JP7267235B2 - ホウ素化合物に基づく新規の軟質材料の合成および最適化方法 - Google Patents
ホウ素化合物に基づく新規の軟質材料の合成および最適化方法 Download PDFInfo
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- JP7267235B2 JP7267235B2 JP2020090442A JP2020090442A JP7267235B2 JP 7267235 B2 JP7267235 B2 JP 7267235B2 JP 2020090442 A JP2020090442 A JP 2020090442A JP 2020090442 A JP2020090442 A JP 2020090442A JP 7267235 B2 JP7267235 B2 JP 7267235B2
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- metal salt
- anion
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- boron
- organic
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- 238000005457 optimization Methods 0.000 title description 6
- 230000015572 biosynthetic process Effects 0.000 title description 2
- 238000003786 synthesis reaction Methods 0.000 title description 2
- 150000001639 boron compounds Chemical class 0.000 title 1
- 239000007779 soft material Substances 0.000 title 1
- 239000003792 electrolyte Substances 0.000 claims description 50
- 229910052751 metal Inorganic materials 0.000 claims description 43
- 239000002184 metal Substances 0.000 claims description 43
- 150000001450 anions Chemical class 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 36
- 150000003839 salts Chemical class 0.000 claims description 36
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 35
- 229910052796 boron Inorganic materials 0.000 claims description 33
- 239000011159 matrix material Substances 0.000 claims description 30
- 239000007787 solid Substances 0.000 claims description 30
- 239000000203 mixture Substances 0.000 claims description 21
- 125000001424 substituent group Chemical group 0.000 claims description 18
- 239000007784 solid electrolyte Substances 0.000 claims description 16
- 150000002892 organic cations Chemical class 0.000 claims description 14
- 150000001768 cations Chemical class 0.000 claims description 13
- -1 salt anion Chemical class 0.000 claims description 9
- 230000002194 synthesizing effect Effects 0.000 claims description 6
- 229910052794 bromium Inorganic materials 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 229910052731 fluorine Inorganic materials 0.000 claims description 5
- 229910052740 iodine Inorganic materials 0.000 claims description 5
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 claims description 4
- 125000004428 fluoroalkoxy group Chemical group 0.000 claims description 4
- 125000003709 fluoroalkyl group Chemical group 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 125000004122 cyclic group Chemical group 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 125000004104 aryloxy group Chemical group 0.000 claims description 2
- 229910000085 borane Inorganic materials 0.000 claims description 2
- 125000004407 fluoroaryl group Chemical group 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 claims 2
- ZXMGHDIOOHOAAE-UHFFFAOYSA-N 1,1,1-trifluoro-n-(trifluoromethylsulfonyl)methanesulfonamide Chemical compound FC(F)(F)S(=O)(=O)NS(=O)(=O)C(F)(F)F ZXMGHDIOOHOAAE-UHFFFAOYSA-N 0.000 claims 1
- 238000001816 cooling Methods 0.000 claims 1
- 150000003949 imides Chemical class 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 229910001416 lithium ion Inorganic materials 0.000 description 4
- 238000012216 screening Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 229910001251 solid state electrolyte alloy Inorganic materials 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- 150000001638 boron Chemical class 0.000 description 2
- 230000005518 electrochemistry Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000001802 infusion Methods 0.000 description 2
- XKFPGUWSSPXXMF-UHFFFAOYSA-N tributyl(methyl)phosphanium Chemical compound CCCC[P+](C)(CCCC)CCCC XKFPGUWSSPXXMF-UHFFFAOYSA-N 0.000 description 2
