JP7348681B1 - Method for producing water-soluble silicon solution - Google Patents

Abstract

The present invention provides a water-soluble silicon solution containing a high concentration of silicon and a method for producing the water-soluble silicon solution, which further improves the usefulness of functional water in various fields. A water-soluble silicon solution is obtained by adding silicon extracted from a mineral or plant containing quartz to functional water containing water-soluble silicic acid. The method for producing a water-soluble silicon solution includes the step of adding silicon extracted from a mineral or plant containing quartz to functional water containing water-soluble silicic acid. [Selection diagram] Figure 1

Description

The present invention relates to a water-soluble silicon solution containing a high concentration of silicon and a method for producing a water-soluble silicon solution, which further improves the usefulness of functional water in various fields. The present invention relates to a method for producing a water-soluble silicon solution having a micellar colloidal structure in which mineral or plant-derived silicon is added to water.

Functional water containing water-soluble silicic acid (hereinafter referred to as functional water) has been confirmed to be useful in various fields including health and beauty, agriculture, livestock, and industry. Functional water is modified water that has useful properties in water modification technology using anti-firestone (a type of pumice), and attempts to bring it to the market are now becoming a reality.

Patent Document 1 discloses an aqueous silicic acid solution that contains silicate ions as a solute, has a silicon content higher than that of tap water, and has a specific gravity of more than 1 at 20°C. Further, Patent Document 1 describes as follows.

“According to the definition of the Japanese Society for Functional Water, functional water is ``an aqueous solution that has acquired reproducible and useful functions through artificial treatment, and for which the scientific basis for treatment and function has been clarified. and that which is about to be revealed.” As long as it is an ``aqueous solution,'' its properties are determined by the type and amount of solute, and the temperature and pressure at which the aqueous solution is placed. First, it is important to evaluate the types and amounts of substances other than water molecules. If we go further into the liquid structure, we need to investigate the arrangement of water around the solute.

Conventionally, in water reforming technology using anti-flinders, it is possible to produce reformed water with useful properties, but no attempt has yet been made to release such water into the world as functional water.

In view of this, the present invention provides water using anti-firestone as functional water. ”

JP2020-63184A

The above-mentioned document 1 is a document related to the provision of functional water, and has a configuration in which water is converted into functional water using anti-flinder stone, and is described as follows.

“In this way, an ortho-silicic acid aqueous solution is structurally stabilized by ortho-silicic acid forming a cyclic hexamer. Since the outer surface is more negatively charged than the outer surface, water molecules can be bonded to or attracted to the outer surface to form a water aggregate with orthosilicic acid as the core.

Normally, it is thought that water molecules in a solvent coexist in both a state where the water molecules are floating alone and a state where they are gathered to some extent to form an aggregate. In pure water, water molecules form aggregates only by hydrogen bonds, but in the ortho-silicic acid aqueous solution according to this embodiment, hexamers of ortho-silicic acid are bonded together by chemical bonds, as shown in FIG. At the same time, water molecules are electrically bonded around the ortho-silicic acid hexamer, forming a stronger aggregate than pure water. On the other hand, the water form of the ortho-silicic acid aqueous solution according to the present embodiment has a smaller aggregate diameter than tap water. Although it is said that the network structure of water in the liquid phase has an extremely short lifespan and constantly changes to another network structure, and that a specific structure is not memorized, it is possible for an aggregate to behave dynamically. The smaller the diameter, the higher the permeability. For example, while the diameter of an aggregate of tap water is about 200 nm, the diameter of an aggregate of water in the aqueous solution according to this embodiment is 80 to 100 nm. ”
In contrast, an object of the present invention is to provide a method for producing a water -soluble silicon solution containing a high concentration of silicon, which further improves the usefulness of functional water in various fields.

