JP7396422B2 - Oil-in-water emulsions containing plant-based milks - Google Patents
Oil-in-water emulsions containing plant-based milks Download PDFInfo
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- JP7396422B2 JP7396422B2 JP2022155053A JP2022155053A JP7396422B2 JP 7396422 B2 JP7396422 B2 JP 7396422B2 JP 2022155053 A JP2022155053 A JP 2022155053A JP 2022155053 A JP2022155053 A JP 2022155053A JP 7396422 B2 JP7396422 B2 JP 7396422B2
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- oil
- water emulsion
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- milk
- fat
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Description
本発明は、植物ベース乳を含む水中油型乳化物に関するものである。 The present invention relates to oil-in-water emulsions containing plant-based milks.
近年の健康志向やSDGsへの関心の高まりから、環境負荷が少ないと言われる植物性成分を含む製品が注目されている。特に、乳原料が不使用の製品、例えば大豆やアーモンドなどから製造される植物ミルクは摂取機会が増え、広がりを見せている。 In recent years, with increasing health consciousness and interest in SDGs, products containing plant-based ingredients that are said to have a low environmental impact are attracting attention. In particular, products that do not use dairy ingredients, such as plant milks made from soybeans and almonds, are being consumed more frequently and are becoming more popular.
このような植物を使用した飲食品などは、その植物由来の豊かな風味が感じられる一方で、例えば、大豆でいう青臭さなど、原料としている植物由来の異風味もあり、商品化では問題となることが多い。 Foods and beverages made from these plants have a rich flavor derived from the plant, but they also have strange flavors derived from the plants they are used as raw materials, such as the grassy smell of soybeans, which can be a problem when commercialized. It often happens.
植物由来の異風味を改善する方法は種々提案されている。例えば、豆乳由来の青臭さ、豆臭さを改善する方法として、減脂大豆蛋白素材を含み、植物ステロールとしてカンペステロール及びスチグマステロールを含む、大豆特有の青臭味等が少ない乳代替飲食品(特許文献1)や、豆乳にココナッツミルクを配合して加熱処理した、飲食後の大豆特有の不快味が抑制された豆乳含有液状飲食品(特許文献2)などが提供されている。 Various methods have been proposed to improve plant-derived off-flavors. For example, as a method to improve the grassy odor and bean odor derived from soy milk, milk substitute drinks and drinks that contain reduced-fat soy protein materials, campesterol and stigmasterol as plant sterols, and have less grassy taste peculiar to soybeans. (Patent Document 1), and soymilk-containing liquid food/beverage products in which soybean milk is blended with coconut milk and heat-treated to suppress the unpleasant taste peculiar to soybeans after eating and drinking (Patent Document 2).
また、アーモンドを使用した飲食品では、アーモンド粉砕品を用いた、香味に優れた飲料、食品及び調味料(特許文献3)、堅果類であるアーモンドペーストを含有する起泡性水中油型乳化物、(特許文献4)、アーモンドミルクを用いた油中水型乳化油脂組成物(特許文献5)などが開示されている。 In addition, food and drink products using almonds include beverages, foods, and seasonings with excellent flavor using ground almond products (Patent Document 3), and foamable oil-in-water emulsions containing almond paste, which is a nut. , (Patent Document 4), a water-in-oil type emulsified oil and fat composition using almond milk (Patent Document 5), and the like are disclosed.
特許文献1では、植物ステロールを配合することで一定の大豆由来の異風味の低減は見られるものの、他の植物由来の乳に対して同様の効果が得られるかは不明である。特許文献2は豆乳由来の異風味を抑制できるものの、ココナッツミルクの配合量次第ではココナッツミルクの風味が豆乳の良い風味よりも勝る懸念もあり、風味のバランスが崩れる場合がある。
また、特許文献3では特定の粒径のアーモンドペーストが香味良好である記載はあるものの、水中油型乳化物への配合や製造方法、異風味についての開示がない。特許文献4でもホイップ性の良好なアーモンドペースト含有クリームが得られているが、風味、特にアーモンド由来の異風味についての検討はなされていない。特許文献5ではコクの付与は記載されているが、この出願もアーモンドミルク由来の異風味については不明である。
In Patent Document 1, although a certain degree of soybean-derived off-flavor is reduced by incorporating plant sterols, it is unclear whether similar effects can be obtained for milks derived from other plants. Although Patent Document 2 can suppress the unusual flavor derived from soy milk, depending on the amount of coconut milk blended, there is a concern that the flavor of coconut milk may outweigh the good flavor of soy milk, and the balance of flavor may be disrupted.
Further, although Patent Document 3 describes that almond paste with a specific particle size has a good flavor, there is no disclosure about blending it into an oil-in-water emulsion, a manufacturing method, or an unusual flavor. Patent Document 4 also provides an almond paste-containing cream with good whippability, but no study has been made on the flavor, especially the off-flavor derived from almonds. Patent Document 5 describes the provision of richness, but this application is also unclear about the unusual flavor derived from almond milk.
斯かる実情に鑑み、豆乳以外にも、風味が良好とされる植物由来の乳であっても、わずかながらその植物由来の穀物臭さ、異風味があるという新たな課題があることを発明者らは見出し、本発明は、植物本来の美味しい風味を損なわずに、植物由来の異風味を抑制することを課題とした。 In view of this fact, the inventors discovered that in addition to soy milk, there is a new problem in that even plant-based milks that are said to have good flavor have a slight grain odor and strange flavor derived from the plant. discovered that the present invention aims to suppress plant-derived off-flavors without impairing the inherent delicious flavor of plants.
本発明者らが上記課題を解決すべく鋭意研究を行ったところ、様々な植物由来の乳を含む水中油型乳化物において、特定の脂肪酸組成を有するランダムエステル交換油脂の配合が、植物乳由来の異風味を抑制することを見出し、本発明を完成させた。 The present inventors conducted intensive research to solve the above problems, and found that in oil-in-water emulsions containing milk derived from various plants, the combination of random transesterified fats and oils having a specific fatty acid composition The present invention has been completed based on the discovery that the off-flavor of the food can be suppressed.
すなわち、本発明は、
(1)下記(A)及び(B)を満たす、ランダムエステル交換油脂、ならびに植物ベース乳を含む、水中油型乳化物、
(A)構成脂肪酸組成中、炭素数6~10の飽和脂肪酸の含有量が0.3~40重量%
(B)構成脂肪酸組成中、炭素数12~14の飽和脂肪酸の含有量が40~80重量%
(2)該ランダムエステル交換油脂が(A)、(B)、及び(C)を満たす、(1)に記載の水中油型乳化物、
(C)構成脂肪酸組成中、オレイン酸含量が10重量%以下
(3)該ランダムエステル交換油脂が(A)、(B)、及び(D)を満たす、(1)に記載の水中油型乳化物、
(D)(炭素数12~14の飽和脂肪酸の含有量)/(炭素数6~10の飽和脂肪酸の含有量)の比が1.0~6.0
(4)該ランダムエステル交換油脂が(A)、(B)、(C)、及び(D)を満たす、(2)に記載の水中油型乳化物、
(D)(炭素数12~14の飽和脂肪酸の含有量)/(炭素数6~10の飽和脂肪酸の含有量)の比が1.0~6.0
(5)上記(A)が1~35重量%である、(1)又は(2)に記載の水中油型乳化物、
(6)上記(A)が1~35重量%である、(3)又は(4)に記載の水中油型乳化物、
(7)該ランダムエステル交換油脂の含有量が、水中油型乳化物の油脂含量(油分)中に0.05重量%以上である、(5)に記載の水中油型乳化物、
(8)該ランダムエステル交換油脂の含有量が、水中油型乳化物の油脂含量(油分)中に0.05重量%以上である、(6)に記載の水中油型乳化物、
(9)該植物ベース乳の由来が、アーモンド、オーツ麦、大豆から選ばれる1つ以上である、(5)に記載の水中油型乳化物、
(10)該植物ベース乳の由来が、アーモンド、オーツ麦、大豆から選ばれる1つ以上である、(6)に記載の水中油型乳化物、
(11)下記(A)及び(B)を満たす、ランダムエステル交換油脂を水中油型乳化物の油脂含量(油分)中に0.05重量%以上、ならびに植物ベース乳を混合して乳化させる、水中油型乳化物の製造方法、
(A)構成脂肪酸組成中、炭素数6~10の飽和脂肪酸の含有量が0.3~40重量%
(B)構成脂肪酸組成中、炭素数12~14の飽和脂肪酸の含有量が40~80重量%
(12)下記(A)及び(B)を満たす、ランダムエステル交換油脂、ならびに植物ベース乳を含む水中油型乳化物における、異風味を抑制させる方法、
(A)構成脂肪酸組成中、炭素数6~10の飽和脂肪酸の含有量が0.3~40重量%
(B)構成脂肪酸組成中、炭素数12~14の飽和脂肪酸の含有量が40~80重量%
に関するものである。
また、換言すれば、
(21)下記(A)及び(B)を満たす、ランダムエステル交換油脂、ならびに植物ベース乳を含む、水中油型乳化物、
(A)構成脂肪酸組成中、炭素数6~10の飽和脂肪酸の含有量が0.3~30重量%
(B)構成脂肪酸組成中、炭素数12~14の飽和脂肪酸の含有量が45~80重量%
(22)該ランダムエステル交換油脂の含有量が、水中油型乳化物の油脂含量(油分)中に0.05~60重量%である、(21)に記載の水中油型乳化物、
(23)該ランダムエステル交換油脂がさらに下記(C)を満たす、(21)又は(22)に記載の水中油型乳化物、
(C)構成脂肪酸組成中、オレイン酸含量が10重量%以下
(24)該植物ベース乳の由来が、アーモンド、オーツ麦、大豆から選ばれる1つ以上である、(21)から(23)のいずれか1項に記載の水中油型乳化物、
(25)(21)から(24)のいずれか1項に記載の水中油型乳化物の製造方法、
(26)該ランダムエステル交換油脂、ならびに該植物ベース乳を含むことを特徴とする、(21)から(24)のいずれか1項に記載の水中油型乳化物における、異風味を抑制させる方法、
に関するものである。
That is, the present invention
(1) An oil-in-water emulsion containing a random transesterified fat and a plant-based milk that satisfies (A) and (B) below,
(A) In the constituent fatty acid composition, the content of saturated fatty acids having 6 to 10 carbon atoms is 0.3 to 40% by weight.
