JP7220205B2 - Coated food fried in oil, method for producing the same, and method for producing food material for fried in oil - Google Patents

Coated food fried in oil, method for producing the same, and method for producing food material for fried in oil Download PDF

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JP7220205B2
JP7220205B2 JP2020510838A JP2020510838A JP7220205B2 JP 7220205 B2 JP7220205 B2 JP 7220205B2 JP 2020510838 A JP2020510838 A JP 2020510838A JP 2020510838 A JP2020510838 A JP 2020510838A JP 7220205 B2 JP7220205 B2 JP 7220205B2
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貴史 伊東
和子 小島
謙太朗 入江
通宏 榊原
総一郎 樋渡
恭一 岩田
亮佑 高須
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Nisshin Seifun Welna Inc
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L17/00Food-from-the-sea products; Fish products; Fish meal; Fish-egg substitutes; Preparation or treatment thereof
    • A23L17/40Shell-fish
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/10General methods of cooking foods, e.g. by roasting or frying

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Description

本発明は、具材の表面に衣が付着した衣付き油ちょう食品、及びその製造中間体であるである油ちょう用食品素材に関する。 TECHNICAL FIELD The present invention relates to a battered food product in which batter is attached to the surface of ingredients, and a food material for frying which is an intermediate in the production thereof.

天ぷら、フライ食品などの衣付き油ちょう食品は、各種の食材からなる具材の表面に衣材を付着させたもの(油ちょう用食品素材)を油ちょうすることで得られる。油ちょう用食品素材を油ちょうすることによって、具材は、衣材により直接揚げ油に触れることなく加熱されてジューシーに仕上がり、衣材は、揚げ油に直接触れることで水分が蒸発してサクサクとした乾いた食感の衣となる。その衣のサクサク感は、衣付き油ちょう食品の美味しさに大きく寄与している。 Battered foods such as tempura and fried foods are obtained by frying ingredients (food materials for frying) in which batter is attached to the surface of ingredients composed of various ingredients. By frying the food material for frying with oil, the ingredients are heated without being in direct contact with the frying oil due to the coating material, and are finished juicy, and the coating material is crispy due to the evaporation of the water content due to the direct contact with the frying oil. It becomes a batter with a dry texture. The crispness of the batter greatly contributes to the deliciousness of the battered fried food.

しかしながら、衣のサクサクとした好ましい食感が味わえるのは調理直後に限られ、調理後に時間が経過すると、具材の水分が衣に移行し、衣のサクサクとした食感が失われ、商品価値が低下するという問題があった。特に近年は、核家族化、個食化の進展などを背景に、自然解凍あるいは電子レンジなどの加熱調理器を用いて加熱調理するだけで簡単に喫食状態にすることが可能な、いわゆるレディトゥイートな調理済みの冷凍衣付き油ちょう食品の需要が急伸しているところ、このような冷凍衣付き油ちょう食品においては、具材から衣への水分移行に起因する食感低下の問題がより顕在化する傾向がある。 However, the crispy texture of the batter can be enjoyed only immediately after cooking, and as time passes after cooking, the moisture in the ingredients moves into the batter, and the crispy batter loses its commercial value. There was a problem that the Especially in recent years, against the background of the trend toward nuclear families and individual meals, so-called ready-to-eat foods that can be easily eaten by simply defrosting naturally or cooking with a heat cooker such as a microwave oven. While the demand for frozen batter-cooked fried foods is rapidly increasing, such frozen batter-covered foods have a problem of reduced texture caused by moisture transfer from ingredients to batter. tend to become

衣付き油ちょう食品の改良技術に関し、特許文献1には、具材としての魚介類の表面に、泡立てられた卵白と小麦粉とを含む一次バッターを付着させ、さらに、該一次バッターの外側に、小麦粉を含む二次バッターを層状に付着させて油ちょうした後、冷凍して天ぷら冷凍食品を製造する方法が記載されている。特許文献1によれば、前記一次バッターは、油ちょう後にその内部に気泡が無数に存在し、具材から出てきた水分(離水)を吸収する作用を有するので、特許文献1記載の方法により得られた天ぷら冷凍食品は、凍結、解凍、再油ちょう後も型崩れや衣の剥がれが無く、口当たりがよいとされている。 Regarding the technology for improving fried food with batter, Patent Document 1 discloses that a primary batter containing whipped egg white and wheat flour is attached to the surface of seafood as an ingredient, and further, on the outside of the primary batter, It describes a method of producing a frozen tempura food by attaching a layer of a secondary batter containing wheat flour, frying it, and then freezing it. According to Patent Document 1, the primary batter has numerous air bubbles inside it after frying, and has the effect of absorbing water (separation) coming out of the ingredients, so the method described in Patent Document 1 The resulting frozen tempura food does not lose its shape or peel off even after being frozen, thawed, and re-boiled, and is said to be palatable.

特許文献2には、活きた魚介類又は甲殻類をその鮮度と旨みを保持したままフライ製品や天ぷら製品などに加工する方法として、具材としての魚介類又は甲殻類の表面に卵白液を付着させて冷凍し、その冷凍物を遠隔地の加工工場に搬送し、該加工工場で解凍してから、バッター液及びパン粉又は天ぷら衣を付着させて油ちょうする方法が記載されている。特許文献2によれば、冷凍前に具材に付着させた卵白液の作用により、その後の冷凍保存中における具材の乾燥が防止されるので、高品質のまま長期間冷凍保存できるとされている。 In Patent Document 2, as a method of processing live seafood or crustaceans into fried products, tempura products, etc. while maintaining their freshness and taste, egg white liquid is attached to the surface of seafood or crustaceans as ingredients. It describes a method in which the frozen product is frozen, transported to a remote processing plant, thawed at the processing plant, and then fried with batter liquid and bread crumbs or tempura batter. According to Patent Document 2, the action of the egg white liquid adhered to the ingredients before freezing prevents the ingredients from drying out during subsequent frozen storage, so that high-quality ingredients can be frozen for a long period of time. there is

特許文献3には、フライ食品などの食品の内部に存在する水分が、より水分含量の低い表面部(例えば天ぷらの衣の部分)に移行することを防止して、その食品が本来有しているクリスピーな食感が損なわれないようにし得る技術として、加熱調理前又は加熱調理後の食品に、ゼインが溶解したアルコール溶液を噴霧、浸漬、塗布するなどして付着させた後、庫内温度が所定温度に設定された恒温庫内で10分程度乾燥させて、該アルコール溶液の付着箇所に疎水性の被覆層を形成する技術が記載されている。 In Patent Document 3, moisture present inside food such as fried food is prevented from migrating to a surface portion with a lower moisture content (for example, tempura batter), and the food originally has As a technique that can prevent the crispy texture of food from being damaged, an alcohol solution in which zein is dissolved is sprayed, immersed, or applied to the food before or after cooking. is dried for about 10 minutes in a thermostat set at a predetermined temperature to form a hydrophobic coating layer on the portion where the alcohol solution adheres.

