JP7228085B2 - Active ester compound and curable composition - Google Patents

Description

The present invention provides an active ester compound having a low elastic modulus under high temperature conditions in a cured product and excellent adhesion to copper foil, etc., a curable composition containing the same, a cured product thereof, a semiconductor sealing material and a printed wiring board. Regarding.

In the technical field of insulating materials used in semiconductors, multilayer printed circuit boards, etc., the development of new resin materials that meet these market trends is required as various electronic components become thinner and smaller. As a performance required for a semiconductor encapsulating material, a low elastic modulus under high temperature conditions is required in order to improve reflowability. In addition to this, in addition to the heat resistance and moisture absorption resistance of the cured product and the adhesion to copper foil, etc., as a countermeasure for increasing the speed and frequency of signals, the dielectric constant and dielectric loss tangent value of the cured product must be low. It is also important that there is no change in physical properties such as glass transition temperature (Tg) as reliability under the environment, and that cure shrinkage and coefficient of linear expansion are low as countermeasures against warpage and distortion accompanying thinning.

A technique of using di(1-naphthyl)isophthalate as a curing agent for epoxy resin is known as a resin material having excellent heat resistance, dielectric properties, etc. in a cured product (see Patent Document 1 below). The epoxy resin composition described in Patent Document 1 uses di(α-naphthyl)isophthalate as an epoxy resin curing agent, so that it can be compared with the case of using a conventional epoxy resin curing agent such as a phenol novolac resin. Although the values of the dielectric constant and dielectric loss tangent of the cured product are certainly low, the elastic modulus of the cured product under high temperature conditions does not satisfy the level required in recent years, and the adhesion to copper foil etc. was also low. . In addition, due to its high melt viscosity, its use is limited in applications requiring low melt viscosity, such as semiconductor encapsulation materials.

JP-A-2003-82063

Therefore, the problem to be solved by the present invention is an active ester compound having a low elastic modulus under high temperature conditions in a cured product and excellent adhesion to copper foil or the like, a curable composition containing the same, and a cured product thereof , to provide a semiconductor encapsulating material and a printed wiring board.

As a result of intensive studies by the present inventors to solve the above problems, the active ester compound, which is a diester compound of a dicyclopentadiene addition type phenol compound and an aromatic monocarboxylic acid or an acid halide thereof, can be used in a cured product under high temperature conditions. The inventors have found that the elastic modulus is low under low pressure, the adhesiveness to copper foil and the like is high, and the melt viscosity is also low, leading to the completion of the present invention.

That is, the present invention has the following structural formula (1)

（式中Ｒ^１はそれぞれ独立して脂肪族炭化水素基、アルコキシ基、ハロゲン原子、アリール基、アラルキル基の何れかである。ｍは０又は１～４の整数であり、ｎは０又は１である。）
で表されるジヒドロキシ化合物（ａ１）と芳香族モノカルボン酸又はその酸ハロゲン化物（ａ２）とのジエステル化物である活性エステル化合物に関する。

(In the formula, each R ¹ is independently an aliphatic hydrocarbon group, an alkoxy group, a halogen atom, an aryl group, or an aralkyl group; m is an integer of 0 or 1 to 4; n is 0 or 1; is.)
It relates to an active ester compound that is a diester of a dihydroxy compound (a1) represented by and an aromatic monocarboxylic acid or an acid halide thereof (a2).

The present invention further relates to a curable composition containing the active ester compound and a curing agent.

The present invention further relates to a cured product of said curable composition.

The present invention further relates to a semiconductor encapsulant using the curable composition.

The present invention further relates to a printed wiring board using the curable composition.

According to the present invention, it is possible to provide an active ester compound whose cured product has a low elastic modulus under high temperature conditions, a curable composition containing the same, a cured product thereof, a semiconductor encapsulating material, and a printed wiring board.

1 is a GPC chart of active ester compound (1) obtained in Example 1. FIG.

The present invention will be described in detail below.
The active ester compound of the present invention has the following structural formula (1)

（式中Ｒ^１はそれぞれ独立して脂肪族炭化水素基、アルコキシ基、ハロゲン原子、アリール基、アラルキル基の何れかである。ｍは０又は１～４の整数であり、ｎは０又は１である。）
で表されるジヒドロキシ化合物（ａ１）と芳香族モノカルボン酸又はその酸ハロゲン化物（ａ２）とのジエステル化物である。

(In the formula, each R ¹ is independently an aliphatic hydrocarbon group, an alkoxy group, a halogen atom, an aryl group, or an aralkyl group; m is an integer of 0 or 1 to 4; n is 0 or 1; is.)
It is a diester of a dihydroxy compound (a1) represented by and an aromatic monocarboxylic acid or an acid halide thereof (a2).

