JP7439893B1 - Premix for flour dough - Google Patents

Premix for flour dough Download PDF

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JP7439893B1
JP7439893B1 JP2022201655A JP2022201655A JP7439893B1 JP 7439893 B1 JP7439893 B1 JP 7439893B1 JP 2022201655 A JP2022201655 A JP 2022201655A JP 2022201655 A JP2022201655 A JP 2022201655A JP 7439893 B1 JP7439893 B1 JP 7439893B1
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flour dough
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flour
rice oil
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JP2024086497A (en
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真紀子 難波
瑠依 安川
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NOF Corp
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Abstract

【課題】本発明の目的は、穀粉生地への分散性に優れ、保存性が向上した、低濃度から高濃度まで任意に穀粉生地へ米油由来ガム質および酵素を配合できる穀粉生地用プレミックスを提供することである。【解決手段】上記課題を解決するために、(A)液糖及び(B)米油由来ガム質又は(C)酵素を含有し、水分活性が0.80以下である穀粉生地用プレミックスを提供する。本発明によれば、穀粉生地への分散性に優れ、保存性が向上した、低濃度から高濃度まで任意に穀粉生地へ米油由来ガム質および酵素を配合できる穀粉生地用プレミックスを提供することができる。【選択図】なし[Problem] The object of the present invention is to provide a premix for flour dough that has excellent dispersibility in flour dough and improved storage stability, and that can optionally incorporate rice oil-derived gummy substances and enzymes into flour dough from low to high concentrations. The goal is to provide the following. [Solution] In order to solve the above problems, a premix for flour dough containing (A) liquid sugar and (B) rice oil-derived gummy substance or (C) enzyme and having a water activity of 0.80 or less is provided. provide. According to the present invention, there is provided a premix for flour dough that has excellent dispersibility in flour dough, has improved storage stability, and can optionally incorporate rice oil-derived gummy substances and enzymes into flour dough from a low concentration to a high concentration. be able to. [Selection diagram] None

Description

本発明は、穀粉生地への分散性、保存性が向上し、低濃度から高濃度まで任意に穀粉生地中へ米油由来ガム質又は酵素を配合できる穀粉生地用プレミックスに関する。 The present invention relates to a premix for flour dough, which has improved dispersibility and storage stability in flour dough, and can optionally incorporate rice oil-derived gummy substances or enzymes into flour dough from low to high concentrations.

穀粉生地を焼成してなる様々な食品を製造する際、原料を穀粉生地へ均一に分散させることは、出来上がる製品の品質安定性にもつながり重要である。
一般的に粉体原料であれば、穀粉と混合することで均一分散させることは可能であるが、酵素などの少量添加する粉体原料では、穀粉に均一に分散することができず、添加した効果を十分に発揮することができない。特許文献1では、流動穀粉生地にも分散しやすいように酵素を含む水中油型乳化油脂組成物を製造し、良好な分散性が得られる方法が提案されている。また、特許文献2では水に不溶の乳化剤をケーキ生地に分散させるため、油脂に乳化剤を溶解し水と乳化した分散性に優れた乳化油脂組成物が提案されている。
When producing various foods made from baked flour dough, it is important to uniformly disperse the raw materials into the flour dough, as this also leads to quality stability of the finished product.
In general, if it is a powder raw material, it is possible to uniformly disperse it by mixing it with grain flour, but if a powder raw material is added in a small amount such as an enzyme, it cannot be uniformly dispersed in the grain flour, and the added The effect cannot be fully demonstrated. Patent Document 1 proposes a method in which an oil-in-water emulsified fat composition containing an enzyme is manufactured so as to be easily dispersed in fluid flour dough, and good dispersibility is obtained. Moreover, in order to disperse a water-insoluble emulsifier in cake batter, Patent Document 2 proposes an emulsified oil and fat composition with excellent dispersibility, which is obtained by dissolving an emulsifier in oil and fat and emulsifying it with water.

特開2018-201457号公報JP 2018-201457 Publication 特開2015-171324号公報Japanese Patent Application Publication No. 2015-171324

しかし、特許文献1の方法では製品の保存性を高めるために加熱殺菌を行うと酵素が失活してしまうため、酵素を含有した水中油型油脂組成物では十分な加熱殺菌ができず、保存性が低下する。また、特許文献2の方法では、油脂と乳化剤の配合比率が固定化したものを穀粉生地に配合することになるため、低濃度から高濃度まで穀粉生地へ乳化剤を任意に配合することができず、油脂を配合できる範囲内でしか乳化剤を配合できない。したがって、穀粉生地へ均一分散が困難な酵素や、水に不溶の素材を穀粉生地へ均一に分散でき、低濃度から高濃度まで任意に有効成分を配合できる、保存性に優れた穀粉生地用プレミックスの提供が望まれている。
米油由来ガム質は、米糠から搾油された精製前の米原油に含まれるガム状の粘着物質であり、各種植物原油の中でも米原油はガム質が特に多く含まれていることが知られている。米油由来ガム質は米油の精製時に副産物として発生する未利用資源であり、これまで有効な活用方法が見出されておらず、家畜飼料用など付加価値の低い用途に使用されてきたにすぎず、穀粉生地に添加した際に得られる有用な効果については見出されていない。本発明者は、米油由来ガム質を穀粉生地に分散させることができれば、穀粉含有食品の食感や外観を向上させる効果があることを見出した。しかし、米油由来ガム質は粘度が高く、水へ不溶のため、穀粉生地への分散性に欠けるとともに、分散しやすい油中水型乳化物や水中油型乳化物のような乳化物とした場合、水相に米糠抽出物が懸濁し、米糠抽出物に含まれる窒素源等により微生物が繁殖し、乳化物の保存性が低下するという課題があった。また、油脂に米油由来ガム質を配合し、穀粉生地への分散性を向上させることはできるが、穀粉生地へ添加できる油脂量は限定的であり、米油由来ガム質の任意量を穀粉生地に添加できないといった課題があった。
また、粉体の酵素においても、穀粉生地への分散性に欠けるため十分な効果が発揮されず、これまで油脂に分散させるなどの方法がとられてきた。しかし、穀粉生地へ添加できる油脂量は限定的であり酵素の任意量を穀粉生地に添加できないといった課題があった。
However, in the method of Patent Document 1, enzymes are deactivated when heat sterilized to improve the shelf life of the product. Sexuality decreases. In addition, in the method of Patent Document 2, a fixed blending ratio of fat and oil and emulsifier is blended into the flour dough, so it is not possible to arbitrarily mix the emulsifier into the flour dough from a low concentration to a high concentration. , emulsifiers can only be blended within the range that oils and fats can be blended. Therefore, enzymes that are difficult to uniformly disperse in flour dough and water-insoluble materials can be uniformly dispersed in flour dough, and active ingredients can be added at any concentration from low to high concentrations. Providing a mix is desired.
Rice oil-derived gum is a gummy sticky substance contained in unrefined rice crude oil extracted from rice bran, and it is known that among various vegetable crude oils, rice crude oil contains particularly high amounts of gum. There is. Rice oil-derived gum is an unused resource that is generated as a by-product during the refining of rice oil, and until now no effective way of utilizing it has been found, and it has been used for low-value-added purposes such as livestock feed. Moreover, no useful effects have been found when added to flour dough. The present inventors have discovered that if rice oil-derived gum can be dispersed in flour dough, it is effective in improving the texture and appearance of flour-containing foods. However, because rice oil-derived gum has a high viscosity and is insoluble in water, it lacks dispersibility in flour dough, and it is difficult to form emulsions such as water-in-oil emulsions and oil-in-water emulsions that are easy to disperse. In this case, the rice bran extract is suspended in the aqueous phase, and the nitrogen source contained in the rice bran extract causes microorganisms to propagate, resulting in a reduction in the shelf life of the emulsion. In addition, it is possible to improve the dispersibility in flour dough by adding gum derived from rice oil to fats and oils, but the amount of oil and fat that can be added to flour dough is limited, and any amount of gum derived from rice oil can be added to flour. The problem was that it could not be added to dough.
Furthermore, enzymes in powder form do not exhibit sufficient effects due to their lack of dispersibility in flour dough, and methods such as dispersing them in fats and oils have been used until now. However, there is a problem in that the amount of oil and fat that can be added to flour dough is limited, and it is not possible to add an arbitrary amount of enzyme to flour dough.

