JP7468877B2 - Cleaning composition - Google Patents
Cleaning composition Download PDFInfo
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- JP7468877B2 JP7468877B2 JP2019086109A JP2019086109A JP7468877B2 JP 7468877 B2 JP7468877 B2 JP 7468877B2 JP 2019086109 A JP2019086109 A JP 2019086109A JP 2019086109 A JP2019086109 A JP 2019086109A JP 7468877 B2 JP7468877 B2 JP 7468877B2
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- 239000000203 mixture Substances 0.000 title claims description 213
- 238000004140 cleaning Methods 0.000 title claims description 188
- 238000005259 measurement Methods 0.000 claims description 119
- 239000006260 foam Substances 0.000 claims description 72
- 238000012360 testing method Methods 0.000 claims description 61
- 239000002562 thickening agent Substances 0.000 claims description 53
- 239000003795 chemical substances by application Substances 0.000 claims description 19
- 239000004094 surface-active agent Substances 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 13
- 239000012085 test solution Substances 0.000 claims description 13
- 229920001285 xanthan gum Polymers 0.000 claims description 9
- 239000000230 xanthan gum Substances 0.000 claims description 9
- 235000010493 xanthan gum Nutrition 0.000 claims description 9
- 229940082509 xanthan gum Drugs 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000012459 cleaning agent Substances 0.000 claims description 6
- 239000012530 fluid Substances 0.000 claims description 5
- 239000003599 detergent Substances 0.000 description 23
- 230000000052 comparative effect Effects 0.000 description 20
- 239000007921 spray Substances 0.000 description 17
- -1 fatty acid salts Chemical class 0.000 description 14
- 150000003839 salts Chemical class 0.000 description 14
- 239000002738 chelating agent Substances 0.000 description 13
- 238000011156 evaluation Methods 0.000 description 10
- 230000007423 decrease Effects 0.000 description 8
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
- 239000000194 fatty acid Substances 0.000 description 8
- 229930195729 fatty acid Natural products 0.000 description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 3
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- BAERPNBPLZWCES-UHFFFAOYSA-N (2-hydroxy-1-phosphonoethyl)phosphonic acid Chemical compound OCC(P(O)(O)=O)P(O)(O)=O BAERPNBPLZWCES-UHFFFAOYSA-N 0.000 description 2
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 description 2
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 description 2
- SZHQPBJEOCHCKM-UHFFFAOYSA-N 2-phosphonobutane-1,2,4-tricarboxylic acid Chemical compound OC(=O)CCC(P(O)(O)=O)(C(O)=O)CC(O)=O SZHQPBJEOCHCKM-UHFFFAOYSA-N 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- 229940120146 EDTMP Drugs 0.000 description 2
- 229920002148 Gellan gum Polymers 0.000 description 2
- 229920002907 Guar gum Polymers 0.000 description 2
- 229920000161 Locust bean gum Polymers 0.000 description 2
- FSVCELGFZIQNCK-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)glycine Chemical compound OCCN(CCO)CC(O)=O FSVCELGFZIQNCK-UHFFFAOYSA-N 0.000 description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 2
- JYXGIOKAKDAARW-UHFFFAOYSA-N N-(2-hydroxyethyl)iminodiacetic acid Chemical compound OCCN(CC(O)=O)CC(O)=O JYXGIOKAKDAARW-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 2
- 229920001284 acidic polysaccharide Polymers 0.000 description 2
- 150000004805 acidic polysaccharides Chemical class 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 235000010418 carrageenan Nutrition 0.000 description 2
- 239000000679 carrageenan Substances 0.000 description 2
- 229920001525 carrageenan Polymers 0.000 description 2
- 229940113118 carrageenan Drugs 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 235000010492 gellan gum Nutrition 0.000 description 2
- 239000000216 gellan gum Substances 0.000 description 2
- 239000000665 guar gum Substances 0.000 description 2
- 235000010417 guar gum Nutrition 0.000 description 2
- 229960002154 guar gum Drugs 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 235000010420 locust bean gum Nutrition 0.000 description 2
- 239000000711 locust bean gum Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 235000010987 pectin Nutrition 0.000 description 2
- 229920001277 pectin Polymers 0.000 description 2
- 239000001814 pectin Substances 0.000 description 2
- 229960003330 pentetic acid Drugs 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 2
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- VKZRWSNIWNFCIQ-WDSKDSINSA-N (2s)-2-[2-[[(1s)-1,2-dicarboxyethyl]amino]ethylamino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)NCCN[C@H](C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-WDSKDSINSA-N 0.000 description 1
- DCCWEYXHEXDZQW-BYPYZUCNSA-N (2s)-2-[bis(carboxymethyl)amino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)N(CC(O)=O)CC(O)=O DCCWEYXHEXDZQW-BYPYZUCNSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- GYSCBCSGKXNZRH-UHFFFAOYSA-N 1-benzothiophene-2-carboxamide Chemical compound C1=CC=C2SC(C(=O)N)=CC2=C1 GYSCBCSGKXNZRH-UHFFFAOYSA-N 0.000 description 1
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- XNCSCQSQSGDGES-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]propyl-(carboxymethyl)amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)C(C)CN(CC(O)=O)CC(O)=O XNCSCQSQSGDGES-UHFFFAOYSA-N 0.000 description 1
- DMQQXDPCRUGSQB-UHFFFAOYSA-N 2-[3-[bis(carboxymethyl)amino]propyl-(carboxymethyl)amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)CCCN(CC(O)=O)CC(O)=O DMQQXDPCRUGSQB-UHFFFAOYSA-N 0.000 description 1
- MFKRHJVUCZRDTF-UHFFFAOYSA-N 3-methoxy-3-methylbutan-1-ol Chemical compound COC(C)(C)CCO MFKRHJVUCZRDTF-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- GHVNFZFCNZKVNT-UHFFFAOYSA-N Decanoic acid Natural products CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- DJLSRKXNWJVNTA-UHFFFAOYSA-N [Si]([O-])([O-])(O)O.[Si](O)(O)(O)O.[Si](O)(O)(O)O.[K+].[K+] Chemical compound [Si]([O-])([O-])(O)O.[Si](O)(O)(O)O.[Si](O)(O)(O)O.[K+].[K+] DJLSRKXNWJVNTA-UHFFFAOYSA-N 0.000 description 1
- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229960003975 potassium Drugs 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 229940086066 potassium hydrogencarbonate Drugs 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000013441 quality evaluation Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- RLQWHDODQVOVKU-UHFFFAOYSA-N tetrapotassium;silicate Chemical compound [K+].[K+].[K+].[K+].[O-][Si]([O-])([O-])[O-] RLQWHDODQVOVKU-UHFFFAOYSA-N 0.000 description 1
- POWFTOSLLWLEBN-UHFFFAOYSA-N tetrasodium;silicate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])[O-] POWFTOSLLWLEBN-UHFFFAOYSA-N 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Images
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- Detergent Compositions (AREA)
Description
本発明は、洗浄剤組成物に関する。 The present invention relates to a cleaning composition.
飲食店、ホテル等の厨房・浴室スーパーマーケット、食品工場における食品製造・加工・調理装置等の洗浄には、洗浄剤組成物が使用される。洗浄剤組成物には、汚れに浸透して乳化・分散させて汚れを除去する界面活性剤、化学反応によって汚れを分解するアルカリ剤等が用いられる。 Detergent compositions are used to clean kitchens and bathrooms in restaurants and hotels, food manufacturing, processing and cooking equipment in supermarkets and food factories. Detergent compositions contain surfactants that penetrate dirt and emulsify and disperse it to remove it, and alkaline agents that break down dirt through chemical reactions.
洗浄対象面に対して汚れが強固に付着している場合、洗浄剤組成物を汚れに対して長時間接触させることで洗浄対象面から汚れを剥離させやすくなる。
ここで、洗浄対象面が垂直面や傾斜面のような液体が流れ落ちやすい面である場合、液体の洗浄剤組成物を洗浄対象面に付着させても流れ落ちてしまうため、洗浄剤組成物と汚れとの接触時間が短くなってしまう。
このような場合には、洗浄剤組成物の粘度を高くすることによって洗浄剤組成物が洗浄対象面から流れ落ちにくいようにして、洗浄剤組成物と汚れとの接触時間を長くすることが望ましい。
しかし、洗浄対象面に対して、スプレー等で洗浄剤組成物を付着させる場合、粘度が高くなることによって、きれいな泡を形成しない、スプレーガンに洗浄剤組成物が詰まるといった問題が起こる可能性がある。
When dirt is firmly attached to the surface to be cleaned, the dirt can be easily peeled off from the surface to be cleaned by keeping the cleaning composition in contact with the dirt for a long period of time.
Here, when the surface to be cleaned is a surface onto which liquids tend to flow, such as a vertical or inclined surface, even if a liquid cleaning composition is applied to the surface to be cleaned, it will flow off, resulting in a short contact time between the cleaning composition and dirt.
In such cases, it is desirable to increase the viscosity of the cleaning composition so that the cleaning composition is less likely to run off the surface to be cleaned, thereby lengthening the contact time between the cleaning composition and the dirt.
However, when the cleaning composition is applied to the surface to be cleaned by spraying or the like, problems may occur, such as the cleaning composition not forming a clear foam or clogging the spray gun due to high viscosity.
特許文献１には、酸性多糖類を含有する水性溶液の高温における粘度低下を抑制するために、天然酸性多糖類を添加することが記載されている。
洗浄剤組成物を洗浄対象面に長時間接触させる方法としては、洗浄剤組成物を泡状にして洗浄対象面に噴射・付着させる方法も考えられる。
しかし、洗浄剤組成物を泡状にして噴射・付着させる場合、付着した泡の流れ落ち等が生じると、洗浄剤組成物が、洗浄対象面以外にも付着してしまい、安全面の問題が生じる。また、付着した泡が流れ落ちると、単位面積当たりの汚れに対する洗浄剤組成物の有効成分が減り、洗浄力の低下が生じる。
このような観点から特許文献１に記載の洗浄剤組成物の噴射性及び定着性は充分とは言えなかった。
As a method for contacting the cleaning composition with the surface to be cleaned for a long period of time, a method in which the cleaning composition is made into a foam and sprayed and adhered to the surface to be cleaned can be considered.
However, when the cleaning composition is sprayed and applied in the form of foam, if the attached foam runs off, the cleaning composition may be attached to surfaces other than the surface to be cleaned, which may cause a safety problem. In addition, if the attached foam runs off, the amount of the active ingredient of the cleaning composition per unit area of dirt decreases, resulting in a decrease in cleaning power.
From this viewpoint, the sprayability and fixability of the cleaning composition described in
本発明は上記問題を解決するためになされたものであり、本発明の目的は、泡状に噴射しやすく、泡状にした際に付着した泡の流れ落ちが生じにくい、洗浄剤組成物を提供することである。 The present invention has been made to solve the above problems, and the object of the present invention is to provide a cleaning composition that is easy to spray in foam form and is less likely to wash off when foamed.
本発明者らは、洗浄剤組成物の粘度及び降伏値を所定の範囲にすると、洗浄剤組成物を泡状にした際に、泡状に噴射しやすく、付着した泡の流れ落ちが生じにくく、泡がきめ細かくなることを見出し本発明を完成させた。 The inventors discovered that when the viscosity and yield value of a cleaning composition are within a certain range, the cleaning composition is easily sprayed as a foam, the attached foam is less likely to run off, and the foam is fine-grained, and thus the present invention was completed.