特開昭59-59181号公報JP-A-59-59181 特開2004-350561号公報JP-A-2004-350561 特開平7-327610号公報JP-A-7-327610

前述した従来技術は、衣付き油ちょう食品の保存中、特に冷凍保存中における具材から衣への水分移行の防止効果の点で改良の余地があり、衣付き油ちょう食品に従来技術を適用しても、一定の保存期間を経て喫食した際には、衣のサクサク感が失われているおそれがある。具材から衣への水分移行の防止に有効な技術は未だ提供されていない。 The above-mentioned conventional technology has room for improvement in terms of the effect of preventing moisture from moving from the ingredients to the batter during storage of the battered fried food, especially during frozen storage. Even so, there is a possibility that the crispness of the batter may be lost when eaten after a certain storage period. No technique has yet been provided that is effective in preventing migration of moisture from ingredients to coating.

本発明の課題は、具材から衣への水分移行が生じ難く、油ちょうしてから時間が経過しても衣のサクサクとした良好な食感が得られる、衣付き油ちょう食品及びその製造方法並びに油ちょう用食品素材の製造方法を提供することである。 An object of the present invention is to provide a batter-coated food product in which water is less likely to migrate from the ingredients to the batter, and a crispy batter with a good texture can be obtained even after a long time has passed since the batter is fried, and a method for producing the same. Another object of the present invention is to provide a method for producing a food material for frying with oil.

本発明は、具材の表面に衣が付着した衣付き油ちょう食品であって、前記具材と前記衣との間に空間が介在し、該空間を該具材から該衣にわたって、タンパク質を含む柱状構造体が延在している衣付き油ちょう食品である。 The present invention is a battered fried food in which batter is attached to the surface of ingredients, wherein a space is interposed between the ingredients and the batter, and the space is spread from the ingredients to the batter to produce protein. It is a battered fried food in which a columnar structure containing is extended.

また本発明は、具材の表面に衣が付着した衣付き油ちょう食品の製造方法であって、具材の表面に衣材が付着した油ちょう用食品素材を製造し、該油ちょう用食品素材を油ちょうして衣付き油ちょう食品を得る工程を有し、前記油ちょう用食品素材の製造工程が、具材の表面に、タンパク質及びアルコールを含有する前処理液を付着させた後、該前処理液の付着部分に水性液を付与する前処理工程と、前記前処理工程を経た具材の表面に衣材を付着させる工程とを有する、衣付き油ちょう食品の製造方法である。 Further, the present invention relates to a method for producing a battered food with batter attached to the surface of ingredients, comprising: producing a food material for frying in which the batter is attached to the surface of ingredients; It has a step of obtaining a batter-coated food by frying the material, and the manufacturing process of the food material for frying includes attaching a pretreatment liquid containing protein and alcohol to the surface of the ingredients, and A method for producing a battered fried food, comprising a pretreatment step of applying an aqueous liquid to a portion to which the pretreatment liquid is applied, and a step of attaching a coating material to the surface of the ingredients that have undergone the pretreatment step.

また本発明は、具材の表面に衣材が付着した油ちょう用食品素材の製造方法であって、具材の表面に、タンパク質及びアルコールを含有する前処理液を付着させた後、該前処理液の付着部分に水性液を付与する前処理工程と、前記前処理工程を経た具材の表面に衣材を付着させる工程とを有する、油ちょう用食品素材の製造方法である。 Further, the present invention is a method for producing a food material for frying in which a coating material is attached to the surface of the ingredients, wherein after attaching a pretreatment liquid containing protein and alcohol to the surface of the ingredients, A method for producing a food material for frying, comprising a pretreatment step of applying an aqueous liquid to a portion to which the treatment liquid is applied, and a step of attaching a coating material to the surface of the ingredient that has undergone the pretreatment step.

図1(a)は、本発明の製造方法で得られた油ちょう用食品素材の一実施形態の模式的な断面図、図1(b)は、該食品素材を油ちょうして得られた本発明の衣付き油ちょう食品の一実施形態の模式的な断面図である。FIG. 1(a) is a schematic cross-sectional view of one embodiment of a food material for frying obtained by the production method of the present invention, and FIG. 1(b) is a book obtained by frying the food material. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic cross-sectional view of one embodiment of the fried food with batter of the invention; 図2は、本発明の衣付き油ちょう食品の一実施形態であるエビ天ぷらの長手方向中央位置での断面の図面代用写真である。FIG. 2 is a drawing-substituting photograph of a cross-section at the center position in the longitudinal direction of shrimp tempura, which is one embodiment of the battered fried food of the present invention. 図3(a)~図3(c)は、それぞれ、本発明の衣付き油ちょう食品の実施例のエビ天ぷらの長手方向中央位置での断面の図面代用写真、図3(d)~図3(h)は、それぞれ、比較例のエビ天ぷらの長手方向中央位置での断面の図面代用写真である。FIGS. 3(a) to 3(c) are photographs of cross-sections at the center position in the longitudinal direction of the shrimp tempura of the example of the fried food with batter of the present invention, and FIGS. 3(d) to 3(d) to FIG. (h) is a drawing-substituting photograph of a cross-section at the center position in the longitudinal direction of the shrimp tempura of the comparative example. 図4は、実施例2のエビ天ぷらの長手方向中央位置での断面のMRI画像である。FIG. 4 is an MRI image of the cross section of the shrimp tempura of Example 2 at the central position in the longitudinal direction.

本発明の衣付き油ちょう食品は、具材の表面に衣が付着したもので、具材の表面に衣材が付着した油ちょう用食品素材を製造し、該油ちょう用食品素材を油ちょうすることで得られる。以下、先ず、本発明の衣付き油ちょう食品の製造方法について説明する。 The batter-coated food of the present invention is a food with batter adhering to the surface of ingredients. obtained by doing Hereinafter, first, the method for producing the fried food with batter of the present invention will be described.

本発明の衣付き油ちょう食品の製造方法の主たる特徴の1つとして、その製造中間体である油ちょう用食品素材の製造工程が挙げられる。斯かる製造工程で実施される本発明の油ちょう用食品素材の製造方法は、衣材を付着する前の具材の表面に特定の前処理を施す点で特徴付けられる。斯かる前処理は、具材の表面に、タンパク質及びアルコールを含有する前処理液を付着させた後、該前処理液の付着部分に水性液を付与する工程(前処理工程)を有する。 One of the main features of the method for producing the battered fried food of the present invention is the production process of the food material for fried oil, which is a production intermediate thereof. The method for producing a food material for frying according to the present invention, which is carried out in such a production process, is characterized in that the surface of the ingredient is subjected to a specific pretreatment before the coating material is applied. Such a pretreatment includes a step (pretreatment step) of applying a pretreatment liquid containing protein and alcohol to the surface of the ingredient, and then applying an aqueous liquid to the portion to which the pretreatment liquid is attached.

本発明に係る前処理液に含有されるタンパク質は、油ちょう用食品素材を油ちょうして得られる衣付き油ちょう食品において、具材と衣との間に介在し、具材から衣への水分移行を阻害する機能を発揮するものであり、斯かる機能が発現することにより本発明の所定の効果が奏される。本発明の所定の効果がより確実に奏されるようにする観点から、本発明に係る前処理液に含有されるタンパク質としては、アルコール溶解性のタンパク質が好ましい。 The protein contained in the pretreatment liquid according to the present invention is interposed between the ingredients and the batter in the batter-coated food obtained by frying the food material for frying, and the water content from the ingredients to the batter It exhibits a function of inhibiting migration, and the expression of such a function produces the predetermined effects of the present invention. Alcohol-soluble proteins are preferable as proteins contained in the pretreatment liquid according to the present invention from the viewpoint of ensuring the desired effects of the present invention.