(B) In the constituent fatty acid composition, the content of saturated fatty acids having 12 to 14 carbon atoms is 40 to 80% by weight.
(2) the oil-in-water emulsion according to (1), wherein the random transesterified oil satisfies (A), (B), and (C);
(C) The oil-in-water emulsion according to (1), wherein the oleic acid content is 10% by weight or less in the constituent fatty acid composition. (3) The random transesterified fat satisfies (A), (B), and (D). thing,
(D) The ratio of (content of saturated fatty acids with 12 to 14 carbon atoms)/(content of saturated fatty acids with 6 to 10 carbon atoms) is 1.0 to 6.0
(4) The oil-in-water emulsion according to (2), wherein the random transesterified oil satisfies (A), (B), (C), and (D);
(D) The ratio of (content of saturated fatty acids with 12 to 14 carbon atoms)/(content of saturated fatty acids with 6 to 10 carbon atoms) is 1.0 to 6.0
(5) The oil-in-water emulsion according to (1) or (2), wherein the above (A) is 1 to 35% by weight;
(6) The oil-in-water emulsion according to (3) or (4), wherein the above (A) is 1 to 35% by weight;
(7) The oil-in-water emulsion according to (5), wherein the content of the random transesterified fat is 0.05% by weight or more in the fat content (oil content) of the oil-in-water emulsion.
(8) The oil-in-water emulsion according to (6), wherein the content of the random transesterified fat is 0.05% by weight or more in the fat content (oil content) of the oil-in-water emulsion.
(9) The oil-in-water emulsion according to (5), wherein the plant-based milk is derived from one or more selected from almonds, oats, and soybeans.
(10) The oil-in-water emulsion according to (6), wherein the plant-based milk is derived from one or more selected from almonds, oats, and soybeans;
(11) Emulsifying a random transesterified fat that satisfies the following (A) and (B) by mixing 0.05% by weight or more in the fat content (oil content) of an oil-in-water emulsion and plant-based milk. A method for producing an oil-in-water emulsion,
(A) In the constituent fatty acid composition, the content of saturated fatty acids having 6 to 10 carbon atoms is 0.3 to 40% by weight.
(B) In the constituent fatty acid composition, the content of saturated fatty acids having 12 to 14 carbon atoms is 40 to 80% by weight.
(12) A method for suppressing off-flavors in an oil-in-water emulsion containing a random transesterified fat and a plant-based milk that satisfies the following (A) and (B),
(A) In the constituent fatty acid composition, the content of saturated fatty acids having 6 to 10 carbon atoms is 0.3 to 40% by weight.
(B) In the constituent fatty acid composition, the content of saturated fatty acids having 12 to 14 carbon atoms is 40 to 80% by weight.
It is related to.
In other words,
(21) An oil-in-water emulsion containing a random transesterified fat and a plant-based milk that satisfies the following (A) and (B),
(A) In the constituent fatty acid composition, the content of saturated fatty acids having 6 to 10 carbon atoms is 0.3 to 30% by weight.
(B) In the constituent fatty acid composition, the content of saturated fatty acids having 12 to 14 carbon atoms is 45 to 80% by weight.
(22) The oil-in-water emulsion according to (21), wherein the content of the random transesterified fat is 0.05 to 60% by weight in the fat content (oil content) of the oil-in-water emulsion.
(23) The oil-in-water emulsion according to (21) or (22), wherein the random transesterified fat further satisfies the following (C):
(C) The oleic acid content in the constituent fatty acid composition is 10% by weight or less. (24) The origin of the plant-based milk is one or more selected from almonds, oats, and soybeans, (21) to (23). The oil-in-water emulsion according to any one of the above,
(25) A method for producing an oil-in-water emulsion according to any one of (21) to (24),
(26) A method for suppressing off-flavor in the oil-in-water emulsion according to any one of (21) to (24), which is characterized by containing the random transesterified oil and fat and the plant-based milk. ,
It is related to.
本発明によれば、植物ベース乳由来の異風味が抑制された水中油型乳化物を提供することができる。しかも、この植物ベース乳由来の異風味の抑制効果は、特定の脂肪酸組成に調整したランダムエステル交換油脂を少量配合することで十分に発揮することができる。
また、本発明によれば、植物ベース乳由来の異風味を抑制しつつ、植物ベース乳の持つ豊かな風味が維持されており、全体的にバランスの取れた風味の水中油型乳化物を提供することができる。
According to the present invention, it is possible to provide an oil-in-water emulsion in which off-flavors derived from plant-based milk are suppressed. Moreover, the effect of suppressing off-flavors derived from this plant-based milk can be sufficiently exerted by blending a small amount of random transesterified oil and fat adjusted to a specific fatty acid composition.
Furthermore, according to the present invention, the rich flavor of plant-based milk is maintained while suppressing the off-flavors derived from plant-based milk, thereby providing an oil-in-water emulsion with an overall well-balanced flavor. can do.
以下、本発明を具体的に説明する。 The present invention will be explained in detail below.
(ランダムエステル交換油脂)
本発明のランダムエステル交換油脂は、下記(A)及び(B)を満たす、ランダムエステル交換油脂である。
(A)構成脂肪酸組成中、炭素数6~10の飽和脂肪酸の含有量が0.3~40重量%
(B)構成脂肪酸組成中、炭素数12~14の飽和脂肪酸の含有量が40~80重量%
なお、構成脂肪酸の測定方法は、AOCS Official Method Ce 1h-05の方法に準拠する。
(Random transesterified fat)
The random transesterified fat and oil of the present invention is a random transesterified fat and oil that satisfies the following (A) and (B).
(A) In the constituent fatty acid composition, the content of saturated fatty acids having 6 to 10 carbon atoms is 0.3 to 40% by weight.
(B) In the constituent fatty acid composition, the content of saturated fatty acids having 12 to 14 carbon atoms is 40 to 80% by weight.
Note that the method for measuring the constituent fatty acids is based on the method of AOCS Official Method Ce 1h-05.
本発明のランダムエステル交換油脂は、好ましくは(A)構成脂肪酸組成中、炭素数6~10の飽和脂肪酸の含有量が1~35重量%、より好ましくは3~35重量%、さらに好ましくは5~25重量%、さらにより好ましくは5~20重量%である。 The random transesterified oil and fat of the present invention preferably has a content of saturated fatty acids having 6 to 10 carbon atoms in the (A) constituent fatty acid composition of 1 to 35% by weight, more preferably 3 to 35% by weight, and still more preferably 5% by weight. -25% by weight, even more preferably 5-20% by weight.
