JP7480949B2 - Food modifier and manufacturing method of modified food - Google Patents

Food modifier and manufacturing method of modified food Download PDF

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Publication number
JP7480949B2
JP7480949B2 JP2022579584A JP2022579584A JP7480949B2 JP 7480949 B2 JP7480949 B2 JP 7480949B2 JP 2022579584 A JP2022579584 A JP 2022579584A JP 2022579584 A JP2022579584 A JP 2022579584A JP 7480949 B2 JP7480949 B2 JP 7480949B2
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food
weight
less
starch
liquid
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JPWO2022168878A1 (en
JPWO2022168878A5 (en
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朋之 斉藤
貴幸 柏原
恭子 桑田
徹 中島
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MIRAIKASEI INC.
Nippon Starch Chemical Co Ltd
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Nippon Starch Chemical Co Ltd
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23PSHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
    • A23P20/00Coating of foodstuffs; Coatings therefor; Making laminated, multi-layered, stuffed or hollow foodstuffs
    • A23P20/10Coating with edible coatings, e.g. with oils or fats
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L13/00Meat products; Meat meal; Preparation or treatment thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L17/00Food-from-the-sea products; Fish products; Fish meal; Fish-egg substitutes; Preparation or treatment thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L17/00Food-from-the-sea products; Fish products; Fish meal; Fish-egg substitutes; Preparation or treatment thereof
    • A23L17/40Shell-fish
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L17/00Food-from-the-sea products; Fish products; Fish meal; Fish-egg substitutes; Preparation or treatment thereof
    • A23L17/50Molluscs
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L19/00Products from fruits or vegetables; Preparation or treatment thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/212Starch; Modified starch; Starch derivatives, e.g. esters or ethers
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/231Pectin; Derivatives thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/238Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin from seeds, e.g. locust bean gum or guar gum
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/244Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin from corms, tubers or roots, e.g. glucomannan
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/256Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin from seaweeds, e.g. alginates, agar or carrageenan
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/262Cellulose; Derivatives thereof, e.g. ethers
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/269Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of microbial origin, e.g. xanthan or dextran
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/30Foods or foodstuffs containing additives; Preparation or treatment thereof containing carbohydrate syrups; containing sugars; containing sugar alcohols, e.g. xylitol; containing starch hydrolysates, e.g. dextrin
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2200/00Function of food ingredients
    • A23V2200/20Ingredients acting on or related to the structure
    • A23V2200/228Gelling agent
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2300/00Processes
    • A23V2300/24Heat, thermal treatment

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Dispersion Chemistry (AREA)
  • Marine Sciences & Fisheries (AREA)
  • Zoology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Molecular Biology (AREA)
  • Jellies, Jams, And Syrups (AREA)
  • General Preparation And Processing Of Foods (AREA)

Description

本開示は食品改質剤及び改質食品の製造方法に関する。特に食品を加熱した際の歩留まりを向上させ、食品の外観を保持する食品改質剤、及び改質食品の製造方法に関する。 The present disclosure relates to a food modifier and a method for producing modified foods. In particular, the present disclosure relates to a food modifier that improves the yield of food when heated and maintains the appearance of the food, and a method for producing modified foods.

食品の改質について、特に畜肉食品及び水産食品は、保存期間中に変色や退色、離水等が起こりやすく、商品価値の低下を招いてしまう。さらに、畜肉食品及び水産食品を調理あるいは加工する場合、原料を単に加熱し、あるいは成型する等の加工処理を行うと、加工時に離水や離油が起こり、食品のもつ好ましい食感や外観が損なわれてしまう。そこで、食品の変色、退色、離水等を防止する目的で、食品改質剤を食品に添加することが行われている。とりわけリン酸塩は冷凍耐性の向上、保水力の改善、歩留まりの向上等の目的で従来から配合されている。 When it comes to modifying food, meat and seafood foods in particular are prone to discoloration, fading, and water separation during storage, which reduces their commercial value. Furthermore, when cooking or processing meat and seafood foods, simply heating the raw materials or subjecting them to processing such as molding can cause water and oil separation during processing, compromising the food's desirable texture and appearance. Therefore, food modifiers are added to foods to prevent discoloration, fading, water separation, etc. In particular, phosphates have traditionally been added to foods with the aim of improving freezing resistance, improving water retention, and increasing yields.

しかしながら、リン酸塩による方法は体内へのカルシウムや亜鉛の吸収阻害等の問題が指摘され、さらにリン酸塩独特の苦みが残ることから、あまり好ましいものではなく、その使用が忌避される傾向にある。However, the method using phosphates has been pointed out to have problems such as inhibiting the absorption of calcium and zinc in the body, and because phosphates leave a bitter taste that is unique to them, it is not very desirable and its use tends to be avoided.

そこで、リン酸塩を含まずに、リン酸塩を配合した食品用品質向上剤と同等以上の効果を有する、食品改質剤の報告がなされている。特許文献1には、タンパク質とアルカリ剤とを含有することを特徴とする食品改質剤が記載されている。特許文献2には、グリシンの可食性金属塩又はグリシンの可食性金属塩及びグリシンの混合水溶液に魚介類を浸漬して含浸させることを特徴とする魚介類の処理方法が記載されている。特許文献3には、穀物タンパク質部分分解物と、アルカリ金属炭酸塩及びアルカリ金属炭酸水素塩から選ばれた少なくとも1種とを有効成分として含有することを特徴とする食肉加工食品の改質剤が記載されている。特許文献4には、膨張剤と食物繊維及び/又はグルコン酸塩とを有効成分として含有することを特徴とする畜肉用改質剤が記載されている。特許文献5には、炭酸塩、酢酸及び有機酸を含有することを特徴とする畜肉又は水産物の日持ち及び歩留まり向上剤が記載されている。 Therefore, food modifiers that do not contain phosphate but have the same or greater effect as food quality improvers containing phosphate have been reported. Patent Document 1 describes a food modifier that contains a protein and an alkaline agent. Patent Document 2 describes a method for treating seafood, which is characterized by immersing and impregnating seafood in an edible metal salt of glycine or a mixed aqueous solution of an edible metal salt of glycine and glycine. Patent Document 3 describes a modifier for processed meat foods, which is characterized by containing a partial hydrolysis product of grain protein and at least one selected from an alkali metal carbonate and an alkali metal hydrogen carbonate as active ingredients. Patent Document 4 describes a meat modifier, which is characterized by containing a leavening agent and dietary fiber and/or gluconate as active ingredients. Patent Document 5 describes a shelf life and yield improver for meat or marine products, which is characterized by containing a carbonate, acetic acid, and an organic acid.

特開2006-050945号公報JP 2006-050945 A 特開2000-300219号公報JP 2000-300219 A 特開2007-267652号公報JP 2007-267652 A 特開2001-000148号公報JP 2001-000148 A 特開2016-029914号公報JP 2016-029914 A

しかしながら、従来の改質剤を使用すると、歩留まりは向上するものの、食品がアルカリ性になってしまうことでアルカリ特有の苦みが感じられ、食品本来の風味を損なってしまうといった問題があった。 However, when using conventional modifiers, although yields improved, problems arose in that the food became alkaline, giving it a bitter taste characteristic of alkaline foods and compromising the food's original flavor.

そこで、リン酸塩を使用する必要なく、なおかつ食品をアルカリ性にすることなく加熱時の歩留まりを向上させ、風味を損なうことなくその外観を保持できる食品改質剤が求められていた。 Therefore, there was a need for a food modifier that could improve yield during heating without using phosphates and without making food alkaline, and that could maintain appearance without compromising flavor.

本開示は、リン酸塩を使用する必要がなく、なおかつ、食品をアルカリ性にすることなく食品を加熱した際の歩留まりを向上させ、食品の外観を保持する食品改質剤、及び食品改質方法を提供することを目的とする。 The present disclosure aims to provide a food modifier and a food modification method that improves the yield of food when heated without requiring the use of phosphates and without making the food alkaline, and that maintains the appearance of the food.

本発明者は上記目的の達成のために鋭意検討を行った結果、可逆熱ゲル化剤と、増粘剤とを含有する食品改質剤を使用した場合に、食品を加熱した際の歩留まりを向上させ、風味を損なうことなく食品の外観を保持することが出来ることを見出し、本開示を完成させるに至った。As a result of intensive research conducted by the inventors to achieve the above-mentioned objective, they discovered that when a food modifier containing a reversible thermal gelling agent and a thickener is used, it is possible to improve the yield when food is heated and to maintain the appearance of the food without compromising its flavor, and thus completed the present disclosure.

本開示の一態様は以下のとおりである。
[項1]
可逆熱ゲル化剤及び増粘剤を含む、食品改質剤。
[項2]
前記可逆熱ゲル化剤の熱ゲル化温度が40℃以上である、項1に記載の食品改質剤。
[項3]
前記増粘剤の15℃における2重量%水溶液の粘度が30mPa・s以上である、項1又は2に記載の食品改質剤。
[項4]
前記可逆熱ゲル化剤がメチルセルロース又はヒドロキシプロピルメチルセルロースである、項1~3のいずれか一項に記載の食品改質剤。
[項5]
前記増粘剤が澱粉、澱粉分解物、カルボキシメチルセルロース、キサンタンガム、グァーガム、ローカストビーンガム、ジェランガム、ネイティブジェランガム、タマリンドシードガム、カラギーナン、ペクチン、アルギン酸ナトリウム、海藻粉末、海藻抽出物、グルコマンナン、及び寒天からなる群から選択される少なくとも一種である、項1~4のいずれか一項に記載の食品改質剤。
[項6]
前記増粘剤が前記澱粉及び前記澱粉分解物の両方を含む、項1~5のいずれか一項に記載の食品改質剤。
[項7]
結晶セルロースを含む、項1~6のいずれか一項に記載の食品改質剤。
[項8]
非増粘性澱粉を含む、項1~7のいずれか一項に記載の食品改質剤。
[項9]
前記食品改質剤に水を加えて撹拌混合して固形分5重量%に調製した食品改質剤液の15℃における粘度が250mPa・s以上である、項1~8のいずれかに記載の食品改質剤。
[項10]
可逆熱ゲル化剤を含む食品改質剤であって、食品改質時に食品に添加され、食品改質後には除去可能な食品改質剤。
[項11]
食品被覆に用いられる、項10に記載の食品改質剤。
[項12]
項1~11のいずれか一項に記載の食品改質剤に水を加えて撹拌混合して食品改質剤液を得る工程(1)、前記食品改質剤液で食品を被覆して被覆食品を得る工程(2)、及び前記被覆食品を可逆熱ゲル化剤の熱ゲル化温度以上で加熱する工程(3)を含む、改質食品の製造方法。
[項13]
前記工程(3)における加熱が、茹で、又は蒸しである、項12に記載の改質食品の製造方法。
[項14]
前記食品改質剤液の粘度が15℃において250mPa・s以上10000mPa・s以下である、項12又は13に記載の改質食品の製造方法。
[項15]
さらに、前記被覆食品を水で洗浄する工程(4)を含む、項12~14のいずれか一項に記載の改質食品の製造方法。
One aspect of the present disclosure is as follows.
[Item 1]
Food modifiers, including reversible thermal gelling agents and thickening agents.
[Item 2]
Item 2. The food modifier according to item 1, wherein the reversible thermal gelling agent has a thermal gelling temperature of 40° C. or higher.
[Item 3]
Item 3. The food modifier according to item 1 or 2, wherein the viscosity of a 2% by weight aqueous solution of the thickener at 15 ° C. is 30 mPa · s or more.
[Item 4]
Item 4. The food modifier according to any one of Items 1 to 3, wherein the reversible heat gelling agent is methylcellulose or hydroxypropylmethylcellulose.
[Item 5]
The thickener is at least one selected from the group consisting of starch, starch hydrolysates, carboxymethylcellulose, xanthan gum, guar gum, locust bean gum, gellan gum, native gellan gum, tamarind seed gum, carrageenan, pectin, sodium alginate, seaweed powder, seaweed extract, glucomannan, and agar. The food modifier according to any one of claims 1 to 4.
[Item 6]
Item 6. The food modifier according to any one of items 1 to 5, wherein the thickener contains both the starch and the starch hydrolysate.
[Item 7]
Item 7. The food modifier according to any one of items 1 to 6, comprising crystalline cellulose.
[Item 8]
Item 8. The food modifier according to any one of Items 1 to 7, comprising a non-thickening starch.
[Item 9]
The food modifier according to any one of items 1 to 8, wherein the viscosity of a food modifier liquid prepared by adding water to the food modifier and stirring and mixing to a solid content of 5% by weight at 15 ° C. is 250 mPa · s or more.
[Item 10]
A food modifier containing a reversible heat gelling agent, which is added to food during food modification and can be removed after the food modification.
[Item 11]
Item 11. The food modifier according to item 10, which is used for food coating.
[Item 12]
A method for producing a modified food, comprising the steps of: (1) adding water to the food modifier according to any one of items 1 to 11 and stirring and mixing to obtain a food modifier liquid; (2) coating a food with the food modifier liquid to obtain a coated food; and (3) heating the coated food at a temperature equal to or higher than the thermal gelling temperature of the reversible thermal gelling agent.
[Item 13]
Item 13. The method for producing a modified food according to item 12, wherein the heating in step (3) is boiling or steaming.
[Item 14]
Item 14. The method for producing a modified food according to item 12 or 13, wherein the viscosity of the food modifier liquid is 250 mPa s or more and 10,000 mPa s or less at 15 ° C.
[Item 15]
The method for producing a modified food according to any one of items 12 to 14, further comprising a step (4) of washing the coated food with water.