本発明者は、米油由来ガム質、酵素を液糖で希釈した穀粉生地用プレミックスにおいて、水分活性を0.80以下とすることで保存性を向上するのみならず、穀粉生地への分散性を向上させることができ、低濃度から高濃度まで任意に穀粉生地中へ米油由来ガム質又は酵素を配合できることを見出した。すなわち本発明の目的は、穀粉生地への分散性に優れ、保存性が向上した、低濃度から高濃度まで任意に穀粉生地へ米油由来ガム質又は酵素を配合できる穀粉生地用プレミックスを提供することである。 The present inventor has developed a premix for flour dough in which rice oil-derived gum and enzymes are diluted with liquid sugar. It has been found that rice oil-derived gummy substances or enzymes can be incorporated into the flour dough at any desired concentration from low to high concentrations. That is, the object of the present invention is to provide a premix for flour dough that has excellent dispersibility in flour dough and improved storage stability, and that can optionally incorporate rice oil-derived gummy substances or enzymes into flour dough from a low concentration to a high concentration. It is to be.

本発明は下記[1]~[5]である
[1](A)液糖及び(B)米油由来ガム質を含有し、水分活性が0.80以下である穀粉生地用プレミックス。
[2]前記(A)液糖の含有量が20質量%以上、90質量%以下であり、前記(B)米油由来ガム質の含有量が10質量%以上、80質量%以下である、[1]に記載の穀粉生地用プレミックス。
[3](A)液糖及び(C)酵素を含有し、水分活性が0.80以下である穀粉生地用プレミックス。
[4]前記(A)液糖の含有量が90質量%以上である、[3]に記載の穀粉生地用プレミックス。
[5](A)液糖、(B)米油由来ガム質及び(C)酵素を含有し、水分活性が0.80以下である穀粉生地用プレミックス。
The present invention is the following [1] to [5] [1] A premix for flour dough containing (A) liquid sugar and (B) gummy substance derived from rice oil and having a water activity of 0.80 or less.
[2] The content of the (A) liquid sugar is 20% by mass or more and 90% by mass or less, and the content of the (B) rice oil-derived gummy substance is 10% by mass or more and 80% by mass or less, The premix for flour dough according to [1].
[3] A premix for flour dough containing (A) liquid sugar and (C) an enzyme and having a water activity of 0.80 or less.
[4] The premix for flour dough according to [3], wherein the content of the liquid sugar (A) is 90% by mass or more.
[5] A premix for flour dough containing (A) liquid sugar, (B) rice oil-derived gum, and (C) an enzyme, and having a water activity of 0.80 or less.

本発明によれば、穀粉生地への分散性に優れ、保存性が向上した、低濃度から高濃度まで任意に穀粉生地へ米油由来ガム質又は酵素を配合できる穀粉生地用プレミックスを提供することができる。
またこれらの穀粉生地用プレミックスは穀粉生地への分散性が向上することにより、例えば製パンにおいてボリューム向上効果やソフトさ向上効果が十分に得られる。
According to the present invention, there is provided a premix for flour dough that has excellent dispersibility in flour dough, has improved storage stability, and can optionally incorporate rice oil-derived gummy substances or enzymes into flour dough from a low concentration to a high concentration. be able to.
Furthermore, these premixes for flour dough have improved dispersibility into flour dough, so that, for example, in bread making, a sufficient volume-improving effect and softness-improving effect can be obtained.

本発明の穀粉生地用プレミックスは、(A)液糖に、(B)米油由来ガム質および酵素から選ばれる1種類以上を含有し、水分活性が0.80以下であることを特徴とするものであり、穀粉生地に混合して使用するものである。
以下、本発明について詳細に説明する。
The premix for flour dough of the present invention is characterized in that it contains (A) liquid sugar, (B) one or more types selected from rice oil-derived gummy substances and enzymes, and has a water activity of 0.80 or less. It is used by mixing it into flour dough.
The present invention will be explained in detail below.

(A)液糖
本発明に用いられる(A)液糖とは、液体状態の糖類、または、粉糖を溶液状態にしたものである。具体的には、グルコース、マント―ス、シュークロース、ラクトース、トレハロース、マルトトリオース、テトラオース、ソルビトール、キシリトール、エリスリトール、マルチトール等の単糖類、二糖類、三糖類、四糖類、五糖類、六糖類、澱粉加水分解物及びこれらを還元した糖アルコール、又は、それらの混合物の液状物、例えば、水飴、還元水飴、砂糖混合ぶどう糖果糖液糖などが用いられる。
流通する商品としては、例えば、「RCS-50」(王子コーンスターチ(株)製、砂糖混合ぶどう糖果糖液糖、水分活性0.73)、「アマミール」(三菱商事フードテック(株)製、還元水飴、水分活性0.82)などが挙げられる。
(A) Liquid sugar The liquid sugar (A) used in the present invention is liquid sugar or powdered sugar in a solution state. Specifically, monosaccharides such as glucose, mantose, sucrose, lactose, trehalose, maltotriose, tetraose, sorbitol, xylitol, erythritol, and maltitol, disaccharides, trisaccharides, tetrasaccharides, pentasaccharides, and hexasaccharides. Saccharides, starch hydrolysates, sugar alcohols obtained by reducing these, or liquids of mixtures thereof, such as starch syrup, reduced starch syrup, sugar-mixed glucose/fructose corn syrup, etc., are used.
Examples of distributed products include "RCS-50" (manufactured by Oji Cornstarch Co., Ltd., sugar-mixed glucose-fructose liquid sugar, water activity 0.73), "Amamil" (manufactured by Mitsubishi Corporation Food Tech Co., Ltd., reduced starch syrup) , water activity 0.82).

本発明によれば、穀粉生地への分散性に優れ、保存性が向上した、低濃度から高濃度まで任意に穀粉生地へ米油由来ガム質および酵素を配合できる穀粉生地用プレミックスを提供することができる。 According to the present invention, there is provided a premix for flour dough that has excellent dispersibility in flour dough, has improved storage stability, and can optionally incorporate rice oil-derived gummy substances and enzymes into flour dough from low to high concentrations. be able to.