すなわち、本発明の洗浄剤組成物は、水と、界面活性剤と、増粘剤とを含む洗浄剤組成物であって、下記に示す洗浄剤組成物の粘度測定試験において、測定温度５℃における、上記洗浄剤組成物の回転数１ｒｐｍのときの粘度が１００～５００ｍＰａ・ｓとなり、測定温度５℃における、上記洗浄剤組成物の回転数１００ｒｐｍのときの粘度が１５～３０ｍＰａ・ｓとなり、下記に示す洗浄剤組成物のせん断応力測定試験において、測定温度５℃における、上記洗浄剤組成物の降伏値が１Ｐａ以下であることを特徴とする。
洗浄剤組成物の粘度測定試験：
Ｅ型粘度計により、回転数１ｒｐｍ及び１００ｒｐｍの条件で洗浄剤組成物の粘度の測定を開始し、各回転数において、測定開始から１分後に測定された当該洗浄剤組成物の粘度を、それぞれ、洗浄剤組成物の粘度測定試験における、回転数が１ｒｐｍのときの粘度及び回転数が１００ｒｐｍのときの粘度とする。
洗浄剤組成物のせん断応力測定試験：
Ｅ型粘度計により、せん断速度３．８３ｓ－１、３８．３ｓ－１、７６．６ｓ－１及び３８３ｓ－１の条件で洗浄剤組成物のせん断応力の測定を開始し、測定開始から１分後に測定された洗浄剤組成物のせん断応力を各せん断速度におけるせん断応力とし、ｘ軸をせん断速度（ｓ－１）の常用対数軸とし、ｙ軸をせん断応力（Ｐａ）の常用対数軸としたグラフに、測定されたせん断応力の値をプロットし、最小二乗法により近似直線を算出し、得られた近似直線のｙ軸の切片の値を降伏値とする。
That is, the cleaning composition of the present invention is a cleaning composition containing water, a surfactant, and a thickener, and is characterized in that, in a viscosity measurement test of the cleaning composition shown below, the cleaning composition has a viscosity of 100 to 500 mPa s at a rotation speed of 1 rpm at a measurement temperature of 5° C. and a viscosity of 15 to 30 mPa s at a rotation speed of 100 rpm at a measurement temperature of 5° C., and in a shear stress measurement test of the cleaning composition shown below, the cleaning composition has a yield value of 1 Pa or less at a measurement temperature of 5° C.
Viscosity measurement test of cleaning composition:
Measurement of the viscosity of the cleaning composition is started at rotation speeds of 1 rpm and 100 rpm using an E-type viscometer. The viscosities of the cleaning composition measured 1 minute after the start of measurement at each rotation speed are defined as the viscosities at a rotation speed of 1 rpm and a rotation speed of 100 rpm, respectively, in the viscosity measurement test of the cleaning composition.
Shear stress measurement test of cleaning composition:
Measurement of the shear stress of the cleaner composition was started using an E-type viscometer under conditions of shear rates of 3.83 s -1 , 38.3 s -1 , 76.6 s -1 and 383 s -1 , and the shear stress of the cleaner composition measured 1 minute after the start of measurement was taken as the shear stress at each shear rate. The measured shear stress values were plotted on a graph with the x-axis being the common logarithm axis of the shear rate (s -1 ) and the y-axis being the common logarithm axis of the shear stress (Pa), and an approximation line was calculated by the least squares method. The intercept of the y-axis of the obtained approximation line was taken as the yield value.
本発明の洗浄剤組成物が、回転数１ｒｐｍのときの粘度が１００～５００ｍＰａ・ｓであり、回転数１００ｒｐｍのときの粘度が１５～３０ｍＰａ・ｓとなるという特徴を有することは、本発明の洗浄剤組成物に加えるせん断応力が小さい場合には粘度が高いが、加えるせん断応力が大きい場合には、粘度が低いことを意味する。
また、本発明の洗浄剤組成物の降伏値が１Ｐａ以下であるという特徴を有することは、洗浄剤組成物の粘度が低下するのに必要なせん断応力が、ある程度小さいことを意味する。
The cleaning composition of the present invention has a characteristic that the viscosity is 100 to 500 mPa·s at a rotation speed of 1 rpm and 15 to 30 mPa·s at a rotation speed of 100 rpm, which means that the viscosity is high when a small shear stress is applied to the cleaning composition of the present invention, but is low when a large shear stress is applied.
Furthermore, the detergent composition of the present invention is characterized in that the yield value is 1 Pa or less, which means that the shear stress required to reduce the viscosity of the detergent composition is relatively small.
後述するように本発明の洗浄剤組成物は、泡状にして使用されることになる。
本発明の洗浄剤組成物では、測定温度５℃における、回転数１ｒｐｍのときの粘度が１００～５００ｍＰａ・ｓであるが、これはせん断応力が加わっていないときの粘度が高いことを意味する。
本発明の洗浄剤組成物は、このような特徴を有するので、泡状にして噴射された後、洗浄対象面への定着性が良好になり、付着した泡の流れ落ちが生じにくい。
As described below, the detergent composition of the present invention is used in the form of a foam.
The cleaning composition of the present invention has a viscosity of 100 to 500 mPa·s when the measurement temperature is 5° C. and the rotation speed is 1 rpm, which means that the viscosity is high when no shear stress is applied.
Since the cleaning composition of the present invention has such characteristics, after being sprayed in foam form, it adheres well to the surface to be cleaned, and the foam is less likely to run off.
本発明の洗浄剤組成物では、測定温度５℃における、回転数１００ｒｐｍのときの粘度が１５～３０ｍＰａ・ｓであるが、これはせん断応力が加わったときの粘度が低いことを意味する。
また、本発明の洗浄剤組成物では、測定温度５℃における、降伏値が１Ｐａ以下であるが、これは粘度が低下するのに必要なせん断応力が低いことを意味する。
本発明の洗浄剤組成物は、このような特徴を有するので、泡状にして噴射する際、洗浄剤組成物が詰まりにくくスムーズに噴射することができ、泡がきめ細かくなる。
The cleaning composition of the present invention has a viscosity of 15 to 30 mPa·s when the measurement temperature is 5° C. and the rotation speed is 100 rpm, which means that the viscosity is low when a shear stress is applied.
Furthermore, in the detergent composition of the present invention, the yield value at a measurement temperature of 5° C. is 1 Pa or less, which means that the shear stress required for reducing the viscosity is low.
The cleaning composition of the present invention has such characteristics, so that when sprayed in foam form, the cleaning composition is less likely to clog and can be sprayed smoothly, producing fine foam.
すなわち、本発明の洗浄剤組成物は、５℃において、泡状にして噴射しやすく、付着した泡の流れ落ちが生じにくく、泡がきめ細かくなる。
一般に、液体の粘度は低温になるほど増加する。常温でスプレー性に問題がなくても、低温時に増粘することにより、寒冷期などで、スプレー詰まりが発生することがある。よって、5℃のスプレー性は重要である。
That is, the cleaning composition of the present invention can be easily sprayed in foam form at 5° C., the foam adhered to the surface is unlikely to run off, and the foam is fine.
In general, the viscosity of a liquid increases as the temperature drops. Even if there are no problems with sprayability at normal temperatures, the viscosity increases at low temperatures, which can cause spray clogging in cold weather. Therefore, sprayability at 5°C is important.
本発明の洗浄剤組成物は、上記の洗浄剤組成物の粘度測定試験において、測定温度２０℃における、上記洗浄剤組成物の回転数１ｒｐｍのときの粘度が１００～５００ｍＰａ・ｓとなり、測定温度２０℃における、上記洗浄剤組成物の回転数１００ｒｐｍのときの粘度が１２～３０ｍＰａ・ｓとなり、上記の洗浄剤組成物のせん断応力測定試験において、測定温度２０℃における、上記洗浄剤組成物の降伏値は１Ｐａ以下であることが望ましい。
本発明の洗浄剤組成物がこのような特徴を有すると、２０℃においても、泡状に噴射しやすく、付着した泡の流れ落ちが生じにくく、泡がきめ細かくなる。
It is desirable that, in the above-mentioned viscosity measurement test of the cleaning composition of the present invention, the cleaning composition has a viscosity of 100 to 500 mPa s at a measurement temperature of 20° C. and a rotation speed of 1 rpm, and that the cleaning composition has a viscosity of 12 to 30 mPa s at a measurement temperature of 20° C. and a rotation speed of 100 rpm, and that in the above-mentioned shear stress measurement test of the cleaning composition, the cleaning composition has a yield value of 1 Pa or less at a measurement temperature of 20° C.
When the cleaning composition of the present invention has such characteristics, it can be easily sprayed in foam even at 20° C., the foam is less likely to run off, and the foam is fine.
本発明の洗浄剤組成物は、洗浄剤組成物のせん断応力測定試験において、測定温度５℃における、上記洗浄剤組成物の降伏値が０．１Ｐａ以上であることが望ましい。
測定温度５℃における、降伏値が０．１Ｐａ未満であると、壁面への定着性が低下しやすくなる。
The detergent composition of the present invention desirably has a yield value of 0.1 Pa or more at a measurement temperature of 5° C. in a shear stress measurement test of the detergent composition.
If the yield value at a measurement temperature of 5° C. is less than 0.1 Pa, the fixation to the wall surface is likely to decrease.
本発明の洗浄剤組成物は、偽塑性流体であることが望ましい。
本発明の洗浄剤組成物が偽塑性流体である場合、本発明の洗浄剤組成物は、せん断応力を受け続けると粘度が次第に低下し、その後、静止すると粘度が次第に上昇するという性質を有することになる。
The cleaning composition of the present invention is preferably a pseudoplastic fluid.
When the cleaning composition of the present invention is a pseudoplastic fluid, the cleaning composition of the present invention has the property that the viscosity gradually decreases when it is continuously subjected to shear stress, and then, when it comes to rest, the viscosity gradually increases.
本発明の洗浄剤組成物では、上記増粘剤は、
下記に示す増粘剤の粘度測定試験において、
回転数が１ｒｐｍのときの粘度が１００～５００ｍＰａ・ｓであり、
回転数が１０ｒｐｍのときの粘度が３５～７０ｍＰａ・ｓであり、
回転数が２０ｒｐｍのときの粘度が２５～５０ｍＰａ・ｓであり、
回転数が１００ｒｐｍのときの粘度が１０～２５ｍＰａ・ｓであり、
増粘剤の粘度測定試験において得られた、上記増粘剤の回転数が１ｒｐｍのときの粘度と、回転数が１００ｒｐｍのときの粘度との比が、（回転数が１００ｒｐｍのときの粘度（ｍＰａ・ｓ））／（回転数が１ｒｐｍのときの粘度（ｍＰａ・ｓ））＝０．０６～０．１０となることが望ましい。
増粘剤の粘度測定試験：
増粘剤の濃度が０．３質量％となるように増粘剤を水に溶解させ試験溶液を作製し、Ｅ型粘度計により測定温度２０℃、回転数１ｒｐｍ、１０ｒｐｍ、２０ｒｐｍ及び１００ｒｐｍの条件で当該試験溶液の粘度の測定を開始し、各回転数において、測定開始から１分後に測定された当該試験溶液の粘度を、それぞれ、増粘剤の粘度測定試験における、回転数が１ｒｐｍのときの粘度、回転数が１０ｒｐｍのときの粘度、回転数が２０ｒｐｍのときの粘度、回転数が１００ｒｐｍのときの粘度とする。
本発明の洗浄剤組成物において、増粘剤が上記性質を有すると、泡状にした際に、付着した泡の流れ落ちが生じにくく、泡がきめ細かくなる。
特に、液温が５～２０℃においてスプレー性が良好になる。
In the cleaning composition of the present invention, the thickener is
In the viscosity measurement test of the thickener shown below,
The viscosity at a rotation speed of 1 rpm is 100 to 500 mPa·s,
The viscosity is 35 to 70 mPa·s when the rotation speed is 10 rpm,
The viscosity is 25 to 50 mPa·s when the rotation speed is 20 rpm,
The viscosity is 10 to 25 mPa·s when the rotation speed is 100 rpm,
It is desirable that the ratio of the viscosity of the thickener when the rotation speed is 1 rpm to the viscosity when the rotation speed is 100 rpm, obtained in a viscosity measurement test of the thickener, be (viscosity (mPa·s) when the rotation speed is 100 rpm)/(viscosity (mPa·s) when the rotation speed is 1 rpm)=0.06 to 0.10.