本発明のランダムエステル交換油脂は、好ましくは(B)構成脂肪酸組成中、炭素数12~14の飽和脂肪酸の含有量が50~80重量%、より好ましくは60~75重量%である。 In the random transesterified oil and fat of the present invention, the content of saturated fatty acids having 12 to 14 carbon atoms in the constituent fatty acid composition (B) is preferably 50 to 80% by weight, more preferably 60 to 75% by weight.
本発明のランダムエステル交換油脂は、好ましくは(C)構成脂肪酸組成中、オレイン酸の含有量が10重量%以下、より好ましくは9重量%以下、さらに好ましくは8重量%以下、さらにより好ましくは6重量%以下である。 The random transesterified oil and fat of the present invention preferably has an oleic acid content of 10% by weight or less, more preferably 9% by weight or less, still more preferably 8% by weight or less, even more preferably, in the constituent fatty acid composition (C). It is 6% by weight or less.
本発明のランダムエステル交換油脂は、好ましくは(D)(炭素数12~14の飽和脂肪酸の含有量)/(炭素数6~10の飽和脂肪酸の含有量)の比が1.0~6.0、より好ましくは1.0~5.0、さらに好ましくは1.3~4.5、さらにより好ましくは1.5~4.0である。 The random transesterified oil and fat of the present invention preferably has a ratio of (D) (content of saturated fatty acids having 12 to 14 carbon atoms)/(content of saturated fatty acids having 6 to 10 carbon atoms) of 1.0 to 6. 0, more preferably 1.0 to 5.0, still more preferably 1.3 to 4.5, even more preferably 1.5 to 4.0.
本発明のランダムエステル交換油脂の原材料としては、前記構成を満たせば、種々の油脂類の配合量で調製して使用することができる。使用することができる油脂類としては、大豆油、菜種油、コーン油、綿実油、落花生油、ヒマワリ油、米油、べにばな油、サフラワー油、オリーブ油、ゴマ油、パーム油、ヤシ油、パーム核油、中鎖脂肪酸結合油脂(MCT)、シア脂、サル脂等の植物油脂及び牛脂、豚脂、乳脂等の動物脂、藻類油、微生物発酵由来の油脂、並びにこれらを分別、水素添加、エステル交換等を施した加工油脂、さらにこれらの混合油脂等が例示できる。 As a raw material for the random transesterified fat and oil of the present invention, various blending amounts of fats and oils can be prepared and used as long as the above-mentioned conditions are satisfied. Oils and fats that can be used include soybean oil, rapeseed oil, corn oil, cottonseed oil, peanut oil, sunflower oil, rice oil, safflower oil, safflower oil, olive oil, sesame oil, palm oil, coconut oil, and palm oil. Vegetable oils and fats such as kernel oil, medium-chain fatty acid-bound fats and oils (MCT), shea fat, and monkey fat; animal fats such as beef tallow, pork fat, and milk fat; algae oil; and fats and oils derived from microbial fermentation, as well as their fractionation, hydrogenation, Examples include processed oils and fats subjected to transesterification, and mixtures thereof.
本発明のランダムエステル交換油脂の原材料として、好ましくはヤシ油、パーム核油、MCT、乳脂並びにこれらを分別、水素添加、エステル交換等を施した加工油脂、さらにこれらの混合油脂等が例示できる。
本発明のランダムエステル交換油脂の特徴としては、原料油脂に非ラウリン系油脂を必須成分として含有する必要がない。本発明の効果を阻害しない範囲内で、非ラウリン系油脂を使用しても良いが、より望ましい態様としては、原料油脂に非ラウリン系油脂を使用しないことが好ましい。
また、動物性原料を含有しない植物ベースの水中油型乳化物を得る場合、ランダムエステル交換油脂の原材料は植物性油脂が好ましい。
Preferred raw materials for the random transesterified fats and oils of the present invention include coconut oil, palm kernel oil, MCT, milk fat, processed fats and oils obtained by fractionating, hydrogenating, and transesterifying these oils, and mixtures of these fats and oils.
As a feature of the random transesterified fat of the present invention, there is no need for the raw material fat to contain a non-lauric fat as an essential component. Non-lauric fats and oils may be used within a range that does not impede the effects of the present invention, but in a more desirable embodiment, it is preferable not to use non-lauric fats and oils as the raw material fat.
Further, when obtaining a plant-based oil-in-water emulsion containing no animal raw materials, the raw material for the random transesterified fat is preferably a vegetable fat.
本発明のランダムエステル交換油脂の原材料に、ラウリン酸を含む油脂を必須成分として使用するのが好ましい。その際、好ましくは該ラウリン酸を含む油脂のヨウ素価(IV)が10以下、より好ましくは5以下、さらに好ましくは1以下のラウリン酸を含む油脂を使用することが好ましい。 It is preferable to use an oil or fat containing lauric acid as an essential component as a raw material for the random transesterified oil or fat of the present invention. At that time, it is preferable to use an oil or fat containing lauric acid whose iodine value (IV) is preferably 10 or less, more preferably 5 or less, and still more preferably 1 or less.
本発明のランダムエステル交換油脂の含有量は、前記植物ベース乳を含む、水中油型乳化物の油脂含量(油分)中に0.05~60重量%が好ましい。より好ましくは0.1~58重量%、さらに好ましくは1.0~55重量%、さらにより好ましくは2.0~10重量%である。前記ランダムエステル交換油脂がこの範囲にあることで、水中油型乳化物の乳化性等に影響することなく、植物ベース乳由来の異風味を抑制することができる。 The content of the random transesterified fat of the present invention is preferably 0.05 to 60% by weight in the fat content (oil content) of the oil-in-water emulsion containing the plant-based milk. More preferably 0.1 to 58% by weight, still more preferably 1.0 to 55% by weight, even more preferably 2.0 to 10% by weight. When the random transesterified oil and fat is within this range, off-flavors derived from plant-based milk can be suppressed without affecting the emulsifying properties of the oil-in-water emulsion.
(植物ベース乳)
本発明は、植物ベース乳を含む水中油型乳化物であるが、係る植物ベース乳とは、植物性原料を基本原料として得られたもの(乳濁状の液体)を指す。原材料となる植物の種類は限定されず、例えば、アーモンド、ヘーゼルナッツ等の種子類、大豆、エンドウ豆、ヘンプ、ルピン豆、空豆、ひよこ豆等の豆類、コメ、オーツ麦などの穀類、キヌア、ココナッツ、亜麻仁等が挙げられ、中でもアーモンド、オーツ麦、大豆が好適である。これらを適当な割合で混合して使用することもできる。
また、植物ベース乳の製造方法は特に限定されず、例えば、原材料の粉砕、浸水/溶解、混合/攪拌、ろ過、均質化、殺菌等の工程によって得られるものが挙げられる。原材料の粉砕したペースト状のもの、原材料を粉末化したものを水等に溶かして得られる液体、原料由来の不溶性画分を含むものも、植物ベース乳として使用することができる。また、植物ベース乳として、原料メーカーが提供する、あるいは市販の植物ベース乳を購入し、本発明に用いても良い。また、他の例示として、大豆粉を水に溶かして得られる大豆乳も使用できる。
水中油型乳化物中、植物ベース乳は0.1重量%以上が好ましい。より好ましくは1~95重量%、さらに好ましくは5~90重量%、さらにより好ましくは5~85重量%である。
(Plant-based milk)
The present invention is an oil-in-water emulsion containing a plant-based milk, and the plant-based milk refers to an emulsion (an emulsion-like liquid) obtained using a plant-based raw material as a basic raw material. The types of plants used as raw materials are not limited, and include seeds such as almonds and hazelnuts, legumes such as soybeans, peas, hemp, lupine beans, fava beans, and chickpeas, grains such as rice and oats, quinoa, and coconuts. , flaxseed, etc., among which almonds, oats, and soybeans are preferred. These can also be used by mixing them in an appropriate ratio.
Furthermore, the method for producing plant-based milk is not particularly limited, and examples thereof include those obtained by pulverizing raw materials, submerging/dissolving, mixing/stirring, filtration, homogenization, sterilization, and other steps. Paste-like products obtained by pulverizing raw materials, liquids obtained by dissolving powdered raw materials in water, etc., and products containing insoluble fractions derived from raw materials can also be used as plant-based milks. Furthermore, as the plant-based milk, plant-based milk provided by a raw material manufacturer or commercially available may be purchased and used in the present invention. Further, as another example, soybean milk obtained by dissolving soybean flour in water can also be used.
The amount of plant-based milk in the oil-in-water emulsion is preferably 0.1% by weight or more. More preferably 1 to 95% by weight, still more preferably 5 to 90% by weight, even more preferably 5 to 85% by weight.
