JP7409739B2 - Fruit juice-flavored carbonated drink with enhanced fruit juice taste and method for producing the same - Google Patents

Fruit juice-flavored carbonated drink with enhanced fruit juice taste and method for producing the same Download PDF

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JP7409739B2
JP7409739B2 JP2019156256A JP2019156256A JP7409739B2 JP 7409739 B2 JP7409739 B2 JP 7409739B2 JP 2019156256 A JP2019156256 A JP 2019156256A JP 2019156256 A JP2019156256 A JP 2019156256A JP 7409739 B2 JP7409739 B2 JP 7409739B2
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fruit juice
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忠良 早川
富美 影嶋
加納 三輪
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Nihon Shokuhin Kako Co Ltd
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Description

本発明は、果汁風味炭酸飲料およびその製造方法に関する。本発明はまた、果汁風味炭酸飲料の果汁感増強方法および果汁風味炭酸飲料の果汁感増強剤に関する。 The present invention relates to a fruit juice flavored carbonated beverage and a method for producing the same. The present invention also relates to a method for enhancing the fruit flavor of a fruit-flavored carbonated beverage and an agent for enhancing the fruit-juice flavor of a fruit-flavored carbonated beverage.

果汁風味炭酸飲料の美味しさを決定付ける大きな要因となるのは、その果汁感にある。しかし、果汁を飲料に配合した場合、果汁そのものが沈殿の原因となり、特に、果汁が柑橘類を主とした酸性果汁である場合には他の成分との相互作用による品質悪化の原因となりやすいため、必然的にその配合量を抑えざるをえないことが多い。また、一般的にオレンジ、グレープフルーツ、リンゴ、グレープ等の果汁風味炭酸飲料に用いられる果汁原料は、高価なため配合量を抑えたり、果汁の配合を止めて香料のみを使用した無果汁飲料としたりすることが多い。 A major factor that determines the taste of fruit juice-flavored carbonated drinks is its fruit juice feel. However, when fruit juice is added to drinks, the fruit juice itself can cause precipitation, and especially when the fruit juice is acidic, mainly from citrus fruits, it is likely to cause quality deterioration due to interaction with other ingredients. In many cases, it is necessary to suppress the amount added. In addition, the fruit juice ingredients used in fruit juice-flavored carbonated drinks, such as orange, grapefruit, apple, and grape, are generally expensive, so the amount of blended fruit juice has to be reduced, or fruit juice has been stopped to create juice-free drinks that only use flavorings. There are many things to do.

しかし、果汁の含有量を減じた飲料や、果汁を含まない飲料は、味が単調で、コクがなく、甘味のみ強い人工的な風味にも感じられてしまうという問題があった。特に近年では、無果汁または低果汁のわずかに果汁風味を感じる果汁風味炭酸飲料が数多く上市されているが、これらの無果汁または低果汁の炭酸飲料は果汁含有量が低いため、各種香料やエキスを用いて果汁風味を付与している。すなわち、無果汁または低果汁の炭酸飲料は、高果汁に比べ、自然な甘味、コク、ボディ感といった果汁感に劣るという問題もあった。このため、無果汁または低果汁の炭酸飲料において、高果汁炭酸飲料のような自然な甘味、コク、ボディ感といった果汁感が付与された果汁炭酸飲料が求められているといえる。 However, beverages with reduced fruit juice content or beverages that do not contain fruit juice have a problem in that they have a monotonous taste, lack richness, and have a strong artificial flavor with only a sweet taste. Particularly in recent years, many fruit juice-flavored carbonated drinks with a slight fruit flavor have been put on the market. is used to impart a fruit juice flavor. That is, carbonated beverages without fruit juice or with low fruit juice have a problem in that they are inferior in fruit juice sensation such as natural sweetness, richness, and body feel compared to carbonated beverages with high fruit juice content. For this reason, it can be said that there is a demand for a fruit juice carbonated drink that has a fruit juice feel such as natural sweetness, richness, and body like a high fruit juice carbonated drink.

これまでに、特定構造を有するグルカンを有効成分とする果汁含有飲食品の果汁感向上剤(特許文献1)や、ゲンチオオリゴ糖を有効成分とする低果汁または無果汁飲料の果汁感付与剤(特許文献2)が提案されている。 So far, we have developed a fruit juice sensation improving agent for fruit juice-containing foods and beverages that uses glucan with a specific structure as an active ingredient (Patent Document 1), and a fruit juice sensitizer for low fruit juice or fruit juice-free beverages that uses gentio-oligosaccharide as an active ingredient (patent document 1). Reference 2) has been proposed.

特開2003-289836号公報JP2003-289836A 特開2011-206030号公報Japanese Patent Application Publication No. 2011-206030

本発明は、果汁感が増強された、新規果汁風味炭酸飲料およびその製造方法を提供することを目的とする。 An object of the present invention is to provide a novel fruit juice flavored carbonated beverage with enhanced fruit juice taste and a method for producing the same.

本発明者らは今般、果汁風味炭酸飲料に難消化性グルカンおよび/またはその加工処理物、果糖及びショ糖を特定の割合で含有させることで、該果汁風味炭酸飲料の果汁感を増強できることを見出した。本発明はこの知見に基づくものである。 The present inventors have recently discovered that the fruit juice flavor of a fruit juice-flavored carbonated beverage can be enhanced by incorporating indigestible glucan and/or its processed product, fructose, and sucrose in a specific ratio into the fruit-flavored carbonated beverage. I found it. The present invention is based on this knowledge.

本発明によれば以下の発明が提供される。
[1](a)難消化性グルカンおよび/またはその加工処理物、(b)果糖並びに(c)ショ糖を含んでなる果汁風味炭酸飲料であって、前記飲料中の上記(a)、(b)および(c)の合計含有量(固形分換算質量)に対する、上記(a)、(b)および(c)のそれぞれの含有量(固形分換算質量)の比率が、5~15%、40~80%および15~45%である、果汁風味炭酸飲料。
[2]果汁含有量が40%以下である、上記[1]に記載の果汁風味炭酸飲料。
[3]果汁風味炭酸飲料の製造方法であって、(a)難消化性グルカンおよび/またはその加工処理物、(b)果糖並びに(c)ショ糖を他の原材料と混合する工程を含んでなり、前記飲料中の上記(a)、(b)および(c)の合計含有量(固形分換算質量)に対する、上記(a)、(b)および(c)のそれぞれの含有量(固形分換算質量)の比率を、5~15%、40~80%および15~45%に調整することを特徴とする、果汁風味炭酸飲料の製造方法。
[4]果汁風味炭酸飲料の果汁含有量が40%以下である、上記[3]に記載の果汁風味炭酸飲料の製造方法。
[5]果汁風味炭酸飲料の果汁感増強方法であって、(a)難消化性グルカンおよび/またはその加工処理物、(b)果糖並びに(c)ショ糖を他の原材料と混合する工程を含んでなり、前記飲料中の上記(a)、(b)および(c)の合計含有量(固形分換算質量)に対する、上記(a)、(b)および(c)のそれぞれの含有量(固形分換算質量)の比率を、5~15%、40~80%および15~45%に調整することを特徴とする、果汁感増強方法。
[6]果汁風味炭酸飲料の果汁含有量が40%以下である、上記[5]に記載の果汁感増強方法。
[7](a)難消化性グルカンおよび/またはその加工処理物、(b)果糖並びに(c)ショ糖を含んでなる果汁風味炭酸飲料の果汁感増強剤であって、前記増強剤中の上記(a)、(b)および(c)の合計含有量(固形分換算質量)に対する、上記(a)、(b)および(c)のそれぞれの含有量(固形分換算質量)の比率が、5~15%、40~80%および15~45%である、果汁感増強剤。
[8]果汁風味炭酸飲料の果汁含有量が40%以下である、上記[7]に記載の果汁感増強剤。
According to the present invention, the following inventions are provided.
[1] A fruit juice-flavored carbonated beverage comprising (a) indigestible glucan and/or a processed product thereof, (b) fructose, and (c) sucrose, which contains the above (a), ( The ratio of the content (solid content equivalent mass) of each of the above (a), (b) and (c) to the total content (solid content equivalent mass) of b) and (c) is 5 to 15%, A fruit juice flavored carbonated beverage having a content of 40 to 80% and a content of 15 to 45%.
[2] The fruit juice-flavored carbonated beverage according to [1] above, which has a fruit juice content of 40% or less.
[3] A method for producing a fruit juice-flavored carbonated beverage, comprising the step of mixing (a) indigestible glucan and/or a processed product thereof, (b) fructose, and (c) sucrose with other raw materials. The content of each of the above (a), (b) and (c) relative to the total content (solid content equivalent mass) of the above (a), (b) and (c) in the beverage A method for producing a fruit juice-flavored carbonated beverage, the method comprising adjusting the ratio of (converted mass) to 5 to 15%, 40 to 80%, and 15 to 45%.
[4] The method for producing a fruit juice-flavored carbonated beverage according to [3] above, wherein the fruit juice-flavored carbonated beverage has a fruit juice content of 40% or less.
[5] A method for enhancing the fruit juice taste of a fruit-flavored carbonated drink, which comprises the steps of mixing (a) indigestible glucan and/or its processed product, (b) fructose, and (c) sucrose with other raw materials. and the content of each of the above (a), (b) and (c) relative to the total content (solid content equivalent mass) of the above (a), (b) and (c) in the drink. A method for enhancing fruit juice taste, which comprises adjusting the ratio of solid content (mass equivalent to solid content) to 5 to 15%, 40 to 80%, and 15 to 45%.
[6] The method for enhancing fruit juice taste according to [5] above, wherein the fruit juice flavored carbonated beverage has a fruit juice content of 40% or less.
[7] A fruit juice taste enhancer for a fruit juice-flavored carbonated beverage comprising (a) indigestible glucan and/or a processed product thereof, (b) fructose, and (c) sucrose, the enhancer comprising: The ratio of each content (solid content equivalent mass) of the above (a), (b) and (c) to the total content (solid content equivalent mass) of the above (a), (b) and (c) is , 5-15%, 40-80% and 15-45%.
[8] The fruit juice taste enhancer according to [7] above, wherein the fruit juice flavored carbonated beverage has a fruit juice content of 40% or less.

