JP7133340B2 - Agricultural chemical composition for surface application - Google Patents

Description

TECHNICAL FIELD The present invention relates to an agricultural chemical composition for water surface application, a solid agricultural chemical package thereof, and a method for producing the same.

As general pesticide formulations, powders, granules, wettable powders, aqueous solutions, flowable formulations, liquid formulations, emulsion formulations, and the like are known. Of these, spraying agents such as wettable powders, water solutions, and emulsions are mainly used in upland fields and non-agricultural lands. There is a problem of environmental impact, and emulsions have a problem of environmental pollution due to solvents and emulsifiers, a problem of fire hazard due to organic solvents, and the like. In addition, many of the active ingredients of agricultural chemicals are poorly soluble in water, and it is often difficult to formulate them into liquid formulations. For these reasons, there is a recent tendency to increase the use of aqueous or oily suspension formulations (flowables) or dry flowables, which have less of these problems.

On the other hand, examples of water-surface application agents for paddy fields include powders, granules, and the like, and granules have been mainly used in the past. Granules are generally applied at 3 to 4 kg per 10 ares, but in recent years, there has been a growing demand for labor-saving spraying of agricultural chemicals, and development of small-volume spraying agents that reduce the application amount of agricultural chemical formulations is required. On the other hand, an attempt to reduce the application amount of the granules inevitably increases the content of the agricultural chemical active ingredient in the granules and also reduces the number of grains per unit area. These are factors that directly affect the biological effects of agricultural chemical active ingredients and the phytotoxicity of crops, and it is required that agricultural chemical formulations be treated uniformly over the entire paddy field as much as possible.

However, the 1 kg granules developed in recent years require a certain amount of skill and experience in order to be uniformly sprayed on flooded sewage fields, and it is not easy to achieve uniform spraying. Since a spraying device is required, it cannot be said that it is necessarily satisfactory as a dosage form aimed at labor saving.

Therefore, in the field of surface application agents for paddy fields, many developments of aqueous suspension formulations have been made for the purpose of saving labor and improving efficiency during spraying. Unlike aqueous suspension formulations used in upland fields and non-agricultural lands, this formulation does not require any special spraying equipment because it is dropped or poured directly from a container into the paddy field without dilution. In addition, the processing amount of the formulation is as small as about 200 ml to 1 liter per 10 ares, so it is light and easy to handle. It is possible to perform treatment by simply irrigating from a water inlet (so-called water inlet treatment). Therefore, since the preparation can be processed with extremely labor-saving, the market has expanded rapidly after its release. However, since the aqueous suspension formulation is a formulation in which an agricultural chemical active ingredient is dispersed or emulsified in water, it has the problem of being difficult to apply to an agricultural chemical active ingredient that is easily hydrolyzed.

In recent years, as a formulation considering the labor saving of pesticide spraying and the environment, solid formulations such as tablets, bean-type formulations, granules, etc. are packed in water-soluble paper such as water-soluble film, and formulations for throwing into paddy fields (packs or jumbo formulations) ) are becoming more prevalent. Although such formulations have the advantage of being easy to process agricultural chemicals for paddy fields, unlike conventional granules and powders, they are not processed uniformly. It settles on the soil surface. Here, since the sediment is foamed or non-foamed to disperse the agricultural chemical active ingredient in the surface water, the undissolved active ingredient particles settle around the dropping point. In addition, the dissolved pesticidal active ingredient forms a high-concentration solution near the surface of the soil at the point of application, and is easily adsorbed by the soil. For this reason, even if the water solubility of the active agricultural chemical ingredient in the formulation for throwing into the paddy field, which is a solid formulation wrapped in water-soluble paper such as a water-soluble film, is quite high, the active ingredient will not be present in the soil near the injection point of the formulation. It has the drawback that it is likely to cause phytotoxicity, uneven efficacy, and adverse effects on subsequent crops due to non-uniformity of the active ingredient of the agricultural chemical, depending on the field conditions and weather conditions.

As such granules, many effervescent tablets have been developed in the past, but the use of non-effervescent granules has become mainstream due to problems in manufacturability and storage stability. For example, [1] (1) an agricultural chemical active ingredient, (2) water-floating granules containing one or more selected from calcined vermiculite, foamed perlite, foamed shirasu and cork, and (3) acetylene alcohol and acetylene A surface-floating pesticide solid agent containing one or more water surface expanders selected from diols and surfactants obtained by adding alkylene oxide thereto, polyvinyl alcohol, derivatives thereof, or polyvinyl alcohol and its Pesticide formulation for throwing into paddy fields, in which the active ingredient is dispersed or dissolved in water, divided into films or sheets made of a derivative (Patent No. 2815535; Patent Document 1), [2] (1) an agrochemical active ingredient and (2) Agricultural chemical granules or tablets in which a powder base having a specific gravity of 1 or less and (3) a surfactant having a high interfacial tension lowering ability are uniformly dispersed (JP-A-7-233002; Patent Document 2), [3] (1) (2) an agriculturally active substance and (3) a substance capable of changing the air-water interfacial tension on the grain nuclei having an apparent specific gravity of less than 1 and a particle size within the range of about 300 μm to about 1,400 μm. (4) A pesticide formulation for water surface application with good floating running properties characterized by being supported and coated using an oily substance (JP-A-9-183701; Patent Document 3), [4] (1) 1 type or (2) one or more surfactants selected from the group consisting of α-olefin sulfonates, α-sulfo fatty acid salts and oleyl methyl tauride salts, and (3) apparent Water surface application containing molded granules having a specific gravity of less than 1 and containing a hollow mineral carrier, a plant carrier, a synthetic resin foam, or one or more of these to impart the property of floating on water An agricultural chemical composition (Patent No. 3535429; Patent Document 4) is known as a technique for improving the spreadability of water-floating granules.

Patent No. 2815535 Japanese Patent Laid-Open No. 7-233002 Japanese Patent Laid-Open No. 9-183701 Patent No. 3535429

However, these existing methods have not always been able to obtain sufficient water surface spreadability in practical situations. That is, in the practical scene, algae, rice husks and other floating matter often cover the water surface of paddy fields. Since the material inhibits the floating and spreading of the agricultural chemical active ingredient, even if the water surface application agent is treated, the agricultural chemical active ingredient cannot spread uniformly. Furthermore, even in paddy fields that seem to have no floating matter at first glance, there may actually be floating matter that cannot be confirmed visually from the banks. Sufficient airborne spread of the active ingredient of the pesticide cannot be expected even if the pesticide is treated. In particular, during the period when so-called medium-term agents are applied, in addition to the increase in suspended matter on the surface of the water, the growth of rice plants and weeds also inhibits the diffusion of active pesticide ingredients. In addition, it is required to strengthen the diffusion performance of the drug.

An object of the present invention is to solve the problem that the pesticide formulation satisfactorily floats and spreads on the surface of the water even under the conditions where there are floating substances that inhibit the floating and spreading of the active ingredient of the pesticide in paddy fields, and even under conditions where rice plants and weeds have grown. Designing an agrochemical formulation is a challenge, but until now no technology has been known that is sufficient to solve several challenges including this challenge at the same time. That is, the pesticide formulation must 1) not require special equipment for spraying, 2) be labor-saving, 3) be safe for sprayers and the environment, and 4) be packaged in a standard form such as a plastic container. 5) There is no danger of insufficient efficacy due to segregation of active ingredients of agricultural chemicals or phytotoxicity due to uneven distribution. Even in such a situation, there has been a demand for an agricultural chemical formulation that has excellent floating and spreadability on the water surface, and 7) that it is stable over time and a method for treating it.

The inventors of the present invention conducted intensive studies with the aim of developing an agricultural chemical formulation that satisfies the above conditions and a processing method thereof. The pesticide composition using the nucleus is novel, and the pesticide composition is packed in a suitable container with a transfer port and directly transferred into the paddy field, or the pesticide composition is broken and dispersed with water. By subdividing into water-soluble films to form individual packages and throwing them into paddy fields, the pesticide composition satisfactorily floats and spreads in the paddy surface water, and the pesticide active ingredients are well distributed throughout the paddy surface water. The present invention has been completed by finding that it is possible to

That is, the present invention is as follows [1]-[10].
[1] (1) one or more active pesticide ingredients, (2) alkylsulfosuccinate salts, (3) one or more extenders selected from the group of compounds below, and (4) 1 An agrochemical composition for water surface application containing grain nuclei (the apparent specific gravity of the grain nuclei is less than 1) containing seeds or two or more hollow mineral carriers, plant carriers and/or synthetic resin foams.
Group of compounds: α-olefin sulfonates and glycol ether solvents.
[2] The agricultural chemical composition for water surface application according to [1], which contains two kinds of spreading agents.
[3] The agricultural chemical composition for water surface application according to [1] or [2], wherein the grain nucleus contains at least one selected from the group consisting of calcined vermiculite, expanded perlite, expanded shirasu and cork.
[4] An agricultural chemical composition for water surface application, which further contains an oily substance in addition to the agricultural chemical composition for water surface application according to any one of [1] to [3].
[5] An agricultural chemical composition for water surface application, which further contains a water-soluble metal salt in addition to the agricultural chemical composition for water surface application according to any one of [1] to [4].
[6] An agricultural chemical composition for water application, comprising the agricultural chemical composition for water application according to any one of [1] to [5] and further containing at least one surfactant.
[7] The agricultural chemical composition for water surface application according to [6], wherein the surfactant is a nonionic surfactant.
[8] The nonionic surfactant is selected from the group consisting of polyoxyalkylene alkyl ethers, polyoxyalkylene alkyl aryl ethers, fatty alcohol alkylene oxide adducts and polyalkyleneoxy fatty acid esters [6] or [7] 3. The agricultural chemical composition for surface application according to .
[9] A solid agricultural chemical package comprising the water-surface application agricultural chemical composition according to any one of [1] to [8] divided into water-soluble films or sheets.
[10] (A) Grain nuclei containing at least one selected from the group consisting of calcined vermiculite, foamed perlite, foamed shirasu and cork (the grain nuclei have an apparent specific gravity of less than 1), optionally containing an oily substance and / or a step of absorbing a glycol ether solvent and (B) adding an agricultural chemical active ingredient, an alkyl sulfosuccinate salt and / or an α-olefin sulfonate to the surface-floating granules obtained in the above step (A), containing the step of coating or absorbing,
(1) one or more active pesticide ingredients, (2) alkylsulfosuccinate salts, (3) one or more extenders selected from the group of compounds below, and (4) calcined vermiculite, foaming A method for producing an agricultural chemical composition for water surface application containing grain nuclei containing at least one selected from the group consisting of perlite, foamed shirasu and cork (the apparent specific gravity of the grain nuclei is less than 1).
Compound group: α-olefin sulfonate and glycol ether solvent

A comparison of the agrochemical composition for water surface application of the present invention with the prior art is as follows.

That is, comparing the pesticide composition for water surface application of the present invention with the water surface floating pesticide solid agent of Patent Document 1, both of them have common agricultural chemical active ingredients and water surface floating grain nuclei, but the water surface application of the present invention The agricultural chemical composition to be applied contains one or more extenders selected from the group of alkylsulfosuccinate salts and compounds (here, the group of compounds refers to α-olefin sulfonates and glycol ether solvents). The point that the water surface-floating pesticide solid agent of Patent Document 1 contains one or more water surface spreaders selected from acetylene alcohol, acetylenediol, and surfactants obtained by adding alkylene oxide to them. And they are different.

When the agricultural chemical composition for water surface application of the present invention is compared with the agricultural chemical granules or tablets of Patent Document 2, both of them contain an agricultural chemical active ingredient, water surface floating granules (in addition, in Patent Document 2, powder base with a specific gravity of 1 or less). However, the agrochemical composition for water surface application of the present invention contains one or more extenders selected from the group of alkylsulfosuccinate salts and compounds (here, the group of compounds is , α-olefin sulfonate and glycol ether solvents), and the agrochemical granules or tablets of Patent Document 2 uniformly disperse surfactants with a large interfacial tension-lowering ability. differ.

When the agricultural chemical composition for water application of the present invention is compared with the agricultural chemical formulation for water surface application of Patent Document 3, both of them contain an agricultural chemical active ingredient, water surface floating grain nuclei (in Patent Document 3, the apparent specific gravity is less than 1 and about 300 μm 1,400 μm to approximately 1,400 μm, and in the present invention, 90% or more of the grain nuclei are usually in the range of 0.710 mm to 4.760 mm.) However, the agricultural chemical composition for water surface application of the present invention contains one or more extenders selected from the group of alkylsulfosuccinate salts and compounds (here, the group of compounds is α-olefin sulfonate and glycol ether In that the agrochemical formulation for water surface application of Patent Document 3 comprises a substance capable of changing the air-water interfacial tension, supported and coated using an oily substance, both are different.

When the agricultural chemical composition for water application of the present invention is compared with the agricultural chemical composition for water application of Patent Document 4, both of them have common agricultural chemical active ingredients and water-floating grain nuclei. The compound contains one or more extenders selected from the group of alkylsulfosuccinate salts and compounds (here, the group of compounds refers to α-olefin sulfonates and glycol ether solvents). The aquatic agricultural chemical composition of Patent Document 4 contains one or more surfactants selected from the group consisting of α-olefin sulfonates, α-sulfo fatty acid salts and oleyl methyl tauride salts. And they are different.

According to the present invention, when the agrochemical composition for water surface application is applied to flooded sewage fields, the agrochemical composition for water surface application self-diffuses in various directions on the water surface as the surfactant dissolves, and the active ingredient of the water surface disperses. Quickly disperses and dissolves uniformly in paddy water. In addition, since the agricultural chemical composition for water surface application of the present invention releases the active agricultural chemical ingredient into water at an extremely high rate, even if the grain nuclei remain on the surface of the water and are blown away by the wind, the active agricultural chemical ingredient has already been released before being blown away. Since it is released, it does not affect the manifestation of its action and effect at all, which is a very favorable feature even in practical situations.

Next, various terms used in this specification will be explained.
The content of the agricultural chemical active ingredient of the present invention in the agricultural chemical composition for water surface application is not particularly limited as long as it is an amount that allows formulation, but is usually 0.1 to 50% per 100 weight of the composition of the present invention. parts by weight, more preferably 1 to 40 parts by weight.
The "active pesticidal ingredient" contained in the pesticide composition for water surface application of the present invention is a herbicidal active ingredient, an insecticidal/acaricidal active ingredient, a fungicidal active ingredient, a plant-regulating ingredient, or a mixed ingredient thereof. There are no particular restrictions on the physical properties of the material itself, as long as it is stable in the composition.

The herbicidal active ingredient contained in the agrochemical composition for water surface application of the present invention is not particularly limited, but examples include bensulfuron-methyl, azimsulfuron, imazosulfuron, halosulfuron-methyl, pyrazosulfuron-ethyl, ethoxysulfuron, cinosulfuron, cyclo sulfamuron, chlorsulfuron, chlorimuron-ethyl, neophensulfuron-methyl, flazasulfuron, sulfometuron-methyl, primisulfuron-methyl, rimsulfuron, propyrisulfuron, metsulfuron-methyl, flucetosulfuron, metazosulfuron, dimepiperate , mefenacet, pretilachlor, molinate, piributicarb, thenylchlor, esprocarb, butamiphos, bromobutide, daimuron, caffenstrol, cyhalofop-butyl, benzofenap, pyrazolate, pyrazoxifene, benfuresate, bentiocarb, eporodan, quinocramine (ACN), simetryne, dimethamethrin, pentoxazone , edbenzanide, dithiopyr, butachlor, oxadiargyl, naproanilide, simmethrin, (2,4-dichlorophenoxy)acetic acid (2,4-D) or its alkyl esters or salts thereof, 4-(4-chloro-o-tolyloxy)butyric acid ( MCPB), oxadiclomefone, fentrazamide, cyclopyrimolate, penoxsulam, bentazone, mesotrione, sulcotrione, benzobicyclone, tefuryltrione, bicyclopyrone, bispyribac, pyribenzoxime, pyriftalide, pyriminobacmethyl, pyrimisulphane, triafamone, etc. mentioned.

The insecticidal/miticidal active ingredient contained in the agrochemical composition for water surface application of the present invention is not particularly limited, but examples include indoxacarb, chromafenozide, pyrimidifen, milbemectin, methomyl, acephate, dinotefuran, thiocyclam, imidacloprid, nitenpyram, Acetamiprid, clothianidin, thiamethoxam, thiacloprid, pyridafenthion, dimethoate, PMP, CVMP, dimethylvinphos, DEP, NAC, MTMC, MIPC, PHC, MPMC, XMC, benflacarb, pirimicarb, oxamyl, thiodicarb, cypermethrin, cartap, bensultap, diflubenzuron , teflubenzuron, chlorfluazuron, buprofezin, hexythiazox, fenbutatin oxide, pyridaben, clofentezine, Bacillus thuringiensis and its toxin, MPP, MEP, diazinon, isoxathion, ethylthiometone, etofenprox, tralomethrin, silafluofen, cyclopro Thrine, benfuracarb, brofuranilide and the like.