本開示によれば、リン酸塩を使用せず、なおかつ食品をアルカリ性にすることなく加熱した際の歩留まりを向上させることが出来る。また、加熱時に生じる食品の外観の劣化を防ぎ、綺麗な見た目を保持することが可能である。さらに、例えばなめこ等の特徴的なぬめり感を有する食品に関して、加熱後にもそのぬめり感を保持することが出来る。 According to the present disclosure, it is possible to improve the yield when heating food without using phosphates and without making the food alkaline. It is also possible to prevent the deterioration of the appearance of the food that occurs when heated, and to maintain a beautiful appearance. Furthermore, for foods that have a characteristic slimy texture, such as nameko mushrooms, it is possible to maintain that slimy texture even after heating.

以下、本開示を実施するための形態について説明する。なお、以下の説明は、本開示の実施形態の一例を示したものであり、これにより本開示の範囲が狭く解釈されることはない。The following describes a form for implementing the present disclosure. Note that the following description is merely an example of an embodiment of the present disclosure, and is not intended to narrow the scope of the present disclosure.

<食品改質剤>
本開示における食品改質剤は可逆熱ゲル化剤を含み、さらに増粘剤を含むことが好ましい。本開示において「食品改質剤」とは、食品の品質を改変又は向上させるために食品の加工又は製造段階において用いられる添加剤である。ここで、食品の品質の例としては、食感、うまみ、外観、歩留まり、加工安定性、製造適性等が挙げられる。
<Food modifier>
The food modifier in the present disclosure preferably contains a reversible thermal gelling agent and further contains a thickener. In the present disclosure, a "food modifier" is an additive used in the processing or manufacturing stage of food to modify or improve the quality of the food. Examples of food quality include texture, flavor, appearance, yield, processing stability, and manufacturing suitability.

[可逆熱ゲル化剤]
本開示における食品改質剤は可逆熱ゲル化剤を含有する。本開示において「可逆熱ゲル化剤」とは水中において可逆的にゾル化/ゲル化する熱相転移性を有するゲル化剤である。可逆熱ゲル化剤は、水中において加熱するとゲル化温度以上より高温でゲル状態であり、ゲル化温度以下まで冷却するとゾル状態となる。
[Reversible thermal gelling agent]
The food modifier in the present disclosure contains a reversible thermal gelling agent. In the present disclosure, a "reversible thermal gelling agent" is a gelling agent that has a thermal phase transition property that reversibly solizes/gels in water. When heated in water, the reversible thermal gelling agent is in a gel state at temperatures above the gelling temperature, and when cooled below the gelling temperature, it is in a sol state.

可逆熱ゲル化剤の熱ゲル化温度は40℃以上、45℃以上、50℃以上、55℃以上、60℃以上、65℃以上、70℃以上、又は75℃以上であってよい。可逆熱ゲル化剤の熱ゲル化温度は95℃以下、90℃以下、85℃以下、又は75℃以下であってよい。熱ゲル化温度は、化学修飾基の種類、化学修飾率、分子量等を変更することにより、変更することが可能である。 The thermal gelation temperature of the reversible thermal gelling agent may be 40°C or more, 45°C or more, 50°C or more, 55°C or more, 60°C or more, 65°C or more, 70°C or more, or 75°C or more. The thermal gelation temperature of the reversible thermal gelling agent may be 95°C or less, 90°C or less, 85°C or less, or 75°C or less. The thermal gelation temperature can be changed by changing the type of chemical modification group, the chemical modification rate, the molecular weight, etc.

可逆熱ゲル化剤は多糖類であってよく、好ましくは化学修飾多糖類である。多糖類の例としては、セルロースが挙げられる。化学修飾の例としてはアルキル化、ヒドロキシアルキル化等が挙げられる。可逆熱ゲル化剤の具体例としてはメチルセルロース、ヒドロキシプロピルメチルセルロース等が挙げられる。可逆熱ゲル化剤は1種単独で用いても良く、2種以上を組み合わせて用いてもよい。The reversible thermal gelling agent may be a polysaccharide, preferably a chemically modified polysaccharide. An example of a polysaccharide is cellulose. Examples of chemical modifications include alkylation, hydroxyalkylation, etc. Specific examples of reversible thermal gelling agents include methylcellulose, hydroxypropylmethylcellulose, etc. The reversible thermal gelling agent may be used alone or in combination of two or more types.

本開示におけるメチルセルロースは、木材、竹、藁、コットン、バガス、バクテリア等から得られるセルロースをメチルエーテル化し、その水溶性を高めたものであってよい。本開示におけるヒドロキシプロピルメチルセルロースは、メチルセルロースにヒドロキシプロポキシル基を導入したものであってよい。いずれの水溶液も通常、常温、常圧で液状である。メチルセルロースの製品例としては、メトローズMCEタイプ(信越化学工業株式会社製)が挙げられる。ヒドロキシプロピルメチルセルロースの製品例としては、メトローズSFEタイプ(信越化学工業株式会社製)、メトローズSEタイプ(信越化学工業株式会社製)、メトローズNEタイプ(信越化学工業株式会社製)等が挙げられる。The methylcellulose in the present disclosure may be cellulose obtained from wood, bamboo, straw, cotton, bagasse, bacteria, etc., which has been methyl-etherified to increase its water solubility. The hydroxypropyl methylcellulose in the present disclosure may be methylcellulose into which a hydroxypropoxyl group has been introduced. Both aqueous solutions are usually liquid at room temperature and normal pressure. Examples of methylcellulose products include Metolose MCE type (manufactured by Shin-Etsu Chemical Co., Ltd.). Examples of hydroxypropyl methylcellulose products include Metolose SFE type (manufactured by Shin-Etsu Chemical Co., Ltd.), Metolose SE type (manufactured by Shin-Etsu Chemical Co., Ltd.), Metolose NE type (manufactured by Shin-Etsu Chemical Co., Ltd.), etc.

[増粘剤]
本開示における食品改質剤は増粘剤を含むことが好ましい。本開示において「増粘剤」とは常温で水に溶解又は分散して粘稠性を生じる高分子物質のことである。本開示において増粘剤は上記可逆熱ゲル化剤を含まない、つまり、可逆熱ゲル性を有しない。
[Thickener]
The food modifier in the present disclosure preferably contains a thickener. In the present disclosure, the "thickener" refers to a polymeric substance that dissolves or disperses in water at room temperature to produce viscosity. In the present disclosure, the thickener does not contain the above-mentioned reversible heat gelling agent, that is, it does not have reversible heat gelation properties.

増粘剤の15℃における2重量%水溶液の粘度が30mPa・s以上、100mPa・s以上、250mPa・s以上、500mPa・s以上、1000mPa・s以上、2500mPa・s以上、又は5000mPa・s以上であってよく、好ましくは250mPa・s以上である。増粘剤の15℃における2重量%水溶液の粘度が50000mPa・s以下、25000mPa・s以下、10000mPa・s以下、5000mPa・s以下、2500mPa・s以下、1000mPa・s以下、又は500mPa・s以下であってよく、好ましくは25000mPa・s以下である。上記粘度は15℃においてBM型回転粘度計を用いて30rpmの回転速度で10秒後に測定した値である。測定にあたっては粘度域に応じて適切なローター(No.1~4)を用いて測定することが出来る。The viscosity of a 2 wt% aqueous solution of the thickener at 15°C may be 30 mPa·s or more, 100 mPa·s or more, 250 mPa·s or more, 500 mPa·s or more, 1000 mPa·s or more, 2500 mPa·s or more, or 5000 mPa·s or more, preferably 250 mPa·s or more. The viscosity of a 2 wt% aqueous solution of the thickener at 15°C may be 50,000 mPa·s or less, 25,000 mPa·s or less, 10,000 mPa·s or less, 5000 mPa·s or less, 2500 mPa·s or less, 1000 mPa·s or less, or 500 mPa·s or less, preferably 25,000 mPa·s or less. The above viscosity is a value measured after 10 seconds at 15°C using a BM type rotational viscometer at a rotation speed of 30 rpm. The measurement can be performed using an appropriate rotor (No. 1 to 4) depending on the viscosity range.

増粘剤の具体例として、澱粉、澱粉分解物、カルボキシメチルセルロース、キサンタンガム、グァーガム、ローカストビーンガム、ジェランガム、ネイティブジェランガム、タマリンドシードガム、カラギーナン、ペクチン、アルギン酸ナトリウム、海藻粉末、海藻抽出物、グルコマンナン、寒天等が挙げられる。これらの物質は1種単独で用いても良く、2種以上を組み合わせて用いてもよい。 Specific examples of thickeners include starch, starch hydrolysates, carboxymethylcellulose, xanthan gum, guar gum, locust bean gum, gellan gum, native gellan gum, tamarind seed gum, carrageenan, pectin, sodium alginate, seaweed powder, seaweed extract, glucomannan, agar, etc. These substances may be used alone or in combination of two or more.

増粘剤は分散性の観点から澱粉及び澱粉分解物のいずれか一方を含むことが好ましい。特に増粘効果の調整が容易であり、澱粉の分散性を高める効果も得られることから、増粘剤は澱粉と澱粉分解物との両方を含むことが好ましい。From the viewpoint of dispersibility, it is preferable that the thickener contains either starch or a starch hydrolysate. In particular, it is preferable that the thickener contains both starch and a starch hydrolysate, since this makes it easy to adjust the thickening effect and also provides the effect of increasing the dispersibility of starch.

澱粉としては、例えば、コーンスターチ、ワキシーコーンスターチ、ハイアミロースコーンスターチ、タピオカ澱粉、ワキシータピオカ澱粉、小麦澱粉、米澱粉、馬鈴薯澱粉、甘藷澱粉、エンドウ澱粉、緑豆澱粉、サゴ澱粉、クズ澱粉等が挙げられる他、コーングリッツ、小麦粉、米粉、切干甘藷粉末、切干タピオカ粉末等、穀粉に代表される澱粉含有粉末も用いることができる。また、澱粉は加工澱粉であってもよい。加工澱粉は酸化処理、エステル化処理、エーテル化処理、架橋処理、エステル化架橋処理、エーテル化架橋処理といった、化学修飾を施して得られる加工澱粉、アルファ化処理、乾熱処理、湿熱処理、ボールミル処理、微粉砕処理、高電圧電場処理、超音波処理、温水処理、漂白処理、殺菌処理、酸処理、アルカリ処理、酵素処理といった、化学修飾を伴わない加工がなされた加工澱粉等であってよい。澱粉は増粘作用が発現するように、必要によりアルファ化処理、ボールミル処理、焙焼酸処理、焙焼アルカリ処理、酵素処理より選ばれる1以上の加工処理を行ってもよい。Examples of starch include corn starch, waxy corn starch, high amylose corn starch, tapioca starch, waxy tapioca starch, wheat starch, rice starch, potato starch, sweet potato starch, pea starch, mung bean starch, sago starch, and arrowroot starch. In addition, starch-containing powders such as cereal flours, such as corn grits, wheat flour, rice flour, dried sweet potato slices powder, and dried tapioca slices powder, can also be used. The starch may be a processed starch. The processed starch may be a processed starch obtained by chemical modification such as oxidation treatment, esterification treatment, etherification treatment, cross-linking treatment, esterification cross-linking treatment, or etherification cross-linking treatment, or a processed starch that has been processed without chemical modification such as gelatinization treatment, dry heat treatment, wet heat treatment, ball mill treatment, fine pulverization treatment, high voltage electric field treatment, ultrasonic treatment, hot water treatment, bleaching treatment, sterilization treatment, acid treatment, alkali treatment, or enzyme treatment. If necessary, the starch may be subjected to one or more processing treatments selected from gelatinization treatment, ball mill treatment, roasting acid treatment, roasting alkali treatment and enzyme treatment so as to exhibit a thickening effect.

澱粉分解物としては、熱処理、酸処理、アルカリ処理、酸化処理、酵素処理等の方法で分解して得られる可溶性澱粉、デキストリン、マルトデキストリン、水飴等と称されるものが挙げられる。 Examples of starch hydrolysates include soluble starch, dextrin, maltodextrin, starch syrup, etc., which are obtained by hydrolysis using methods such as heat treatment, acid treatment, alkali treatment, oxidation treatment, and enzyme treatment.

増粘剤の量は、可逆熱ゲル化剤100重量部に対して1重量部以上、5重量部以上、10重量部以上、50重量部以上、75重量部以上、100重量部以上、250重量部以上、500重量部以上、750重量部以上、又は1000重量部以上であってよく、好ましくは50重量部以上である。増粘剤の量は、可逆熱ゲル化剤100重量部に対して3000重量部以下、2000重量部以下、1000重量部以下、750重量部以下、500重量部以下、250重量部以下、又は100重量部以下であってよく、好ましくは500重量部以下である。The amount of the thickener may be 1 part by weight or more, 5 parts by weight or more, 10 parts by weight or more, 50 parts by weight or more, 75 parts by weight or more, 100 parts by weight or more, 250 parts by weight or more, 500 parts by weight or more, 750 parts by weight or more, or 1000 parts by weight or more, and preferably 50 parts by weight or more, relative to 100 parts by weight of the reversible heat gelling agent. The amount of the thickener may be 3000 parts by weight or less, 2000 parts by weight or less, 1000 parts by weight or less, 750 parts by weight or less, 500 parts by weight or less, 250 parts by weight or less, or 100 parts by weight or less, and preferably 500 parts by weight or less, relative to 100 parts by weight of the reversible heat gelling agent.

増粘剤中、澱粉の比率は10重量%以上、25重量%以上、35重量%以上、45重量%以上、55重量%以上、65重量%以上、75重量%以上、85重量%以上、又は95重量%以上であってよい。増粘剤中、澱粉の比率は100重量%以下、90重量%以下、80重量%以下、70重量%以下、60重量%以下、50重量%以下、又は40重量%以下であってよい。The proportion of starch in the thickener may be 10% by weight or more, 25% by weight or more, 35% by weight or more, 45% by weight or more, 55% by weight or more, 65% by weight or more, 75% by weight or more, 85% by weight or more, or 95% by weight or more. The proportion of starch in the thickener may be 100% by weight or less, 90% by weight or less, 80% by weight or less, 70% by weight or less, 60% by weight or less, 50% by weight or less, or 40% by weight or less.