(A)液糖の水分活性は0.85以下が好ましく、0.80以下がさらに好ましく、0.75以下が特に好ましい。また、下限値としては、特に制限されないが、0.60以上が好ましく、0.65以上が特に好ましい。
さらに、水分活性が0.85以下の(A)液糖と(B)米油由来ガム質を混合した場合、穀粉生地への分散性を向上するとともに保存期間の長期化に伴うカビ等の微生物の発生を抑制しつつ、(B)米油由来ガム質の分離の発生を抑制することができる。(A)液糖の自由水の量が増加すると、(B)米油由来ガム質の分散性の低下を引き起こすおそれがあり、(A)液糖の水分活性は小さいことが好ましい。
また、水分活性が0.85以下の(A)液糖と(C)酵素を混合した場合、保存期間の経過による(C)酵素の活性低下を抑制して、穀粉生地用プレミックスとして優れた機能を得られるとともに保存期間の長期化に伴うカビ等の微生物の発生を抑制する。
(A) The water activity of liquid sugar is preferably 0.85 or less, more preferably 0.80 or less, and particularly preferably 0.75 or less. Further, the lower limit value is not particularly limited, but is preferably 0.60 or more, particularly preferably 0.65 or more.
Furthermore, when (A) liquid sugar with a water activity of 0.85 or less and (B) rice oil-derived gummy substance are mixed, dispersibility into flour dough is improved and microorganisms such as mold are generated due to a prolonged storage period. (B) Separation of rice oil-derived gum can be suppressed. (A) If the amount of free water in the liquid sugar increases, (B) there is a risk that the dispersibility of the rice oil-derived gum quality will decrease, so it is preferable that the water activity of the liquid sugar (A) is low.
In addition, when (A) liquid sugar with a water activity of 0.85 or less and (C) enzyme are mixed, the decrease in the activity of (C) enzyme due to the passage of the storage period is suppressed, making it an excellent premix for flour dough. It not only provides functionality, but also suppresses the growth of microorganisms such as mold during long storage periods.

本発明の穀粉生地用プレミックスにおける(A)液糖の含有量は、(B)米油由来ガム質や(C)酵素の含有量によって適宜調整されるが、例えば、下限値としては、20質量%以上、30質量%以上、40質量%以上、50質量%以上、60質量%以上、70質量%以上、80質量%以上、90質量%以上、95質量%以上である。また、(B)米油由来ガム質を含有する穀粉生地用プレミックスの場合には、上限値としては、例えば、90質量%以下、80質量%以下、70質量%以下、60質量%以下である。 The content of (A) liquid sugar in the premix for flour dough of the present invention is appropriately adjusted depending on the content of (B) rice oil-derived gum and (C) enzyme, but for example, the lower limit is 20 % by mass or more, 30% by mass or more, 40% by mass or more, 50% by mass or more, 60% by mass or more, 70% by mass or more, 80% by mass or more, 90% by mass or more, 95% by mass or more. In the case of (B) a premix for flour dough containing rice oil-derived gum, the upper limit values are, for example, 90% by mass or less, 80% by mass or less, 70% by mass or less, and 60% by mass or less. be.

(B)米油由来ガム質
本発明に用いる(B)米油由来ガム質は、米糠から搾油された精製前の米原油に含まれるガム状の粘着物質であり、米油精製時の副生成物である。各種植物原油の中でも、米原油に特異的に多くガム質が含まれている。
その製造方法は特に限定されないが、米糠を110~120℃のクッカー処理し、水分を低減させたのち、ヘキサンを用いて搾油後、ヘキサンを留去し、得られた米原油に60~90℃の温水を対油1~3質量%添加し、穏やかに攪拌することにより米油由来ガム質を米原油から析出させ、その後、沈殿、遠心分離など任意の方法により米原油から分離し、乾燥、蒸留等などにより水分を除去して米油由来ガム質を得ることができる。これは米油の一般的な精製工程で得られた副生成物である。
なお、米原油から得られるアセトン不溶物量は、米糠に含まれるホスホリパーゼの活性や米糠の保存状態、水和条件により変動する。また、米油由来ガム質に含まれるアセトン不溶物の含有量は、遠心分離などの米原油から米油由来ガム質を分離する手段により調整することができる。
(B) Rice oil-derived gum (B) Rice oil-derived gum used in the present invention is a gummy sticky substance contained in unrefined rice crude oil extracted from rice bran, and is a by-product during rice oil refining. It is a thing. Among various vegetable crude oils, US crude oil contains a uniquely large amount of gum.
The manufacturing method is not particularly limited, but rice bran is treated in a cooker at 110 to 120°C to reduce moisture content, and then oil is extracted using hexane, the hexane is distilled off, and the resulting rice crude oil is heated to 60 to 90°C. Rice oil-derived gum is precipitated from the rice crude oil by adding 1 to 3% by mass of warm water to the oil and stirring gently, and then separated from the rice crude oil by any method such as precipitation or centrifugation, dried, Rice oil-derived gum can be obtained by removing water by distillation or the like. This is a byproduct obtained in the common refining process of rice oil.
The amount of acetone insoluble matter obtained from rice crude oil varies depending on the activity of phospholipase contained in rice bran, the storage state of rice bran, and hydration conditions. Further, the content of acetone insoluble matter contained in the rice oil-derived gum can be adjusted by means of separating the rice oil-derived gum from the rice crude oil, such as centrifugation.

本発明の(B)米油由来ガム質には、ホスファチジルコリン、ホスファチジルエタノールアミン、ホスファチジルイノシトール、ホスファチジン酸等からなるリン脂質混合物、トリグリセライド、遊離脂肪酸、ロウ、その他多種の成分が含まれる混合物であり、その成分のすべてを特定することはできないが、上記の工程を経て米原油から得られたものであり、アセトン不溶物20質量%以上75質量%以下、酸価50以下、水分含量5質量%以下であるものが好ましく、水分含量1質量%以下であるものがより好ましい。アセトン不溶物の下限値としてより好ましくは35質量%以上である。なお、アセトン不溶物は基準油脂分析試験法の「4.3.1-2013 アセトン不溶物」に準じて、酸価は基準油脂分析試験法の「2.3.1-2013 酸価」に準じて測定した。 The (B) rice oil-derived gum of the present invention is a mixture containing a phospholipid mixture consisting of phosphatidylcholine, phosphatidylethanolamine, phosphatidylinositol, phosphatidic acid, etc., triglyceride, free fatty acids, wax, and various other components, Although it is not possible to identify all of its components, it is obtained from US crude oil through the above process, and contains acetone insoluble matter of 20% to 75% by mass, acid value of 50% or less, and water content of 5% by mass or less. It is preferable that the water content is 1% by mass or less, and more preferably that the water content is 1% by mass or less. The lower limit of the acetone insoluble matter is more preferably 35% by mass or more. In addition, acetone insoluble matter is determined according to "4.3.1-2013 Acetone Insoluble Matter" of the Standard Oil and Fat Analysis Test Method, and acid value is determined according to "2.3.1-2013 Acid Value" of the Standard Oil and Fat Analysis Test Method. It was measured using

(B)米油由来ガム質は粘度が高く、水へ不溶のためそのまま穀粉生地へ添加しても分散せず効果を発揮することができない。しかし(A)液糖と(B)米油由来ガム質を混合し、穀粉生地へ添加した場合、液糖の水への親和性により(B)米油由来ガム質は容易に穀粉生地へ均一分散することができる。穀粉生地へ均一分散した(B)米油由来ガム質は、グルテンの繋がりを強め、例えばパンにおいてはボリューム向上効果やソフトさ向上効果等が得られる。 (B) Rice oil-derived gum has a high viscosity and is insoluble in water, so even if it is added to flour dough as it is, it will not disperse and will not be effective. However, when (A) liquid sugar and (B) rice oil-derived gum are mixed and added to flour dough, (B) rice oil-derived gum is easily uniformly added to the flour dough due to the affinity of liquid sugar for water. Can be dispersed. The rice oil-derived gum (B) uniformly dispersed in the flour dough strengthens the bond of gluten, and can improve the volume and softness of bread, for example.