The fungicidal active ingredient contained in the pesticide composition for water surface application of the present invention is not particularly limited, but examples include simeconazole, hydroxyisoxazole, tecloftalam, diclomedine, penthiopyrad, pyroquilone, ziram, thiuram, captan, TPN, fthalide, triclofosmethyl, fosetyl, thiophanate-methyl, benomyl, carventazole, thiabentazole, diethofencarb, iprodione, vinclozoline, procymidone, fluorimide, oxycarboxin, mepronil, flutolanil, penciclon, metalaxyl, oxadixyl, triadimefon, hexaconazole, trifolin, blasticidin S, kasugamycin, polyoxin, validamycin A, PCNB, dazomet, triazine, probenazole, isoprothiolane, tricyclazole, tetraconazole, triclamide, oxolinic acid, dimethomorph, cymoxanil, tolprocarb, MON-240 and the like.

The plant-regulating ingredients contained in the pesticide composition for water surface application of the present invention are not particularly limited, but examples include maleic hydrazide or a salt thereof, abscisic acid, calcium peroxide, inabenfide, paclobutrazol, uniconazole, and tripentenol. , psychocell and the like.

Further active ingredients for agrochemicals optionally used in the present invention include one or more of the above-described herbicidal active ingredients, insecticidal/miticidal active ingredients, fungicidal active ingredients, plant-regulating ingredients, and the like. can be used in combination.

The alkylsulfosuccinate salt used in the present invention means, for example, a salt of monoalkylsulfosuccinic acid such as di(2-ethylhexyl)sulfosuccinic acid, a salt of dialkylsulfosuccinic acid such as dioctylsulfosuccinic acid, Among them, a salt of dioctylsulfosuccinic acid is preferable. The salt is not particularly limited, and examples thereof include salts with alkali metals such as sodium and potassium, salts with alkaline earth metals such as calcium and magnesium, and salts with ammonia (ammonium salts). Sodium or calcium salts are preferred and generally function as extenders.

In the present invention, one or more extenders selected from α-olefin sulfonates and glycol ether solvents are used. Preferably two or more extenders are used.

The α-olefin sulfonate used in the present invention is a sulfonated product made from crude oil (petroleum) as a raw material, and has excellent biodegradability, is very safe for skin and eyes, and is resistant to acids and alkalis. It has human- and environment-friendly characteristics such as being stable against water and having excellent resistance to hard water. , which acts as an extender.

The α-olefin sulfonate salt is not particularly limited, but examples include salts with alkali metals such as sodium and potassium, salts with alkaline earth metals such as calcium and magnesium, and salts with ammonia (ammonium salts ), salts with various amines, and salts with sodium, ammonium, or calcium are preferred.

The glycol ether-based solvent used in the present invention is not particularly limited. , ethylene glycol monoisobutyl ether, ethylene glycol mono-t-butyl ether, ethylene glycol mono-2-methylpentyl ether, ethylene glycol monohexyl ether, ethylene glycol mono-2-ethylhexyl ether, ethylene glycol monovinyl ether, ethylene glycol monoallyl ether, ethylene glycol monobenzyl ether, ethylene glycol monophenyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monoisopropyl ether, diethylene glycol monobutyl ether, diethylene glycol monoisobutyl ether, diethylene glycol monohexyl Ether, diethylene glycol mono 2-ethylhexyl ether, diethylene glycol monoallyl ether, diethylene glycol monobenzyl ether, diethylene glycol monophenyl ether, diethylene glycol mono (methylphenyl) ether, diethylene glycol dimethyl ether, diethylene glycol methyl ethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, diethylene glycol di Vinyl ether, diethylene glycol ethyl vinyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, triethylene glycol monobutyl ether, triethylene glycol monovinyl ether, triethylene glycol dimethyl ether, tetraethylene glycol monophenyl ether, tetraethylene glycol diethyl ether, polyethylene Glycol monomethyl ether Propylene glycol monomethyl ether, Propylene glycol monoethyl ether, Propylene glycol monopropyl ether, Propylene glycol monoisopropyl ether, Propylene glycol monobutyl ether, Propylene glycol phenyl ether, Propylene glycol mono(methylphenyl) ether, Propylene glycol dimethyl ether, Propylene glycol Diethyl ether, propylene glycol dipropyl ether, propylene glycol diisopropyl ether, propylene glycol dibutyl ether, propylene glycol diisobutyl ether, propylene glycol diallyl ether, propylene glycol diphenyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene glycol mono Propyl ether, dipropylene glycol monobutyl ether, dipropylene glycol dimethyl ether, dipropylene glycol diethyl ether, dipropylene glycol dibutyl ether, dipropylene glycol diisobutyl ether, dipropylene glycol allyl ether, tripropylene glycol monomethyl ether, tripropylene glycol monoethyl ether , tripropylene glycol monobutyl ether, butylene glycol monomethyl ether, butylene glycol dimethyl ether, 3-methoxy-3-methyl-1-butanol, etc., and usually function as an extender.

The grain nucleus used in the present invention usually functions as a buoyant material, and is not particularly limited as long as it is a granular substance having the property of floating on water. and/or granules containing a synthetic resin foam, the granules having an apparent specific gravity of less than 1. For example, hollow mineral carriers such as calcined vermiculite, calcined vermiculite, foamed perlite, and foamed shirasu; plant carriers such as cork; granular materials such as synthetic resin foams such as styrene foam; granules that have been given the property of floating on water and are molded, preferably calcined vermiculite, foamed perlite, foamed shirasu, or cork, and more preferably calcined vermiculite, foamed perlite, or cork. The blending ratio in the agrochemical composition for water surface application of the present invention is preferably 1 to 50% by weight, more preferably 5 to 30% by weight, based on the total amount of the composition.

The agricultural chemical composition for water surface application of the present invention can be prepared, for example, by allowing grain nuclei having an apparent specific gravity of less than 1 to carry an agricultural chemical active ingredient or the like, or by allowing the grain nuclei having an apparent specific gravity of less than 1 to support an agricultural chemical active ingredient or the like. can be produced by coating the

When the grain nucleus having an apparent specific gravity of less than 1 carries an agricultural chemical active ingredient or the like, the amount of the agricultural chemical active ingredient or the like incorporated into the grain nucleus is within the range in which the agricultural chemical composition for water surface application floats on the water surface. is enough. Depending on the type and grade of the grain nucleus, the type of the active ingredient of the agricultural chemical, the type and amount of the other auxiliary agents, etc., it can be appropriately selected and blended. In order to do so, the blending ratio in the agrochemical composition for surface application of the present invention is usually 10 to 90% by weight, preferably 20 to 70% by weight.

When the surface of grain nuclei having an apparent specific gravity of less than 1 is coated with an active agricultural chemical ingredient, an alkylsulfosuccinate salt, an extender, etc., the agricultural chemical composition for water surface application of the present invention can be produced by the following coating method. can be done.

Specifically, (1) a method of coating grain nuclei, which usually have an apparent specific gravity of less than 1, with an agricultural chemical active ingredient, an alkylsulfosuccinate salt, an extender, and optionally other auxiliary agents;
(2) granules containing grain nuclei having an apparent specific gravity of less than 1, all of the agricultural chemical active ingredients, alkyl sulfosuccinate salts, and optionally other auxiliary agents, and an oily substance that is liquid at room temperature, one or and (3) granulation containing grain nuclei having an apparent specific gravity of less than 1, some agricultural chemical active ingredients, alkyl sulfosuccinate salts, and optionally other auxiliary agents. A method of coating one or more of the above-mentioned extenders with an oily substance that is liquid at room temperature, and further coating one or more of the above-mentioned extenders and the rest of the agricultural chemical active ingredient.

When grain nuclei having an apparent specific gravity of less than 1 are impregnated with an agricultural chemical active ingredient, an alkylsulfosuccinate salt, an extender, etc., the water surface application agricultural chemical composition of the present invention is produced by the following impregnation method. be able to.

That is, (1) a method of impregnating grain nuclei, which usually have an apparent specific gravity of less than 1, with an agricultural chemical active ingredient, an alkylsulfosuccinate salt, an extender, and optionally other auxiliary agents;
(2) granules containing grain nuclei having an apparent specific gravity of less than 1, all of the agricultural chemical active ingredients, alkyl sulfosuccinate salts, and optionally other auxiliary agents, and an oily substance that is liquid at room temperature, one or and (3) granulation containing grain nuclei having an apparent specific gravity of less than 1, some agricultural chemical active ingredients, alkyl sulfosuccinate salts, and optionally other auxiliary agents. A method of impregnating an oily substance that is liquid at room temperature with one or more of the above-mentioned extenders, and then impregnating with one or more of the above-mentioned extenders and the rest of the agricultural chemical active ingredients.

The oily substance that is liquid at room temperature used in the present invention does not adversely affect particle growth, decomposition, etc. of the active agricultural chemical, and has the property of being able to uniformly coat the surface of the grain nucleus having an apparent specific gravity of less than 1 with the active agricultural chemical. A solvent with a high boiling point, low toxicity, high flash point, low viscosity, a specific gravity of less than 1, and a low dissolving power for the active ingredient of agricultural chemicals is preferable, for example, low viscosity liquid paraffin , chlorinated paraffin, isoparaffin, machine oil, polybutene, paraffinic, naphthenic, and various high boiling point solvents such as aromatic oils; vegetable oils such as coconut oil, soybean oil and rapeseed oil; animal oils such as whale oil and sardine oil; Silicone oils, various esters of monomers or dicarboxylic acids such as oleic acid, coconut fatty acid, maleic acid, fumaric acid, phthalic acid, adipic acid; plasticizers such as various esters of phosphoric acid such as tributyl phosphate and trichloroethyl phosphate glycols such as ethylene glycol, diethylene glycol, butanediol and various esters and ethers thereof; lactones such as ε-caprolactone and γ-butyrolactone; N-methylpyrrolidone; and various liquid surfactants. be able to.

The amount of the oily substance that is liquid at normal temperature used in the present invention varies depending on the type of agricultural chemical active ingredient, the type and amount of other auxiliary agents, and can be appropriately selected and blended. In order to impart good floating and spreadability on the water surface to the agricultural chemical composition for application, the blending ratio in the agricultural chemical composition for application on water is usually 1 to 60%, preferably 5 to 40%.

The pesticide composition for water surface application is not particularly limited as long as it is in the form usually used for water surface application, but granules are preferred.
The binder used for molding the granules in the present invention is a mixture of grain nuclei having an apparent specific gravity of less than 1 and optionally other adjuvants, agricultural chemical active ingredients, surfactants and other water surface spreaders. , used for granule molding, examples include dextrin, polyvinyl alcohol, polyvinylpyrrolidone, salts of carboxymethyl cellulose, methyl cellulose, gum arabic, polyethylene glycol and derivatives thereof, tab powder and bentonite. For example, lignin sulfonate, carboxylic acid and sulfonic acid type polysoaps can also be used as dispersants, and bentonite and lignin sulfonate are particularly useful because they are relatively inexpensive and can be used as bulking agents. be.

Bentonite and sodium salt of carboxymethylcellulose, in particular, as binders used in the present invention have a strong binding force, can control the disintegration time of granules in water, and have swelling properties themselves. It has the advantage that the granules can be completely disintegrated after disintegration. The amount of the binder used in the present invention includes the type of binder, the type of grain nuclei having an apparent specific gravity of less than 1, the composition and production method, the formulation, preparation method, and shape of the agricultural chemical granule, and the type of the active ingredient of the agricultural chemical. , physical properties, and the type and amount of other adjuvants, which vary depending on the formulation, can be selected and determined as appropriate. For example, the mixing ratio of bentonite is usually 3 to 70%, preferably 5 to 30%, in the agrochemical composition for water surface application of the present invention, and the mixing ratio of other binders is 0. .1 to 30%, preferably about 0.5 to 20%.

Other adjuvants can be added to the agricultural chemical composition for surface application of the present invention for various purposes. Other adjuvants include, for example, surfactants, oil-absorbing carriers, antifoaming agents, antifungal agents, solvents or stabilizers, i.e., adjuvant components such as colorants, extenders, preservatives, and pH adjusters. can be added. Surfactants are preferred.

Surfactants used in the present invention are not particularly limited as long as they are commonly used in agricultural chemicals, and include anionic surfactants, nonionic surfactants, cationic surfactants or zwitterionic surfactants. Any surfactant such as an active agent can be used, and one or more of these can be used.

Examples of anionic surfactants include alkyl phosphates, alkyl sulfates, polyoxyalkylene alkyl ether phosphates, polyoxyethylene alkyl ether sulfates, alkylaryl phosphates, and alkylaryl sulfates. , polyoxyalkylene alkylaryl ether phosphate, polyoxyalkylene alkyl aryl ether sulfate, alkylphenol phosphate, alkylphenol phosphate, alkylphenol sulfate, alkylphenol sulfate, polyoxyalkylenealkylphenol phosphate, polyoxyalkylenealkylphenol Phosphate ester salt, polyoxyalkylenealkylphenol sulfate, polyoxyalkylenealkylphenol sulfate, styrylphenol phosphate, styrylphenol phosphate, styrylphenol sulfate, styrylphenol sulfate, polyoxyalkylenestyrylphenol phosphate, poly Oxyalkylenestyrylphenol phosphate, polyoxyalkylenestyrylphenol sulfate, polyoxyalkylenestyrylphenol sulfate, distyrylphenol phosphate, distyrylphenol phosphate, distyrylphenol sulfate, distyrylphenol sulfate , polyoxyalkylene distyrylphenol phosphate, polyoxyalkylene distyrylphenol phosphate, polyoxyalkylene distyrylphenol sulfate, polyoxyalkylene distyrylphenol sulfate, tristyrylphenol phosphate, tristyrylphenol phosphate salt, tristyrylphenol sulfate, tristyrylphenol sulfate, polyoxyalkylene tristyrylphenol phosphate, polyoxyalkylene tristyrylphenol phosphate, polyoxyalkylene tristyrylphenol sulfate, polyoxyalkylene tristyrylphenol sulfate ester salts, alkyl succinate sulfonates, dialkyl succinate sulfonates, polyoxyalkylene dialkyl succinate sulfonates, etc., preferably alkyl phosphate salts, polyoxyalkylene alkyl ether phosphate ester salts, alkyl Aryl Phosphate Ester Salt, Polyoxyalkylene Alkyl Aryl A Teruphosphate, alkylphenol phosphate, styrylphenol phosphate, polyoxyalkylene styrylphenol phosphate, distyrylphenol phosphate, distyrylphenol phosphate, polyoxyalkylene distyrylphenol phosphate, polyoxyalkylene di Examples include styrylphenol phosphate, tristyrylphenol phosphate, tristyrylphenol phosphate, polyoxyalkylene tristyrylphenol phosphate, and polyoxyalkylene tristyrylphenol phosphate.

Examples of nonionic surfactants include fatty alcohol alkylene oxide adducts, polyalkyleneoxy fatty acid esters, sorbitan surfactants or their alkylene oxide adducts, polyglycerin fatty acid esters, alkyl polysaccharide surfactants, Sucroglyceride, polyoxyalkylene alkyl ether, polyoxyethylene alkyl ether, polyoxyalkylene alkyl aryl ether, polyoxyalkylene alkyl phenol ether, polyoxyalkylene styrylphenol ether, polyoxyalkylene distyrylphenol ether or polyoxyalkylene tristyrylphenol Ethers and the like, preferably aliphatic alcohol alkylene oxide adducts, polyalkyleneoxy fatty acid esters, polyoxyalkylene alkyl ethers, polyoxyethylene alkyl ethers, polyoxyalkylene alkylaryl ethers, polyoxyalkylene alkylphenol ethers, poly Oxyalkylenestyrylphenol ethers, polyoxyalkylenedistyrylphenol ethers, polyoxyalkylenetristyrylphenol ethers and the like, more preferably polyoxyalkylenealkyl ethers, polyoxyalkylenealkylaryl ethers, aliphatic alcohol alkylene oxide addition and polyalkyleneoxy fatty acid esters.

These ethylene oxide-added surfactants may partially contain propylene oxide.

Examples of cationic surfactants include aliphatic tertiary amines or salts thereof, aliphatic tertiary amine-aliphatic amine alkylene oxide adducts or salts thereof, and aliphatic quaternary amine salts.

