JP7090483B2 - Flame-retardant resin composition, molded body using it, insulated electric wire, cable and optical fiber cable - Google Patents

Description

The present invention relates to a flame-retardant resin composition, a molded body using the same, an insulated electric wire, a cable, and an optical fiber cable.

In recent years, in OA equipment such as televisions, personal computers, printers, building materials, automobile interior materials, electronic parts, cables, optical fiber cables, etc., the demand for flame retardancy has become stricter from the viewpoint of fire prevention. Therefore, materials having high flame retardancy have been used for these.

As a material having such high flame retardancy, a flame retardant resin composition in which a phosphate compound is blended with a polyolefin resin is known (see Patent Document 1 below).

Japanese Unexamined Patent Publication No. 2014-65522

The flame-retardant resin composition described in Patent Document 1 exhibits excellent flame-retardant properties. However, the flame-retardant resin composition described in Patent Document 1 has room for improvement in terms of processability.

Therefore, there has been a demand for a flame-retardant resin composition having excellent flame retardancy and capable of improving processability.

The present invention has been made in view of the above circumstances, and is a flame-retardant resin composition having excellent flame retardancy and capable of improving processability, a molded body using the same, an insulated electric wire, and a cable. And to provide fiber optic cables.

The present inventors have repeated studies to solve the above problems. As a result, it has been found that the above-mentioned problems can be solved by a flame-retardant resin composition in which a specific phosphate compound is blended with a polyolefin resin in a specific ratio and a specific organic phosphorus compound and a specific ester compound are used. rice field.

（上記一般式（１）中、ｍは１～１００の整数を表す。）

（上記一般式（２）中、Ｘ^１及びＸ^２は同一又は異なるものであり、下記一般式（３）で表される。）

（上記一般式（３）中、ＡＬは炭素数１～５の分岐状又は直鎖状の脂肪族炭化水素基であり、Ａｒは、置換基を有してもよいフェニル基、ナフチル基又はアントリル基であり、ＡＬ中の任意の炭素原子に結合する。ｎは１～３の整数を示す。） That is, the present invention contains a polyolefin resin (A), a phosphate compound (B), an organic phosphorus compound (C), and an ester compound (D), and the phosphate compound (B) is the polyolefin. The resin (A) is blended in a ratio of more than 0 parts by mass and less than 20 parts by mass with respect to 100 parts by mass, and the phosphate compound (B) is a phosphoric acid represented by the following general formula (1) and a molecule. The organic phosphorus compound (C) is represented by the following general formula (2), and the ester compound (D) is a monoester compound or a diester compound, which contains a salt with an amine compound having at least one amino group. It is a flame-retardant resin composition containing at least one selected from the group consisting of.

(In the above general formula (1), m represents an integer from 1 to 100.)

(In the above general formula (2), X ¹ and X ² are the same or different, and are represented by the following general formula (3).)

(In the above general formula (3), AL is a branched or linear aliphatic hydrocarbon group having 1 to 5 carbon atoms, and Ar is a phenyl group, a naphthyl group or anthryl which may have a substituent. It is a group and is bonded to any carbon atom in AL. N indicates an integer of 1 to 3).

The flame-retardant resin composition of the present invention has excellent flame-retardant properties and can improve processability.

The present inventors infer the reason why the flame-retardant resin composition of the present invention has excellent flame-retardant property as follows.

That is, the phosphate compound contains a salt of phosphoric acid represented by the above general formula (1) and an amine compound having at least one amino group in the molecule, and is a flame-retardant resin composition. Produces a dense foam insulation layer when burned. Therefore, the combustion of the polyolefin resin is suppressed, and the flame-retardant resin composition is imparted with self-extinguishing property. Here, when another flame retardant such as a metal hydroxide or a silicone-based compound is used in combination with the above phosphate compound, the formation of a dense foamed heat insulating layer is inhibited. On the other hand, the organic phosphorus compound represented by the above general formula (2) is considered to suppress the combustion of the polyolefin resin by the radical trapping action in the solid phase. Moreover, since the organophosphorus compound has a phosphonic acid compound in its skeleton, it is considered to be compatible with a flame retardant composed of a phosphate compound. Further, since the above-mentioned organophosphorus compound has a pentaerythritol ester having an action of promoting carbonization during combustion in its skeleton, unlike other flame retardants such as metal hydroxides and silicone-based compounds, a dense foamed heat insulating layer is formed. It is considered that it is difficult to inhibit. Further, in the flame-retardant resin composition of the present invention, the temperature at which the radical trapping action is exhibited is close to the temperature at which the dense foamed heat insulating layer is formed, and the self-flame-retardant resin composition self at a temperature near the temperature at which the radical trapping action is exhibited. It is thought that the fire extinguishing property will increase sharply. Further, since the ester compound contains a hydroxyl group having a dehydrating ability, it is considered that the ester compound functions as a flame retardant aid. From the above, it is considered that the flame-retardant resin composition of the present invention has excellent flame-retardant properties.

Further, although the reason why the flame-retardant resin composition of the present invention can improve the processability is not clear, the present inventors speculate as follows.

That is, since the organic phosphorus compound has a planar structure and has few steric obstacles, when the flame-retardant resin composition is processed by using the phosphate compound and the organic phosphorus compound in combination. It is thought that the fluidity can be improved. Further, since the ester compound has a smaller polarity and a lower melting point than the polyhydric alcohol, it is considered that uniform dispersion in the polyolefin resin becomes possible. Therefore, it is considered that the flame-retardant resin composition can improve the processability.