本発明の穀粉生地用プレミックスにおける(B)米油由来ガム質の含有量は特に制限されないが、例えば10質量%以上、80質量%以下である。10質量%以上の場合には(B)米油由来ガム質の効果を十分に発揮することができる。また80質量%以下であれば本発明の穀粉生地用プレミックスを穀粉生地に混合する際の分散性に優れ、本発明の効果を十分に発揮することができる。(B)米油由来ガム質の含有量の下限値は、好ましくは20質量%以上であり、より好ましくは30質量%以上である。(B)米油由来ガム質の含有量の上限値は、好ましくは70質量%以下であり、より好ましくは60質量%以下である。 The content of (B) rice oil-derived gum in the flour dough premix of the present invention is not particularly limited, but is, for example, 10% by mass or more and 80% by mass or less. When the amount is 10% by mass or more, the effect of (B) rice oil-derived gum can be fully exhibited. Further, if it is 80% by mass or less, the premix for flour dough of the present invention has excellent dispersibility when mixed into flour dough, and the effects of the present invention can be fully exhibited. (B) The lower limit of the content of rice oil-derived gum is preferably 20% by mass or more, more preferably 30% by mass or more. (B) The upper limit of the content of rice oil-derived gum is preferably 70% by mass or less, more preferably 60% by mass or less.

(B)米油由来ガム質は上記方法にて製造してもよく、市販品を入手してもよい。市販品としては、例えば、「Ricelec BK」(Irgovel社製)等が商業的に入手できる。 (B) Rice oil-derived gum may be produced by the above method, or may be obtained as a commercially available product. As a commercially available product, for example, "Ricelec BK" (manufactured by Irgovel) is commercially available.

(C)酵素
本発明に用いる(C)酵素の種類は特に制限されないが、例えば、α-アミラーゼ、マルトース生成α-アミラーゼ、β-アミラーゼ、グルコアミラーゼ、イソアミラーゼ、プロテアーゼ、グルコースオキシダーゼ、セルラーゼ、ヘミセルラーゼ、4-α-グルカノトランスフェラーゼ、6-α-グルカノトランスフェラーゼ等の粉末酵素が好ましく用いられる。
(C) Enzyme The type of enzyme (C) used in the present invention is not particularly limited, but includes, for example, α-amylase, maltose-producing α-amylase, β-amylase, glucoamylase, isoamylase, protease, glucose oxidase, cellulase, hemi-amylase, Powdered enzymes such as cellulase, 4-α-glucanotransferase, and 6-α-glucanotransferase are preferably used.

本発明の穀粉生地用プレミックスにおける(C)酵素の含有量は特に制限されないが、例えば0.1~5質量%である。0.1質量%以上の場合には(C)酵素の効果を十分に発揮することができる。また5質量%以下であれば本発明の穀粉生地用プレミックスを穀粉生地に混合する際の分散性に優れ、本発明の効果を十分に発揮することができる。(C)酵素の含有量の下限値は、好ましくは0.2質量%以上であり、より好ましくは0.4質量%以上である。(C)酵素の含有量の上限値は、好ましくは4質量%以下であり、より好ましくは3質量%以下である。 The content of the enzyme (C) in the flour dough premix of the present invention is not particularly limited, but is, for example, 0.1 to 5% by mass. When the amount is 0.1% by mass or more, the effect of the enzyme (C) can be fully exhibited. Further, if it is 5% by mass or less, the premix for flour dough of the present invention has excellent dispersibility when mixed into flour dough, and the effects of the present invention can be fully exhibited. (C) The lower limit of the enzyme content is preferably 0.2% by mass or more, more preferably 0.4% by mass or more. (C) The upper limit of the enzyme content is preferably 4% by mass or less, more preferably 3% by mass or less.

水溶性の(A)液糖に(C)酵素を分散させることで、穀粉生地中の澱粉やグルテン等になじみやすく、生地への分散性を向上することができるため、酵素の機能を最大限に発揮することができる。 By dispersing (C) the enzyme in the water-soluble (A) liquid sugar, it becomes more compatible with the starch, gluten, etc. in the flour dough, and its dispersibility into the dough can be improved, maximizing the function of the enzyme. can be demonstrated.

[水分活性]
水分活性とは食品中の自由水の割合を表す数値であり、食品の保存性の指標とされるものである。本発明では、穀粉生地用プレミックスの水分活性を0.80以下とすることにより、穀粉生地用プレミックスの保存性を高めることができ、さらに穀粉生地への分散性が優れるといった想定外の効果を見出した。穀粉生地用プレミックスの保存性の観点から、0.75以下が好ましい。また、(B)米油由来ガム質又は(C)酵素の穀粉生地への分散性が向上するという観点から、0.50以上が好ましく、0.60以上がより好ましく、0.65以上が特に好ましい。
なお、本発明の水分活性は、水分活性測定装置(商品名:HygroLab、Rotronic社製)を用いて測定した。
[Water activity]
Water activity is a numerical value representing the proportion of free water in food, and is used as an index of food preservability. In the present invention, by setting the water activity of the premix for flour dough to 0.80 or less, it is possible to improve the storage stability of the premix for flour dough, and the unexpected effect is that the premix for flour dough has excellent dispersibility. I found out. From the viewpoint of storage stability of the premix for flour dough, it is preferably 0.75 or less. In addition, from the viewpoint of improving the dispersibility of (B) rice oil-derived gum or (C) enzyme into flour dough, it is preferably 0.50 or more, more preferably 0.60 or more, and particularly 0.65 or more. preferable.
The water activity of the present invention was measured using a water activity measuring device (trade name: HygroLab, manufactured by Rotronic).