本発明によれば飲料中の難消化性グルカンおよび/またはその加工処理物、果糖およびショ糖の含有比率を特定範囲内に調整することにより果汁風味炭酸飲料の果汁感を増強することができる。 According to the present invention, the fruit flavor of a fruit-flavored carbonated beverage can be enhanced by adjusting the content ratio of indigestible glucan and/or its processed product, fructose, and sucrose in the beverage within a specific range.

発明の具体的説明Specific description of the invention

本発明において「果汁風味炭酸飲料」とは、果汁風味が付与された炭酸飲料を意味し、果汁風味が付与された炭酸飲料であれば、いずれのものでもよい。果汁風味炭酸飲料としては、炭酸ノンアルコール飲料(例えば、果実入り炭酸飲料、果汁入り炭酸飲料、清涼炭酸飲料、炭酸入りニアウォーター、炭酸入りスポーツドリンク、フルーツ風味炭酸飲料、フルーツ風味乳性炭酸飲料)および炭酸アルコール飲料(例えば、チュウハイ)が挙げられる。 In the present invention, the term "fruit juice flavored carbonated beverage" refers to a carbonated beverage flavored with fruit juice, and any carbonated beverage flavored with fruit juice may be used. Fruit juice-flavored carbonated drinks include carbonated non-alcoholic drinks (for example, fruit-flavored carbonated drinks, fruit juice-containing carbonated drinks, soft carbonated drinks, carbonated near water, carbonated sports drinks, fruit-flavored carbonated drinks, fruit-flavored milky carbonated drinks). and carbonated alcoholic beverages (eg, Chuhai).

本発明において「果汁風味」とは、果汁が有する香気、甘味、酸味、苦味、自然な風味、フレッシュ感、コク等を意味し、果汁や果肉など果実そのものを用いて付与された風味、果実由来の果実から抽出されたエキスや香料を用いて付与された風味、さらには人工的に合成された物質を用いて付与された風味のいずれであってもよい。人工的に合成された物質としては、例えば、果実の香りを有する合成香料が挙げられる。 In the present invention, "fruit juice flavor" refers to the aroma, sweetness, sourness, bitterness, natural flavor, freshness, richness, etc. that fruit juice has, and includes the flavor imparted by using the fruit itself such as fruit juice and pulp, and the flavor derived from fruit. The flavor may be imparted using an extract or flavoring agent extracted from the fruit, or the flavor may be imparted using an artificially synthesized substance. Examples of artificially synthesized substances include synthetic fragrances with fruity scents.

本発明において「果汁風味」や「果汁感」の対象となる果実としては、特に限定されるものではないが、例えば、オレンジ、グレープフルーツ、蜜柑、ぽんかん、甘夏、柚子、レモン等の柑橘系果実や、葡萄、桃、リンゴ、パイナップル、ウメ、チェリー、キウイ、イチゴ、ブルーベリー、メロン、バナナ、マンゴー、梨、洋梨等が挙げられる。 In the present invention, fruits that are subject to "fruit juice flavor" or "fruit juice feeling" are not particularly limited, but include, for example, citrus fruits such as oranges, grapefruit, mandarin oranges, ponkan, sweet summer, yuzu, and lemon. Examples of fruits include grapes, peaches, apples, pineapples, plums, cherries, kiwis, strawberries, blueberries, melons, bananas, mangoes, pears, and pears.

本発明の果汁風味炭酸飲料は、(a)難消化性グルカンおよび/またはその加工処理物、(b)果糖並びに(c)ショ糖を組合せて含有することを特徴とするものである。以下、各成分について説明する。 The fruit juice-flavored carbonated beverage of the present invention is characterized by containing a combination of (a) indigestible glucan and/or a processed product thereof, (b) fructose, and (c) sucrose. Each component will be explained below.

(a)難消化性グルカンおよびその加工処理物
本発明において使用する「難消化性グルカン」は、難消化性のグルカン(グルコースポリマー)を意味する。本発明の難消化性グルカンは、DE70~100の澱粉分解物を加熱処理により縮合反応させた糖縮合物からなるものである。
(a) Indigestible glucan and processed products thereof "Indigestible glucan" used in the present invention means indigestible glucan (glucose polymer). The indigestible glucan of the present invention is made of a sugar condensate obtained by subjecting a starch decomposition product having a DE of 70 to 100 to a condensation reaction through heat treatment.

難消化性グルカンの原料となる澱粉分解物としては、DEが70~100である澱粉分解物を使用することができる。澱粉分解物は、例えば、澱粉を酸で加水分解したものでも、酵素で加水分解したものでもよい。ここで、「DE(Dextrose Equivalent)」とは、澱粉分解物の分解度合いの指標であり、試料中の還元糖をブドウ糖として固形分に対する百分率で示した値である。澱粉分解物のDEは、例えばレーンエイノン法で測定することができる。難消化性グルカンの原料となる澱粉分解物は、DEが75~100であることが好ましく、80~100であることがより好ましい。 As the starch decomposition product serving as a raw material for indigestible glucan, a starch decomposition product having a DE of 70 to 100 can be used. The starch decomposition product may be, for example, one obtained by hydrolyzing starch with an acid or an enzyme. Here, "DE (Dextrose Equivalent)" is an index of the degree of decomposition of starch decomposition products, and is a value expressed as a percentage of the solid content, assuming that the reducing sugar in the sample is glucose. The DE of starch decomposition products can be measured, for example, by the Lane-Eynon method. The DE of the starch decomposition product used as a raw material for indigestible glucan is preferably 75 to 100, more preferably 80 to 100.

本発明に用いられる「DE70~100の澱粉分解物」は、DEが所定の範囲を満たす澱粉分解物であればよく、例えば、マルトオリゴ糖、水飴、粉飴、グルコース等が挙げられる。その性状も特に制限はなく、結晶品(無水ぶどう糖結晶、含水ぶどう糖結晶等)、液状品(液状ぶどう糖、水飴等)、非結晶粉末品(粉飴等)のいずれでもよいが、ハンドリングや製造コストを考慮すると液状品を用いることが好ましい。特に、グルコースの精製工程で生じる副産物である「ハイドロール」と呼ばれるグルコースシラップの使用は、リサイクルや原料コスト削減の観点から極めて有利である。 The "starch decomposition product with a DE of 70 to 100" used in the present invention may be any starch decomposition product whose DE satisfies a predetermined range, and examples thereof include maltooligosaccharides, starch syrup, powdered candy, glucose, and the like. There are no particular restrictions on its properties, and it may be crystalline (anhydrous glucose crystals, hydrated glucose crystals, etc.), liquid (liquid glucose, starch syrup, etc.), or amorphous powder (powdered candy, etc.), but handling and manufacturing costs are high. Considering this, it is preferable to use a liquid product. In particular, the use of glucose syrup called "hydrol", which is a byproduct produced in the glucose purification process, is extremely advantageous from the viewpoint of recycling and reducing raw material costs.

本発明において「加熱縮合」は、澱粉分解物を加熱条件下において縮合させることをいい、加熱縮合方法は当業者に周知である。加熱縮合における加熱条件は、縮合反応により本発明の難消化性グルカンが得られれば特に制限はなく、当業者であれば加熱条件を適宜決定することができるが、得られる難消化性グルカン(糖縮合物)の食物繊維含有量が70%以上となるように加熱することが好ましく、例えば、100℃~300℃で1~180分間、より好ましくは、150℃~250℃で1~180分間加熱処理することで本発明の難消化性グルカンを製造することができる。 In the present invention, "heat condensation" refers to condensing starch decomposition products under heating conditions, and heat condensation methods are well known to those skilled in the art. The heating conditions in the thermal condensation are not particularly limited as long as the indigestible glucan of the present invention can be obtained by the condensation reaction, and those skilled in the art can appropriately determine the heating conditions. It is preferable to heat the condensate) so that the dietary fiber content is 70% or more, for example, at 100°C to 300°C for 1 to 180 minutes, more preferably at 150°C to 250°C for 1 to 180 minutes. By this treatment, the indigestible glucan of the present invention can be produced.

加熱縮合処理に用いる加熱機器としては、例えば、棚式熱風乾燥機、薄膜式蒸発器、フラッシュエバポレーター、減圧乾燥機、熱風乾燥機、スチームジャケットスクリューコンベヤー、ドラムドライヤー、エクストルーダー、ウォームシャフト反応機、ニーダー等が挙げられる。また、加熱縮合処理は常圧条件下で行ってもよく、減圧条件下で反応を行ってもよい。減圧条件下で行った場合、反応生成物の着色度が低下する点で有利である。 Examples of heating equipment used in the heating condensation treatment include a shelf type hot air dryer, a thin film type evaporator, a flash evaporator, a vacuum dryer, a hot air dryer, a steam jacket screw conveyor, a drum dryer, an extruder, a worm shaft reactor, Examples include kneaders and the like. Further, the heat condensation treatment may be performed under normal pressure conditions, or the reaction may be performed under reduced pressure conditions. When carried out under reduced pressure conditions, it is advantageous in that the degree of coloration of the reaction product is reduced.

本発明において加熱縮合処理は、無触媒条件下で行ってもよいが、縮合反応の反応効率の点から触媒存在下で行うことが好ましい。前記触媒としては糖縮合反応を触媒するものであれば特に制限はないが、例えば、塩酸、リン酸、硫酸、硝酸等の無機酸、クエン酸、フマル酸、酒石酸、コハク酸、酢酸等の有機酸、珪藻土、活性白土、酸性白土、ベントナイト、カオリナイト、タルク等の鉱物性物質および水蒸気炭、塩化亜鉛炭、スルホン化活性炭、酸化活性炭等の活性炭を用いることができる。得られる水溶性食物繊維素材の着色や安全性、更には味・臭いを考慮すると、触媒として活性炭を用いることが好ましい。前記各触媒は2種以上を組み合わせて使用することもできる。 In the present invention, the thermal condensation treatment may be performed under non-catalytic conditions, but from the viewpoint of reaction efficiency of the condensation reaction, it is preferably performed in the presence of a catalyst. The catalyst is not particularly limited as long as it catalyzes the sugar condensation reaction, but examples include inorganic acids such as hydrochloric acid, phosphoric acid, sulfuric acid, and nitric acid, and organic acids such as citric acid, fumaric acid, tartaric acid, succinic acid, and acetic acid. Mineral substances such as acid, diatomaceous earth, activated clay, acid clay, bentonite, kaolinite, and talc, and activated carbon such as steam charcoal, zinc chloride charcoal, sulfonated activated carbon, and oxidized activated carbon can be used. Considering the coloring and safety of the resulting water-soluble dietary fiber material, as well as the taste and odor, it is preferable to use activated carbon as a catalyst. Each of the above catalysts can also be used in combination of two or more.

本発明に用いられる難消化性グルカンは上記手法で得られた難消化性グルカンをそのまま用いても良く、あるいは、食物繊維含有量の増加や着色の低減等を目的として食品加工上許容される処理が施された難消化性グルカンの各種処理物(本明細書において「加工処理物」という)を用いてもよい。難消化性グルカンの加工処理物としては、例えば、難消化性グルカン酵素処理物、難消化性グルカン分画処理物、難消化性グルカン還元処理物が挙げられる。 The indigestible glucan used in the present invention may be the indigestible glucan obtained by the above method as it is, or may be subjected to any acceptable food processing treatment for the purpose of increasing the dietary fiber content or reducing coloring. Various processed products of indigestible glucans (herein referred to as "processed products") may be used. Examples of processed products of indigestible glucan include indigestible glucan enzyme-treated products, indigestible glucan fractionation products, and indigestible glucan reduction products.

本発明において「難消化性グルカン酵素処理物」は、難消化性グルカンを糖質分解酵素や異性化酵素で酵素処理して得ることができる。 In the present invention, the "indigestible glucan enzyme-treated product" can be obtained by enzymatically treating indigestible glucan with a carbohydrate degrading enzyme or an isomerase.

本発明において「糖質分解酵素」は、糖質に作用し加水分解反応を触媒する酵素を意味し、例えば、α-アミラーゼ、β-アミラーゼ、グルコアミラーゼ(アミログルコシダーゼ)、イソアミラーゼ、プルラナーゼ、α-グルコシダーゼ、シクロデキストリングルカノトランスフェラーゼ、β-グルコシダーゼ、β-ガラクトシダーゼ、β-マンノシダーゼ、β-フルクトシダーゼ、セロビアーゼ、ゲンチオビアーゼが挙げられる。糖質分解酵素は、単独で用いてもよく、複数の酵素を組み合わせて用いてもよい。難消化性グルカンへの分解作用からα-アミラーゼおよびグルコアミラーゼが好ましく、両酵素のいずれかを単独で作用させてもよいが、α-アミラーゼおよびグルコアミラーゼを共に作用させるのが特に好ましい。 In the present invention, "carbohydrate degrading enzyme" means an enzyme that acts on carbohydrates and catalyzes a hydrolysis reaction, such as α-amylase, β-amylase, glucoamylase (amyloglucosidase), isoamylase, pullulanase, α - Glucosidase, cyclodextrin glucanotransferase, β-glucosidase, β-galactosidase, β-mannosidase, β-fructosidase, cellobiase, gentiobiase. Carbohydrate degrading enzymes may be used alone or in combination of multiple enzymes. α-amylase and glucoamylase are preferred because of their degrading action on indigestible glucan, and although either enzyme may act alone, it is particularly preferred that α-amylase and glucoamylase act together.

本発明において糖質分解酵素処理の条件は、酵素処理により難消化性グルカンの易消化性部分が消化される条件であれば特に制限はなく、当業者であれば酵素処理条件を適宜決定することができるが、酵素処理により固形分当たりグルコース含有量が1質量%以上、より好ましくは2質量%以上増加するように処理するのが好ましく、例えば、20~120℃で30分間~48時間、より好ましくは、50~100℃で30分間~48時間酵素処理することができる。 In the present invention, the conditions for the carbohydrate degrading enzyme treatment are not particularly limited as long as the easily digestible portion of the indigestible glucan is digested by the enzyme treatment, and those skilled in the art can appropriately determine the enzyme treatment conditions. However, it is preferable that the enzyme treatment increases the glucose content per solid content by 1% by mass or more, more preferably by 2% by mass or more, for example, at 20 to 120°C for 30 minutes to 48 hours. Preferably, the enzyme treatment can be performed at 50 to 100°C for 30 minutes to 48 hours.

本発明において「異性化酵素」は、糖質に作用し異性化反応を触媒する酵素を意味し、例えば、マンノースエピメラーゼ、グルコースイソアミラーゼが挙げられる。糖異性化酵素は、単独で用いてもよく、上記糖質分解酵素と組み合わせて用いてもよい。 In the present invention, "isomerase" means an enzyme that acts on carbohydrates and catalyzes an isomerization reaction, and includes, for example, mannose epimerase and glucose isoamylase. Glycoisomerase may be used alone or in combination with the above-mentioned carbohydrate degrading enzymes.

本発明において「難消化性グルカン分画処理物」は、難消化性グルカンおよび/またはその酵素処理物を、分画処理して得ることができる。膜分離やゲルろ過クロマトグラフィー等の分画手段で分画処理し、特定重合度の糖質を除去したものをいう。加えて、食物繊維含有量を高めることで食物繊維としての価値や食物繊維由来の生理機能を高めることができる。この「分画処理」は、二糖以下の含有量が固形分当たり15質量%以下、好ましくは10質量%以下、より好ましくは5質量%以下となるように実施することができる。 In the present invention, the "indigestible glucan fractionation product" can be obtained by fractionating indigestible glucan and/or its enzyme-treated product. It refers to carbohydrates that have been subjected to fractionation treatment such as membrane separation or gel filtration chromatography to remove carbohydrates with a specific degree of polymerization. In addition, by increasing the dietary fiber content, the value of dietary fiber and the physiological functions derived from dietary fiber can be increased. This "fractionation treatment" can be carried out so that the content of disaccharides or less is 15% by mass or less, preferably 10% by mass or less, more preferably 5% by mass or less based on the solid content.