好ましい態様としては、前記植物ベース乳は、わずかながら豆臭さ・穀物臭さのような異風味が存在する。本発明の前記ランダムエステル交換油脂を植物ベース乳と共に水中油型乳化物に配合することで、簡便に、その植物ベース乳由来の異風味が抑制される。例えば、アーモンドミルクには苦みを伴う穀物臭さ、オーツミルクには草っぽい穀物臭が、それぞれ感じられるが、前記ランダムエステル交換油脂を一定量配合するだけで、これら異風味が顕著に抑制され、また、豊かな風味に繋がる、喫食直後に感じる各植物ベース乳由来のフレーバーリリースと後半に感じる濃厚感の発現が良く、全体の風味が良好な乳化物が得られる。また、豆乳には青臭さや豆臭さがあるが、豆乳を含む水中油型乳化物に対しても、前記ランダムエステル交換油脂を配合するという平易な方法で、異風味が抑制され、豆乳の濃厚感も損なわず、乳化物全体の風味もかなり良い。 In a preferred embodiment, the plant-based milk has a slight off-flavor such as a soy or grain smell. By blending the random transesterified oil and fat of the present invention into an oil-in-water emulsion together with a plant-based milk, off-flavors derived from the plant-based milk can be easily suppressed. For example, almond milk has a bitter grain smell, and oat milk has a grassy grain smell, but by simply adding a certain amount of the random transesterified oil, these off-flavors can be significantly suppressed. In addition, an emulsion with a good overall flavor can be obtained, with good flavor release from each plant-based milk that is felt immediately after consumption and a rich feeling felt in the latter half, which leads to a rich flavor. In addition, soy milk has a grassy and soy odor, but by adding the random transesterified oil to an oil-in-water emulsion containing soy milk, the off-flavor can be suppressed and the richness of soy milk can be improved. The flavor is not impaired, and the flavor of the emulsion as a whole is quite good.
(水中油型乳化物)
本発明の水中油型乳化物は、前記ランダムエステル交換油脂を含むが、ランダムエステル交換油脂の含有により、植物ベース乳を含む水中油型乳化物の植物ベース乳由来の異風味を抑制することができ、植物ベース乳の持つフレーバーリリースと濃厚さを維持した水中油型乳化物である。
(oil-in-water emulsion)
The oil-in-water emulsion of the present invention contains the random transesterified fat, and by containing the random transesterified fat, it is possible to suppress the off-flavor derived from the plant-based milk in the oil-in-water emulsion containing the plant-based milk. It is an oil-in-water emulsion that maintains the flavor release and richness of plant-based milk.
本発明の水中油型乳化物は、前記植物ベース乳と前記ランダムエステル交換油脂とを含むが、前記ランダムエステル交換油脂のみである必要はなく、前記ランダムエステル交換油脂を少なくとも水中油型乳化物の油脂含量(油分)中に0.05重量%以上含まれていれば、別途植物油脂を含んでも良い。また、前記ランダムエステル交換油脂のみの態様でも良い。より好ましくは0.05~60重量%、さらに好ましくは0.1~58重量%、さらにより好ましくは1.0~55重量%、最も好ましくは2.0~10重量%である。植物油脂は、特に限定されず、例えば、ヤシ油、パーム油、パーム核油、菜種油、ヒマワリ油等が挙げられる。より好ましくは、ヤシ油、パーム油並びにこれらの分別油や硬化油が良く、特に植物ベース乳の持つフレーバーリリースと濃厚感の発現が良く、水中油型乳化物全体の風味が良くなる。また、本発明の水中油型乳化物は、動物性原料、植物性原料、及び微生物発酵由来の動物性原料や植物性原料から選ばれる原料を1種以上含んでも良いが、動物性原料を含有しない植物ベースの水中油型乳化物を得る場合、植物性原料が好ましい。 The oil-in-water emulsion of the present invention includes the plant-based milk and the random transesterified fat, but it does not have to be only the random transesterified fat; Vegetable oil may be separately included as long as it is contained in the oil content (oil) in an amount of 0.05% by weight or more. Further, an embodiment in which only the random transesterified oil or fat is used may be used. More preferably 0.05 to 60% by weight, still more preferably 0.1 to 58% by weight, even more preferably 1.0 to 55% by weight, most preferably 2.0 to 10% by weight. The vegetable oil is not particularly limited, and examples thereof include coconut oil, palm oil, palm kernel oil, rapeseed oil, and sunflower oil. More preferably, coconut oil, palm oil, and their fractionated oils and hydrogenated oils are good, and in particular, the flavor release and richness of plant-based milk are good, and the overall flavor of the oil-in-water emulsion is good. Further, the oil-in-water emulsion of the present invention may contain one or more raw materials selected from animal raw materials, vegetable raw materials, and animal raw materials and vegetable raw materials derived from microbial fermentation, but does not contain animal raw materials. Vegetable raw materials are preferred when obtaining plant-based oil-in-water emulsions that do not contain any oil.
本発明の水中油型乳化物における油脂含量(油分)は、特に限定されず、例えば、植物ベース乳に由来する油分との合計で0.01~65重量%である。より好ましくは、0.05~60重量%である。水中油型乳化物の油分がこの範囲にあると、安定した乳化物が得られる。 The oil content (oil content) in the oil-in-water emulsion of the present invention is not particularly limited, and is, for example, 0.01 to 65% by weight in total including the oil content derived from plant-based milk. More preferably, it is 0.05 to 60% by weight. When the oil content of the oil-in-water emulsion is within this range, a stable emulsion can be obtained.
本発明の水中油型乳化物は、必要に応じて副原料を配合することができる。例えば、乳原料(生乳、生乳、脱脂濃縮乳、脱脂粉乳、生クリーム、バター等)や、糖質甘味料(砂糖、水あめ、果糖、ぶどう糖、糖アルコール、トレハロース等)や、安定剤(グアーガム、ローカストビーンガム、キサンタンガム、アラビアガム、カラギナン、アルギン酸ナトリウム、CMC、水溶性セルロース、ゼラチン、ペクチン等)や、澱粉(イネ・小麦・米等の穀類由来の澱粉や、トウモロコシ由来の澱粉や、馬鈴薯・タピオカ等のいも類由来の澱粉等、もしくはこれらの加工澱粉や化工澱粉等)や、乳化剤(レシチン、ショ糖脂肪酸エステル、プロピレングリコール脂肪酸エステル、ソルビタン脂肪酸エステル、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、有機酸モノグリセリド等)や、食塩や、着香料や、着色料や、酸味料や、風味原料(コーヒー、ココア、茶類、チョコレート原料、果汁、果肉、種実類、蜂蜜、メープルシロップ、酒類等)や、各種栄養素(蛋白質や、アミノ酸や、ポリデキストロース、イヌリン、難消化性デキストリンなどの食物繊維や、ビタミン類や、ミネラル類等)等が挙げられる。
また、本発明の水中油型乳化物の形態は、特に限定されず、例えば、飲料、ホイップクリーム、フィリング、ホワイトナー等に使用することができる。
The oil-in-water emulsion of the present invention may contain auxiliary raw materials as required. For example, dairy ingredients (raw milk, raw milk, skim concentrated milk, skim milk powder, fresh cream, butter, etc.), carbohydrate sweeteners (sugar, starch syrup, fructose, glucose, sugar alcohol, trehalose, etc.), stabilizers (guar gum, locust bean gum, xanthan gum, gum arabic, carrageenan, sodium alginate, CMC, water-soluble cellulose, gelatin, pectin, etc.), starch (starch derived from grains such as rice, wheat, rice, starch derived from corn, starch derived from potato, Starches derived from potatoes such as tapioca, or processed starches or modified starches, etc.), emulsifiers (lecithin, sucrose fatty acid esters, propylene glycol fatty acid esters, sorbitan fatty acid esters, glycerin fatty acid esters, polyglycerin fatty acid esters, organic acid monoglycerides, etc.), salt, flavoring agents, coloring agents, acidulants, flavor materials (coffee, cocoa, tea, chocolate raw materials, fruit juice, pulp, seeds, honey, maple syrup, alcoholic beverages, etc.), , various nutrients (proteins, amino acids, dietary fibers such as polydextrose, inulin, indigestible dextrin, vitamins, minerals, etc.).
Further, the form of the oil-in-water emulsion of the present invention is not particularly limited, and can be used, for example, in beverages, whipped cream, fillings, whiteners, and the like.