Viscosity measurement test for thickeners:
A test solution was prepared by dissolving a thickener in water so that the concentration of the thickener was 0.3% by mass, and measurement of the viscosity of the test solution was started using an E-type viscometer at a measurement temperature of 20°C and rotation speeds of 1 rpm, 10 rpm, 20 rpm, and 100 rpm. The viscosities of the test solution measured 1 minute after the start of measurement at each rotation speed were designated as the viscosity at a rotation speed of 1 rpm, the viscosity at a rotation speed of 10 rpm, the viscosity at a rotation speed of 20 rpm, and the viscosity at a rotation speed of 100 rpm, respectively, in the viscosity measurement test of the thickener.
In the cleaning composition of the present invention, when the thickener has the above-mentioned properties, when the composition is foamed, the foam is less likely to run off and the foam becomes fine.
In particular, the sprayability is good when the liquid temperature is 5 to 20°C.
本発明の洗浄剤組成物では、上記増粘剤は、ｙ軸を粘度（ｍＰａ・ｓ）の軸とし、ｘ軸を回転数（ｒｐｍ）の軸としたグラフにおいて、上記の増粘剤の粘度測定試験により得られた粘度をプロットした際に、上記の増粘剤の粘度測定試験により得られた粘度が、下記式（１）～（３）を満たす範囲に含まれることが望ましい。
ｙ＝ｂｘａ・・・（１）
－０．６０≦ａ・・・（２）
１００≦ｂ≦５００・・・（３）
In the cleaning agent composition of the present invention, when the viscosity of the thickener obtained by the viscosity measurement test is plotted on a graph with the y-axis representing the viscosity (mPa s) and the x-axis representing the rotation speed (rpm), it is preferable that the viscosity of the thickener obtained by the viscosity measurement test falls within a range that satisfies the following formulas (1) to (3):
y = bx a ... (1)
−0.60≦a (2)
100≦b≦500...(3)
また、本発明の洗浄剤組成物では、上記増粘剤は、ｙ軸を粘度（ｍＰａ・ｓ）の常用対数軸とし、ｘ軸を回転数（ｒｐｍ）の常用対数軸としたグラフにおいて、上記の増粘剤の粘度測定試験により得られた粘度をプロットし、最小二乗法により近似直線を求めた際に、上記近似直線の傾きが、－０．６０以上となることが望ましい。 Furthermore, in the cleaning composition of the present invention, when the viscosity of the thickener obtained by the viscosity measurement test is plotted on a graph in which the y-axis is a common logarithm axis of viscosity (mPa·s) and the x-axis is a common logarithm axis of rotation speed (rpm), and an approximation line is obtained by the least squares method, it is desirable that the slope of the approximation line be -0.60 or more.
増粘剤が上記範囲の性質を有する場合、本発明の洗浄剤組成物を泡状にして噴射する際に、応力がかかることで、洗浄剤組成物の粘度がより適度に低下し、泡状にしやすくなる。
また、本発明の洗浄剤組成物が洗浄対象面に付着した後、洗浄剤組成物の粘度がより適度に上昇し、付着した泡の流れ落ちが生じにくくなる。
When the thickener has properties within the above ranges, when the cleaning composition of the present invention is foamed and sprayed, stress is applied to the cleaning composition, which reduces the viscosity of the cleaning composition to an appropriate degree, making it easier to foam the composition.
In addition, after the cleaning composition of the present invention is applied to the surface to be cleaned, the viscosity of the cleaning composition increases more appropriately, making it difficult for the applied foam to run off.
本発明の洗浄剤組成物では、上記増粘剤は、キサンタンガム、ゲランガム、グアーガム、ローカストビーンガム、ペクチン及びカラギーナンからなる群から選択された少なくとも１種であることが望ましい。
これらの化合物は、本発明の洗浄剤組成物における増粘剤として適している。
In the cleaning composition of the present invention, the thickener is desirably at least one selected from the group consisting of xanthan gum, gellan gum, guar gum, locust bean gum, pectin and carrageenan.
These compounds are suitable as thickeners in the cleaning compositions of the present invention.
本発明の洗浄剤組成物では、上記界面活性剤の含有量は、０．１～２０．０質量％であることが望ましい。
界面活性剤の含有量が０．１質量％未満であると、界面活性剤の量が少ないので充分な洗浄効果が得られにくくなる。
界面活性剤の含有量が２０．０質量％を超えると、外観が均一透明を保ちにくくなる。
In the cleaning composition of the present invention, the content of the surfactant is desirably 0.1 to 20.0% by mass.
If the content of the surfactant is less than 0.1% by mass, the amount of the surfactant is so small that it is difficult to obtain a sufficient cleaning effect.
If the surfactant content exceeds 20.0% by mass, it becomes difficult to maintain a uniform and transparent appearance.
本発明の洗浄剤組成物では、上記増粘剤の含有量は、０．１～２．０質量％であることが望ましい。
増粘剤の含有量が０．１質量％未満であると、粘度が低くなりすぎて、垂直面や傾斜面のような洗浄面に洗浄剤組成物が定着しにくくなり、流れ落ちやすくなる。
増粘剤の含有量が２．０質量％を超えると、粘度が高くなりすぎて、泡状にして噴射する際に、泡噴射器が詰まりやすくなる。
In the cleaning composition of the present invention, the content of the thickener is desirably 0.1 to 2.0% by mass.
If the content of the thickener is less than 0.1% by mass, the viscosity will be too low, making it difficult for the detergent composition to adhere to a cleaning surface such as a vertical or inclined surface, and it will tend to run off.
If the content of the thickener exceeds 2.0% by mass, the viscosity becomes too high, and the foam sprayer is likely to become clogged when the foam is sprayed.
本発明の洗浄剤組成物は、さらに、アルカリ剤を含むことが望ましい。
本発明の洗浄剤組成物がアルカリ剤を含むことにより、油汚れに対する洗浄力が向上する。
The cleaning composition of the present invention desirably further contains an alkaline agent.
By including an alkaline agent in the detergent composition of the present invention, the cleaning power against oily stains is improved.
本発明の洗浄剤組成物では、上記アルカリ剤の含有量は、０．１～２０．０質量％であることが望ましい。
アルカリ剤の含有量が０．１質量％未満であると、アルカリ剤の量が少ないので充分な洗浄効果が得られにくくなる。
アルカリ剤の含有量が２０．０質量％を超えると、外観が均一透明を保ちにくくなる。
In the cleaning composition of the present invention, the content of the alkaline agent is desirably 0.1 to 20.0% by mass.
If the content of the alkaline agent is less than 0.1% by mass, the amount of the alkaline agent is so small that it is difficult to obtain a sufficient cleaning effect.
If the content of the alkali agent exceeds 20.0% by mass, it becomes difficult to maintain a uniform and transparent appearance.
本発明の洗浄剤組成物は、ｐＨが６以上であることが望ましい。 The cleaning composition of the present invention preferably has a pH of 6 or higher.
本発明の洗浄剤組成物は、泡噴射器用であることが望ましい。
泡噴射器を用いることにより、本発明の洗浄剤組成物を泡状にして洗浄対象面に噴射・付着させることができる。
The cleaning composition of the present invention is preferably for use in foam sprayers.
By using a foam sprayer, the cleaning composition of the present invention can be made into a foam and sprayed onto and adhered to the surface to be cleaned.
本発明の洗浄剤組成物は、粘度及び降伏値が上記の所定の範囲内である。
そのため、５℃において、本発明の洗浄剤組成物を泡状にして、洗浄対象面に噴射・付着させた際に、泡状に噴射しやすく、付着した泡の流れ落ちが生じにくく、泡がきめ細かくなる。
The cleaning composition of the present invention has a viscosity and a yield value within the above-mentioned ranges.
Therefore, when the cleaning composition of the present invention is foamed and sprayed and adhered to a surface to be cleaned at 5°C, the foam is easily sprayed, the adhered foam is less likely to run off, and the foam is fine.
以下、本発明の洗浄剤組成物について、具体的な実施形態を示しながら説明するが、本発明はこれらの実施形態だけに限定されるものではない。 The cleaning composition of the present invention will be described below with reference to specific embodiments, but the present invention is not limited to these embodiments.
本発明の洗浄剤組成物は、水と、界面活性剤と、増粘剤とを含む洗浄剤組成物であり、所定の粘度及び降伏値を有する。
まず、洗浄剤組成物の粘度及び降伏値について以下に説明する。
The cleaning composition of the present invention is a cleaning composition containing water, a surfactant, and a thickener, and has a predetermined viscosity and yield value.
First, the viscosity and yield value of the cleaning composition will be described below.
本発明の洗浄剤組成物は、下記に示す洗浄剤組成物の粘度測定試験において、測定温度５℃における、洗浄剤組成物の回転数１ｒｐｍのときの粘度が１００～５００ｍＰａ・ｓである。測定温度５℃における、洗浄剤組成物の回転数１ｒｐｍのときの粘度は、１５０～４５０ｍＰａ・ｓとなることが望ましく、２００～４００ｍＰａ・ｓとなることがより望ましい。 In the cleaning composition of the present invention, in the viscosity measurement test of the cleaning composition shown below, the viscosity is 100 to 500 mPa·s when the cleaning composition is rotated at 1 rpm at a measurement temperature of 5°C. The viscosity of the cleaning composition when the cleaning composition is rotated at 1 rpm at a measurement temperature of 5°C is preferably 150 to 450 mPa·s, and more preferably 200 to 400 mPa·s.
また、本発明の洗浄剤組成物は、下記に示す洗浄剤組成物の粘度測定試験において、測定温度５℃における、洗浄剤組成物の回転数１００ｒｐｍのときの粘度が１５～３０ｍＰａ・ｓである。測定温度５℃における、洗浄剤組成物の回転数１００ｒｐｍのときの粘度は、２０～３０ｍＰａ・ｓとなることが望ましく、２２～２９ｍＰａ・ｓとなることがより望ましい。 Furthermore, in the viscosity measurement test of the cleaning composition shown below, the cleaning composition of the present invention has a viscosity of 15 to 30 mPa·s when the cleaning composition is rotated at 100 rpm at a measurement temperature of 5°C. The viscosity of the cleaning composition when the cleaning composition is rotated at 100 rpm at a measurement temperature of 5°C is preferably 20 to 30 mPa·s, and more preferably 22 to 29 mPa·s.
＜洗浄剤組成物の粘度測定試験＞
以下に、「洗浄剤組成物の粘度測定試験」について説明する。
まず、測定対象物となる洗浄剤組成物を、Ｅ型粘度計により、回転数１ｒｐｍ及び１００ｒｐｍの条件で粘度の測定を開始する。
各回転数において、測定開始から１分後に測定された当該洗浄剤組成物の粘度を、それぞれ、洗浄剤組成物の粘度測定試験における、回転数が１ｒｐｍのときの粘度及び回転数が１００ｒｐｍのときの粘度とする。
Ｅ型粘度計としては、例えば、東機産業株式会社製、型番：ＴＶＥ－２５Ｅを使用することができる。
<Viscosity measurement test of cleaning composition>
The "Viscosity measurement test for cleaning composition" will be described below.