In the dihydroxy compound (a1), each ^R1 is independently an aliphatic hydrocarbon group, an alkoxy group, a halogen atom, an aryl group, or an aralkyl group. The aliphatic hydrocarbon group may be linear or branched, and may have an unsaturated bond in its structure. Specifically, alkyl groups such as methyl group, ethyl group, propyl group, butyl group, pentyl group and hexyl group; cycloalkyl groups such as cyclohexyl group; unsaturated groups such as vinyl group, allyl group and propargyl group. A bond-containing group and the like are included. Examples of the alkoxy group include a methoxy group, an ethoxy group, a propyloxy group, and a butoxy group. The halogen atom includes a fluorine atom, a chlorine atom, a bromine atom, and the like. Examples of the aryl group include a phenyl group, a naphthyl group, an anthryl group, and structural sites in which the aromatic nuclei of these groups are substituted with the aliphatic hydrocarbon group, alkoxy group, halogen atom, or the like. Examples of the aralkyl group include a benzyl group, a phenylethyl group, a naphthylmethyl group, a naphthylethyl group, and structural sites in which the aromatic nuclei of these groups are substituted with the alkyl group, alkoxy group, halogen atom, or the like. The dihydroxy compound (a1) may be used alone or in combination of two or more compounds having different types of substituents or different substitution positions.

The aromatic monocarboxylic acid or its acid halide (a2) is benzenecarboxylic acid, naphthalenecarboxylic acid, and an aliphatic hydrocarbon group, an alkoxy group, a halogen atom, an aryl group, an aralkyl group, or the like substituted on the aromatic nucleus of these acids. Examples include compounds having one or more groups, and acid halides thereof. One of these may be used alone, or two or more of them may be used in combination. Among them, benzenecarboxylic acid or a halide thereof is preferable because the elastic modulus of the cured product under high temperature conditions is low and it becomes an active ester compound having excellent curability. Therefore, a more preferable structure of the active ester compound of the present invention is represented by the following structural formula (2).

（式中Ｒ^１、Ｒ^２はそれぞれ独立して脂肪族炭化水素基、アルコキシ基、ハロゲン原子、アリール基、アラルキル基の何れかである。ｍは０又は１～４の整数であり、ｎは０又は１であり、ｋは０又は１～５の整数である。）

(wherein R ¹ and R ² are each independently an aliphatic hydrocarbon group, an alkoxy group, a halogen atom, an aryl group, or an aralkyl group; m is an integer of 0 or 1 to 4; n is 0 or 1, and k is 0 or an integer from 1 to 5.)

The reaction between the dihydroxy compound (a1) and the aromatic monocarboxylic acid or its acid halide (a2) is carried out, for example, by a method of heating and stirring at a temperature of about 40 to 65° C. in the presence of an alkali catalyst. can be done. You may perform reaction in an organic solvent as needed. After completion of the reaction, if desired, the reaction product may be purified by washing with water, reprecipitation, or the like.

Examples of the alkali catalyst include sodium hydroxide, potassium hydroxide, triethylamine, pyridine and the like. Each of these may be used alone, or two or more of them may be used in combination. Also, it may be used as an aqueous solution of about 3.0 to 30%. Among them, sodium hydroxide or potassium hydroxide with high catalytic ability is preferable.

Examples of the organic solvent include ketone solvents such as acetone, methyl ethyl ketone, methyl isobutyl ketone, and cyclohexanone; acetic ester solvents such as ethyl acetate, butyl acetate, cellosolve acetate, propylene glycol monomethyl ether acetate, and carbitol acetate; cellosolve, and butyl carbitol; carbitol solvents such as toluene, aromatic hydrocarbon solvents such as toluene and xylene, dimethylformamide, dimethylacetamide, N-methylpyrrolidone and the like. Each of these may be used alone, or two or more of them may be used as a mixed solvent.

The reaction ratio between the dihydroxy compound (a1) and the aromatic monocarboxylic acid or acid halide thereof (a2) is such that the desired active ester compound can be obtained in a high yield. It is preferable that the ratio of the aromatic monocarboxylic acid or its acid halide (a2) is 0.95 to 1.05 mol per 1 mol of the total of the above.