本発明の水中油型乳化物の製造方法は、前記植物ベース乳と前記ランダムエステル交換油脂とを混合して乳化させる工程を含む。さらには、前記植物ベース乳と前記ランダムエステル交換油脂に、前記ランダムエステル交換油脂以外の前記植物油脂とを混合しても良い。前記植物ベース乳は水相に、前記ランダムエステル交換油脂は油相に、それぞれ他の原材料と共に混合する。乳化工程においての混合方法は特に限定されず、慣用の攪拌手段、例えば、攪拌棒などを用いた手攪拌や、攪拌子や攪拌翼を備えた機械的攪拌、超音波分散機などが利用できる。これらのうち、機械的攪拌が汎用される。機械的攪拌として、例えば、ホモミキサー、ホモジナイザー、ホモディスパー、ヘンシェルミキサー、バンバリーミキサー、ボンミキサー、V型ミキサー、インラインミキサー等が挙げられる。機械的攪拌を使用する場合、攪拌速度は、処理量に応じて適宜選択できる。乳化工程において加熱温度は、例えば、50℃~90℃程度である。得られた水中油型乳化物は、油脂類の結晶状態を安定化させ、適度な粘度に調整するため、熟成(エージング)処理する熟成工程に供しても良い。得られた水中油型乳化物は、必要に応じて殺菌処理を行っても良く、行わなくても良い。殺菌処理しても品質劣化を抑制でき、殺菌方法としては加熱処理等が挙げられる。 The method for producing an oil-in-water emulsion of the present invention includes the step of mixing and emulsifying the plant-based milk and the random transesterified fat. Furthermore, the plant-based milk and the random transesterified fat may be mixed with the vegetable fat other than the random transesterified fat. The plant-based milk is mixed into the water phase, and the random transesterified oil and fat is mixed into the oil phase, along with other raw materials. The mixing method in the emulsification step is not particularly limited, and conventional stirring means such as manual stirring using a stirring bar, mechanical stirring equipped with a stirring bar or stirring blade, and an ultrasonic disperser can be used. Among these, mechanical stirring is commonly used. Examples of mechanical stirring include a homomixer, homogenizer, homodisper, Henschel mixer, Banbury mixer, Bonn mixer, V-type mixer, and in-line mixer. When using mechanical stirring, the stirring speed can be selected as appropriate depending on the amount to be processed. The heating temperature in the emulsification step is, for example, about 50°C to 90°C. The obtained oil-in-water emulsion may be subjected to an aging process in order to stabilize the crystalline state of the oil and fat and adjust the viscosity to an appropriate level. The obtained oil-in-water emulsion may or may not be sterilized if necessary. Even with sterilization treatment, quality deterioration can be suppressed, and examples of sterilization methods include heat treatment.
前記乳化工程を経て得られた水中油型乳化物は、さらにホイップ工程に供することにより、ホイップドクリーム(ホイップ後のホイップクリーム)を調製することができる。ホイップ工程では、乳化工程で得られた乳化物が部分的に解乳化すると共に、組成物が抱気することにより、ホイップドクリームが得られる。
また前記乳化工程を経て得られた水中油型乳化物は、フリージング工程及び硬化工程に供することで、冷菓を調製することができる。フリージング工程では、ミックス液をフリーザーにより急激に冷却させて水分を凍結させながら適当量の空気を混入させ、ミックス液中に微細な空気の泡と氷の結晶粒、脂肪粒子を分散させ、半流動状のソフトクリーム状とする。硬化工程では、これを充填・成形・包装した後、―20℃~―40℃に急冷却し、一定の形を保持し凍結させる。
The oil-in-water emulsion obtained through the emulsification step can be further subjected to a whipping step to prepare whipped cream (whipped cream after whipping). In the whipping step, the emulsion obtained in the emulsification step is partially demulsified and the composition is inflated, thereby obtaining whipped cream.
Moreover, the oil-in-water emulsion obtained through the emulsification step can be subjected to a freezing step and a hardening step to prepare a frozen dessert. In the freezing process, the mix liquid is rapidly cooled in a freezer to freeze the moisture and mix an appropriate amount of air, which disperses fine air bubbles, ice crystal grains, and fat particles in the mix liquid, making it semi-solid. Make it into a soft cream-like shape. In the hardening process, after being filled, molded, and packaged, it is rapidly cooled to -20°C to -40°C to maintain a certain shape and freeze.
例えば、アーモンドミルクを用いたホイップドクリームの調製として、次のような調製方法を挙げることができる。前記ランダムエステル交換油脂、他の油脂を加温融解し、油溶性乳化剤等を加えて混合溶解し、油相とする。別途、温水に水溶性成分等を混合溶解し、水相とする。乳化タンクにて油相と水相を調合し、65℃で30分間ホモミキサーで予備乳化し、均質化する(圧力4Mpa)。その後、超高温殺菌設備にて殺菌処理し(144℃で4秒)、直ちに冷却することで、異風味が抑制され、また濃厚感を感じるフレーバーリリースの良いアーモンドミルクを用いたホイップドクリームを得ることができる。上述の副原料等を適宜使用することができる。 For example, the following method can be used to prepare whipped cream using almond milk. The random transesterified fat and other fats and oils are heated and melted, and an oil-soluble emulsifier and the like are added and mixed and dissolved to form an oil phase. Separately, water-soluble components are mixed and dissolved in warm water to form an aqueous phase. The oil phase and the aqueous phase are mixed in an emulsification tank, and pre-emulsified and homogenized using a homomixer at 65° C. for 30 minutes (pressure 4 MPa). After that, it is sterilized in ultra-high temperature sterilization equipment (144°C for 4 seconds) and immediately cooled to suppress off-flavors and produce whipped cream using almond milk that has a rich flavor and good flavor release. be able to. The above-mentioned auxiliary raw materials and the like can be used as appropriate.
本発明の異風味を抑制する方法は、前記ランダムエステル交換油脂、ならびに該植物ベース乳を含むことを特徴とする水中油型乳化物において、効果を発揮することができる。前記ランダムエステル交換油脂は、水中油型乳化物の油脂含量(油分)中に0.05~60重量%、より好ましくは0.1~58重量%、さらに好ましくは1.0~55重量%、さらにより好ましくは2.0~10重量%である。前記ランダムエステル交換油脂の含量が上記範囲を満たしていれば、他の油脂と併用しても、植物ベース乳の異風味抑制効果を得ることができる。また、水中油型乳化物の調製方法は、上述の通りである。 The method for suppressing off-flavors of the present invention can be effective in an oil-in-water emulsion characterized by containing the random transesterified oil and fat and the plant-based milk. The random transesterified fat is 0.05 to 60% by weight, more preferably 0.1 to 58% by weight, even more preferably 1.0 to 55% by weight in the fat content (oil content) of the oil-in-water emulsion. Even more preferably it is 2.0 to 10% by weight. As long as the content of the random transesterified fat and oil satisfies the above range, even when used in combination with other fats and oils, the effect of suppressing off-flavors of plant-based milk can be obtained. Moreover, the method for preparing the oil-in-water emulsion is as described above.
(実施例)
以降に本発明をより詳細に説明する。なお、文中「部」及び「%」は特に断りのない限り重量基準を意味する。
(Example)
The present invention will be explained in more detail below. In addition, "part" and "%" in the text mean a weight basis unless otherwise specified.
(検討油脂の調製)
表1の配合に従い、次の方法で各検討油脂を調製した。すなわち、各油脂を混合し、ナトリウムメチラートを用いて80℃にてランダムエステル交換反応を行ったあと、常法に従い水洗/脱色/脱臭を行い、各検討油脂を得た。検討に用いた油脂はいずれも不二製油(株)社製のものを使用した。中鎖脂肪酸結合油脂として、n―オクタン酸(炭素数8)とn―デカン酸(炭素数10)を構成脂肪酸とし、これらの重量比が60:40であるMCT-64(不二製油(株)社製)を用いた。また、検討に用いた油脂のヨウ素価(IV)を表1に記載した。なお、各検討油脂の脂肪酸組成分析はAOCS Official Method Ce 1h-05の方法に準じて測定した。各検討油脂の組成を表1に記載した。
(Preparation of studied fats and oils)
According to the formulations in Table 1, each oil and fat to be studied was prepared in the following manner. That is, each fat and oil was mixed, subjected to random transesterification reaction at 80° C. using sodium methylate, and then washed with water/decolorized/deodorized in accordance with conventional methods to obtain each fat and oil to be examined. All oils and fats used in the study were manufactured by Fuji Oil Co., Ltd. MCT-64 (Fuji Oil Co., Ltd.), which has n-octanoic acid (8 carbon atoms) and n-decanoic acid (10 carbon atoms) as constituent fatty acids, with a weight ratio of 60:40, is used as a medium-chain fatty acid-bound oil. ) manufactured by ) was used. Furthermore, the iodine values (IV) of the oils and fats used in the study are listed in Table 1. In addition, fatty acid composition analysis of each studied oil and fat was measured according to the method of AOCS Official Method Ce 1h-05. The composition of each studied oil and fat is listed in Table 1.