First, the viscosity of the cleaning composition to be measured is measured using an E-type viscometer at rotation speeds of 1 rpm and 100 rpm.
At each rotation speed, the viscosity of the cleaning composition measured 1 minute after the start of measurement is defined as the viscosity at a rotation speed of 1 rpm and the viscosity at a rotation speed of 100 rpm in the viscosity measurement test of the cleaning composition, respectively.
As the E-type viscometer, for example, a model TVE-25E manufactured by Toki Sangyo Co., Ltd. can be used.
本発明の洗浄剤組成物において、回転数１ｒｐｍのときの粘度が１００～５００ｍＰａ・ｓであり、回転数１００ｒｐｍのときの粘度が１５～３０ｍＰａ・ｓとなるという特徴を有することは、本発明の洗浄剤組成物に加えるせん断応力が小さい場合には粘度が高いが、加えるせん断応力が大きい場合には、粘度が低いことを意味する。 The cleaning composition of the present invention has a characteristic that the viscosity is 100 to 500 mPa·s at a rotation speed of 1 rpm and 15 to 30 mPa·s at a rotation speed of 100 rpm, which means that the viscosity is high when the shear stress applied to the cleaning composition of the present invention is small, but is low when the shear stress applied is large.
本発明の洗浄剤組成物は、泡状にして使用されることになる。
本発明の洗浄剤組成物では、測定温度５℃における、回転数１ｒｐｍのときの粘度が１００～５００ｍＰａ・ｓであるが、これはせん断応力が加わっていないときの粘度が高いことを意味する。
本発明の洗浄剤組成物は、このような特徴を有するので、泡状にして噴射された後、洗浄対象面への定着性が良好になり、付着した泡の流れ落ちが生じにくい。
The cleaning composition of the present invention is used in the form of a foam.
The cleaning composition of the present invention has a viscosity of 100 to 500 mPa·s when the measurement temperature is 5° C. and the rotation speed is 1 rpm, which means that the viscosity is high when no shear stress is applied.
Since the cleaning composition of the present invention has such characteristics, after being sprayed in foam form, it adheres well to the surface to be cleaned, and the foam is less likely to run off.
本発明の洗浄剤組成物では、測定温度５℃における、回転数１００ｒｐｍのときの粘度が１５～３０ｍＰａ・ｓであるが、これはせん断応力が加わったときの粘度が低いことを意味する。
そのため、本発明の洗浄剤組成物を、泡状にして噴射する際、スムーズに噴射することができ、泡がきめ細かくなる。
The cleaning composition of the present invention has a viscosity of 15 to 30 mPa·s when the measurement temperature is 5° C. and the rotation speed is 100 rpm, which means that the viscosity is low when a shear stress is applied.
Therefore, when the cleaning composition of the present invention is sprayed in foam form, it can be sprayed smoothly and the foam becomes fine.
なお、測定温度５℃における、回転数１ｒｐｍのときの粘度が５００ｍＰａ・ｓを超えると、洗浄対象面に付着後の洗浄剤組成物の粘度が高くなるので、拭き取りにくくなる。また、泡噴射器で洗浄剤組成物を噴射することが困難になり、洗浄対象面まで洗浄剤が届きにくくなる。
測定温度５℃における、回転数１００ｒｐｍのときの粘度が１５ｍＰａ・ｓ未満であると、壁面への付着性が低下しやすくなる。
If the viscosity exceeds 500 mPa·s at a measurement temperature of 5° C. and a rotation speed of 1 rpm, the viscosity of the cleaning composition after adhering to the surface to be cleaned will be high, making it difficult to wipe off. Also, it will be difficult to spray the cleaning composition with a foam sprayer, making it difficult for the cleaning composition to reach the surface to be cleaned.
If the viscosity is less than 15 mPa·s when the measurement temperature is 5° C. and the rotation speed is 100 rpm, the adhesion to the wall surface is likely to decrease.
本発明の洗浄剤組成物は、上記の洗浄剤組成物の粘度測定試験において、測定温度２０℃における、洗浄剤組成物の回転数１ｒｐｍのときの粘度が１００～５００ｍＰａ・ｓであることが望ましく、１５０～４５０ｍＰａ・ｓとなることがより望ましく、２００～４００ｍＰａ・ｓとなることがさらに望ましい。 In the above-mentioned viscosity measurement test of the cleaning composition of the present invention, the viscosity at a measurement temperature of 20°C and a rotation speed of the cleaning composition of 1 rpm is preferably 100 to 500 mPa·s, more preferably 150 to 450 mPa·s, and even more preferably 200 to 400 mPa·s.
また、本発明の洗浄剤組成物は、上記の洗浄剤組成物の粘度測定試験において、測定温度２０℃における、洗浄剤組成物の回転数１００ｒｐｍのときの粘度が１２～３０ｍＰａ・ｓであることが望ましく、１８～２８ｍＰａ・ｓとなることがより望ましく、１８～２５ｍＰａ・ｓとなることがさらに望ましい。 Furthermore, in the above-mentioned viscosity measurement test of the cleaning composition of the present invention, the viscosity at a measurement temperature of 20°C and a rotation speed of the cleaning composition of 100 rpm is preferably 12 to 30 mPa·s, more preferably 18 to 28 mPa·s, and even more preferably 18 to 25 mPa·s.
本発明の洗浄剤組成物がこのような特徴を有すると、２０℃においても、泡状に噴射しやすく、付着した泡の流れ落ちが生じにくく、泡がきめ細かくなる。 When the cleaning composition of the present invention has these characteristics, it is easy to spray in foam even at 20°C, the attached foam is less likely to run off, and the foam is fine.
本発明の洗浄剤組成物は、下記に示す洗浄剤組成物のせん断応力測定試験において、測定温度５℃における、洗浄剤組成物の降伏値が１Ｐａ以下である。
測定温度５℃における、洗浄剤組成物の降伏値は、０．１～１Ｐａであることが望ましく、０．２～１Ｐａであることがより望ましく、０．３～０．９Ｐａであることがさらに望ましい。
＜洗浄剤組成物の粘度測定試験＞
以下に、「洗浄剤組成物のせん断応力測定試験」について説明する。
まず、Ｅ型粘度計により、せん断速度３．８３ｓ－１、３８．３ｓ－１、７６．６ｓ－１及び３８３ｓ－１の条件で洗浄剤組成物のせん断応力の測定を開始しする。
測定開始から１分後に測定された洗浄剤組成物のせん断応力を各せん断速度におけるせん断応力とする。
次に、ｘ軸をせん断速度（ｓ－１）の常用対数軸とし、ｙ軸をせん断応力（Ｐａ）の常用対数軸としたグラフに、測定されたせん断応力の値をプロットし、最小二乗法により近似直線を算出し、得られた近似直線のｙ軸の切片の値を降伏値とする。
Ｅ型粘度計としては、例えば、東機産業株式会社製、型番：ＴＶＥ－２５Ｅを使用することができる。
せん断速度は、Ｅ型粘度計に用いるコーンロータの固有係数と回転数との積により設定することができる。
例えば、東機産業株式会社製のコーンロータ（型番：１°３４´×Ｒ２４）は、固有係数が３．８３なので、せん断速度を３．８３ｓ－１、３８．３ｓ－１、７６．６ｓ－１及び３８３ｓ－１とする場合には、回転数を１ｒｐｍ、１０ｒｐｍ、２０ｒｐｍ及び１００ｒｐｍとすればよい。
The detergent composition of the present invention has a yield value of 1 Pa or less at a measurement temperature of 5° C. in the shear stress measurement test of the detergent composition shown below.
The yield value of the cleaning composition at a measurement temperature of 5° C. is preferably 0.1 to 1 Pa, more preferably 0.2 to 1 Pa, and even more preferably 0.3 to 0.9 Pa.
<Viscosity measurement test of cleaning composition>
The "shear stress measurement test for the cleaning composition" will be described below.
First, measurement of the shear stress of the cleaning composition is started using an E-type viscometer under conditions of shear rates of 3.83 s -1 , 38.3 s -1 , 76.6 s -1 and 383 s -1 .
The shear stress of the cleaning composition measured one minute after the start of measurement is defined as the shear stress at each shear rate.
Next, the measured shear stress values are plotted on a graph with the x-axis representing the common logarithm of shear rate (s -1 ) and the y-axis representing the common logarithm of shear stress (Pa), an approximation line is calculated by the least squares method, and the intercept of the y-axis of the obtained approximation line is taken as the yield value.
As the E-type viscometer, for example, a model TVE-25E manufactured by Toki Sangyo Co., Ltd. can be used.
The shear rate can be set by the product of the inherent coefficient of the cone rotor used in the E-type viscometer and the rotation speed.
For example, the cone rotor (model number: 1°34'×R24) manufactured by Toki Sangyo Co., Ltd. has a specific coefficient of 3.83, so when the shear rates are 3.83 s −1 , 38.3 s −1 , 76.6 s −1 and 383 s −1 , the rotation speeds can be 1 rpm, 10 rpm, 20 rpm and 100 rpm.
また、本発明の洗浄剤組成物では、測定温度５℃における、降伏値が１Ｐａ以下であるが、これは粘度が低下するのに必要なせん断応力が低いことを意味する。
そのため、本発明の洗浄剤組成物を、泡状にして噴射する際、スムーズに噴射することができ、泡がきめ細かくなる。
Furthermore, in the detergent composition of the present invention, the yield value at a measurement temperature of 5° C. is 1 Pa or less, which means that the shear stress required for reducing the viscosity is low.
Therefore, when the cleaning composition of the present invention is sprayed in foam form, it can be sprayed smoothly and the foam becomes fine.
測定温度５℃における、降伏値が０．１Ｐａ未満であると、壁面への付着性が低下しやすくなる。 If the yield value is less than 0.1 Pa at a measurement temperature of 5°C, adhesion to the wall surface is likely to decrease.
また、本発明の洗浄剤組成物は、測定温度２０℃における、洗浄剤組成物の降伏値が１Ｐａ以下であることが望ましく、０．１５～１Ｐａであることがより望ましく、０．１８～０．９Ｐａであることがさらに望ましい。 Furthermore, the yield value of the cleaning composition of the present invention at a measurement temperature of 20°C is preferably 1 Pa or less, more preferably 0.15 to 1 Pa, and even more preferably 0.18 to 0.9 Pa.
本発明の洗浄剤組成物がこのような特徴を有すると、２０℃においても、泡状に噴射しやすく、泡がきめ細かくなる。 When the cleaning composition of the present invention has these characteristics, it is easy to spray in foam even at 20°C, and the foam is fine.
本発明の洗浄剤組成物は、偽塑性流体であることが望ましい。
本発明の洗浄剤組成物が偽塑性流体である場合、本発明の洗浄剤組成物は、せん断応力を受け続けると粘度が次第に低下し、その後、静止すると粘度が次第に上昇するという性質を有することになる。
The cleaning composition of the present invention is preferably a pseudoplastic fluid.
When the cleaning composition of the present invention is a pseudoplastic fluid, the cleaning composition of the present invention has the property that the viscosity gradually decreases when it is continuously subjected to shear stress, and then, when it comes to rest, the viscosity gradually increases.