増粘剤中、澱粉分解物の比率は10重量%以上、25重量%以上、35重量%以上、45重量%以上、55重量%以上、65重量%以上、75重量%以上、又は85重量%以上であってよい。増粘剤中、澱粉分解物の比率は100重量%以下、90重量%以下、80重量%以下、70重量%以下、60重量%以下、50重量%以下、又は40重量%以下であってよい。The proportion of starch hydrolysates in the thickener may be 10% by weight or more, 25% by weight or more, 35% by weight or more, 45% by weight or more, 55% by weight or more, 65% by weight or more, 75% by weight or more, or 85% by weight or more. The proportion of starch hydrolysates in the thickener may be 100% by weight or less, 90% by weight or less, 80% by weight or less, 70% by weight or less, 60% by weight or less, 50% by weight or less, or 40% by weight or less.

増粘剤が澱粉及び澱粉分解物の両方を含んでもよい。澱粉分解物の量は澱粉100重量部に対して10重量部以上、25重量部以上、50重量部以上、75重量部以上、又は100重量部以上であってよい。澱粉分解物の量は澱粉100重量部に対して、300重量部以下、200重量部以下、150重量部以下、100重量部以下、80重量部以下、60重量部以下、40重量部以下、又は20重量部以下であってよい。The thickener may include both starch and starch hydrolysates. The amount of starch hydrolysates may be 10 parts by weight or more, 25 parts by weight or more, 50 parts by weight or more, 75 parts by weight or more, or 100 parts by weight or more, relative to 100 parts by weight of starch. The amount of starch hydrolysates may be 300 parts by weight or less, 200 parts by weight or less, 150 parts by weight or less, 100 parts by weight or less, 80 parts by weight or less, 60 parts by weight or less, 40 parts by weight or less, or 20 parts by weight or less, relative to 100 parts by weight of starch.

[結晶セルロース]
本開示における食品改質剤はさらに、結晶セルロースを含むことが好ましい。結晶セルロースの構造が、食品改質剤の被覆状態における食材との親和性を高め、表面付着を補助すると考えられる。また、結晶セルロースは水に不溶で耐熱性があるため、可逆熱ゲル化剤が形成するゲル構造を補強することにより、歩留まりを向上させると推定される。結晶セルロースとして、その表面を水溶性高分子でコーティングした結晶セルロース製剤を使用してもよい。結晶セルロース製剤を使用する場合、結晶セルロースの含有率は60%以上であってよく、70%以上が好ましく、80%以上がより好ましい。
[Crystalline Cellulose]
The food modifier of the present disclosure preferably further comprises crystalline cellulose. It is considered that the structure of crystalline cellulose enhances the affinity of the food modifier with foodstuffs in the coated state, and assists surface adhesion. In addition, since crystalline cellulose is insoluble in water and heat-resistant, it is presumed that the gel structure formed by the reversible thermal gelling agent is reinforced, thereby improving yield. As crystalline cellulose, a crystalline cellulose preparation whose surface is coated with a water-soluble polymer may be used. When using a crystalline cellulose preparation, the content of crystalline cellulose may be 60% or more, preferably 70% or more, and more preferably 80% or more.

結晶セルロースの量は、可逆熱ゲル化剤100重量部に対して1重量部以上、5重量部以上、10重量部以上、25重量部以上、50重量部以上、75重量部以上、100重量部以上、200重量部以上、又は300重量部以上であってよく、好ましくは10重量部以上、より好ましくは25重量部以上である。結晶セルロースの量は、可逆熱ゲル化剤100重量部に対して1000重量部以下、750重量部以下、500重量部以下、400重量部以下、300重量部以下、200重量部以下、100重量部以下、又は50重量部以下であってよく、好ましくは500重量部以下、より好ましくは300重量部以下、である。The amount of crystalline cellulose may be 1 part by weight or more, 5 parts by weight or more, 10 parts by weight or more, 25 parts by weight or more, 50 parts by weight or more, 75 parts by weight or more, 100 parts by weight or more, 200 parts by weight or more, or 300 parts by weight or more, preferably 10 parts by weight or more, more preferably 25 parts by weight or more, relative to 100 parts by weight of the reversible heat gelling agent. The amount of crystalline cellulose may be 1000 parts by weight or less, 750 parts by weight or less, 500 parts by weight or less, 400 parts by weight or less, 300 parts by weight or less, 200 parts by weight or less, 100 parts by weight or less, or 50 parts by weight or less, preferably 500 parts by weight or less, more preferably 300 parts by weight or less, relative to 100 parts by weight of the reversible heat gelling agent.

[非増粘性澱粉]
本開示における食品改質剤は、結晶セルロースに代えて又は結晶セルロースに加えて、非増粘性澱粉を含むことが好ましい。非増粘性澱粉は増粘性を示さない澱粉のことであり増粘剤としては機能しない。非増粘性澱粉は、水に難溶で耐熱性が高く、可逆熱ゲル化剤が形成するゲル構造を補強することにより、歩留まりを向上させると推定される。
[Non-thickening starch]
The food modifier of the present disclosure preferably contains non-thickening starch instead of or in addition to crystalline cellulose. Non-thickening starch is starch that does not exhibit thickening properties and does not function as a thickening agent. Non-thickening starch is poorly soluble in water and has high heat resistance, and is presumed to improve yield by reinforcing the gel structure formed by the reversible thermal gelling agent.

非増粘性澱粉の15℃における2重量%液の粘度は0.01mPa・s以上、0.1mPa・s以上、又は1mPa・s以上であってよい。非増粘性澱粉の15℃における2重量%液の粘度は30mPa・s未満、20mPa・s以下、10mPa・s以下、5mPa・s以下、2.5mPa・s以下、又は1mPa・s以下であってよく、好ましくは10mPa・s以下である。上記粘度は15℃においてBM型回転粘度計を用いて30rpmの回転速度で10秒後に測定した値である。測定にあたっては粘度域に応じて適切なローター(No.1~4)を用いて測定することが出来る。The viscosity of a 2 wt% solution of non-thickening starch at 15°C may be 0.01 mPa·s or more, 0.1 mPa·s or more, or 1 mPa·s or more. The viscosity of a 2 wt% solution of non-thickening starch at 15°C may be less than 30 mPa·s, 20 mPa·s or less, 10 mPa·s or less, 5 mPa·s or less, 2.5 mPa·s or less, or 1 mPa·s or less, preferably 10 mPa·s or less. The above viscosity is the value measured after 10 seconds at 15°C using a BM type rotational viscometer at a rotation speed of 30 rpm. The measurement can be performed using an appropriate rotor (No. 1 to 4) depending on the viscosity range.

非増粘性澱粉は非増粘性を示すために澱粉に非増粘処理を施したものであってよい。 Non-thickening starch may be starch that has been subjected to a non-thickening treatment to exhibit non-thickening properties.

非増粘処理は、非増粘性を示すことができれば、特に限定されないが、典型的には架橋処理である。架橋処理の例としては、リン酸架橋処理、アセチル化アジピン酸架橋処理で代表されるエステル化架橋処理、ヒドロオキシプロピル架橋処理で代表されるエーテル化架橋処理、等が挙げられる。架橋処理に用いられる架橋剤の例としては、トリメタリン酸ナトリウム、メタリン酸塩、トリメタリン酸ナトリウム/トリポリリン酸ナトリウム、オキシ塩化リン、アジピン酸/酢酸混合無水物、エピクロロヒドリン、アクロレイン、シアヌリッククロライド、ホルムアルデヒド、グリオキザール、アジピン酸ジヒドラジド、ジイソシアネート、ビスエチレン尿素、ジアルデヒド化合物、ジエポキシド化合物、ポリエポキシド化合物、及びそれらの組合せ等が挙げられる。The non-thickening treatment is not particularly limited as long as it can exhibit non-thickening properties, but is typically a crosslinking treatment. Examples of crosslinking treatments include phosphate crosslinking treatment, esterification crosslinking treatment represented by acetylated adipic acid crosslinking treatment, and etherification crosslinking treatment represented by hydroxypropyl crosslinking treatment. Examples of crosslinking agents used in crosslinking treatments include sodium trimetaphosphate, metaphosphates, sodium trimetaphosphate/sodium tripolyphosphate, phosphorus oxychloride, adipic acid/acetic acid mixed anhydride, epichlorohydrin, acrolein, cyanuric chloride, formaldehyde, glyoxal, adipic acid dihydrazide, diisocyanate, bisethylene urea, dialdehyde compounds, diepoxide compounds, polyepoxide compounds, and combinations thereof.

非増粘性澱粉の原料澱粉の種類は特に限定されず、コーンスターチ、ワキシーコーンスターチ、ハイアミロースコーンスターチ、タピオカ澱粉、ワキシータピオカ澱粉、小麦澱粉、米澱粉、馬鈴薯澱粉、甘藷澱粉、エンドウ澱粉、緑豆澱粉、サゴ澱粉、クズ澱粉等が挙げられる他、コーングリッツ、小麦粉、米粉、切干甘藷粉末、切干タピオカ粉末等、穀粉に代表される澱粉を使用することができる。 The type of raw starch for non-thickening starch is not particularly limited, and examples include corn starch, waxy corn starch, high amylose corn starch, tapioca starch, waxy tapioca starch, wheat starch, rice starch, potato starch, sweet potato starch, pea starch, mung bean starch, sago starch, kudzu starch, etc., as well as starches represented by grain flours such as corn grits, wheat flour, rice flour, dried sweet potato powder, and dried tapioca powder.

非増粘性澱粉は、加工処理、例えば、酸化処理、エステル化処理、エーテル化処理等の化学加工処理、アルファ化処理、乾熱処理、湿熱処理、ボールミル処理、微粉砕処理、高電圧電場処理、超音波処理、温水処理、漂白処理、殺菌処理、酸処理、アルカリ処理、酵素処理といった化学修飾を伴わない加工処理を施されていてもよく、好ましくはアルファ化処理が施されている。 Non-thickening starch may have been subjected to processing treatments that do not involve chemical modification, such as chemical processing treatments such as oxidation treatment, esterification treatment, and etherification treatment, gelatinization treatment, dry heat treatment, wet heat treatment, ball mill treatment, fine grinding treatment, high-voltage electric field treatment, ultrasonic treatment, hot water treatment, bleaching treatment, sterilization treatment, acid treatment, alkali treatment, and enzyme treatment, and is preferably subjected to gelatinization treatment.

非増粘性澱粉の量は、可逆熱ゲル化剤100重量部に対して1重量部以上、5重量部以上、10重量部以上、25重量部以上、50重量部以上、75重量部以上、100重量部以上、200重量部以上、又は300重量部以上であってよく、好ましくは10重量部以上、より好ましくは25重量部以上である。非増粘性澱粉の量は、可逆熱ゲル化剤100重量部に対して1000重量部以下、750重量部以下、500重量部以下、400重量部以下、300重量部以下、200重量部以下、100重量部以下、又は50重量部以下であってよく、好ましくは500重量部以下、より好ましくは300重量部以下、である。The amount of non-thickening starch may be 1 part by weight or more, 5 parts by weight or more, 10 parts by weight or more, 25 parts by weight or more, 50 parts by weight or more, 75 parts by weight or more, 100 parts by weight or more, 200 parts by weight or more, or 300 parts by weight or more, preferably 10 parts by weight or more, more preferably 25 parts by weight or more, based on 100 parts by weight of the reversible heat gelling agent. The amount of non-thickening starch may be 1000 parts by weight or less, 750 parts by weight or less, 500 parts by weight or less, 400 parts by weight or less, 300 parts by weight or less, 200 parts by weight or less, 100 parts by weight or less, or 50 parts by weight or less, based on 100 parts by weight of the reversible heat gelling agent, preferably 500 parts by weight or less, more preferably 300 parts by weight or less.

非増粘性澱粉と結晶セルロースの両方が食品改質剤に含まれていてもよい。非増粘性澱粉と結晶セルロースの合計中、非増粘性澱粉の比率は、1重量%以上、3重量%以上、5重量%以上、10重量%以上、20重量%以上、30重量%以上、50重量%以上、80重量%以上、90重量%以上であってよい。非増粘性澱粉と結晶セルロースの合計中、非増粘性澱粉の比率は、99重量%以下、75重量%以下、50重量%以下、25重量%以下、10重量%以下、又は5重量%以下であってよい。Both non-thickening starch and crystalline cellulose may be included in the food modifier. The ratio of non-thickening starch in the total of non-thickening starch and crystalline cellulose may be 1% by weight or more, 3% by weight or more, 5% by weight or more, 10% by weight or more, 20% by weight or more, 30% by weight or more, 50% by weight or more, 80% by weight or more, 90% by weight or more. The ratio of non-thickening starch in the total of non-thickening starch and crystalline cellulose may be 99% by weight or less, 75% by weight or less, 50% by weight or less, 25% by weight or less, 10% by weight or less, or 5% by weight or less.