In order to achieve the above object, the method for producing a water-soluble silicon solution according to the present invention includes:
A step of producing a water-soluble silicon solution by adding silicon extracted from a mineral or plant containing quartz to functional water containing water-soluble silicic acid,
The water-soluble silicon solution has a multilayered micelle colloidal structure aggregated based on nano silicon particles.
It is characterized by
Furthermore, the method for producing a water-soluble silicon solution according to the present invention includes:
A step of adding silicon extracted from a mineral or plant containing quartz to functional water containing water-soluble silicic acid;
A step of bringing the silicon-added functional water into contact with an unglazed body using 70% by weight or more of anti-firestone powder, shaped into a desired shape such as a roughly spherical shape using clay as a binder, and sintered at 1000°C to 1500°C. and,
A glaze containing anti-flint, made by using 97% by weight of anti-flint powder and adding 3% by weight of synthetic glue and an appropriate amount of silicon water, was applied to the surface of the unglazed body and fired at 1000°C to 1500°C. a step of contacting the fired body with the functional water that has been in contact with the bisque fired body to obtain a water-soluble silicon solution;
Equipped with
The aqueous silicon solution contains orthosilicic acid that forms oligomeric hexamers.
It is characterized by

The functional water may include anti-flinder, igneous rock, or water containing rock-derived silicic acid, or hot spring water or spring water.

It is preferable to contain 8000 mass ppm or more of silicate ions.

It is preferable to contain silicon in an amount of 0.8% by mass or more and 0.93% by mass or less.

It is preferable to include amorphous silicon derived from minerals or plants.

According to the present invention, it is formally produced by the fourth-stage dissociation of orthosilicic acid, and in an aqueous solution, for example, even if it is strongly basic, no ions are confirmed, and it is similar to natural minerals such as magnesium salt olivine. Found in minerals and called nesosilicate. Orthosilicate (SiO4-4), which has a regular tetrahedral structure and an Si-0 bond distance of 164 pm in the iron olivine crystal, can be used. Thereby, it is possible to provide a method for producing a water -soluble silicon solution containing a high concentration of silicon, which further improves the usefulness of functional water in various fields.

(a) A diagram explaining the hierarchical structure of water, and (b) An enlarged view of its main parts showing the structure of a tetrahedron (regular tetrahedron). Schematic diagram showing hydrogen bonding and dipole properties of water (a) A diagram showing the surface negative charge of a colloid, and (b) A diagram showing the charge and its function of collective action of silicon compound colloidal particles. Diagrams showing the crystal structure of orthosilicate oligomer hexamers; (a) shows a microscopic photograph of squeezed yuzu juice, and (b) shows a microscopic photograph of tomato skin. Diagram showing the process pattern of energy evolution of micellar colloidal Schematic diagram showing the structure of a water generator Configuration diagram showing silicon aqueous solution generation system Flow chart of the manufacturing method of water-soluble silicon solution Comparative photograph of the conventional seaweed concentrate (a) and the biomatrix seaweed of the present invention, showing the structure of the multilayered micellar colloidal (b) in which the aggregation of the present invention has progressed.

Hereinafter, each embodiment of the present invention will be sequentially described based on the drawings. These are preferred examples and are not limited to the description of each embodiment and/or the drawings. Therefore, structures that partially change the configuration within the scope of the spirit of the invention, structures that can achieve the same features and effects, etc. are within the scope of the present invention.

Traditionally, an "aqueous solution" is a state in which solute and water are uniformly mixed in the form of molecules, atoms, and ions, and since it is an "aqueous solution," its properties depend on the type and amount of the solute. It is determined by the temperature and pressure at which the aqueous solution is placed. Therefore, it is important to evaluate the types and amounts of substances other than water molecules. If we go further into the liquid structure, we need to examine the arrangement of water around the solute.

On the other hand, water is an extremely complex and dynamic mixture of molecules, atoms, and ions of dissolved substances that are mixed together in a colloidal state, so water aggregates have a hierarchical structure. You can say it's the body.