Amphoteric surfactants include, for example, amino acid-type amphoteric surfactants such as sodium laurylaminopropionate; Examples include amphoteric surfactants; sulfate type amphoteric surfactants; sulfonate type amphoteric surfactants; and phosphate type amphoteric surfactants.

Surfactants used in one embodiment of the pesticide composition for water surface application in the present invention are preferably anionic surfactants or nonionic surfactants, particularly nonionic surfactants. .

The oil-absorbing carrier used in the present invention is not particularly limited as long as it is commonly used in agricultural chemicals. and preferably vegetable powder, perlite or amorphous silicon dioxide.

The antifoaming agent used in the agricultural chemical composition for water surface application of the present invention is not particularly limited as long as it is usually used in agricultural chemical formulations. Alcohol-based antifoaming agents; amyl alcohol, diisobutyl carbitol, tributyl phosphate, oleic acid, tall oil, metal soap, surfactants with low HLB (e.g., sorbitan laurate monoester, sorbitan laurate triester, polyethylene glycol fatty acid ester , acetylene glycol derivatives, pluronic nonionic surfactants, etc.), organic polar compound antifoaming agents such as acetylene glycol derivatives; mineral oil surfactant formulations, mineral oil and fatty acid metal salt surfactant formulations and silicone resin antifoaming agents such as silicone resins, surfactant formulations of silicone resins, and inorganic powder formulations of silicone resins.

The antifungal agent used in the agrochemical composition for water surface application of the present invention is not particularly limited as long as it is commonly used in agrochemical formulations. Examples include parachlorometaxylenol, polyhexamethylenebiguanidide hydrochloride, 1,2-benzisothiazolin-3-one, methyl parahydroxybenzoate, ethyl parahydroxybenzoate, propyl parahydroxybenzoate, butyl parahydroxybenzoate, heptyl parahydroxybenzoate, benzyl parahydroxybenzoate, parahydroxybenzoic acid ester, sorbic acid, orthophenylphenol, sodium orthophenylphenate, glutardialdehyde, quaternary ammonium compounds, tri-(N-chlorohexyldiazeniumdioxy)-aluminum, tetrahydro-3,5-dimethyl-2H-1,3, 5-thiadiazine-2-thione, 2,5-dimethoxytetrahydrofuran, dimethylol urea, sodium N-methyldithiocarbamate, phenoxyethanol, glyoxal, glutaraldehyde, 1,3,5-tris(2-hydroxyethyl)-1,3, 5-hexahydrotriazine, benzalkonium chloride, phenoxypropanol, tetramethylacetylenediurea, povidone iodin, potassium sorbate, 2-bromo-2-nitropropane-1,3-diol, thiazolone, and the like.

The solvent used in the agrochemical composition for water surface application of the present invention is not particularly limited as long as it is commonly used in agrochemicals. For example, alkylbenzene, methylnaphthalene, liquid paraffin, ligroin, kerosene, kerosene, n-decane, isododecane, tetralin, decalin, turpentine oil, pine oil, adipic acid, gluconic acid, maleic acid, lactic acid, benzoic acid, phthalic acid, apple Acid, fumaric acid, succinic acid, tartaric acid, citric acid, lauric acid, oleic acid, coconut oil fatty acid, cyclohexanone, cyclohexenylcyclohexanone, acetylacetone, acetophenone, methylbutyl ketone, ethylene glycol, diethylene glycol, triethylene glycol, propylene Glycol, dipropylene glycol, tripropylene glycol, epichlorohydrin, diglycidyl ether, dioxane, triethyl phosphate, tributyl phosphate, soybean oil, rapeseed oil, sesame oil, rice oil, coconut oil, sunflower oil, sardine oil, whale oil, dimethyl sulfoxide, N,N-dimethylacetamide, N-ethylpyrrolidone or N-methylpyrrolidone, and the like.

The coloring agent used in the agrochemical composition for water surface application of the present invention is not particularly limited as long as it is commonly used in agricultural chemicals. Green G. The mixing ratio of the coloring agent used is usually 0.05 to 0.5% by weight, preferably 0.1 to 0.3% by weight, relative to the total amount of the composition.

Bulking agents used in the pesticide composition for water surface application of the present invention include, for example, fine mineral powders generally used as carriers for pesticides, such as talc, clay, amorphous silicon dioxide, diatomaceous earth, perlite, calcium carbonate, and magnesium carbonate. In addition, resin powder such as vinyl chloride, chlorinated polyethylene, chlorinated polypropylene, sugars such as glucose, sugar, lactose, carboxymethyl cellulose or its salts, microcrystalline cellulose, wood flour, rice bran, wheat bran, rice husk powder, coffee Examples include organic substances such as bean powder, cellulose powder, and licorice powder, water-soluble metal salts such as sodium sulfate, ammonium sulfate, and potassium chloride, and urea. Preferred are water-soluble metal salts that dissolve in water and do not form precipitates. In addition, the amount of the extender to be blended is the minimum necessary amount excluding the essential components of the agrochemical composition for water surface application of the present invention. is usually 0.1 to 90% by weight, preferably 0.5 to 70% by weight.

The preservative used in the agricultural chemical composition for water surface application of the present invention is not particularly limited as long as it is commonly used in agricultural chemicals, and is preferably sorbic acid, potassium sorbate, parachlorometaxylenol, paraoxy butyl benzoate or sodium dehydroacetate. The proportion of the preservative used is usually 0.1-3% by weight, preferably 0.2-2% by weight, relative to the total amount of the composition.

The pH adjuster used in the agricultural chemical composition for application to water of the present invention is not particularly limited as long as it is commonly used in agricultural chemicals. Examples include inorganic acids such as phosphoric acid; organic acids such as sodium citrate, organic metal salts such as potassium hydrogen phthalate; disodium hydrogen phosphate, sodium dihydrogen phosphate, dipotassium hydrogen phosphate, potassium dihydrogen phosphate, sodium carbonate, potassium carbonate, inorganic metal salts such as sodium borate; hydroxides such as sodium hydroxide and potassium hydroxide; or organic amines such as triethanolamine; It is a salt or hydroxide, and more preferably hydrochloric acid, citric acid, succinic acid, sodium hydroxide, potassium hydroxide or sodium carbonate. In addition, the pH adjusters used can be used singly or in combination of two or more.

Next, the water surface application pesticide composition of the present invention and the method for producing the same will be described. In addition, the following description is an example, and does not limit the present invention. In order to produce the agricultural chemical composition for water surface application of the present invention, when the agricultural chemical active ingredient is solid, the agricultural chemical active ingredient is usually finely pulverized by a dry or wet method, and the pulverized product of the obtained agricultural chemical active ingredient is After mixing with grain nuclei having a specific gravity of less than 1, a spreading agent and other auxiliary agents, it is formulated into granules by dry or wet granulation. Wet molding machines to be used include extrusion granulators, mixing granulators, fluid bed granulators and tumbling granulators, and dry molding machines include roller compactors, tablet presses and briquetting machines. and hydraulic molding machines.

When the pesticidal composition for water surface application of the present invention is formulated into granules, after mixing grain nuclei having an apparent specific gravity of less than 1 and other necessary auxiliaries, the pesticidal active ingredient is contained using the above molding machine. It is also possible to preliminarily prepare a so-called "basic granule" containing only a part of the active ingredient and to coat or absorb the active ingredient of the pesticide together with the rest of the other ingredients, or to mix all the ingredients in advance. After that, it may be directly molded into granules using the molding machine described above.

When using a liquid agricultural chemical active ingredient or a liquid agricultural chemical active ingredient, it is absorbed into a grain nucleus having an apparent specific gravity of less than 1 or a carrier with oil absorption ability, and thereafter, the same method as for a solid agricultural chemical active ingredient is used. Alternatively, the granules and other auxiliaries of less than 1 are formed into granules in advance, and the liquid active ingredient of the agricultural chemical or the liquid active ingredient of the agricultural chemical is absorbed or coated in the form of the present invention. A surface-applied pesticide composition can be obtained.

When the agrochemical composition for water surface application of the present invention is a granule, the grain size of the granule is such that if there are many portions with a particle size larger than 0.6 mm, it is difficult for the granule to sink in water, or the rapid disintegration of the granules is suppressed. When the particle size is smaller than 5 mm, it is difficult for the particles to be blown away by the wind, and it does not take too long for the particles to disintegrate and disperse. Therefore, it is usually preferred that 90% or more of the granules fall within the range of 0.710 mm to 4.760 mm.

The agrochemical composition for water application of the present invention obtained in this manner is directly poured into paddy fields from a box, bottle, bag or the like fitted with an appropriate inlet, or is divided into water-soluble films or sheets. It can be thrown in from the ridge and so on. Since the pesticide composition for water surface application of the present invention is designed to release the active ingredient of the pesticide while spreading on the water surface, it does not need to enter the paddy field and uniformly spray unlike general granules. For this reason, it is possible to obtain a sufficient biological effect by appropriately treating it in paddy fields. The water-soluble film or sheet used in the present invention is a film or sheet having properties such that it dissolves or disperses in water. (e.g., non-woven fabric), pullulan film, sodium salt of carboxymethyl cellulose and cellulose, polyethylene oxide and derivatives thereof, and particularly polyvinyl alcohol or derivatives thereof. The film (hereinafter abbreviated as PVA film) itself easily disperses or dissolves in water, and has the property of spreading the agricultural chemical composition for water surface application of the present invention on the water surface.

The PVA film used in the present invention is, for example, a film made of polyvinyl alcohol having a degree of polymerization of 1000 to 2000 and a degree of saponification of 85 to 95% together with a small amount of plasticizer, stabilizer, etc. Also included are films containing a small amount of copolymers such as carboxylic acids in the polymer. The thickness of the PVA film is usually 25-70 μm, preferably 30-50 μm, considering film strength and dissolution time. Also, the ends of the PVA film are advantageously heat-sealable.

When packaged in the above PVA film, the weight of one package is usually 10 to 200 g, preferably 20 to 60 g, as a result of considering the ease of throwing, and the number of packages is usually 10. A sufficient biological effect can be exhibited by dropping 2 to 40 particles per are, preferably 4 to 20 particles.

The pesticidal composition for water surface application of the present invention and the control method using the composition are effective against, for example, the following types of plant diseases and pests and weeds. Specific pests to be controlled by the present invention are exemplified below.

Examples of plant diseases include Pyricularia oryzae, Thanatephorus cucumeris, Cochliobolus miyabeanus, Gibberella fujikuroi, and Pythium spp., Fusarium. spp., Trichoderma spp., Rhizopus spp., Rhizoctonia solani, etc.), rice malt (Claviceps virens), smut (Tilletia barelayana);
Powdery mildew of wheat (Erysiphe graminis f.sp.hordei;
f. sp. tritici), rust (Puccinia striiformis;
Ｐｕｃｃｉｎｉａ ｇｒａｍｉｎｉｓ、Ｐｕｃｃｉｎｉａ ｒｅｃｏｎｄｉｔａ、Ｐｕｃｃｉｎｉａ ｈｏｒｄｅｉ）、斑葉病（Ｐｙｒｅｎｏｐｈｏｒａ ｇｒａｍｉｎｅａ）、網斑病（Ｐｙｒｅｎｏｐｈｏｒａ ｔｅｒｅｓ）、赤かび病（Ｆｕｓａｒｉｕｍ ｇｒａｍｉｎｅａｒｕｍ、Ｆｕｓａｒｉｕｍ ｃｕｌｍｏｒｕｍ、Ｆｕｓａｒｉｕｍ ａｖｅｎａｃｅｕｍ、Ｍｉｃｒｏｄｏｃｈｉｕｍ ｎｉｖａｌｅ）、雪腐病（Ｔｙｐｈｕｌａ ｉｎｃａｒｎａｔａ、 Ｔｙｐｈｕｌａ ｉｓｈｉｋａｒｉｅｎｓｉｓ、Ｍｉｃｒｏｎｅｃｔｒｉｅｌｌａ ｎｉｖａｌｉｓ）、裸黒穂病（Ｕｓｔｉｌａｇｏ ｎｕｄａ、Ｕｓｔｉｌａｇｏ ｔｒｉｔｉｃｉ、Ｕｓｔｉｌａｇｏ ｎｉｇｒａ、Ｕｓｔｉｌａｇｏ ａｖｅｎａｅ）、なまぐさ黒穂病（Ｔｉｌｌｅｔｉａ ｃａｒｉｅｓ、Ｔｉｌｌｅｔｉａ ｐａｎｃｉｃｉｉ）、眼紋病（Ｐｓｅｕｄｏｃｅｒｃｏｓｐｏｒｅｌｌａ ｈｅｒｐｏｔｒｉｃｈｏｉｄｅｓ）、株腐病（Ｒｈｉｚｏｃｔｏｎｉａ ｃｅｒｅａｌｉｓ） , Rhynchosporium secalis, Septoria tritici, Leptosphaeria nodorum, Fusarium spp., Pythium spp., Rhizoctonia spp., Septoria nodorum. blight (Gaeumannomyces graminis), anthracnose (Colletotrichum gramaminicola), ergot (Claviceps purpurea), leaf spot (Cochliobolus sativus);
Fusarium head blight of corn (Fusarium graminearum, etc.), shoot-off blight (Fusarium avenaceum, Penicillium spp, Pythium spp., Rhizoctonia spp), rust (Puccinia sorghi), leaf blight (Cochliobolus heterostroph), smut maydis), Colletotrichum gramaminicola, Cochliobolus carbonum;
Grape downy mildew (Plasmopora viticola), rust (Phakopsora ampelopsidis), powdery mildew (Uncinula necator), black rot (Elsinoe ampelina), late rot (Glomerella cingulata), black rot (Guignardia bidwellii), vine Phomopsis viticola, Zygophila jamaicensis, Botrytis cinerea, Diaporthe medusaea, Helicobasidium mompa, Rosellinix necatrix;
Apple powdery mildew (Podosphaera leucotricha), scab (Venturia inaequalis), leaf spot (Alternaria alternata (Apple pathotype)), red star (Gymnosporangium yamadae), Monillia (Monillia sapomali), rot輪紋病（Ｂｏｔｒｙｏｓｐｈａｅｒｉａ ｂｅｒｅｎｇｅｒｉａｎａ）、炭疽病（Ｃｏｌｌｅｔｏｔｒｉｃｈｕｍ ａｃｕｔａｔｕｍ）、すす点病（Ｚｙｇｏｐｈｉａｌａ ｊａｍａｉｃｅｎｓｉｓ）、すす斑病（Ｇｌｏｅｏｄｅｓ ｐｏｍｉｇｅｎａ）、黒点病（Ｍｙｃｏｓｐｈａｅｒｅｌｌａ ｐｏｍｉ）、紫紋羽病（Ｈｅｌｉｃｏｂａｓｉｄｉｕｍ ｍｏｍｐａ）、白紋羽disease (Rosellinia necatrix), blight (Phomopsis mali, Diaporthe tanakae), brown spot (Diplocarpon mali);
Alternaria alternata (Japanese pear pathotype), Venturia nashicola, Gymnosporangium haraeanum, Physalospora piricola, Diaportheres, Diaporthe medusa Phytophthora cactorum;
Peach scab (Cladosporium carpophilum), Pomopsis sp., Phytophthora sp., Anthracnose (Gloeosporium laeticolor);
Anthracnose of cherry (Glomerella cingulata), fungal rot of young fruit (Monilinia kusanoi), ash star disease (Monilinia fructicola);
Oyster anthracnose (Gloeosporium kaki), defoliation (Cercospora kaki; Mycosphaerella nawae), powdery mildew (Phyllactinia kakikora);
citrus black spot (Diaporthe citri), green mold (Penicillium digitatum), blue mold (Penicillium italicum), scab (Elsinoe fawcettii);
Botrytis cinerea on tomatoes, cucumbers, beans, strawberries, potatoes, cabbage, eggplant, lettuce, etc.;
Sclerotinia sclerotiorum of tomatoes, cucumbers, beans, strawberries, potatoes, rapeseed, cabbage, eggplant, lettuce, etc.;
Seedling blight (Rhizoctonia spp., Pythium spp., Fusarium spp., Phythophthora spp., Sclerotinia sclerotiorum, etc.) of various vegetables such as tomatoes, cucumbers, beans, radishes, watermelons, eggplants, rapeseeds, green peppers, spinach, and sugar beets;
ウリ類のべと病（Ｐｓｅｕｄｏｐｅｒｏｎｏｓｐｏｒａ ｃｕｂｅｎｓｉｓ）、うどんこ病（Ｓｐｈａｅｒｏｔｈｅｃａ ｆｕｌｉｇｉｎｅａ）、炭疽病（Ｃｏｌｌｅｔｏｔｒｉｃｈｕｍ ｌａｇｅｎａｒｉｕｍ）、つる枯病（Ｍｙｃｏｓｐｈａｅｒｅｌｌａ ｍｅｌｏｎｉｓ）、つる割病（Ｆｕｓａｒｉｕｍ ｏｘｙｓｐｏｒｕｍ）、疫病（Ｐｈｙｔｏｐｈｔｈｏｒａ ｐａｒａｓｉｔｉｃａ、Ｐｈｙｔｏｐｈｔｈｏｒａ ｍｅｌｏｎｉｓ、 Phytophthora nicotianae, Phytophthora drechsleri, Phytophthora capsici, etc.);
トマトの輪紋病（Ａｌｔｅｒｎａｒｉａ ｓｏｌａｎｉ）、葉かび病（Ｃｌａｄｏｓｐｏｒｉｕｍ ｆｕｌｖａｍ）、疫病（Ｐｈｙｔｏｐｈｔｈｏｒａ ｉｎｆｅｓｔａｎｓ）、萎凋病（Ｆｕｓａｒｉｕｍ ｏｘｙｓｐｏｒｕｍ）、根腐病（Ｐｙｔｈｉｕｍ ｍｙｒｉｏｔｙｌｕｍ、Ｐｙｔｈｉｕｍ ｄｉｓｓｏｔｏｃｕｍ）、炭疽病（Ｃｏｌｌｅｔｏｔｒｉｃｈｕｍ ｐｈｏｍｏｉｄｅｓ）；
eggplant powdery mildew (such as Sphaerotheca fuliginea), sooty mildew (Mycovellosiella nattrassii), late blight (Phytophthora infestans), brown rot (Phytophthora capsici);
Rapeseed black spot (Alternaria brassicae), cruciferous vegetable black spot (Alternaria brassicae, etc.), white spot (Cercosporella brassicae), root rot (Leptospheria maculans), clubroot (Plasmodiophora brassicae), downy mildew (Plasmodiophora brassicae) Peronospora brassicae);
Cabbage stock rot (Rhizoctonia solani), chlorosis (Fusarium oxysporum);
Chinese cabbage end rot (Rhizoctonia solani), yellow spot (Verticillium dahlie);
Allium rust (Puccinia allii), black spot (Alternaria porri), white silk disease (Sclerotium rolfsii. Sclerotium rolfsii), white plague (Phytophthora porri);
Cercospora kikuchii, Elsinoe glycinnes, Diaporthe phaseololum, Rhizoctonia solani, Phytophthora megasperma, downy mildew, Peronosphaman rust of soybean (Phakopsora pachyrhizi), Anthrax (Colletotrichum truncatum);
Anthracnose of kidney beans (Colletotrichum lindemuthianum);
peanut black spot (Mycosphaerella personatum), brown spot (Cercospora arachidicola);
pea powdery mildew (Erysiphe pisi), downy mildew (Peronospora pisi);
fava bean downy mildew (Peronospora viciae), late blight (Phytophthora nicotianae);
Summer blight of potatoes (Alternaria solani), black bruise (Rhizoctonia solani), late blight (Phytophthora infestans), silver rot (Spondylocladium atrovirens), dry rot (Fusarium oxysporum, Fusarium solani), powdery mildew );
Cercospora beticola of sugar beet, Peronospora schachtii, Aphanomyces cochioides, Phoma batae;
Black leaf blight of carrots (Alternaria dauci);
powdery mildew of strawberries (Sphaerotheca humuli), late blight (Phytophthora nicotianae), anthracnose (Gromerella cingulata), fruit rot (Pythium ultimum Trow var. ultimate);
Exobasidium reticulatum of tea, Elsinoe leucospira, Colletotrichum theaesinensis, Pestalotiopsis longiseta;
Alternaria alternata (Tobacco pathotype), powdery mildew (Erysiphe cichoracearum), anthracnose (Colletotrichum tabacum), late blight (Phytophthora parasitica);
cotton wilt (Fusarium oxysporum);
sclerotinia of sunflower (Sclerotinia sclerotiorum);
rose scab (Diplocarpon rosae), powdery mildew (Sphaerotheca pannosa), late blight (Phytophthora megasperma), downy mildew (Peronospora sparsa);
Chrysanthemum brown spot (Septoria chrysanthemi-indici), white rust (Puccinia horiana), late blight (Phytophthora cactorum); Curvularia geniculata), Rust (Puccinia zoysiae), Helminthporium leaf blight (Cochliobolus sp.), Rhynchosporium secalis, Take-off (Gaeumannomyces graminis), Anthracnose (Colletotrichuma brown) Sclerotinia (Typula incarnata), snow rot black small sclerotinia (Typula ishikariensis), snow rot large sclerotinia (Sclerotinia borealis), fairy ring (Marasmius oreades, etc.), pythium disease (Pythium aphanidermatum, etc.), etc. However, it is not limited to these.