[その他成分]
本開示の食品改質剤には、その効果を阻害しない範囲で、乳酸カルシウム、塩化ナトリウム、グルタミン酸ナトリウム、みりん、料理酒等の調味料、砂糖、果糖、ぶどう糖、水飴、はちみつ、キシロース、乳糖、異性化糖、アスパルテーム、ステビア、グリシン、アラニン、ソーマチン、サッカリン等の甘味料、ソルビトール、マルチトール、キシリトール等、還元水飴、還元澱粉分解物等の糖アルコール、オールスパイス、ペッパー、ナツメグ、メース等の香辛料、安息香酸ナトリウム、ソルビン酸、パラオキシ安息香酸エステル等の保存料、還元デキストリン、還元オリゴ糖、還元水飴等の還元澱粉分解物、環状デキストリン、グリセリン、ヒアルロン酸、イヌリン等の製造用剤、アスコルビン酸、アスコルビン酸カルシウム、ミックストコフェロール、カテキン等の酸化防止剤、オクテニルコハク酸澱粉ナトリウム、レシチン、グリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル等の乳化剤、酢酸カルシウム、グルコン酸カルシウム、塩化カルシウム、貝カルシウム等の強化剤、大豆タンパク、乾燥卵白、小麦グルテン、乳タンパク、血漿タンパク製剤等のタンパク質、カラメル色素、クチナシ色素、カロテノイド色素、コチニール色素等の着色料、香料等を併用してもよい。
[Other ingredients]
The food modifier of the present disclosure may include, within a range that does not inhibit the effects of the food modifier, seasonings such as calcium lactate, sodium chloride, sodium glutamate, mirin, and cooking sake; sweeteners such as sugar, fructose, glucose, starch syrup, honey, xylose, lactose, isomerized sugar, aspartame, stevia, glycine, alanine, thaumatin, and saccharin; sugar alcohols such as sorbitol, maltitol, and xylitol, reduced starch syrup, and reduced starch hydrolysates; spices such as allspice, pepper, nutmeg, and mace; preservatives such as sodium benzoate, sorbic acid, and paraoxybenzoic acid esters; reduced starch components such as reduced dextrin, reduced oligosaccharides, and reduced starch syrup. Manufacturing agents such as hydrolysates, cyclic dextrin, glycerin, hyaluronic acid, inulin, etc., antioxidants such as ascorbic acid, calcium ascorbate, mixed tocopherols, catechin, etc., emulsifiers such as starch sodium octenylsuccinate, lecithin, glycerin fatty acid esters, sucrose fatty acid esters, sorbitan fatty acid esters, etc., strengthening agents such as calcium acetate, calcium gluconate, calcium chloride, shellfish calcium, etc., proteins such as soy protein, dried egg white, wheat gluten, milk protein, plasma protein preparations, etc., coloring agents such as caramel color, gardenia color, carotenoid color, cochineal color, etc., fragrances, etc. may also be used in combination.

[食品改質剤の粘度特性]
食品改質剤に水を加えて撹拌混合して固形分5重量%となるように調製した食品改質剤液の15℃における粘度は、30mPa・s以上、100mPa・s以上、250mPa・s以上、300mPa・s以上、500mPa・s以上、1000mPa・s以上、2500mPa・s以上、又は5000mPa・s以上であってよく、好ましくは250mPa・s以上、より好ましくは1000mPa・s以上である。食品改質剤に水を加えて撹拌混合して、固形分5重量%となるように調製した食品改質剤液の15℃における粘度は、50000mPa・s以下、25000mPa・s以下、10000mPa・s以下、5000mPa・s以下、2500mPa・s以下、1000mPa・s以下、又は500mPa・s以下であってよく、好ましくは10000mPa・s以下、より好ましくは5000mPa・sである。粘度範囲が上記範囲にあることが実用上の歩留まり向上性や作業性の観点から適切である。上記粘度は15℃においてBM型回転粘度計を用いて30rpmの回転速度で10秒後に測定した値である。測定にあたっては粘度域に応じて適切なローター(No.1~4)を用いて測定することが出来る。例えば、粘度は公知の方法により調整できる。例えば、増粘剤の組み合わせや添加量により粘度調整できる。また、粘度調整は粉砕化・造粒等の手段により、改質剤の粒径又は分散性を変化させることにより、行われてもよい。ここで、粉体化・造粒の方法としては、特に限定されず、凍結粉砕、乾式粉砕、湿式粉砕、低温粉砕、篩押出造粒、攪拌造粒、流動層造粒、転動造粒、シート造粒、乾式造粒、スプレードライ、真空ドラムドライ等が挙げられる。
[Viscosity characteristics of food modifiers]
The viscosity at 15°C of a food modifier liquid prepared by adding water to the food modifier and stirring and mixing to give a solids content of 5% by weight may be 30 mPa·s or more, 100 mPa·s or more, 250 mPa·s or more, 300 mPa·s or more, 500 mPa·s or more, 1000 mPa·s or more, 2500 mPa·s or more, or 5000 mPa·s or more, preferably 250 mPa·s or more, and more preferably 1000 mPa·s or more. The viscosity of the food modifier liquid at 15°C prepared by adding water to the food modifier and stirring and mixing to a solid content of 5% by weight may be 50,000 mPa·s or less, 25,000 mPa·s or less, 10,000 mPa·s or less, 5,000 mPa·s or less, 2500 mPa·s or less, 1000 mPa·s or less, or 500 mPa·s or less, preferably 10,000 mPa·s or less, more preferably 5,000 mPa·s. It is appropriate for the viscosity range to be within the above range from the viewpoint of practical yield improvement and workability. The above viscosity is a value measured after 10 seconds at 15°C using a BM type rotational viscometer at a rotation speed of 30 rpm. The measurement can be performed using an appropriate rotor (No. 1 to 4) depending on the viscosity range. For example, the viscosity can be adjusted by a known method. For example, the viscosity can be adjusted by the combination or amount of thickener added. The viscosity may be adjusted by changing the particle size or dispersibility of the modifier by means of pulverization, granulation, etc. Here, the method of pulverization and granulation is not particularly limited, and examples thereof include freeze pulverization, dry pulverization, wet pulverization, low-temperature pulverization, sieve extrusion granulation, stirring granulation, fluidized bed granulation, rolling granulation, sheet granulation, dry granulation, spray drying, vacuum drum drying, etc.

[食品改質剤の用途]
上述の可逆熱ゲル化剤を含む食品改質剤は、食品改質時に食品に添加され、食品改質後には除去可能な食品改質剤であることが好ましい。特に本開示における食品改質剤は、下記の改質食品の製造方法の説明にあるように、食品改質の際の食品被覆に用いられることが好適であり、特に加熱による食品改質の際の食品被覆に好適に用いられる。食品改質剤は食品改質後には除去されてもよいし、食品改質後に除去されずにさらなる食品改質工程(食品加工工程)に供されたり、食品の最終形態に存在したりしてもよい。食品改質剤の除去の方法は、洗浄による除去であってよい。
[Food modifier applications]
The food modifier containing the above-mentioned reversible thermal gelling agent is preferably a food modifier that is added to food during food modification and can be removed after food modification. In particular, the food modifier in the present disclosure is preferably used for food coating during food modification, as described in the following method for producing modified food, and is particularly preferably used for food coating during food modification by heating. The food modifier may be removed after food modification, or may be used in a further food modification step (food processing step) without being removed after food modification, or may be present in the final form of the food. The method for removing the food modifier may be removal by washing.

<改質食品の製造方法>
本開示における改質食品の製造方法は食品改質剤に水を加えて撹拌混合して食品改質剤液を得る工程(1)、食品を前記食品改質剤液で被覆して被覆食品を得る工程(2)、及び前記被覆食品を可逆熱ゲル化剤の熱ゲル化温度以上で加熱する工程(3)を含む。本開示における改質食品の製造方法はさらに前記被覆食品を水で洗浄する工程(4)を含んでよい
<Method of manufacturing modified food>
The method for producing modified foods in the present disclosure includes the steps of (1) adding water to a food modifier and stirring to obtain a food modifier liquid, (2) coating a food with the food modifier liquid to obtain a coated food, and (3) heating the coated food at a temperature equal to or higher than the thermal gelling temperature of the reversible thermal gelling agent. The method for producing modified foods in the present disclosure may further include the step of (4) washing the coated food with water.

[食品改質剤液を得る工程(1)]
本開示における改質食品の製造方法は食品改質剤に水を加えて撹拌混合して食品改質剤液を得る工程(1)を含む。上述した食品改質剤に水を加えて撹拌混合することで食品改質剤液を作成することができる。食品改質剤液の粘度は、30mPa・s以上、100mPa・s以上、250mPa・s以上、300mPa・s以上、500mPa・s以上、1000mPa・s以上、2500mPa・s以上、又は5000mPa・s以上であってよく、好ましくは250mPa・s以上、より好ましくは300mPa・s以上である。食品改質剤液の粘度は、50000mPa・s以下、25000mPa・s以下、10000mPa・s以下、5000mPa・s以下、2500mPa・s以下、1000mPa・s以下、又は500mPa・s以下であってよく、好ましくは10000mPa・s以下、より好ましくは5000mPa・sである。粘度範囲が上記範囲にあることが実用上の歩留まり向上性や作業性の観点から適切である。上記粘度は15℃においてBM型回転粘度計を用いて30rpmの回転速度で10秒後に測定した値である。測定にあたっては粘度域に応じて適切なローター(No.1~4)を用いて測定することが出来る。
[Step (1) of obtaining food modifier liquid]
The method for producing modified foods in the present disclosure includes a step (1) of adding water to a food modifier and stirring and mixing to obtain a food modifier liquid. The food modifier liquid can be produced by adding water to the above-mentioned food modifier and stirring and mixing. The viscosity of the food modifier liquid may be 30 mPa·s or more, 100 mPa·s or more, 250 mPa·s or more, 300 mPa·s or more, 500 mPa·s or more, 1000 mPa·s or more, 2500 mPa·s or more, or 5000 mPa·s or more, preferably 250 mPa·s or more, more preferably 300 mPa·s or more. The viscosity of the food modifier liquid may be 50,000 mPa·s or less, 25,000 mPa·s or less, 10,000 mPa·s or less, 5,000 mPa·s or less, 2500 mPa·s or less, 1000 mPa·s or less, or 500 mPa·s or less, preferably 10,000 mPa·s or less, more preferably 5,000 mPa·s. The viscosity range in the above range is appropriate from the viewpoint of practical yield improvement and workability. The above viscosity is a value measured after 10 seconds at 15°C using a BM type rotational viscometer at a rotation speed of 30 rpm. The measurement can be performed using an appropriate rotor (No. 1 to 4) depending on the viscosity range.

食品改質剤液における水分量は食品改質剤液の粘度を上記範囲に調節するために適宜調節できる。食品改質剤液における水分量は、50重量%以上、75重量%以上、85重量%以上、90重量%以上、92.5重量%以上、95重量%以上、又は97.5重量%以上であってよく、好ましくは90重量%以上である。食品改質剤液における水分量は、99重量%以下、98重量%以下、96重量%以下、94重量%以下、92重量%以下、90重量%以下、85重量%以下、75重量%以下であってよく、好ましくは98重量%以下である。The amount of water in the food modifier liquid can be adjusted appropriately to adjust the viscosity of the food modifier liquid to the above range. The amount of water in the food modifier liquid may be 50% by weight or more, 75% by weight or more, 85% by weight or more, 90% by weight or more, 92.5% by weight or more, 95% by weight or more, or 97.5% by weight or more, and is preferably 90% by weight or more. The amount of water in the food modifier liquid may be 99% by weight or less, 98% by weight or less, 96% by weight or less, 94% by weight or less, 92% by weight or less, 90% by weight or less, 85% by weight or less, 75% by weight or less, and is preferably 98% by weight or less.

食品改質剤液における固形分量は食品改質剤液の粘度を上記範囲に調節するために適宜調節できる。食品改質剤液における固形分量は、1重量%以上、2重量%以上、4重量%以上、6重量%以上、8重量%以上、10重量%以上、15重量%以上、又は25重量%以上であってよく、好ましくは2重量%以上である。食品改質剤液における固形分量は、50重量%以下、25重量%以下、15重量%以下、10重量%以下、7.5重量%以下、5重量%以下、又は2.5重量%以下であってよく、好ましくは10重量%以下である。The amount of solids in the food modifier liquid can be adjusted appropriately to adjust the viscosity of the food modifier liquid to the above range. The amount of solids in the food modifier liquid may be 1% by weight or more, 2% by weight or more, 4% by weight or more, 6% by weight or more, 8% by weight or more, 10% by weight or more, 15% by weight or more, or 25% by weight or more, preferably 2% by weight or more. The amount of solids in the food modifier liquid may be 50% by weight or less, 25% by weight or less, 15% by weight or less, 10% by weight or less, 7.5% by weight or less, 5% by weight or less, or 2.5% by weight or less, preferably 10% by weight or less.

食品改質剤液のpHは中性、弱酸性又は弱アルカリ性であってよい。食品改質剤液のpHは5.0以上、6.0以上、6.5以上、6.7以上、又は6.9以上であってよい。食品改質剤液のpHは9.0以下、8.0以下、7.5以下、8.0以下、7.3以下、又は7.1以下であってよい。The pH of the food modifier liquid may be neutral, weakly acidic or weakly alkaline. The pH of the food modifier liquid may be 5.0 or more, 6.0 or more, 6.5 or more, 6.7 or more, or 6.9 or more. The pH of the food modifier liquid may be 9.0 or less, 8.0 or less, 7.5 or less, 8.0 or less, 7.3 or less, or 7.1 or less.

[被覆食品を得る工程(2)]
本開示における改質食品の製造方法は食品を前記食品改質剤液で被覆して被覆食品を得る工程(2)を含む。食品を前記食品改質剤液で被覆する方法は、限定されないが、食品改質剤液に食品を浸漬する浸漬塗布であってよい。浸漬塗布を用いることが好ましいが、その他の方法として、食品改質剤液に食品を噴霧する方法、インジェクションによる方法、食品改質剤を粉末のままで食品に添加する方法も可能である。
[Step (2) of obtaining coated food]
The method for producing modified foods in the present disclosure includes a step (2) of coating a food with the food modifier liquid to obtain a coated food. The method for coating a food with the food modifier liquid is not limited, but may be a dip coating method in which the food is immersed in the food modifier liquid. Although dip coating is preferably used, other methods include a method of spraying the food in the food modifier liquid, a method using an injection method, and a method of adding the food modifier in powder form to the food.