In other words, water is a macroscopic bond because the silicon compound "silica sand salt" has stronger hydrogen bonds than water molecules, and it is considered to be the same as the structure of the universe, so it is best to think of it as a hierarchical structure. Most understandable.

The present invention is based on the idea of this hierarchical structure and aims to solve the problems.

A hierarchical structure, which is the basis of the idea of the present invention, has physical properties with gaps. For example, to explain the hierarchical structure (basic structure) of water shown in Figures 1 (a) and (b), water is a 3 angstrom (10 Å = 1 mm) tetrahedron, It is a structure that has oxygen O at the center of gravity, hydrogen H (+) at two vertices, and oxygen O (-) at the other two vertices, and the hydrogen bonds that attract these molecules to each other. Become. They form a group (cluster) with charge positions. This cluster is generally considered to be an assembly of 21 molecules. In FIG. 1(b), meta-silicic acid in hot springs, ortho-silicic acid in seawater, etc. are explained.

The water-soluble silicon solution of the present invention is obtained by adding amorphous silicon extracted from a mineral or plant containing quartz to functional water containing water-soluble silicic acid. The functional water preferably includes water containing anti-fossil, igneous or rock-derived silicic acid, or hot spring water or spring water. The water-soluble silicon solution preferably contains 8000 mass ppm or more and 9000 mass ppm of silicate ions. Further, the water-soluble silicon solution preferably contains silicon in an amount of 0.8% by mass or more and 0.93% by mass or less.

Silicates are the main constituents of minerals and are the second most abundant minerals in the earth's crust, second only to oxygen. Various oxides and orthosilicates are produced in the form of minerals such as quartz, feldspar, crystal, garnet, opal, mica, and asbestos, but water-soluble silicon is produced in the form of natural stones with compositions similar to silicon and alumina. A common method is to contact the silicon with water to obtain water-soluble silicon eluted in the water. Therefore, water-soluble silicon is an orthosilicate, as in the natural world there is very low concentration of orthosilicic acid leached from ores such as stones (reportedly, the average concentration in seawater is 0.00673 g/l). .

Next, the breathing work of water (the repeated action "movement" of dissociation and collection of minerals in water) will be explained.

The primary particles have a size of 2 nanometers (2 nm), the secondary particles that are combined with these particles have a size of 20-30 nanometers (20-30 nm), and the tertiary particles that are combined with these secondary particles are Each particle has a size of 100 nanometers (100 nm), and as shown in FIG. 1(a), each particle constantly repeats violent dissociation and aggregation. Approximately 240 to 250 tetrahedral water molecules are packed into a primary particle of approximately 2 nm. This tetrahedron has a network structure with hydrogen as an intermediary. Both secondary and tertiary particles are the same network, and water is never static; it is constantly moving and vibrating, and propagating its vibration waves into the surrounding space. There are many gaps between particles, and anything other than water can freely enter into these gaps, which is why substances dissolve in water.

Therefore, long-wavelength vibrations of water masses are captured at frequencies of 500 to 4,000 kHz (wavelengths of 75 to 600 m, medium to long wave range of radio waves). This wavelength range is about 300 times larger than the cluster vibration range of water, which has an average of 5.4 molecules in a little less than about 6 angstroms. Frequency comparison calculations show that the population size is approximately 170 to 180 nm (approximately 140 to 150 million molecules), and many molecules of this level are found. Larger particles have longer wavelengths, and smaller particles have shorter wavelengths. As spectral analysis using a pulse spectrometer Aqua Analyzer revealed the existence of autonomous rhythms inherent in water, water moves in aggregated and discrete states (autonomous rhythmic movements and pulsations that exchange energy). ).

In addition, the hidden power of a group of water is two forces generated from the "rhythmic force of the group", one of which is the vibrational effect of the field as a solvent. Like a catalyst that regulates the stability of a solution, it acts as an energy source to maintain order in the solution through the rhythmic action of the field.