本発明に係る前処理液に含有されるタンパク質として特に好ましいのは、ゼイン(Zein)である。ゼインは、特許文献3に記載されているようにツエインなどとも呼ばれる。ゼインは、トウモロコシの主要なタンパク質であり、アルコール可溶性の貯蔵タンパク質であるプロラミン系物質である。 Zein is particularly preferable as the protein contained in the pretreatment liquid according to the present invention. Zein is also called zein as described in Patent Document 3. Zein is a major protein in maize, a prolamin-based substance that is an alcohol-soluble storage protein.

本発明に係る前処理液は、タンパク質とアルコールとを混合することで調製できる。タンパク質としてゼインを使用した場合、ゼインはアルコール可溶性であるので、本発明に係る前処理液は、タンパク質(ゼイン)が溶解したアルコール溶液である。前記アルコールとしては、例えば、エタノール、プロパノール等の炭素数2~3のアルコールが挙げられ、これらの1種を単独で又は2種以上を組み合わせて用いることができる。前記アルコールには、アルコールに加えてさらに水、純水、蒸留水、水道水、酸性水、アルカリ水、中性水等の水性成分を含む、含水アルコールが包含される。含水アルコール中のアルコール含有量は、通常70体積%以上である。これらのアルコールの中でも特に、操作性や環境性の点から、エタノール(含水エタノール)が好ましい。 The pretreatment liquid according to the present invention can be prepared by mixing protein and alcohol. When zein is used as the protein, since zein is alcohol-soluble, the pretreatment liquid according to the present invention is an alcohol solution in which protein (zein) is dissolved. Examples of the alcohol include alcohols having 2 to 3 carbon atoms such as ethanol and propanol, and these alcohols can be used alone or in combination of two or more. The alcohol includes water-containing alcohols containing aqueous components such as water, pure water, distilled water, tap water, acidic water, alkaline water, and neutral water in addition to alcohol. The alcohol content in the hydrous alcohol is usually 70% by volume or more. Among these alcohols, ethanol (hydrous ethanol) is particularly preferable from the viewpoint of operability and environmental friendliness.

本発明に係る前処理液において、タンパク質の含有量は特に制限されないが、衣付き油ちょう食品における具材から衣への水分移行をより確実に防止する観点から、該前処理後に具材に付着するタンパク質の量が、具材100質量部に対して固形分換算で、好ましくは0.5~10質量部、さらに好ましくは1~5質量部となるように調整することが好ましい。具材に対するタンパク質の付着量が少なすぎると、前処理を行う意義に乏しく、また、該付着量が多すぎると、衣付き油ちょう食品を食したときに膜っぽさが強くなって食感が低下すると共に、タンパク質臭が強くなって食味が低下するおそれがある。具材に対するタンパク質の付着量を前記の好ましい範囲とする観点から、本発明に係る前処理液におけるタンパク質の含有量は、該前処理液の全質量に対して、好ましくは5~35質量%、さらに好ましくは10~25質量%である。 In the pretreatment liquid according to the present invention, the content of protein is not particularly limited, but from the viewpoint of more reliably preventing the migration of moisture from the ingredients to the batter in the battered fried food, The amount of protein to be added is preferably 0.5 to 10 parts by mass, more preferably 1 to 5 parts by mass in terms of solid content per 100 parts by mass of ingredients. If the amount of protein adhered to the ingredients is too small, the pretreatment is meaningless, and if the amount adhered is too large, the food with batter will have a strong filmy texture when eaten. is lowered, the protein smell becomes stronger and the taste may be lowered. From the viewpoint of making the amount of protein adhered to ingredients within the above preferred range, the content of protein in the pretreatment liquid according to the present invention is preferably 5 to 35% by mass with respect to the total mass of the pretreatment liquid. More preferably, it is 10 to 25% by mass.

本発明に係る前処理液は、典型的には、タンパク質(好ましくはゼイン)及びアルコールのみを含有するが、必要に応じ、両成分以外の他の成分を含有してもよい。この他の成分としては、例えば、ゼイン以外のタンパク質、油脂、脂肪酸、各種調味料、香辛料、香料等が挙げられ、これらの1種を単独で又は2種以上を組み合わせて用いることができる。 The pretreatment liquid according to the present invention typically contains only protein (preferably zein) and alcohol, but may contain other components in addition to these components, if necessary. Other ingredients include, for example, proteins other than zein, oils and fats, fatty acids, various seasonings, spices, fragrances, and the like, and these can be used alone or in combination of two or more.

本発明に係る前処理工程において、具材の表面に前処理液を付着させる方法は特に制限されず、例えば、前処理液中に具材を浸漬する方法、スプレーなどの噴霧手段を用いて具材の表面に前処理液を噴霧する方法、刷毛などの塗布手段を用いて具材の表面に前処理液を塗布する方法が挙げられる。また前処理液は、典型的には、具材の表面全体に付着するが、具材の表面の一部に部分的に付着してもよい。本発明の所定の効果をより確実に奏させるようにする観点から、前処理液中に具材を浸漬する方法が好ましく、斯かる浸漬法により、具材の表面全体に前処理液を付着させることが好ましい。前処理液中に具材を浸漬する時間は制限されないが、特に長くとる必要はなく、通常は、前処理液中に具材を浸漬した後、速やかに引き上げる。 In the pretreatment process according to the present invention, the method of attaching the pretreatment liquid to the surface of the ingredients is not particularly limited. Examples include a method of spraying the pretreatment liquid onto the surface of the material, and a method of applying the pretreatment liquid to the surface of the ingredient using a coating means such as a brush. Also, the pretreatment liquid typically adheres to the entire surface of the ingredient, but may partially adhere to a part of the surface of the ingredient. From the viewpoint of ensuring the desired effect of the present invention, a method of immersing the ingredients in the pretreatment liquid is preferable. By such an immersion method, the pretreatment liquid is adhered to the entire surface of the ingredients. is preferred. Although the time for which the ingredients are immersed in the pretreatment liquid is not limited, it does not have to be particularly long, and usually the ingredients are immersed in the pretreatment liquid and then quickly pulled out.

本発明に係る前処理工程においては、浸漬法などにより具材の表面に前処理液を付着させた後、その前処理液の付着部分に水性液を付与する。この前処理液の付着部分に対する水性液の付与は、具材の表面に前処理液を付着させた後、速やかに行うことが好ましい。換言すれば、具材の表面に前処理液を付着させた後、その付着した前処理液が乾燥する前に、速やかに前処理液に水性液を付与することが好ましい。具材の表面に前処理液を付着させた時点から、その付着部分に水性液を付与するまでの時間は、好ましくは30秒以下、さらに好ましくは10秒以下である。 In the pretreatment process according to the present invention, after the pretreatment liquid is applied to the surface of the ingredients by an immersion method or the like, an aqueous liquid is applied to the portion where the pretreatment liquid is adhered. It is preferable that the application of the aqueous liquid to the portion to which the pretreatment liquid is applied is performed immediately after the pretreatment liquid is attached to the surface of the ingredients. In other words, it is preferable to apply the aqueous liquid to the pretreatment liquid immediately after the pretreatment liquid has adhered to the surface of the ingredients and before the adhered pretreatment liquid dries. The time from the time when the pretreatment liquid is attached to the surface of the ingredient until the time when the aqueous liquid is applied to the attached portion is preferably 30 seconds or less, more preferably 10 seconds or less.