本開示における「食品」とは、例えば、牛肉、豚肉、鶏肉、羊肉、馬肉、猪肉等の畜肉食品や、エビ、イカ、タコ、白身魚、赤身魚、カニ、ホタテ、アワビ等の水産食品、なめこ、しいたけ、まいたけ、えのき、エリンギ、ブナシメジ、マッシュルーム等のきのこ類、ブロッコリー、カリフラワー、キャベツ、アスパラガス、タマネギ、ハクサイ、レタス等の葉菜類、ジャガイモ、サツマイモ、ダイコン、ニンジン、サトイモ、ゴボウ等の根菜類等が挙げられる。畜肉食品や水産食品については、切断、挽肉、すり身等の加工処理が施された食品、例えば、ソーセージ、ハム、カマボコ、ちくわ、はんぺん等を含む。加熱処理後の食品を、さらなる加工食品の原材料として使用する場合、あらかじめ使用する加工食品の原材料として好ましい大きさにカットしてあってもよい。 In the present disclosure, "food" refers to, for example, meat products such as beef, pork, chicken, lamb, horse meat, and wild boar meat; seafood products such as shrimp, squid, octopus, white fish, red fish, crab, scallops, and abalone; mushrooms such as nameko, shiitake, maitake, enoki, king oyster mushroom, buna shimeji, and mushrooms; leafy vegetables such as broccoli, cauliflower, cabbage, asparagus, onion, Chinese cabbage, and lettuce; and root vegetables such as potato, sweet potato, radish, carrot, taro, and burdock. Meat products and seafood products include foods that have been processed, such as cut, ground, or surimi, for example, sausage, ham, kamaboko, chikuwa, and hanpen. When the heat-treated food is used as a raw material for further processed foods, it may be cut into a size that is preferred as the raw material for the processed food to be used.

食品改質剤液に食品を浸漬する時間は食品の形態によって異なってよく、1秒以上、15秒以上、30秒以上、1分以上、10分以上、1時間以上、又は12時間以上であってよく、24時間以内、15時間以内、5時間以内、30分以内、5分以内、1分以内、又は30秒以内であってよい。本開示における食品改質剤は浸漬時間が短い(例えば、1分未満)場合であっても、歩留まり向上や外観の保持といった本開示の目的を達成することが出来る点において非常に優れている。The time for immersing the food in the food modifier liquid may vary depending on the form of the food, and may be 1 second or more, 15 seconds or more, 30 seconds or more, 1 minute or more, 10 minutes or more, 1 hour or more, or 12 hours or more, or 24 hours or less, 15 hours or less, 5 hours or less, 30 minutes or less, 5 minutes or less, 1 minute or less, or 30 seconds or less. The food modifiers disclosed herein are excellent in that they can achieve the objectives of the present disclosure, such as improving yield and maintaining appearance, even when the immersion time is short (e.g., less than 1 minute).

食品改質剤液に食品を浸漬する際の食品改質剤液の温度は、0℃以上、3℃以上、10℃以上、15℃以上、又は20℃以上であってよく、40℃以下、30℃以下、25℃以下、20℃以下、15℃以下、10℃以下、又は5℃以下であってよい。長時間浸漬における、食品の変質、雑菌の繁殖の恐れを抑制する観点から、低温(例えば15℃以下、10℃以下)であってよい。 The temperature of the food modifier liquid when immersing food in the food modifier liquid may be 0°C or higher, 3°C or higher, 10°C or higher, 15°C or higher, or 20°C or higher, and may be 40°C or lower, 30°C or lower, 25°C or lower, 20°C or lower, 15°C or lower, 10°C or lower, or 5°C or lower. From the viewpoint of preventing deterioration of the food and the risk of bacterial growth during long-term immersion, the temperature may be low (e.g., 15°C or lower, 10°C or lower).

[被覆食品を加熱する工程(3)]
本開示における改質食品の製造方法は被覆食品を熱ゲル化温度以上で加熱する工程(3)を含む。熱ゲル化剤の熱ゲル化作用を発現させるために、加熱温度は熱ゲル化剤の熱ゲル化温度以上である。加熱温度は熱ゲル化温度よりも1℃以上、3℃以上、5℃以上、10℃以上、15℃以上、20℃以上、25℃以上高くてもよい。加熱時間は食品及び食品の加工目的によって適宜決定されてよい。
[Step (3) of heating the coated food]
The method for producing a modified food product according to the present disclosure includes a step (3) of heating the coated food product at or above the thermal gelation temperature. In order to exert the thermal gelling action of the thermal gelling agent, the heating temperature is equal to or above the thermal gelation temperature of the thermal gelling agent. The heating temperature may be higher than the thermal gelation temperature by 1° C. or more, 3° C. or more, 5° C. or more, 10° C. or more, 15° C. or more, 20° C. or more, or 25° C. or more. The heating time may be appropriately determined depending on the food product and the purpose of processing the food product.

被覆食品の加熱方法としては、焼成、揚げ、ゆで、蒸し、電子レンジによる加熱、燻製、燻煙等が挙げられるが、本開示に好適な加熱方法としては、茹で、又は蒸しが挙げられる。 Methods for heating coated foods include baking, frying, boiling, steaming, heating in a microwave oven, smoking, etc., but the heating methods preferred for this disclosure include boiling or steaming.

[前記被覆食品を水洗浄する工程(4)]
本開示における改質食品の製造方法は、上記加熱後において、前記被覆食品を水で洗浄する工程(4)を含んでよい。洗浄に用いる水の温度は、0℃以上、3℃以上、10℃以上、15℃以上、又は20℃以上であってよく、40℃以下、30℃以下、25℃以下、20℃以下、15℃以下、10℃以下、又は5℃以下であってよい。
[Step (4) of washing the coated food with water]
The method for producing the modified food product of the present disclosure may include a step (4) of washing the coated food product with water after the heating. The temperature of the water used for washing may be 0° C. or higher, 3° C. or higher, 10° C. or higher, 15° C. or higher, or 20° C. or higher, and may be 40° C. or lower, 30° C. or lower, 25° C. or lower, 20° C. or lower, 15° C. or lower, 10° C. or lower, or 5° C. or lower.

<作用効果>
本開示によれば、加熱によって食品から流出する水分や油分を防ぎ、歩留まりを向上させたり、食品の外観を綺麗に保持したり、食品のもつ食感やぬめり感等の特性が失われるのを防ぐ効果がある。本方法の原理を説明すると、食品改質剤に水を加える際、増粘剤の効果により食品改質剤液に粘度が発現することで、食品への付着が容易になり、液だれし難くする効果が得られる。さらに、結晶セルロースの作用によって食品との親和性が高まり、付着作用をより強固にする。食品改質剤液に食品を浸した後、加熱を行っていくと、可逆熱ゲル化剤の作用で、食品改質剤液がゲル化を始める。ゲル化した食品改質剤液が食品を被覆することにより、食品内部への加熱が緩やかに行われ、急激な温度変化によるドリップ(水分や油分の流出)を防ぐことが出来る他、食品の外観が損なわれてしまうのを防ぐ効果が得られる。また、結晶セルロースがゲル構造を補強することで、加熱の最中に食品改質剤液が剥がれるのを防ぐ作用がある。食品との加熱後、食品を冷水で洗い流すことによりゲルの温度が低下し、可逆熱ゲル化剤が形成するゲルがほどけ、被覆されていた食品改質剤が食品から離れることで、食品改質剤そのものを食すことなく、本開示の目的を達成することが出来る。
<Action and effect>
According to the present disclosure, the method has the effect of preventing moisture and oil from flowing out of food due to heating, improving yield, maintaining the appearance of the food clean, and preventing the loss of characteristics such as texture and sliminess of the food. The principle of the method is as follows: when water is added to the food modifier, the viscosity of the food modifier liquid is generated by the effect of the thickener, making it easier to adhere to the food and less likely to drip. Furthermore, the affinity with the food is increased by the action of the crystalline cellulose, making the adhesion stronger. When the food is immersed in the food modifier liquid and heated, the food modifier liquid begins to gel due to the action of the reversible thermal gelling agent. The gelled food modifier liquid covers the food, so that the inside of the food is heated slowly, preventing dripping (flow of moisture and oil) due to sudden temperature changes, and preventing the appearance of the food from being damaged. In addition, the crystalline cellulose reinforces the gel structure, preventing the food modifier liquid from peeling off during heating. After heating with the food, the temperature of the gel is reduced by rinsing the food with cold water, the gel formed by the reversible thermal gelling agent unravels, and the coated food modifier becomes detached from the food, thereby achieving the object of the present disclosure without having to eat the food modifier itself.

以下、実施例に基づいて本開示を更に詳細に説明する。なお、以下に説明する実施例は、本開示の代表的な実施例の一例を示したものであり、本開示は以下の実施例に限定されるものではない。また、特に記載のない限り、「部」とは「重量部」を意味するものとする。The present disclosure will be described in further detail below based on examples. Note that the examples described below are representative examples of the present disclosure, and the present disclosure is not limited to the following examples. In addition, unless otherwise specified, "parts" refers to "parts by weight."

<甘えび>
[実施例1]
(食品改質剤液の調製)
可逆熱ゲル化剤としてメチルセルロース(メトローズMCE-4000:信越化学工業株式会社製)2.0部を、増粘剤として馬鈴薯澱粉をドラムドライヤーで乾燥し粉砕して14meshを通過したアルファ化澱粉2.0部及び馬鈴薯澱粉を酵素処理により分解した澱粉分解物(分散剤)1.0部を、粉体の状態で混合し、食品改質剤とした。15℃の冷水を、食品改質剤と合わせて100部になるように加え、すぐに撹拌混合した。得られた食品改質剤液(以下、単に「液」と表記することがある)を、液1とした。液1の粘度を、15℃においてBM型回転粘度計(VISCOMETER MODEL BMII;東機産業株式会社製)を用いて30rpmの回転速度で10秒後に測定した。また、pHメーター(LAQUA F-71S;株式会社堀場製作所製)を用いて、液1のpHを測定した。
<Sweet shrimp>
[Example 1]
(Preparation of food modifier liquid)
2.0 parts of methylcellulose (Metolose MCE-4000: manufactured by Shin-Etsu Chemical Co., Ltd.) as a reversible heat gelling agent, 2.0 parts of pregelatinized starch obtained by drying potato starch in a drum dryer, pulverizing it and passing it through a 14 mesh as a thickening agent, and 1.0 parts of starch hydrolyzate (dispersant) obtained by enzymatically decomposing potato starch were mixed in the powder state to obtain a food modifier. 15°C cold water was added to the food modifier so that the total amount was 100 parts, and the mixture was immediately stirred and mixed. The obtained food modifier liquid (hereinafter sometimes simply referred to as "liquid") was named Liquid 1. The viscosity of Liquid 1 was measured after 10 seconds at a rotation speed of 30 rpm using a BM type rotational viscometer (VISCOMETER MODEL BMII; manufactured by Toki Sangyo Co., Ltd.) at 15°C. In addition, the pH of Liquid 1 was measured using a pH meter (LAQUA F-71S; manufactured by Horiba, Ltd.).

(浸漬)
生のホッコクアカエビ(以下、甘えびと表記。2.0~3.0g/匹)の殻と尾を取り、重量を測定した。重量測定後の甘えびを液1に1分間浸漬した。
(Immersion)
The shells and tails of raw northern red shrimp (hereinafter referred to as sweet shrimp, 2.0 to 3.0 g/piece) were removed and the shrimp were weighed. After the weight measurement, the sweet shrimp was immersed in Liquid 1 for 1 minute.

(ボイル槽への投入)
液1に浸漬した甘えびを、90±2℃に調整したボイル槽に投入した。30秒間ボイルし、その後甘えびの周りを被覆している液1を流水で洗浄した。甘えびの形が崩れない程度に網で水を切り、重量を測定した。[ボイル前の重量測定、浸漬、ボイル槽への投入、流水洗浄、水切り、ボイル・洗浄後の重量測定]の一連の操作を独立に3回行った。液1を用いて一連の操作を行ったものを、実施例1とした。
(Adding to boiling tank)
The shrimp immersed in Liquid 1 were placed in a boiling tank adjusted to 90±2°C. The shrimp were boiled for 30 seconds, after which the Liquid 1 covering the shrimp was washed with running water. The shrimp were drained using a net so that their shape was not distorted, and their weight was measured. The series of operations of [weight measurement before boiling, immersion, placement in the boiling tank, washing with running water, draining, and weight measurement after boiling and washing] was carried out three times independently. The series of operations carried out using Liquid 1 was designated Example 1.

[比較例1]
食品改質剤液を用いずに甘えびをそのままボイル槽に投入した以外は実施例1と同様の方法で一連の操作を行ったものを、比較例1とした。なお、ボイル後の甘えびには液が付着していないが、流水で洗浄する工程は実施例1と同様に行った。
[Comparative Example 1]
A series of operations was carried out in the same manner as in Example 1, except that the sweet shrimp was directly put into the boiling tank without using the food modifier liquid, and this was used as Comparative Example 1. Although no liquid was attached to the sweet shrimp after boiling, the process of washing them with running water was carried out in the same manner as in Example 1.