In the flame-retardant resin composition, it is preferable that the organic phosphorus compound (C) is blended in a proportion of more than 0 parts by mass and less than 50 parts by mass with respect to 100 parts by mass of the polyolefin resin (A). ..

In this case, the flame retardancy of the flame-retardant resin composition can be further improved as compared with the case where the compounding ratio of the organic phosphorus compound (C) to 100 parts by mass of the polyolefin resin (A) is 50 parts by mass or more. .. Further, the processability and flame retardancy of the flame-retardant resin composition can be further improved as compared with the case where the compounding ratio of the organic phosphorus compound (C) to 100 parts by mass of the polyolefin resin (A) is 0 parts by mass. can.

In the flame-retardant resin composition, it is preferable that the ester compound (D) is blended in a proportion of more than 0 parts by mass and less than 5 parts by mass with respect to 100 parts by mass of the polyolefin resin (A).

In this case, better flame retardancy and processability can be obtained in the flame-retardant resin composition as compared with the case where the blending ratio of the ester compound (D) with respect to 100 parts by mass of the polyolefin resin (A) is 0 parts by mass. Be done. Further, the bloom in the flame-retardant resin composition can be more sufficiently suppressed as compared with the case where the blending ratio of the ester compound (D) with respect to 100 parts by mass of the polyolefin resin (A) is 5 parts by mass or more. Here, although it is not clear why the flame-retardant resin composition can suppress bloom, the present inventors speculate as follows.

That is, as described above, since the organophosphorus compound has a phosphonic acid compound in its skeleton, it is considered to have good compatibility with the phosphate compound. Further, as described above, since the ester compound has a smaller polarity and a lower melting point than the polyhydric alcohol, it is considered that uniform dispersion in the polyolefin resin becomes possible. Therefore, it is considered that the flame-retardant resin composition can suppress bloom.

In the flame-retardant resin composition, it is preferable that X ¹ and X ² in the general formula (2) are benzyl groups.

In this case, better processability can be obtained in the flame-retardant resin composition as compared with the case where X ¹ and X ² in the general formula (2) are not benzyl groups.

In the flame-retardant resin composition, m in the general formula (1) is 1 to 2, and the amine compound is an amine compound containing a triazine ring, an amine compound containing a piperazine ring, and an amine containing a triazine ring. It is preferably composed of a mixture with a compound, ammonia, or guanidyl urea.

In this case, the flame retardancy of the flame retardant resin composition is effectively improved.

In the flame-retardant resin composition, it is preferable that the amine compound is composed of a mixture of an amine compound containing a piperazine ring and an amine compound containing a triazine ring.

In this case, the flame retardancy of the flame-retardant resin composition is further improved as compared with the case where the amine compound is composed of an amine compound other than the above mixture.

In the flame-retardant resin composition, the melting point of the ester compound (D) is preferably 50 ° C. or higher and 180 ° C. or lower.

In this case, the ester compound (D) is more sufficiently suppressed from bleeding out to the surface of the flame-retardant resin composition even in a high temperature environment, as compared with the case where the melting point of the ester compound (D) is less than 50 ° C. can. That is, bloom in the flame-retardant resin composition can be more sufficiently suppressed. Further, as compared with the case where the melting point of the ester compound (D) exceeds 180 ° C., the ester compound (D) is easily melted and dispersed during processing of the flame-retardant resin composition, so that the flame-retardant resin composition can be used. The flame retardancy and appearance of the molded product obtained by processing can be further improved.

In the flame-retardant resin composition, it is preferable that the fluorine-based drip inhibitor (E) is further blended in a proportion of more than 0 parts by mass and less than 10 parts by mass with respect to 100 parts by mass of the polyolefin resin (A). ..

In this case, unlike the case where the compounding ratio of the fluorine-based drip inhibitor (E) to 100 parts by mass of the polyolefin resin (A) is 0 parts by mass, it is possible to prevent drip and prevent the spread of fire due to drip. The flame retardancy of the flame retardant resin composition can be improved. Further, the melt viscosity of the flame-retardant resin composition becomes too high as compared with the case where the compounding ratio of the fluorine-based drip inhibitor (E) to 100 parts by mass of the polyolefin resin (A) is 10 parts by mass or more. It is sufficiently suppressed and the processability of the flame-retardant resin composition is further improved.

In the flame-retardant resin composition, it is preferable that the polyolefin resin (A) contains a polypropylene resin.

In this case, the flame-retardant resin composition can have better heat resistance.

In the flame-retardant resin composition, it is preferable that the polyolefin resin (A) contains an elastomer.

In this case, the flame-retardant resin composition is more excellent in impact resistance and cold resistance as compared with the case where the polyolefin resin (A) does not contain an elastomer.

In the flame-retardant resin composition, the content of the elastomer in the polyolefin resin (A) is preferably 60% by mass or less.

In this case, the flame retardancy of the flame-retardant resin composition can be further improved as compared with the case where the content of the elastomer in the polyolefin resin (A) exceeds 60% by mass.

Further, the present invention is a molded product containing the above-mentioned flame-retardant resin composition.

