JP7090759B2 - Pharmaceutical composition, incense stick for pest control, and method for enhancing diffusion of insecticidal components using them - Google Patents

Description

The present invention relates to an improvement of an incense stick for controlling pests.

Pest control incense sticks, especially mosquito coils, are mainly intended for the extermination of adult mosquitoes, and have long been popular in ordinary households as indispensable in the summer.
This mosquito coil is an incense stick base material such as pyrethroid insecticidal component, fuel-supporting agent / bulking agent (vegetable powder, mineral powder, charcoal powder, etc.) and paste (vegetable binder, starch, etc.), and necessary. If so, add an aqueous solution containing a colorant to a mixed powder containing a fragrance, a starch-proofing agent, etc., knead it, and then apply it to an extruder to form a plate-like sheet. It is common to make it.
Mosquito coils have the convenience of being easily used anywhere with a single match, maintain a certain insecticidal effect until they burn out, and have excellent diffusion power of the active ingredient, so it is very rational even from the present day when science has advanced. It can be said that it is a typical insecticidal form.
Insect control incense sticks such as mosquito coils with a long history have been used more and more outdoors due to the recent outdoor boom, and indoors, they are suitable for specifications in a wide space due to changes in the living environment. Therefore, it has been required to have excellent diffusivity of the insecticidal component. In addition, there is a demand for a scent that matches the pest control incense stick due to recent changes in the usage environment, and improvements by blending various fragrances and stimulants to alleviate the irritation associated with combustion are being considered. There is.

Japanese Unexamined Patent Publication No. 2014-148503 JP-A-2017-1977

An object of the present invention is to provide an incense stick for controlling pests, which is excellent in spreading an insecticidal component.