本発明における穀粉生地とは、穀粉に水、卵などの液状成分を混ぜ合わせた生地を指す。穀粉生地は加熱工程を経て、パン、ケーキ等さまざまな食品となる。特に限定されないが、穀粉としては、小麦粉、そば粉、ライ麦粉、大麦粉、米粉、トウモロコシ粉、オーツ粉末、小麦澱粉、トウモロコシ澱粉、モチ種トウモロコシ澱粉、馬鈴薯澱粉、さつまいも澱粉、タピオカ澱粉、米澱粉、さご澱粉、くず澱粉等を挙げることができる。穀粉の他に、イースト、イーストフード、乳化剤、油脂、加工澱粉、乳製品、食塩、糖類、調味料(グルタミン酸ソーダ類や核酸類)、保存料、ビタミン、カルシウム等の強化剤、蛋白質、アミノ酸、化学膨張剤、フレーバー、レーズン等の乾燥果実等が挙げられる。
穀粉生地は、その目的(パン、スポンジケーキ等)により水分量が異なるが、穀粉生地の水分活性は一般的に0.75以上0.98以下である。この範囲の水分活性である穀粉生地を本発明では好ましく用いることができる。
The flour dough in the present invention refers to a dough made by mixing flour with liquid ingredients such as water and eggs. Flour dough goes through a heating process and is made into various foods such as bread and cakes. Examples of grain flour include, but are not limited to, wheat flour, buckwheat flour, rye flour, barley flour, rice flour, corn flour, oat powder, wheat starch, corn starch, waxy corn starch, potato starch, sweet potato starch, tapioca starch, and rice starch. , sago starch, kudzu starch, etc. In addition to flour, yeast, yeast food, emulsifiers, oils and fats, modified starches, dairy products, salt, sugars, seasonings (sodium glutamates and nucleic acids), preservatives, vitamins, fortifiers such as calcium, proteins, amino acids, Examples include chemical leavening agents, flavors, and dried fruits such as raisins.
Although the water content of flour dough differs depending on its purpose (bread, sponge cake, etc.), the water activity of flour dough is generally 0.75 or more and 0.98 or less. Flour dough having a water activity within this range can be preferably used in the present invention.

[穀粉生地用プレミックスの製造方法]
本発明における穀粉生地用プレミックスは(A)液糖に対して、(B)米油由来ガム質および(C)酵素から選ばれる1種以上を添加、混合できればよい。
[Method for producing premix for flour dough]
The premix for flour dough in the present invention may be prepared by adding and mixing one or more selected from (B) rice oil-derived gummy substances and (C) enzymes to (A) liquid sugar.

次に実施例を挙げて本発明を説明する。
[米油由来ガム質の製造]
米糠を120℃で加熱後、ヘキサンにて油溶成分を抽出し、110℃にて加熱することで溶媒を除去した米原油を用いた。
米原油を70℃に加温し、遠心分離を行い、夾雑物である沈殿部を除去した。その後、70℃の温水を米原油に対して3質量%添加し、攪拌後、遠心分離を行い、沈殿した水和物を得た。この水和物を、凍結乾燥機にて乾燥させ、水分量が5質量%以下となった米油由来ガム質を得た。得られた米油由来ガム質を以下のアセトン不溶物量は30質量%であった。
得られた米油由来ガム質を用いて、以下に示す実施例の穀粉生地用プレミックスを製造した。
Next, the present invention will be explained with reference to Examples.
[Production of gum derived from rice oil]
Rice bran was heated at 120°C, oil-soluble components were extracted with hexane, and the solvent was removed by heating at 110°C. US crude oil was used.
US crude oil was heated to 70°C and centrifuged to remove the precipitate, which is an impurity. Thereafter, 70° C. warm water was added in an amount of 3% by mass based on the US crude oil, and after stirring, centrifugation was performed to obtain a precipitated hydrate. This hydrate was dried in a freeze dryer to obtain a rice oil-derived gum having a moisture content of 5% by mass or less. The amount of acetone insoluble matter in the obtained rice oil-derived gum substance was 30% by mass.
Using the obtained rice oil-derived gum, a premix for flour dough according to the following example was produced.

[穀粉生地用プレミックスの製造]
(実施例1-1~1-5、比較例1-1~1-2)
表1に示す配合組成の穀粉生地用プレミックスをベースに以下の方法により製造した。実施例1-1では、液糖(RCS-50)5kgをビーカー内でプロペラ攪拌にて攪拌しながら45℃まで加温する。そこに、45℃に加温した米油由来ガム質 5kgを少しずつ加え、投入後20分間攪拌を行い、穀粉生地用プレミックスを得た。
同様に、実施例1-2~1-5ついても表1に示す配合組成をベースに穀粉生地用プレミックスを上記方法で製造した。比較例1-1については米油ガム質と液糖(RCS-50)を混合せず、穀粉生地へ別々に添加した。比較例1-2については45℃まで加温した水5kgをビーカー内でプロペラ攪拌にて攪拌しながら、45℃に加温した米油由来ガム質 5kgを少しずつ加え、投入後20分間攪拌を行い、穀粉生地用プレミックスを得たが、攪拌停止直後に分離した。そして分離したものを穀粉生地へ添加した。
[Manufacture of premix for flour dough]
(Examples 1-1 to 1-5, Comparative Examples 1-1 to 1-2)
It was produced by the following method based on a flour dough premix having the composition shown in Table 1. In Example 1-1, 5 kg of liquid sugar (RCS-50) is heated to 45° C. while stirring with a propeller in a beaker. There, 5 kg of rice oil-derived gum substance heated to 45° C. was added little by little, and after addition, stirring was performed for 20 minutes to obtain a premix for flour dough.
Similarly, for Examples 1-2 to 1-5, premixes for flour dough were produced using the above method based on the formulation shown in Table 1. In Comparative Example 1-1, rice oil gum and liquid sugar (RCS-50) were not mixed, but were added separately to the flour dough. For Comparative Example 1-2, 5 kg of water heated to 45°C was stirred with a propeller in a beaker, and 5 kg of rice oil-derived gum substance heated to 45°C was added little by little, and stirred for 20 minutes after addition. A premix for flour dough was obtained, but it separated immediately after stirring was stopped. The separated product was then added to the flour dough.

(実施例2-1、比較例2-1~2-2)
表2に示す配合組成の穀粉生地用プレミックスをベースに以下の方法により製造した。実施例2-1では、液糖(RCS-50)9.95kgをビーカー内でプロペラ攪拌にて攪拌しながら45℃まで加温する。そこに、粉末酵素(スミチームL)50gを少しずつ加え、投入後20分間攪拌を行い、穀粉生地用プレミックスを得た。
比較例2-1については、液糖(RCS-50)と粉末酵素(スミチームL)を混合せず、穀粉生地へ別々に添加した。比較例2-2については45℃まで加温した水9.95kgをビーカー内でプロペラ攪拌にて攪拌しながら、粉末酵素(スミチームL)50gを少しずつ加え、投入後20分間攪拌を行い、穀粉生地用プレミックスを得た。
(Example 2-1, Comparative Examples 2-1 to 2-2)
It was manufactured by the following method based on a flour dough premix having the composition shown in Table 2. In Example 2-1, 9.95 kg of liquid sugar (RCS-50) is heated to 45° C. while stirring with a propeller in a beaker. There, 50 g of powdered enzyme (Sumizyme L) was added little by little, and after addition, stirring was performed for 20 minutes to obtain a premix for flour dough.
In Comparative Example 2-1, liquid sugar (RCS-50) and powdered enzyme (Sumizyme L) were not mixed, but were added separately to the flour dough. For Comparative Example 2-2, 9.95 kg of water heated to 45°C was stirred with a propeller in a beaker, and 50 g of powdered enzyme (Sumizyme L) was added little by little. A premix for dough was obtained.