In addition, pests include, for example, Anguinea: ANGUINIDAE such as Anguina agristis, Anguina tritici, Ditylenchus destructor, etc., and TYLENCHORYNCHIDAE such as Tylenchorhynchus,クセンチュウ（Ｔｙｌｅｎｃｈｏｒｈｙｎｃｈｕｓ ｍａｒｔｉｎｉ）、イシュクセンチュウ（Ｔｙｌｅｎｃｈｏｒｈｙｎｃｈｕｓ ｓｐ．）など、ＰＲＡＴＹＬＥＮＣＨＩＤＡＥとして、イマムラネモグリセンチュウ（Ｈｉｒｓｃｈｍａｎｎｉｅｌｌａ ｉｍａｍｕｒｉ）、イネネモグリセンチュウ（Ｈｉｒｓｃｈｍａｎｎｉｅｌｌａ ｏｒｙｚａｅ）、ミナミネグサレセンチュウ（Ｐｒａｔｙｌｅｎｃｈｕｓ ｃｏｆｆｅａｅ）、スズランネグサレセンチュウ（Ｐｒａｔｙｌｅｎｃｈｕｓ ｃｏｎｖａｌｌａｒｉａｅ）、キクネグサレセンチュウ（Ｐｒａｔｙｌｅｎｃｈｕｓ ｆａｌｌａｘ）、チャネグサレセンチュウ（Ｐｒａｔｙｌｅｎｃｈｕｓ ｌｏｏｓｉ）、ムギネグサレセンチュウ（Ｐｒａｔｙｌｅｎｃｈｕｓ ｎｅｇｌｅｃｔｕｓ）、キタネグサレセンチュウ（Ｐｒａｔｙｌｅｎｃｈｕｓ ｐｅｎｎｔｒａｎｓ）、ネグサレセンチュウ（Ｐｒａｔｙｌｅｎｃｈｕｓ ｓｐ．）など、ＨＯＰＬＯＬＡＭＩＤＡＥとして、ナミラセンセンチュウ（Ｈｅｌｉｃｏｔｙｌｅｎｃｈｕｓ ｄｉｈｙｓｔｅｒａ）、チャラセンセンチュウ（Ｈｅｌｉｃｏｔｙｌｅｎｃｈｕｓ ｅｒｙｔｈｒｉｎａｅ）、ラセンセンチュウ（Ｈｅｌｉｃｏｔｙｌｅｎｃｈｕｓ ｓｐ．）、ヤリセンチュウ（Ｈｏｐｏｌａｉｍｕｓ ｓｐ．）、ニセフクロセンチュウ（Ｒｏｔｙｌｅｎｃｈｕｌｕｓ ｒｅｎｉｆｏｒｍｉｓ）、ブラキュルムラセンセンチュウ（Ｓｓｕｔｅｌｌｏｎｅｍａ ｂｒａｃｈｙｕｒｕｍ） Such as HETERODERIDAE, wheat cyst nematode (Bidera avenae), cactusist nematode (Cactodera cacti), false cyst nematode (Cryphodera sp.), potato cyst nematode (Globodera rostochiensis), rice cyst nematode (heterodera elachista),ダイズシストセンチュウ（ｈｅｔｅｒｏｄｅｒａ ｇｌｙｃｉｎｅｓ）、クローバーシストセンチュウ（ｈｅｔｅｒｏｄｅｒａ ｔｒｉｆｏｌｉｉ）など、ＭＥＬＯＩＤＯＧＹＮＩＤＡＥとして、アレナリアネコブセンチュウ（Ｍｅｌｏｉｄｏｇｙｎｅ ａｒｅｎａｒｉａ）、ツバキネコブセンチュウ（Ｍｅｌｏｉｄｏｇｙｎｅ ｃａｍｅｌｌｉａｅ）、シバネコブセンチュウ（Ｍｅｌｏｉｄｏｇｙｎｅ ｇｒａｍｉｎｉｓ）、キタネコブセンチュウ（Ｍｅｌｏｉｄｏｇｙｎｅ ｈａｐｌａ）、サツマイモMeloidogyne incognita, Meloidogyne sp. )Such,
DORYLAIMIDA: as LONGIDORIDAE, as TRICEDO, including Longidorus martini, Longidorus sp., Xiphinema americanum, Xiphinema sp. , such as Trichodorus sp.
ダニ目（ＡＣＡＲＩＮＡ）：ＴＡＲＳＯＮＥＭＩＤＡＥとして、チャノホコリダニ（Ｐｏｌｙｐｈａｇｏｔａｒｓｏｎｅｍｕｓ ｌａｔｕｓ）、シクラメンホコリダニ（Ｓｔｅｎｅｏｔａｒｓｏｎｅｍａｕ ｐａｌｌｉｄｕｓ）、アシボソホコリダニ（Ｔａｒｓｏｎｅｍｕｓ ｗａｉｔｅｉ）など、ＰＹＥＭＯＴＩＤＡＥとして、シラミダニ（Ｐｙｅｍｏｔｅｓ ｖｅｎｔｒｉｃｏｓｕｓ）など、ＥＵＰＯＤＩＤＡＥとして、ムギダニ（Ｐｅｎｔｈａｌｅｕｓ ｍａｊｏｒ）など、 ＴＥＮＵＩＰＡＬＰＩＤＡＥとして、ブドウヒメハダニ（Ｂｒｅｖｉｐａｌｐｕｓ ｌｅｗｉｓｉ）、チャノヒメハダニ（Ｂｒｅｖｉｐａｌｐｕｓ ｏｂｏｖａｔｕｓ）、パイナップルヒメハダニ（Ｄｏｌｉｃｈｏｔｅｔｒａｎｙｃｈｕｓ ｆｌｏｒｏｄａｎｕｓ）、カキヒメハダニ（Ｔｅｎｕｉｐａｌｐｕｓ ｚｈｉｚｈｉｌａｓｈｖｉｌｉａｅ）など、ＴＵＣＫＥＲＥＬＬＩＤＡＥとして、ナミケナガハダニ（Ｔｕｃｋｅｒｅｌｌａ ｐａｖｏｎｉｆｏｒｍｉｓ）など、ＴＥＴＲＡＮＹＣＨＩＤＡＥとして、クローバーハダニ（Ｂｒｙｏｂｉａ ｐｒａｅｔｉｏｓａ ）、ニセクローバーハダニ（Ｂｒｙｏｂｉａ ｒｕｂｒｉｏｃｕｌｕｓ）、アンズハダニ（Ｅｏｔｅｔｒａｎｙｃｈｕｓ ｂｏｒｅｕｓ）、ミチノクハダニ（Ｅｏｔｅｔｒａｎｙｃｈｕｓ ｇｅｎｉｃｕｌａｔｕｓ）、クリハダニ（Ｅｏｔｅｔｒａｎｙｃｈｕｓ ｐｒｕｎｉ）、コウノシロハダニ（Ｅｏｔｅｔｒａｎｙｃｈｕｓ ｓｅｘｍａｎａｃｕｌａｔｕｓ）、スミスハダニ（Ｅｏｔｅｔｒａｎｙｃｈｕｓ ｓｍｉｔｈｉ）、クルミハダニ（Ｅｏｔｅｔｒａｎｙｃｈｕｓ ｕｎｃａｔｕｓ）、スギノハダニ（Ｏｌｉｇｏｎｙｃｈｕｓ ｈｏｎｄｏｅｎｓｉｓ）、チビコブハダニ（Ｏｌｉｇｏｎｙｃｈｕｓ ｉｌｉｃｉｓ）、カラマツハダニ（Ｏｌｉｇｏｎｙｃｈｕｓ ｋａｒａｍａｔｕｓ）、ミカンハダニ（Ｐａｎｏｎｙｃｈｕｓ ｃｉｔｒｉ）、リンゴハダニ（Ｐａｎｏｎｙｃｈｕｓ ｕｌｍｉ）、ニセナミハダニ（Ｔｅｔｒａｎｙｃｈｕｓ ｃｉｎｎａｂａｒｉｎｕｓ）、カンザワハダニ（Ｔｅｔｒａｎｙｃｈｕｓ ｋａｎｚａｗａｉ）、ナミハダニ（Ｔｅｔｒａｎｙｃｈｕｓ ｕｒｔｉｃａｅ）、 such as Tetranychus viennensis, as ERIOPHIDAE, Acaphylla theae,チューリップサビダニ（Ａｃｅｒｉａ ｔｕｌｉｐａｅ）、ミカンサビダニ（ａｃｕｌｏｐｓ ｐｅｌｅｋａｓｓｉ）、モモサビダニ（Ａｃｕｌｕｓ ｆｏｃｋｅｕｉ）、リンゴサビダニ（Ａｃｕｌｕｓ ｓｃｈｌｅｃｈｔｅｎｄａｌｉ）、チャノサビダニ（Ｃａｌａｃａｒｕｓ ｃａｒｉｎａｔｕｓ）、ブドウサビダニ（Ｃａｌｅｐｉｔｒｉｍｅｒｕｓ ｖｉｔｉｓ）、ナシサビダニ（Ｅｐｉｔｒｉｍｅｒｕｓ ｐｙｒｉ）、ニセナシサビダニ（ Eriophyes chibaensis), ACARIDAE such as Acarus siro, Aleuroglyphus ovatus, Rhizoglyphus robini, Tyrophagus putrescentiae, etc.
Thysanura: Lepismatidae such as Ctenolepisma villosa, Lepisma saccharina, Thermobia domestica, etc.
直翅目（ｏｒｔｈｏｐｔｅｒａ）：ＢＬＡＴＴＩＤＡＥとして、ワモンゴキブリ（Ｐｅｒｉｐｌａｎｅｔａ ａｍｅｒｉｃａｎａ）、クロゴキブリ（Ｐｅｒｉｐｌａｎｅｔａ ｆｕｌｉｇｉｎｏｓａ）、ヤマトゴキブリ（Ｐｅｒｉｐｌａｎｅｔａ ｊａｐｏｎｉｃａ）など、ＢＬＡＴＴＥＬＬＩＤＡＥとして、チャバネゴキブリ（Ｂｌａｔｔｅｌｌａ ｇｅｒｍａｎｉｃａ）、ヒメチャバネゴキブリ（Ｂｌａｔｔｅｌｌａ ｌｉｔｕｒｉｃｏｌｌｉｓ）など、ＴＥＴＴＩＧＯＮＩＩＤＡＥとして, Homorocoryphus jezoensis, Homorocoryphus lineosus, etc. GRYLLOTALPIDAE, such as Kera (Gryllotalpa sp.), ACRIDIDAE, Oxya hyla intricata, Oxyaisye, etc.
Termites (ISOPTERA): Cryptotermes domesticus, Coptotermes formosanus, Reticulitermes formosanus, Odontotermes formosanus, etc.
アザミウマ目（ＴＨＹＳＡＮＯＰＴＥＲＡ）：ＴＨＲＩＰＩＤＡＥとして、クサキイロアザミウマ（Ａｎａｐｈｏｔｈｒｉｐｓ ｏｂｓｃｕｒｕｓ）、トゲブトアザミウマ（Ｃｈｉｒｏｔｈｒｉｐｓ ｍａｎｉｃａｔｕｓ）、チャノクロアザミウマ（Ｄｅｎｄｒｏｔｈｒｉｐｓ ｍｉｎｏｗａｉ）、ヒラズハナアザミウマ（Ｆｒａｎｋｌｉｎｉｅｌｌａ ｉｎｔｏｎｓａ）、ユリキイロアザミウマ（Ｆｒａｎｋｌｉｎｉｅｌｌａ ｌｉｌｉｖｏｒａ）、クロトンアザミウマ（ Ｈｅｌｉｏｔｈｒｉｐｓ ｈａｅｍｏｒｒｈｏｉｄａｌｉｓ）、コスモスアザミウマ（Ｍｉｃｒｏｃｅｐｈａｌｏｔｈｒｉｐｓ ａｂｄｏｍｉｎａｌｉｓ）、ダイズアザミウマ（Ｍｙｃｔｅｒｏｔｈｒｉｐｓ ｇｌｙｃｉｎｅｓ）、クワアザミウマ（Ｐｓｅｕｄｏｄｅｎｄｒｏｔｈｒｉｐｓ ｍｏｒｉ）、チャノキイロアザミウマ（Ｓｃｉｒｔｏｔｈｒｉｐｓ ｄｏｒｓａｌｉｓ）、アカオビアザミウマ（Ｓｅｌｅｎｏｔｈｒｉｐｓ ｒｕｂｒｏｃｉｎｃｔｕｓ）、イネアザミウマ（Ｓｔｅｎｃｈａｅｔｏｔｈｒｉｐｓ ｂｉｆｏｒｍｉｓ）、ネギクロアザミウマ（Ｔｈｒｉｐｓ ａｌｌｉｏｒｕｍ）、ビワハナアザミウマ（Ｔｈｒｉｐｓ ｃｏｌｏｒａｔｕｓ）、キイロハナアザミウマ（Ｔｈｒｉｐｓ ｆｌａｖａｓ）、ハナアザミウマ（Ｔｈｒｉｐｓ ｈａｗａｉｉｅｎｓｉｓ）、クロゲハナアザミウマ（Ｔｈｒｉｐｓ ｎｉｇｒｏｐｉｌｏｓｕｓ）、ミナミキイロアザミウマ（Ｔｈｒｉｐｓ ｐａｌｍｉ）、ミカンキイロアザミウマ（Ｆｒａｎｋｌｉｎｉｅｌｌａ Occidentalis), Thrips setosus, Gladiolus thrips (Thrips simplex), Thrips tabaci, etc., as PHLAEOTHRIPIDAE, Rice thrips (Haplothrips aculeatus), Chinese thrips (Haplothrips), Haplothrips kurdjumovi, Haplothrips nigar, Leeuwania pasanii, Liothrips flordensis, Liothrips vaneeckei thrips (Litotetothrips pasaniae), persimmon thrips (Ponticulothrips diospyrosi), etc.
半翅目（ＨＥＭＩＰＴＥＲＡ）：ＰＥＮＴＡＴＯＭＩＤＡＥとして、ムラサキカメムシ（Ｃａｒｐｏｃｏｒｉｓ ｐｕｒｐｕｒｅｉｐｅｎｎｉｓ）、ブチヒゲカメムシ（Ｄｏｌｙｃｏｒｉｓ ｂａｃｃａｒｕｍ）、ヒメナガメ（Ｅｕｒｙｄｅｍａ ｐｕｌｃｈｒｕｍ）、ナガメ（Ｅｕｒｙｄｅｍａ ｒｕｇｏｓｕｍ）、マルシラホシカメムシ（Ｅｙｓａｒｃｏｒｉｓ ｇｕｔｔｉｇｅｒ）、オオトゲシラホシカメムシ（ Ｅｙｓａｒｃｏｒｉｓ ｌｅｗｉｓｉ）、トゲシラホシカメムシ（Ｅｙｓａｒｃｏｒｉｓ ｐａｒｖｕｓ）、シラホシカメムシ（Ｅｙｓａｒｃｏｒｉｓ ｖｅｎｔｒａｌｉｓ）、ツヤアオカメムシ（Ｇｌａｕｃｉａｓ ｓｕｂｐｕｎｃｔａｔｕｓ）、アカスジカメムシ（Ｇｒａｐｈｏｓｏｍａ ｒｕｂｒｏｌｉｎｅａｔｕｍ）、クサギカメムシ（Ｈａｌｙｏｍｏｒｐｈａ ｍｉｓｔａ）、イネカメムシ（Ｌａｇｙｎｏｔｏｍｕｓ ｅｌｏｎｇａｔｕｓ）、アオクサカメムシ（ Ｎｅｚａｒａ ａｎｔｅｎｎａｔａ）、ミナミアオカメムシ（Ｎｅｚａｒａ ｖｉｒｉｄｕｌａ）、イチモンジカメムシ（Ｐｉｅｚｏｄｏｒｕｓ ｈｙｂｎｅｒｉ）、チャバネアオカメムシ（Ｐｌａｕｔｉａ ｓｔａｌｉ）、イネクロカメムシ（Ｓｃｏｔｉｎｏｐｈａｒａ ｌｕｒｉｄａ）、イワサキカメムシ（Ｓｔａｒｉｏｄｅｓ ｉｗａｓａｋｉｉ）など、ＣＯＲＥＩＤＡＥとして、ホオズキカメムシ（Ａｃａｎｔｈｏｃｏｒｉｓ sordidus), large spider stink bug (Anacanthocoris striicornis), beetle stink bug (Cletus punctiger), lesser stink bug (Cletus trigonus), stink bug (Molipteryx fulginosa), etc., as ALYDIDAE, bean stink bug (Leptocoris), RHOPALIDAE such as Leptocorisa chinensis, Leptocorisa oratorius, Riptortus clavatus, Liorhyalhyssus, etc. Long-tailed stink bug (Cavelerius sacch) ａｒｉｖｏｒｕｓ）、ホソコバネナガカメムシ（Ｍａｃｒｏｐｅｓ ｏｂｎｕｂｉｌｕｓ）、ヒラタヒョウタンナガカメムシ（Ｐａｃｈｙｂｒａｃｈｉｕｓ ｌｕｒｉｄｕｓ）、クロアシホソナガカメムシ（Ｐａｒｏｍｉｕｓ ｅｘｇｕｕｓ）、コバネヒョウタンナガカメムシ（Ｔｏｇｏ ｈｅｍｉｐｔｅｒｕｓ）など、ＰＹＲＲＨＯＣＯＲＩＤＡＥとして、アカホシカメムシ（Ｄｙｓｄｅｒｃｕｓ ｃｉｎｇｕｌａｔｕｓ）、ヒメアカホシカメムシ（Ｄｙｓｄｅｒｃｕｓ ｐｏｅｃｉｌｕｓ）など、ＴＩＮＧＩＤＡＥとして、キクグンバイ（Ｇａｌｅａｔｕｓ ｓｐｉｎｉｆｒｏｎｓ）、ヤナギグンバイ（Ｍｅｔａｓａｌｉｓ ｐｏｐｕｌｉ）、クスグンバイ（Ｓｔｅｐｈａｎｉｔｉｓ ｆａｓｃｉｉｃａｒｉｎａ）、ナシグンバイ（Ｓｔｅｐｈａｎｉｔｉｓ ｓａｓｈｉ）、ツツジグンバイ（Ｓｔｅｐｈａｎｉｔｉｓ ｐｙｒｉｏｉｄｅｓ）、ヒメグンバイ（Ｕｈｌｅｒｉｔｅｓ ｄｅｂｉｌｅ）、クルミグンバイ（Ｕｈｌｅｒｉｔｅｓ ｌａｔｉｕｓ）など、ＭＩＲＩＤＡＥとして、ヒゲナガカスミカメ（Ａｄｅｌｐｈｏｃｏｒｉｓ ｌｉｎｅｏｌａｔｕｓ）、ブチヒゲクロカスミカメ（Ａｄｅｌｐｈｏｃｏｒｉｓ ｔｒｉａｎｎｕｌａｔｕｓ）、コアオカスミカメ（Ａｐｏｌｙｇｕｓ ｌｕｃｏｒｕｍ）、ツマグロアオカスミカメ（Ａｐｏｌｙｇｕｓ ｓｐｉｎｏｌａｉ）、アカホシカスミカメ（Ｃｒｅｏｎｔｉａｄｅｓ ｐａｌｌｉｄｉｆｅｒ）、タバコカスミカメ（Ｃｙｒｔｏｐｅｌｔｉｓ ｔｅｎｎｕｉｓ）、オオクロトビカスミカメ（Ｅｃｔｏｍｅｔｏｐｔｅｒｕｓ ｍｉｃａｎｔｕｌｕｓ）、クロトビカスミカメ（Ｈａｌｔｉｃｉｅｌｌｕｓ ｉｎｓｕｌａｒｉｓ）、リンゴクロカスミカメ（Ｈｅｔｅｒｏｃｏｒｄｙｌｕｓ ｆｌａｖｉｐｅｓ）、マキバカスミカメ（Ｌｙｇｕｓ ｄｉｓｐｏｎｓｉ）、マダラカスミカメ（Ｌｙｇｕｓ ｓａｕｎｄｅｒｓｉ）、テンサイカスミカメ（ｏｒｔｈｏｔｙｌｕｓ ｆｌａｖｏｓｐａｒｓｕｓ ), Stenodema calcaratum, Stenotus binotatus, Stenotus rubrovittatus, Taylorlygus pallidulus, Trigonotylus coel ｅｓｔｉａｌｉｕｍ）など、ＣＩＣＡＤＩＤＡＥとして、アブラゼミ（Ｇｒａｐｔｏｐｓａｌｔｒｉａ ｎｉｇｒｏｆｕｓｃａｔａ）など、ＡＰＨＲＯＰＨＯＲＩＤＡＥとして、マエキアワフキ（Ａｐｈｒｏｐｈｏｒａ ｃｏｓｔａｌｉｓ）、マツアワフキ（Ａｐｈｒｏｐｈｏｒａ ｆｌａｖｉｐｅｓ）、ブドウアワフキ（Ａｐｈｒｏｐｈｏｒａ ｉｎｔｅｒｍｅｄｉａ）、ヒメフタテンナガアワフキ（Ｃｌｏｖｉａ ｐｕｎｃｔａｔａ）、ホソアワフキ（Ｐｈｉｌａｅｎｕｓ ｓｐｕｍａｒｉｕｓ ）など、ＴＥＴＴＩＧＥＬＬＩＤＡＥとして、ツマグロオオヨコバイ（Ｂｏｔｈｒｏｇｏｎｉａ ｊａｐｏｎｉｃａ）、オオヨコバイ（Ｃｉｃａｄｅｌｌａ ｖｉｒｉｄｉｓ）など、ＣＩＣＡＤＥＬＬＩＤＡＥとして、カシヒメヨコバイ（Ａｇｕｒｉａｈａｎａ ｑｕｅｒｃｕｓ）、ハンノヒメヨコバイ（Ａｌｎｅｔｏｉｄｉａ ａｌｎｅｔｉ）、カンキツヒメヨコバイ（Ａｐｈｅｌｉｏｎａ ｆｅｒｒｕｇｉｎｅａ）、フタテンヒメヨコバイ（Ａｒｂｏｒｉｄｉａ ａｐｉｃａｒｉｓ）、ミドリヒメヨコバイ（Ｅｄｗａｒｄｓｉａｎａ ｆｌａｖｅｓｃｅｎｓ）、バラヒメヨコバイ（Ｅｄｗａｒｄｓｉａｎａ ｒｏｓａｅ）、マツヒメヨコバイ（Ｅｍｐｏａｓｃａ ａｂｉｅｔｉｓ）、チャノミドリヒメヨコバイ（Ｅｍｐｏａｓｃａ ｏｎｕｋｉｉ）、イネキイロヒメヨコバイ（Ｔｈａｉａ ｓｕｂｒｕｆａ）、ミカンヒメヨコバイ（Ｚｙｇｉｎｅｌｌａ ｃｉｔｒｉ）など、ＤＥＬＴＯＣＥＰＨＡＬＩＤＡＥとして、フタテンヨコバイ（Ｍａｃｒｏｓｔｅｌｅｓ ｆａｓｃｉｆｒｏｎｓ）、ツマグロヨコバイ（Ｎｅｐｈｏｔｅｔｔｉｘ ｃｉｎｃｔｉｃｅｐｓ）、クロスジツマグロヨコバイ（Ｎｅｐｈｏｔｅｔｔｉｘ ｎｉｇｒｏｐｉｃｔｕｓ）、タイワンツマグロヨコバイ（Ｎｅｐｈｏｔｅｔｔｉｘ ｖｉｒｅｓｃｅｎｓ）、リンゴマダラヨコバイ（Ｏｒｉｅｎｔｕｓ ｉｓｈｉｄａｉ）、イナズマヨコバイ(Recilia dorsalis), wheat leafhopper (Sorhoanus tritici), Hannonaga leafhopper (Speusottettix subfusculus), etc., as DELPHACIDAE, Laodelphax striatellus, brown planthopper (Nilaparvata lugens), sugar planthopper (Nilaparvata lugens)ウモロコシウンカ（Ｐｅｒｅｇｒｉｎｕｓ ｍａｉｄｉｓ）、クロフツノウンカ（Ｐｅｒｋｉｎｓｉｅｌｌａ ｓａｃｃｈａｒｉｃｉｄａ）、セジロウンカ（Ｓｏｇａｔｅｌｌａ ｆｕｒｃｉｆｅｒａ）、ヒエウンカ（Ｓｏｇａｔｅｌｌａ ｐａｎｉｃｉｃｏｌａ）など、ＰＳＹＬＬＩＤＡＥとして、クワキジラミ（Ａｎｏｍｏｍｅｕｒａ ｍｏｒｉ）、セグロヒメキジラミ（Ｃａｌｏｐｈｙａ ｎｉｇｒｉｄｏｒｓａｌｉｓ）、ミカンキジラミ（Ｄｉａｐｈｏｒｉｎａ ｃｉｔｒｉ） 、ヤマアサキジラミ（Ｍｅｓｏｈｏｍｏｔｏｍａ ｃａｍｐｈｏｒａｅ）、トドキジラミ（Ｐｓｙｌｌａ ａｂｉｅｔｉ）、ハンノキジラミ（Ｐｓｙｌｌａ ａｌｎｉ）、ヤマトキジラミ（Ｐｓｙｌｌａ ｊａｍａｔｏｎｉｃａ）、リンゴキジラミ（Ｐｓｙｌｌａ ｍａｌｉ）、クロリンゴキジラミ（Ｐｓｙｌｌａ ｍａｌｉｖｏｒｅｌｌａ）、ナシジキラミ（Ｐｓｙｌｌａ ｐｙｒｉｓｕｇａ）、トベラキジラミ（ Ｐｓｙｌｌａ ｔｏｂｉｒａｅ）、クストガリキジラミ（Ｔｒｉｏｚａ ｃａｍｐｈｏｒａｅ）、クリトガリキジラミ（Ｔｒｉｏｚａ ｑｕｅｒｃｉｃｏｌａ）など、ＡＬＥＹＲＯＤＩＤＡＥとして、ミカントゲコナジラミ（Ａｌｅｕｒｏｃａｎｔｈｕｓ ｓｐｉｎｉｆｅｒｕｓ）、ブドウコナジラミ（Ａｌｅｕｒｏｌｏｂｕｓ ｔａｏｎａｂａｅ）、タバココナジラミ（Ｂｅｍｉｓｉａ ｔａｂａｃｉ）、ミカンコナジラミ（Ｄｉａｌｅｕｒｏｄｅｓ ｃｉｔｒｉ）、オンシツコナジラミ（Ｔｒｉａｌｅｕｒｏｄｅｓ ｖａｐｏｒａｒｉｏｒｕｍ）、シルバーリーフコナジラミなど、ＰＨＹＬＬＯＸＥＲＩＤＡＥとして、ブドウネアブラムシ（Ｖｉｔｅｕｓ ｖｉｔｉｆｏｌｉｉ）など、ＰＥＭＰＨＩＧＩＤＡＥとして、リンゴネアブラムシ（Ａｐｈｉｄｏｎｕｇｕｉｓ ｍａｌｉ）、リンゴワタムシ（Ｅｒｉｏｓｏｍａ ｌａｎｉｇｅｒｕｍ）、サトウキビネワタムシ（Ｇｅｏｉｃａ ｌｕｃｉｆｕｇａ )Such,
ＡＰＨＩＤＩＤＡＥとして、エンドウヒゲナガアブラムシ（Ａｃｙｒｔｈｏｓｉｐｈｏｎ ｐｉｓｕｍ）、ユキヤナギアブラムシ（Ａｐｈｉｓ ｃｉｔｒｉｃｏｌａ）、マメアブラムシ（Ａｐｈｉｓ ｃｒａｃｃｉｖｏｒａ）、ヤナギアブラムシ（Ａｐｈｉｓ ｆａｒｉｎｏｓｅ ｙａｎａｇｉｃｏｌａ）、ワタアブラムシ（Ａｐｈｉｓ ｇｏｓｓｙｐｉｉ）、ジャガイモヒゲナガアブラムシ（Ａｕｌａｃｏｒｔｈｕｍ ｓｏｌａｎｉ）、ムギワラギクオマルアブラムシ（Ｂｒａｃｈｙｃａｕｄｕｓ ｈｅｌｉｃｈｒｙｓｉ）、ダイコンアブラムシ（Ｂｒｅｖｉｃｏｒｙｎｅ ｂｒａｓｓｉｃａｅ）、チューリップネアブラムシ（Ｄｙｓａｐｈｉｓ ｔｕｌｉｐａｅ）、カバワタフキマダラアブラムシ（Ｅｕｃｅｒａｐｈｉｓ ｐｕｎｃｔｉｐｅｎｎｉｓ）、モモコフキアブラムシ（Ｈｙａｌｏｐｔｅｒｕｓ ｐｒｕｎｉ）、ニセダイコンアブラムシ（Ｌｉｐａｐｈｉｓ ｅｒｙｓｉｍｉ）、キクヒメヒゲナガアブラムシ（Ｍａｃｒｏｓｉｐｈｏｎｉｅｌｌａ ｓａｎｂｏｒｎｉ）、チューリップヒゲナガアブラムシ（Ｍａｃｒｏｓｉｐｈｕｍ ｅｕｐｈｏｒｂｉａｅ）、ソラマメヒゲナガアブラムシ（Ｍｅｇｏｕｒａ ｃｒａｓｓｉｃａｕｄａ）、ナシコフキアブラムシ（Ｍｅｌａｎａｐｈｉｓ ｓｉｐｈｏｎｅｌｌａ）、リンゴコブアブラムシ（Ｍｙｚｕｓ ｍａｌｉｓｕｃｔｕｓ）、ウメコブアブラムシ（Ｍｙｚｕｓ ｍｕｍｅｃｏｌａ）、モモアカアブラムシ（Ｍｙｚｕｓ ｐｅｒｓｉｃａｅ）、ネギアブラムシ（Ｎｅｏｔｏｘｏｐｔｅｒａ ｆｏｒｍｏｓａｎａ）、リンゴミドリアブラムシ（Ｏｖａｔｕｓ ｍａｌｉｃｏｌｅｎｓ）、ハスクビレアブラムシ（Ｒｈｏｐａｌｏｓｏｐｈｕｍ ｎｙｍｐｈａｅａｅ）、ムギクビレアブラムシ（Ｒｈｏｐａｌｏｓｏｐｈｕｍ ｐａｄｉ）、オカボノアカアブラムシ（Ｒｈｏｐａｌｏｓｏｐｈｕｍ ｒｕｆｉａｂｄｏｍｉｎａｌｉｓ）、ナシマルアブラムシ（Ｓａｐｐａｐｈｉｓ ｐｉｒｉ） , Schizaphis piricola, Sitobion akebiae, Sitobion ibarae, Toxoptera aurantii, Toxoptera citricidus, Peach aphid (Tubercidus) ｅｐｈａｌｕｓ ｍｏｍｏｎｉｓ）、タイワンヒゲナガアブラムシ（Ｕｒｏｅｕｃｏｎ ｆｏｒｍｏｓａｎｕｍ）など、ＭＡＲＧＡＲＯＤＩＤＡＥとして、オオワラジカイガラムシ（Ｄｒｏｓｉｃｈａ ｃｏｒｐｕｌｅｎｔａ）、イセリアカイガラムシ（Ｉｃｅｒｙａ ｐｕｒｃｈａｓｉ）など、ＰＳＥＵＤＯＣＯＣＣＩＤＡＥとして、マツモトコナカイガラムシ（Ｃｒｉｓｉｃｏｃｃｕｓ ｍａｔｓｕｍｏｔｏｉ）、マツコナカイガラムシ（Ｃｒｉｓｉｃｏｃｃｕｓ ｐｉｎｉ） 、ナシコナカイガラムシ（Ｄｙｓｍｉｃｏｃｃｕｓ ｗｉｓｔａｒｉａｅ）、ミカンコナカイガラムシ（Ｐｌａｎｏｃｏｃｃｕｓ ｃｉｔｒｉ）、フジコナカイガラムシ（Ｐｌａｎｏｃｏｃｃｕｓ ｋｒａｎｕｈｉａｅ）、ミカンヒメコナカイガラムシ（Ｐｓｅｕｄｏｃｏｃｃｕｓ ｃｉｔｒｉｃｕｌｕｓ）、クワコナカイガラムシ（Ｐｓｅｕｄｏｃｏｃｃｕｓ ｃｏｍｓｔｏｃｋｉ）など、ＣＯＣＣＩＤＡＥとして、ツノロウムシ（Ｃｅｒｏｐｌａｓｔｅｓ ｃｅｒｉｆｅｒｕｓ ）、ルビーロウムシ（Ｃｅｒｏｐｌａｓｔｅｓ ｒｕｂｅｎｓ）、ミカンヒラタカイガラムシ（Ｃｏｃｃｕｓ ｄｉｓｃｒｅｐａｎｓ）、ヒラタカタカイガラムシ（Ｃｏｃｃｕｓ ｈｅｓｐｅｒｉｄｕｍ）、カンキツカタカイガラムシ（Ｃｏｃｃｕｓ ｐｓｅｕｄｏｍａｇｎｏｌｉａｒｕｍ）、イボタロウムシ（Ｅｒｉｃｅｒｕｓ ｐｅｌａ）、ミズキカタカイガラムシ（Ｌｅｃａｎｉｕｍ ｃｏｒｎｉ）、チャノカタカイガラムシ（ Ｌｅｃａｎｉｕｍ ｐｅｒｓｉｃａｅ）、ミカンワタカイガラムシ（Ｐｕｌｖｉｎａｒｉａ ａｕｒａｎｔｉｉ）、ミカンヒメワタカイガラムシ（Ｐｕｌｖｉｎａｒｉａ ｃｉｔｒｉｃｏｌａ）、クワワタカイガラムシ（Ｐｕｌｖｉｎａｒｉａ ｋｕｗａｃｏｌａ）など、ＤＩＡＳＰＩＤＩＤＡＥとして、カンキツカイガラムシ（Ａｎｄａｓｐｉｓ ｋａｓｈｉｃｏｌａ）、アカマルカイガラムシ（Ａｏｎｉｄｉｅｌｌａ ａｕｒａｎｔｉｉ）、キマルカイガラムシ（ Aonidiella citrina), Aspidiotus destructor, Aspidiotus hederae, Chrysophalus ficus, Nashimaru scale (San Jose scale: Comstockspis pern ｉｃｉｏｓａ）、クロカタマルカイガラムシ（Ｄｕｐｌａｓｐｉｄｉｏｔｕｓ ｃｌａｖｉｇｅｒ）、ミカンカキカイガラムシ（Ｌｅｐｉｄｏｓａｐｈｅｓ ｂｅｃｋｉｉ）、リンゴカキカイガラムシ（Ｌｅｐｉｄｏｓａｐｈｅｓ ｕｌｍｉ）、ナシシロナガカイガラムシ（Ｌｅｐｈｏｌｅｕｃａｓｐｉｓ ｊａｐｏｎｉｃａ）、ナシクロホシカイガラムシ（Ｐａｒｌａｔｏｒｅｏｐｓｉｓ ｐｙｒｉ）、ツバキクロホシカイガラムシ（Ｐａｒｌａｔｏｒｉａ ｃａｍｅｌｌｉａｅ）、チャノクロホシカイガラムシ（Ｐａｒｌａｔｏｒｉａ ｔｈｅａｅ）、ヒメクロカイガラムシ（Ｐａｒｌａｔｏｒｉａ ｚｉｚｉｐｈｉ）、ハランナガカイガラムシ（Ｐｉｎｎａｓｐｉｓ ａｓｐｉｄｉｓｔｒａｅ）、ミカンマルカイガラムシ（Ｐｓｅｕｄａｏｎｉｄｉａ ｄｕｐｌｅｘ）、チャノマルカイガラムシ（Ｐｓｅｕｄａｏｎｉｄｉａ ｐａｅｏｎｉａｅ）、クワシロカイガラムシ（ Pseudaulacaspis pentagona), white scale beetle (Pseudaulacaspis prunicola), Yanone scale beetle (Unaspis yanonensis), etc.