次に、本発明の洗浄剤組成物の各組成について以下に説明する。
（界面活性剤）
界面活性剤としては、アニオン性界面活性剤、両性界面活性剤、ノニオン性界面活性剤、カチオン性界面活性剤が挙げられる。
アニオン性界面活性剤としては、脂肪酸塩、アルキルエーテルカルボン酸塩（ＡＥＳ）、アルカンスルホン酸塩、α－オレフィンスルホン酸塩、α－スルホメチルエステル塩、アルキルベンゼンスルホン酸塩（ＬＡＳ）、アルキルコハク酸塩、アルキル硫酸エステル塩、アルキルエーテル硫酸エステル塩、ポリオキシアルキレンアルキル硫酸エステル塩等が挙げられる。
両性界面活性剤としては、アルキルアミノベタイン、アルキルアミドベタイン、アルキルアミノスルホベタイン、アルキルアミンオキシド等が挙げられる。
ノニオン性界面活性剤としては、ポリオキシアルキレンアルキルエーテル、ポリオキシアルキレンアルキルフェニルエーテル、ポリオキシアルキレン脂肪酸エステル、ポリオキシアルキレンソルビタン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステル、アルキルポリグルコシド、ポリオキシエチレンメチルエーテル脂肪酸エステル、脂肪酸アルカノールアミド、ポリオキシアルキレンアルキルアミン等が挙げられる。
カチオン性界面活性剤としては、アルキルベンジルジメチルアンモニウム塩、アルキルジメチルヒドロキシエチルアンモニウム塩、ジアルキルジメチルアンモニウム塩、トリアルキル型四級アンモニウム塩等が挙げられる。
Next, each component of the detergent composition of the present invention will be described below.
(Surfactant)
The surfactant may be an anionic surfactant, an amphoteric surfactant, a nonionic surfactant, or a cationic surfactant.
Examples of the anionic surfactant include fatty acid salts, alkyl ether carboxylates (AES), alkanesulfonates, α-olefin sulfonates, α-sulfomethyl ester salts, alkylbenzenesulfonates (LAS), alkylsuccinates, alkyl sulfates, alkyl ether sulfates, and polyoxyalkylene alkyl sulfates.
Examples of the amphoteric surfactant include alkylaminobetaine, alkylamidobetaine, alkylaminosulfobetaine, and alkylamine oxide.
Examples of nonionic surfactants include polyoxyalkylene alkyl ethers, polyoxyalkylene alkylphenyl ethers, polyoxyalkylene fatty acid esters, polyoxyalkylene sorbitan fatty acid esters, polyglycerin fatty acid esters, sorbitan fatty acid esters, sucrose fatty acid esters, alkyl polyglucosides, polyoxyethylene methyl ether fatty acid esters, fatty acid alkanolamides, and polyoxyalkylene alkylamines.
Examples of the cationic surfactant include alkylbenzyldimethylammonium salts, alkyldimethylhydroxyethylammonium salts, dialkyldimethylammonium salts, and trialkyl-type quaternary ammonium salts.
本発明の洗浄剤組成物では、界面活性剤の含有量は、０．１～２０．０質量％であることが望ましく、１．５～１０．０質量％であることがより望ましい。
界面活性剤の含有量が０．１質量％未満であると、界面活性剤の量が少ないので充分な洗浄効果が得られにくくなる。
界面活性剤の含有量が２０．０質量％を超えると、外観が均一透明を保ちにくくなる。
In the cleaning composition of the present invention, the content of the surfactant is preferably 0.1 to 20.0% by mass, and more preferably 1.5 to 10.0% by mass.
If the content of the surfactant is less than 0.1% by mass, the amount of the surfactant is so small that it is difficult to obtain a sufficient cleaning effect.
If the surfactant content exceeds 20.0% by mass, it becomes difficult to maintain a uniform and transparent appearance.
（増粘剤）
本発明の洗浄剤組成物の増粘剤は、下記に示す増粘剤の粘度測定試験において以下の性質を示すことが望ましい。
回転数が１ｒｐｍのときの粘度が１００～５００ｍＰａ・ｓである。
回転数が１０ｒｐｍのときの粘度が３５～７０ｍＰａ・ｓである。
回転数が２０ｒｐｍのときの粘度が２５～５０ｍＰａ・ｓである。
回転数が１００ｒｐｍのときの粘度が１０～２５ｍＰａ・ｓである。
増粘剤の回転数が１ｒｐｍのときの粘度と、回転数が１００ｒｐｍのときの粘度との比が、（回転数が１００ｒｐｍのときの粘度（ｍＰａ・ｓ））／（回転数が１ｒｐｍのときの粘度（ｍＰａ・ｓ））＝０．０６～０．１０である。
(Thickener)
It is desirable that the thickener for the cleaning composition of the present invention exhibits the following properties in the viscosity measurement test for thickeners described below.
The viscosity is 100 to 500 mPa·s when the rotation speed is 1 rpm.
The viscosity is 35 to 70 mPa·s when the rotation speed is 10 rpm.
The viscosity is 25 to 50 mPa·s when the rotation speed is 20 rpm.
The viscosity is 10 to 25 mPa·s when the rotation speed is 100 rpm.
The ratio of the viscosity of the thickener when the rotation speed is 1 rpm to the viscosity when the rotation speed is 100 rpm is (viscosity (mPa·s) when the rotation speed is 100 rpm)/(viscosity (mPa·s) when the rotation speed is 1 rpm)=0.06 to 0.10.
＜増粘剤の粘度測定試験＞
まず、増粘剤の濃度が０．３質量％となるように増粘剤を水に溶解させ試験溶液を作製する。
<Viscosity measurement test of thickener>
First, a test solution is prepared by dissolving a thickener in water so that the concentration of the thickener is 0.3% by mass.
次に、作製した試験溶液１ｍＬを用いて、Ｅ型粘度計により測定温度２０℃、回転数１ｒｐｍ、１０ｒｐｍ、２０ｒｐｍ及び１００ｒｐｍの条件で当該試験溶液の粘度の測定を開始する。
Ｅ型粘度計としては、例えば、東機産業株式会社製、型番：ＴＶＥ－２５Ｅを使用することができる。
Next, using 1 mL of the prepared test solution, measurement of the viscosity of the test solution is started using an E-type viscometer at a measurement temperature of 20° C. and rotation speeds of 1 rpm, 10 rpm, 20 rpm, and 100 rpm.
As the E-type viscometer, for example, a model TVE-25E manufactured by Toki Sangyo Co., Ltd. can be used.
次に、測定開始から１分後に各回転数における試験溶液の粘度を測定する。
回転数１ｒｐｍ、１０ｒｐｍ、２０ｒｐｍ及び１００ｒｐｍの条件で得られた各粘度を、それぞれ、増粘剤の粘度測定試験における、回転数が１ｒｐｍのときの粘度、回転数が１０ｒｐｍのときの粘度、回転数が２０ｒｐｍのときの粘度、回転数が１００ｒｐｍのときの粘度とする。
Next, one minute after the start of the measurement, the viscosity of the test solution at each rotation speed is measured.
The viscosities obtained under the conditions of rotation speeds of 1 rpm, 10 rpm, 20 rpm, and 100 rpm are respectively defined as the viscosity at a rotation speed of 1 rpm, the viscosity at a rotation speed of 10 rpm, the viscosity at a rotation speed of 20 rpm, and the viscosity at a rotation speed of 100 rpm in the viscosity measurement test of the thickener.
本発明の洗浄剤組成物の増粘剤は、上記の増粘剤の粘度測定試験において以下の性質を示すことがより望ましい。
ずなわち、回転数が１ｒｐｍのときの粘度は、１００～４５０ｍＰａ・ｓであることが望ましく、１００～３００ｍＰａ・ｓであることがより望ましい。
回転数が１０ｒｐｍのときの粘度は、３５～６０ｍＰａ・ｓであることが望ましく、３５～５０ｍＰａ・ｓであることがより望ましい。
回転数が２０ｒｐｍのときの粘度は、２５～４５ｍＰａ・ｓであることが望ましく、２５～４０ｍＰａ・ｓであることがより望ましい。
回転数が１００ｒｐｍのときの粘度は、１０～２０ｍＰａ・ｓであることが望ましく、１０～１５ｍＰａ・ｓであることがより望ましい。
It is more desirable that the thickener of the cleaning composition of the present invention exhibits the following properties in the above-mentioned viscosity measurement test of the thickener.
That is, the viscosity at a rotation speed of 1 rpm is preferably 100 to 450 mPa·s, and more preferably 100 to 300 mPa·s.
The viscosity at a rotation speed of 10 rpm is preferably 35 to 60 mPa·s, and more preferably 35 to 50 mPa·s.
The viscosity at a rotation speed of 20 rpm is preferably 25 to 45 mPa·s, and more preferably 25 to 40 mPa·s.
The viscosity at a rotation speed of 100 rpm is preferably 10 to 20 mPa·s, and more preferably 10 to 15 mPa·s.
また、本発明の洗浄剤組成物において、増粘剤の回転数が１ｒｐｍのときの粘度と、回転数が１００ｒｐｍのときの粘度との比は、（回転数が１ｒｐｍのときの粘度（ｍＰａ・ｓ））／（回転数が１００ｒｐｍのときの粘度（ｍＰａ・ｓ））＝０．０６～０．０９であることが望ましく、０．０７～０．０９であることがより望ましい。 Furthermore, in the cleaning composition of the present invention, the ratio of the viscosity of the thickener when the rotation speed is 1 rpm to the viscosity when the rotation speed is 100 rpm is preferably (viscosity (mPa·s) when the rotation speed is 1 rpm)/(viscosity (mPa·s) when the rotation speed is 100 rpm)=0.06 to 0.09, and more preferably 0.07 to 0.09.
増粘剤が上記性質を有する場合、本発明の洗浄剤組成物を泡状にして噴射する際に、洗浄剤組成物の粘度が適度に低下し、泡状にしやすくなる。
また、本発明の洗浄剤組成物が洗浄対象面に付着した後、洗浄剤組成物の粘度が適度に上昇し、付着した泡の流れ落ちが生じにくくなる。
When the thickener has the above-mentioned properties, when the detergent composition of the present invention is foamed and sprayed, the viscosity of the detergent composition is appropriately reduced, making it easier to foam.
In addition, after the cleaning composition of the present invention is applied to the surface to be cleaned, the viscosity of the cleaning composition increases appropriately, making it difficult for the applied foam to run off.
また、本発明の洗浄剤組成物では、上記増粘剤の粘度測定試験において得られた各回転数における粘度（ｍＰａ・ｓ）をｙ軸に、回転数（ｒｐｍ）をｘ軸にプロットした際に、下記式（１）～（３）を満たす範囲に含まれることが望ましい。
ｙ＝ｂｘａ・・・（１）
－０．６０≦ａ・・・（２）
１００≦ｂ≦５００・・・（３）
なお、式（２）におけるａの範囲は、－０．６０～－０．３０であることがより望ましく、－０．６０～－０．４０であることがさらに望ましい。
また、式（３）におけるｂの範囲は、１００～４００であることがより望ましく、１００～３００であることがさらに望ましい。
In addition, in the cleaning composition of the present invention, when the viscosity (mPa s) at each rotation speed obtained in the viscosity measurement test of the thickener is plotted on the y-axis and the rotation speed (rpm) on the x-axis, it is desirable that the viscosity be within a range satisfying the following formulas (1) to (3).
y = bx a ... (1)
−0.60≦a (2)
100≦b≦500...(3)
The range of a in formula (2) is more preferably from −0.60 to −0.30, and even more preferably from −0.60 to −0.40.
Moreover, the range of b in formula (3) is more preferably 100-400, and further preferably 100-300.
また、本発明の洗浄剤組成物では、増粘剤は、ｙ軸を粘度（ｍＰａ・ｓ）の常用対数軸とし、ｘ軸を回転数（ｒｐｍ）の常用対数軸としたグラフにおいて、上記の増粘剤の粘度測定試験により得られた粘度をプロットし、最小二乗法により近似直線を求めた際に、上記近似直線の傾きが、－０．６０以上となることが望ましく、－０．６０～－０．４０になることがより望ましい。 In addition, in the cleaning composition of the present invention, when the viscosity of the thickener obtained by the viscosity measurement test is plotted on a graph in which the y-axis is a common logarithm axis of viscosity (mPa·s) and the x-axis is a common logarithm axis of rotation speed (rpm), and an approximation line is determined by the least squares method, it is preferable that the slope of the approximation line be -0.60 or more, and more preferably -0.60 to -0.40.