In the present invention, a compound having a trimethylbicyclo [3.1.0] hexane skeleton and / or a trimethylcyclopentenyl skeleton is unexpectedly blended in various trial studies of compounding components in order to achieve the above object. It was found that the diffusivity of pyrethroid insecticidal components is increased.
That is, the present invention achieves the above object by the following configuration and exhibits excellent effects.
(1) Pyrethroid insecticidal components and
Incense stick base material and
A compound having a trimethylbicyclo [3.1.0] hexane skeleton and / or a trimethylcyclopentenyl skeleton, and
An incense stick for controlling pests containing.
(2) The compound having the trimethylbicyclo [3.1.0] hexane skeleton and / or the trimethylcyclopentenyl skeleton is
[1-Methyl-2- (1,2,2-trimethylbicyclo [3.1.0] hexa-3-ylmethyl) cyclopropyl] methanol,
3-Methyl-5- (2,2,3-trimethyl-3-cyclopentene-1-yl) -pentane-2-ol,
2-Ethyl-4- (2,2,3-trimethyl-3-cyclopentene-1-yl) -2-buten-1-ol,
(E)-(R) -2-Ethyl-4- (2,2,3-trimethyl-3-cyclopentene-1-yl) -2-buten-1-ol,
2-Methyl-4- (2,2,3-trimethyl-3-cyclopentene-1-yl) -2-buten-1-ol,
2-Methyl-4- (2,2,3-trimethyl-3-cyclopentene-1-yl) -butane-1-ol,
3-Methyl-5- (2,2,3-trimethyl-3-cyclopentene-1-yl) -4-penten-2-ol,
3,3-dimethyl-5- (2,2,3-trimethyl-3'-cyclopentene-1-yl) -4-penten-2-ol, and 2-methyl-4-methylene-4- (2,2) , 3-trimethyl-3-cyclopentene-1-yl) -butanol,
The incense stick for pest control according to (1), which is at least one selected from.
(3) The compound having the trimethylbicyclo [3.1.0] hexane skeleton and / or the trimethylcyclopentenyl skeleton is
[1-Methyl-2- (1,2,2-trimethylbicyclo [3.1.0] hexa-3-ylmethyl) cyclopropyl] The incense stick for pest control according to (2), which is methanol.
(4) The pest control incense stick according to any one of (1) to (3), which further contains a fragrance and / or an irritant-relieving agent.
(5) The fragrances are galaxolide, cashmeren, and iso-esuper (7-acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethylnaphthalene). ), Isolongihoranone, methylyonone, cis-3-hexenol, santalol, and sandalwood oil, which is at least one selected from the pest control incense stick according to (4).
(6) The pest control incense stick according to (4), wherein the stimulant alleviating agent is N-phenylacetamide and / or N,2-dimethyl-N-phenylbutaneamide.
(7) The incense base material is at least selected from pyrethrum extract powder as a vegetable powder, citrus epidermis powder, tea powder, coconut shell powder, ebony powder, and / or tab powder as a plant binder. The pest control incense according to any one of (1) to (6), which contains one kind.
(8) For pest control incense sticks containing pyrethroid insecticidal components and incense stick base materials
A method for enhancing the diffusion of an insecticidal component of the pyrethroid-based insecticidal component, which further comprises a compound having a trimethylbicyclo [3.1.0] hexane skeleton and / or a trimethylcyclopentenyl skeleton.
(9) The compound having a trimethylbicyclo [3.1.0] hexane skeleton and / or a trimethylcyclopentenyl skeleton is
[1-Methyl-2- (1,2,2-trimethylbicyclo [3.1.0] hexa-3-ylmethyl) cyclopropyl] methanol,
3-Methyl-5- (2,2,3-trimethyl-3-cyclopentene-1-yl) -pentane-2-ol,
2-Ethyl-4- (2,2,3-trimethyl-3-cyclopentene-1-yl) -2-buten-1-ol,
(E)-(R) -2-Ethyl-4- (2,2,3-trimethyl-3-cyclopentene-1-yl) -2-buten-1-ol,
2-Methyl-4- (2,2,3-trimethyl-3-cyclopentene-1-yl) -2-buten-1-ol),
2-Methyl-4- (2,2,3-trimethyl-3-cyclopentene-1-yl) -butane-1-ol,
3-Methyl-5- (2,2,3-trimethyl-3-cyclopentene-1-yl) -4-penten-2-ol,
3,3-dimethyl-5- (2,2,3-trimethyl-3'-cyclopentene-1-yl) -4-penten-2-ol, and 2-methyl-4-methylene-4- (2,2) , 3-trimethyl-3-cyclopentene-1-yl) -butanol,
The method for enhancing the diffusion of an insecticidal component according to (8), which is at least one selected from the above.
(10) The compound having a trimethylbicyclo [3.1.0] hexane skeleton and / or a trimethylcyclopentenyl skeleton is
[1-Methyl-2- (1,2,2-trimethylbicyclo [3.1.0] hexa-3-ylmethyl) cyclopropyl] The method for enhancing the diffusion of insecticidal components according to (8) or (9), which is methanol. ..

The incense stick for controlling pests of the present invention is excellent in the diffusion of pyrethroid-based insecticidal components due to the effect of blending the insecticidal component diffusion enhancer. Further, by blending a predetermined fragrance and / or a stimulant alleviating agent together with the insecticidal component diffusion enhancer, not only the stimulus is reduced by burning the base material but also a scent suitable for a pest control incense stick is imparted, and its practicality is extremely high.

The pest control incense stick of the present invention uses a pyrethroid insecticidal ingredient as an active ingredient from the viewpoint of insecticidal efficacy and safety. Pyrethroid insecticidal components include pyrethrin, allethrin, flamethrin, prarethrin, empentrin, terraresulin, transfluthrin, metoflutrin, profluthrin, 4-methoxymethyl-2,3,5,6-tetrafluorobenzyl 2,2,3,3. -Examples include, but are not limited to, tetramethylcyclopropanecarboxylate. In addition, when an asymmetric carbon or an optical isomer or a geometric isomer based on a double bond is present in the chemical structure, it goes without saying that the present invention includes each alone or an arbitrary mixture.
The content of the pyrethroid insecticidal component is preferably 0.005 to 2.0% by mass with respect to the total amount of the pest control incense stick.

In the present invention, N- (2-ethylhexyl) -bicyclo [2,2,1] hepta-5-ene-2,3-dicarboxyimide (hereinafter referred to as efficacy enhancer A) is used to enhance the insecticidal efficacy. ), Piperonyl butoxide, Resen 384 and other synergists can also be added. The synergist may be added in an amount of 0.1 to 20.0 times the amount of the pyrethroid insecticidal component.