The other is the electrical energy effect induced by the rhythmic movement of the collective electric dipole, which serves as the energy source for the activation of the solution. It has already been demonstrated in the scientific world that water has both electricity and magnetism, and these two forces can be thought of as, for example, the ``dynamic force of a group of water.''

If we consider the determination of water's power (energy) from a different perspective, for example, it can be viewed scientifically based on the literary concepts of "order" and "activity" and includes physics, chemistry, and mathematics. . According to Contortion Theory, ``In principle, the ``order'' of a group of water ends up in the solid ``ice,'' and the ``activity'' ends in the gas ``steam.'' According to this flow, order is a force that tries to maintain a ``gathering'' group, and it becomes a so-called restraining force, and as it progresses, the movement of the group itself is completely restricted and becomes ``ice''. In this state, its activity as a liquid ceases. Activity is the ability of the "water molecules" that make up the "gathering" to exert their individuality, and they separate from the group and dissipate into the atmosphere. As it progresses further, the centripetal force of the group itself disappears, and it boils and evaporates. It disappears in the "gaseous" state (described later), and its activity as a liquid stops.

In other words, order and activity in water groups are two sides of the same coin. It is the liquid that is most capable of two-sided activities, that is, the inclusive range of ``moderation.'' Water is considered to be ``water of moderation'' because small group activities exist in which both order and activity can fulfill their functions. In addition, as an example to simply explain the hierarchical structure of water mentioned above, water molecules are considered to be individuals, water clusters are considered to be at the nuclear family level, primary particles are equivalent to large families and villages, and secondary particles are equivalent to large families and villages. In cities and towns, tertiary particles correspond to prefecture-level populations. In other words, the ``order'' and ``activity'' of human relationships (human society) are considered to be the same in water groups.

To explain in detail the structure of the tetrahedron (regular tetrahedron) shown in Figure 1 (a) and (b), carbon with atomic number 6 uses the S orbital and P orbital of the L shell separately. By combining all of them and creating a new trajectory of four rays with the same energy order, we can create a beautifully balanced three-dimensional system. This is the structure of a regular tetrahedron (a regular triangular pyramid with four vertices, made up of four regular triangular faces) called an sp3 hybrid orbital.

The nucleus of the atom exists in the center (center of gravity) of the regular tetrahedron, and is opposed to the electrons located at the four vertices. Each of the four electrons can join hands and form a covalent bond with the electrons of another substance at the same position and with the same force. And create various combinations. The completely isotropic, completely unbiased, balanced, and simple three-dimensional shape created by carbon is considered to be the basic element from which organic compounds are born.

This idea also applies to silicon. Just as four orbitals of carbon combine in the L shell to create an sp3 hybrid orbital with a new energy level, a similar sp3 hybrid orbital can be created in the M shell. That is the element with atomic number 14 (silicon/Si). It covalently bonds with oxygen (O) at each of the four vertices to form a regular tetrahedral structure. This atomic property is also the reason why silicon is so valuable in everything from electronics to medicine. Silicon works closely with oxygen, and in nature various compounds are constructed based on the silicon compound silica SiO2.

According to physics, the constituent atoms of any crystal vibrate and emit light even at absolute zero (-273 degrees Celsius). Similarly, in water, not only the hydrogen and oxygen in the tetrahedral structure vibrate, but the tetrahedral structure also vibrates, and the vibration waves propagate throughout space. Not only a single tetrahedron but also a network group undergoes unique vibrations, and this vibration is the source of long-wavelength pulsations in a larger group. It is said to be the "vibration of the water field."