増粘剤が上記性質を有する場合、本発明の洗浄剤組成物を泡状にして噴射する際に、洗浄剤組成物の粘度がより適度に低下し、泡状にしやすくなる。
また、本発明の洗浄剤組成物が洗浄対象面に付着した後、洗浄剤組成物の粘度がより適度に上昇し、付着した泡の流れ落ちが生じにくくなる。
When the thickener has the above-mentioned properties, when the detergent composition of the present invention is sprayed in foam form, the viscosity of the detergent composition is more appropriately reduced, making it easier to foam.
In addition, after the cleaning composition of the present invention is applied to the surface to be cleaned, the viscosity of the cleaning composition increases more appropriately, making it difficult for the applied foam to run off.
本発明の洗浄剤組成物において、増粘剤は、キサンタンガム、ゲランガム、グアーガム、ローカストビーンガム、ペクチン及びカラギーナンからなる群から選択された少なくとも１種であることが望ましい。
これらの中ではキサンタンガムであることが望ましい。
これらの化合物は、本発明の洗浄剤組成物における増粘剤として適している。
In the detergent composition of the present invention, the thickener is desirably at least one selected from the group consisting of xanthan gum, gellan gum, guar gum, locust bean gum, pectin and carrageenan.
Of these, xanthan gum is preferred.
These compounds are suitable as thickeners in the cleaning compositions of the present invention.
本発明の洗浄剤組成物のｐＨは、６以上であることが望ましく、１１以上であることがより望ましく、１３以上であることがさらに望ましい。
特に洗浄剤組成物のｐＨが１１以上であると、油汚れに対する洗浄力を向上させることができる。
ｐＨの測定は、市販のｐＨメーター等を用いて行えばよいが、例えば、堀場製作所製、Ｄ－２１型を用いて測定することができる。
The pH of the cleaning composition of the present invention is preferably 6 or more, more preferably 11 or more, and even more preferably 13 or more.
In particular, when the pH of the detergent composition is 11 or more, the cleaning power against oily stains can be improved.
The pH may be measured using a commercially available pH meter, for example, Model D-21, manufactured by Horiba, Ltd.
本発明の洗浄剤組成物は、その他の成分として、アルカリ剤、溶剤、キレート剤、可溶化剤、安定化剤、色素、香料、防腐剤等を含んでいてもよい。 The cleaning composition of the present invention may contain other components such as an alkaline agent, a solvent, a chelating agent, a solubilizing agent, a stabilizer, a colorant, a fragrance, a preservative, etc.
本発明の洗浄剤組成物がアルカリ剤を含む場合、油汚れに対する洗浄力が向上する。
アルカリ剤としては、アルカリ金属水酸化物（水酸化ナトリウム、水酸化カリウム等）、炭酸塩又は炭酸水素塩（炭酸ナトリウム、炭酸カリウム、炭酸水素ナトリウム、炭酸水素カリウム等）、ケイ酸塩（メタケイ酸ナトリウム、セスキケイ酸ナトリウム、オルソケイ酸ナトリウム、メタケイ酸カリウム、セスキケイ酸カリウム、オルソケイ酸カリウム等）、アルカノールアミン類（モノエタノールアミン、ジエタノールアミン、トリエタノールアミン等）が望ましい。
これらのアルカリ剤は、水和物となっていてもよい。
これらの中で、アルカリ金属水酸化物であることが望ましく、水酸化ナトリウム及び水酸化カリウムからなる群から選択された少なくとも１種であることがより望ましい。
これらのアルカリ剤は組み合わせて使用してもよい。
When the detergent composition of the present invention contains an alkaline agent, the cleaning power against oily stains is improved.
As the alkaline agent, alkali metal hydroxides (sodium hydroxide, potassium hydroxide, etc.), carbonates or hydrogen carbonates (sodium carbonate, potassium carbonate, sodium hydrogen carbonate, potassium hydrogen carbonate, etc.), silicates (sodium metasilicate, sodium sesquisilicate, sodium orthosilicate, potassium metasilicate, potassium sesquisilicate, potassium orthosilicate, etc.), and alkanolamines (monoethanolamine, diethanolamine, triethanolamine, etc.) are preferable.
These alkaline agents may be in the form of hydrates.
Among these, an alkali metal hydroxide is preferable, and at least one selected from the group consisting of sodium hydroxide and potassium hydroxide is more preferable.
These alkaline agents may be used in combination.
アルカリ剤の含有量は、０．１～２０．０質量％であることが望ましく、０．１～１０．０質量％であることがより望ましく、５．０～９．８質量％であることがさらに望ましい。
アルカリ剤の含有量が０．１質量％未満であると、アルカリ剤の量が少ないので充分な洗浄効果が得られにくくなる。
アルカリ剤の含有量が２０．０質量％を超えると、外観が均一透明を保ちにくくなる。
The content of the alkaline agent is preferably 0.1 to 20.0 mass %, more preferably 0.1 to 10.0 mass %, and further preferably 5.0 to 9.8 mass %.
If the content of the alkaline agent is less than 0.1% by mass, the amount of the alkaline agent is so small that it is difficult to obtain a sufficient cleaning effect.
If the content of the alkali agent exceeds 20.0% by mass, it becomes difficult to maintain a uniform and transparent appearance.
溶剤としては、ジエチレングリコールモノブチルエーテル、プロピレングリコールモノメチルエーテル、３－メトキシ－３－メチル－１－ブタノール等が挙げられる。
溶剤の含有量は特に限定されないが、１．０～５．０質量％であることが好ましい。
Examples of the solvent include diethylene glycol monobutyl ether, propylene glycol monomethyl ether, and 3-methoxy-3-methyl-1-butanol.
The content of the solvent is not particularly limited, but is preferably 1.0 to 5.0% by mass.
キレート剤としては、ヒドロキシカルボン酸系、アミノカルボン酸系、ホスホン酸系、リン酸系、エーテルカルボン酸塩系等が挙げられ、これらを併用してもよい。これらの中では、ヒドロキシカルボン酸系のキレート剤、及び、アミノカルボン酸系のキレート剤が好ましい。
キレート剤の含有量は特に限定されないが、０．１～２．０質量％であることが好ましい。
Examples of the chelating agent include hydroxycarboxylic acid-based, aminocarboxylic acid-based, phosphonic acid-based, phosphoric acid-based, and ether carboxylate-based agents, and these may be used in combination. Among these, hydroxycarboxylic acid-based and aminocarboxylic acid-based chelating agents are preferred.
The content of the chelating agent is not particularly limited, but is preferably 0.1 to 2.0% by mass.
ヒドロキシカルボン酸系のキレート剤としては、例えば、リンゴ酸、クエン酸、乳酸、酒石酸、グルコン酸又はこれらの塩が挙げられる。 Hydroxycarboxylic acid chelating agents include, for example, malic acid, citric acid, lactic acid, tartaric acid, gluconic acid, or salts thereof.
アミノカルボン酸系のキレート剤としては、エチレンジアミン四酢酸（ＥＤＴＡ）、ニトリロ三酢酸（ＮＴＡ）、メチルグリシン二酢酸（ＭＧＤＡ）、ジエチレントリアミン五酢酸（ＤＴＰＡ）、ヒドロキシエチルエチレンジアミン三酢酸（ＨＥＤＴＡ）、トリエチレンテトラミン六酢酸（ＴＴＨＡ）、グルタミン酸二酢酸（ＧＬＤＡ）、ヒドロキシエチルイミノ二酢酸（ＨＩＤＡ）、ジヒドロキシエチルグリシン（ＤＨＥＧ）、１，３－プロパンジアミン四酢酸（ＰＤＴＡ）、１，３－ジアミノ－２－ヒドロキシプロパン六酢酸（ＤＰＴＡ－ＯＨ）、アスパラギン酸二酢酸（ＡＳＤＡ）、エチレンジアミンコハク酸（ＥＤＤＳ）又はこれらの塩等が挙げられる。 Aminocarboxylic acid chelating agents include ethylenediaminetetraacetic acid (EDTA), nitrilotriacetic acid (NTA), methylglycine diacetic acid (MGDA), diethylenetriaminepentaacetic acid (DTPA), hydroxyethylethylenediaminetriacetic acid (HEDTA), triethylenetetraminehexaacetic acid (TTHA), glutamic acid diacetic acid (GLDA), hydroxyethyliminodiacetic acid (HIDA), dihydroxyethylglycine (DHEG), 1,3-propanediaminetetraacetic acid (PDTA), 1,3-diamino-2-hydroxypropanehexaacetic acid (DPTA-OH), aspartic acid diacetic acid (ASDA), ethylenediaminesuccinic acid (EDDS), or salts thereof.
ホスホン酸系のキレート剤としては、ヒドロキシエチリデンジホスホン酸（ＨＥＤＰ）、ニトリロトリメチレンホスホン酸（ＮＴＭＰ）、ホスホノブタントリカルボン酸（ＰＢＴＣ）、エチレンジアミンテトラメチレンホスホン酸（ＥＤＴＭＰ）等が挙げられる。
上記キレート剤はホスホン酸部分の少なくとも一部が塩になっていてもよい。
Examples of the phosphonic acid-based chelating agent include hydroxyethylidene diphosphonic acid (HEDP), nitrilotrimethylene phosphonic acid (NTMP), phosphonobutane tricarboxylic acid (PBTC), and ethylenediaminetetramethylene phosphonic acid (EDTMP).
The chelating agent may have at least a portion of the phosphonic acid moiety in the form of a salt.
リン酸系のキレート剤としては、トリポリリン酸、ヘキサメタリン酸又はこれらの塩等が挙げられる。 Examples of phosphoric acid-based chelating agents include tripolyphosphate, hexametaphosphoric acid, and salts thereof.
上記キレート剤における塩としては、例えば、カリウム、ナトリウム等のアルカリ金属の塩；マグネシウム、カルシウム等のアルカリ土類金属の塩を挙げることができる。中でも、アルカリ金属の塩が好ましく、ナトリウム塩又はカリウム塩がより好ましい。
また、キレート剤とキレート剤の塩がアルカリ洗浄剤組成物の中で混在していてもよく、キレート剤がアルカリ洗浄剤組成物に含まれている場合にその後にナトリウムイオン等が加えられることによって塩となっていてもよい。
Examples of the salt in the chelating agent include salts of alkali metals such as potassium and sodium, and salts of alkaline earth metals such as magnesium and calcium. Among these, salts of alkali metals are preferred, and sodium salts or potassium salts are more preferred.
In addition, the chelating agent and the salt of the chelating agent may be mixed in the alkaline detergent composition, or when the chelating agent is contained in the alkaline detergent composition, sodium ions or the like may be added thereto to form a salt.
可溶化剤としては、デカン酸、２－エチルヘキサン酸又はこれらの塩等が挙げられる。
可溶化剤の含有量は特に限定されないが、１．０～３．０質量％であることが好ましい。
The solubilizing agent includes decanoic acid, 2-ethylhexanoic acid, or salts thereof.
The content of the solubilizer is not particularly limited, but is preferably 1.0 to 3.0% by mass.
安定化剤としては、トコフェロール酢酸エステル、亜硫酸ナトリウム等が挙げられる。
安定化剤の含有量は特に限定されないが、１．０～２．０質量％であることが好ましい。
The stabilizers include tocopherol acetate, sodium sulfite, and the like.
The content of the stabilizer is not particularly limited, but is preferably 1.0 to 2.0% by mass.