鱗翅目（ＬＥＰＩＤＯＰＴＥＲＡ）：コウモリガ（Ｅｎｄｏｃｌｙｔａ ｅｘｃｒｅｃｅｎｓ）、キマダラコウモリ（Ｅｎｄｏｃｌｙｔａ ｓｉｎｅｎｓｉｓ）、シロテンコウモリ（Ｐａｌｐｉｆｅｒ ｓｅｘｎｏｔａｔａ）、バラハマキ（Ａｃｌｅｒｉｓ ｃｏｍａｒｉａｎａ）、リンゴコカクモンハマキ（Ａｄｏｘｏｐｈｙｅｓ ｏｒａｎａ ｆａｓｃｉａｔａ）、チャノコカクモンハマキ（Ａｄｏｘｏｐｈｙｅｓ ｓｐ ．）、リンゴモンハマキ（Ａｒｃｈｉｐｓ ｂｒｅｖｉｐｌｉｃａｎｕｓ）、ミダレカクモンハマキ（Ａｒｃｈｉｐｓ ｆｕｓｃｏｃｕｐｒｅａｎｕｓ）、カクモンハマキ（Ａｒｃｈｉｐｓ ｘｙｌｏｓｔｅａｎｕｓ）、イグサシンムシガ（Ｂａｃｔｒａ ｆｕｒｆｕｒａｎａ）、ホソバハイイロハマキ（Ｃｎｅｐｈａｓｉａ ｃｉｎｅｒｅｉｐａｌｐａｎａ）、クリミガ（Ｃｙｄｉａ ｋｕｒｏｋｏｉ）、クリミドリシンクイガ（Ｅｕｃｏｅｎｏｇｅｎｅｓ ａｅｓｔｕｏｓａ）、ナシヒメシンクイ（Ｇｒａｐｈｏｌｉｔａ ｍｏｌｅｓｔａ）、チャハマキ（Ｈｏｍｏｎａ ｍａｇｎａｎｉｍａ）、リンゴオオハマキ（Ｈｏｓｈｉｍｏａ ａｄｕｍｂｒａｔａｎａ）、マメシンクイガ（Ｌｅｇｕｍｉｎｉｖｏｒａ ｇｌｙｃｉｎｉｖｏｒｅｌｌａ）、アズキサヤムシガ（Ｍａｔｓｕｍｕｒａｅｓｅｓ ａｚｕｋｉｖｏｒａ）、ダイズサヤムシガ（Ｍａｔｓｕｍｕｒａｅｓｅｓ ｆａｌｃａｎａ）、マメヒメサヤムシガ（Ｍａｔｓｕｍｕｒａｅｓｅｓ ｐｈａｓｅｏｌｉ）、リンゴハイイロハマキ（Ｓｐｉｌｏｎｏｔａ ｌｅｃｈｒｉａｓｐｉｓ）、リンゴシロヒメハマキ（Ｓｐｉｌｏｎｏｔａ ｏｃｅｌｌａｎａ）、ブドウホソハマキ（Ｅｕｐｏｅｃｉｌｌｉａ ａｍｂｉｇｕｅｌｌａ）、クワイホソハマキ（Ｐｈａｌｏｎｉｄｉａ ｍｅｓｏｔｙｐａ）、ヨモギオオホソハマキ（Ｐｈｔｈｅｏｃｈｒｏｉｄｅｓ ｃｌａｎｄｅｓｔｉｎａ）、ミノガ（Ｂａｍｂａｌｉｎａ ｓｐ．）、オオミノガ（Ｅｕｍｅｔａ ｊａｐｏｎｉｃａ）、チャミノガ（Ｅｕｍｅｔａ ｍｉｎｕｓｃｕｌｅ）、コクガ（Ｎｅｍａｐｏｇｏｎ ｇｒａｎｅｌｌｕｓ）、イガ（Ｔｉｎｅａ ｔｒａｎｓｌｕｃｅｎｓ）、ナシチビガ（Ｂｕｃｃｕｌａｔｒｉｘ ｐｙｒｉｃｏｒｅｌｌａ）、モモハモグリガ（Ｌｙｏｎｅｔｉａ ｃｌｅｒｋｅｌｌａ）、ギンモンハモグリガ（Ｌｙｏｎｅｔｉａ ｐｒｕｎｉｆｏｌｉｅｌｌａ ）、マメホソガ（Ｃａｌｏｐｔｉｌｉａ ｓｏｙｅｌｌａ）、チャノホソガ（Ｃａｌｏｐｔｉｌｉａ ｔｈｅｉｖｏｒａ）、リンゴホソガ（Ｃａｌｏｐｔｉｌｉａ ｚａｃｈｒｙｓａ）、カキホソガ（Ｃｕｐｈｏｄｅｓ ｄｉｏｓｐｙｒｏｓｅｌｌａ）、キンモンホソガ（Ｐｈｙｌｌｏｎｏｒｙｃｔｅｒ ｒｉｎｇｏｎｉｅｌｌａ）、ナシホソガ（Ｓｐｕｌｅｒｉｎａ ａｓｔａｕｒｏｔａ）、ミカンハモグリガ（Ｐｈｙｌｌｏｃｎｉｓｔｉｓ ｃｉｔｒｅｌｌａ）、ブドウハモグリガ（Ｐｈｙｌｌｏｃｎｉｓｔｉｓ ｔｏｐａｒｃｈａ ）、ネギコガ（Ａｃｒｏｌｅｐｉｏｐｓｉｓ ｓａｐｐｏｒｅｎｓｉｓ）、ヤマノイモコガ（Ａｃｒｏｌｅｐｉｏｐｓｉｓ ｓｕｚｕｋｉｅｌｌａ）、コナガ（Ｐｌｕｔｅｌｌａ ｘｙｌｏｓｔｅｌｌａ）、リンゴヒメシンクイ（Ａｒｇｙｒｅｓｔｈｉａ ｃｏｎｊｕｇｅｌｌａ）、ブドウスカシバ（Ｐａｒａｎｔｈｒｅｎｅ ｒｅｇａｌｉｓ）、コスカシバ（Ｓｙｎａｎｔｈｅｄｏｎ ｈｅｃｔｏｒ）、カキノヘタムシガ（Ｓｔａｔｈｍｏｐｏｄａ ｍａｓｉｎｉｓｓａ）、イモキバガ（Ｂｒａｃｈｍｉａ ｔｒｉａｎｎｕｌｅｌｌａ）、モモシンクイガ（Ｃａｒｐｏｓｉｎａ ｎｉｐｏｎｅｎｓｉｓ）、リンゴハマキクロバ（Ｉｌｌｉｂｅｒｉｓ ｐｒｕｎｉ）、クロシタアオイラガ（Ｌｏｔｏｉａ ｓｉｎｉｃａ）、イラガ（Ｍｏｎｅｍａ ｆｌａｖｅｓｃｅｎｓ）、ナシイラガ（Ｎａｒｏｓｏｉｄｅｕｓ ｆｌａｖｉｄｏｒｓａｌｉｓ）、アオイラガ（Ｐａｒａｓａ ｃｏｎｓｏｃｉａ）、ヒメクロイラガ（Ｓｃｏｐｅｌｏｄｅｓ ｃｏｎｔｒａｃｕｓ）、ニカメイガ（Ｃｈｉｌｏ ｓｕｐｐｒｅｓｓａｌｉｓ）、コブノメイガ（Ｃｎａｐｈａｌｏｃｒｏｃｉｓ ｍｅｄｉｎａｌｉｓ）、モモノゴマダラノメイガ（Ｃｏｎｏｇｅｔｈｅｓ ｐｕｎｃｔｉｆｅｒａｌｉｓ）、ワタヘリクロノメイガ（Ｄｉａｐｈａｎｉａ ｉｎｄｉｃａ）、ナシマダラメイガ（Ｅｃｔｏｍｙｅｌｏｉｓ ｐｙｒｉｖｏｒｅｌｌａ）、スジコナマダラメイガ（Ｅｐｈｅｓｔｉａ ｋｕｅｈｎｉｅｌｌａ）、シロイチモジマダラメイガ(Etiella zinckenella), Croftamon Madarameimo (Euzophera batangensis), Quanomeimo (Glyphodes pyroalis), High-madaranomeimo (Hellulla undalis), Inate Hamaki ( Ｍａｒａｓｍｉａ ｅｘｉｇｕａ）、マメノメイガ（Ｍａｒｕｃａ ｔｅｓｔｕｌａｌｉｓ）、ワタノメイガ（Ｎｏｔａｒｃｈａ ｄｅｒｏｇａｔｅ）、アワノメイガ（Ｏｓｔｒｉｎｉａ ｆｕｒｎａｃａｌｉｓ）、アズキノメイガ（Ｏｓｔｒｉｎｉａ ｓｃａｐｕｌａｌｉｓ）、フキノメイガ（Ｏｓｔｒｉｎｉａ ｚａｇｕｌｉａｅｖｉ）、シバツトガ（Ｐａｒａｐｅｄｉａｓｉａ ｔｅｔｅｒｒｅｌｌａ）、ウコンノメイガ（Ｐｌｅｕｒｏｐｔｙａ ｒｕｒａｌｉｓ）、サンカメイガ（ Ｓｃｉｒｐｏｐｈａｇａ ｉｎｃｅｒｔｕｌａｓ）、イチモンジセセリ（Ｐａｒｎａｒａ ｇｕｔｔａｔａ）、モンキアゲハ（Ｐａｐｉｌｉｏ ｈｅｌｅｎｕｓ）、キアゲハ（Ｐａｐｉｌｉｏ ｍａｃｈａｏｎ ｈｉｐｐｏｃｒａｔｅｓ）、アゲハ（Ｐａｐｉｌｉｏ ｘｕｔｈｕｓ）、モンキチョウ（Ｃｏｌｉａｓ ｅｒａｔｅ ｐｏｌｉｏｇｒａｐｈｕｓ）、モンシロチョウ（Ｐｉｅｒｉｓ ｒａｐａｅ ｃｒｕｃｉｖｏｒａ）、ウラナミシジミ（Ｌａｍｐｉｄｅｓ ｂｏｅｔｉｃｕｓ）、スモモエダシャク（Ａｎｇｅｒｏｎａ ｐｒｕｎａｒｉａ）、ヨモギエダシャク（Ａｓｃｏｔｉｓ ｓｅｌｅｎａｒｉａ）、トビモンオオエダシャク（Ｂｉｓｔｏｎ ｒｏｂｕｓｔｕｍ）、ウメエダシャク（Ｃｙｓｔｉｄｉａ ｃｏｕａｇｇａｒｉａ）、マツカレハ（Ｄｅｎｄｒｏｌｉｍｕｓ ｓｐｅｃｔａｂｉｌｉｓ）、オビカレハ（Ｍａｌａｃｏｓｏｍａ ｎｅｕｓｔｒｉａ ｔｅｓｔａｃｅａ）、リンゴカレハ（Ｏｄｏｎｅｓｔｉｓ ｐｒｕｎｉ ｊａｐｏｎｅｎｓｉｓ）、オオスカシバ（Ｃｅｐｈｏｎｏｄｅｓ ｈｙｌａｓ）、ブドウスズメ（Ａｃｏｓｍｅｒｙｘ ｃａｓｔａｎｅａ）、ツヤマアカシャチホコ（Ｃｌｏｓｔｅｒａ ａｎａｃｈｏｒｅｔａ）、セグロシャチホコ（Ｃｌｏｓｔｅｒａ ａｎａｓｔｏｍｏｓｉｓ）、モンクロシャチホコ（Ｐｈａｌｅｒａ ｆｌａｖｅｓｃｅｎｓ）、オオトビモンシャチホコ（Ｐｈａｌｅｒｏｄｏｎｔａ ｍａｎｌｅｙｉ）、シャチホコガ（Ｓｔａｕｒｏｐｕｓ ｆａｇｉ ｐｅｒｓｉｍｉｌｉｓ ), Euproctis pseudoconspersa, Euproctis similes, Euproctis subflava, Lymantria dispar, Orgyia thyel ｌｉｎａ）、アメリカシロヒトリ（Ｈｙｐｈａｎｔｒｉａ ｃｕｎｅａ）、クワゴマダラヒトリ（Ｓｐｉｌｏｓｏｍａ ｉｍｐａｒｉｌｉｓ）、ミツモンキンウワバ（Ａｃａｎｔｈｏｐｌｕｓｉａ ａｇｎａｔａ）、ナカジロシタバ（Ａｅｄｉａ ｌｅｕｃｏｍｅｌａｓ）、タマナヤガ（Ａｇｒｏｔｉｓ ｉｐｓｉｌｏｎ）、カブラヤガ（Ａｇｒｏｔｉｓ ｓｅｇｅｔｕｍ）、アカキリバ（Ａｎｏｍｉｓ ｍｅｓｏｇｏｎａ） 、タマナギンウワバ（Ａｕｔｏｇｒａｐｈａ ｎｉｇｒｉｓｉｇｎａ）、イラクサギンウワバ（Ｔｒｉｃｈｏｐｌｕｓｉａ ｎｉ）、オオタバコガ（Ｈｅｌｉｃｏｖｅｒｐａ ａｒｍｉｇｅｒａ）、タバコガ（Ｈｅｌｉｃｏｖｅｒｐａ ａｓｓｕｌｔａ）、ツメクサガ（Ｈｅｌｉｏｔｈｉｓ ｍａｒｉｔｉｍｅ）、ヨトウガ（Ｍａｍｅｓｔｒａ ｂｒａｓｓｉｃａｅ）、フタオビコヤガ（Ｎａｒａｎｇａ ａｅｎｅｓｃｅｎｓ）、アワヨトウ（Ｐｓｅｕｄａｌｅｔｉａ ｓｅｐａｒａｔａ） 、イネヨトウ（Ｓｅｓａｍｉａ ｉｎｆｅｒｅｎｓ）、スジキリヨトウ（Ｓｐｏｄｏｐｔｅｒａ ｄｅｐｒａｖａｔａ）、シロイチモジヨトウ（Ｓｐｏｄｏｐｔｅｒａ ｅｘｉｇｕａ）、ハスモンヨトウ（Ｓｐｏｄｏｐｔｅｒａ ｌｉｔｕｒａ）、リンゴケンモン（Ｔｒｉａｎｅａ ｉｎｔｅｒｍｅｄｉａ）、ナシケンモン（Ｖｉｍｉｎｉａ ｒｕｍｉｃｉｓ）、シロモンヤガ（Ｘｅｓｔｉａ ｃ－ｎｉｇｒｕｍ）など、
甲虫目（ＣＯＬＥＯＰＴＥＲＡ）：チャイロコガネ（Ａｄｏｒｅｔｕｓ ｔｅｎｕｉｍａｃｕｌａｔｕｓ）、ドウガネブイブイ（Ａｎｏｍａｌａ ｃｕｐｒｅａ）、ヒメコガネ（Ａｎｏｍａｌａ ｒｕｆｏｃｕｐｒｅａ）、ハナムグリ（Ｅｕｃｅｔｏｎｉａ ｐｉｌｉｆｅｒａ）、アオハナムグリ（Ｅｕｃｅｔｏｎｉａ ｒｏｅｌｏｆｓｉ）、ナガチャコガネ（Ｈｅｐｔｏｐｈｙｌｌａ ｐｉｃｅａ）、コフキコガネ（Ｍｅｌｏｌｏｎｔｈａ ｊａｐｏｎｉｃａ）、コガネムシ（Ｍｉｍｅｌａ ｓｐｌｅｎｄｅｎｓ）、コアオハナムグリ（Ｏｘｙｃｅｔｏｎｉａ ｊｕｃｕｎｄａ）、マメコガネ（Ｐｏｐｉｌｌｉａ ｊａｐｏｎｉｃａ）、ヒメマルカツオブシムシ（Ａｎｔｈｒｅｎｕｓ ｖｅｒｂａｓｃｉ）、ヒメカツオブシムシ（Ａｔｔａｇｅｎｕｓ ｕｎｉｃｏｌｏｒ ｊａｐｏｎｉｃｕｓ）、タバコシバンムシ（Ｌａｓｉｏｄｅｒｍａ ｓｅｒｒｉｃｏｒｎｅ）、ヒラタキクイムシ（Ｌｙｃｔｕｓ ｂｒｕｎｎｅｕｓ）、ガイマイデオキスイ（Ｃａｒｐｏｐｈｉｌｕｓ ｄｉｍｉｄｉａｔｕｓ）、クリヤケシキスイ（Ｃａｒｐｏｐｈｉｌｕｓ ｈｅｍｉｐｔｅｒｕｓ）、オオニジュウヤホシテントウ（Ｅｐｉｌａｃｈｎａ ｖｉｇｉｎｔｉｏｃｔｏｍａｃｕｌａｔａ）、ニジュウヤホシテントウ（Ｅｐｉｌａｃｈｎａ ｖｉｇｉｎｔｉｏｃｔｏｐｕｎｃｔａｔａ）、ヒメゴミムシダマシ（Ａｌｐｈｉｔｏｂｉｕｓ ｌａｅｖｉｇａｔｕｓ）、ゴミムシダマシ（Ｎｅａｔｕｓ ｐｉｃｉｐｅｓ）、ヒメコクヌストモドキ（Ｐａｌｏｒｕｓ ｒａｔｚｅｂｕｒｇｉｉ）、コヒメコクヌストモドキ（Ｐａｌｏｒｕｓ ｓｕｂｄｅｐｒｅｓｓｕｓ）、チャイロコメノゴミムシダマシ（Ｔｅｎｅｂｒｉｏ ｍｏｌｉｔｏｒ）、コクヌストモドキ（Ｔｒｉｂｏｌｉｕｍ ｃａｓｔａｎｅｕｍ）、ヒラタコクヌストモドキ（Ｔｒｉｂｏｌｉｕｍ ｃｏｎｆｕｓｕｍ）、マメハンミョウ（Ｅｐｉｃａｕｔａ ｇｏｒｈａｍｉ）、キマダラカミキリ（Ａｅｏｌｅｓｔｈｅｓ ｃｈｒｙｓｏｔｈｒｉｘ ), Anoplophora malasiaca, Monochamus alternatus, Psacothea hilaris, Xylotrechus pyrrhoderus, Xystrocena gl ｏｂｏｓａ）、アズキゾウムシ（Ｃａｌｌｏｓｏｂｒｕｃｈｕｓ ｃｈｉｎｅｎｓｉｓ）、ウリハムシ（Ａｕｌａｃｏｐｈａｒａ ｆｅｍｏｒａｌｉｓ）、チャイロサルハムシ（Ｂａｓｉｌｅｐｔａ ｂａｌｙｉ）、カメノコハムシ（Ｃａｓｓｉｄａ ｎｅｂｕｌｏｓａ）、テンサイトビハムシ（Ｃｈａｅｔｏｃｎｅｍａ ｃｏｎｃｉｎｎａ）、イモサルハムシＣｏｌａｓｐｏｓｏｍａ ｄａｕｒｉｃｕｍ）、ジュウシホシクビナガハムシ（ Ｃｒｉｏｃｅｒｉｓ ｑｕａｔｕｏｒｄｅｃｉｍｐｕｎｃｔａｔａ）、イネネクイハムシ（Ｄｏｎａｃｉａ ｐｒｏｖｏｓｔｉ）、ルリハムシ（Ｌｉｎａｅｉｄｅａ ａｅｎｅａ）、キアシノミハムシ（Ｌｕｐｅｒｏｍｏｒｐｈａ ｔｕｎｅｂｒｏｓａ）、フタスジヒメハムシ（Ｍｅｄｙｔｈｉａ ｎｉｇｒｏｂｉｌｉｎｅａｔａ）、イネドロオイムシ（Ｏｕｌｅｍａ ｏｒｙｚａｅ）、ヒメキバネサルハムシ（Ｐａｇｒｉａ ｓｉｇｎａｔａ）、ダイコンハムシ（Ｐｈａｅｄｏｎ ｂｒａｓｓｉｃａｅ）、キスジノミハムシ（Ｐｈｙｌｌｏｔｒｅｔａ ｓｔｒｉｏｌａｔａ）、ウメチョッキリゾウムシ（Ｉｎｖｏｌｖｕｌｕｓ ｃｕｐｒｅｕｓ）、モモチョッキリゾウムシ（Ｒｈｙｎｃｈｉｔｅｓ ｈｅｒｏｓ）、アリモドキゾウムシ（Ｃｙｌａｓ ｆｏｒｍｉｃａｒｉｕｓ）、リンゴハナゾウムシ（Ａｎｔｈｏｎｏｍｕｓ ｐｏｍｏｒｕｍ）、ダイコンサルゾウムシ（Ｃｅｕｔｈｏｒｈｙｎｃｈｉｄｉｕｓ ａｌｂｏｓｕｔｕｒａｌｉｓ） 、クリシギゾウムシ（Ｃｕｒｃｕｌｉｏ ｓｉｋｋｉｍｅｎｅｓｉｓ）、イネゾウムシ（Ｅｃｈｉｎｏｃｎｅｍｕｓ ｓｑｕａｍｅｕｓ）、イモゾウムシ（Ｅｕｓｃｅｐｅｓ ｐｏｓｔｆａｓｃｉａｔｕｓ）、ツメクサタコゾウムシ（Ｈｙｐｅｒａ ｎｉｇｒｉｒｏｓｔｒｉｓ）、アルファルファタコゾウムシ（Ｈｙｐｅｒａ ｐｏｓｔｉｃａ）、イネミズゾウムシ（Ｌｉｓｓｏｒｈｏｐｔｒｕｓ ｏｒｙｚｏｐｈｉｌｕｓ）、ヤサイゾウムシ（Ｌｉｓｔｒｏｄｅｒｅｓ ｃｏｓｔｉｒｏｓｔｒｉｓ）、リンゴPhyllobius armatus, Sitona japonicus, Sitophilus oryzae, Sitophilus zeamais, Sphenophrus venatus vestitus degree,
Hymenoptera (HYMENOPTERA): Athalia japonica, Athalia rosae tuficornis, Arge mali, Arge pagana, Dryocosmus kuriphilus, etc.
Diptera: Tipula aino, Bradysia agrestis, Asphondylia sp., Dacus cucurbitae, Dacus dorsalis, Dacus,オウトウハマダラミバエ（Ｒｈａｃｏｃｈｌａｅｎａ ｊａｐｏｎｉｃａ）、イネミギワバエ（Ｈｙｄｒｅｌｌｉａ ｇｒｉｓｅｏｌａ）、イネクキミギワバエ（Ｈｙｄｒｅｌｌｉａ ｓａｓａｋｉｉ）、オウトウショウジョウバエ（Ｄｒｏｓｏｐｈｉｌａ ｓｕｚｕｋｉｉ）、イネキモグリバエＣｈｌｏｒｏｐｓ ｏｒｙｚａｅ）、ムギキモグリバエ（Ｍｅｒｏｍｕｚａ ｎｉｇｒｉｖｅｎｔｒｉｓ）、イネハモグリバエ（Ａｇｒｏｍｙｚａ ｏｒｙｚａｅ）、ナモグリバエ（ Ｃｈｒｏｍａｔｏｍｙｉａ ｈｏｒｔｉｃｏｌａ）、ナスハモグリバエ（Ｌｉｒｉｏｍｙｚａ ｂｒｙｏｎｉａｅ）、ネギハモグリバエ（Ｌｉｒｉｏｍｙｚａ ｃｈｉｎｅｎｓｉｓ）、マメハモグリバエ（Ｌｉｒｉｏｍｙｚａ ｔｒｉｆｏｌｉｉ）、トマトハモグリバエ（Ｌｉｒｉｏｍｙｚａ ｓａｔｉｖａｅ）、アシグロハモグリバエ（Ｌｉｒｉｏｍｙｚａ ｈｕｉｄｏｂｒｅｎｓｉｓ）、タマネギバエ（Ｄｅｌｉａ ａｎｔｉｑｕａ）、タネバエ（Ｄｅｌｉａ ｐｌａｔｕｒａ ）、テンサイモグリハナバエ（Ｐｅｇｏｍｙａ ｃｕｎｉｃｕｌａｒｉａ）、イエバエ（Ｍｕｓｃａ ｄｏｍｅｓｔｉｃａ）、クロキンバエ（Ｐｈｏｒｍｉａ ｒｅｇｉｎａ）、アカイエカ（Ｃｕｌｅｘ ｐｉｐｉｅｎｓ ｐａｌｌｅｎｓ Ｃｏｑｕｉｌｌｅｔｔ）、チカイエカ（Ｃｕｌｅｘ ｐｉｐｉｅｎｓ ｍｏｌｅｓｔｕｓ Ｆｏｒｓｋａｌ）、シナハマダラカ（Ａｎｏｐｈｅｌｅｓ（Ａｎｏｐｈｅｌｅｓ）ｓｉｎｅｎｓｉｓ Ｗｉｅｄｅｍａｎｎ）、ヒトスジシマカ(Aedes albopictus (Skuse)) and the like, but are not limited thereto.