Examples of the incense base material include fuel-supporting agents / bulking agents (vegetable powder, mineral powder, charcoal powder, etc.) and pastes (vegetable binder, starch, etc.), which are highly practical in the present invention. Selected from pesticide chrysanthemum extract starch powder as plant powder, citrus epidermis powder, tea powder, coconut shell powder, ebony powder, and / or tab powder as plant binder to provide pest control incense. At least one is preferably used. The tea powder referred to in the present invention includes not only ordinary dried tea leaves powdered but also tea-extracted tea powder obtained by drying and powdering tea leaves obtained by filtering tea.
The incense base material may be appropriately blended in the range of 1.0 to 99% by mass, preferably 10 to 80% by mass, and more preferably 20 to 70% by mass with respect to the total amount of the pest control incense. Combined with the insecticidal component diffusion enhancer described later, the diffusivity of the insecticidal component is further enhanced, and a wide range of pest control is possible.
Of course, as long as it does not interfere with the gist of the present invention, for example, wood powder such as fir, toga, hinoki (vegetable powder), ash soil, clay, kaolin, talc, etc. (mineral powder), or A fuel-supporting agent / bulking agent other than the above, such as plain ash (charcoal powder), or a paste other than the above, such as starch, tapioca powder, carboxymethyl cellulose (CMC), and polyvinyl alcohol, may be appropriately blended. As a result of the test, it was preferable to keep the amount of wood powder to 45% or less of the total amount of incense sticks for pest control and to avoid the use of pine and cedar.

The incense stick for controlling pests of the present invention is characterized by containing a compound having a trimethylbicyclo [3.1.0] hexane skeleton and / or a trimethylcyclopentenyl skeleton as an insecticidal component diffusion enhancer together with the above components.
As a compound having a trimethylbicyclo [3.1.0] hexane skeleton, specifically,
[1-Methyl-2- (1,2,2-trimethylbicyclo [3.1.0] hexa-3-ylmethyl) cyclopropyl] methanol (Givaudan "Javanol") is exemplified.
Specifically, as a compound having a trimethylcyclopentenyl skeleton,
3-Methyl-5- (2,2,3-trimethyl-3-cyclopentene-1-yl) -pentane-2-ol (Givaudan "Sandaroa"),
2-Ethyl-4- (2,2,3-trimethyl-3-cyclopentene-1-yl) -2-buten-1-ol (IFF "Bakudanol"),
(E)-(R) -2-Ethyl-4- (2,2,3-trimethyl-3-cyclopentene-1-yl) -2-buten-1-ol (Takasago International Corporation "Revosandor") ,
2-Methyl-4- (2,2,3-trimethyl-3-cyclopentene-1-yl) -2-buten-1-ol (Kao Corporation, "Sandals My Solcore"),
2-Methyl-4- (2,2,3-trimethyl-3-cyclopentene-1-yl) -butane-1-ol (Simrise "Bramanol"),
3-Methyl-5- (2,2,3-trimethyl-3-cyclopentene-1-yl) -4-penten-2-ol (Givaudan "Evanol"),
3,3-Dimethyl-5- (2,2,3-trimethyl-3'-cyclopentene-1-yl) -4-penten-2-ol (Filmenich "Polysantoll"),
Examples thereof include 2-methyl-4-methylene-4- (2,2,3-trimethyl-3-cyclopentene-1-yl) -butanol (Filmenich "Filsantoll").
At least one selected from these is blended in the range of 0.0001 to 2.0% by mass, more preferably 0.0001 to 1% by mass, based on the total amount of the pest control incense stick.
These compounds are used as synthetic fragrances with a sandalwood-like scent, and when blended, they give a mild sandalwood scent, but the effect of increasing the diffusion of pyrethroid insecticidal components has not been known until now. Is.

Among the above-mentioned insecticidal component diffusion enhancers, [1-methyl-2- (1,2,2-trimethylbicyclo [3.1.0] hexa-3-ylmethyl) cyclopropyl] methanol is particularly preferably used. It is presumed that the unique chemical properties including the ring structure are involved in the diffusivity in terms of efficiently diffusing the insecticidal component during use in combination with the burning state of the pest control incense.