本発明の洗浄剤組成物の使用方法としては、泡状にして洗浄対象面に噴射・付着させる方法が挙げられる。
これまで説明してきたように、本発明の洗浄剤組成物は、泡状にして洗浄対象面に噴射・付着させた際に、付着した泡の流れ落ちが生じにくく、泡がきめ細かくなる。
そのため、洗浄対象面を好適に洗浄することができる。
The method for using the cleaning composition of the present invention includes forming it into a foam and spraying and attaching it to the surface to be cleaned.
As described above, when the cleaning composition of the present invention is foamed and sprayed onto and adhered to a surface to be cleaned, the foam is less likely to run off and the foam becomes fine.
Therefore, the surface to be cleaned can be cleaned suitably.
また、本発明の洗浄剤組成物を使用する場合には、泡噴射器を用いることが望ましい。
すなわち、本発明の洗浄剤組成物は、泡噴射器用であってもよい。
泡噴射器としては、例えば、ハンドポンプ、フォーマー、スプレーボトル、スプレーガン等が挙げられる。
When using the cleaning composition of the present invention, it is desirable to use a foam sprayer.
That is, the cleaning agent composition of the present invention may be used for a foam sprayer.
Examples of foam sprayers include hand pumps, foamers, spray bottles, and spray guns.
以下に本発明をより具体的に説明する実施例を示すが、本発明はこれらの実施例に限定されるものではない。 The following examples are provided to more specifically explain the present invention, but the present invention is not limited to these examples.
（増粘剤）
増粘剤として、８種のキサンタンガム（キサンタンガム１～キサンタンガム８）を準備した。
各キサンタンガムを用い、以下の手順で、増粘剤の粘度測定試験を行った。
まず、濃度が０．３質量％となるように各キサンタンガムを水に溶解させ試験溶液を作製した。
当該試験溶液１ｍＬをＥ型粘度計（東機産業株式会社製、型番：ＴＶＥ－２５Ｅ）により測定温度２０℃、回転数１ｒｐｍ、１０ｒｐｍ、２０ｒｐｍ及び１００ｒｐｍの条件で当該試験溶液の粘度の測定を開始した。
各回転数において、測定開始から１分後に測定された当該試験溶液の粘度を、それぞれ、回転数が１ｒｐｍのときの粘度、回転数が１０ｒｐｍのときの粘度、回転数が２０ｒｐｍのときの粘度、回転数が１００ｒｐｍのときの粘度とした。結果を表１に示す。
(Thickener)
Eight types of xanthan gum (
Using each xanthan gum, a viscosity measurement test of the thickener was carried out according to the following procedure.
First, each xanthan gum was dissolved in water to a concentration of 0.3% by mass to prepare a test solution.
Measurement of the viscosity of 1 mL of the test solution was started using an E-type viscometer (manufactured by Toki Sangyo Co., Ltd., model number: TVE-25E) at a measurement temperature of 20° C. and rotation speeds of 1 rpm, 10 rpm, 20 rpm, and 100 rpm.
The viscosity of the test solution measured 1 minute after the start of the measurement at each rotation speed was determined as the viscosity at a rotation speed of 1 rpm, the viscosity at a rotation speed of 10 rpm, the viscosity at a rotation speed of 20 rpm, and the viscosity at a rotation speed of 100 rpm. The results are shown in Table 1.
（実施例１～２４）及び（比較例１～１３）
表２～表４に示す組成の実施例１～２４に係る洗浄剤組成物及び比較例１～１３に係る洗浄剤組成物を作製した。
なお、表２～表４中の数値は「質量％」を意味する。
(Examples 1 to 24) and (Comparative Examples 1 to 13)
Cleaning compositions according to Examples 1 to 24 and cleaning compositions according to Comparative Examples 1 to 13 having the compositions shown in Tables 2 to 4 were prepared.
The numerical values in Tables 2 to 4 represent "mass %."
（洗浄剤組成物の粘度測定試験）
各実施例及び各比較例に係る洗浄剤組成物を用い、Ｅ型粘度計（東機産業株式会社製、型番：ＴＶＥ－２５Ｅ）により、測定温度を５℃として、回転数１ｒｐｍ及び１００ｒｐｍの条件で各実施例及び各比較例に係る洗浄剤組成物の粘度の測定を開始した。
各回転数において、測定開始から１分後に測定された当該洗浄剤組成物の粘度を、それぞれ、回転数が１ｒｐｍのときの粘度及び回転数が１００ｒｐｍのときの粘度とした。
また、測定温度を２０℃とし、同様の試験を行った。
結果を表２～４に示す。
(Viscosity Measurement Test of Cleaning Composition)
Using the cleaning composition according to each Example and Comparative Example, the viscosity of the cleaning composition according to each Example and Comparative Example was measured using an E-type viscometer (manufactured by Toki Sangyo Co., Ltd., model number: TVE-25E) at a measurement temperature of 5° C. and rotation speeds of 1 rpm and 100 rpm.
At each rotation speed, the viscosity of the cleaning composition measured 1 minute after the start of measurement was recorded as the viscosity at a rotation speed of 1 rpm and the viscosity at a rotation speed of 100 rpm, respectively.
Moreover, the same test was carried out at a measurement temperature of 20°C.
The results are shown in Tables 2 to 4.
（洗浄剤組成物のせん断応力測定試験）
各実施例及び各比較例に係る洗浄剤組成物を用い、Ｅ型粘度計（東機産業株式会社製、型番：ＴＶＥ－２５Ｅ）及びコーンロータ（東機産業株式会社製、型番：１°３４´×Ｒ２４）を用い、測定温度を５℃として、回転数を１ｒｐｍ、１０ｒｐｍ、２０ｒｐｍ及び１００ｒｐｍにおけるせん断応力の測定を開始した、
測定開始から１分後に測定された洗浄剤組成物のせん断応力を各せん断速度におけるせん断応力とした。
なお、コーンロータの固有係数は、３．８３なので、測定されたせん断応力は、それぞれ、せん断速度が３．８３ｓ－１、３８．３ｓ－１、７６．６ｓ－１及び３８３ｓ－１のときのせん断応力となる。
次に、ｘ軸をせん断速度（ｓ－１）の常用対数軸とし、ｙ軸をせん断応力（Ｐａ）の常用対数軸としたグラフに、測定されたせん断応力の値をプロットし、最小二乗法により近似直線を算出し、得られた近似直線のｙ軸の切片の値を、測定温度５℃における各実施例及び各比較例に係る洗浄剤組成物の降伏値とした。
結果を表２～４に示す。
(Shear stress measurement test of cleaning composition)
Using the cleaning agent compositions according to each Example and Comparative Example, an E-type viscometer (manufactured by Toki Sangyo Co., Ltd., model number: TVE-25E) and a cone rotor (manufactured by Toki Sangyo Co., Ltd., model number: 1°34'×R24) were used, and the measurement of shear stress was started at a measurement temperature of 5° C. and rotation speeds of 1 rpm, 10 rpm, 20 rpm, and 100 rpm.
The shear stress of the cleaning composition measured one minute after the start of the measurement was regarded as the shear stress at each shear rate.
Since the specific coefficient of the cone rotor is 3.83, the measured shear stresses are the shear stresses when the shear rates are 3.83 s -1 , 38.3 s -1 , 76.6 s -1 and 383 s -1 , respectively.
Next, the measured shear stress values were plotted on a graph in which the x-axis represents the common logarithm of shear rate (s -1 ) and the y-axis represents the common logarithm of shear stress (Pa), and an approximation line was calculated by the least squares method. The intercept of the y-axis of the obtained approximation line was taken as the yield value of each of the cleaning compositions according to the Examples and Comparative Examples at a measurement temperature of 5°C.
The results are shown in Tables 2 to 4.
実施例１及び比較例１に係る洗浄剤組成物を用い、洗浄剤組成物のせん断応力測定試験を行い、算出された近似直線を図１に示す。
図１は、実施例１及び比較例１に係る洗浄剤組成物を用い、測定温度を５℃として洗浄剤組成物のせん断応力測定試験を行い、ｘ軸をせん断速度（ｓ－１）の常用対数軸とし、ｙ軸をせん断応力（Ｐａ）の常用対数軸としたグラフに、測定されたせん断応力の値をプロットし、最小二乗法により算出した近似直線を示すグラフである。
A shear stress measurement test for the cleaning composition was carried out using the cleaning compositions of Example 1 and Comparative Example 1, and the calculated approximation lines are shown in FIG.
FIG. 1 is a graph showing an approximation line calculated by the least squares method, in which a shear stress measurement test for the cleaning composition of Example 1 and Comparative Example 1 was performed at a measurement temperature of 5° C., the measured shear stress values were plotted on a graph in which the x-axis is a common logarithm axis of shear rate ( s −1 ) and the y-axis is a common logarithm axis of shear stress (Pa).
また、測定温度を２０℃とし、同様の試験を行い、測定温度２０℃における各実施例及び各比較例に係る洗浄剤組成物の降伏値を算出した。
結果を表２～４に示す。
Moreover, the same test was carried out at a measurement temperature of 20° C., and the yield value of each of the cleaning compositions according to the Examples and Comparative Examples at a measurement temperature of 20° C. was calculated.
The results are shown in Tables 2 to 4.
（スプレー試験）
５℃又は２０℃の各実施例に係る洗浄剤組成物及び各比較例に係る洗浄剤組成物をスプレーガンに充填し、モデル洗浄対象面であるステンレス板に、約１５ｃｍの距離から洗浄剤組成物を泡状にして噴射し、スプレー性、泡定着性及び泡質の評価を行った。
なお、スプレーガンは、キャニオン株式会社製「Ｔ－９５」、キャニオン株式会社製「Ｔ－８１００」及び株式会社ライフプラテック製「ＴＳ－０１Ｆ」を用いた。
評価基準は以下の通りである。
(Spray test)
The cleaning compositions of each Example and each Comparative Example were filled into a spray gun at 5°C or 20°C, and the cleaning compositions were sprayed in foam form onto a stainless steel plate, which was a model surface to be cleaned, from a distance of about 15 cm, and the sprayability, foam fixation property and foam quality were evaluated.
The spray guns used were "T-95" manufactured by Canyon Co., Ltd., "T-8100" manufactured by Canyon Co., Ltd., and "TS-01F" manufactured by Life Platec Corporation.
The evaluation criteria are as follows:
（スプレー性の評価基準）
スプレー性の評価基準は以下の通りである。結果を表２～４に示す。
Ａ：勢いよく吐出される。
Ｂ：わずかに液詰まりが起きて吐出される。
Ｃ：液詰まりが起きて吐出されず、対象面に届かない。
(Sprayability Evaluation Criteria)
The evaluation criteria for sprayability were as follows. The results are shown in Tables 2 to 4.
A: It is ejected with force.
B: The liquid is discharged with slight clogging.
C: Liquid is clogged and not dispensed, and does not reach the target surface.
（泡定着性の評価基準）
垂直に立てたステンレス板に泡状の洗浄剤組成物を付着させた後、泡の先端が１５ｃｍ垂れるまでの時間を測定し泡定着性を評価した。
泡定着性の評価基準は以下の通りである。結果を表２～４に示す。
Ａ：６０秒以上
Ｂ：４０秒以上、６０秒未満
Ｃ：４０秒未満
(Evaluation Criteria for Foam Fixation)
The foam-like cleaning composition was applied to a vertically standing stainless steel plate, and the time until the tip of the foam dropped 15 cm was measured to evaluate foam fixation.
The evaluation criteria for bubble fixation were as follows: The results are shown in Tables 2 to 4.