このように、具材の表面における前処理液の付着部分に水性液を付与することにより、該前処理液が被膜化し、具材の表面に被膜が形成される。こうして形成された被膜は、前処理液中のタンパク質(好ましくはゼイン)を主体とするものであり、衣付き油ちょう食品において具材から衣への水分移行を防止する役割を担う。特許文献3記載の技術では、食品の表面にゼインを含む液を付着させた後、該食品を恒温庫内に収容して10分程度乾燥させることで該液を被膜化しているが、本発明者らの知見によれば、このような乾燥による被膜化法よりも、本発明で採用した被膜化法、即ち、乾燥させずに水性液の付与により被膜化する方法の方が、具材表面に均一な被膜が形成されやすく、結果として、衣付き油ちょう食品における具材から衣への水分移行が効果的に防止される。本発明に係る前処理工程において、具材表面の前処理液の付着部分に付着させる水性液としては、典型的には、水が用いられるが、前述した被膜化を阻害しない範囲で、水に他の成分を含有させてもよい。この水に含有可能な他の成分としては、例えば、酸、アルカリ、pH調整剤等が挙げられる。 By applying the aqueous liquid to the portion of the surface of the ingredient to which the pretreatment liquid is attached, the pretreatment liquid forms a film, and a film is formed on the surface of the ingredient. The film thus formed is mainly composed of the protein (preferably zein) in the pretreatment liquid, and plays a role in preventing moisture transfer from the ingredients to the coating in the coated fried food. In the technique described in Patent Document 3, after a liquid containing zein is attached to the surface of food, the food is placed in a constant temperature oven and dried for about 10 minutes to coat the liquid. According to the findings of those, the coating method adopted in the present invention, that is, the method of coating by applying an aqueous liquid without drying, rather than such a coating method by drying, is better for the ingredients surface. A uniform film is likely to be formed on the coating, and as a result, migration of moisture from the ingredients of the fried food with coating to the coating is effectively prevented. In the pretreatment step according to the present invention, water is typically used as the aqueous liquid to be adhered to the pretreatment liquid adhered portion of the surface of the ingredient, but water is used to the extent that it does not inhibit the film formation described above. Other ingredients may be included. Other components that can be contained in this water include, for example, acids, alkalis, and pH adjusters.

本発明に係る前処理工程において、具材表面の前処理液の付着部分に水性液を付与する方法は特に制限されず、例えば、水性液中に具材を浸漬する方法、スプレーなどの噴霧手段を用いて具材の表面に水性液を噴霧する方法、刷毛などの塗布手段を用いて具材の表面に水性液を塗布する方法が挙げられる。本発明の所定の効果をより確実に奏させるようにする観点から、前処理液が付着した具材を水性液中に浸漬する方法が好ましい。 In the pretreatment process according to the present invention, the method of applying the aqueous liquid to the pretreatment liquid adhered portion of the surface of the ingredients is not particularly limited, and examples include a method of immersing the ingredients in the aqueous liquid, and spraying means such as spraying. and a method of applying the aqueous liquid to the surface of the ingredients using a coating means such as a brush. From the viewpoint of ensuring the desired effects of the present invention, a method of immersing the ingredients to which the pretreatment liquid has adhered in an aqueous liquid is preferred.

本発明に係る前処理工程、即ち、具材の表面に前記前処理液を付着させた後、該前処理液の付着部分に水性液を付与する工程は、1回だけ行ってもよく、複数回行ってもよい。通常、前処理工程を複数回行うことで、前処理後に具材に付着するタンパク質の量が増加するので、衣付き油ちょう食品における具材から衣への水分移行防止効果が向上し得るが、斯かるタンパク質の付着量が多すぎると、前述した通り食味食感が低下するおそれがある。以上を考慮すると、本発明に係る前処理工程の実施回数は、好ましくは1~4回、さらに好ましくは2~4回である。 The pretreatment step according to the present invention, that is, the step of applying the aqueous liquid to the adhered portion of the pretreatment liquid after the pretreatment liquid is attached to the surface of the ingredient may be performed only once, or may be performed more than once. You can go back and forth. Usually, by performing the pretreatment process multiple times, the amount of protein that adheres to the ingredients after pretreatment increases, so the effect of preventing moisture migration from the ingredients to the batter in the battered food can be improved. If the amount of such attached protein is too large, the taste and texture may deteriorate as described above. Considering the above, the number of times the pretreatment step according to the present invention is performed is preferably 1 to 4 times, more preferably 2 to 4 times.

本発明の油ちょう用食品素材の製造方法においては、前述した前処理工程の実施後に、その前処理済み具材の表面に衣材を付着させる。これにより、目的とする油ちょう用食品素材が得られる。衣材としては、この種の衣付き油ちょう食品の製造に使用可能なものを特に制限なく用いることができる。一般的に衣付き油ちょう食品の衣材は、常温常圧で粉末状であり、具材に直接付着させて用いるブレダータイプと、常温常圧で液状であり、具材に絡めて用いるバッタータイプとに分類されるところ、本発明ではいずれのタイプも使用できる。特に、水分移行防止効果が顕著なことから、後者のバッタータイプの衣材が好ましい。バッタータイプの衣材は、穀粉類を主体とする原料粉に液体を添加し混合することで調製できる。この原料粉に添加する液体としては、水が一般的であるが、水以外の液体、例えば、牛乳、出し汁、煮汁などを用いることもでき、これらの1種を単独で又は2種以上を組み合わせて用いることができる。 In the method for producing a food material for frying according to the present invention, a coating material is attached to the surface of the pretreated ingredients after performing the pretreatment process described above. As a result, the desired food material for frying is obtained. As the coating material, any material that can be used in the production of this type of coated food fried in oil can be used without particular limitation. In general, the coating material for fried food with coating is powdery at normal temperature and pressure, and the blender type is used by directly adhering to the ingredients. Both types can be used in the present invention. In particular, the latter batter-type coating material is preferable because of its remarkable effect of preventing migration of moisture. A batter-type coating material can be prepared by adding a liquid to a raw material powder mainly composed of cereal flour and mixing the mixture. As the liquid to be added to the raw material flour, water is generally used, but liquids other than water, such as milk, soup stock, and broth, can also be used. can be used

本発明で用いる衣材は、典型的には、主成分として、穀粉及び澱粉からなる群から選択される1種以上の穀粉類を含有する。前記穀粉としては、例えば、薄力粉、中力粉、強力粉、小麦全粒粉、デュラムセモリナ等の小麦粉;ライ麦粉、米粉、コーンフラワー、コーングリッツ、大豆粉等が挙げられる。前記澱粉としては、例えば、馬鈴薯澱粉、小麦澱粉、コーンスターチ、ワキシーコーンスターチ、米澱粉、タピオカ澱粉等の未加工澱粉、及びこれら未加工澱粉に油脂加工、α化、エーテル化、エステル化、アセチル化、架橋処理、酸化処理等の処理の1つ以上を施した加工澱粉等が挙げられる。 The coating material used in the present invention typically contains, as a main component, one or more grain flours selected from the group consisting of grain flour and starch. Examples of the grain flour include soft flour, all-purpose flour, hard flour, whole wheat flour, durum semolina and other flours; rye flour, rice flour, corn flour, corn grits, soybean flour and the like. Examples of the starch include unprocessed starches such as potato starch, wheat starch, corn starch, waxy corn starch, rice starch and tapioca starch, and these unprocessed starches processed with oil, pregelatinized, etherified, esterified, acetylated, Examples include modified starch that has been subjected to one or more treatments such as cross-linking treatment and oxidation treatment.