- GCRCSLNXFKCFHB-UHFFFAOYSA-N triethyl(hexyl)azanium Chemical compound CCCCCC[N+](CC)(CC)CC GCRCSLNXFKCFHB-UHFFFAOYSA-N 0.000 description 2
- CUIGTYKJLRVARY-UHFFFAOYSA-N triethyl(hexyl)phosphanium Chemical compound CCCCCC[P+](CC)(CC)CC CUIGTYKJLRVARY-UHFFFAOYSA-N 0.000 description 2
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 1
- IDTCZPKYVMKLRZ-UHFFFAOYSA-N 1-(2-methoxyethyl)-1-methylpyrrolidin-1-ium Chemical compound COCC[N+]1(C)CCCC1 IDTCZPKYVMKLRZ-UHFFFAOYSA-N 0.000 description 1
- PXELHGDYRQLRQO-UHFFFAOYSA-N 1-butyl-1-methylpyrrolidin-1-ium Chemical compound CCCC[N+]1(C)CCCC1 PXELHGDYRQLRQO-UHFFFAOYSA-N 0.000 description 1
- NIHOUJYFWMURBG-UHFFFAOYSA-N 1-ethyl-1-methylpyrrolidin-1-ium Chemical compound CC[N+]1(C)CCCC1 NIHOUJYFWMURBG-UHFFFAOYSA-N 0.000 description 1
- OGLIVJFAKNJZRE-UHFFFAOYSA-N 1-methyl-1-propylpiperidin-1-ium Chemical compound CCC[N+]1(C)CCCCC1 OGLIVJFAKNJZRE-UHFFFAOYSA-N 0.000 description 1
- YQFWGCSKGJMGHE-UHFFFAOYSA-N 1-methyl-1-propylpyrrolidin-1-ium Chemical compound CCC[N+]1(C)CCCC1 YQFWGCSKGJMGHE-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004992 Ionic Liquid Crystal Substances 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- BXHHZLMBMOBPEH-UHFFFAOYSA-N diethyl-(2-methoxyethyl)-methylazanium Chemical compound CC[N+](C)(CC)CCOC BXHHZLMBMOBPEH-UHFFFAOYSA-N 0.000 description 1
- KSRKBDUROZKZBR-UHFFFAOYSA-N diethyl-methyl-propylazanium Chemical compound CCC[N+](C)(CC)CC KSRKBDUROZKZBR-UHFFFAOYSA-N 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910003480 inorganic solid Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 238000002898 library design Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- TZWFFXFQARPFJN-UHFFFAOYSA-N triethyl(methyl)phosphanium Chemical compound CC[P+](C)(CC)CC TZWFFXFQARPFJN-UHFFFAOYSA-N 0.000 description 1
- QMKRJORUUNAPBZ-UHFFFAOYSA-N trimethyl(propan-2-yl)phosphanium Chemical compound CC(C)[P+](C)(C)C QMKRJORUUNAPBZ-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0562—Solid materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/24—Alkaline accumulators
- H01M10/26—Selection of materials as electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0082—Organic polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0088—Composites
- H01M2300/0091—Composites in the form of mixtures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Dispersion Chemistry (AREA)
- Secondary Cells (AREA)
- Conductive Materials (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16/424,876 US11502333B2 (en) | 2019-05-29 | 2019-05-29 | Method for synthesizing novel soft materials based on boron compounds |
| US16/424,876 | 2019-05-29 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2020194772A JP2020194772A (ja) | 2020-12-03 |
| JP2020194772A5 JP2020194772A5 (https=) | 2022-11-15 |
| JP7267235B2 true JP7267235B2 (ja) | 2023-05-01 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2020090442A Active JP7267235B2 (ja) | 2019-05-29 | 2020-05-25 | ホウ素化合物に基づく新規の軟質材料の合成および最適化方法 |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US11502333B2 (https=) |
| JP (1) | JP7267235B2 (https=) |
| CN (1) | CN112018434B (https=) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11811020B2 (en) | 2021-02-02 | 2023-11-07 | Toyota Motor Engineering & Manufacturing North America, Inc. | Electrolytes with ultrahigh closo-borate concentrations |
| US11728511B2 (en) * | 2021-03-01 | 2023-08-15 | Toyota Motor Engineering & Manufacturing North America, Inc. | Uniform organic-ceramic composites including a hard-inorganic lithium ion electrolyte and a plurality of soft electrolytes, solid-state batteries including the same, and methods of preparing the same |
