JP7113781B2 - 二酸化炭素還元反応に用いられる新規窒素ドープ銅ナノ触媒 - Google Patents

二酸化炭素還元反応に用いられる新規窒素ドープ銅ナノ触媒 Download PDF

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JP7113781B2
JP7113781B2 JP2019076149A JP2019076149A JP7113781B2 JP 7113781 B2 JP7113781 B2 JP 7113781B2 JP 2019076149 A JP2019076149 A JP 2019076149A JP 2019076149 A JP2019076149 A JP 2019076149A JP 7113781 B2 JP7113781 B2 JP 7113781B2
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copper
nanoparticles
production method
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alkylamine
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チェン シュタン
チェン グガン
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Honda Motor Co Ltd
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    • C01B21/0615—Binary compounds of nitrogen with metals, with silicon, or with boron, or with carbon, i.e. nitrides; Compounds of nitrogen with more than one metal, silicon or boron with transition metals other than titanium, zirconium or hafnium
    • C01B21/0625—Binary compounds of nitrogen with metals, with silicon, or with boron, or with carbon, i.e. nitrides; Compounds of nitrogen with more than one metal, silicon or boron with transition metals other than titanium, zirconium or hafnium with copper
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JP2019076149A 2018-04-13 2019-04-12 二酸化炭素還元反応に用いられる新規窒素ドープ銅ナノ触媒 Expired - Fee Related JP7113781B2 (ja)

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US15/953,079 2018-04-13
US15/953,079 US10883183B2 (en) 2018-04-13 2018-04-13 Method of preparing copper-copper nitride nanocatalysts for carbon dioxides reduction reaction

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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11267712B2 (en) * 2018-10-10 2022-03-08 Honda Motor Co., Ltd. Tuning products selectivity of CO2 reduction reaction with surface ligands
WO2022072434A1 (en) * 2020-09-30 2022-04-07 Ut-Battelle, Llc Alloy based electrochemical catalyst for conversion of carbon dioxide to hydrocarbons
CN113249748B (zh) * 2021-04-21 2022-08-12 北京航天动力研究所 一种氮掺杂的氧化亚铜电催化剂、制备方法、电极及应用
US12080895B2 (en) * 2022-08-09 2024-09-03 Honda Motor Co., Ltd. Method for the synthesis of high efficiency PT branched nanocatalysts
CN115710724B (zh) * 2022-11-06 2025-07-08 浙江工业大学 一种用于电催化还原二氧化碳的非金属掺杂铜基催化材料及其制备方法和应用
CN116288418B (zh) * 2023-02-16 2025-09-05 国家能源集团新能源技术研究院有限公司 碳基疏水催化电极材料的制备及其在二氧化碳电催化中的应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008057041A (ja) 2006-08-29 2008-03-13 Samsung Electro Mech Co Ltd キュービック形態の銅ナノ粒子の製造方法
JP2009084677A (ja) 2007-09-28 2009-04-23 Samsung Electro Mech Co Ltd ロッド形状のナノ粒子を含む金属ナノ粒子の製造方法
JP2012184451A (ja) 2011-03-03 2012-09-27 Hitachi Cable Ltd 金属微粒子の製造方法及びそれにより得られる金属ペースト並びに金属皮膜
CN102941350A (zh) 2012-11-06 2013-02-27 南京工业大学 一种纳米铜粉的制备方法

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6033422B2 (ja) * 1981-10-26 1985-08-02 三菱瓦斯化学株式会社 炭酸エステルの製造法
CN102276644B (zh) * 2003-08-14 2014-09-03 孟山都技术公司 含有过渡金属-碳化物和氮化物的催化剂、它们的制备方法和作为氧化和脱氢催化剂的用途
WO2005060610A2 (en) 2003-12-11 2005-07-07 The Trustees Of Columbia University In The City Ofnew York Nano-sized particles, processes of making, compositions and uses thereof
GB0409877D0 (en) 2004-04-30 2004-06-09 Univ Manchester Preparation of nanoparticle materials
US7208133B2 (en) 2004-11-22 2007-04-24 International Business Machines Corporation Method for the preparation of IV-VI semiconductor nanoparticles
CN101583425A (zh) * 2005-02-17 2009-11-18 孟山都技术公司 含过渡金属的催化剂、包含含过渡金属的催化剂的催化剂组合物、它们的制备方法和作为氧化催化剂的用途
TW200811055A (en) 2006-04-12 2008-03-01 Nanomas Technologies Inc Nanoparticles, methods of making, and applications using same
WO2008033388A2 (en) * 2006-09-12 2008-03-20 Qd Vision, Inc. A composite including nanoparticles, methods, and products including a composite
KR100814295B1 (ko) 2006-10-10 2008-03-18 삼성전기주식회사 구리 나노입자의 제조방법 및 그에 의해 제조된 구리나노입자
KR20090012605A (ko) 2007-07-30 2009-02-04 삼성전기주식회사 금속 나노입자의 제조방법
KR20090032839A (ko) 2007-09-28 2009-04-01 삼성전기주식회사 구리계 나노입자의 제조방법
CN101327433A (zh) * 2008-07-30 2008-12-24 中国科学院山西煤炭化学研究所 一种纳米金属碳化物催化剂及制备和应用
US8486305B2 (en) 2009-11-30 2013-07-16 Lockheed Martin Corporation Nanoparticle composition and methods of making the same
CN101805011B (zh) 2010-04-06 2011-11-09 厦门大学 Cu2O超细纳米粒子与自组装纳米微球及其制备方法
US8845878B2 (en) * 2010-07-29 2014-09-30 Liquid Light, Inc. Reducing carbon dioxide to products
US8852835B2 (en) * 2012-12-12 2014-10-07 Xerox Corporation Black toner
CN103933978B (zh) * 2014-04-10 2015-12-30 中国科学院福建物质结构研究所 一种用于二氧化碳催化转化的负载型纳米催化剂及其制备方法和应用
WO2015195650A1 (en) 2014-06-16 2015-12-23 Kansas State University Research Foundation Direct transformation of bulk materials to nanoparticles
EP3169434A1 (en) * 2014-07-14 2017-05-24 Yeda Research and Development Co., Ltd. Copper nanoparticles for oxidation of pollutants
KR101725315B1 (ko) 2015-04-15 2017-04-10 성균관대학교산학협력단 다양한 크기 조절 및 대용량 합성이 가능한 균일한 구리 나노결정 및 이의 제조 방법
US20170314148A1 (en) 2016-05-02 2017-11-02 Ut-Battelle, Llc Electrochemical catalyst for conversion of co2 to ethanol

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008057041A (ja) 2006-08-29 2008-03-13 Samsung Electro Mech Co Ltd キュービック形態の銅ナノ粒子の製造方法
JP2009084677A (ja) 2007-09-28 2009-04-23 Samsung Electro Mech Co Ltd ロッド形状のナノ粒子を含む金属ナノ粒子の製造方法
JP2012184451A (ja) 2011-03-03 2012-09-27 Hitachi Cable Ltd 金属微粒子の製造方法及びそれにより得られる金属ペースト並びに金属皮膜
CN102941350A (zh) 2012-11-06 2013-02-27 南京工业大学 一种纳米铜粉的制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Chem.Commun.，2011年，vol.47，p.3604-3606

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CN110368974B (zh) 2022-04-26
JP2019205993A (ja) 2019-12-05
DE102019203866A1 (de) 2019-10-17
CN110368974A (zh) 2019-10-25
US10883183B2 (en) 2021-01-05

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