In FIG. 2, hydrogen bonding and dipole characteristics of water will be explained. The source of electrical energy is the dual physical chemistry of water molecules: dipole properties that allow them to behave like magnets, and hydrogen bonds that bind them to other molecules or water molecules with their four arms. It has unique electrical properties. The oxygen atoms that make up water molecules have a stronger ability to attract electrons than hydrogen atoms, and the electron distribution of water molecules is biased toward the oxygen atoms. Water molecules are particles with a negative charge on the oxygen atom side and a positive charge on the hydrogen atom side. In other words, water molecules are in a state where a positive and a negative polarity are paired like a bar magnet, and this is the origin of the important electric energy of water called dipole characteristics (the basis of the phenomenon of dielectric polarization).

The positively charged hydrogen atoms in water molecules are negatively charged atoms and molecules such as oxygen, which form light electrical hydrogen bonds. The double helix structure of genetic DNA is also connected by hydrogen bonds. Of course, water molecules composed of hydrogen and oxygen form hydrogen bonds with each other. As a result, a number of water molecules come together to form a mass called a cluster, which I mentioned earlier. Because water has two functions: vibration and electric energy, water forms a group called ``order'' and can also exert electric power ``activity'' as a group.

FIGS. 3(a) and 3(b) are diagrams showing the "interface properties" and the electrical properties of colloids, "surface negative charge," which greatly affect the water population.

Here, to explain the structure of the above-mentioned Koshirikige, the raw material of the soil (clay mineral) is rock, and the skeleton of the rock is made of silicon. Clay minerals, which are silicon compounds formed by weathering rocks, have a negative charge and electrically attract cations such as calcium, magnesium, potassium, ammonium, sodium, and hydrogen. As these minerals weather, they release their nutrients. These cations are easily replaced by root acids (hydrogen ions) secreted from plant roots and absorbed by the plant. It plays a role in retaining nutrients for clay minerals. Without silicon, most of the nutrients on the earth's surface would be washed away by water and disappear. Furthermore, to explain the electrical energy action of silicon minerals, the surface negative charge of silicon mineral colloidal particles is one of the elements of ``blood smoothness'', a basic element of health. Furthermore, the electrical properties of silicon and the regular tetrahedral structure hidden deep within it are described in Figure 1. In the unique basic structure of silicon compounds, in which silicon has four hands and oxygen is located at each apex, these phenomena are all caused by the four electrons located in the outermost shell of the element silicon and the outermost shell of oxygen. This is due to a covalent bond between two unpaired electrons (an unstable state in which electrons with rotational spins in the same direction are in the same orbit). The oxygen at the apex of the bond has one unstable matching electron. Through these matching electrons, electron-donating bond transfer spreads the population. This phenomenon is considered to be the surface negative charge effect of the silicate colloid particles shown in FIG. 3(a).

Furthermore, the electrochemical properties of colloidal particles will be explained. We focus on the ``zeta potential,'' which is the electrical behavior of silicate colloid particles as a group. FIG. 3(B) is the basis of the composition range of the electric double layer of the water population, and can also be said to be the core of the electrical population composition that is the unitary existence of the dielectric polarization of the aqueous solution. This is an important element in elucidating the scientific theory of water groups.

Ionized positive ions surround colloid particles with a negative surface charge and act together as a group. Furthermore, a layer that is affected by the charge force of the ion layer is formed around it. Although there is some delay in following the collective movement, the outer edge interface portion of the layer becomes electrically neutral. Those up to this position are members of the group. Figure 3 (b) shows the charge of silicon compound colloidal particles that act in a group and the characteristic aspects of their function. As the absolute value of the zeta potential increases, the repulsive force between particles becomes stronger and the stability of the particles increases. Conversely, as the data potential approaches zero, particles tend to condense. Therefore, zeta potential is used as an index of dispersion stability of dispersed particles.