本発明において「分画処理」は、固形分当たりの二糖以下の含有量を15質量%以下にすることができる処理であれば特に制限はなく、その分離方法は当業者に周知の手段を利用することができる。例えば、膜分離、ゲルろ過クロマトグラフィー、カーボン-セライトカラムクロマトグラフィー、強酸性陽イオン交換カラムクロマトグラフィー、エタノール沈殿、溶媒沈殿等当業者に周知の糖質の精製手段を分画処理に使用することができる。 In the present invention, "fractionation treatment" is not particularly limited as long as it is a treatment that can reduce the content of disaccharides or less per solid content to 15% by mass or less, and the separation method can be any method well known to those skilled in the art. can be used. For example, carbohydrate purification means well known to those skilled in the art, such as membrane separation, gel filtration chromatography, carbon-celite column chromatography, strongly acidic cation exchange column chromatography, ethanol precipitation, and solvent precipitation, may be used for the fractionation treatment. I can do it.

本発明において「難消化性グルカン還元処理物」は、難消化性グルカン、難消化性グルカン酵素処理物、難消化性グルカン分画処理物のいずれかを単独または複数組み合わせたものを還元処理して得ることができる。 In the present invention, "indigestible glucan reduced product" refers to indigestible glucan, indigestible glucan enzyme-treated product, or indigestible glucan fractionated product, either singly or in combination, which is reduced. Obtainable.

本発明において「還元処理」は、糖の還元末端のグルコシル基のアルデヒド基を水酸基に還元する処理をいう。還元処理方法は当業者に周知であり、例えば、ヒドリド還元剤を用いる方法、プロトン性溶媒中の金属を用いる方法、電解還元方法、接触水素化反応方法が挙げられる。本発明においては、少量の糖アルコールを調製する場合にはヒドリド還元剤を用いる方法が簡便で、かつ、特殊な装置を必要とせず好都合であり、一方で、工業的に大規模に実施する場合には、経済性に優れ、副生成物も少ないという点から、接触水素化反応を用いる方法が好ましい。「接触水素化反応」とは、触媒の存在下、不飽和有機化合物の二重結合部に水素を添加する反応であり、一般に水添反応ともいわれている。還元処理を実施することにより、本発明で使用する難消化性グルカンやその加工処理物の着色を低減したり、酸・アルカリに対する安定性を高めたり、加熱による褐変反応やアミノ酸、タンパク質とのメイラード反応を抑制したりすることができる。 In the present invention, "reduction treatment" refers to treatment for reducing the aldehyde group of the glucosyl group at the reducing end of sugar to a hydroxyl group. Reduction treatment methods are well known to those skilled in the art, and include, for example, a method using a hydride reducing agent, a method using a metal in a protic solvent, an electrolytic reduction method, and a catalytic hydrogenation reaction method. In the present invention, when preparing a small amount of sugar alcohol, the method using a hydride reducing agent is convenient and does not require special equipment, and on the other hand, when carried out on an industrial scale, For this purpose, a method using a catalytic hydrogenation reaction is preferable because it is economical and produces fewer by-products. The "catalytic hydrogenation reaction" is a reaction in which hydrogen is added to the double bond of an unsaturated organic compound in the presence of a catalyst, and is also generally referred to as a hydrogenation reaction. By carrying out the reduction treatment, it is possible to reduce the coloration of the indigestible glucan used in the present invention and its processed products, increase the stability against acids and alkalis, and reduce the browning reaction caused by heating and Maillard reaction with amino acids and proteins. It is possible to suppress the reaction.

本発明の難消化性グルカンおよび/またはその加工処理物は、水溶性食物繊維(本明細書において、単に「食物繊維」ということがある)を有するものである。本発明の難消化性グルカンおよび/またはその加工処理物の食物繊維含有量は、果汁風味炭酸飲料に効率的に果汁感およびボディ感を付与する観点から、下限値は70%(好ましくは75%)とすることができ、上限値は90%(好ましくは80%)とすることができる。これらの下限値および上限値はそれぞれ任意に組み合わせることができ、上記含有比率の範囲は、例えば、70~90%(好ましくは75~80%)とすることができる。本発明において水溶性食物繊維含量は、平成27年3月30日消食表第139号「食品表示基準について」における「別添栄養成分等の分析方法等」に記載されている高速液体クロマトグラフ法(酵素-HPLC法)により測定することができる。 The indigestible glucan and/or its processed product of the present invention contains water-soluble dietary fiber (herein sometimes simply referred to as "dietary fiber"). The dietary fiber content of the indigestible glucan and/or its processed product of the present invention has a lower limit of 70% (preferably 75%) from the viewpoint of efficiently imparting a fruit flavor and a body texture to fruit juice-flavored carbonated beverages. ), and the upper limit can be 90% (preferably 80%). These lower and upper limits can be arbitrarily combined, and the range of the content ratio can be, for example, 70 to 90% (preferably 75 to 80%). In the present invention, the water-soluble dietary fiber content is determined using the high-performance liquid chromatography method described in "Analysis methods for nutritional components, etc. attached" in "Food Labeling Standards", No. 139 of the Food and Nutrition Table dated March 30, 2015. (enzyme-HPLC method).

本発明の難消化性グルカンおよび/またはその加工処理物は、必要に応じて活性炭により脱色したものや、イオン交換樹脂によりイオン性成分を除去したものを濃縮し、濃縮液とすることができる。保存性やその後の用途においては、脱色、イオン除去したものを微生物の繁殖が問題とならない程度の水分活性となるまで濃縮することが好適である。あるいは、用途によっては、利用しやすいように乾燥させて、粉末とすることもできる。乾燥は、通常、凍結乾燥、噴霧乾燥、ドラム乾燥等の公知の方法により実施できる。乾燥物は、必要により粉砕することが望ましい。すなわち、本発明の難消化性グルカンおよび/またはその加工処理物の態様は、その用途に応じて好適な性状を選択することができる。 The indigestible glucan and/or its processed product of the present invention can be decolorized using activated carbon or removed from ionic components using an ion exchange resin, if necessary, and then concentrated to obtain a concentrated solution. In terms of storage stability and subsequent uses, it is preferable to concentrate the decolorized and ion-removed product until the water activity reaches a level where microbial growth does not become a problem. Alternatively, depending on the application, it can be dried and made into a powder for easy use. Drying can usually be carried out by known methods such as freeze drying, spray drying, drum drying, etc. It is desirable that the dried material be pulverized if necessary. That is, suitable properties of the indigestible glucan and/or the processed product of the present invention can be selected depending on the intended use.

(b)果糖
本発明において「果糖」は、フルクトースともいい、単糖類の一種である。本発明に使用する「果糖」は、果糖を含むものであれば、いずれの形態のものも使用することができ、例えば、結晶果糖、高果糖液糖(果糖90%以上)、異性化糖由来の果糖、果汁由来の果糖等が挙げられる。
(b) Fructose In the present invention, "fructose" is also referred to as fructose, and is a type of monosaccharide. The "fructose" used in the present invention can be in any form as long as it contains fructose, such as crystalline fructose, high fructose corn syrup (90% or more fructose), and high fructose derived from isomerized sugar. Examples include fructose derived from fruit juice, and fructose derived from fruit juice.

(c)ショ糖
本発明において「ショ糖」は、スクロースともいい、二糖類の一種である。本発明に使用する「ショ糖」は、ショ糖を含むものであれば、いずれの形態のものも使用することができ、例えば、グラニュー糖、液糖、上白糖、白双糖、三温糖、中双糖、氷砂糖、和三盆、黒砂糖等を使用でき、さらには、果汁由来のショ糖等も使用することができる。
(c) Sucrose In the present invention, "sucrose" is also referred to as sucrose, and is a type of disaccharide. The "sucrose" used in the present invention can be in any form as long as it contains sucrose; for example, granulated sugar, liquid sugar, white sugar, white sugar, and white sugar. , sugar sugar, rock sugar, wasanbon sugar, brown sugar, etc. can be used, and sucrose derived from fruit juice can also be used.