Since this molded product contains a flame-retardant resin composition having excellent flame retardancy and capable of improving processability, various uses requiring both excellent flame retardancy and good appearance are required. Applicable to.

Further, the present invention is an insulating electric wire provided with a conductor and an insulating layer covering the conductor, wherein the insulating layer is composed of the above-mentioned flame-retardant resin composition.

Since the insulated wire of the present invention contains an insulating layer composed of a flame-retardant resin composition having excellent flame retardancy and capable of improving processability, it has excellent flame retardancy and a good appearance. It becomes possible to have.

Further, the present invention includes a conductor, an insulated wire having an insulating layer covering the conductor, and a coating layer covering the insulated wire, and at least one of the insulating layer and the coating layer is flame-retardant. A cable composed of a sex resin composition.

The cable of the present invention has excellent flame retardancy because at least one of the insulating layer and the coating layer is composed of a flame retardant resin composition having excellent flame retardancy and capable of improving processability. And it is possible to have a good appearance.

Further, the present invention includes an optical fiber and a coating portion that covers the optical fiber, the coating portion has an insulator that covers the optical fiber, and the insulator has the above-mentioned flame-retardant resin composition. It is an optical fiber cable composed of things.

In the optical fiber cable of the present invention, the insulator that covers the optical fiber in the covering portion is composed of a flame-retardant resin composition that has excellent flame retardancy and can improve processability. It is possible to have excellent flame retardancy and good appearance.

According to the present invention, there is provided a flame-retardant resin composition having excellent flame retardancy and capable of improving processability, a molded product, an insulated wire, a cable and an optical fiber cable using the same.

It is a partial side view which shows one Embodiment of the cable of this invention. FIG. 3 is a cross-sectional view taken along the line II-II of FIG. It is sectional drawing which shows one Embodiment of the optical fiber cable of this invention.

Hereinafter, embodiments of the present invention will be described in detail.

（上記一般式（１）中、ｍは１～１００の整数を表す。）

（上記一般式（２）中、Ｘ^１及びＸ^２は同一又は異なるものであり、下記一般式（３）で表される。）

（上記一般式（３）中、ＡＬは炭素数１～５の分岐状又は直鎖状の脂肪族炭化水素基であり、Ａｒは、置換基を有してもよいフェニル基、ナフチル基又はアントリル基であり、ＡＬ中の任意の炭素原子に結合する。ｎは１～３の整数を示す。） <Flame-retardant resin composition>
The flame-retardant resin composition of the present invention contains a polyolefin resin (A), a phosphate compound (B), an organic phosphorus compound (C), and an ester compound (D). Here, the phosphate compound (B) is blended in a proportion of more than 0 parts by mass and less than 20 parts by mass with respect to 100 parts by mass of the polyolefin resin (A). The phosphate compound (B) contains a salt of phosphoric acid represented by the following general formula (1) and an amine compound having at least one amino group in the molecule, and the organic phosphorus compound (C) is described below. It is represented by the general formula (2). Further, the ester compound (D) contains at least one selected from the group consisting of a monoester compound and a diester compound.

(In the above general formula (1), m represents an integer from 1 to 100.)

(In the above general formula (2), X ¹ and X ² are the same or different, and are represented by the following general formula (3).)

(In the above general formula (3), AL is a branched or linear aliphatic hydrocarbon group having 1 to 5 carbon atoms, and Ar is a phenyl group, a naphthyl group or anthryl which may have a substituent. It is a group and is bonded to any carbon atom in AL. N indicates an integer of 1 to 3).

The flame-retardant resin composition of the present invention has excellent flame-retardant properties and can improve processability.

Hereinafter, the polyolefin resin (A), the phosphate compound (B), the organic phosphorus compound (C) and the ester compound (D) will be described in detail.

(A) Polyolefin Resin Polyolefin resins have structural units derived from olefins (unsaturated aliphatic hydrocarbons) in their molecules. Polyolefin resins include homopolymers of olefins and co-weights of olefins different from each other. In addition to coalescing, copolymers of olefins and non-olefins are also included. Specific examples of the polyolefin resin include, for example, polyethylene (PE), polypropylene (PP), ethylene-ethyl acrylate copolymer (EEA), ethylene-vinyl acetate copolymer (EVA), ethylene-propylene copolymer and elastoma. And so on. These can be used alone or in combination of two or more.

Examples of the elastoma include a modified polypropylene-based elastoma, an olefin crystal-ethylene-butylene-olefin crystal copolymer (CEBC copolymer), a styrene-based elastoma, and a hydrogenated product modified by hydrogenating them. .. These can be used alone or in combination of two or more.

Examples of the styrene-based elastoma include styrene-butadiene rubber (SBR), styrene-ethylene-butadiene-styrene copolymer (SEBS copolymer), styrene-propylene-butadiene-styrene copolymer (SPBS copolymer), and styrene. Examples thereof include block copolymers of olefin and styrene such as -butadiene-styrene copolymer (SBS copolymer) and styrene-isoprene-styrene copolymer (SIS copolymer). These can be used alone or in combination of two or more.

Examples of the hydrogenated product include hydrogenated SBR, hydrogenated SEBS copolymer, hydrogenated SPBS copolymer, hydrogenated SBS copolymer and hydrogenated SIS copolymer. These can be used alone or in combination of two or more.