本発明で用いる衣材は、穀粉類以外の他の成分を含有してもよい。この他の成分としては、例えば、膨張剤、卵黄粉、蛋白質、各種糖類、乳化剤、油脂、増粘剤、食塩、アミノ酸系あるいは核酸系調味料、着色料、香辛料、香料、ビタミン等の栄養成分、着色料等が挙げられ、製造する衣付き油ちょう食品の種類等に応じて、これらの1種を単独で又は2種以上を組み合わせて用いることができる。 The coating material used in the present invention may contain ingredients other than cereal flour. Other ingredients include, for example, swelling agents, egg yolk powder, proteins, various sugars, emulsifiers, fats and oils, thickeners, salt, amino acid-based or nucleic acid-based seasonings, coloring agents, spices, flavors, nutritional ingredients such as vitamins. , coloring agents, etc., and these can be used alone or in combination of two or more depending on the type of the battered fried food to be produced.

本発明は、様々な具材に適用できる。本発明が適用可能な具材としては、例えば、エビ、カニ、イカ、貝類などの魚介類;鶏、豚、牛、羊、ヤギ等の畜肉類;イモ類、カボチャ、ナス、ピーマン、レンコンなどの野菜類;シイタケなどのキノコ類が挙げられる。特にエビ、イカに好適である。 The present invention can be applied to various ingredients. Examples of ingredients to which the present invention can be applied include seafood such as shrimp, crab, squid, and shellfish; meat such as chicken, pork, beef, sheep, and goat; potatoes, pumpkin, eggplant, green pepper, lotus root, and the like. vegetables; and mushrooms such as shiitake mushrooms. Especially suitable for shrimp and squid.

前述した本発明の製造方法で得られた油ちょう用食品素材は、衣付き油ちょう食品の製造中間体であり、冷蔵又は冷凍保存が可能である。冷蔵又は冷凍保存した油ちょう用食品素材を常法に従って油ちょうすることで、衣付き油ちょう食品が得られる。 The food material for fried food obtained by the production method of the present invention described above is a production intermediate for the fried food with batter, and can be refrigerated or frozen. By frying the refrigerated or frozen food material for frying according to a conventional method, the batter-coated food can be obtained.

本発明の衣付き油ちょう食品の製造方法においては、油ちょう用食品素材を油ちょうする前に、必要に応じ、該食品素材の表面に打ち粉を付着させてもよい。前記打ち粉としては、この種の衣付き油ちょう食品の製造において打ち粉として通常用いられるものを特に制限なく用いることができ、例えば、衣材として使用可能な前記穀粉類、膨張剤、卵黄粉、蛋白質、各種糖類、乳化剤、油脂、増粘剤、食塩、アミノ酸系あるいは核酸系調味料、着色料、香辛料、香料、ビタミン等の栄養成分、着色料等が挙げられる。 In the method for producing the battered food material of the present invention, dusting powder may be adhered to the surface of the food material, if necessary, prior to frying the food material. As the dusting powder, those that are usually used as dusting powder in the production of this type of coated fried food can be used without particular limitation. , proteins, various sugars, emulsifiers, oils and fats, thickeners, salt, amino acid-based or nucleic acid-based seasonings, coloring agents, spices, flavors, nutrients such as vitamins, and coloring agents.

本発明の衣付き油ちょう食品の製造方法は、油ちょう用食品素材の油ちょう後に、その油ちょうによって得られた衣付き油ちょう食品を冷凍する工程を有していてもよい。衣付き油ちょう食品を冷凍して得られた冷凍衣付き油ちょう食品は、長期保存が可能である。冷凍方法は特に限定されず、急速冷凍でも緩慢冷凍でもよい。 The method for producing the fried food with batter of the present invention may have a step of freezing the food with batter obtained by frying the food material for frying with oil after frying. A frozen battered fried food obtained by freezing a battered fried food can be stored for a long period of time. The freezing method is not particularly limited, and quick freezing or slow freezing may be used.

図1(a)には、本発明の製造方法で得られた油ちょう用食品素材の一実施形態である油ちょう用食品素材1の模式的な断面、図1(b)は、本発明の衣付き油ちょう食品の一実施形態であり、該食品素材1を油ちょうして得られた衣付き油ちょう食品10の模式的な断面が示されている。油ちょう用食品素材1は、具材2、被膜3、打ち粉4及び衣材5を含んで構成され、内側から外側に向かってこの順で配されている。被膜3は、前述した前処理工程、即ち、「具材2の表面にタンパク質及びアルコールを含有する前処理液を付着させた後、該前処理液の付着部分に水性液を付与する工程」によって形成されたものであり、典型的には図1(a)に示すように、具材2の表面に密着している。尚、打ち粉4は前述したように任意成分であり、無くても構わない。 FIG. 1(a) shows a schematic cross section of the food material for frying 1, which is one embodiment of the food material for frying obtained by the production method of the present invention, and FIG. It is one embodiment of a food product coated with oil, and a schematic cross section of a food product coated with oil 10 obtained by cooking the food material 1 is shown. A food material 1 for frying is composed of an ingredient 2, a film 3, a dusting powder 4 and a coating material 5, which are arranged in this order from the inside to the outside. The film 3 is formed by the pretreatment step described above, that is, "the step of applying a pretreatment liquid containing protein and alcohol to the surface of the ingredient 2 and then applying an aqueous liquid to the portion where the pretreatment liquid is attached". It is formed, and typically adheres to the surface of the ingredients 2 as shown in FIG. 1(a). The dusting powder 4 is an optional component as described above, and may be omitted.

図1(a)に示す如き構成の油ちょう用食品素材1を常法に従って油ちょうすると、衣材5が衣50となり、図1(b)に示す如き構成の衣付き油ちょう食品10となる。衣付き油ちょう食品10においては、油ちょう用食品素材1における具材2が油ちょうによって収縮する結果、具材2と衣50との間(図示の形態では具材2と打ち粉4との間)に空間Sが形成される。具材2と衣50との間に空間Sが介在することにより、具材2から衣50への水分移行が効果的に防止されるため、衣付き油ちょう食品10は、その製造後(油ちょう後)から長時間が経過し、あるいは冷凍保存された場合でも、衣50がサクサクとした良好な食感を有し得る。しかも空間Sには、具材2から衣50にわたって柱状構造体30が延在して衣50を具材2側から支持しているため、衣50の保形性が向上して空間Sが潰れにくくなっている。このため、衣付き油ちょう食品10は、具材2から衣50への水分移行の防止効果を長期間にわたって安定的に発現し得る。柱状構造体30は、油ちょう前の油ちょう用食品素材1における被膜3が構造的に変化して形成されたもので、前処理液中のタンパク質(ゼイン)を主体とする。柱状構造体30は通常、具材2と衣50との間に複数形成されている。 When the food material 1 for frying having the structure shown in FIG. 1(a) is fried according to a conventional method, the coating material 5 becomes the coating 50, and the coated oil-frying food 10 having the structure shown in FIG. 1(b) is obtained. . In the battered food 10, as a result of the shrinkage of the ingredients 2 in the food material 1 for frying, there is a gap between the ingredients 2 and the batter 50 (in the illustrated form, between the ingredients 2 and the dusting powder 4). A space S is formed between them. By interposing the space S between the ingredients 2 and the coating 50, moisture migration from the ingredients 2 to the coating 50 is effectively prevented. Even after a long period of time has passed after cooking, or even when frozen, the batter 50 can have a good crunchy texture. Moreover, in the space S, the columnar structure 30 extends from the ingredient 2 to the coating 50 and supports the coating 50 from the ingredient 2 side, so the shape retention of the coating 50 is improved and the space S is crushed. It's getting harder. Therefore, the coated fried food 10 can stably exhibit the effect of preventing migration of moisture from the ingredients 2 to the coating 50 over a long period of time. The columnar structures 30 are formed by structurally changing the film 3 in the food material for frying 1 before frying, and are mainly composed of protein (zein) in the pretreatment liquid. A plurality of columnar structures 30 are usually formed between the ingredient 2 and the coating 50 .