FIG. 4 is a diagram showing the crystal structure of an orthosilicate oligomer hexamer (cyclic hexamer). Clay minerals, as cyclic hexamers, contain 73-77% silica (SiO2), 13-15% sodium (Na), 1-2% lime (CaO2), and 0.65-0.77% magnesium (MgO). , and other 7.3 to 9%. It has the property of having a specific vibration period due to external force, and due to this property, it affects water molecules when placed in water. For example, aluminum exhibits a type of amorphous allophane, montmorillonite, and saponite in which six or more silicon atoms are bonded to aluminum as a core. However, allophane is a clay quasi-mineral made of amorphous or low crystallinity hydrated aluminum, orthosilicate. Montmorillonite is a type of clay mineral (orthosilicate mineral) and belongs to the smectite group. The chemical composition is Na0.66Si8(Al3.34Mg0.66)O20(OH)4. The crystal system is monoclinic. It is one of the clay minerals. Saponite is a Mg-rich species of the montmorillonite family of clay minerals. The composition is Na0.66(Si7.34Al0.66)Mg6O20(OH)4, but the species in which a part of Mg is replaced with Al is aluminum saponite, and it contains 0.4 ppm of silicon and 0.4 ppm of magnesium from this clay mineral. 2 ppm is eluted, but no aluminum is eluted. Aluminum is a condensation product with a large molecular weight, and exists as an aluminum orthosilicate ion in which some of the Si atoms in the orthosilicate ion are replaced with Al3+ ions.The orthosilicate forms an octahedron of aluminum and alumina, and the orthosilicate captures the + ions. It is thought that because many hands of oxygen extend outward, oxygen and water combine, and only ortho-silicic acid is eluted into water as an oligomeric cyclic hexamer of ortho-silicic acid.

Also, orthosilicic acid in seawater is unstable, but it can be stabilized by mutating into a cyclic multimer. Since the stable form is a cyclic hexamer, for example, the oligomer has strong hydrophilicity, and water molecules are bound to and attached to the inside and around the oligomer, forming a strong colloid. I can understand.

In addition, in FIG. 4, (a) shows a microscopic photograph of squeezed yuzu juice, and (b) shows a microscopic photograph of tomato skin.

FIG. 5 and FIG. 9(b) are diagrams showing the process pattern of energy evolution of micellar colloidal. Umo (registered trademark) is generally based on colloids of 2 nm or less in size, and is a group of colloids gathered together in a rhythmic rhythm, including micellar colloid particles (hereinafter referred to as MC) of 400 to 1000 nm, and hollow particles. When type MC and three-layer type MC are formed, aggregation progresses, and particles of 3 to 6 μm are formed, multi-layer type MC is formed. The aqueous silicon solution of the present invention preferably has a multilayered micellar colloidal configuration based on nano-sized silicon particles of about 2 nm. In other words, it is considered that a form that follows changes in the surrounding environment has been secured. On the other hand, in the comparative example shown in FIG. 9(a), which is a conventional raw material concentrated solution of sea cucumber, the particles are not aggregated.

Therefore, the functionality of umo (registered trademark), for example, the permeability, can be improved. Furthermore, in the mechanical field, it is effective in extending the life of cutting blades and tools, and in the living environment, it can contribute to the possibility of long-term preservation of water and the preservation of vegetables.

FIG. 6 is a schematic diagram of the water generator 1, which is an apparatus for producing functional water. The water generator 1 includes an anti-firestone tower 2, a GO tower 3, an RC tower 4, and a faucet 5.

The water generator 1 is a cylindrical container filled with natural firestone, and comes into contact with the firestone when water is passed through the firestone tower 2. In addition, filtered raw water (tap water) is introduced into the anti-flame stone tower 2, and the functional water that has passed through the anti-flame stone tower 2 is transferred to the GO tower 3. The GO tower 3 is filled with spherical bisque bodies (ceramic fired bodies) manufactured using anti-firestone powder. This unglazed body uses 70% by weight or more of anti-flinder powder adjusted to a relatively coarse particle size of, for example, 50 micrometers or more and 550 micrometers or less, and uses clay as a binder to form a desired shape such as a substantially spherical shape. It is formed by high temperature sintering at about 1000°C to 1500°C.