A: 60 seconds or more B: 40 seconds or more, less than 60 seconds C: Less than 40 seconds
実施例１、比較例２、比較例９に係る洗浄剤組成物を用いたスプレー試験において、各洗浄剤組成物をステンレス板に付着させた後、２０秒経過後の写真を図２に示す。
図２は、実施例１、比較例２、比較例９に係る洗浄剤組成物を用いたスプレー試験における泡定着性の評価に係る写真である。
In the spray test using the cleaning compositions of Example 1, Comparative Example 2, and Comparative Example 9, photographs taken 20 seconds after each cleaning composition was applied to a stainless steel plate are shown in FIG.
FIG. 2 is a photograph showing the evaluation of foam fixation in a spray test using the cleaning agent compositions of Example 1, Comparative Example 2, and Comparative Example 9.
（泡質の評価基準）
垂直に立てたステンレス板に泡状の洗浄剤組成物を付着させた直後に写真をとり、泡のきめ細かさを観察した。評価基準は以下の通りである。
Ａ：最も大きい気泡の径が１．０ｍｍ以下である。
Ｂ：最も大きい気泡の径が１．０ｍｍを超える。
この評価基準の代表例として、実施例１及び比較例２に係る洗浄剤組成物を用いたスプレー試験における泡質を評価するための写真を図３に示す。
図３は、実施例１及び比較例２に係る洗浄剤組成物を用いたスプレー試験における泡質の評価に係る写真である。
(Foam quality evaluation criteria)
The foam-like cleaning composition was applied to a vertically standing stainless steel plate, and immediately after that, a photograph was taken to observe the fineness of the foam. The evaluation criteria were as follows:
A: The diameter of the largest bubble is 1.0 mm or less.
B: The diameter of the largest bubble exceeds 1.0 mm.
As a representative example of this evaluation standard, photographs for evaluating foam quality in a spray test using the cleaning compositions of Example 1 and Comparative Example 2 are shown in FIG.
FIG. 3 is a set of photographs relating to the evaluation of foam quality in a spray test using the cleaning compositions of Example 1 and Comparative Example 2.
表２～４に示すように、各実施例に係る洗浄剤組成物は、粘度及び降伏値が所定の範囲内であるので、スプレー性、泡定着性及び泡質が良好な評価となった。 As shown in Tables 2 to 4, the cleaning composition according to each example had a viscosity and yield value within the specified range, and was therefore rated as good in terms of sprayability, foam retention, and foam quality.
Claims (9)
下記に示す洗浄剤組成物の粘度測定試験において、
測定温度５℃における、前記洗浄剤組成物の回転数１ｒｐｍのときの粘度が１００～５００ｍＰａ・ｓとなり、
測定温度５℃における、前記洗浄剤組成物の回転数１００ｒｐｍのときの粘度が１５～３０ｍＰａ・ｓとなり、
下記に示す洗浄剤組成物のせん断応力測定試験において、
測定温度５℃における、前記洗浄剤組成物の降伏値が１Ｐａ以下であり、
前記増粘剤は、キサンタンガムであり、下記に示す増粘剤の粘度測定試験において、
回転数が１ｒｐｍのときの粘度が１００～５００ｍＰａ・ｓであり、
回転数が１０ｒｐｍのときの粘度が３５～７０ｍＰａ・ｓであり、
回転数が２０ｒｐｍのときの粘度が２５～５０ｍＰａ・ｓであり、
回転数が１００ｒｐｍのときの粘度が１０～２５ｍＰａ・ｓであり、
増粘剤の粘度測定試験において得られた、前記増粘剤の回転数が１ｒｐｍのときの粘度と、回転数が１００ｒｐｍのときの粘度との比が、（回転数が１００ｒｐｍのときの粘度（ｍＰａ・ｓ））／（回転数が１ｒｐｍのときの粘度（ｍＰａ・ｓ））＝０．０６～０．１０となり、
前記増粘剤の含有量は、０．１～２．０質量％であり、
ｐＨが６以上であり、
泡噴射器用であることを特徴とする洗浄剤組成物。
洗浄剤組成物の粘度測定試験：
Ｅ型粘度計により、回転数１ｒｐｍ及び１００ｒｐｍの条件で洗浄剤組成物の粘度の測定を開始し、
各回転数において、測定開始から１分後に測定された当該洗浄剤組成物の粘度を、それぞれ、洗浄剤組成物の粘度測定試験における、回転数が１ｒｐｍのときの粘度及び回転数が１００ｒｐｍのときの粘度とする。
洗浄剤組成物のせん断応力測定試験：
Ｅ型粘度計により、せん断速度３．８３ｓ－１、３８．３ｓ－１、７６．６ｓ－１及び３８３ｓ－１の条件で洗浄剤組成物のせん断応力の測定を開始し、
測定開始から１分後に測定された洗浄剤組成物のせん断応力を各せん断速度におけるせん断応力とし、
ｘ軸をせん断速度（ｓ－１）の常用対数軸とし、ｙ軸をせん断応力（Ｐａ）の常用対数軸としたグラフに、測定されたせん断応力の値をプロットし、最小二乗法により近似直線を算出し、得られた近似直線のｙ軸の切片の値を降伏値とする。
増粘剤の粘度測定試験：
増粘剤の濃度が０．３質量％となるように増粘剤を水に溶解させ試験溶液を作製し、Ｅ型粘度計により測定温度２０℃、回転数１ｒｐｍ、１０ｒｐｍ、２０ｒｐｍ及び１００ｒｐｍの条件で当該試験溶液の粘度の測定を開始し、各回転数において、測定開始から１分後に測定された当該試験溶液の粘度を、それぞれ、増粘剤の粘度測定試験における、回転数が１ｒｐｍのときの粘度、回転数が１０ｒｐｍのときの粘度、回転数が２０ｒｐｍのときの粘度、回転数が１００ｒｐｍのときの粘度とする。 A cleaning composition comprising water, a surfactant, and a thickener,
In the viscosity measurement test of the cleaning composition shown below,
The viscosity of the cleaning composition at a measurement temperature of 5° C. and a rotation speed of 1 rpm is 100 to 500 mPa s,
The viscosity of the cleaning composition at a measurement temperature of 5° C. and a rotation speed of 100 rpm is 15 to 30 mPa s,
In the shear stress measurement test of the cleaning composition shown below,
The yield value of the cleaning composition at a measurement temperature of 5° C. is 1 Pa or less,
The thickener is xanthan gum, and in the viscosity measurement test of the thickener shown below,
The viscosity at a rotation speed of 1 rpm is 100 to 500 mPa·s,
The viscosity at a rotation speed of 10 rpm is 35 to 70 mPa·s,
The viscosity is 25 to 50 mPa·s when the rotation speed is 20 rpm,
The viscosity is 10 to 25 mPa·s when the rotation speed is 100 rpm,
The ratio of the viscosity of the thickener when the rotation speed is 1 rpm to the viscosity when the rotation speed is 100 rpm, obtained in a viscosity measurement test of the thickener, is (viscosity (mPa s) when the rotation speed is 100 rpm)/(viscosity (mPa s) when the rotation speed is 1 rpm)=0.06 to 0.10,
The content of the thickener is 0.1 to 2.0% by mass,
The pH is 6 or more,
A cleaning composition for use in a foam injector.
Viscosity measurement test of cleaning composition:
Measurement of the viscosity of the cleaning composition was started using an E-type viscometer at rotation speeds of 1 rpm and 100 rpm.
At each rotation speed, the viscosity of the cleaning composition measured 1 minute after the start of measurement is defined as the viscosity at a rotation speed of 1 rpm and the viscosity at a rotation speed of 100 rpm in the viscosity measurement test of the cleaning composition, respectively.
Shear stress measurement test of cleaning composition:
Measurement of the shear stress of the cleaning composition was started using an E-type viscometer at shear rates of 3.83 s −1 , 38.3 s −1 , 76.6 s −1 and 383 s −1 ;
The shear stress of the cleaning composition measured 1 minute after the start of measurement was defined as the shear stress at each shear rate.
The measured shear stress values are plotted on a graph with the x-axis representing the common logarithm of shear rate (s -1 ) and the y-axis representing the common logarithm of shear stress (Pa), an approximation line is calculated by the least squares method, and the intercept of the y-axis of the obtained approximation line is regarded as the yield value.
Viscosity measurement test for thickeners:
A test solution was prepared by dissolving a thickener in water so that the concentration of the thickener was 0.3% by mass, and measurement of the viscosity of the test solution was started using an E-type viscometer at a measurement temperature of 20°C and rotation speeds of 1 rpm, 10 rpm, 20 rpm, and 100 rpm. The viscosities of the test solution measured 1 minute after the start of measurement at each rotation speed were designated as the viscosity at a rotation speed of 1 rpm, the viscosity at a rotation speed of 10 rpm, the viscosity at a rotation speed of 20 rpm, and the viscosity at a rotation speed of 100 rpm, respectively, in the viscosity measurement test of the thickener.
測定温度２０℃における、前記洗浄剤組成物の回転数１ｒｐｍのときの粘度が１００～５００ｍＰａ・ｓとなり、
測定温度２０℃における、前記洗浄剤組成物の回転数１００ｒｐｍのときの粘度が１２～３０ｍＰａ・ｓとなり、
上記の洗浄剤組成物のせん断応力測定試験において、
測定温度２０℃における、前記洗浄剤組成物の降伏値は１Ｐａ以下である請求項１に記載の洗浄剤組成物。 In the viscosity measurement test of the above cleaning composition,
The viscosity of the cleaning composition at a measurement temperature of 20° C. and a rotation speed of 1 rpm is 100 to 500 mPa s,
The viscosity of the cleaning composition at a measurement temperature of 20° C. and a rotation speed of 100 rpm is 12 to 30 mPa s,
In the shear stress measurement test of the above cleaning composition,
2. The cleaning composition according to claim 1, wherein the yield value of the cleaning composition at a measurement temperature of 20° C. is 1 Pa or less.
測定温度５℃における、前記洗浄剤組成物の降伏値が０．１Ｐａ以上である請求項１又は２に記載の洗浄剤組成物。 In the shear stress measurement test of the above cleaning composition,
3. The cleaning composition according to claim 1, wherein the yield value of the cleaning composition at a measurement temperature of 5°C is 0.1 Pa or more.
ｙ＝ｂｘａ・・・（１）
－０．６０≦ａ・・・（２）
１００≦ｂ≦５００・・・（３） The cleaning agent composition according to any one of claims 1 to 4, wherein, when the viscosity of the thickener obtained by the viscosity measurement test is plotted on a graph with the y-axis representing viscosity (mPa s) and the x-axis representing rotation speed (rpm), the viscosity of the thickener obtained by the viscosity measurement test falls within a range that satisfies the following formulas (1) to (3):
y = bx a ... (1)
−0.60≦a (2)
100≦b≦500...(3)
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| JP2001107095A (en) | 1999-10-08 | 2001-04-17 | Lion Corp | Bleaching detergent |
| WO2013001761A1 (en) | 2011-06-27 | 2013-01-03 | 昭栄薬品株式会社 | Thixotropic composition |
| WO2018026626A1 (en) | 2016-08-01 | 2018-02-08 | The Procter & Gamble Company | Phase-stable, sprayable freshening compositions comprising suspended particles and methods of freshening the air or a surface with the same |
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| JP2001107095A (en) | 1999-10-08 | 2001-04-17 | Lion Corp | Bleaching detergent |
| WO2013001761A1 (en) | 2011-06-27 | 2013-01-03 | 昭栄薬品株式会社 | Thixotropic composition |
| WO2018026626A1 (en) | 2016-08-01 | 2018-02-08 | The Procter & Gamble Company | Phase-stable, sprayable freshening compositions comprising suspended particles and methods of freshening the air or a surface with the same |
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