[実施例2]
実施例1と同様の方法で、メチルセルロースを1.0部、アルファ化澱粉を4.0部に変更して食品改質剤液を調製した実施例2の組成について、実施例1とともに表1に示した。なお、実施例2に対応する、食品改質剤と冷水の混合液を液2とした。
[Example 2]
The composition of Example 2, in which a food modifier liquid was prepared in the same manner as in Example 1, except that the amount of methyl cellulose was changed to 1.0 part and the amount of pregelatinized starch was changed to 4.0 parts, is shown in Table 1 together with that of Example 1. The mixture of food modifier and cold water corresponding to Example 2 was designated as Liquid 2.

[実施例3~10]
実施例1と同様の方法で、さらに結晶セルロース製剤を追加して試験を行った。結晶セルロース製剤としてセオラスRC-591S(旭化成株式会社製、結晶セルロースを89%含む)、あるいはセオラスCL-611S(旭化成株式会社製、結晶セルロースを85%含む)を用いた。メチルセルロース、結晶セルロース製剤、アルファ化澱粉の量を変更して液を調製した、実施例3~10の組成について、表1に示した。なお、実施例3~10に対応する、食品改質剤と冷水の混合液を、それぞれ液3~10とした。
[Examples 3 to 10]
A test was conducted by adding a crystalline cellulose preparation in the same manner as in Example 1. As the crystalline cellulose preparation, CEOLUS RC-591S (manufactured by Asahi Kasei Corporation, containing 89% crystalline cellulose) or CEOLUS CL-611S (manufactured by Asahi Kasei Corporation, containing 85% crystalline cellulose) was used. The compositions of Examples 3 to 10, in which the amounts of methylcellulose, crystalline cellulose preparation, and pregelatinized starch were changed to prepare the liquids, are shown in Table 1. The mixed liquids of food modifier and cold water corresponding to Examples 3 to 10 were designated as Liquids 3 to 10, respectively.

Figure 0007480949000001
Figure 0007480949000001

[評価]
歩留まり向上とボイル・洗浄後の甘えびの外観を下記基準で評価した。歩留まり率は、重量測定器としてEK-410i(株式会社エー・アンド・デイ製)を使用し、ボイル前の平均重量とボイル・洗浄後の平均重量との重量変化率として定義した。
(歩留まり向上の評価基準)
◎:比較例1を基準とした際の歩留まり率の向上が6ポイント以上である。
○:比較例1を基準とした際の歩留まり率の向上が3ポイント以上6ポイント未満である。
△:比較例1を基準とした際の歩留まり率の向上が0ポイント以上3ポイント未満である。
×:比較例1を基準とした際の歩留まり率の向上が0ポイント未満である。
(外観の評価基準)
◎:身の剥がれが全くなく(全長の0%)、非常に良好。
○:わずかに身の剥がれが見られるが(全長の5%未満)、良好。
×:身の剥がれが目立ち(全長の5%以上)、不良。
[evaluation]
The yield improvement and the appearance of the shrimp after boiling and washing were evaluated according to the following criteria. The yield rate was defined as the weight change rate between the average weight before boiling and the average weight after boiling and washing, using an EK-410i weight measuring device (manufactured by A&D Co., Ltd.).
(Evaluation criteria for yield improvement)
⊚: The yield rate is improved by 6 points or more when Comparative Example 1 is used as the standard.
◯: The improvement in yield rate compared to Comparative Example 1 is 3 points or more and less than 6 points.
Δ: The improvement in yield rate compared to Comparative Example 1 is 0 points or more and less than 3 points.
×: The improvement in yield rate compared to Comparative Example 1 is less than 0 points.
(Appearance Evaluation Criteria)
⊚: No peeling at all (0% of total length), very good.
○: Slight peeling of flesh observed (less than 5% of total length), but in good condition.
×: Peeling of flesh is noticeable (5% or more of the total length), poor quality.

実施例1~10及び比較例1について、液の粘度、pH、甘えびの歩留まり率、歩留まり向上の評価、外観の評価を表2に示した。 For Examples 1 to 10 and Comparative Example 1, the liquid viscosity, pH, sweet shrimp yield rate, yield improvement evaluation, and appearance evaluation are shown in Table 2.

Figure 0007480949000002
Figure 0007480949000002

液を調製せず、甘えびをそのままボイル槽に投入した比較例1は、甘えびの身が大きく剥がれてしまい、不良という結果になった。一方、メチルセルロース、アルファ化澱粉、澱粉分解物を含む液を用いた実施例1及び2は、比較例1より歩留まり率が向上し、甘えびの外観も良好であった。In Comparative Example 1, where the shrimp were placed directly into the boiling tank without preparing any liquid, the shrimp meat peeled off in large pieces, resulting in a poor result. On the other hand, in Examples 1 and 2, where a liquid containing methylcellulose, pregelatinized starch, and starch hydrolysates was used, the yield rate was higher than in Comparative Example 1, and the appearance of the shrimp was also good.

メチルセルロース、結晶セルロース製剤、アルファ化澱粉、澱粉分解物を含む液を用いた実施例3~10は、結晶セルロース製剤を含まない液を用いた対応する組成の実施例1及び2よりも、歩留まり率あるいは外観の評価がより良好であった。例えば、実施例1と固形分が同一であり、かつ結晶セルロース製剤を含む実施例7及び8は、実施例1より歩留まり率が高く、外観の評価がより良好であった。同様に、実施例2と固形分が同一であり、かつ結晶セルロース製剤を含む実施例9についても、実施例2より歩留まり率が高く、外観の評価がより良好であった。 Examples 3 to 10, which used liquids containing methylcellulose, a crystalline cellulose preparation, pregelatinized starch, and a starch hydrolysate, had better yield rates or appearance ratings than Examples 1 and 2, which had the corresponding compositions and used liquids that did not contain a crystalline cellulose preparation. For example, Examples 7 and 8, which had the same solid content as Example 1 and contained a crystalline cellulose preparation, had higher yield rates and better appearance ratings than Example 1. Similarly, Example 9, which had the same solid content as Example 2 and contained a crystalline cellulose preparation, had a higher yield rate and better appearance ratings than Example 2.

<赤えび-1>
[実施例11]
(浸漬)
生のアルゼンチンアカエビ(以下、赤えびと表記。10.8~14.6g/匹)の頭、殻、尾を取り、重量を測定した。重量測定後の赤えびを、実施例7の液7に1分間浸漬した。
<Red shrimp-1>
[Example 11]
(Immersion)
The head, shell, and tail of raw Argentine red shrimp (hereinafter referred to as red shrimp, 10.8 to 14.6 g/piece) were removed and weighed. The red shrimp after the weight measurement were immersed in liquid 7 of Example 7 for 1 minute.

(ボイル槽への投入)
実施例7の液7に浸漬した赤えびを、90±2℃に調整したボイル槽に投入した。1分間ボイルし、その後赤えびの周りを被覆している液7を流水で洗浄した。赤えびの形が崩れない程度に網で水を切り、重量を測定した。[ボイル前の重量測定、浸漬、ボイル槽への投入、流水洗浄、水切り、ボイル・洗浄後の重量測定]の一連の操作を独立に3回行った。液7を用いて一連の操作を行ったものを、実施例11とした。
(Adding to boiling tank)
The shrimp immersed in liquid 7 of Example 7 were placed in a boiling tank adjusted to 90±2°C. The shrimp were boiled for 1 minute, and then the liquid 7 covering the shrimp was washed with running water. The shrimp were drained using a net so that their shape was not distorted, and their weight was measured. The series of operations of [weight measurement before boiling, immersion, placement in the boiling tank, washing with running water, draining, and weight measurement after boiling and washing] was carried out three times independently. The series of operations carried out using liquid 7 was designated Example 11.

[比較例2]
食品改質剤液を用いずに赤えびをそのままボイル槽に投入した以外は実施例11と同様の方法で一連の操作を行ったもの比較例2とした。なお、ボイル後の赤えびには液が付着していないが、流水で洗浄する工程は実施例11と同様に行った。
[Comparative Example 2]
A series of operations was carried out in the same manner as in Example 11, except that the shrimp were directly put into the boiling tank without using the food modifier liquid, to prepare Comparative Example 2. Although no liquid was attached to the shrimp after boiling, the process of washing them with running water was carried out in the same manner as in Example 11.

[評価]
実施例11及び比較例2について、歩留まり向上とボイル・洗浄後の赤えびの外観を下記基準で評価した。歩留まり率は、重量測定器としてEK-410i(株式会社エー・アンド・デイ製)を使用し、ボイル前の平均とボイル後の平均との重量変化率として定義した。
(歩留まり向上の評価基準)
◎:比較例2を基準とした際の歩留まり率の向上が6ポイント以上である。
○:比較例2を基準とした際の歩留まり率の向上が3ポイント以上6ポイント未満である。
△:比較例2を基準とした際の歩留まり率の向上が0ポイント以上3ポイント未満である。
×:比較例2を基準とした際の歩留まり率の向上が0ポイント未満である。
(外観の評価基準)
◎:身の剥がれが全くなく(全長の0%)、非常に良好。
○:わずかに身の剥がれが見られるが(全長の5%未満)、良好。
×:身の剥がれが目立ち(全長の5%以上)、不良。
[evaluation]
For Example 11 and Comparative Example 2, the yield improvement and the appearance of the red shrimp after boiling and washing were evaluated according to the following criteria. The yield rate was defined as the rate of change in weight between the average before boiling and the average after boiling, using an EK-410i (manufactured by A&D Co., Ltd.) as a weight measuring device.
(Evaluation criteria for yield improvement)
⊚: The yield rate is improved by 6 points or more when the comparative example 2 is used as the standard.
◯: The improvement in yield rate when Comparative Example 2 is taken as the standard is 3 points or more and less than 6 points.
Δ: The improvement in yield rate when compared with Comparative Example 2 is 0 points or more and less than 3 points.
×: The improvement in yield rate compared to Comparative Example 2 is less than 0 points.
(Appearance Evaluation Criteria)
⊚: No peeling at all (0% of total length), very good.
○: Slight peeling of flesh observed (less than 5% of total length), but in good condition.
×: Peeling of flesh is noticeable (5% or more of the total length), poor quality.

実施例11及び比較例2について、赤えびの歩留まり率、歩留まり向上の評価、外観の評価を表3に示した。 The red shrimp yield rate, yield improvement evaluation, and appearance evaluation for Example 11 and Comparison Example 2 are shown in Table 3.

Figure 0007480949000003
Figure 0007480949000003

液を調製せず、赤えびをそのままボイル槽に投入した比較例2は、赤えびの身が大きく剥がれてしまい、不良という結果になった。一方、液7を用いた実施例11は、ボイル時間を同じくする比較例2より歩留まり率が向上し、赤えびの外観も良好であった。In Comparative Example 2, where the shrimp were simply placed in the boiling tank without preparing the liquid, the shrimp meat peeled off in large pieces, resulting in a poor result. On the other hand, in Example 11, where Liquid 7 was used, the yield rate was improved compared to Comparative Example 2, which had the same boiling time, and the appearance of the shrimp was also good.

<赤えび-2>
[実施例12]
ボイル時間を1分から2分に変更した以外は実施例11と同様の方法で行ったものを、実施例12とした。
<Red shrimp-2>
[Example 12]
Example 12 was prepared in the same manner as Example 11, except that the boiling time was changed from 1 minute to 2 minutes.

[比較例3]
食品改質剤液を用いずに赤えびをそのままボイル槽に投入した以外は実施例12と同様の方法で一連の操作を行ったものを、比較例3とした。
[Comparative Example 3]
Comparative Example 3 was prepared by carrying out a series of operations similar to those in Example 12, except that red shrimp were directly placed in the boiling tank without using any food modifier liquid.

[評価]
実施例12及び比較例3について、歩留まり向上とボイル・洗浄後の赤えびの外観を下記基準で評価した。外観の評価基準については、実施例11及び比較例2と同様とした。なお、歩留まり率は、重量測定器としてEK-410i(株式会社エー・アンド・デイ製)を使用し、ボイル前の平均とボイル後の平均との重量変化率として定義した。
(歩留まり向上の評価基準)
◎:比較例3を基準とした際の歩留まり率の向上が6ポイント以上である。
○:比較例3を基準とした際の歩留まり率の向上が3ポイント以上6ポイント未満である。
△:比較例3を基準とした際の歩留まり率の向上が0ポイント以上3ポイント未満である。
×:比較例3を基準とした際の歩留まり率の向上が0ポイント未満である。
[evaluation]
For Example 12 and Comparative Example 3, the yield improvement and the appearance of the red shrimp after boiling and washing were evaluated according to the following criteria. The evaluation criteria for appearance were the same as those for Example 11 and Comparative Example 2. The yield rate was defined as the rate of change in weight between the average before boiling and the average after boiling, using an EK-410i (manufactured by A&D Co., Ltd.) as a weight measuring device.
(Evaluation criteria for yield improvement)
⊚: The yield rate is improved by 6 points or more when the comparative example 3 is used as the standard.
◯: The improvement in yield rate when Comparative Example 3 is taken as the standard is 3 points or more and less than 6 points.
Δ: The improvement in yield rate when compared with Comparative Example 3 is 0 points or more and less than 3 points.
×: The improvement in yield rate when Comparative Example 3 is taken as the standard is less than 0 points.

実施例12及び比較例3について、赤えびの歩留まり率、歩留まり向上の評価、外観の評価を表4に示した。 The red shrimp yield rate, yield improvement evaluation, and appearance evaluation for Example 12 and Comparison Example 3 are shown in Table 4.

Figure 0007480949000004
Figure 0007480949000004

液を調製せず、赤えびをそのままボイル槽に投入した比較例3は、赤えびの身が大きく剥がれてしまい、不良という結果になった。一方、液7を用いた実施例12は、ボイル時間を同じくする比較例3より歩留まり率が向上し、赤えびの外観も良好であった。In Comparative Example 3, where the shrimp were simply placed in the boiling tank without preparing the liquid, the shrimp meat peeled off in large pieces, resulting in a poor result. On the other hand, in Example 12, where Liquid 7 was used, the yield rate was improved compared to Comparative Example 3, which had the same boiling time, and the appearance of the shrimp was also good.