| JP7563373B2 (ja) * | 2021-12-28 | 2024-10-08 | トヨタ自動車株式会社 | 固体電解質、固体電解質の製造方法および全固体電池 |
| US12469884B2 (en) | 2022-06-22 | 2025-11-11 | Toyota Motor Engineering & Manufacturing North America, Inc. | Electrolytes with low cationic mobility activation energies |
| US20240106007A1 (en) * | 2022-09-28 | 2024-03-28 | Toyota Motor Engineering & Manufacturing North America, Inc. | Anodically stable and highly conducting borane solid state battery electrolytes |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017094250A1 (ja) | 2015-11-30 | 2017-06-08 | 日本ゼオン株式会社 | 非水系二次電池接着層用組成物、非水系二次電池用接着層および非水系二次電池 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4201839A (en) | 1978-11-01 | 1980-05-06 | Exxon Research And Engineering Co. | Cell containing an alkali metal anode, a solid cathode, and a closoborane and/or closocarborane electrolyte |
| AU2003901144A0 (en) * | 2003-03-13 | 2003-03-27 | Monash University School Of Chemistry | Room temperature ionic liquid electrolytes for lithium secondary batteries |
| CA2479589C (en) | 2003-09-04 | 2011-05-24 | Air Products And Chemicals, Inc. | Polyfluorinated boron cluster anions for lithium electrolytes |
| US7419623B2 (en) * | 2004-08-03 | 2008-09-02 | Air Products And Chemicals, Inc. | Proton conducting mediums for electrochemical devices and electrochemical devices comprising the same |
| US20070048605A1 (en) | 2005-08-23 | 2007-03-01 | Pez Guido P | Stable electrolyte counteranions for electrochemical devices |
| FR2935382B1 (fr) * | 2008-08-29 | 2010-10-08 | Centre Nat Rech Scient | Sel d'anion pentacylique et son utilisation comme electrolyte |
| EP2658026A1 (en) * | 2010-12-22 | 2013-10-30 | Contour Energy Systems, Inc. | Fluoride ion battery compositions |
| US20130078532A1 (en) * | 2011-09-27 | 2013-03-28 | Zonghai Chen | Non-aqueous electrolytes for lithium ion batteries |
| US9312566B2 (en) | 2012-08-02 | 2016-04-12 | Toyota Motor Engineering & Manufacturing North America, Inc. | Magnesium borohydride and its derivatives as magnesium ion transfer media |
| US9455473B1 (en) * | 2015-05-12 | 2016-09-27 | Toyota Motor Engineering & Manufacturing North America, Inc. | Ionic liquids for rechargeable magnesium battery |
| US10553897B2 (en) * | 2015-06-16 | 2020-02-04 | Governement Of The United States Of America, As Represented By The Secretary Of Commerce | Ambient temperature superionic conducting salt including metal cation and borate anion or carborate anion and process for making ambient temperature superionic conducting salt |
| US11479470B2 (en) | 2016-02-18 | 2022-10-25 | The Regents Of The University Of California | Three-dimensional boron-rich clusters |
| US20180277913A1 (en) * | 2017-03-23 | 2018-09-27 | Nanotek Instruments, Inc. | Non-flammable Quasi-Solid Electrolyte and Lithium Secondary Batteries Containing Same |
| CN110679008B (zh) * | 2017-06-02 | 2022-09-20 | 纳米技术仪器公司 | 形状适形的碱金属-硫电池 |
| US10673095B2 (en) * | 2017-09-13 | 2020-06-02 | Toyota Motor Engineering & Manufacturing North America, Inc. | Electrochemical cells having ionic liquid-containing electrolytes |
-
2019
- 2019-05-29 US US16/424,876 patent/US11502333B2/en active Active
-
2020
- 2020-05-18 CN CN202010417398.4A patent/CN112018434B/zh active Active
- 2020-05-25 JP JP2020090442A patent/JP7267235B2/ja active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017094250A1 (ja) | 2015-11-30 | 2017-06-08 | 日本ゼオン株式会社 | 非水系二次電池接着層用組成物、非水系二次電池用接着層および非水系二次電池 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2020194772A (ja) | 2020-12-03 |
| CN112018434A (zh) | 2020-12-01 |
| US11502333B2 (en) | 2022-11-15 |
| US20200381777A1 (en) | 2020-12-03 |
| CN112018434B (zh) | 2024-04-30 |
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