<検討1>アーモンドミルクを配合した水中油型乳化物の検討
(検討油脂の調製)
本検討では検討油脂1を用いた。その他に、ヤシ油、硬化ヤシ油、パーム中融点油(ヨウ素価46)を用いた(何れも不二製油(株)社製)。
<Study 1> Study of oil-in-water emulsion containing almond milk (preparation of study oil)
In this study, study fat 1 was used. In addition, coconut oil, hydrogenated coconut oil, and palm medium melting point oil (iodine value 46) were used (all manufactured by Fuji Oil Co., Ltd.).
(アーモンドミルクを用いた水中油型乳化物の調製)
下記の調製方法にて、アーモンドミルクを用いた水中油型乳化物を得た。
1. 市販のアーモンドミルク飲料(江崎グリコ(株)社製、アーモンド効果(砂糖不使用)、脂質含量1.5%)を99部(比較例1、2、実施例1~6)あるいは97部(比較例3、実施例7、8)を、ホモミキサー(60℃で5000rpm)にて混合しながら、表2に記載の油脂を1部(比較例1、2、実施例1~6)あるいは3部(比較例3、実施例7、8)添加した。
2. 20分間攪拌した。
3. 2で得られた溶液を高圧ホモゲナイザー(15Mpa)に通液し、試飲に供する水中油型乳化物を得た。
なお、水中油型乳化物の油脂含量(油分)中の検討油脂の配合量を表2に記載した。
(Preparation of oil-in-water emulsion using almond milk)
An oil-in-water emulsion using almond milk was obtained by the following preparation method.
1. Commercially available almond milk drink (manufactured by Ezaki Glico Co., Ltd., almond effect (sugar free), fat content 1.5%) was added to 99 parts (Comparative Examples 1 and 2, Examples 1 to 6) or 97 parts (Comparative Examples 1 and 2, Examples 1 to 6). Example 3, Examples 7, 8) were mixed in a homomixer (60°C, 5000 rpm), while adding 1 part (Comparative Examples 1, 2, Examples 1 to 6) or 3 parts of the fats and oils listed in Table 2. (Comparative Example 3, Examples 7 and 8) Added.
2. Stirred for 20 minutes.
3. The solution obtained in step 2 was passed through a high-pressure homogenizer (15 MPa) to obtain an oil-in-water emulsion to be sampled.
In addition, Table 2 shows the blending amount of the studied fats and oils in the fats and oils content (oil content) of the oil-in-water emulsion.
(評価方法)
評価は、植物ベース乳由来の異風味の有無と風味強度とし、それぞれ下記のように評価した。パネラー16名で官能評価を行い、パネラーの合議で、各評価共に3点以上のものを総合評価合格(○と表記)とした。評価結果を表2に記載した。
○アーモンドミルク由来の異風味(苦みを伴う穀物臭さ)の有無
1点:異風味がかなり感じられる。
2点:異風味が感じられる。
3点:異風味がわずかに感じられるが、喫食できる風味である。
4点:異風味が感じられない。
5点:異風味が全く感じられない。
○風味強度(喫食直後に感じるフレーバーリリースの強度と、後半に感じるアーモンドミルク由来の濃厚感の強度)
1点:フレーバーリリースがかなり弱く、アーモンドミルク由来の濃厚感が全く感じられない。
2点:フレーバーリリースが弱く、アーモンドミルク由来の濃厚感がわずかに感じる。
3点:フレーバーリリースがあり、アーモンドミルク由来の濃厚感を感じる。
4点:フレーバーリリースが強く、アーモンドミルク由来の濃厚感を良く感じる。
5点:フレーバーリリースがかなり強く、アーモンドミルク由来の濃厚感も強く感じ、乳化物全体の風味がかなり良い。
(Evaluation method)
The evaluation was based on the presence or absence of off-flavors derived from plant-based milk and the flavor intensity, and each was evaluated as follows. Sensory evaluation was conducted by 16 panelists, and in consensus among the panelists, those with 3 or more points in each evaluation were considered to have passed the overall evaluation (denoted as ○). The evaluation results are listed in Table 2.
○ Presence or absence of off-flavor derived from almond milk (grain smell with bitterness) 1 point: Off-flavor is felt considerably.
2 points: A strange flavor is felt.
3 points: A slightly off-flavor is felt, but the flavor is edible.
4 points: No strange flavor detected.
5 points: No off-flavor felt at all.
○Flavor intensity (intensity of flavor release felt immediately after eating and intensity of richness derived from almond milk felt in the second half)
1 point: Flavor release is quite weak, and the richness derived from almond milk cannot be felt at all.
2 points: Flavor release is weak, and the richness derived from almond milk is slightly felt.
3 points: There is a flavor release and you can feel the richness derived from almond milk.
4 points: The flavor release is strong, and you can feel the richness derived from almond milk.
5 points: The flavor release is quite strong, the richness derived from almond milk is felt strongly, and the flavor of the emulsion as a whole is quite good.
アーモンドミルクを配合した水中油型乳化物において、ヤシ油を水中油型乳化物中の1部あるいは3部配合した比較例1と3では、何れもアーモンドミルク由来のフレーバーリリースと濃厚感が感じられるものの、異風味がかなり感じられた。また、硬化ヤシ油を配合した水中油型乳化物においても、ヤシ油と同様の傾向であった(比較例2)。
各検討油脂あるいは各検討油脂とパーム中融点油を配合した実施例1~8では、アーモンドミルク由来のフレーバーリリースと濃厚感が感じつつ、異風味が全く感じられなかった。検討油脂とパーム中融点油との併用では、バランスの取れた風味の良い乳化物が得られた。
In Comparative Examples 1 and 3, in which 1 part or 3 parts of coconut oil was added to the oil-in-water emulsion containing almond milk, flavor release and richness derived from almond milk were felt in both cases. However, I could sense a very strange flavor. Furthermore, an oil-in-water emulsion containing hydrogenated coconut oil had the same tendency as coconut oil (Comparative Example 2).
In Examples 1 to 8 in which each of the tested oils and fats or each tested oil and fat were blended with palm medium melting point oil, the flavor release and richness derived from almond milk were felt, but no off-flavor was felt at all. When the studied oil and fat were used in combination with palm medium melting point oil, an emulsion with a well-balanced flavor was obtained.
<検討2>オーツミルクを配合した水中油型乳化物の検討
(検討油脂)
本検討では検討油脂1を用いた。その他、ヤシ油とパーム中融点油を用いた。
<Study 2> Study of oil-in-water emulsion containing oat milk (studyed oil and fat)
In this study, study fat 1 was used. In addition, coconut oil and palm medium melting point oil were used.
(オーツミルクを用いた水中油型乳化物の調製)
下記の調製方法にて、オーツミルクを用いた水中油型乳化物を得た。
1. 市販のオーツミルク飲料(ダノンジャパン(株)社製、alpro(砂糖不使用)、脂質含量1.4%)99部を、ホモミキサー(60℃で5000rpm)にて混合しながら、表2に記載の油脂を1部添加した。
2. 20分間攪拌した。
3. 2で得られた溶液を高圧ホモゲナイザー(15Mpa)に通液し、試飲に供する水中油型乳化物を得た。
なお、水中油型乳化物の油脂含量(油分)中の検討油脂の配合量を表3に記載した。
(Preparation of oil-in-water emulsion using oat milk)
An oil-in-water emulsion using oat milk was obtained by the following preparation method.
1. While mixing 99 parts of a commercially available oat milk drink (manufactured by Danone Japan Co., Ltd., ALPRO (sugar-free), fat content 1.4%) in a homomixer (5000 rpm at 60°C), the ingredients listed in Table 2 were mixed. 1 part of fat and oil was added.
2. Stirred for 20 minutes.
3. The solution obtained in step 2 was passed through a high-pressure homogenizer (15 MPa) to obtain an oil-in-water emulsion to be sampled.
Note that Table 3 lists the blending amounts of the studied fats and oils in the fat content (oil content) of the oil-in-water emulsion.