The polyolefin resin (A) preferably contains a polypropylene resin among the above specific examples. In this case, the flame-retardant resin composition can have better heat resistance than the case where the polyolefin resin (A) does not contain the polypropylene resin.

In this case, the content of the polypropylene resin in the polyolefin resin (A) is not particularly limited, but is preferably 30 to 100% by mass.

The polyolefin resin (A) preferably contains an elastomer among the above specific examples. In this case, the flame-retardant resin composition is more excellent in impact resistance and cold resistance as compared with the case where the polyolefin resin (A) does not contain an elastomer.

The polyolefin resin (A) preferably further contains an elastomer in addition to the polypropylene resin. In this case, the flame-retardant resin composition is more excellent in impact resistance and cold resistance as compared with the case where the polyolefin resin (A) does not contain an elastomer. Further, the flame-retardant resin composition is more excellent in heat resistance than the case where the polyolefin resin (A) does not contain the polypropylene resin.

In this case, the content of the elastomer in the polyolefin resin (A) is not particularly limited, but is preferably 60% by mass or less. In this case, the flame retardancy of the flame-retardant resin composition can be further improved as compared with the case where the content of the elastomer in the polyolefin resin (A) exceeds 60% by mass. Further, the content of the elastomer in the polyolefin resin (A) is more preferably less than 40% by mass. In this case, the flame retardancy of the flame-retardant resin composition can be further improved as compared with the case where the content of the elastomer in the polyolefin resin (A) is 40% by mass or more. The content of the elastomer in the polyolefin resin (A) is particularly preferably 20% by mass or less. In this case, the flame retardancy of the flame-retardant resin composition can be further improved as compared with the case where the content of the elastomer in the polyolefin resin (A) exceeds 20% by mass. However, the content of the elastomer in the polyolefin resin (A) is preferably 10% by mass or more. In this case, the processability of the flame-retardant resin composition can be further improved as compared with the case where the content of the elastomer in the polyolefin resin (A) is less than 10% by mass.

(B) Phosphate compound As described above, the phosphate compound comprises a salt of the phosphoric acid represented by the above general formula (1) and an amine compound having at least one amino group in the molecule. Contains a phosphate amine salt compound. Here, it is assumed that the "amino group" includes not only -NH ₂ but also -NH-.

In the general formula (1), m is preferably 1 or 2. In this case, the flame-retardant resin composition has more excellent flame-retardant property than the case where m is 3 or more.

Specific examples of the phosphoric acid represented by the general formula (1) include polyphosphoric acid such as pyrophosphoric acid and triphosphoric acid, and monophosphoric acid such as orthophosphoric acid.

Examples of the amine compound include an aliphatic diamine, an amine compound containing a piperazine ring, an amine compound containing a triazine ring, ammonia, and guanylurea. These can be used alone or in combination of two or more.

As the aliphatic diamine, those having 1 to 15 carbon atoms are preferably used. Examples of such an aliphatic diamine include N, N, N', N'-tetramethyldiaminomethane, ethylenediamine, N, N'-dimethylethylenediamine, N, N'-diethylethylenediamine, N, N-dimethylethylenediamine, and the like. N, N-diethylethylenediamine, N, N, N', N'-tetramethylethylenediamine, N, N, N', N'-diethylethylenediamine, 1,2-propanediamine, 1,3-propanediamine, tetramethylene Examples thereof include diamine, pentamethylenediamine, hexamethylenediamine, 1,7-diaminoheptane, 1,8-diaminooctane, 1,9-diaminononane and 1,10-diaminodecane. These can be used alone or in combination of two or more.

Examples of the amine compound containing a piperazine ring include piperazine, trans-2,5-dimethylpiperazine, 1,4-bis (2-aminoethyl) piperazine, and 1,4-bis (3-aminopropyl) piperazine. These can be used alone or in combination of two or more.

Examples of the amine compound containing a triazine ring include melamine, acetoguanamine, benzoguanamine, acrylic guanamine, 2,4-diamino-6-nonyl-1,3,5-triazine, 2,4-diamino-6-hydroxy-1, 3,5-Triazine, 2-amino-4,6-dihydroxy-1,3,5-Triazine, 2,4-diamino-6-methoxy-1,3,5-Triazine, 2,4-diamino-6 -Ethoxy-1,3,5-triazine, 2,4-diamino-6-propoxy-1,3,5-triazine, 2,4-diamino-6-isopropoxy-1,3,5-triazine, 2, Examples thereof include 4-diamino-6-mercapto-1,3,5-triazine and 2-amino-4,6-dimercapto-1,3,5-triazine. These can be used alone or in combination of two or more.

When m in the general formula (1) representing phosphoric acid is 1 to 2, the amine compound is an amine compound containing a triazine ring, or a mixture of an amine compound containing a piperazine ring and an amine compound containing a triazine ring. , Ammonia, or guanidyl urea is preferred. In this case, the flame retardancy of the flame retardant resin composition is effectively improved.

The amine compound is preferably composed of a mixture of an amine compound containing a piperazine ring and an amine compound containing a triazine ring. In this case, the flame retardancy of the flame-retardant resin composition is further improved as compared with the case where the amine compound is composed of an amine compound other than the above mixture. Here, the content of the amine compound containing the piperazine ring in the mixture is preferably 20 to 55% by mass. In this case, better flame retardancy can be obtained in the flame-retardant resin composition as compared with the case where the content of the amine compound containing the piperazine ring in the mixture is out of the above range.