本発明においては、(a)難消化性グルカンおよび/またはその加工処理物、(b)果糖並びに(c)ショ糖の合計含有量(固形分換算質量)に対する、上記(a)の含有量(固形分換算質量)の比率は、果汁風味炭酸飲料に適度な果汁感およびボディ感を付与する観点から、下限値は5%(好ましくは7%)とすることができ、上限値は15%(好ましくは10%)とすることができる。これらの下限値および上限値はそれぞれ任意に組み合わせることができ、上記含有比率の範囲は、例えば、5~15%(好ましくは5~10%)とすることができる。 In the present invention, the content of (a) above relative to the total content (mass equivalent to solid content) of (a) indigestible glucan and/or its processed product, (b) fructose, and (c) sucrose is The lower limit of the ratio of solid content equivalent mass) can be set to 5% (preferably 7%), and the upper limit to 15% ( (preferably 10%). These lower and upper limits can be arbitrarily combined, and the range of the content ratio can be, for example, 5 to 15% (preferably 5 to 10%).

本発明においては、(a)難消化性グルカンおよび/またはその加工処理物、(b)果糖並びに(c)ショ糖の合計含有量(固形分換算質量)に対する、上記(b)の含有量(固形分換算質量)の比率は、果汁風味炭酸飲料に適度な果汁感およびボディ感を付与するとともに適度な甘味を付与する観点から、下限値は40%(好ましくは45%)とすることができ、上限値は80%(好ましくは70%)とすることができる。これらの下限値および上限値はそれぞれ任意に組み合わせることができ、上記含有比率の範囲は、例えば、40~80%(好ましくは45~80%)とすることができる。 In the present invention, the content of (b) above relative to the total content (solid content equivalent mass) of (a) indigestible glucan and/or processed product thereof, (b) fructose, and (c) sucrose is The lower limit of the ratio (solid content equivalent mass) can be set to 40% (preferably 45%) from the viewpoint of imparting an appropriate fruit feel and body feeling to the fruit juice-flavored carbonated beverage as well as an appropriate sweetness. , the upper limit can be 80% (preferably 70%). These lower and upper limits can be arbitrarily combined, and the range of the content ratio can be, for example, 40 to 80% (preferably 45 to 80%).

本発明においては、(a)難消化性グルカンおよび/またはその加工処理物、(b)果糖並びに(c)ショ糖の合計含有量(固形分換算質量)に対する、上記(c)の含有量(固形分換算質量)の比率は、果汁風味炭酸飲料に適度な果汁感およびボディ感を付与するとともに適度な甘味を付与する観点から、下限値は15%(好ましくは20%)とすることができ、上限値は45%(好ましくは30%)とすることができる。これらの下限値および上限値はそれぞれ任意に組み合わせることができ、上記含有比率の範囲は、例えば、15~45%とすることができる。 In the present invention, the content of (c) above relative to the total content (mass equivalent to solid content) of (a) indigestible glucan and/or its processed product, (b) fructose, and (c) sucrose ( The lower limit of the ratio (solid content equivalent mass) can be set to 15% (preferably 20%) from the viewpoint of imparting an appropriate fruit feel and body feeling to the fruit juice-flavored carbonated beverage as well as an appropriate sweetness. , the upper limit can be 45% (preferably 30%). These lower and upper limits can be arbitrarily combined, and the range of the content ratio can be, for example, 15 to 45%.

本発明において、(a)難消化性グルカンおよび/またはその加工処理物、(b)果糖並びに(c)ショ糖を果汁風味炭酸飲料に含有させるときは、炭酸飲料全体に対する上記(a)、(b)および(c)の合計量(固形分換算質量)の比率は0.5~20%(好ましくは3~12%、より好ましくは5~8%)とすることができる。 In the present invention, when (a) indigestible glucan and/or its processed product, (b) fructose, and (c) sucrose are contained in a fruit juice flavored carbonated beverage, the above (a), ( The ratio of the total amount (solid content equivalent mass) of b) and (c) can be 0.5 to 20% (preferably 3 to 12%, more preferably 5 to 8%).

飲料中の前記(a)、(b)および(c)の含有量は、例えば、高速液体クロマトグラフィー法(HPLC法)により測定することができる。 The contents of (a), (b) and (c) in the beverage can be measured, for example, by high performance liquid chromatography (HPLC).

本発明の果汁風味炭酸飲料は果汁風味を有することから、前記(a)、(b)および(c)に加えて、果汁、果肉、果汁エキス、果実エキスおよび香料からなる群から選択される1種または2種以上の果汁風味付与成分を含有していてもよい。果汁風味の対象となる果実の例としては前記したものが挙げられる。 Since the fruit juice flavored carbonated beverage of the present invention has a fruit juice flavor, in addition to the above (a), (b), and (c), one selected from the group consisting of fruit juice, fruit pulp, fruit juice extract, fruit extract, and flavoring agent is added. It may contain seeds or two or more kinds of fruit juice flavor imparting components. Examples of fruits to which fruit juice flavor is applied include those mentioned above.

本発明の果汁風味炭酸飲料に含まれる果汁含有量は特に限定されるものではないが、該飲料中の果汁含有量を40%以下(好ましくは30%以下、より好ましくは20%以下、さらに好ましくは10%以下)とすることができる。本発明の果汁風味炭酸飲料中の果汁含有量の下限値は0%とすることができる。本発明の果汁風味炭酸飲料によれば果汁炭酸飲料および無果汁炭酸飲料が提供される。 The fruit juice content contained in the fruit juice-flavored carbonated beverage of the present invention is not particularly limited, but the fruit juice content in the beverage should be 40% or less (preferably 30% or less, more preferably 20% or less, even more preferably (10% or less). The lower limit of the fruit juice content in the fruit juice flavored carbonated beverage of the present invention can be 0%. According to the fruit juice flavored carbonated beverage of the present invention, a fruit juice carbonated beverage and a non-fruit juice carbonated beverage are provided.

本発明の果汁風味炭酸飲料は液体原料を含んでいてもよい。液体原料としては、水(例えば、飲用水)、炭酸水が挙げられる。ここで「炭酸水」とは、飲用に適した水に二酸化炭素を圧入したものを意味する。液体原料として水などの非炭酸水を用いた場合には炭酸ガス添加工程により炭酸ガスを付与してもよい。また液体原料として炭酸水を用いた場合でも炭酸ガス添加工程により炭酸ガスを付与し、炭酸感がより強い飲料としてもよい。 The fruit juice flavored carbonated beverage of the present invention may contain a liquid raw material. Examples of liquid raw materials include water (for example, drinking water) and carbonated water. Here, "carbonated water" refers to water suitable for drinking with carbon dioxide injected under pressure. When non-carbonated water such as water is used as the liquid raw material, carbon dioxide gas may be added by a carbon dioxide gas addition step. Even when carbonated water is used as the liquid raw material, carbon dioxide gas may be added in the carbon dioxide gas addition step to produce a beverage with a stronger carbonated taste.

本発明の果汁風味炭酸飲料がアルコール飲料の場合、本発明の飲料はアルコール(エタノール)を含んでなるものである。本発明に使用する「アルコール」は、アルコール(エタノール)を含むものであれば、いずれの形態のものも使用することができ、例えば、原料用アルコール類および醸造用アルコール類に加えて、ウイスキー、バーボン、ブランデー、スピリッツ類(例えば、ウォッカ)、リキュール類、果実酒、日本酒、中国酒、焼酎、発泡酒、チュウハイ等のアルコール飲料が挙げられる。なお、本発明の果汁風味炭酸アルコール飲料のアルコール濃度(アルコール分の含有量)は、特に限定されないが、例えば1~10v/v%であり、好ましくは2~8v/v%(より好ましくは3~6v/v%)である。 When the fruit juice flavored carbonated beverage of the present invention is an alcoholic beverage, the beverage of the present invention contains alcohol (ethanol). The "alcohol" used in the present invention can be in any form as long as it contains alcohol (ethanol). For example, in addition to raw material alcohols and brewing alcohols, whiskey, Examples include alcoholic beverages such as bourbon, brandy, spirits (eg, vodka), liqueurs, fruit wine, Japanese sake, Chinese sake, shochu, low-malt beer, and chuhai. The alcohol concentration (alcohol content) of the fruit juice-flavored carbonated alcoholic beverage of the present invention is not particularly limited, but is, for example, 1 to 10 v/v%, preferably 2 to 8 v/v% (more preferably 3 v/v%). ~6v/v%).