<なめこ>
[実施例13]
(浸漬)
なめこ20部を、100部の実施例7の液7に投入し、1分間浸漬した。
<Nameko>
[Example 13]
(Immersion)
20 parts of nameko mushrooms were added to 100 parts of Liquid 7 of Example 7 and immersed for 1 minute.

(ボイル槽への投入)
実施例7の液7に浸漬したなめこをザルですくい、90±2℃に調整したボイル槽に投入した。1分間ボイルし、その後なめこの周りを被覆している液7を流水で洗浄した。ザルに移して10分間水を切り、再度[浸漬、ボイル槽への投入]の操作を行った後、なめこを網の上に広げて室温で4時間以上風乾した。すなわち、本操作は下記の順番で行った。
(1)液7を調製、(2)なめこを液7に1分間浸漬、(3)浸漬したなめこをボイル槽に投入して1分間ボイル、(4)ボイルしたなめこを流水で洗浄、(5)ザルに移して10分間水切り、(6)水切りしたなめこを再度液7に1分間浸漬、(7)再浸漬したなめこをボイル槽に投入して1分間ボイル、(8)再ボイルしたなめこを流水で洗浄、(9)網の上に広げて室温で4時間以上風乾。
一連の操作を行ったものを、実施例13とした。
(Adding to boiling tank)
The mushrooms soaked in Liquid 7 of Example 7 were scooped up in a sieve and placed in a boiling tank adjusted to 90±2°C. They were boiled for 1 minute, and then the Liquid 7 covering the mushrooms was washed with running water. They were transferred to a sieve and drained for 10 minutes, and after the operation of [soaking and placing in boiling tank] was repeated, the mushrooms were spread on a net and air-dried at room temperature for 4 hours or more. That is, this operation was carried out in the following order.
(1) Prepare liquid 7; (2) immerse the mushrooms in liquid 7 for 1 minute; (3) place the immersed mushrooms in a boiling tank and boil for 1 minute; (4) wash the boiled mushrooms under running water; (5) transfer to a colander and drain for 10 minutes; (6) immerse the drained mushrooms again in liquid 7 for 1 minute; (7) place the re-immersed mushrooms in the boiling tank and boil for 1 minute; (8) wash the re-boiled mushrooms under running water; and (9) spread on a wire rack and air-dry at room temperature for at least 4 hours.
The result of carrying out a series of operations was designated as Example 13.

[比較例4]
食品改質剤液を用いずになめこをそのままボイル槽に投入した以外は実施例13と同様の方法で一連の操作を行ったものを、比較例4とした。すなわち、本操作は下記の順番で行った。
(1)なめこをボイル槽に投入して1分間ボイル、(2)ボイルしたなめこを流水で洗浄、(3)ザルに移して10分間水切り、(4)水切りしたなめこをボイル槽に投入して1分間ボイル、(5)再ボイルしたなめこを流水で洗浄、(6)網の上に広げて室温で4時間以上風乾。
[Comparative Example 4]
A series of operations was carried out in the same manner as in Example 13, except that the nameko mushrooms were directly put into the boiling tank without using the food modifier liquid, to prepare Comparative Example 4. That is, the operations were carried out in the following order.
(1) Place the mushrooms in a boiling tank and boil for 1 minute, (2) wash the boiled mushrooms under running water, (3) transfer to a colander and drain for 10 minutes, (4) place the drained mushrooms in the boiling tank and boil for 1 minute, (5) wash the re-boiled mushrooms under running water, and (6) spread them out on a wire rack and air-dry at room temperature for at least 4 hours.

[評価]
ボイル、風乾後のなめこについて、ぬめり感を下記基準で評価した。
(ぬめり感の評価基準)
○:ボイル前と同等のぬめり感があり、ぬめり感が強い。
×:ボイル前より明らかにぬめり感が弱い。
[evaluation]
After boiling and air drying, the nameko mushrooms were evaluated for sliminess according to the following criteria.
(Evaluation criteria for slimy feeling)
◯: The texture is slimy, similar to that before boiling, and is very slimy.
×: The texture is clearly less slimy than before boiling.

実施例13及び比較例4について、なめこのぬめり感の評価を表5に示した。 The evaluation of the slimy feel of the mushrooms for Example 13 and Comparison Example 4 is shown in Table 5.

Figure 0007480949000005
Figure 0007480949000005

液を調製せず、なめこをそのままボイル槽に投入した比較例4は、ボイル前に比べてなめこのぬめり感が明らかに弱くなり、なめこ特有のツヤも失われていた。一方、液7を用いた実施例13は、ボイル前のなめこのぬめり感を保持しており、なめこ特有のツヤがあった。In Comparative Example 4, where the mushrooms were placed directly into the boiling tank without preparing any liquid, the mushrooms were noticeably less slimy than before they were boiled, and they lost their characteristic shine. On the other hand, in Example 13, where Liquid 7 was used, the mushrooms retained the slimy feel they had before they were boiled, and retained their characteristic shine.

<バナメイエビ>
[実施例14]
(食品改質剤液の調製)
可逆熱ゲル化剤としてメチルセルロース(メトローズMCE-4000:信越化学工業株式会社製)0.96部を、増粘剤として馬鈴薯澱粉をドラムドライヤーで乾燥し粉砕して42meshを通過したアルファ化澱粉1.12部及び馬鈴薯澱粉を酵素処理により分解した澱粉分解物(分散剤)0.96部を、結晶セルロース製剤としてセオラスRC-591S(旭化成株式会社製、結晶セルロースを89%含む)あるいはセオラスCL-611S(旭化成株式会社製、結晶セルロースを85%含む)0.96部を混合・造粒し、食品改質剤とした。15℃の冷水を、食品改質剤と合わせて100部になるように加え、すぐに撹拌混合した。得られた食品改質剤液を、液14とした。液14の粘度を、15℃においてBM型回転粘度計(VISCOMETER MODEL BMII;東機産業株式会社製)を用いて30rpmの回転速度で10秒後に測定した。また、pHメーター(LAQUA F-71S;株式会社堀場製作所製)を用いて、液14のpHを測定した。液14の組成について表6に示した。

Figure 0007480949000006
<White shrimp>
[Example 14]
(Preparation of food modifier liquid)
0.96 parts of methylcellulose (Metolose MCE-4000: manufactured by Shin-Etsu Chemical Co., Ltd.) as a reversible heat gelling agent, 1.12 parts of pregelatinized starch obtained by drying potato starch in a drum dryer, pulverizing it and passing it through a 42 mesh screen as a thickening agent, and 0.96 parts of starch hydrolyzate (dispersant) obtained by enzymatically decomposing potato starch as a thickening agent, and 0.96 parts of CEOLUS RC-591S (manufactured by Asahi Kasei Co., Ltd., containing 89% crystalline cellulose) or CEOLUS CL-611S (manufactured by Asahi Kasei Co., Ltd., containing 85% crystalline cellulose) as a crystalline cellulose preparation were mixed and granulated to prepare a food modifier. 15°C cold water was added so that the total amount of the food modifier and the mixture was 100 parts, and the mixture was immediately stirred and mixed. The obtained food modifier liquid was designated as Liquid 14. The viscosity of Liquid 14 was measured at 15° C. after 10 seconds at a rotation speed of 30 rpm using a BM type rotational viscometer (VISCOMETER MODEL BMII; manufactured by Toki Sangyo Co., Ltd.). The pH of Liquid 14 was also measured using a pH meter (LAQUA F-71S; manufactured by Horiba, Ltd.). The composition of Liquid 14 is shown in Table 6.
Figure 0007480949000006

(浸漬)
生のバナメイエビの殻と尾を取り、重量を測定した。重量測定後のバナメイエビを液14に1分間浸漬した。
(Immersion)
The shells and tails of raw white shrimp were removed and the weights were measured. The white shrimps after the weight measurement were immersed in the liquid 14 for 1 minute.

(ボイル槽への投入)
液14に浸漬したバナメイエビを、90±2℃に調整したボイル槽に投入した。2分間ボイルし、その後バナメイエビの周りを被覆している液1を流水で洗浄した。バナメイエビの形が崩れない程度に網で水を切り、重量を測定した。[ボイル前の重量測定、浸漬、ボイル槽への投入、流水洗浄、水切り、ボイル・洗浄後の重量測定]の一連の操作を独立に少なくとも3回行った。液14を用いて一連の操作を行ったものを、実施例14とした。
(Adding to boiling tank)
The white shrimp immersed in liquid 14 were placed in a boiling tank adjusted to 90±2°C. The shrimp were boiled for 2 minutes, and then the liquid 1 covering the white shrimp was washed with running water. The shrimp were drained with a net so that their shape was not distorted, and their weight was measured. The series of operations of [weight measurement before boiling, immersion, placement in the boiling tank, washing with running water, draining, and weight measurement after boiling and washing] was performed at least three times independently. The series of operations performed using liquid 14 was designated as Example 14.

[比較例5]
食品改質剤液を用いずにバナメイエビをそのままボイル槽に投入した以外は実施例14と同様の方法で一連の操作を行ったものを、比較例5とした。なお、ボイル後のバナメイエビには液が付着していないが、流水で洗浄する工程は実施例14と同様に行った。
[Comparative Example 5]
A series of operations was carried out in the same manner as in Example 14, except that the white shrimp was directly put into the boiling tank without using the food modifier liquid, and this was used as Comparative Example 5. Although no liquid was attached to the white shrimp after boiling, the process of washing them with running water was carried out in the same manner as in Example 14.

[評価]
歩留まり向上(比較例5との歩留まり率の差)を評価した。歩留まり率は、重量測定器としてEK-410i(株式会社エー・アンド・デイ製)を使用し、ボイル前の平均重量とボイル・洗浄後の平均重量との重量変化率として定義した。
[evaluation]
The yield improvement (difference in yield rate from Comparative Example 5) was evaluated. The yield rate was defined as the weight change rate between the average weight before boiling and the average weight after boiling and washing, using an EK-410i (manufactured by A&D Co., Ltd.) as a weight measuring device.

表面質感を下記基準で評価した。
◎:比較例5と比較して、表面の艶(みずみずしさ)が明らかに増大している。
○:比較例5と比較して、表面の艶(みずみずしさ)が同程度である。
×:比較例5と比較して、表面の艶(みずみずしさ)が明らかに減少している。
The surface texture was evaluated according to the following criteria.
⊚: Compared with Comparative Example 5, the surface gloss (freshness) is clearly increased.
◯: Compared with Comparative Example 5, the surface gloss (freshness) is about the same.
×: Compared with Comparative Example 5, the surface gloss (freshness) is clearly reduced.

食感を下記基準で評価した。
◎:比較例5と比較して、弾力(噛み応え)が明らかに増大している。
○:比較例5と比較して、弾力(噛み応え)が同程度である。
×:比較例5と比較して、弾力(噛み応え)が明らかに減少している。
The texture was evaluated according to the following criteria.
⊚: Compared with Comparative Example 5, the elasticity (chewing resistance) is clearly increased.
○: Compared with Comparative Example 5, the elasticity (chewing resistance) is about the same.
×: Compared with Comparative Example 5, the elasticity (chewing resistance) is clearly decreased.

味の濃さを下記基準で評価した。
◎:比較例5と比較して、味の濃さが明らかに増大している。
○:比較例5と比較して、味の濃さが同程度である。
×:比較例5と比較して、味の濃さが明らかに減少している。
The intensity of the flavor was evaluated according to the following criteria.
⊚: Compared with Comparative Example 5, the flavor intensity is clearly increased.
◯: Compared to Comparative Example 5, the flavor intensity is about the same.
×: Compared with Comparative Example 5, the flavor intensity is clearly decreased.

実施例14及び比較例5について、液の粘度、pH、バナメイエビの歩留まり率、並びに、歩留まり向上、表面質感、食感、及び味の評価を表7に示した。 For Example 14 and Comparative Example 5, the liquid viscosity, pH, white shrimp yield rate, and evaluation of yield improvement, surface texture, texture, and taste are shown in Table 7.

Figure 0007480949000007
Figure 0007480949000007

本開示の改質剤を用いた実施例14は、ブランクである比較例5と比較して、歩留まりが向上し、表面質感、食感、及び味の評価においても良好であった。 Example 14, which used the modifier of the present disclosure, had improved yield and was also favorable in terms of surface texture, mouthfeel, and taste compared to the blank comparison example 5.

実施例14及び比較例5の方法で得られたボイル後のバナメイエビそれぞれ20匹についてアミノ酸分析を行い、ボイル後のバナメイエビ一匹あたりのアミノ酸量を求めた。結果を下記表8に示した。

Figure 0007480949000008
Amino acid analysis was carried out on 20 boiled white-leaf shrimps obtained by the methods of Example 14 and Comparative Example 5, and the amount of amino acids per boiled white-leaf shrimp was determined. The results are shown in Table 8 below.
Figure 0007480949000008

表8から明らかなように、本開示の改質剤を用いた実施例14はブランクサンプルである比較例5よりもアミノ酸量が約18%多く、アミノ酸の流出を抑えることができることがわかった。As is clear from Table 8, Example 14, which used the modifying agent of the present disclosure, had an amino acid amount that was approximately 18% greater than that of Comparative Example 5, the blank sample, and it was found that the leakage of amino acids could be suppressed.