In the present invention, as the raw material for the dihydroxy compound (a1), a compound partially containing an oligomer component (a3) represented by the following structural formula (3), in which t is an integer of 1 or more, may be used.

（式中Ｒ^１はそれぞれ独立して脂肪族炭化水素基、アルコキシ基、ハロゲン原子、アリール基、アラルキル基の何れかである。ｍは０又は１～４の整数であり、ｎは０又は１であり、ｔは０又は１以上の整数である。）

(In the formula, each R ¹ is independently an aliphatic hydrocarbon group, an alkoxy group, a halogen atom, an aryl group, or an aralkyl group; m is an integer of 0 or 1 to 4; n is 0 or 1; and t is an integer of 0 or 1 or more.)

In this case, the content of the dihydroxy compound (a1) in the raw material of the dihydroxy compound (a1) is preferably 50% or more, more preferably 65 to 90%, because the effects of the present invention are sufficiently exhibited. is preferably in the range of Further, the content of the component in which t is 1 in the structural formula (3) in the raw material of the dihydroxy compound (a1) is preferably in the range of 5 to 30%. Furthermore, the sum of the dihydroxy compound (a1) in the raw material of the dihydroxy compound (a1) and the component where t is 1 in the structural formula (3), that is, when t is 0 or 1 in the structural formula (3) The sum of one component is preferably 70% or more, more preferably 85% or more. The average value of t in structural formula (3) in the dihydroxy compound (a1) raw material is preferably in the range of 0.05 to 0.8. The average value of t is a calculated value calculated from the number average molecular weight (Mn) of the raw material of the dihydroxy compound (a1).

In the present invention, the content and molecular weight of each component in the raw material of the dihydroxy compound (a1) and the content and molecular weight of each component in the active ester composition described later are determined from the area ratio of the GPC chart measured under the following conditions. It is a calculated value.

Measuring device: "HLC-8320 GPC" manufactured by Tosoh Corporation,
Column: Guard column "HXL-L" manufactured by Tosoh Corporation
+ "TSK-GEL G4000HXL" manufactured by Tosoh Corporation
+ "TSK-GEL G3000HXL" manufactured by Tosoh Corporation
+ "TSK-GEL G2000HXL" manufactured by Tosoh Corporation
+ "TSK-GEL G2000HXL" manufactured by Tosoh Corporation
Detector: RI (differential refractometer)
Data processing: "GPC Workstation EcoSEC-WorkStation" manufactured by Tosoh Corporation
Measurement conditions: Column temperature 40°C
Developing solvent Tetrahydrofuran
Flow rate 1.0 ml/min Standard: The following monodisperse polystyrene having a known molecular weight was used according to the measurement manual of "GPC-8320".
(Polystyrene used)
"A-500" manufactured by Tosoh Corporation
"A-1000" manufactured by Tosoh Corporation
"A-2500" manufactured by Tosoh Corporation
"A-5000" manufactured by Tosoh Corporation
"F-1" manufactured by Tosoh Corporation
"F-2" manufactured by Tosoh Corporation
"F-4" manufactured by Tosoh Corporation
"F-10" manufactured by Tosoh Corporation
"F-20" manufactured by Tosoh Corporation
"F-40" manufactured by Tosoh Corporation
"F-80" manufactured by Tosoh Corporation
"F-128" manufactured by Tosoh Corporation
Sample: 1.0% by mass of tetrahydrofuran solution in terms of resin solid content filtered through a microfilter (50 μl)

When the dihydroxy compound (a1) raw material partially contains the oligomer component (a3), the reaction ratio between the dihydroxy compound (a1) raw material and the aromatic monocarboxylic acid or its acid halide (a2) is the desired Since the active ester compound can be obtained in a high yield, the amount of the aromatic monocarboxylic acid or its acid halide (a2) is 0.95 to 1 mol per 1 mol of the hydroxyl groups in the raw material of the dihydroxy compound (a1). A ratio of 0.05 mol is preferred.

When the dihydroxy compound (a1) raw material partially contains the oligomer component (a3), the active ester compound of the present invention is a compound represented by the following structural formula (4), wherein t is an integer of 1 or more. It is obtained as an active ester composition containing a polyester compound.