As described above, the phosphate compound is blended in a proportion of more than 0 parts by mass and less than 20 parts by mass with respect to 100 parts by mass of the polyolefin resin (A). In this case, more excellent flame retardancy can be obtained in the flame-retardant resin composition as compared with the case where the compounding ratio of the phosphate compound is 0 parts by mass. Further, the processability of the flame-retardant resin composition can be further improved as compared with the case where the compounding ratio of the phosphate compound is 20 parts by mass or more.

Further, the mixing ratio of the phosphate compound to 100 parts by mass of the polyolefin resin (A) is preferably 15 parts by mass or less. In this case, the processability of the flame-retardant resin composition can be further improved as compared with the case where the compounding ratio of the phosphate compound to 100 parts by mass of the polyolefin resin (A) exceeds 15 parts by mass. The mixing ratio of the phosphate compound to 100 parts by mass of the polyolefin resin (A) is more preferably 10 parts by mass or less from the viewpoint of further improving the processability of the flame-retardant resin composition.

The mixing ratio of the phosphate compound to 100 parts by mass of the polyolefin resin (A) is preferably more than 1 part by mass. In this case, more excellent flame retardancy can be obtained in the flame-retardant resin composition as compared with the case where the compounding ratio of the phosphate compound to 100 parts by mass of the polyolefin resin (A) is 1 part by mass or less. Further, it is more preferable that the mixing ratio of the phosphate compound with respect to 100 parts by mass of the polyolefin resin (A) is more than 3 parts by mass. In this case, more excellent flame retardancy can be obtained in the flame-retardant resin composition as compared with the case where the compounding ratio of the phosphate compound to 100 parts by mass of the polyolefin resin (A) is 3 parts by mass or less. Further, it is particularly preferable that the blending ratio of the phosphate compound with respect to 100 parts by mass of the polyolefin resin (A) is more than 5 parts by mass. In this case, more excellent flame retardancy can be obtained in the flame-retardant resin composition as compared with the case where the compounding ratio of the phosphate compound to 100 parts by mass of the polyolefin resin (A) is 5 parts by mass or less.

(C) Organophosphorus compound The organic phosphorus compound (C) is represented by the above general formula (2) as described above.

X ¹ and X ² in the general formula (2) are represented by the general formula (3). X ¹ and X ² may be the same or different from each other.

AL in the above general formula (3) is a branched or linear aliphatic hydrocarbon group having 1 to 5 carbon atoms, and the aliphatic hydrocarbon group may have 1 or 2 carbon atoms. preferable. Further, Ar in the above general formula (3) is a phenyl group, a naphthyl group or an anthryl group which may have a substituent, and is bonded to an arbitrary carbon atom in AL. Of these, the phenyl group is preferable as Ar. Further, in the above general formula (3), n is an integer of 1 to 3, but n is preferably 1 or 2.

It is particularly preferable that X ¹ and X ² in the above general formula (2) are benzyl groups (phenylmethyl groups). In this case, better processability can be obtained in the flame-retardant resin composition as compared with the case where X ¹ and X ² in the general formula (2) are not benzyl groups.

As described above, the organic phosphorus compound (C) is preferably blended in a proportion of more than 0 parts by mass and less than 50 parts by mass with respect to 100 parts by mass of the polyolefin resin (A). In this case, the flame retardancy of the flame-retardant resin composition can be further improved as compared with the case where the compounding ratio of the organic phosphorus compound (C) to 100 parts by mass of the polyolefin resin (A) is 50 parts by mass or more. .. Further, the processability and flame retardancy of the flame-retardant resin composition can be further improved as compared with the case where the compounding ratio of the organic phosphorus compound (C) to 100 parts by mass of the polyolefin resin (A) is 0 parts by mass. can.

The blending ratio of the organic phosphorus compound (C) to 100 parts by mass of the polyolefin resin (A) is preferably 1 part by mass or more. In this case, the flame-retardant resin composition has better processability and flame retardancy than the case where the compounding ratio of the organic phosphorus compound (C) to 100 parts by mass of the polyolefin resin (A) is less than 1 part by mass. Is obtained. The blending ratio of the organic phosphorus compound (C) to 100 parts by mass of the polyolefin resin (A) shall be 2.5 parts by mass or more from the viewpoint of further improving the processability and flame retardancy of the flame-retardant resin composition. Is more preferably 5 parts by mass or more, further preferably 8 parts by mass or more, and particularly preferably 10 parts by mass or more.

The blending ratio of the organic phosphorus compound (C) to 100 parts by mass of the polyolefin resin (A) is preferably 40 parts by mass or less. In this case, the flame retardancy of the flame-retardant resin composition can be further improved as compared with the case where the compounding ratio of the organic phosphorus compound (C) to 100 parts by mass of the polyolefin resin (A) exceeds 40 parts by mass. The blending ratio of the organic phosphorus compound (C) to 100 parts by mass of the polyolefin resin (A) is preferably 30 parts by mass or less.

(D) Ester compound The ester compound (D) improves the processability of the flame-retardant resin composition and functions as a flame-retardant aid to improve the flame-retardant property of the flame-retardant resin composition. The ester compound (D) contains at least one selected from the group consisting of monoester compounds and diester compounds.