<その他食材>
[実施例15]
(浸漬)
生の豚ひれ肉を約3cm角×1cmにカットし、重量を測定した。重量測定後の豚ひれ肉を液14に1分間浸漬した。
<Other ingredients>
[Example 15]
(Immersion)
Raw pork fillet was cut into pieces of about 3 cm square x 1 cm, and the weight was measured. After the weight measurement, the pork fillet was immersed in liquid 14 for 1 minute.

(ボイル槽への投入)
液14に浸漬した豚ひれ肉を、90±2℃に調整したボイル槽に投入した。4分間ボイルし、その後豚ひれ肉の周りを被覆している液1を流水で洗浄した。豚ひれ肉の形が崩れない程度に網で水を切り、重量を測定した。[ボイル前の重量測定、浸漬、ボイル槽への投入、流水洗浄、水切り、ボイル・洗浄後の重量測定]の一連の操作を独立に少なくとも3回行った。液14を用いて一連の操作を行ったものを、実施例15とした。
(Adding to boiling tank)
The pork fillet immersed in liquid 14 was placed in a boiling tank adjusted to 90±2°C. After boiling for 4 minutes, the liquid 1 covering the pork fillet was washed with running water. The pork fillet was drained with a net to the extent that its shape was not distorted, and its weight was measured. The series of operations of [weight measurement before boiling, immersion, placing in a boiling tank, washing with running water, draining, and weight measurement after boiling and washing] was performed at least three times independently. The series of operations performed using liquid 14 was designated as Example 15.

[ブランクサンプル]
食品改質剤液を用いない以外は実施例15と同様の方法で、豚ひれ肉をそのままボイル槽に投入し、一連の操作を行ったものを、ブランクサンプルとした。なお、ボイル後の豚ひれ肉には液が付着していないが、流水で洗浄する工程は実施例15と同様に行った。
[Blank sample]
A blank sample was prepared by placing pork fillet directly into the boiling tank and carrying out a series of operations in the same manner as in Example 15, except that no food modifier liquid was used. Although no liquid was attached to the pork fillet after boiling, the process of washing with running water was carried out in the same manner as in Example 15.

[評価]
歩留まり向上(ブランクサンプルとの歩留まり率の差)を評価した。歩留まり率は、重量測定器としてEK-410i(株式会社エー・アンド・デイ製)を使用し、ボイル前の平均重量とボイル・洗浄後の平均重量との重量変化率として定義した。また、実施例15で得られたサンプルと、ブランクサンプルとで、外観、味の濃さや、食感等についても比較評価した。結果を表9にまとめた。
[evaluation]
The yield improvement (difference in yield rate from the blank sample) was evaluated. The yield rate was defined as the weight change rate between the average weight before boiling and the average weight after boiling and washing, using an EK-410i (manufactured by A&D Co., Ltd.) as a weight measuring device. In addition, the sample obtained in Example 15 was compared with the blank sample in terms of appearance, flavor intensity, texture, etc. The results are summarized in Table 9.

[実施例16~25]
豚ひれ肉に代えて、豚ロース肉、豚もも肉、豚レバー、牛ロース肉、鶏むね肉、鶏もも肉、いか足、赤貝開き、ほたて貝柱、又は本マグロ中トロを用い、茹で時間を食材に合わせて変更した以外は、実施例15と同様に一連の操作を行ったものをそれぞれ実施例16~25とした。実施例16~25について実施例15と同様の評価を行ったものを表9に示す。
[Examples 16 to 25]
Examples 16 to 25 were produced by carrying out a series of operations similar to those in Example 15, except that pork loin, pork thigh, pork liver, beef loin, chicken breast, chicken thigh, squid leg, filleted ark shell, scallop, or bluefin tuna fatty tuna was used instead of pork fillet, and the boiling time was changed according to the ingredient. Examples 16 to 25 were evaluated in the same manner as in Example 15, and the results are shown in Table 9.

[実施例26]
豚ひれ肉に代えて冷凍タコを用い、茹で時間を2分とし、液14に代えて液7を用いた以外は、実施例15と同様に一連の操作を行ったものを実施例26とした。実施例26について実施例15と同様の評価を行ったものを表9に示す。各実施例の全体的な風味の傾向として、ブランクと比較した歩留り率は向上しているが、味が薄くなる又は水っぽくなるということはなく、食感・味の濃さは同等であり、良好な味わいを示した。



Figure 0007480949000009
[Example 26]
Example 26 was prepared by carrying out a series of operations similar to those of Example 15, except that frozen octopus was used instead of pork fillet, the boiling time was 2 minutes, and liquid 7 was used instead of liquid 14. Example 26 was evaluated in the same manner as Example 15, and the results are shown in Table 9. As an overall trend in flavor for each Example, the yield rate was improved compared to the blank, but the flavor did not become weak or watery, and the texture and flavor intensity were the same, showing a good flavor.



Figure 0007480949000009

<非増粘性澱粉の使用>
[実施例27]
(食品改質剤液の調製)
実施例1と同様の方法で、さらに非増粘性澱粉を追加して試験を行った。非増粘性澱粉として15℃における2重量%水溶液の粘度が2.0mPa・sのアルファ化リン酸架橋澱粉を用いた。メチルセルロース、アルファ化澱粉、澱粉分解物、非増粘性澱粉を用いて液を調製した、実施例27の組成について、表10に示した。なお、実施例27に対応する、食品改質剤と冷水の混合液を、液27とした。

Figure 0007480949000010
<Use of non-thickening starch>
[Example 27]
(Preparation of food modifier liquid)
A test was conducted by adding non-thickening starch in the same manner as in Example 1. A pregelatinized phosphate cross-linked starch having a viscosity of 2.0 mPa·s in a 2% by weight aqueous solution at 15°C was used as the non-thickening starch. The composition of Example 27, in which a liquid was prepared using methylcellulose, pregelatinized starch, starch hydrolysate, and non-thickening starch, is shown in Table 10. The mixture of food modifier and cold water corresponding to Example 27 was designated as Liquid 27.
Figure 0007480949000010

液1に代えて液27を用いたほか、ボイル時間を30秒から2分に変更した以外は実施例1と同様の方法で甘えびに試験を行ったものを、実施例27とした。 Example 27 was produced by testing sweet shrimp in the same manner as Example 1, except that liquid 27 was used instead of liquid 1 and the boiling time was changed from 30 seconds to 2 minutes.

[比較例6]
食品改質剤液を用いずに甘えびをそのままボイル槽に投入した以外は実施例27と同様の方法で一連の操作を行ったものを、比較例6とした。なお、ボイル後の甘えびには液が付着していないが、流水で洗浄する工程は実施例27と同様に行った。
[Comparative Example 6]
A series of operations was carried out in the same manner as in Example 27, except that the sweet shrimp was directly put into the boiling tank without using the food modifier liquid, and this was used as Comparative Example 6. Although no liquid was attached to the sweet shrimp after boiling, the process of washing with running water was carried out in the same manner as in Example 27.

[評価]
歩留まり向上とボイル・洗浄後の甘えびの外観を下記基準で評価した。歩留まり率は、重量測定器としてEK-410i(株式会社エー・アンド・デイ製)を使用し、ボイル前の平均重量とボイル・洗浄後の平均重量との重量変化率として定義した。
(歩留まり向上の評価基準)
◎:比較例6を基準とした際の歩留まり率の向上が6ポイント以上である。
○:比較例6を基準とした際の歩留まり率の向上が3ポイント以上6ポイント未満である。
△:比較例6を基準とした際の歩留まり率の向上が0ポイント以上3ポイント未満である。
×:比較例6を基準とした際の歩留まり率の向上が0ポイント未満である。
(外観の評価基準)
◎:身の剥がれが全くなく(全長の0%)、非常に良好。
○:わずかに身の剥がれが見られるが(全長の5%未満)、良好。
×:身の剥がれが目立ち(全長の5%以上)、不良。
[evaluation]
The yield improvement and the appearance of the shrimp after boiling and washing were evaluated according to the following criteria. The yield rate was defined as the weight change rate between the average weight before boiling and the average weight after boiling and washing, using an EK-410i weight measuring device (manufactured by A&D Co., Ltd.).
(Evaluation criteria for yield improvement)
⊚: The yield rate is improved by 6 points or more when the comparative example 6 is used as the standard.
◯: The improvement in yield rate when Comparative Example 6 is taken as the standard is 3 points or more and less than 6 points.
Δ: The improvement in yield rate when compared with Comparative Example 6 is 0 points or more and less than 3 points.
×: The improvement in yield rate when Comparative Example 6 is taken as the standard is less than 0 points.
(Appearance Evaluation Criteria)
⊚: No peeling at all (0% of total length), very good.
○: Slight peeling of flesh observed (less than 5% of total length), but in good condition.
×: Peeling of flesh is noticeable (5% or more of the total length), poor quality.

[評価]
実施例27及び比較例6について、液の粘度、pH、甘えびの歩留まり率、歩留まり向上の評価、外観の評価を表11に示した。
[evaluation]
For Example 27 and Comparative Example 6, the viscosity and pH of the liquid, sweet shrimp yield rate, evaluation of yield improvement, and evaluation of appearance are shown in Table 11.

Figure 0007480949000011
Figure 0007480949000011

液を調製せず、甘えびをそのままボイル槽に投入した比較例6は、甘えびの身が大きく剥がれてしまい、不良という結果になった。一方、メチルセルロース、アルファ化澱粉、澱粉分解物、非増粘性澱粉を含む液を用いた実施例27は、比較例6より歩留まり率が向上し、甘えびの外観も良好であった。In Comparative Example 6, where the shrimp were directly placed in the boiling tank without preparing the liquid, the shrimp meat peeled off in large pieces, resulting in a poor result. On the other hand, in Example 27, where a liquid containing methylcellulose, pregelatinized starch, starch hydrolysate, and non-thickening starch was used, the yield rate was higher than in Comparative Example 6, and the appearance of the shrimp was also good.

Claims (11)

可逆熱ゲル化剤及び増粘剤を含む食品被覆用改質剤であって、
前記可逆熱ゲル化剤がメチルセルロース又はヒドロキシプロピルメチルセルロースであり、
前記増粘剤が澱粉及び澱粉分解物の両方を含み、
前記食品被覆用改質剤に水を加えて撹拌混合して固形分5重量%に調製した食品被覆用改質剤液の15℃における粘度が250mPa・s以上である、
食品被覆用改質剤(但し、フライドポテト製造用及び乾燥フィルムコーティング形成用を除く)。
A food coating modifier comprising a reversible thermal gelling agent and a thickening agent,
the reversible thermal gelling agent is methylcellulose or hydroxypropylmethylcellulose;
The thickener comprises both starch and a starch hydrolysate,
The viscosity of the food coating modifier liquid prepared by adding water to the food coating modifier and stirring and mixing to a solid content of 5% by weight at 15°C is 250 mPa s or more.
Food coating modifier (except for use in French fries production and in forming dry film coatings).
前記可逆熱ゲル化剤の熱ゲル化温度が40℃以上である、請求項1に記載の食品被覆用改質剤。 The food coating modifier according to claim 1 , wherein the reversible thermal gelling agent has a thermal gelling temperature of 40° C. or higher. 前記増粘剤の15℃における2重量%水溶液の粘度が30mPa・s以上である、請求項1又は2に記載の食品被覆用改質剤。 3. The food coating modifier according to claim 1, wherein the viscosity of a 2% by weight aqueous solution of the thickener at 15°C is 30 mPa·s or more. 結晶セルロースを含む、請求項1~3のいずれか一項に記載の食品被覆用改質剤。 The food coating modifier according to any one of claims 1 to 3, comprising crystalline cellulose. 15℃における2重量%液の粘度が30mPa・s未満である、非増粘性澱粉を含む、請求項1~4のいずれか一項に記載の食品被覆用改質剤。 The food coating modifier according to any one of claims 1 to 4, comprising a non-thickening starch having a viscosity of a 2 wt% solution at 15°C of less than 30 mPa·s. 食品改質時に食品に添加され、食品改質後には除去可能な、請求項1~のいずれか一項に記載の食品被覆用改質剤。 The food coating modifier according to any one of claims 1 to 5 , which is added to food during food modification and can be removed after the food modification. ゲル状態で食品を被覆するために用いられる、請求項1~のいずれか一項に記載の食品被覆用改質剤。 The food coating modifier according to any one of claims 1 to 6 , which is used in a gel state to coat food. 請求項1~のいずれか一項に記載の食品被覆用改質剤に水を加えて撹拌混合して食品被覆用改質剤液を得る工程(1)、前記食品被覆用改質剤液で食品を被覆して被覆食品を得る工程(2)、及び前記被覆食品を可逆熱ゲル化剤の熱ゲル化温度以上で加熱する工程(3)を含む、改質食品の製造方法。 A method for producing a modified food, comprising the steps of: (1) adding water to the food coating modifier according to any one of claims 1 to 7 and stirring and mixing to obtain a food coating modifier liquid; (2) coating a food with the food coating modifier liquid to obtain a coated food; and (3) heating the coated food at a temperature equal to or higher than the thermal gelling temperature of the reversible thermal gelling agent. 前記工程(3)における加熱が、茹で、又は蒸しである、請求項に記載の改質食品の製造方法。 The method for producing a modified food product according to claim 8 , wherein the heating in step (3) is boiling or steaming. 前記食品被覆用改質剤液の粘度が15℃において250mPa・s以上10000mPa・s以下である、請求項8又は9に記載の改質食品の製造方法。 The method for producing a modified food according to claim 8 or 9 , wherein the viscosity of the food coating modifier liquid is 250 mPa·s or more and 10,000 mPa·s or less at 15°C. さらに、前記被覆食品を水で洗浄する工程(4)を含む、請求項8~10のいずれか一項に記載の改質食品の製造方法。 The method for producing a modified food product according to any one of claims 8 to 10 , further comprising a step (4) of washing the coated food product with water.
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