Further, in the present invention, it is preferable to contain a fragrance having a boiling point of 250 ° C. or higher and 400 ° C. or lower as a base note component. Since such fragrances volatilize and diffuse when burning incense sticks, they give off a mellow "peaceful scent" as a base note ingredient, and are suitable for insecticidal ingredient diffusion enhancers to design a wide range of fragrances. Not only is it possible, but it is also considered to have an auxiliary effect of the insecticidal component diffusion enhancer.
Specifically, galaxolide, muskketone, hexyl cinnamic aldehyde, ethylene brush rate, methyl atlasate, hexyl salicylate, tricyclodecenyl acetate, oranger crystal, ambroxane, cash melan, caron, heliotropin, dihydroindenyl. -2,4-dioxane, indole, methyl sedrill ketone, methyl β-naphthyl ketone, methyl dihydrojasmonate, rosephenone, coumarin, vanillin, stylux resinoid, iso-e super (7-acetyl-1,2, 3,4,5,6,7,8-octahydro-1,1,6,7-tetramethylnaphthalene) (hereinafter referred to as "iso-e super"), benzylbenzoate, benzylsalicylate, ionone, Lilyaldehyde, isolongihoranone, acetoacetic acid-m-xylidide, acetoacetic acid-o-toluidide, acetosyringone, acetyltriethylcitrate, benzophenone, benzylcaprilate, benzylcinnamate, benzyleugenol, benzyllaurate, benzylmethyl Methyl, benzylphenyl ether, benzylphenyl acetate, geranylanthranilate, geranylhexanoate, geranylcyclopentanone, geranylphenylacetate, hexylphenylacetate, icosan, indan, cinnamylbutyrate, cinnamylphenylacetate, hexenyl Benzoate, Citral diethylacetal, Isoamylbenzoate, Linalyloctanoate, 1-mentylsalicylate, Citronerylanthranilate, Dimethylphenethylcarbinylisobutyrate, Diphenyloxide, Dodecylbutyrate, Ethylvanirate, Ethylvanillin, Menthyl Isovalerate, methoxyethylphenylglycidate, methyl2,4-dihydroxy-3,6-dimethylbenzoate, nerolidylacetate, nerylisovalerate, octenylcyclopentanone, octylcaprylate, phenethylisoamyl ether, phenethyloctano Ate, phenethylphenyl acetate, ethyl vaniline acetate, ethyl vaniline propylene glycol acetal, ethylhexyl palmitate, eugenylbenzoate, farnesol, farnesyl acetate, farnesyl methyl ether, formaldehyde cyclododecylmethyl acetal, Formylethyltetramethyltetraline, flufurylbenzoate, γ-dodecalactone, phenethylsalicylate, phenoxyethylpropionate, phenylbenzoate, phenyldisulfide, santalylbutyrate, tetrahydro-psoid-ionone, theobromine, valensen, santalol, And sandalwood oil and the like, and at least one selected from these is blended in the range of 0.001 to 2.0% by mass with respect to the total amount of the pest control incense stick. When the above-mentioned fragrance component is contained in the essential oil, it is needless to say that the essential oil is also included in the present invention.
Among the above fragrance components, it is particularly preferable that the fragrance component is at least one selected from galaxoride, cash melanin, iso-esuper, isolongihoranone, santalol, and sandalwood oil.

Further, it is also possible to further contain a fragrance having a boiling point of less than 250 ° C. to adjust the fragrance tone and volatility as the top note and middle note components of the fragrance.
For example, p-tert-butylcyclohexyl acetate, o-tert-butylcyclohexyl acetate, p-tert-pentylcyclohexyl acetate, benzyl acetate, phenylethyl acetate, styralyl acetate, anisyl acetate, cinnamyl acetate, terpinyl acetate, Acetate ester compounds such as dihydroterpinyl acetate, linaryl acetate, ethyl linaryl acetate, citronellyl acetate, geranyl acetate, neryl acetate, borneyl acetate, and isobornyl acetate, allylhexanoate, allylheptanoate, allylocta Allyl ester compounds such as Noate, allylisobutyloxyacetate, allyl n-amyloxyacetate, allylcyclohexylacetate, allylcyclohexylpropionate, allylcyclohexyloxyacetate, allylphenoxyacetate, as well as terpineol, geraniol, dihydromilsenol, Monoterpene alcohols such as borneol, menthol, citronerol, nerol, linalol, ethyllinalol, timol, phenylethyl alcohol, and eugenol or aromatic alcohols with 10 carbon atoms, as well as limonene, α-pinene, terpinen, methylyonone, Examples thereof include, but are not limited to, tonalide and anisaldehyde.
Among the above fragrance components, it is particularly preferable to contain at least methylyonone.