The ester compound (D) is an ester compound of a polyhydric alcohol and a fatty acid. Since the ester compound always has a hydroxyl group in the molecule, it can have a dehydrating ability and can function as a flame retardant aid.

The valence of the polyhydric alcohol may be divalent or higher, but is preferably 4 to 10 valences. Examples of the polyhydric alcohol include pentaerythritol, sorbitol, sorbitan, and condensed dimers or trimers thereof. These can be used alone or in combination of two or more.

Examples of fatty acids include saturated fatty acids and unsaturated fatty acids. Examples of the saturated fatty acid include palmitic acid, higher saturated fatty acid typified by stearic acid, and saturated fatty acid diacid typified by adipic acid. Examples of unsaturated fatty acids include unsaturated higher fatty acids typified by oleic acid and erucic acid. Here, "higher grade" means that the number of carbon atoms of the fatty acid is 6 or more. The number of carbon atoms of the higher fatty acid is preferably 12 to 18 because it is easily available in terms of price and quantity.

Specific examples of the ester compound (D) include pentaerythritol monostearate, sorbitan monostearate, glycerol monostearate, dipentaerythritol adipate, and dipentaerythritol adipate.

The melting point of the ester compound (D) is preferably 50 ° C. or higher and 180 ° C. or lower. In this case, the ester compound (D) is more sufficiently suppressed from bleeding out to the surface of the flame-retardant resin composition even in a high temperature environment, as compared with the case where the melting point of the ester compound (D) is less than 50 ° C. can. That is, the bloom of the flame-retardant resin composition can be suppressed more sufficiently. Further, as compared with the case where the melting point of the ester compound (D) exceeds 180 ° C., the ester compound (D) is easily melted and dispersed during processing of the flame-retardant resin composition, so that the flame-retardant resin composition can be used. The flame retardancy and appearance of the molded product obtained by processing can be further improved.

The melting point of the ester compound (D) is preferably 100 ° C. or lower. In this case, the processability of the flame-retardant resin composition can be further improved. The melting point of the ester compound (D) is more preferably 70 ° C. or lower.

As described above, the ester compound (D) is preferably blended in a proportion of more than 0 parts by mass and less than 5 parts by mass with respect to 100 parts by mass of the polyolefin resin (A). In this case, the ester compound (D) bleeds out to the surface of the flame-retardant resin composition as compared with the case where the blending ratio of the ester compound (D) with respect to 100 parts by mass of the polyolefin resin (A) is 5 parts by mass or more. It can be suppressed more sufficiently. That is, the bloom in the flame-retardant resin composition can be more sufficiently suppressed as compared with the case where the blending ratio of the ester compound (D) with respect to 100 parts by mass of the polyolefin resin (A) is 5 parts by mass or more. Further, the flame retardancy and processability of the flame-retardant resin composition can be further improved as compared with the case where the blending ratio of the ester compound (D) with respect to 100 parts by mass of the polyolefin resin (A) is 0 parts by mass. ..

The blending ratio of the ester compound (D) with respect to 100 parts by mass of the polyolefin resin (A) is more preferably 0.5 parts by mass or more. In this case, the processability and flame retardancy of the flame-retardant resin composition are further improved as compared with the case where the blending ratio of the ester compound (D) with respect to 100 parts by mass of the polyolefin resin (A) is less than 0.5 parts by mass. Can be made to.

It is even more preferable that the blending ratio of the ester compound (D) with respect to 100 parts by mass of the polyolefin resin (A) is 1 part by mass or more. In this case, the processability and flame retardancy of the flame-retardant resin composition are further improved as compared with the case where the blending ratio of the ester compound (D) with respect to 100 parts by mass of the polyolefin resin (A) is less than 1 part by mass. Can be done.

It is particularly preferable that the blending ratio of the ester compound (D) with respect to 100 parts by mass of the polyolefin resin (A) is 2 parts by mass or more. In this case, the processability of the flame-retardant resin composition can be further improved as compared with the case where the blending ratio of the ester compound (D) with respect to 100 parts by mass of the polyolefin resin (A) is less than 2 parts by mass.

The flame-retardant resin composition of the present invention comprises the above-mentioned polyolefin resin (A), phosphate compound (B), organic phosphorus compound (C) and ester compound (D), as well as a fluorine-based drip inhibitor (E). May include. Hereinafter, the fluorine-based drip inhibitor (E) will be described in detail.

(E) Fluorine-based drip inhibitor The fluorine-based drip inhibitor (E) contains a fluorine-containing fluorine-containing compound and is capable of preventing resin dripping or dripping (drip) of molten resin during combustion. Any such fluorine-containing compound may be used, and examples thereof include fluorine-based resins such as polytetrafluoroethylene (hereinafter referred to as “PTFE”), polyvinylidene fluoride, and polyhexafluoropropylene. The fluorine-containing compound may be unmodified or modified, but is preferably modified. In this case, as compared with the case where the fluorine-containing compound is not modified, the fluorine-containing compound is efficiently fibrillated, and the dispersibility in the flame-retardant resin composition is further improved. As a result, the drip prevention function of the fluorine-based drip inhibitor (E) can be further improved. Further, since the melt tension of the flame-retardant resin composition becomes larger, the processability and moldability of the flame-retardant resin composition can be further improved. Examples of the modified fluorine-containing compound include acid-modified polytetrafluoroethylene.