The functional water that has passed through the GO tower 3 is returned from the RC tower 4 to the circulation tank. In addition, if the water generator 1 has a structure equipped with the RC tower 4, it may be used for improving raw water quality or for silicon aqueous solution applications (for example, industrial applications where the particle size of water aggregates is smaller and high permeability is required). Depending on the case, the water is passed through the RC tower 4 and then returned to the water generator 1 or a tank (not shown). The RC tower 4 is filled with spherical fired bodies manufactured using firestone powder. This fired body is formed by, for example, using 97% by weight of anti-flint powder with a size of 50 micrometers or more and 550 micrometers or less on the surface of an unglazed body, and further adding 3% by weight of synthetic glue and an appropriate amount of silicon water. A glaze containing anti-firestone is applied and fired at a firing temperature of 1000°C to 1500°C.

A method for producing a water-soluble silicon solution is shown in the flowchart shown in FIG. First, tap water is procured as raw water (ST-1) and filtered for clarification (ST-2). Specifically, it is the removal of chlorine and impurities. Subsequently, the water is treated in the water generator 1 and circulated (ST-3). For example, water flow treatment is performed for a predetermined period of time using anti-flinder layer treatment. Thereafter, silicon derived from minerals or plants is added to the treated water (ST-4), and the water is stored for a period of time or mixed if necessary (ST-5). Mixing is performed under specified pressure and/or time control (ST-6). Through this exemplary process, a desired multilayered micelle colloid is constructed (ST-7), and then the product is taken out (ST-8). A water-soluble silicon solution is then obtained.

As described above, the ortho-silicic acid aqueous solution forms a cyclic hexamer and is structurally stabilized. In the hexamer of ortho-silicic acid, the outer surface is more negatively charged than in the monomer, dimer, and other low-mer forms, and water molecules are bonded to or attracted to the outer surface, causing ortho-silicic acid to become a nucleus. It forms an aggregate of water. Therefore, the water molecules in the solvent coexist in both a state in which the water molecules are floating alone and a state in which they gather to some extent to form an aggregate. Therefore, in pure water, water molecules form aggregates using only hydrogen bonds. In an ortho-silicic acid aqueous solution, as shown in Figure 4, ortho-silicic acid hexamers are bonded together by chemical bonds, and water molecules are electrically bonded around the ortho-silicic acid hexamers, so it is different from pure water. Forms a stronger aggregate. On the other hand, the water form of the ortho-silicic acid aqueous solution has a smaller diameter aggregate than that of tap water. The network structure of water in the liquid phase has an extremely short lifespan, constantly changing to another network structure, and a specific structure is not memorized. , the permeability becomes higher. For example, the diameter of an aggregate of tap water is about 200 nm, but the diameter of an aggregate of water in an aqueous solution is 80 to 100 nm. That is, it increases the penetrating power (improvement of permeability).

As shown in FIG. 4, water molecules form hydrogen bonds with each other because the hydrogen atoms of one water molecule are attracted to the oxygen atoms of other water molecules. However, in an ortho-silicic acid aqueous solution, ortho-silicic acid is present, and the hydrogen atoms of water molecules are more strongly attracted to the oxygen atoms of ortho-silicic acid than to the oxygen atoms of other water molecules. Therefore, in an ortho-silicic acid aqueous solution, as shown in Figure 2 or Figure 3 (a) and (b), ortho-silicic acid and water molecules are strongly bonded to form a primary aggregate with a diameter of 2 nm or less. . In addition, in the ortho-silicic acid aqueous solution, it is thought that due to the presence of many primary aggregates, the primary aggregates with a diameter of 2 nm or less aggregate with each other to form secondary aggregates with a diameter of about 0.4 to 1.2 nm. FIG. 5 is a diagram for explaining primary aggregates and secondary aggregates of an ortho-silicate aqueous solution. In FIG. 5, (A) shows spherical secondary aggregates, and (B) to (D) illustrates a donut-shaped secondary aggregate. As shown in FIG. 4, orthosilicic acid in seawater is unstable and is stabilized in the form of a cyclic polymer. The most stable form is the cyclic hexamer. Oligomers have strong hydrophilic properties, and water molecules are bound to and attached to the inside and surroundings of the oligomers, forming a strong colloidal structure.