図2には、本発明の衣付き油ちょう食品の一実施形態であり、本発明の製造方法によって実際に得られた衣付き油ちょう食品である、エビ天ぷらの断面の図面代用写真が2枚示されている。図2の2枚の断面写真は、それぞれ別のエビ天ぷらのもので、いずれの写真も、エビ天ぷらをその長手方向と交差する方向に切断した場合の切断面の写真である。図2の符号は、前述した図1の模式図における符号と対応している。図2から明らかなように、本発明の製造方法によって実際に製造されたエビ天ぷらには、具材2(エビ)と衣50との間に空間Sが形成されていると共に、空間Sに柱状構造体30が複数形成されており、各柱状構造体30が、衣50を具材2の表面から離間させた状態で支持する支柱として機能している。 FIG. 2 shows two drawings substitute photographs of the cross section of shrimp tempura, which is one embodiment of the fried food with batter of the present invention and is the food fried with batter actually obtained by the production method of the present invention. It is shown. The two cross-sectional photographs in FIG. 2 are of different shrimp tempura, and both photographs are photographs of a cut surface when the shrimp tempura is cut in a direction intersecting with the longitudinal direction. The reference numerals in FIG. 2 correspond to the reference numerals in the schematic diagram of FIG. 1 described above. As is clear from FIG. 2, in the shrimp tempura actually produced by the production method of the present invention, a space S is formed between the ingredient 2 (shrimp) and the batter 50, and the space S has a columnar shape. A plurality of structures 30 are formed, and each columnar structure 30 functions as a support supporting the coating 50 in a state of being separated from the surface of the ingredients 2 .

特に、比較的水分含量の多い具材は、油ちょう後の体積の収縮率が大きいため、衣付き油ちょう食品において具材と衣との間に空間が形成されやすく、図2に示す如き断面を持った衣付き油ちょう食品が得られやすい。そのような具材としては、例えば、魚介類の一種であるエビを例示できる。即ち本発明は、具材としてエビを用いた場合に特に有用である。 In particular, ingredients with a relatively high water content have a large volumetric shrinkage after frying, so a space is likely to be formed between the ingredients and the batter in the fried food with batter, and the cross section as shown in FIG. It is easy to obtain a battered fried food with a As such an ingredient, for example, shrimp, which is a type of seafood, can be exemplified. That is, the present invention is particularly useful when shrimp is used as an ingredient.

具材2から衣50への水分移行の防止と食味食感とのバランスの観点から、衣付き油ちょう食品10の断面における空間Sの占める割合(空間率)は、好ましくは5~50%、さらに好ましくは15~50%である。特に、1)衣付き油ちょう食品10の長手方向中央位置での断面、2)該長手方向中央位置から長手方向の一方向に3mm離間した位置での断面、及び3)該長手方向中央位置から長手方向の該一方向とは反対方向に3mm離間した位置での断面それぞれの前記空間率の平均値が、前記範囲にあることが好ましい。前記空間率は下記方法により測定される。前記空間率は、具材の種類、前述した前処理工程で使用する前処理液の組成、前処理液(タンパク質)の付着量などを適宜調整することで調整できる。 From the viewpoint of the balance between the prevention of moisture migration from the ingredients 2 to the coating 50 and the taste and texture, the ratio (space ratio) of the space S in the cross section of the fried food with coating 10 is preferably 5 to 50%. More preferably 15 to 50%. In particular, 1) a cross section at the longitudinal center position of the battered fried food 10, 2) a cross section at a position separated by 3 mm in one longitudinal direction from the longitudinal center position, and 3) from the longitudinal center position It is preferable that the average value of the void ratios of the respective cross sections at positions separated by 3 mm in the direction opposite to the one longitudinal direction is within the above range. The void ratio is measured by the following method. The void ratio can be adjusted by appropriately adjusting the type of ingredients, the composition of the pretreatment liquid used in the pretreatment step described above, the adhesion amount of the pretreatment liquid (protein), and the like.

<空間率の測定方法>
測定対象の衣付き油ちょう食品(例えばエビ天ぷら)を、具材の周囲に衣が存在する部位を含むように切断してサンプルとする。このサンプルについてMRI測定を行って切断面の画像を得、該画像を解析して、具材と衣との間に介在する空間の断面積(S1)を測定し、これと該画像における衣付き油ちょう食品の全断面積(S0)とから、次式により空間率(%)を算出する。空間率(%)=(S1/S0)×100
<Method for measuring void ratio>
A battered fried food (for example, shrimp tempura) to be measured is cut so as to include the portion where the batter exists around the ingredients to obtain a sample. MRI measurement is performed on this sample to obtain an image of the cut surface, the image is analyzed, the cross-sectional area (S1) of the space interposed between the ingredients and the coating is measured, and this and the coating in the image From the total cross-sectional area (S0) of the fried food, the void ratio (%) is calculated by the following formula. Space ratio (%) = (S1/S0) x 100

前記測定方法について補足すると、MRI測定に用いるサンプルは、核磁気共鳴(NMR)スペクトル測定用チューブ(直径25mm、ガラス製)に収容する。この測定用チューブをMRI測定装置(例えば、7.1-T micro-imaging system (DRX300WB, Bruker, Karlsruhe, Germany))にセットし、T2(スピン-スピン緩和時間又は横緩和時間)分布の測定を行う。画像解析には、例えば、ParaVision imaging software (ver. 3.0.2, Bruker) を用いることができる。尚、サンプルの大きさは、切断面と直交する方向の長さが2cm程度となるようにすることが好ましい。例えば、測定対象が一般的な形状のエビ天ぷらの場合、エビ天ぷらの長手方向中央位置を含む、同方向に約2cmにわたる部分(衣付き油ちょう食品の長手方向中央部)を切り出してサンプルとすることが好ましい。 To supplement the measurement method, a sample used for MRI measurement is placed in a nuclear magnetic resonance (NMR) spectrum measurement tube (25 mm in diameter, made of glass). This measurement tube is set in an MRI measurement device (eg, 7.1-T micro-imaging system (DRX300WB, Bruker, Karlsruhe, Germany)) to measure T2 (spin-spin relaxation time or transverse relaxation time) distribution. For image analysis, for example, ParaVision imaging software (ver. 3.0.2, Bruker) can be used. The size of the sample is preferably such that the length in the direction perpendicular to the cut surface is about 2 cm. For example, if the object to be measured is shrimp tempura with a general shape, cut out a portion that extends about 2 cm in the same direction, including the center position of the shrimp tempura in the longitudinal direction (central portion in the longitudinal direction of the fried food with batter) and use it as a sample. is preferred.