Further, in the present invention, it is preferable to contain an N-phenylalkylamide derivative or the like as a stimulant relieving agent. By blending N-phenylacetamide or N,2-dimethyl-N-phenylbutaneamide as the N-phenylalkylamide derivative, it is also effective to further alleviate irritation during use. Furthermore, by blending a "green scent" typified by cis-3-hexenol, it is possible to bring about a relaxing effect as well as alleviate irritation during use and realize a scent suitable for pest control incense sticks.

In addition to the above components, additives such as antifungal agents, stabilizers, and colorants may be added to the pest control incense stick of the present invention. Examples of the fungicide include dehydroacetic acid salt and sorbate salt, and the typical stabilizer is dibutylhydroxytoluene (BHT). Malachite green is used as the colorant, and the green swirl incense that brings out a cool feeling is the mainstream, but it is also practical to use a highly safe pigment that corresponds to a food additive. For example, edible blue No. 1 and edible yellow No. 4 and / or edible red No. 106 can be combined to realize a green color that replaces malachite green, or a yellow-green incense stick, a purple incense stick, or the like can be produced.

The incense stick for pest control of the present invention is prepared by adding an aqueous solution containing a colorant to a mixed powder containing the above-mentioned components and water, kneading the incense stick, and then subjecting the incense stick to a plate-like sheet by an extruder. It is generally manufactured by drying to about 10%. It is also possible to add the pyrethroid insecticidal component and / or the fragrance component by means such as spraying, coating, dropping, and dipping after incense molding containing no pyrethroid insecticidal component and / or fragrance component.

The pest control incense of the present invention thus obtained has excellent diffusion power of pyrethroid insecticidal components while maintaining the quality of the conventional pest control incense, and is imparted with a highly palatable scent. It has a high control effect on mosquitoes, flies, cockroaches, flea, bed bugs, flies, and yusurika. Examples of mosquitoes include common house mosquito, Aedes albopictus, London Underground mosquito, Kodaka mosquito, Culex quinquefa, and Ceratopogonidae.

Next, the pest control incense stick of the present invention will be described in more detail based on specific examples, but the present invention is not limited to these.

0.3 parts of dl, d-T80-aresulin, 0.7 parts of efficacy enhancer A, 26 parts of pyrethrum-extracted starch (vegetable powder) as a fuel-supporting agent / bulking agent, and citrus epidermis (vegetable). 15 parts of powder), 33.5 parts of wood powder (vegetable powder derived from fir), 8 parts of tab powder (vegetable binder), 12 parts of α-starch, and CMC as glue. 4 parts, 0.0001 parts of Javanol as an insecticidal component diffusion enhancer, 0.01 parts of N-phenylacetamide and cis-3-hexenol as stimulants, and a fragrance component containing Santa roll etc. (boiling point is 250 ° C) As a starch-proofing agent, a mixed powder containing 0.1 part of a base note component (base note component of 400 ° C or lower) and 0.09 part of a fragrance component (top note and middle note component having a boiling point of less than 250 ° C) containing methylyonone. Add 0.3 parts of starch dehydroacetate and 100 parts of water, knead, put into a plate-shaped sheet by an extruder, punch out into a spiral shape with a punching machine, and dry to a moisture content of about 7 to 10% to a yellowish brown pest. The control incense A was manufactured.

The pest control incense stick A of the present invention thus obtained emitted the scent of sandalwood when opened before use, and no offensive odor or pungent odor was felt. When I used it while sleeping in a room with 6 tatami mats, the scent of sandalwood lasted until the end of use, giving me a feeling of relaxation and not being bothered by mosquitoes during that time.