(評価方法)
評価は、植物ベース乳由来の異風味の有無と風味強度とし、それぞれ下記のように評価した。パネラー13名で官能評価を行い、パネラーの合議で、各評価共に3点以上のものを総合評価合格(○と表記)とした。評価結果を表3に記載した。
○オーツミルク由来の異風味(草っぽい穀物臭)の有無
1点:異風味がかなり感じられる。
2点:異風味が感じられる。
3点:異風味がわずかに感じられるが、喫食できる風味である。
4点:異風味が感じられない。
5点:異風味が全く感じられない。
○風味強度(喫食直後に感じるフレーバーリリースの強度と、後半に感じるオーツミルク由来の濃厚感の強度)
1点:フレーバーリリースがかなり弱く、オーツミルク由来の濃厚感が全く感じられない。
2点:フレーバーリリースが弱く、オーツミルク由来の濃厚感がわずかに感じる。
3点:フレーバーリリースがあり、オーツミルク由来の濃厚感を感じる。
4点:フレーバーリリースが強く、オーツミルク由来の濃厚感を良く感じる。
5点:フレーバーリリースがかなり強く、オーツミルク由来の濃厚感も強く感じ、乳化物全体の風味がかなり良い。
(Evaluation method)
The evaluation was based on the presence or absence of off-flavors derived from plant-based milk and the flavor intensity, and each was evaluated as follows. A sensory evaluation was conducted by 13 panelists, and in a consensus of the panelists, those with 3 or more points in each evaluation were considered to have passed the overall evaluation (denoted as ○). The evaluation results are listed in Table 3.
○ Presence or absence of off-flavor derived from oat milk (grassy grain odor) 1 point: Off-flavor can be felt considerably.
2 points: A strange flavor is felt.
3 points: A slightly off-flavor is felt, but the flavor is edible.
4 points: No strange flavor detected.
5 points: No off-flavor felt at all.
○Flavor intensity (intensity of flavor release felt immediately after eating and intensity of richness derived from oat milk felt in the second half)
1 point: Flavor release is quite weak, and the richness derived from oat milk cannot be felt at all.
2 points: Flavor release is weak, and the richness derived from oat milk is felt slightly.
3 points: There is a flavor release and you can feel the richness derived from oat milk.
4 points: Strong flavor release, with a good richness derived from oat milk.
5 points: The flavor release is quite strong, the richness derived from oat milk is felt strongly, and the flavor of the emulsion as a whole is quite good.
オーツミルクを配合した水中油型乳化物において、ヤシ油を配合した比較例4では、オーツミルク由来のフレーバーリリースと濃厚感はかなり強いが、同時に異風味がかなり感じられた。一方、検討油脂1あるいは検討油脂1とパーム中融点油を配合した実施例9、10では、オーツミルク由来の異風味は全く感じられず、またオーツミルク由来の濃厚感も感じられた。 In Comparative Example 4, in which coconut oil was blended into an oil-in-water emulsion containing oat milk, the flavor release and richness derived from oat milk were quite strong, but at the same time, a considerable off-flavor was felt. On the other hand, in Examples 9 and 10 in which the tested fat 1 or the tested fat 1 was blended with palm medium melting point oil, no unusual flavor derived from oat milk was felt, and a rich feeling derived from oat milk was also felt.
<検討3>豆乳を配合した水中油型乳化物の検討
(検討油脂)
本検討には検討油脂1、4、5、6、7、8を用いた。その他に、ヤシ油、パーム中融点油、ステアリン酸及びオレイン酸を主体とする油脂(不二製油(株)社製、上昇融点25℃)を用いた。
<Study 3> Study of oil-in-water emulsion containing soy milk (studyed oil and fat)
In this study, test fats and oils 1, 4, 5, 6, 7, and 8 were used. In addition, coconut oil, palm medium melting point oil, and oils and fats mainly containing stearic acid and oleic acid (manufactured by Fuji Oil Co., Ltd., rising melting point 25° C.) were used.
(豆乳を用いた水中油型乳化物の調製)
下記の調製方法にて、豆乳を用いた水中油型乳化物を得た。
1. 表4の配合に従い、油脂以外の全てを混合しながら、ホモミキサー(60℃で5000rpm)にて混合しながら、表5に記載の油脂を添加した。なお、比較例5のブランクは、油脂を添加せず、代わりに水を増やして調製した。
2. 6000rpmで20分間攪拌した。
3. 2で得られた溶液を高圧ホモゲナイザー(15Mpa)に通液し、5℃で一晩エージングし、試飲に供する水中油型乳化物を得た。
なお、水中油型乳化物の油脂含量(油分)中の検討油脂の配合量を表5に記載した。
(Preparation of oil-in-water emulsion using soy milk)
An oil-in-water emulsion using soybean milk was obtained by the following preparation method.
1. According to the formulation in Table 4, the fats and oils listed in Table 5 were added while mixing everything except the fats and oils using a homomixer (60° C., 5000 rpm). Note that the blank of Comparative Example 5 was prepared without adding oil or fat, and instead adding water.
2. The mixture was stirred at 6000 rpm for 20 minutes.
3. The solution obtained in step 2 was passed through a high-pressure homogenizer (15 MPa) and aged at 5° C. overnight to obtain an oil-in-water emulsion for tasting.
In addition, Table 5 shows the blending amount of the studied fats and oils in the fat content (oil content) of the oil-in-water emulsion.
(評価方法)
評価は、植物ベース乳由来の異風味の有無と風味強度とし、それぞれ下記のように評価した。パネラー11名で官能評価を行い、パネラーの合議で、各評価共に3点以上のものを総合評価合格(○と表記)とした。評価結果を表5に記載した。
○豆乳由来の異風味(青臭さや豆臭さ)の有無
1点:異風味がかなり感じられる。
2点:異風味が感じられる。
3点:異風味がわずかに感じられるが、喫食できる風味である。
4点:異風味が感じられない。
5点:異風味が全く感じられない。
○風味強度(喫食直後に感じるフレーバーリリースの強度と、後半に感じる豆乳由来の濃厚感の強度)
1点:フレーバーリリースがかなり弱く、豆乳由来の濃厚感が全く感じられない。
2点:フレーバーリリースが弱く、豆乳由来の濃厚感がわずかに感じる。
3点:フレーバーリリースがあり、豆乳由来の濃厚感を感じる。
4点:フレーバーリリースが強く、豆乳由来の濃厚感を良く感じる。
5点:フレーバーリリースがかなり強く、豆乳由来の濃厚感も強く感じ、乳化物全体の風味がかなり良い。
(Evaluation method)
The evaluation was based on the presence or absence of off-flavors derived from plant-based milk and the flavor intensity, and each was evaluated as follows. A sensory evaluation was conducted by 11 panelists, and in a consensus among the panelists, those with 3 or more points in each evaluation were considered to have passed the overall evaluation (denoted as ○). The evaluation results are listed in Table 5.
○ Presence or absence of off-flavor derived from soy milk (grassy odor or bean odor) 1 point: Off-flavor is felt considerably.
2 points: A strange flavor is felt.
3 points: A slightly off-flavor is felt, but the flavor is edible.
4 points: No strange flavor detected.
5 points: No off-flavor felt at all.
○Flavor intensity (intensity of flavor release felt immediately after consumption and intensity of richness derived from soy milk felt in the second half)
1 point: Flavor release is quite weak, and the richness derived from soy milk cannot be felt at all.
2 points: Flavor release is weak, and the richness derived from soy milk is slightly felt.
3 points: There is a flavor release and you can feel the richness derived from soy milk.
4 points: The flavor release is strong, and you can feel the richness derived from soy milk.
5 points: The flavor release is quite strong, the richness derived from soy milk is felt strongly, and the flavor of the emulsion as a whole is quite good.