以下、実施例により本発明をさらに詳細に説明するが、本発明は以下の実施例に限定されるものではない。 EXAMPLES The present invention will be described in more detail below with reference to examples, but the present invention is not limited to the following examples.

〔実施例1~3〕
市販の天ぷら粉(日清フーズ(株)製、商品名「コツのいらない天ぷら粉」)100質量部に、水160質量部を添加、混合して、天ぷらバッター(衣材)を調製した。また、具材として殻を除いたエビ(ブラックタイガー、全長21-25cm)を用意した。また、エタノールの含有量が80体積%の含水エタノール80質量部と、ゼイン(小林香料(株)製、商品名「小林ツェインDP-N」)20質量部とを混合して、前処理材としての前処理液を調製した。
前処理液中にエビを浸漬して該エビの表面全体に前処理液を付着させた後、速やかに該エビの全体を水中に浸漬し、前処理済みのエビを得た(前処理工程)。具材(エビ)を前処理液又は水に浸漬する操作は、内部に前処理液又は水が収容された容器の該内部に具材全体を投入後、該内部から具材を速やかに引き上げることによって実施した。尚、実施例2及び3については、斯かる前処理工程を複数回連続して行った。こうして得られた前処理済みのエビに対し、その表面全体に加工澱粉(打ち粉)を付着させた後、さらに天ぷらバッターを付着させて、エビ天ぷらを製造した。
[Examples 1 to 3]
160 parts by mass of water was added to 100 parts by mass of commercially available tempura flour (manufactured by Nisshin Foods Co., Ltd., trade name “Tempura flour without tips”) and mixed to prepare a tempura batter (coating material). Shrimp (black tiger, total length 21-25 cm) was also prepared as an ingredient. In addition, 80 parts by mass of hydrous ethanol with an ethanol content of 80% by volume and 20 parts by mass of zein (manufactured by Kobayashi Perfumery Co., Ltd., trade name "Kobayashi Zein DP-N") are mixed and used as a pretreatment material. was prepared.
After immersing the shrimp in the pretreatment liquid to adhere the pretreatment liquid to the entire surface of the shrimp, the entire shrimp was rapidly immersed in water to obtain the pretreated shrimp (pretreatment step). . The operation of immersing the ingredients (shrimp) in the pretreatment liquid or water is to quickly pull up the ingredients from the inside of the container containing the pretreatment liquid or water after the entire ingredients are put into the inside of the container. conducted by Incidentally, in Examples 2 and 3, such a pretreatment step was continuously performed a plurality of times. After applying modified starch (dusting flour) to the entire surface of the pretreated shrimp thus obtained, tempura batter was further applied to produce shrimp tempura.

〔比較例1〕
前処理工程を実施しなかった以外は実施例1と同様にして、エビ天ぷらを製造した。
[Comparative Example 1]
Shrimp tempura was produced in the same manner as in Example 1, except that the pretreatment step was not performed.

〔比較例2~5〕
前処理工程を下記の工程に変更した以外は実施例1と同様にして、エビ天ぷらを製造した。
比較例2:エビの表面全体にスプレーで前処理液を噴霧した後、15分間風乾した。ここで用いた前処理材としての前処理液は、エタノールの含有量が80体積%の含水エタノール90質量部と、ゼイン(小林香料(株)製、商品名「小林ツェインDP-N」)10質量部とを混合して調製した。
比較例3:実施例1で用いたものと同じ前処理液中にエビを浸漬して該エビの表面全体に前処理液を付着させた後、該エビを水中に浸漬せずに、15分間風乾した。
比較例4:エビの表面全体に卵白液(前処理材)を付着させた。
比較例5:エビの表面全体に粉末卵白(前処理材)を打ち粉した。
[Comparative Examples 2 to 5]
Shrimp tempura was produced in the same manner as in Example 1, except that the pretreatment process was changed to the following process.
Comparative Example 2: After spraying the pretreatment liquid over the entire surface of the shrimp, the shrimp was air-dried for 15 minutes. The pretreatment liquid as the pretreatment material used here was composed of 90 parts by mass of hydrous ethanol having an ethanol content of 80% by volume and 10 parts of zein (manufactured by Kobayashi Koryo Co., Ltd., trade name "Kobayashi Zein DP-N"). It was prepared by mixing parts by mass.
Comparative Example 3: Shrimp were immersed in the same pretreatment liquid as used in Example 1 to adhere the pretreatment liquid to the entire surface of the shrimp, and then the shrimp was not immersed in water for 15 minutes. Air dried.
Comparative Example 4: An egg white solution (pretreatment material) was applied to the entire surface of the shrimp.
Comparative Example 5: The entire surface of the shrimp was dusted with powdered egg white (pretreatment material).

〔評価試験〕
油槽にキャノーラ油を入れて加熱し、油温が170℃に達した時点で、各実施例及び比較例のエビ天ぷらをキャノーラ油に一度に投入し、2分半油ちょうしてエビ天ぷらを製造した。こうして製造したエビ天ぷらを急速凍結させ、-20℃の冷凍庫で14日間保存した。その後、各冷凍エビ天ぷらを常温で解凍し、10名の専門パネラーにより、エビ天ぷらの食感を下記評価基準によって評価した
〔Evaluation test〕
Canola oil was put in an oil bath and heated, and when the oil temperature reached 170 ° C., the shrimp tempura of each example and comparative example was put into the canola oil at once and fried for 2 and a half minutes to produce shrimp tempura. . The shrimp tempura thus prepared was quickly frozen and stored in a -20°C freezer for 14 days. After that, each frozen shrimp tempura was thawed at room temperature, and 10 expert panelists evaluated the texture of the shrimp tempura according to the following evaluation criteria.

(天ぷらの食感の評価基準)
5点:衣に非常にサクミがあり、とても軽い食感で非常に良好。
4点:衣にサクミがあり、軽い食感で良好。
3点:衣にややサクミがある。
2点:衣にサクミが無く、やや水気を感じる食感でやや不良。
1点:衣にサクミが全く無く、かなり水気を感じる食感で不良。
(Evaluation criteria for texture of tempura)
5 points: The batter was extremely crispy, and the texture was very light and very good.
4 points: There is crispness in the batter, and the texture is light and good.
3 points: Slightly crispy on the clothes.
2 points: The batter did not have crispy texture, and the texture was a little wet.
1 point: The batter did not have any squeaky feeling, and the texture of the batter felt quite wet, which was unsatisfactory.

Figure 0007220205000001
Figure 0007220205000001

表1に示す通り、各実施例のエビ天ぷらは、「具材の表面にタンパク質及びアルコールを含有する前処理液を付着させた後、該前処理液の付着部分に水性液を付与する前処理工程」を経て製造されているため、該前処理工程を経ていない各比較例に比して、衣のサクミがあって食感に優れていた。 As shown in Table 1, the shrimp tempura of each example was "a pretreatment in which a pretreatment liquid containing protein and alcohol is attached to the surface of the ingredients, and then an aqueous liquid is applied to the portion where the pretreatment liquid is attached. Since it was manufactured through the "process", the batter was crunchy and had an excellent texture compared to each comparative example that did not undergo the pretreatment process.