本発明の果汁風味炭酸飲料はまた、果汁感およびボディ感を阻害しない範囲で、前記(a)、(b)および(c)以外の他の成分を含有することができる。他の成分の例としては、糖類、糖アルコールおよび澱粉類等;直鎖デキストリン、分岐デキストンおよび環状デキストン等のデキストリン類;甘味料、安定剤、乳化剤、ゲル化剤、着色料、着香料、苦味料、保存料、酸化防止剤およびpH調整剤等の食品添加物;油脂、乳および乳製品、有機酸、有機酸塩、無機塩、酵素、ビタミン類、酵母エキス、調味料等の呈味成分、その他各種食品素材等が挙げられる。 The fruit juice-flavored carbonated beverage of the present invention may also contain other components other than the above-mentioned (a), (b), and (c) as long as the fruit juice flavor and body texture are not impaired. Examples of other ingredients include sugars, sugar alcohols, and starches; dextrins such as linear dextrins, branched dextones, and cyclic dextones; sweeteners, stabilizers, emulsifiers, gelling agents, colorants, flavors, and bitterness. food additives such as additives, preservatives, antioxidants, and pH adjusters; flavor components such as fats and oils, milk and dairy products, organic acids, organic acid salts, inorganic salts, enzymes, vitamins, yeast extracts, seasonings, etc. , and other various food materials.

本発明によれば、果汁感やボディ感が増強された果汁風味炭酸飲料が提供される。低果汁含有量(例えば、果汁含有量が40%以下)の果汁風味炭酸飲料においてもこの効果は奏されることから、本発明によれば、無果汁または低果汁の果汁風味炭酸飲料において、高果汁炭酸飲料のような自然な甘味、コク、ボディ感といった果汁感が付与された果汁炭酸飲料を提供できる点で有利である。本発明において「果汁感」とは、果実の様な自然な甘味、コク、ボディ感からなる総合的な呈味感をいう。本発明において「ボディ感」とは、果汁感の構成要素の一つで、果実の様な厚みのある呈味感をいう。 According to the present invention, a fruit juice-flavored carbonated beverage with enhanced fruit juice taste and body taste is provided. This effect is achieved even in fruit juice-flavored carbonated drinks with low fruit juice content (for example, fruit juice content of 40% or less). It is advantageous in that it is possible to provide a fruit juice carbonated drink that has a natural sweetness, richness, and body feeling similar to a fruit juice carbonated drink. In the present invention, "juice taste" refers to the overall taste sensation consisting of natural sweetness like fruit, richness, and body. In the present invention, "body feeling" is one of the components of fruit juice feeling, and refers to a thick taste sensation similar to fruit.

本発明の難消化性グルカンおよび/またはその加工処理物は、水溶性食物繊維成分を有するものである。ここで、食物繊維の中でも水溶性食物繊維は、便通改善効果、食後血糖上昇抑制効果、食後中性脂肪の上昇抑制効果等の生理機能を有することが報告されており、特定保健用食品を含むさまざまな機能性食品が販売されている。従って、本発明の果汁風味炭酸飲料は、整腸作用、血糖上昇抑制作用、脂質代謝改善作用等の水溶性食物繊維が有する生理機能の発揮が期待される。また、水溶性食物繊維の機能である増粘効果や、脂肪代替効果、乳化効果などの飲食品の物性改善効果も期待される。 The indigestible glucan and/or its processed product of the present invention has a water-soluble dietary fiber component. Among dietary fibers, water-soluble dietary fibers have been reported to have physiological functions such as improving bowel movements, suppressing postprandial blood sugar rises, and suppressing postprandial triglyceride rises, and include foods for specified health uses. Various functional foods are on sale. Therefore, the fruit juice-flavored carbonated beverage of the present invention is expected to exhibit the physiological functions possessed by water-soluble dietary fibers, such as intestinal regulation, blood sugar rise suppressing, and lipid metabolism improving effects. It is also expected to improve the physical properties of foods and drinks, such as the thickening effect, fat substitution effect, and emulsification effect, which are the functions of water-soluble dietary fiber.

本発明の果汁風味炭酸飲料の製造は、(a)難消化性グルカンおよび/またはその加工処理物、(b)果糖並びに(c)ショ糖が所定の含有比率で飲料に含まれるようにすること以外は、飲料の製造に用いられる通常の方法に従って実施することができる。例えば、本発明の果汁風味炭酸飲料が清涼飲料の場合には、水を含む原材料を準備し、所定の含有比率となるように、前記(a)、(b)および(c)を他の原材料と混合ないし調合することにより、飲料を製造することができる。なお、前記(a)、(b)および(c)の他の原材料への添加時期や添加順序は特に限定されない。 The fruit juice-flavored carbonated beverage of the present invention is produced by making the beverage contain (a) indigestible glucan and/or its processed product, (b) fructose, and (c) sucrose in a predetermined content ratio. Other than this, it can be carried out according to the usual methods used for manufacturing beverages. For example, when the fruit juice flavored carbonated drink of the present invention is a soft drink, raw materials containing water are prepared, and the above (a), (b), and (c) are added to other raw materials so as to have a predetermined content ratio. Beverages can be produced by mixing or blending with. Note that the timing and order of addition of the above (a), (b), and (c) to other raw materials are not particularly limited.

本発明の果汁風味炭酸飲料の製造においては、上記調合工程に加えて、充填工程および殺菌工程等の工程(場合によってはさらに炭酸ガス添加工程)を経て容器詰め飲料として提供することができる。例えば、調合工程で得られた飲料あるいは調合工程後の炭酸ガス添加工程を経て得られた飲料を常法に従って殺菌し、容器に充填することができる。殺菌は容器への充填前であっても充填後であってもよい。 In the production of the fruit juice-flavored carbonated beverage of the present invention, in addition to the above-mentioned preparation process, it can be provided as a packaged beverage through processes such as a filling process and a sterilization process (in some cases, a carbon dioxide gas addition process). For example, the beverage obtained in the blending step or the beverage obtained through the carbon dioxide addition step after the blending step can be sterilized in accordance with a conventional method and then filled into containers. Sterilization may be performed before or after filling the container.

本発明によれば、果汁風味炭酸飲料の果汁感増強方法が提供される。本発明の果汁感増強方法は、本発明の果汁風味炭酸飲料およびその製造方法に関する記載に従って実施することができる。 According to the present invention, a method for enhancing the fruit juice taste of a fruit juice-flavored carbonated beverage is provided. The fruit juice taste enhancing method of the present invention can be carried out according to the description regarding the fruit juice flavored carbonated beverage of the present invention and the method for producing the same.

本発明によれば、果汁風味炭酸飲料の果汁感増強剤が提供される。本発明の果汁感増強剤は、本発明の果汁風味炭酸飲料およびその製造方法に関する記載に従って実施することができる。すなわち、本発明の果汁感増強剤を他の原材料と混合ないし調合することにより、本発明の果汁風味炭酸飲料を製造することができる。本発明の果汁感増強剤は、炭酸飲料全体に対する上記(a)、(b)および(c)の合計量(固形分換算質量)の比率が0.5~20%(好ましくは3~12%、より好ましくは5~8%)となるように原材料に配合することができる。 According to the present invention, a fruit juice taste enhancer for fruit juice-flavored carbonated drinks is provided. The fruit juice taste enhancer of the present invention can be produced according to the description regarding the fruit juice flavored carbonated beverage of the present invention and its manufacturing method. That is, the fruit juice flavor carbonated beverage of the present invention can be produced by mixing or blending the fruit juice taste enhancer of the present invention with other raw materials. In the fruit juice taste enhancer of the present invention, the ratio of the total amount (solid content equivalent mass) of the above (a), (b) and (c) to the entire carbonated beverage is 0.5 to 20% (preferably 3 to 12%). , more preferably 5 to 8%).

以下の例に基づいて本発明を具体的に説明するが、本発明はこれらの例に限定されるものではない。なお、本明細書において特に記載の無い場合は「%」は質量%を意味し、また「固形分」当たりの割合や「固形分」の含有割合(濃度)に言及した場合には、固形成分の質量に基づいて定められた割合を意味するものとする。 The present invention will be specifically explained based on the following examples, but the present invention is not limited to these examples. In addition, unless otherwise specified in this specification, "%" means mass %, and when referring to the percentage per "solid content" or the content ratio (concentration) of "solid content", it refers to the solid component. shall mean the proportion determined based on the mass of

例1:グレープフルーツ風味炭酸飲料
表1に示した配合で炭酸水に各種原料を加え、炭酸飲料を調製した。難消化性グルカンはフィットファイバー#80(日本食品化工社製、固形分濃度72質量%の液状品、食物繊維含有量78%(酵素HPLC法))を、果糖は結晶果糖(日新製糖社製、粉末品)を、ショ糖はグラニュー糖(日新製糖社製、粉末品)を、それぞれ用いた。
Example 1: Grapefruit-flavored carbonated beverage A carbonated beverage was prepared by adding various raw materials to carbonated water according to the formulation shown in Table 1. The indigestible glucan is Fit Fiber #80 (manufactured by Nihon Shokuhin Kako Co., Ltd., liquid product with a solid content concentration of 72% by mass, dietary fiber content 78% (enzyme HPLC method)), and the fructose is crystalline fructose (manufactured by Nisshin Sugar Co., Ltd.). , powder product) and granulated sugar (manufactured by Nisshin Sugar Co., Ltd., powder product) were used as the sucrose.