（式中Ｒ^１、Ｒ^２はそれぞれ独立して脂肪族炭化水素基、アルコキシ基、ハロゲン原子、アリール基、アラルキル基の何れかである。ｍは０又は１～４の整数であり、ｎは０又は１であり、ｋは０又は１～５の整数であり、ｔは０又は１以上の整数である。）

(wherein R ¹ and R ² are each independently an aliphatic hydrocarbon group, an alkoxy group, a halogen atom, an aryl group, or an aralkyl group; m is an integer of 0 or 1 to 4; n is 0 or 1, k is 0 or an integer of 1 to 5, and t is 0 or an integer of 1 or more.)

In this case, the content of the diester compound in the active ester composition, that is, the content of the active ester compound of the present invention is preferably 50% or more, 65 to 95%, since the effect of the present invention is fully exhibited. % range is preferred. Further, it is preferable that the content of the component in which t is 1 in the structural formula (4) is in the range of 5 to 30% in the active ester composition. Furthermore, the sum of the active ester compound in the active ester composition and the components in which t is 1 in the structural formula (4), that is, the sum of the components in which t is 0 or 1 in the structural formula (4) is It is preferably 70% or more, more preferably 85% or more. The content of each component in the active ester composition is a value calculated from the area ratio of the GPC chart measured under the above conditions. The average value of t in the active ester composition is preferably in the range of 0.05 to 0.8. The average value of t is a calculated value calculated from the number average molecular weight (Mn) of the active ester composition.

The melt viscosity of the active ester compound or the active ester composition of the present invention is preferably in the range of 0.01 to 50 dPa s at 150° C. measured with an ICI viscometer in accordance with ASTM D4287. A range of 0.01 to 5 dPa·s is particularly preferred.

The curable composition of the present invention may contain other active ester compounds in combination with the active ester compound or the active ester composition of the present invention. Examples of the other active ester compounds include an esterified product of a compound having one phenolic hydroxyl group in the molecular structure and an aromatic polycarboxylic acid or an acid halide thereof, the dihydroxy compound (a1), and the oligomer component (a3). Esterified products of compounds having two or more phenolic hydroxyl groups other than aromatic monocarboxylic acids or acid halides thereof, compounds having one phenolic hydroxyl group in the molecular structure, aromatic polycarboxylic acids or acid halides thereof And esters of compounds having two or more phenolic hydroxyl groups in the molecular structure, aromatic polycarboxylic acids or acid halides thereof, compounds having two or more phenolic hydroxyl groups in the molecular structure and aromatic monocarboxylic acids or their Examples include esterified products of acid halides.

When the other active ester compound is used, the effect of the present invention is sufficiently exhibited, so the ratio of the active ester compound of the present invention or the active ester composition to the total of all active ester compounds is 70% by mass or more. and more preferably 80% by mass or more. The melt viscosity of the active ester compound as a whole is preferably in the range of 0.01 to 50 dPa·s, particularly preferably in the range of 0.01 to 5 dPa·s. The melt viscosity of the compound is a value at 150° C. measured with an ICI viscometer according to ASTM D4287.

The curable composition of the present invention contains the above active ester compound and a curing agent. The curing agent may be any compound that can react with the active ester compound, and various compounds can be used without particular limitation. An example of a curing agent includes, for example, an epoxy resin.

Examples of the epoxy resin include phenol novolak type epoxy resin, cresol novolak type epoxy resin, naphthol novolak type epoxy resin, bisphenol novolak type epoxy resin, biphenol novolak type epoxy resin, bisphenol type epoxy resin, biphenyl type epoxy resin, and triphenolmethane. type epoxy resin, tetraphenolethane type epoxy resin, dicyclopentadiene-phenol addition reaction type epoxy resin, phenol aralkyl type epoxy resin, naphthol aralkyl type epoxy resin, and the like.