Examples of weeds include various weeds that are problematic in paddy fields, such as gramineous weeds such as barnacle; Cyperaceae weeds, such as Cyperaceae, Shizui, and Blackwei; and Antrocidae weeds, such as Pleurotus, Omodaka, and Hera Omodaka, and various weeds that are problematic in non-agricultural lands, upland fields, and orchards, such as nightshade and datura Weeds of the Solanaceae family, mallow weeds such as velvetleaf and goldfinch, convolvulaceae weeds such as Ipomoea purpurea and bindweed, weeds of the family Amaranthaceae such as black-and-white barnacles and blue-bellied vines, chrysanthemums such as barnacles, ragweeds, barkweeds and fleabanes cruciferous weeds such as mustard and shepherd's purse; Chenopodiaceous weeds such as chlomoth and pigweed; violetaceous weeds such as field pansy; caryophyllaceous weeds such as chickweed; Weeds, Purslane family weeds such as purslane, Scrophulariaceae weeds such as Scrophulariaceae, Scrophulariaceae weeds such as Scrophulariaceae, Scrophulariaceae weeds such as Scrophulariaceae, Labiaceae weeds such as Scrophulariaceae, Euphorbiaceae weeds such as sorghum, barnyard barnyard grass, sorghum, crabgrass, goosegrass, bluegrass, sorghum, oat, and barley , Poaceae weeds such as ryegrass, green foxtail and Allium japonica; not to be