図3は、急速凍結する前の各実施例及び比較例のエビ天ぷらの長手方向中央位置での断面の図面代用写真であり、図3(a)~図3(c)は実施例1~3、図3(d)~図3(h)は比較例1~5である。図3から明らかなように、各比較例は、具材と衣とが密接していて両者間に空間がほとんど介在していないのに対し、各実施例は、具材と衣との間に比較的大きな空間が介在している。また、図3では確認し難いかもしれないが、各実施例における具材と衣との間の空間には、具材から衣にわたって柱状構造体が延在していることが確認された。この柱状構造体は、前記の通り、タンパク質(ゼイン)からなると考えられる。このような、実施例と比較例とのエビ天ぷらの断面構造の違いが、食感の違いとして現れていると推察される。 FIG. 3 is a drawing substitute photograph of the cross section at the longitudinal center position of the shrimp tempura of each example and comparative example before quick freezing, and FIGS. 3(d) to 3(h) are Comparative Examples 1 to 5. FIG. As is clear from FIG. 3, in each comparative example, the ingredients and the clothing are in close contact with each other, and there is almost no space between them, whereas in each example, the ingredients and the clothing are in close contact with each other. A relatively large space intervenes. In addition, although it may be difficult to confirm in FIG. 3, it was confirmed that the columnar structure extends from the ingredients to the batter in the space between the ingredients and the batter in each example. As described above, this columnar structure is considered to consist of protein (zein). It is speculated that the difference in the cross-sectional structure of the shrimp tempura of the example and the comparative example appears as the difference in texture.

また、最も評価の高い実施例2のエビ天ぷらについて、急速凍結する前にMRI測定を利用した前記方法により空間率を測定したところ、具材と衣との間の空間率は25%であった。このときの実施例2のエビ天ぷらの長手方向中央位置での断面のMRI画像を図4に示す。図4のMRI画像では、実施例2の具材と衣との間の空間に前記柱状構造体が存在していることが確認できる。一方、比較例1のエビ天ぷらの空間率は1%であった。この比較例1の空間率と図3の各比較例のエビ天ぷらの断面構造とを考慮すると、比較例1以外の他の比較例のエビ天ぷらの空間率も、比較例1と同程度(5%未満)であると考えられる。 In addition, for the shrimp tempura of Example 2, which received the highest evaluation, the void ratio was measured by the method using MRI measurement before quick freezing, and the void ratio between the ingredients and the batter was 25%. . FIG. 4 shows an MRI image of the cross section of the shrimp tempura of Example 2 at this time at the center position in the longitudinal direction. In the MRI image of FIG. 4, it can be confirmed that the columnar structures are present in the space between the ingredients of Example 2 and the batter. On the other hand, the void ratio of the shrimp tempura of Comparative Example 1 was 1%. Considering the space ratio of Comparative Example 1 and the cross-sectional structure of the shrimp tempura of each comparative example in FIG. %).

本発明によれば、具材から衣への水分移行が生じ難く、油ちょうしてから時間が経過しても衣のサクサクとした良好な食感が得られる、衣付き油ちょう食品が提供される。本発明の油ちょう用食品素材は、冷凍保存における食感の劣化耐性に優れ、長期間の冷凍保存が可能であり、保存後に常法に従って油ちょうするだけで、食感の良好な高品質の衣付き油ちょう食品となる。 ADVANTAGE OF THE INVENTION According to the present invention, it is possible to provide a batter-coated food product in which water is less likely to migrate from the ingredients to the batter, and the batter is crispy and has a good texture even after a long period of time has passed since the batter is fried. . The food material for frying of the present invention is excellent in texture deterioration resistance during frozen storage, can be frozen for a long period of time, and can be fried in a high quality with a good texture by simply frying in accordance with a conventional method after storage. It becomes a fried food with batter.

Claims (7)

具材の表面に衣が付着した衣付き油ちょう食品であって、
前記具材と前記衣との間に空間が介在し、該空間を該具材から該衣にわたって、ゼインを含む柱状構造体が延在しており、
前記空間の体積が、前記衣付き油ちょう食品の体積の5~50%である衣付き油ちょう食品。
A battered fried food with batter attached to the surface of the ingredients,
A space is interposed between the ingredients and the clothing, and a columnar structure containing zein extends through the space from the ingredients to the clothing ,
A battered fried food, wherein the volume of the space is 5 to 50% of the volume of the battered fried food .
前記具材がエビである請求項に記載の衣付き油ちょう食品。 The battered fried food according to claim 1 , wherein the ingredient is shrimp. 具材の表面に衣が付着した衣付き油ちょう食品の製造方法であって、
具材の表面に衣材が付着した油ちょう用食品素材を製造し、該油ちょう用食品素材を油ちょうして衣付き油ちょう食品を得る工程を有し、
前記油ちょう用食品素材の製造工程が、
具材の表面に、タンパク質及びアルコールを含有する前処理液を付着させた後、該前処理液の付着部分に水性液を付与する前処理工程と、
前記前処理工程を経た具材の表面に常温常圧で液状の衣材を付着させる工程とを有する、衣付き油ちょう食品の製造方法。
A method for producing a battered fried food in which batter is attached to the surface of ingredients,
a step of producing a food material for frying in which a coating material is attached to the surface of an ingredient, and frying the food material for frying to obtain a coated food,
The manufacturing process of the food material for frying is
A pretreatment step in which a pretreatment liquid containing protein and alcohol is attached to the surface of the ingredients, and then an aqueous liquid is applied to the portion where the pretreatment liquid is attached;
A method for producing a coated fried food, comprising a step of attaching a liquid coating material at normal temperature and pressure to the surface of the ingredients that have undergone the pretreatment step.
前記アルコールがエタノールである請求項に記載の衣付き油ちょう食品の製造方法。 The method for producing a battered fried food according to claim 3 , wherein the alcohol is ethanol. 前記前処理工程において、具材100質量部に対して前記タンパク質を0.5~10質量部付着させる請求項又はに記載の衣付き油ちょう食品の製造方法。 5. The method for producing a battered fried food according to claim 3 or 4 , wherein 0.5 to 10 parts by mass of the protein is attached to 100 parts by mass of ingredients in the pretreatment step. 前記油ちょう後に前記衣付き油ちょう食品を冷凍する工程を有する請求項のいずれか1項に記載の衣付き油ちょう食品の製造方法。 The method for producing a coated fried food according to any one of claims 3 to 5, further comprising a step of freezing the coated fried food after the cooking. 具材の表面に衣材が付着した油ちょう用食品素材の製造方法であって、
具材の表面に、タンパク質及びアルコールを含有する前処理液を付着させた後、該前処理液の付着部分に水性液を付与する前処理工程と、
前記前処理工程を経た具材の表面に常温常圧で液状の衣材を付着させる工程とを有する、油ちょう用食品素材の製造方法。
A method for producing a food material for frying in which a coating material is attached to the surface of the ingredients,
A pretreatment step in which a pretreatment liquid containing protein and alcohol is attached to the surface of the ingredients, and then an aqueous liquid is applied to the portion where the pretreatment liquid is attached;
A method for producing a food material for frying, comprising a step of attaching a liquid coating material at normal temperature and normal pressure to the surface of the ingredients that have undergone the pretreatment step.
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WO2007072770A1 (en) 2005-12-21 2007-06-28 Fuji Oil Company, Limited Fried food with regulated moisture migration

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