In the curable composition of the present invention, the mixing ratio of the active ester compound and the curing agent is not particularly limited, and can be appropriately adjusted according to the desired performance of the cured product. As an example of formulation when an epoxy resin is used as a curing agent, the total amount of functional groups in the active ester compound is 0.7 to 1.5 mol with respect to the total 1 mol of epoxy groups in the curable composition. It is preferable that the ratio be

The curable composition of the invention may further contain other resin components. Other resin components include, for example, diaminodiphenylmethane, diethylenetriamine, triethylenetetramine, diaminodiphenylsulfone, isophoronediamine, imidazole, BF ₃ -amine complexes, amine compounds such as guanidine derivatives; Amide compounds such as polyamide resin synthesized from ethylenediamine; phthalic anhydride, trimellitic anhydride, pyromellitic anhydride, maleic anhydride, tetrahydrophthalic anhydride, methyltetrahydrophthalic anhydride, methylnadic anhydride, hexahydrophthalic anhydride acids, acid anhydrides such as methylhexahydrophthalic anhydride; cyanate ester resins; bismaleimide resins; benzoxazine resins; styrene-maleic anhydride resins; Examples thereof include polyphosphate esters and phosphate-carbonate copolymers. Each of these may be used alone, or two or more of them may be used in combination. The blending ratio of these other resin components is not particularly limited, and can be appropriately adjusted according to the desired cured product performance and the like.

The curable composition of the present invention may optionally contain various additives such as curing accelerators, flame retardants, inorganic fillers, silane coupling agents, mold release agents, pigments and emulsifiers.

Examples of the curing accelerator include phosphorus compounds, tertiary amines, imidazole compounds, pyridine compounds, organic acid metal salts, Lewis acids, and amine complex salts. Among them, triphenylphosphine is a phosphorus compound and 1,8-diazabicyclo-[5.4.0]-undecene (DBU ), the imidazole compound is preferably 2-ethyl-4-methylimidazole, and the pyridine compound is preferably 4-dimethylaminopyridine.

The flame retardant is, for example, red phosphorus, monoammonium phosphate, diammonium phosphate, triammonium phosphate, ammonium phosphate such as ammonium polyphosphate, inorganic phosphorus compounds such as phosphoric acid amide; compound, phosphinic acid compound, phosphine oxide compound, phosphorane compound, organic nitrogen-containing phosphorus compound, 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, 10-(2,5-dihydroxyphenyl )-10H-9-oxa-10-phosphaphenanthrene-10-oxide, 10-(2,7-dihydroxynaphthyl)-10H-9-oxa-10-phosphaphenanthrene-10-oxide and other cyclic organic phosphorus organic phosphorus compounds such as compounds and derivatives obtained by reacting them with compounds such as epoxy resins and phenolic resins; triazine compounds, cyanuric acid compounds, isocyanuric acid compounds, nitrogen-based flame retardants such as phenothiazine; silicone oils, silicone rubbers, silicones silicone-based flame retardants such as resins; and inorganic flame retardants such as metal hydroxides, metal oxides, metal carbonate compounds, metal powders, boron compounds, and low-melting glass. When using these flame retardants, it is preferably in the range of 0.1 to 20% by mass in the curable composition.

The inorganic filler is blended, for example, when the curable composition of the present invention is used as a semiconductor sealing material. Examples of the inorganic filler include fused silica, crystalline silica, alumina, silicon nitride, and aluminum hydroxide. Among them, the fused silica is preferable because it allows a larger amount of inorganic filler to be blended. The fused silica may be crushed or spherical, but spherical fused silica is mainly used in order to increase the amount of fused silica and to suppress the increase in the melt viscosity of the curable composition. is preferred. Furthermore, in order to increase the compounding amount of spherical silica, it is preferable to appropriately adjust the particle size distribution of spherical silica. The filling rate is preferably in the range of 0.5 to 95 parts by mass per 100 parts by mass of the curable composition.

In addition, when the curable composition of the present invention is used as a conductive paste, a conductive filler such as silver powder or copper powder can be used.

As described in detail above, the active ester compound of the present invention and the curable composition containing the same are characterized by having a low elastic modulus in the cured product under high-temperature conditions and excellent adhesion to copper foil and the like. In addition, it has excellent solubility in general-purpose organic solvents, heat resistance, water absorption resistance, low curing shrinkage, excellent dielectric properties, and low melt viscosity. is also sufficiently high. Therefore, it can be widely used for electronic materials such as printed wiring boards, semiconductor sealing materials, and resist materials, as well as for paints, adhesives, moldings, and the like.