得られた炭酸飲料に関し、「果汁感」および「ボディ感」に関し、下記基準で官能評価を実施した。 Regarding the obtained carbonated beverage, sensory evaluation was performed on "fruit juice feel" and "body feeling" according to the following criteria.

「果汁感」とは、果実の様な自然な甘味、コク、ボディ感からなる総合的な呈味感をいう。「果汁感」に関しては、果糖のみを配合した比較区1を0点として±5点の11段階で評価した。点数が高いほど果汁感が強く、点数が低い程果汁感が弱い。 "Juice" refers to the overall taste sensation consisting of natural fruit-like sweetness, richness, and body. Regarding the "juice feel", evaluation was made on an 11-point scale of ±5 points, with Comparative Group 1 containing only fructose being 0 points. The higher the score, the stronger the fruit juice taste, and the lower the score, the weaker the fruit juice taste.

「ボディ感」とは、果汁感の構成要素の一つで、果実の様な厚みのある呈味感をいう。「ボディ感」に関しては、果糖のみを配合した比較区1を0点として±5点の11段階で評価した。点数が高いほどボディ感が強く、点数が低い程ボディ感が弱い。 "Body" is one of the components of fruit juice, and refers to a thick, fruit-like taste. Regarding the "body feel", evaluation was made on an 11-point scale of ±5 points, with Comparative Group 1 containing only fructose being 0 points. The higher the score, the stronger the sense of body, and the lower the score, the weaker the sense of body.

官能評価は4名の訓練されたパネラーで実施し、その平均点を算出した。その結果を表1に示した。 Sensory evaluation was conducted by four trained panelists, and the average score was calculated. The results are shown in Table 1.

Figure 0007409739000001
Figure 0007409739000001

表1の通り、難消化性グルカン、果糖、ショ糖を一定の割合で配合したグレープフルーツ風味炭酸飲料(試験区1~9)は、果糖のみを配合した炭酸飲料(比較区1)に比べ、果汁感およびボディ感が改善されており、特に難消化性グルカン5~10%、果糖45~80%、ショ糖15~45%とした炭酸飲料(試験区1~6)は、改善効果が顕著であった。また、ショ糖を配合せず、果糖、難消化性グルカンを配合した炭酸飲料(比較区2)は、難消化性グルカン、果糖、ショ糖を配合した炭酸飲料に比べ、果汁感、ボディ感の改善効果が弱く、好ましい炭酸飲料ではなかった。また、炭酸水を配合していない飲料(比較区3)は、炭酸水を配合した飲料(試験区4)に比べ、改善効果が低かった。 As shown in Table 1, the grapefruit-flavored carbonated drinks containing indigestible glucan, fructose, and sucrose at a certain ratio (test groups 1 to 9) had a lower fruit juice content than the carbonated drinks containing only fructose (comparison group 1). The improvement effect was particularly remarkable for carbonated drinks containing 5-10% indigestible glucan, 45-80% fructose, and 15-45% sucrose (Test Groups 1-6). there were. In addition, the carbonated drink containing fructose and indigestible glucan without sucrose (comparison group 2) had a lower fruit juice and body feel compared to the carbonated drink containing indigestible glucan, fructose, and sucrose. The improvement effect was weak and it was not a desirable carbonated drink. Furthermore, the beverage that did not contain carbonated water (comparative group 3) had a lower improvement effect than the beverage that contained carbonated water (test group 4).

例2:グレープフルーツ風味炭酸飲料
表2に示した配合で炭酸水に各種原料を加え、グレープフルーツ風味炭酸飲料を調製した。なお、難消化性グルカン還元処理物は、フィットファイバー#80(日本食品化工社製、固形分濃度72質量%の液状品、食物繊維含量78%(酵素HPLC法))を還元処理した難消化性グルカン還元処理物(固形分濃度70質量%の液状品、食物繊維含量77%(酵素HPLC法))を用いた。難消化性デキストリンは、ファイバーソルII(松谷化学工業社製、粉末品)、果糖は結晶果糖(日新製糖社製、粉末品)、ショ糖はグラニュー糖(日新製糖社製、粉末品)を用いた。
Example 2: Grapefruit-flavored carbonated beverage A grapefruit-flavored carbonated beverage was prepared by adding various raw materials to carbonated water according to the formulation shown in Table 2. The indigestible glucan reduced product is an indigestible product obtained by reducing Fit Fiber #80 (manufactured by Nihon Shokuhin Kako Co., Ltd., liquid product with solid content concentration of 72% by mass, dietary fiber content of 78% (enzyme HPLC method)). A glucan-reduced product (liquid product with solid content concentration of 70% by mass, dietary fiber content of 77% (enzyme HPLC method)) was used. Indigestible dextrin is Fibersol II (manufactured by Matsutani Chemical Industry Co., Ltd., powder product), fructose is crystalline fructose (manufactured by Nisshin Sugar Co., Ltd., powder product), and sucrose is granulated sugar (manufactured by Nisshin Sugar Co., Ltd., powder product). was used.

例1と同様に官能評価を実施し、その平均点を算出した。その結果を表2に示した。 Sensory evaluation was performed in the same manner as in Example 1, and the average score was calculated. The results are shown in Table 2.

Figure 0007409739000002
Figure 0007409739000002

表2の通り、難消化性グルカン還元処理物、果糖、ショ糖を一定の割合で配合したグレープフルーツ風味炭酸飲料(試験区10~12)は、果糖のみを配合した飲料(比較区1)に比べ、果汁感・ボディ感が改善されていた。また、難消化性デキストリンを配合した飲料(比較区4)は、ボディ感は向上したものの、果汁感が低下しており、好ましいグレープフルーツ風味炭酸飲料ではなかった。 As shown in Table 2, the grapefruit-flavored carbonated drinks containing indigestible glucan reduction products, fructose, and sucrose at a certain ratio (test groups 10 to 12) were compared to the drinks containing only fructose (comparison group 1). , the fruit juice feeling and body feeling were improved. In addition, although the drink containing indigestible dextrin (comparative group 4) had an improved body feeling, the fruit juice feeling was decreased, and it was not a desirable grapefruit-flavored carbonated drink.

例3:グレープフルーツチュウハイ
表3に示した配合で炭酸水に各種原料を加え、グレープフルーツチューハイ(アルコール濃度:4v/v%)を調製した。なお、難消化性グルカンはフィットファイバー#80(日本食品化工社製、固形分濃度72質量%の液状品、食物繊維含有量78%(酵素HPLC法))を用いた。また、果糖は結晶果糖(日新製糖社製、粉末品)、ショ糖はグラニュー糖(日新製糖社製、粉末品)を用いた。
Example 3: Grapefruit Chu- Hi Grapefruit Chu-Hi (alcohol concentration: 4v/v%) was prepared by adding various raw materials to carbonated water according to the formulation shown in Table 3. As the indigestible glucan, Fit Fiber #80 (manufactured by Nippon Shokuhin Kako Co., Ltd., liquid product with solid content concentration of 72% by mass, dietary fiber content of 78% (enzyme HPLC method)) was used. Furthermore, crystalline fructose (manufactured by Nisshin Sugar Co., Ltd., powder product) was used as the fructose, and granulated sugar (manufactured by Nisshin Sugar Co., Ltd., powder product) was used as the sucrose.

果糖のみを配合した比較区5を0点とした以外は、例1と同様に官能評価を実施し、その平均点を算出した。その結果を表3に示した。 Sensory evaluation was carried out in the same manner as in Example 1, except that comparative group 5 containing only fructose was given a score of 0, and the average score was calculated. The results are shown in Table 3.

Figure 0007409739000003
Figure 0007409739000003

表3の通り、難消化性グルカン、果糖、ショ糖を一定の割合で配合したグレープフルーツチューハイ(試験区13~15)は、果糖のみを配合した飲料(比較区5)に比べ、果汁感・ボディ感が改善されており、好ましい味のグレープフルーツチューハイであった。 As shown in Table 3, the grapefruit chu-hi containing indigestible glucan, fructose, and sucrose at a certain ratio (Test Groups 13 to 15) had a stronger fruit feel and body than the drink containing only fructose (Comparative Group 5). The grapefruit chu-hi had an improved texture and a pleasant taste.