The fluorine-based drip inhibitor (E) is preferably blended in a proportion of more than 0 parts by mass and less than 10 parts by mass with respect to 100 parts by mass of the polyolefin resin (A). In this case, unlike the case where the compounding ratio of the fluorine-based drip inhibitor (E) to 100 parts by mass of the polyolefin resin (A) is 0 parts by mass, it is possible to prevent drip and prevent the spread of fire due to drip. The flame retardancy of the flame retardant resin composition can be improved. Further, the melt viscosity of the flame-retardant resin composition becomes too high as compared with the case where the compounding ratio of the fluorine-based drip inhibitor (E) to 100 parts by mass of the polyolefin resin (A) is 10 parts by mass or more. It is sufficiently suppressed and the processability of the flame-retardant resin composition is further improved.

The mixing ratio of the fluorine-based drip inhibitor (E) to 100 parts by mass of the polyolefin resin (A) is more preferably 0.5 parts by mass or more. In this case, the flame-retardant resin composition has better flame retardancy than the case where the compounding ratio of the fluorine-based drip inhibitor (E) to 100 parts by mass of the polyolefin resin (A) is less than 0.5 parts by mass. Is obtained. Further, the mixing ratio of the fluorine-based drip inhibitor (E) to 100 parts by mass of the polyolefin resin (A) is more preferably 2 parts by mass or more.

However, the mixing ratio of the fluorine-based drip inhibitor (E) to 100 parts by mass of the polyolefin resin (A) is more preferably 5 parts by mass or less. In this case, the melt viscosity of the flame-retardant resin composition becomes too high as compared with the case where the compounding ratio of the fluorine-based drip inhibitor (E) to 100 parts by mass of the polyolefin resin (A) exceeds 5 parts by mass. It is sufficiently suppressed and the processability of the flame-retardant resin composition is further improved.

The mixing ratio of the fluorine-based drip inhibitor (E) to 100 parts by mass of the polyolefin resin (A) is more preferably 3 parts by mass or less from the viewpoint of further improving the processability of the flame-retardant resin composition. ..

The flame-retardant resin composition contains an antioxidant, a heat deterioration inhibitor, an ultraviolet absorber, a light-resistant agent, an anti-fog agent, a colorant, a filler, and a cross-linking agent as long as the flame retardancy and processability are not affected. Agents, foaming agents, heat radiating agents and the like may be further contained as required.

The flame-retardant resin composition comprises a polyolefin resin (A), a phosphate compound (B), an organic phosphoric acid compound (C), an ester compound (D) and, if necessary, a fluorine-based drip inhibitor (E). It can be obtained by kneading. Kneading involves the heat required to melt the polyolefin resin (A), the phosphate compound (B), the organic phosphoric acid compound (C), the ester compound (D), and, if necessary, a fluorine-based drip inhibitor ( It can be carried out using a kneader capable of applying and processing the shear required to disperse E). As the kneader, for example, an open roll, a twin-screw extruder, a Banbury mixer, a pressurized kneader, or the like can be used.

<Molded body>
Next, the molded product of the present invention will be described.

The molded product of the present invention contains the above-mentioned flame-retardant resin composition. Since this molded product contains a flame-retardant resin composition having excellent flame retardancy and capable of improving processability, various uses requiring both excellent flame retardancy and good appearance are required. Applicable to. Such applications include, for example, TV back panels, capacitor cases, insulating films inside keyboards, panels inside heaters, flame-retardant sheets for buildings, dashboards for automobiles, packaging materials, housings for home appliances, and the like. Be done.

Examples of the shape of the molded body of the present invention include a sheet shape and a plate shape, and the shape of the molded body is preferably a sheet shape.

The molded body can be obtained by molding the flame-retardant resin composition by using, for example, an extrusion molding method, an injection molding method, a vacuum forming method, a press molding method, or the like. The molded body may be composed of the flame-retardant resin composition alone, or may be composed of a flame-retardant resin composition and a reinforcing material such as glass cloth or paper in combination depending on the application.

<Cable>
Next, the cable of the present invention will be described with reference to FIGS. 1 and 2. FIG. 1 is a partial side view showing an embodiment of the cable according to the present invention. FIG. 2 is a cross-sectional view taken along the line II-II of FIG.

As shown in FIGS. 1 and 2, the cable 10 includes an insulated wire 4 and a tubular covering layer 3 that covers the insulated wire 4. The insulated wire 4 has a conductor 1 and a tubular insulating layer 2 that covers the conductor 1.

Here, the tubular insulating layer 2 and the coating layer 3 are composed of the above-mentioned flame-retardant resin composition, and the above-mentioned flame-retardant resin composition has excellent flame retardancy and improves workability. be able to. Therefore, the insulating layer 2 and the coating layer 3 made of the flame-retardant resin composition can have excellent flame retardancy and a good appearance. Therefore, the cable 10 can have excellent flame retardancy and good appearance.

(conductor)
The conductor 1 may be composed of only one wire, or may be a bundle of a plurality of wires. Further, the conductor 1 is not particularly limited in terms of the conductor diameter, the material of the conductor, and the like, and can be appropriately determined depending on the intended use. Examples of the material of the conductor 1 include a metal conductor and a non-metal conductor. As the metal conductor, for example, copper, aluminum, or an alloy containing them is preferable. As the non-metal conductor, a conductive substance such as a carbon material can be used. When the conductor 1 is made of a metal conductor, the cable 10 is a metal cable.