When the curable composition of the present invention is used for printed wiring boards or build-up adhesive films, it is generally preferred to mix and dilute an organic solvent. Examples of the organic solvent include methyl ethyl ketone, acetone, dimethylformamide, methyl isobutyl ketone, methoxypropanol, cyclohexanone, methyl cellosolve, ethyl diglycol acetate, and propylene glycol monomethyl ether acetate. The type and blending amount of the organic solvent can be appropriately adjusted according to the environment in which the curable composition is used. is preferable, and it is preferable to use it at a ratio of 40 to 80% by mass of non-volatile matter. For build-up adhesive film applications, ketone solvents such as acetone, methyl ethyl ketone, and cyclohexanone; acetic ester solvents such as ethyl acetate, butyl acetate, cellosolve acetate, propylene glycol monomethyl ether acetate, and carbitol acetate; and carbitols such as cellosolve and butyl carbitol. It is preferable to use solvents such as aromatic hydrocarbon solvents such as toluene and xylene, dimethylformamide, dimethylacetamide, N-methylpyrrolidone, etc., and it is preferable to use such a proportion that the non-volatile content is 30 to 60% by mass.

In addition, a method for producing a printed wiring board using the curable composition of the present invention includes, for example, impregnating a reinforcing base material with the curable composition and curing to obtain a prepreg, which is overlapped with a copper foil and heated. A method of crimping can be mentioned. Examples of the reinforcing base material include paper, glass cloth, glass nonwoven fabric, aramid paper, aramid cloth, glass mat, and glass roving cloth. Although the amount of the curable composition to be impregnated is not particularly limited, it is usually preferable to adjust the resin content in the prepreg to 20 to 60% by mass.

When the curable composition of the present invention is used as a semiconductor encapsulant, it is generally preferred to incorporate an inorganic filler. The semiconductor encapsulating material can be prepared by mixing formulations using, for example, an extruder, a kneader, rolls, or the like. A method of molding a semiconductor package using the obtained semiconductor encapsulating material includes, for example, molding the semiconductor encapsulating material using a cast molding machine, a transfer molding machine, an injection molding machine, etc. A method of heating for 2 to 10 hours under certain conditions can be mentioned, and a semiconductor device, which is a molded product, can be obtained by such a method.

EXAMPLES Next, the present invention will be specifically described with reference to examples and comparative examples. Descriptions of "parts" and "%" in the examples are based on mass unless otherwise specified.

Measurement conditions of GPC Measurement equipment: "HLC-8320 GPC" manufactured by Tosoh Corporation,
Column: Guard column "HXL-L" manufactured by Tosoh Corporation
+ "TSK-GEL G4000HXL" manufactured by Tosoh Corporation
+ "TSK-GEL G3000HXL" manufactured by Tosoh Corporation
+ "TSK-GEL G2000HXL" manufactured by Tosoh Corporation
+ "TSK-GEL G2000HXL" manufactured by Tosoh Corporation
Detector: RI (differential refractometer)
Data processing: "GPC Workstation EcoSEC-WorkStation" manufactured by Tosoh Corporation
Measurement conditions: Column temperature 40°C
Developing solvent Tetrahydrofuran
Flow rate 1.0 ml/min Standard: The following monodisperse polystyrene having a known molecular weight was used according to the measurement manual of "GPC-8320".
(Polystyrene used)
"A-500" manufactured by Tosoh Corporation
"A-1000" manufactured by Tosoh Corporation
"A-2500" manufactured by Tosoh Corporation
"A-5000" manufactured by Tosoh Corporation
"F-1" manufactured by Tosoh Corporation
"F-2" manufactured by Tosoh Corporation
"F-4" manufactured by Tosoh Corporation
"F-10" manufactured by Tosoh Corporation
"F-20" manufactured by Tosoh Corporation
"F-40" manufactured by Tosoh Corporation
"F-80" manufactured by Tosoh Corporation
"F-128" manufactured by Tosoh Corporation
Sample: 1.0% by mass of tetrahydrofuran solution in terms of resin solid content filtered through a microfilter (50 μl)

Melt Viscosity Measurement Method In the examples of the present application, the melt viscosity of the active ester compound or composition was measured by an ICI viscometer at 150° C. according to ASTM D4287.