(実施例3-1、比較例3-1)
表3に示す配合組成の穀粉生地用プレミックスをベースに以下の方法により製造した。液糖(RCS―50)4.95kgをビーカー内でプロペラ攪拌にて攪拌しながら45℃まで加温する。そこに、45℃に加温した米油由来ガム質 5kgを少しずつ加え、投入後10分間攪拌を行い、さらに粉末酵素(スミチームL)50gを少しづつ加え、投入後10分間攪拌を行い、穀粉生地用プレミックスを得た。比較例3-1については、液糖(RCS-50)、米油由来ガム質及び粉末酵素(スミチームL)を混合せず、穀粉生地へ別々に添加した。
(Example 3-1, Comparative Example 3-1)
It was produced by the following method based on a flour dough premix having the composition shown in Table 3. 4.95 kg of liquid sugar (RCS-50) is heated to 45°C while stirring with a propeller in a beaker. Add 5 kg of rice oil-derived gum heated to 45°C little by little, stir for 10 minutes, then add 50 g of powdered enzyme (Sumizyme L) little by little, stir for 10 minutes after adding, and stir for 10 minutes. A premix for dough was obtained. For Comparative Example 3-1, liquid sugar (RCS-50), rice oil-derived gummy material, and powdered enzyme (Sumizyme L) were not mixed, but were added separately to the flour dough.

[評価方法]
それぞれの評価項目について、評価方法を下記に記す。
[Evaluation method]
The evaluation method for each evaluation item is described below.

(穀粉生地用プレミックスの水分活性)
製造した穀粉生地用プレミックスの水分活性は水分活性測定装置(商品名:HygroLab、Rotronic社製)を用いて測定した。具体的には、実施例又は比較例の穀粉生地用プレミックス各10gを水分活性測定装置の専用シャーレに配置し、25℃で水分活性を測定した。
(Water activity of premix for flour dough)
The water activity of the produced flour dough premix was measured using a water activity measuring device (trade name: HygroLab, manufactured by Rotronic). Specifically, 10 g of each of the flour dough premixes of Examples and Comparative Examples were placed in a special petri dish of a water activity measuring device, and the water activity was measured at 25°C.

(穀粉生地用プレミックスの状態)
製造した穀粉生地用プレミックスを30℃、30日間保管し、状態について目視にて確認した。分離(沈殿)がないものを「良好」とし、分離(沈殿)があるものを「分離」とした。「良好」のみ合格とした。実施例1-1~1-5、比較例1-2について、米油由来ガム質と液糖が分離していないか確認を行った。実施例2-1、比較例2-2について、酵素が底部へ沈殿していないか確認を行った。実施例3-1について、米油由来ガム質と、液糖及び酵素が分離・沈殿していないか確認を行った。
(State of premix for flour dough)
The produced flour dough premix was stored at 30°C for 30 days, and its condition was visually confirmed. Those with no separation (precipitation) were rated as "good", and those with separation (precipitation) were rated as "separated". Only "good" scores were accepted. Regarding Examples 1-1 to 1-5 and Comparative Example 1-2, it was confirmed whether the rice oil-derived gum and liquid sugar were separated. Regarding Example 2-1 and Comparative Example 2-2, it was confirmed whether the enzyme was precipitated to the bottom. Regarding Example 3-1, it was confirmed whether rice oil-derived gum, liquid sugar, and enzymes were separated and precipitated.

(穀粉生地用プレミックスの保存性)
製造した穀粉生地用プレミックスを30℃、30日間保管し、カビの発生について目視にて確認した。カビの発生がわずかにでも確認できたものは「有」、発生が確認できなかったものは「無」とした。「無」のみ合格とした。
(Storability of premix for flour dough)
The produced premix for flour dough was stored at 30°C for 30 days, and the occurrence of mold was visually confirmed. Items where even the slightest amount of mold growth was confirmed were rated as ``Yes,'' and items where no mold growth could be confirmed were rated as ``No.'' Only “none” was considered a pass.

(穀粉生地への分散性評価:目視試験)
小麦粉1kg、イースト20g、イーストフード1g、上白糖50g、塩17g、脱脂粉乳20g、水690gを関東混合機工業(株)製ミキサーボウルに投入し、ドゥフックにて低速2分間、中低速5分間攪拌後、ショートニング50gを投入し、低速3分間、中低速3分間混合後、穀粉生地用プレミックス10g投入し、低速にて攪拌し、目視にて穀粉生地用プレミックスの分散状況を確認した。
穀粉生地用プレミックスが穀粉生地へ添加後攪拌にて1分以下で分散した場合を「5」、1分を超えて2分以下で分散した場合を「4」、2分を超えて3分以下で分散した場合を「3」、3分を超えて5分以下で分散した場合を「2」、5分を超えても分散しない場合を「1」とし評価した。「5」、「4」のみ合格とした。
なお、表2実施例2-1、比較例2-1~2-2、実施例3-1、比較例3-1の酵素の分散性については目視にて確認できないため、製パン試験においてのボリューム、ソフトさ評価結果を分散性評価の指標とした。
(Evaluation of dispersibility in flour dough: visual test)
Put 1 kg of flour, 20 g of yeast, 1 g of yeast food, 50 g of caster sugar, 17 g of salt, 20 g of skim milk powder, and 690 g of water into a mixer bowl manufactured by Kanto Mixture Machinery Co., Ltd., and mix with a dough hook for 2 minutes on low speed and 5 minutes on medium-low speed. After that, 50 g of shortening was added, mixed for 3 minutes at low speed and 3 minutes at medium-low speed, 10 g of premix for flour dough was added, stirred at low speed, and the dispersion status of the premix for flour dough was visually confirmed.
``5'' if the premix for flour dough was dispersed within 1 minute by stirring after being added to the flour dough; ``4'' if it was dispersed in more than 1 minute and less than 2 minutes; The evaluation was given as "3" if the product was dispersed for less than 3 minutes, "2" if the product was dispersed in more than 3 minutes but not more than 5 minutes, and "1" if the product was not dispersed even after 5 minutes. Only "5" and "4" were considered to be passed.
In addition, since the dispersibility of the enzymes in Table 2 Example 2-1, Comparative Examples 2-1 to 2-2, Example 3-1, and Comparative Example 3-1 cannot be visually confirmed, The volume and softness evaluation results were used as indicators for dispersion evaluation.