The term "spreadability index" as used herein refers to the spreadability of an agrochemical composition for water surface application on the water surface expressed in a numerical value in the range of 0 to 15 points (full score of 15 points). It has good spreadability, preferably 7 points or more, more preferably 9 points or more, and even more preferably 11 points or more. The test method for water surface spreadability is as follows.

25 L of tap water is poured into a toyu with a length of 4 m and a width of 14 cm, and 2 g of rice husk powder is uniformly distributed on the water surface, assuming obstacles (floating matter) on the surface of the paddy field. After standing still, 280 mg of the pesticide composition for water surface application was added to a point 10 cm from one end of the toyu. The distance and the state of expansion after 5 minutes of application are visually inspected, judged according to the evaluation criteria shown in Table 1 below, and the expansion index of each item is totaled to obtain each expansion index. When the spreadability of conventional agricultural chemical formulations is evaluated in this test system, the water surface spreadability is less than 9 points, but when the water surface application agricultural chemical composition of the present invention is similarly evaluated, the spreadability index is favorably is as high as 11 points or more, and it can be seen that the pesticide composition for water surface application of the present invention has far superior water surface spreadability compared to the prior art.

Formulation examples of the agrochemical composition for application to water according to the present invention will be described in detail below, but the present invention is not limited thereto. In addition, in the following formulation examples, "%" indicates % by mass.

Trial production example 1
Cyclopyrimolate bulk (purity 99.1%) 50.67 parts, M-3801G (trademark) (α-olefin sulfonic acid sodium salt) (Daiichi Kogyo Seiyaku Co., Ltd.) 5.00 parts, Carplex ( Registered trademark) 80D (white carbon) (manufactured by Evonik Japan Co., Ltd.) 10.00 parts and Seiko Talc GTA (manufactured by Seiko Sangyo Co., Ltd.) 34.33 parts are mixed, and this mixture is sample mill (registered trademark) KII- The mixture was dry pulverized with Type 1 (manufactured by Dalton) to obtain a cyclopyrimolate premix (pesticidal active ingredient amount: 50.0%).

Trial production example 2
Pyrazolate bulk (purity 93.7%) 80.04 parts, M-3801G (trademark) (α-olefin sulfonic acid sodium salt) (Daiichi Kogyo Seiyaku Co., Ltd.) 5.00 parts, Carplex (registered trademark) 80D (white carbon) (manufactured by Evonik Japan Co., Ltd.) 6.00 parts and Seiko Talc GTA (manufactured by Seiko Sangyo Co., Ltd.) 8.96 parts are mixed, and the mixture is sample mill (registered trademark) KII-1 type ( Dalton) to obtain a pyrazolate premix (75.0% pesticide active ingredient).

Trial production example 3
Simeconazole bulk (purity 96.7%) 77.56 parts, M-3801G (trademark) (α-olefin sulfonic acid sodium salt) (manufactured by Daiichi Kogyo Seiyaku Co., Ltd.) 10.0 parts and Carplex (registered trademark) 12.44 parts of #1120 (white carbon) (manufactured by Evonik Japan Co., Ltd.) was mixed, the mixture was pulverized with a jet mill (registered trademark), and simeconazole premix (pesticide active ingredient amount: 75.0%) was obtained. got

Trial production example 4
Cyclopyrimolate bulk (purity 99.1%) 50.67 parts, M-3801G (trademark) (α-olefin sulfonic acid sodium salt) (Daiichi Kogyo Seiyaku Co., Ltd.) 10.00 parts and Seiko Talc GTA (manufactured by Seiko Sangyo Co., Ltd.) 39.33 parts are mixed, the mixture is dry-ground with a sample mill (registered trademark) KII-1 type (manufactured by Dalton), and cyclopyrimolate premix (pesticide active ingredient amount 50 .0%) was obtained.

Example 1
34.0 parts of Hirucon (registered trademark) S1-600 (manufactured by Hiruishi Tech Co., Ltd.) (calcined vermiculite, 0.6 mm undercut product, apparent specific gravity: 0.1) was placed in Lab Mixer (registered trademark) to obtain grain nuclei. , JXTG Energy Super Oil (registered trademark) M100 (manufactured by JXTG Energy Co., Ltd.) 44.0 parts and New Cole (registered trademark) 291 PG (manufactured by Nippon Nyukazai Co., Ltd.) (dioctyl sulfosuccinate sodium salt) 2.0 parts was added to wet the surface of the grain nuclei. Next, 10.0 parts of the cyclopyrimolate premix of Trial Production Example 1 was added to the obtained grain nuclei and mixed to coat the surface of the grain nuclei with the premix, and then 10.0 parts of neutral anhydrous sodium sulfate was added. By adding and mixing parts, granules containing 5.0% of cyclopyrimolate in which the surfaces of the grain nuclei were coated with the neutral anhydrous Glauber's salt were obtained.

Example 2
34.0 parts of Hirucon (registered trademark) S1-600 (manufactured by Hiruishi Tech Co., Ltd.) (calcined vermiculite, 0.6 mm undercut product, apparent specific gravity: 0.1) was placed in Lab Mixer (registered trademark) to obtain grain nuclei. , JXTG Energy Super Oil (registered trademark) M100 (manufactured by JXTG Energy Co., Ltd.) 40.0 parts, ethylhexyl diglycol 4.0 parts and New Cole (registered trademark) 291PG (manufactured by Nippon Emulsifier Co., Ltd.) (dioctyl sulfosuccinate 2.0 parts of phosphate sodium salt) was added to moisten the surface of the grain nucleus. Next, 10.0 parts of the cyclopyrimolate premix of Trial Production Example 4 was added to the obtained grain nuclei and mixed to coat the surface of the grain nuclei with the premix. By adding and mixing parts, granules containing 5.0% of cyclopyrimolate in which the surfaces of the grain nuclei were coated with the neutral anhydrous Glauber's salt were obtained.

Example 3
34.0 parts of Hirucon (registered trademark) S1-600 (manufactured by Hiruishi Tech Co., Ltd.) (calcined vermiculite, 0.6 mm undercut product, apparent specific gravity: 0.1) was placed in Lab Mixer (registered trademark) to obtain grain nuclei. , JXTG Energy Super Oil (registered trademark) M100 (manufactured by JXTG Energy Co., Ltd.) 40.0 parts, ethylhexyl diglycol 4.0 parts and New Cole (registered trademark) 291PG (manufactured by Nippon Emulsifier Co., Ltd.) (dioctyl sulfosuccinate 2.0 parts of phosphate sodium salt) was added to moisten the surface of the grain nuclei. Next, 10.0 parts of the cyclopyrimolate premix of Trial Production Example 1 was added to the obtained grain nuclei and mixed to coat the surface of the grain nuclei with the premix, and then 10.0 parts of neutral anhydrous sodium sulfate was added. By adding and mixing parts, granules containing 5.0% of cyclopyrimolate in which the surfaces of the grain nuclei were coated with the neutral anhydrous Glauber's salt were obtained.

Example 4
Hirukon (registered trademark) S1-600 (manufactured by Hiruishi Tech Co., Ltd.) (calcined vermiculite, 0.6 mm undercut product, apparent specific gravity: 0.1) 34.0 parts was charged into Lab Mixer (registered trademark), JXTG Energy Super Oil (registered trademark) M100 (manufactured by JXTG Energy Co., Ltd.) 40.0 parts, ethylhexyl diglycol 4.0 parts and Newcol (registered trademark) 291PG (manufactured by Nippon Nyukazai Co., Ltd.) (dioctyl sulfosuccinate sodium salt)2. 0 part was added to wet the surface of the grain nuclei. Next, 15.0 parts of the pyrazolate premix of Trial Production Example 2 was added to the obtained grain nuclei and mixed to coat the surface of the grain nuclei with the premix, and then 5.0 parts of neutral anhydrous sodium sulfate was added. Granules containing 10.0% of pyrazolate in which the surfaces of the grain nuclei were coated with the neutral anhydrous Glauber's salt were obtained.

Example 5
Hirukon (registered trademark) S1-600 (manufactured by Hiruishi Tech Co., Ltd.) (calcined vermiculite, 0.6 mm undercut product, apparent specific gravity: 0.1) 34.0 parts was charged into Lab Mixer (registered trademark), JXTG Energy Super Oil (registered trademark) M100 (manufactured by JXTG Energy Co., Ltd.) 40.0 parts, ethylhexyl diglycol 4.0 parts and Newcol (registered trademark) 291PG (manufactured by Nippon Nyukazai Co., Ltd.) (dioctyl sulfosuccinate sodium salt)2. 0 part was added to wet the surface of the grain nuclei. Next, 12.0 parts of the simeconazole premix of Trial Production Example 3 was added to the obtained grain nuclei and mixed to coat the surface of the grain nuclei with the premix, and then 10.0 parts of neutral anhydrous sodium sulfate. were added and mixed to obtain granules containing 9.0% of simeconazole in which the surfaces of the grain nuclei were coated with the neutral anhydrous Glauber's salt.

Comparative example 1
Hirukon (registered trademark) S1-600 (manufactured by Hiruishi Tech Co., Ltd.) (calcined vermiculite, 0.6 mm undercut product, apparent specific gravity: 0.1) 34.0 parts was charged into Lab Mixer (registered trademark), JXTG Energy Super Oil 46.0 parts of (registered trademark) M100 (manufactured by JXTG Nippon Oil & Energy Corporation) was added to moisten the surfaces of the grain nuclei. Next, 10.0 parts of the cyclopyrimolate premix of Trial Production Example 1 was added to the obtained grain nuclei and mixed to coat the surface of the grain nuclei with the premix, and then 10.0 parts of neutral anhydrous sodium sulfate was added. By adding and mixing parts, granules containing 5.0% of cyclopyrimolate in which the surfaces of the grain nuclei were coated with the neutral anhydrous Glauber's salt were obtained.

Comparative example 2
Hirukon (registered trademark) S1-600 (manufactured by Hiruishi Tech Co., Ltd.) (calcined vermiculite, 0.6 mm undercut product, apparent specific gravity: 0.1) 34.0 parts was charged into Lab Mixer (registered trademark), JXTG Energy Super Oil 42.0 parts of (registered trademark) M100 (manufactured by JXTG Nippon Oil & Energy Corporation) and 4.0 parts of ethylhexyldiglycol were added to moisten the surface of the grain nuclei. Next, 10.0 parts of the cyclopyrimolate premix of Trial Production Example 1 was added to the obtained grain nuclei and mixed to coat the surface of the grain nuclei with the premix, and then 10.0 parts of neutral anhydrous sodium sulfate was added. By adding and mixing parts, granules containing 5.0% of cyclopyrimolate in which the surfaces of the grain nuclei were coated with the neutral anhydrous Glauber's salt were obtained.

Comparative example 3
Hirukon (registered trademark) S1-600 (manufactured by Hiruishi Tech Co., Ltd.) (calcined vermiculite, 0.6 mm undercut product, apparent specific gravity: 0.1) 34.0 parts was charged into Lab Mixer (registered trademark), JXTG Energy Super Oil 42.0 parts of (registered trademark) M100 (manufactured by JXTG Nippon Oil & Energy Corporation) and 4.0 parts of ethylhexyl diglycol were added to moisten the surface of the grains. Next, 15.0 parts of the pyrazolate premix of Trial Production Example 2 was added to the obtained grain nuclei and mixed to coat the surface of the grain nuclei with the premix, and then 5.0 parts of neutral anhydrous sodium sulfate was added. Granules containing 5.0% of pyrazolate in which the surfaces of the grain nuclei were coated with the neutral anhydrous Glauber's salt were obtained.

Test Example 1 Spreadability test of granules 25 L of tap water is put in a toyu with a length of 4 m and a width of 14 cm, and assuming an obstacle (floating object) on the surface of the field, Sumiselco (registered trademark) (Sumikin Bussan Co., Ltd.) 2 g of pulverized rice husk manufactured by the company was treated so as to be even on the surface of the water. After standing still, 280 mg of the granules described in Examples 1 to 5 and Comparative Examples 1 to 3 were added to a point 10 cm from one end of the toyu, reaching 1.5 m from the point of introduction of each granule after charging. The time, the longest reachable distance from the injection point, and the expansion state after 5 minutes of injection were visually inspected, judged according to the evaluation criteria described in Table 1 above, and the expansion index of each item was totaled to obtain each. A spreading index was obtained. Table 2 shows the results.

As is clear from Test Example 1 above, the pesticide composition for water surface application of the present invention has very good water surface spreading floatability even on a water surface where obstacles are present, and even when obstacles are present on the water surface, Even if the diffusion of the drug is inhibited by the growth of rice or weeds, it is possible to uniformly disperse the active ingredient of the agricultural chemical over the entire field surface.

The agrochemical composition for water surface application of the present invention has extremely excellent diffusibility on the water surface and can be applied even when rice plants and weeds are growing. Therefore, it is a useful formulation as an agricultural material.

Claims (10)

(1) one or more active pesticide ingredients, (2) alkylsulfosuccinate salts, (3) one or more extenders selected from the group of compounds below , (4) liquid at room temperature A water surface containing an oily substance and ( 5 ) grain nuclei containing one or more hollow mineral carriers, plant carriers and/or synthetic resin foams (the apparent specific gravity of the grain nuclei is less than 1). Agricultural chemical granules (provided that they do not contain water-soluble solid organic acid salts other than alkylsulfosuccinate salts and α-olefinsulfonates, and do not contain superabsorbent polymers) .
Group of compounds: α-olefin sulfonates and glycol ether solvents. 2. The agricultural chemical granules for water surface application according to claim 1, comprising two kinds of spreading agents. 3. The agricultural chemical granules for water surface application according to claim 1 or 2, wherein the grain nuclei contain at least one selected from the group consisting of calcined vermiculite, expanded perlite, expanded shirasu and cork. 4. The pesticide granules for water surface application according to any one of claims 1 to 3, containing 1 to 60% of an oily substance that is liquid at room temperature . An agricultural chemical granule for water surface application, which further comprises a water-soluble metal salt in addition to the agricultural chemical granule for water surface application according to any one of claims 1 to 4. An agricultural chemical granule for water application, comprising the agricultural chemical granule for water application according to any one of claims 1 to 5 and further containing at least one surfactant . 7. Agrochemical granules for water surface application according to claim 6, wherein the surfactant is a nonionic surfactant. 8. Water surface application according to claim 6 or 7, wherein the nonionic surfactant is selected from the group consisting of polyoxyalkylene alkyl ethers, polyoxyalkylene alkyl aryl ethers, fatty alcohol alkylene oxide adducts and polyalkyleneoxy fatty acid esters. Pesticide granules . 9. A solid pesticide package for packaging the pesticide granules for water surface application according to any one of claims 1 to 8 in a water-soluble film or sheet. (A) Grain nuclei containing at least one selected from the group consisting of calcined vermiculite, foamed perlite, foamed shirasu and cork (the apparent specific gravity of the grain nuclei is less than 1) are added to an oily substance that is liquid at room temperature and a and (B) coating the surface-floating granules obtained in the above step (A) with an agricultural chemical active ingredient, an alkyl sulfosuccinate salt and optionally an α-olefin sulfonate. containing a step of absorbing or absorbing
(1) one or more active pesticide ingredients, (2) alkylsulfosuccinate salts, (3) one or more extenders selected from the group of compounds below , (4) liquid at room temperature Agricultural chemical granules for water surface application containing an oily substance and ( 5 ) grain nuclei containing at least one selected from the group consisting of calcined vermiculite, foamed perlite, foamed shirasu and cork (the grain nuclei have an apparent specific gravity of less than 1). A method for producing an agent (provided that it does not contain a water-soluble solid organic acid salt other than an alkylsulfosuccinate salt and an α-olefinsulfonate salt, and a superabsorbent polymer) .
Group of compounds: α-olefin sulfonates and glycol ether solvents.