method and production apparatus of pure water

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004223357A (en) 2003-01-21 2004-08-12 Toshiba Corp Flocculant injecting/controlling apparatus
JP2017077513A (en) 2015-10-19 2017-04-27 栗田工業株式会社 Production method and production apparatus of pure water
JP2017077525A (en) 2015-10-20 2017-04-27 株式会社東芝 Flocculant injection support device and control method

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