例4:グレープフルーツ果汁炭酸飲料
表4に示した配合で炭酸水に各種原料を加え、30%果汁グレープフルーツ炭酸飲料を試作した。なお、難消化性グルカンはフィットファイバー#80(日本食品化工社製、固形分濃度72質量%の液状品、食物繊維含有量78%(酵素HPLC法))を用いた。また、果糖は結晶果糖(日新製糖社製、粉末品)、ショ糖はグラニュー糖(日新製糖社製、粉末品)を用いた。
Example 4: Carbonated grapefruit juice drink A 30% carbonated grapefruit juice drink was prepared by adding various raw materials to carbonated water according to the formulation shown in Table 4. As the indigestible glucan, Fit Fiber #80 (manufactured by Nippon Shokuhin Kako Co., Ltd., liquid product with solid content concentration of 72% by mass, dietary fiber content of 78% (enzyme HPLC method)) was used. Furthermore, crystalline fructose (manufactured by Nisshin Sugar Co., Ltd., powder product) was used as the fructose, and granulated sugar (manufactured by Nisshin Sugar Co., Ltd., powder product) was used as the sucrose.

果糖のみを配合した飲料(比較区6)を0点とした以外は、例1と同様に官能評価を実施し、その平均点を算出した。その結果を表4に示した。 Sensory evaluation was performed in the same manner as in Example 1, except that the beverage containing only fructose (comparative group 6) was given a score of 0, and the average score was calculated. The results are shown in Table 4.

Figure 0007409739000004
Figure 0007409739000004

表4の通り、難消化性グルカン、果糖、ショ糖を一定の割合で配合したグレープフルーツ果汁炭酸飲料(試験区16~18)は、果糖のみを配合した飲料(比較区6)に比べ、果汁感・ボディ感が改善されており、好ましいグレープフルーツ果汁炭酸飲料であった。 As shown in Table 4, the grapefruit juice carbonated drinks containing indigestible glucan, fructose, and sucrose at a certain ratio (test groups 16 to 18) had a more fruity taste than the drinks containing only fructose (comparison group 6). - It was a preferable grapefruit juice carbonated drink with improved body feel.

例5:グレープ風味炭酸飲料
表5に示した配合で炭酸水に各種原料を加え、グレープ風味炭酸飲料を調製した。なお、難消化性グルカンはフィットファイバー#80(日本食品化工社製、固形分濃度72質量%の液状品、食物繊維含有量78%(酵素HPLC法))を用いた。また、果糖は結晶果糖(日新製糖社製、粉末品)、ショ糖はグラニュー糖(日新製糖社製、粉末品)を用いた。
Example 5: Grape-flavored carbonated beverage A grape-flavored carbonated beverage was prepared by adding various raw materials to carbonated water according to the formulation shown in Table 5. As the indigestible glucan, Fit Fiber #80 (manufactured by Nippon Shokuhin Kako Co., Ltd., liquid product with solid content concentration of 72% by mass, dietary fiber content of 78% (enzyme HPLC method)) was used. Furthermore, crystalline fructose (manufactured by Nisshin Sugar Co., Ltd., powder product) was used as the fructose, and granulated sugar (manufactured by Nisshin Sugar Co., Ltd., powder product) was used as the sucrose.

果糖のみを配合した飲料(比較区7)を0点とした以外は、例1と同様に官能評価を実施し、その平均点を算出した。その結果を表5に示した。 Sensory evaluation was performed in the same manner as in Example 1, except that the beverage containing only fructose (comparative group 7) was given a score of 0, and the average score was calculated. The results are shown in Table 5.

Figure 0007409739000005
Figure 0007409739000005

表5の通り、難消化性グルカン、果糖、ショ糖を一定の割合で配合したグレープ風味炭酸飲料(試験区19~21)は、果糖のみを配合した飲料(比較区7)に比べ、果汁感・ボディ感が改善されており、好ましいグレープ風味炭酸飲料であった。 As shown in Table 5, the grape-flavored carbonated drinks containing indigestible glucan, fructose, and sucrose at a certain ratio (test groups 19 to 21) had a more fruity flavor than the drinks containing only fructose (comparison group 7). - It was a preferable grape-flavored carbonated drink with improved body feel.

Claims (8)

(a)難消化性グルカンおよび/またはその加工処理物、(b)果糖並びに(c)ショ糖を含んでなる果汁風味炭酸飲料であって、前記飲料中の上記(a)、(b)および(c)の合計含有量(固形分換算質量)に対する、上記(a)、(b)および(c)のそれぞれの含有量(固形分換算質量)の比率が、5~15%、40~80%および15~45%である、果汁風味炭酸飲料。 A fruit juice-flavored carbonated drink comprising (a) indigestible glucan and/or a processed product thereof, (b) fructose, and (c) sucrose, the above-mentioned (a), (b) and The ratio of each content (solid content equivalent mass) of the above (a), (b) and (c) to the total content (solid content equivalent mass) of (c) is 5 to 15%, 40 to 80%. % and 15 to 45%. 果汁含有量が40%以下である、請求項1に記載の果汁風味炭酸飲料。 The fruit juice flavored carbonated beverage according to claim 1, having a fruit juice content of 40% or less. 果汁風味炭酸飲料の製造方法であって、(a)難消化性グルカンおよび/またはその加工処理物、(b)果糖並びに(c)ショ糖を他の原材料と混合する工程を含んでなり、前記飲料中の上記(a)、(b)および(c)の合計含有量(固形分換算質量)に対する、上記(a)、(b)および(c)のそれぞれの含有量(固形分換算質量)の比率を、5~15%、40~80%および15~45%に調整することを特徴とする、果汁風味炭酸飲料の製造方法。 A method for producing a fruit juice-flavored carbonated beverage, comprising the step of mixing (a) indigestible glucan and/or a processed product thereof, (b) fructose, and (c) sucrose with other raw materials, The content of each of the above (a), (b) and (c) (solid content equivalent mass) relative to the total content (solid content equivalent mass) of the above (a), (b) and (c) in the beverage A method for producing a fruit juice-flavored carbonated beverage, the method comprising adjusting the ratio of 5 to 15%, 40 to 80%, and 15 to 45%. 果汁風味炭酸飲料の果汁含有量が40%以下である、請求項3に記載の果汁風味炭酸飲料の製造方法。 The method for producing a fruit juice-flavored carbonated beverage according to claim 3, wherein the fruit juice-flavored carbonated beverage has a fruit juice content of 40% or less. 果汁風味炭酸飲料の果汁感増強方法であって、(a)難消化性グルカンおよび/またはその加工処理物、(b)果糖並びに(c)ショ糖を他の原材料と混合する工程を含んでなり、前記飲料中の上記(a)、(b)および(c)の合計含有量(固形分換算質量)に対する、上記(a)、(b)および(c)のそれぞれの含有量(固形分換算質量)の比率を、5~15%、40~80%および15~45%に調整することを特徴とする、果汁感増強方法。 A method for enhancing the fruit juice sensation of a fruit-flavored carbonated beverage, the method comprising the step of mixing (a) indigestible glucan and/or a processed product thereof, (b) fructose, and (c) sucrose with other raw materials. , the content of each of the above (a), (b) and (c) (in terms of solid content) relative to the total content (in terms of solid content) of (a), (b) and (c) in the beverage A method for enhancing fruit juice sensation, which comprises adjusting the ratio of (mass) to 5 to 15%, 40 to 80%, and 15 to 45%. 果汁風味炭酸飲料の果汁含有量が40%以下である、請求項5に記載の果汁感増強方法。 The method for enhancing fruit juice taste according to claim 5, wherein the fruit juice flavored carbonated beverage has a fruit juice content of 40% or less. (a)難消化性グルカンおよび/またはその加工処理物、(b)果糖並びに(c)ショ糖を含んでなる果汁風味炭酸飲料の果汁感増強剤であって、前記増強剤中の上記(a)、(b)および(c)の合計含有量(固形分換算質量)に対する、上記(a)、(b)および(c)のそれぞれの含有量(固形分換算質量)の比率が、5~15%、40~80%および15~45%である、果汁感増強剤。 A fruit juice taste enhancer for a fruit juice-flavored carbonated beverage comprising (a) an indigestible glucan and/or a processed product thereof, (b) fructose, and (c) sucrose, the above-mentioned (a) in the enhancer. ), (b) and (c), the ratio of each content (solid content equivalent mass) of the above (a), (b) and (c) to the total content (solid content equivalent mass) is 5 to 15%, 40-80% and 15-45%. 果汁風味炭酸飲料の果汁含有量が40%以下である、請求項7に記載の果汁感増強剤。 The fruit juice taste enhancer according to claim 7, wherein the fruit juice flavor enhancer has a fruit juice content of 40% or less.
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