Similar to the pest control incense A, the pest control incense B manufactured by replacing only the pest control component diffusion enhancer with Sandaroa, the pest control incense C manufactured by replacing only the pest control component diffusion enhancer with Bagdanol, and the pest control component. Pest control incense D manufactured by replacing only the diffusion enhancer with Revosandor, pest control incense E manufactured by replacing only the insecticidal component diffusion enhancer with sandal mysol core, and pest control component diffusion enhancer replaced with bramanol. The pest control incense F produced in the above was prepared. When these incense sticks were tested in a 6 tatami room in the same way as the pest control incense stick A, the scent of sandalwood persisted, there was no pungent odor, a feeling of relaxation was brought about, and mosquitoes were annoyed during that time. I was able to confirm that there was no such thing.

Various pest control incense sticks shown in Table 1 (the composition of the potency enhancer, the colorant, the fungicide and water is the same as in Example 1) were prepared according to Example 1, and the performance was evaluated for the following items. did. The results are shown in Table 2.

<Sensory test>
The pest control incense sticks of Examples 1 to 10 and Comparative Examples 1 to 5 were installed in a room of 6 tatami mats, ignited and burned. Then, the scent emitted from the incense stick was evaluated by 10 panelists. The evaluation items were "stimulation relaxation" and "scent preference", the highest score was 10 points, the lowest score was 1, and the average score of 10 panelists was calculated for each incense stick.

<Diffusion speed>
The pest control incense sticks of Examples 1 to 10 and Comparative Examples 1 to 5 were installed in one of the four corners of a room having a size of 6 tatami mats, and ignited and burned. A glass tube filled with silica gel is connected to a vacuum pump to blow air at a height of 1 m at a location 2 m and 4 m away from the incense stick installation position on the diagonal line extending from the incense stick installation position to the opposite corner of the room. Collected over time every 10 minutes until 30 minutes after ignition. The amount of the insecticidal component collected in the glass tube was eluted with a solvent and analyzed by gas chromatography to quantify the amount of the insecticidal component, and 10 minutes after the start, the amount collected at a position 2 m away was 4 m away. At the position, the case of detection after 10 minutes from the start was evaluated as ⊚, the case of detection after 10 minutes to 20 minutes was evaluated as ◯, and the case of detection after 20 minutes to 30 minutes was evaluated as Δ.

As a result of the test, the present invention having an insecticidal component diffusion enhancer is superior in distant diffusion of the insecticidal component as compared with the comparative example not containing it, and therefore, it is a pest control incense stick having a higher immediate effect over a wider range. It was shown to be possible. The insecticidal component diffusion enhancing effect was particularly remarkable when Javanol was contained, and it was considered to be an effective component.
Further, comparing the present invention 1 with the comparative example 1, the blending of the insecticidal component diffusion enhancer is based on the effect of enhancing the insecticidal component diffusion, the effect of the stimulant stimulant to alleviate the irritation when smoking, and the blending of the fragrance component. It shows the effect of further enhancing the evaluation of palatability, and the fragrance components at that time include galaxoride, cash melanin, iso-e-super, isolongihoranone, methylyonone, santalol, sandalwood oil, and cis-3-. The formulation of hexenol was more effective.
As described above, it was shown that the coexistence of not only the insecticidal component diffusion enhancer but also the stimulant relieving agent and the predetermined fragrance component enhances each effect and can be an excellent pest control incense stick.

The pest control incense stick of the present invention is highly practical as an insecticide, and can be applied to other incense sticks such as Buddhist altar incense sticks.

Claims (10)