FIG. 7 is a diagram showing a silicon aqueous solution production system 01, which is composed of a raw water tank 02, a circulation tank 03, a storage tank 04, a silicon aqueous solution outlet 05, and a water generator 1. Add silicon as indicated by the arrow.

In addition (1), the ortho-silicic acid aqueous solution mainly contains cyclic hexameric ortho-silicic acid, and has the characteristic that water molecules gather around the cyclic-hexameric ortho-silicic acid in a hexagonal structure. In addition, in the ortho-silicic acid aqueous solution according to the present embodiment, water molecules gather around the cyclic hexamer ortho-silicic acid in a hexagonal structure, so that the specific gravity and dielectric constant have different characteristics from tap water. It is considered to have the following.

In addition, as (2), the ortho-silicate aqueous solution (water-soluble silicon) is water-soluble silicon derived from quartzite produced by contact with quartz, or water-soluble silicon derived from plants, and the ortho-silicate aqueous solution (water-soluble silicon) is The content of water-soluble silicon can be increased, and orthosilicic acid can easily form hexamers. Preferably, the ortho-silicic acid aqueous solution to which plant-derived water-soluble silicon has been added is housed in a device equipped with a vibration device, and by imparting unique vibrations and/or stirring, the hexamer of ortho-silicic acid is produced. It is thought that it can contribute to the formation of

The present invention is capable of various embodiments and modifications without departing from the broad spirit and scope of the invention. Further, the embodiments described above are for explaining the present invention, and do not limit the scope of the present invention.

1 Water generator 2 Firestone tower 3 GO tower 4 RC tower 5 Faucet 01 Silicon aqueous solution generation system 02 Raw water tank 03 Circulation tank 04 Storage tank 05 Outlet

Claims (6)

A step of producing a water-soluble silicon solution by adding silicon extracted from a mineral or plant containing quartz to functional water containing water-soluble silicic acid,
The water-soluble silicon solution has a multilayered micelle colloidal structure aggregated based on nano silicon particles.
A method for producing a water-soluble silicon solution, characterized in that: A step of adding silicon extracted from minerals or plants containing quartz to functional water containing water-soluble silicic acid;
A step of bringing the silicon-added functional water into contact with an unglazed body using 70% by weight or more of anti-firestone powder, shaped into a desired shape such as a roughly spherical shape using clay as a binder, and sintered at 1000°C to 1500°C. and,
A glaze containing anti-flint, made by using 97% by weight of anti-flint powder and adding 3% by weight of synthetic glue and an appropriate amount of silicon water, was applied to the surface of the unglazed body and fired at 1000°C to 1500°C. a step of contacting the fired body with the functional water that has been in contact with the bisque fired body to obtain a water-soluble silicon solution;
Equipped with
The aqueous silicon solution contains orthosilicic acid that forms oligomeric hexamers.
A method for producing a water-soluble silicon solution, characterized by: The functional water includes water containing anti-flinder rock, igneous rock, or rock-derived silicic acid, or hot spring water or spring water.
The method for producing a water-soluble silicon solution according to claim 1 or 2. Contains 8000 mass ppm or more of silicate ions,
The method for producing a water-soluble silicon solution according to claim 1 or 2. Contains 0.8% by mass or more and 0.93% by mass or less of silicon,
The method for producing a water-soluble silicon solution according to claim 1 or 2. Contains amorphous silicon of mineral or plant origin,
The method for producing a water-soluble silicon solution according to claim 1 or 2.