Example 1 Production of Active Ester Composition (1) A flask equipped with a thermometer, a dropping funnel, a condenser, a fractionating tube, and a stirrer was charged with a dicyclopentadiene-added phenol compound (m is 0 in the structural formula (3) above). , and the average value of t calculated from the number average molecular weight (Mn) is 0.2. rice field. Next, 218 g of benzoyl chloride was charged and dissolved while the inside of the system was replaced with nitrogen under reduced pressure. 0.8 g of tetrabutylammonium bromide was added, and while purging with nitrogen gas, the inside of the system was controlled at 60° C. or lower, and 420 g of a 20% aqueous sodium hydroxide solution was added dropwise over 3 hours. After the dropwise addition was completed, the mixture was allowed to react while stirring for 1 hour. After completion of the reaction, the reaction mixture was allowed to stand still for liquid separation, and the aqueous layer was removed. After adding water to the remaining organic layer and stirring and mixing for about 15 minutes, the mixture was allowed to stand for liquid separation, and the aqueous layer was removed. After repeating this operation until the pH of the aqueous layer reached 7, water and toluene were removed by decanter dehydration to obtain an active ester composition (1). A GPC chart of the active ester composition (1) is shown in FIG. The content of the diester compound in the active ester composition (1) calculated from the area ratio of the GPC chart is 77%, and the content of the component corresponding to the compound in which t is 1 in the structural formula (4) is 15. %Met. Moreover, the melt viscosity of the active ester composition (1) was 1.48 dPa·s.

Comparative Production Example 1 Production of active ester compound (1′) A flask equipped with a thermometer, a dropping funnel, a condenser, a fractionating tube and a stirrer was charged with 202 g of isophthaloyl chloride and 1250 g of toluene, and the system was decompressed and replaced with nitrogen. while it was dissolved. Then, 288 g of 1-naphthol was charged and dissolved while replacing the pressure in the system with nitrogen. 0.6 g of tetrabutylammonium bromide was added, and while purging with nitrogen gas, the inside of the system was controlled at 60° C. or less, and 420 g of a 20% aqueous sodium hydroxide solution was added dropwise over 3 hours. After the dropwise addition was completed, the mixture was allowed to react while stirring for 1 hour. After completion of the reaction, the reaction mixture was allowed to stand still for liquid separation, and the aqueous layer was removed. After adding water to the remaining organic layer and stirring and mixing for about 15 minutes, the mixture was allowed to stand for liquid separation, and the aqueous layer was removed. After repeating this operation until the pH of the aqueous layer reached 7, water and toluene were removed by decanter dehydration to obtain an active ester compound (1′). The melt viscosity of the active ester compound (1') was 0.65 dPa·s.

Example 2 and Comparative Example 1
A curable composition was produced by blending each component in the ratio shown in Table 1 below, and an evaluation test was performed in the following manner. Table 1 shows the results.

Measurement of Storage Modulus under High Temperature Conditions The curable composition was poured into a mold and molded at a temperature of 175° C. for 10 minutes using a press. The molded product was removed from the mold and cured at a temperature of 175° C. for 5 hours to obtain a cured product.
A test piece having a size of 5 mm×54 mm×2.4 mm was cut out from the cured product. Using a viscoelasticity measuring device (“Solid viscoelasticity measuring device RSAII” manufactured by Rheometric Co., Ltd.), the storage modulus at 260° C. was measured using a rectangular tension method, a frequency of 1 Hz, and a heating temperature of 3° C./min. It was measured.

Evaluation of copper foil adhesion Using a vacuum forming machine (“MHPC-VF” manufactured by Meiki Seisakusho Co., Ltd.), the copper foil and the copper foil are cured under the conditions of a mold temperature of 175 ° C., a molding pressure of 0.4 MPa, and a curing time of 90 minutes. A laminate of objects was produced.
A test piece having a width of 7 mm and a length of 200 mm was cut out from the laminate obtained above, and the peel strength of the copper foil was measured according to JIS K 6854 at a peel rate of 50 mm/min.

Epoxy resin (*1): cresol novolac type epoxy resin (manufactured by DIC Corporation "N-655-EXP-S", epoxy equivalent 202 g/equivalent)

Claims (6)

Structural formula (3) below

(In the formula, each R ¹ is independently an aliphatic hydrocarbon group, an alkoxy group, a halogen atom, an aryl group, or an aralkyl group; m is an integer of 0 or 1 to 4; n is 0 or 1; , and the average value of t is in the range of 0.05 to 0.8.)
An active ester composition which is an ester of a hydroxy compound (a1) represented by and an aromatic monocarboxylic acid or an acid halide thereof (a2). 2. The active ester composition according to claim 1, wherein the content of the dihydroxy compound in the hydroxy compound (a1) is 65 to 90% by mass. A curable composition comprising the active ester composition according to claim 1 or 2 and a curing agent. A cured product of the curable composition according to claim 3 . A semiconductor sealing material using the curable composition according to claim 3 . A printed wiring board using the curable composition according to claim 3 .

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