Pyrethroid insecticidal ingredients and
Incense stick base material and
A compound having a trimethylbicyclo [3.1.0] hexane skeleton and / or a trimethylcyclopentenyl skeleton, and
An incense stick for pest control that contains
The incense stick base material is an incense stick for pest control, which is blended in an amount of 1.0 to 99% by mass with respect to the total amount of the incense stick for controlling pests. The compound having a trimethylbicyclo [3.1.0] hexane skeleton and / or a trimethylcyclopentenyl skeleton
[1-Methyl-2- (1,2,2-trimethylbicyclo [3.1.0] hexa-3-ylmethyl) cyclopropyl] methanol,
3-Methyl-5- (2,2,3-trimethyl-3-cyclopentene-1-yl) -pentane-2-ol,
2-Ethyl-4- (2,2,3-trimethyl-3-cyclopentene-1-yl) -2-buten-1-ol,
(E)-(R) -2-Ethyl-4- (2,2,3-trimethyl-3-cyclopentene-1-yl) -2-buten-1-ol,
2-Methyl-4- (2,2,3-trimethyl-3-cyclopentene-1-yl) -2-buten-1-ol,
2-Methyl-4- (2,2,3-trimethyl-3-cyclopentene-1-yl) -butane-1-ol,
3-Methyl-5- (2,2,3-trimethyl-3-cyclopentene-1-yl) -4-penten-2-ol,
3,3-dimethyl-5- (2,2,3-trimethyl-3'-cyclopentene-1-yl) -4-penten-2-ol, and 2-methyl-4-methylene-4- (2,2) , 3-trimethyl-3-cyclopentene-1-yl) -butanol,
The pest control incense stick according to claim 1, wherein the incense stick is at least one selected from the above. The compound having a trimethylbicyclo [3.1.0] hexane skeleton and / or a trimethylcyclopentenyl skeleton
[1-Methyl-2- (1,2,2-trimethylbicyclo [3.1.0] hexa-3-ylmethyl) cyclopropyl] The incense stick for pest control according to claim 2, which is methanol. .. The pest control incense stick according to any one of claims 1 to 3, further comprising a fragrance and / or an irritant-relieving agent. The fragrances are galaxolide, cashmeren, iso-esuper (7-acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethylnaphthalene), iso. The pest control incense stick according to claim 4, wherein the incense stick is at least one selected from longiphoranone, methylyonone, cis-3-hexenol, santalol, and sandalwood oil. The pest control incense stick according to claim 4, wherein the stimulant alleviating agent is N-phenylacetamide and / or N,2-dimethyl-N-phenylbutaneamide. The incense base material is at least one selected from pyrethrum extract powder as a vegetable powder, citrus epidermis powder, tea powder, coconut shell powder, pyrethrum powder, and / or tab powder as a plant binder. The pest control incense according to any one of claims 1 to 6, wherein the incense is contained. For pest control incense sticks containing pyrethroid insecticidal components and incense stick base material,
Further, a method for enhancing the diffusion of an insecticidal component of the pyrethroid-based insecticidal component containing a compound having a trimethylbicyclo [3.1.0] hexane skeleton and / or a trimethylcyclopentenyl skeleton.
The method for enhancing the diffusion of an insecticidal component of the pyrethroid-based insecticidal component , wherein the incense base material is blended in an amount of 1.0 to 99% by mass with respect to the total amount of the incense stick for controlling pests . The compound having a trimethylbicyclo [3.1.0] hexane skeleton and / or a trimethylcyclopentenyl skeleton
[1-Methyl-2- (1,2,2-trimethylbicyclo [3.1.0] hexa-3-ylmethyl) cyclopropyl] methanol,
3-Methyl-5- (2,2,3-trimethyl-3-cyclopentene-1-yl) -pentane-2-ol,
2-Ethyl-4- (2,2,3-trimethyl-3-cyclopentene-1-yl) -2-buten-1-ol,
(E)-(R) -2-Ethyl-4- (2,2,3-trimethyl-3-cyclopentene-1-yl) -2-buten-1-ol,
2-Methyl-4- (2,2,3-trimethyl-3-cyclopentene-1-yl) -2-buten-1-ol),
2-Methyl-4- (2,2,3-trimethyl-3-cyclopentene-1-yl) -butane-1-ol,
3-Methyl-5- (2,2,3-trimethyl-3-cyclopentene-1-yl) -4-penten-2-ol,
3,3-dimethyl-5- (2,2,3-trimethyl-3'-cyclopentene-1-yl) -4-penten-2-ol, and 2-methyl-4-methylene-4- (2,2) , 3-trimethyl-3-cyclopentene-1-yl) -butanol,
The method for enhancing diffusion of an insecticidal component according to claim 8, wherein the method is at least one selected from the above. The compound having a trimethylbicyclo [3.1.0] hexane skeleton and / or a trimethylcyclopentenyl skeleton
[1-Methyl-2- (1,2,2-trimethylbicyclo [3.1.0] hexa-3-ylmethyl) cyclopropyl] The insecticidal component according to claim 8 or 9, which is methanol. Diffusion enhancement method.