(穀粉生地への分散性評価:製パン試験)
ボリューム、ソフトさの評価については以下に示す配合にてワンローフ食パンを製造し評価を行った。なお、米油由来ガム質および酵素は穀粉生地へ均一に分散しなければ十分な効果を発揮できないことから、ボリューム、ソフトさ評価は穀粉生地への分散性評価の指標となる。
小麦粉1kg、イースト20g、イーストフード1g、上白糖50g、食塩17g、脱脂粉乳20g、水690gを関東混合機工業(株)製ミキサーボウルに投入し、ドゥフックにて低速2分間、中低速5分間攪拌後、ショートニング50gを投入し、低速3分間、中低速3分間混合後、穀粉生地用プレミックス10g投入し、低速2分間攪拌し穀粉生地(パン生地)を得た。80分間発酵したのち、430gに分割し、20分間のベンチタイムをとり、(株)オシキリ製モルダーにてコッペパン型に成型し、食パン型に詰め、温度38℃、湿度85%にて60分間ホイロをとり、上火180℃、下火210℃のオーブンにて28分間焼成しワンローフ食パンを製造した。製造後、室温まで自然放冷し、ビニール袋に密閉し室温で保管した。保管1日後に、ボリューム、ソフトさの評価を行った。
(Evaluation of dispersibility in flour dough: bread making test)
Regarding the evaluation of volume and softness, one loaf bread was manufactured and evaluated using the formulation shown below. Note that rice oil-derived gums and enzymes cannot exhibit their full effect unless they are uniformly dispersed in the flour dough, so volume and softness evaluations are indicators for evaluating dispersibility in the flour dough.
1 kg of flour, 20 g of yeast, 1 g of yeast food, 50 g of caster sugar, 17 g of salt, 20 g of skim milk powder, and 690 g of water were placed in a mixer bowl manufactured by Kanto Mixture Machinery Co., Ltd., and stirred with a dough hook for 2 minutes at low speed and 5 minutes at medium-low speed. After that, 50 g of shortening was added, mixed for 3 minutes at low speed and 3 minutes at medium-low speed, 10 g of premix for flour dough was added, and stirred at low speed for 2 minutes to obtain flour dough (bread dough). After fermenting for 80 minutes, it was divided into 430g portions, benched for 20 minutes, molded into a coppépan shape using a molder manufactured by Oshikiri Co., Ltd., packed into bread molds, and baked for 60 minutes at a temperature of 38℃ and a humidity of 85%. was taken and baked in an oven with a top heat of 180°C and a bottom heat of 210°C for 28 minutes to produce a one-loaf bread. After production, it was allowed to cool naturally to room temperature, then sealed in a plastic bag and stored at room temperature. After one day of storage, volume and softness were evaluated.

(ボリュームの評価方法)
焼成後1日目のワンローフ食パンの比容積を測定し、ボリューム評価の指標とした。比容積は、アステックス(株)製3Dレーザー体積計を用いて測定した。各表において、比較例1-1、比較例2-1、比較例3-1のワンローフ食パンの比容積を100とし、比容積が105以上の場合を「5」、105未満、102以上の場合を「4」、98以上、102未満の場合を「3」、95以上、98未満の場合を「2」、95未満の場合を「1」として評価した。「5」、「4」のみ合格とした。
(Volume evaluation method)
The specific volume of the one-loaf bread on the first day after baking was measured and used as an index for volume evaluation. The specific volume was measured using a 3D laser volume meter manufactured by Astex Corporation. In each table, the specific volume of the one-loaf bread of Comparative Example 1-1, Comparative Example 2-1, and Comparative Example 3-1 is taken as 100, and when the specific volume is 105 or more, it is "5", and when it is less than 105, and 102 or more, it is "5". ``4'', 98 or more and less than 102, ``3'', 95 or more, but less than 98, ``2'', and less than 95, ``1''. Only "5" and "4" were considered to be passed.

(ソフトさの評価方法)
焼成後1日目のワンローフ食パンのソフトさを測定し、ソフトさ評価の指標とした。ワンローフ食パンを幅3cmでスライスし、中心部を4cm×4cmの正方形にカットしたものをサンプルとした。上面から1.5cm圧縮するのに必要な応力[N]を(株)山電製レオメーターで測定し、ソフトさの指標とした。各表において、比較例1-1、比較例2-1、比較例3-1のワンローフ食パンのソフトさを100とし、ソフトさが90未満の場合を「5」、90以上、95未満の場合を「4」、95以上、105未満の場合を「3」、105以上、110未満の場合を「2」、110以上の場合を「1」として評価した。「5」、「4」のみ合格とした。
(Softness evaluation method)
The softness of the one-loaf bread on the first day after baking was measured and used as an index for softness evaluation. One loaf bread was sliced to a width of 3 cm, and the center was cut into a 4 cm x 4 cm square to serve as a sample. The stress [N] required to compress the top surface by 1.5 cm was measured using a rheometer manufactured by Yamaden Co., Ltd., and was used as an index of softness. In each table, the softness of the one-loaf breads of Comparative Example 1-1, Comparative Example 2-1, and Comparative Example 3-1 is 100, and if the softness is less than 90, it is 5, and if it is 90 or more and less than 95, it is 100. ``4'', 95 or more and less than 105, ``3'', 105 or more, but less than 110, ``2'', and 110 or more, ``1''. Only "5" and "4" were considered to be passed.

(酵素の残存活性)
1分間に1μmolのグルコースに相当する還元糖を生成する酵素量を1uとして定義し、1%の可溶性デンプン溶液を基質とし、40℃、pH7で10分間反応させ、生じた還元糖を定量することで酵素活性を求めた。
30℃、30日間保管した穀粉生地用プレミックス中の酵素活性を測定し、スミチームLの酵素活性から残存活性を評価した。
スミチームLの酵素活性を100とした際に、酵素の残存活性が95以上の場合を「5」、95未満90以上の場合を「4」、90未満85以上の場合を「3」、85未満80以上の場合を「2」、80未満の場合を「1」として評価した。「5」のみ合格とした。
(Residual activity of enzyme)
The amount of enzyme that produces reducing sugar equivalent to 1 μmol of glucose per minute is defined as 1 u. Using 1% soluble starch solution as a substrate, react at 40°C and pH 7 for 10 minutes, and quantify the resulting reducing sugar. Enzyme activity was determined.
The enzyme activity in the premix for flour dough stored at 30°C for 30 days was measured, and the residual activity was evaluated from the enzyme activity of Sumiteam L.
When the enzyme activity of Sumiteam L is set as 100, the residual activity of the enzyme is 95 or more, "5", less than 95, 90 or more, "4", less than 90, 85 or more, "3", less than 85. A score of 80 or more was rated as "2" and a score of less than 80 was graded as "1". Only "5" was passed.