豆乳を用いた水中油型乳化物において、油脂を含まないブランクでは(比較例5)、豆乳由来の異風味がかなり感じられ、またフレーバーリリースと濃厚感が弱く感じた。各検討油脂を含まない比較例6~8では、何れも豆乳由来のフレーバーリリースと濃厚感の強度は良いものの、豆乳由来の異風味が感じられた。特に比較例7と8では、かなり強い豆乳由来の異風味が感じられた。
検討油脂1、検討油脂4~8を配合した実施例11~16では、豆乳由来の異風味が感じられず、フレーバーリリースと濃厚感の強度も良好であった。また、比較例5~7の油脂の10%を検討油脂1、5、8に各々置換した実施例17~25でも、豆乳由来の異風味は全く感じられず、フレーバーリリースと濃厚感もかなり強く、乳化物全体の風味が良好であった。特に、ヤシ油と検討油脂を併用することで、バランスの取れた風味の良い乳化物であった(実施例17、実施例23)。また、パーム中融点油を容量依存的に検討油脂1に置換しても、豆乳由来の異風味はほぼ感じられず、風味強度も良好であった(実施例26~28)。
この検討から、各検討油脂は共に配合する油脂の種類に関係なく、また各検討油脂を少量配合しても、豆乳由来の異風味を十分に抑制することが確認された。合わせてフレーバーリリースと濃厚感が良好で、バランスの取れた風味の水中油型乳化物を得ることができた。
In the oil-in-water emulsion using soymilk, in the blank containing no fat or oil (Comparative Example 5), the off-flavor derived from soymilk was felt considerably, and flavor release and richness were felt to be weak. In Comparative Examples 6 to 8, which did not contain any of the studied oils and fats, the flavor release and richness derived from soy milk were good, but an off-flavor derived from soy milk was felt. In particular, in Comparative Examples 7 and 8, a fairly strong soy milk-derived off-flavor was felt.
In Examples 11 to 16, in which the tested oils and fats 1 and the tested oils and fats 4 to 8 were blended, no off-flavor derived from soy milk was felt, and the flavor release and richness were good. Furthermore, in Examples 17 to 25, in which 10% of the fats and oils in Comparative Examples 5 to 7 were replaced with the tested fats and oils 1, 5, and 8, respectively, no unusual flavor derived from soy milk was felt, and the flavor release and richness were also quite strong. The flavor of the entire emulsion was good. In particular, by using coconut oil and the tested oil/fat in combination, emulsions with a well-balanced flavor were obtained (Example 17, Example 23). Furthermore, even when the palm medium melting point oil was replaced with the tested oil/fat 1 in a volume-dependent manner, the off-flavor derived from soybean milk was hardly felt and the flavor intensity was good (Examples 26 to 28).
From this study, it was confirmed that each of the tested oils and fats can sufficiently suppress the off-flavors derived from soy milk, regardless of the type of fats and oils that are blended together, and even when a small amount of each tested fat and oil is blended. In addition, it was possible to obtain an oil-in-water emulsion with good flavor release and richness, and a well-balanced flavor.
<検討4>豆乳を配合した水中油型乳化物の検討
(検討油脂)
本検討では検討油脂1を用いた。その他に、ヤシ油とパーム中融点油を用いた。
<Study 4> Study of oil-in-water emulsion containing soy milk (study oil)
In this study, study fat 1 was used. In addition, coconut oil and palm medium melting point oil were used.
(豆乳を用いた水中油型乳化物の調製)
下記の調製方法にて、殺菌処理した、豆乳を用いた水中油型乳化物を得た。
1. 表4の配合に従い、油脂以外の全てを混合しながら、ホモミキサー(60℃で5000rpm)にて混合しながら、表6に記載の油脂を添加した。
2. 6000rpmで20分間攪拌した。
3. 2で得られた溶液を超高温殺菌設備にて殺菌処理した(145℃で7秒)。
4. 殺菌後の溶液を高圧ホモゲナイザー(15Mpa)に通液し、5℃で一晩エージングし、試飲に供する水中油型乳化物を得た。
なお、水中油型乳化物の油脂含量(油分)中の検討油脂の配合量を表6に記載した。
(Preparation of oil-in-water emulsion using soy milk)
An oil-in-water emulsion using sterilized soybean milk was obtained by the following preparation method.
1. According to the formulation in Table 4, the fats and oils listed in Table 6 were added while mixing everything except the fats and oils using a homomixer (60° C., 5000 rpm).
2. The mixture was stirred at 6000 rpm for 20 minutes.
3. The solution obtained in step 2 was sterilized using ultra-high temperature sterilization equipment (145° C. for 7 seconds).
4. The sterilized solution was passed through a high-pressure homogenizer (15 MPa) and aged at 5° C. overnight to obtain an oil-in-water emulsion for tasting.
In addition, Table 6 shows the blending amount of the studied fats and oils in the fat content (oil content) of the oil-in-water emulsion.
(評価方法)
評価は、検討3を踏襲した。評価結果を表6に記載した。
(Evaluation method)
The evaluation followed Study 3. The evaluation results are listed in Table 6.
豆乳を含む水中油型乳化物を殺菌しても、比較例9のヤシ油を配合したものはフレーバーリリースと濃厚感が強いが、異風味が感じられたのに対し、実施例29の検討油脂1配合あるいは実施例30のパーム中融点油の10%を検討油脂1で置換したものでは、何れも豆乳由来の異風味は感じられず、風味強度も良好であった。
本発明のランダムエステル交換油脂を水中油型乳化物に少量配合することでも、植物ベース乳由来の異風味を十分抑制することができ、また植物ベース由来の豊かな風味も感じることができることを確認した。
Even when the oil-in-water emulsion containing soy milk was sterilized, the one containing coconut oil in Comparative Example 9 had strong flavor release and richness, but had an off-flavor. 1 formulation or in which 10% of the palm medium melting point oil of Example 30 was replaced with Study Oil 1, no off-flavor derived from soy milk was felt and the flavor intensity was good.
It was confirmed that by blending a small amount of the random transesterified fat of the present invention into an oil-in-water emulsion, it was possible to sufficiently suppress the off-flavors derived from plant-based milk, and also to enjoy the rich flavor derived from plant-based milk. did.
Claims (12)
(A)構成脂肪酸組成中、炭素数6~10の飽和脂肪酸の含有量が0.3~40重量%
(B)構成脂肪酸組成中、炭素数12~14の飽和脂肪酸の含有量が40~80重量% An oil-in-water emulsion that satisfies (A) and (B) below and includes a random transesterified fat and oil and a plant-based milk.
(A) In the constituent fatty acid composition, the content of saturated fatty acids having 6 to 10 carbon atoms is 0.3 to 40% by weight.
(B) In the constituent fatty acid composition, the content of saturated fatty acids having 12 to 14 carbon atoms is 40 to 80% by weight.
(C)構成脂肪酸組成中、オレイン酸含量が10重量%以下 The oil-in-water emulsion according to claim 1, wherein the random transesterified fat satisfies (A), (B), and (C).
(C) Oleic acid content is 10% by weight or less in the constituent fatty acid composition
(D)(炭素数12~14の飽和脂肪酸の含有量)/(炭素数6~10の飽和脂肪酸の含有量)の比が1.0~6.0 The oil-in-water emulsion according to claim 1, wherein the random transesterified oil satisfies (A), (B), and (D).
(D) The ratio of (content of saturated fatty acids with 12 to 14 carbon atoms)/(content of saturated fatty acids with 6 to 10 carbon atoms) is 1.0 to 6.0
(D)(炭素数12~14の飽和脂肪酸の含有量)/(炭素数6~10の飽和脂肪酸の含有量)の比が1.0~6.0 The oil-in-water emulsion according to claim 2, wherein the random transesterified oil or fat satisfies (A), (B), (C), and (D).
(D) The ratio of (content of saturated fatty acids with 12 to 14 carbon atoms)/(content of saturated fatty acids with 6 to 10 carbon atoms) is 1.0 to 6.0
(A)構成脂肪酸組成中、炭素数6~10の飽和脂肪酸の含有量が0.3~40重量%
(B)構成脂肪酸組成中、炭素数12~14の飽和脂肪酸の含有量が40~80重量% An oil-in-water emulsion that satisfies the following (A) and (B) and emulsifies by mixing 0.05% by weight or more of random transesterified fat into the fat content (oil content) of an oil-in-water emulsion and plant-based milk. Method for producing emulsion.
(A) In the constituent fatty acid composition, the content of saturated fatty acids having 6 to 10 carbon atoms is 0.3 to 40% by weight.
(B) In the constituent fatty acid composition, the content of saturated fatty acids having 12 to 14 carbon atoms is 40 to 80% by weight.
(A)構成脂肪酸組成中、炭素数6~10の飽和脂肪酸の含有量が0.3~40重量%
(B)構成脂肪酸組成中、炭素数12~14の飽和脂肪酸の含有量が40~80重量% A method for suppressing off-flavors in an oil-in-water emulsion containing a random transesterified fat and a plant-based milk that satisfies (A) and (B) below.
(A) In the constituent fatty acid composition, the content of saturated fatty acids having 6 to 10 carbon atoms is 0.3 to 40% by weight.
(B) In the constituent fatty acid composition, the content of saturated fatty acids having 12 to 14 carbon atoms is 40 to 80% by weight.
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JP2008161106A (en) | 2006-12-28 | 2008-07-17 | Nof Corp | Oil and fat composition for whipped cream |
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