(評価結果)
表1より、(A)液糖に(B)米油由来ガム質を混合することで分離なく良好な状態の穀粉生地用プレミックスが得られることが分かる。またカビ等の発生もなく、穀粉生地への分散性も優れていることが分かる。さらに、米油由来ガム質が穀粉生地へ均一分散することで、パンのボリューム、ソフトさが向上することが分かる(実施例1-1~1-5)。一方、穀粉生地用プレミックスの原料である米油由来ガム質と液糖を、混合することなく別々に穀粉生地へ投入した場合、米油由来ガム質は穀粉生地中へ均一分散せず、その結果してパンのボリューム、ソフトさ向上効果は得られない(比較例1-1)。また、プレミックスの原料として液糖ではなく水を用いた場合、米油由来ガム質と水は分離し、さらにカビの発生がみられた(比較例1-2)。
表2より、(A)液糖に(C)酵素を混合することで酵素は液糖内に均一分散され良好な状態の穀粉生地用プレミックスが得られることが分かる。またカビ等の発生もなく保存期間中の酵素の残存活性も高く維持された。さらに酵素が液糖内に均一分散することで、穀粉生地へ酵素が均一分散することができ、パンのボリューム、ソフトさが向上することが分かる(実施例2-1)。一方、穀粉生地用プレミックスの原料である酵素と液糖を、混合することなく別々に穀粉生地へ投入した場合、酵素は穀粉生地中へ均一分散せず、その結果してパンのボリューム、ソフトさ向上効果は得られない(比較例2-1)。プレミックスの原料として液糖ではなく水を用いた場合、酵素は溶解せず沈殿し、穀粉生地中へ均一分散せず、その結果としてパンのボリューム、ソフトさ向上効果は得られないことが分かる(比較例2-2)。
表3においても、表1、表2の結果と同様に本発明の穀粉生地用プレミックスを用いると良好な結果が得られた(実施例3-1)。一方、穀粉生地用プレミックスの原料である液糖、米油由来ガム質、酵素を、混合することなく別々に穀粉生地へ投入した場合、パンのボリューム、ソフトさ向上効果は得られなかった(比較例3-1)。
(Evaluation results)
From Table 1, it can be seen that a premix for flour dough in good condition without separation can be obtained by mixing (B) rice oil-derived gum with (A) liquid sugar. Furthermore, it was found that there was no occurrence of mold or the like, and the dispersibility into the flour dough was excellent. Furthermore, it can be seen that the volume and softness of bread are improved by uniformly dispersing the rice oil-derived gum into the flour dough (Examples 1-1 to 1-5). On the other hand, when rice oil-derived gum and liquid sugar, which are raw materials for a premix for flour dough, are added to flour dough separately without mixing, the rice oil-derived gum is not uniformly dispersed in the flour dough; As a result, the effect of improving bread volume and softness cannot be obtained (Comparative Example 1-1). Furthermore, when water was used instead of liquid sugar as the raw material for the premix, the gum derived from rice oil and water were separated, and furthermore, mold growth was observed (Comparative Example 1-2).
Table 2 shows that by mixing (A) the enzyme (C) with the liquid sugar, the enzyme is uniformly dispersed in the liquid sugar and a flour dough premix in good condition can be obtained. Furthermore, there was no growth of mold or the like, and the residual activity of the enzyme was maintained at a high level during the storage period. Furthermore, it can be seen that by uniformly dispersing the enzyme in the liquid sugar, the enzyme can be uniformly dispersed in the flour dough, improving the volume and softness of the bread (Example 2-1). On the other hand, if enzymes and liquid sugar, which are the raw materials for the flour dough premix, are added to the flour dough separately without mixing, the enzymes will not be uniformly dispersed in the flour dough, resulting in lower volume and softness of the bread. No effect of improving the thickness was obtained (Comparative Example 2-1). It can be seen that when water is used instead of liquid sugar as the raw material for the premix, the enzyme does not dissolve but precipitates and is not uniformly dispersed in the flour dough, resulting in no improvement in bread volume and softness. (Comparative Example 2-2).
Also in Table 3, similar to the results in Tables 1 and 2, good results were obtained when the premix for flour dough of the present invention was used (Example 3-1). On the other hand, when liquid sugar, rice oil-derived gum, and enzymes, which are the raw materials for the flour dough premix, were added to the flour dough separately without mixing them, no improvement in bread volume or softness was obtained ( Comparative Example 3-1).

(使用原料)
(1)(商品名)「Ricelec BK」、Irgovel製、アセトン不溶物量60質量%
(2)(商品名)「RCS-50」、王子コーンスターチ(株)製、砂糖混合ぶどう糖果糖液糖、水分活性0.73
(3)(商品名)「アマミール」、三菱商事フードテック(株)製、還元水飴、水分活性0.82
(4)(商品名)「スミチームL」、新日本化学工業(株)製、12000u/g、至適温度50℃


(Raw materials used)
(1) (Product name) "Ricelec BK", manufactured by Irgovel, acetone insoluble matter amount 60% by mass
(2) (Product name) "RCS-50", manufactured by Oji Cornstarch Co., Ltd., glucose mixed with sugar, high-fructose corn syrup, water activity 0.73
(3) (Product name) "Amamil", manufactured by Mitsubishi Corporation Food Tech Co., Ltd., reduced starch syrup, water activity 0.82
(4) (Product name) "SumiTeam L", manufactured by Shin Nippon Chemical Industry Co., Ltd., 12000u/g, optimum temperature 50℃


Claims (3)

(A)液糖及び(B)米油由来ガム質を含有し、水分活性が0.80以下であり、
前記(A)液糖の含有量が20質量%以上、90質量%以下であり、前記(B)米油由来ガム質の含有量が10質量%以上、80質量%以下である、穀粉生地用プレミックス。
Contains (A) liquid sugar and (B) rice oil-derived gummy substance, and has a water activity of 0.80 or less,
For flour dough, the content of the (A) liquid sugar is 20% by mass or more and 90% by mass or less, and the content of the (B) rice oil-derived gummy substance is 10% by mass or more and 80% by mass or less. Premix.
(A)液糖及び(C)酵素を含有し、水分活性が0.80以下であり、
前記(A)液糖の含有量が90質量%以上である、穀粉生地用プレミックス。
Contains (A) liquid sugar and (C) an enzyme, and has a water activity of 0.80 or less,
A premix for flour dough , wherein the content of the liquid sugar (A) is 90% by mass or more .
(A)液糖、(B)米油由来ガム質及び(C)酵素を含有し、水分活性が0.80以下であり、
前記(B)米油由来ガム質の含有量が10質量%以上、又は、前記(A)液糖の含有量が90質量%以上である、穀粉生地用プレミックス。
Contains (A) liquid sugar, (B) rice oil-derived gum and (C) enzyme, and has a water activity of 0.80 or less,
A premix for flour dough, wherein the content of the rice oil-derived gum (B) is 10% by mass or more, or the content of the liquid sugar (A) is 90% by mass or more .
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003000136A (en) 2001-06-25 2003-01-07 Asahi Denka Kogyo Kk Puff-improving agent and oil and fat composition for roll-in
JP2006121990A (en) 2004-10-29 2006-05-18 Kaneka Corp Phospholipid-containing oil and fat, and oil and fat processed food using the same
JP2014140365A (en) 2012-12-28 2014-08-07 Kao Corp Baked confectionery
JP2021103990A (en) 2019-12-26 2021-07-26 日油株式会社 Oil-in-water emulsified oil and fat composition for liquid leaven dough
JP2023082679A (en) 2021-12-02 2023-06-14 日清オイリオグループ株式会社 Oil-in-water type emulsion

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003000136A (en) 2001-06-25 2003-01-07 Asahi Denka Kogyo Kk Puff-improving agent and oil and fat composition for roll-in
JP2006121990A (en) 2004-10-29 2006-05-18 Kaneka Corp Phospholipid-containing oil and fat, and oil and fat processed food using the same
JP2014140365A (en) 2012-12-28 2014-08-07 Kao Corp Baked confectionery
JP2021103990A (en) 2019-12-26 2021-07-26 日油株式会社 Oil-in-water emulsified oil and fat composition for liquid leaven dough
JP2023082679A (en) 2021-12-02 2023-06-14 日清オイリオグループ株式会社 Oil-in-water type emulsion

Non-Patent Citations (1)

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Title
公益社団法人 日本油化学会,2. 油脂の製造,改訂新版 油脂製品の知識,2018年,p.82

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