(Coating layer)
The coating layer 3 is a so-called sheath, which protects the insulating layer 2 from physical or chemical damage.

<Optical fiber cable>
Next, the optical fiber cable of the present invention will be described with reference to FIG. FIG. 3 is a cross-sectional view showing an embodiment of the optical fiber cable of the present invention.

As shown in FIG. 3, the optical fiber cable 20 includes two tension members 22 and 23, an optical fiber 24, and a covering portion 25 that covers them. Here, the optical fiber 24 is provided so as to penetrate the covering portion 25. Here, the covering portion 25 is composed of an insulator that covers the optical fiber 24, and the insulator is composed of a flame-retardant resin composition that constitutes the insulating layer 2 and the coating layer 3 of the insulating wire 4 in the above embodiment. Will be done.

Here, the covering portion 25 is composed of the above-mentioned flame-retardant resin composition, and the above-mentioned flame-retardant resin composition has excellent flame retardancy and can improve processability. Therefore, the covering portion 25 made of the flame-retardant resin composition can have excellent flame retardancy and a good appearance. Therefore, the optical fiber cable 20 can have excellent flame retardancy and a good appearance.

The present invention is not limited to the above embodiment. For example, in the above embodiment, the cable 10 having one insulated wire 4 is used as the cable, but the cable of the present invention is not limited to the cable having one insulated wire 4, and the covering layer 3 is not limited to the cable. A cable having two or more insulated wires 4 inside may be used. Further, a resin portion made of polypropylene or the like may be provided between the covering layer 3 and the insulating electric wire 4.

Further, in the above embodiment, the insulating layer 2 and the covering layer 3 of the insulating electric wire 4 are made of the above-mentioned flame-retardant resin composition, but the insulating layer 2 is made of a normal insulating resin, and only the covering layer 3 is formed. , The above-mentioned flame-retardant resin composition may be composed.

In the optical fiber cable 20, the covering portion 25 is made of an insulator, but the covering portion 25 may further have a covering body that covers the insulator. Here, the covering body may or may not be composed of the flame-retardant resin composition constituting the insulating layer 2 and the covering layer 3 of the insulating electric wire 4 in the above embodiment, but the above-mentioned embodiment. In the form, it is preferably composed of a flame-retardant resin composition constituting the insulating layer 2 and the covering layer 3 of the insulated wire 4.

Further, in the above embodiment, the optical fiber cable 20 has tension members 22 and 23, but in the optical fiber cable of the present invention, the tension member is not always necessary and can be omitted.

Hereinafter, the contents of the present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited to the following Examples.

(Examples 1 to 52 and Comparative Examples 1 to 8)
Tables 1 to 11 show the polyolefin resin (A), phosphate compound (B), organophosphorus compound (C), ester compound (D), non-ester compound (D *), and fluorine-based drip inhibitor (E). The mixture was blended in the indicated blending amount and kneaded at 180 ° C. using an open roll to obtain a flame-retardant resin composition. In Tables 1 to 11, the unit of the blending amount of each blending component is a mass part.

Specifically, the polyolefin resin (A), phosphate compound (B), organophosphorus compound (C), ester compound (D), non-ester compound (D *) and fluorine-based drip inhibitor (E) are specifically used. The following were used.

(A) Polyolefin resin (A1) Block copolymer of ethylene and propylene (b-EP-1, manufactured by Prime Polymer Co., Ltd., MFR = 3.5 g / 10 min)
(A2) Block copolymer of ethylene and propylene (b-EP-2, manufactured by Prime Polymer Co., Ltd., MFR = 30 g / 10 min)
(A3) Homo-polypropylene (h-PP, manufactured by Prime Polymer Co., Ltd.)
(A4) High-density polyethylene (HDPE, manufactured by Japan Polyethylene Corporation)
(A5) Linear low density polyethylene (LLDPE, manufactured by Sumitomo Chemical Co., Ltd.)
(A6) Modified polypropylene resin (PP elastomer, manufactured by Mitsui Chemicals, Inc.)
(A7) Hydrogenated styrene-butadiene rubber (hydrogenated SBR, manufactured by JSR Corporation)
(A8) Olefin Crystal Ethylene Butylene Olefin Block Copolymer (CEBC, manufactured by JSR Corporation)

(B) Phosphate compound (B1) Flame-retardant agent composed of piperazine pyrophosphate and melamine pyrophosphate (B2) Flame-retardant agent composed of piperazine pyrophosphate, melamine pyrophosphate and zinc oxide (B3) Melamine pyrophosphate Flame-retardant agent composed of (B4) Flame-retardant agent composed of melamine orthophosphate (B5) Flame-retardant agent composed of melamine polyphosphate Melamine polyphosphate is a salt of polyphosphoric acid and melamine, and polyphosphoric acid is a general formula. (1) Phosphoric acid having m of 3 or more in (1).
(B6) Flame Retardant Composed of Ammonium Polyphosphate Ammonium polyphosphate is a salt of polyphosphoric acid and ammonia, and polyphosphoric acid is a phosphoric acid having m of 3 or more in the general formula (1).
(B7) Flame-retardant agent composed of guanylurea phosphate Phosphorus guanylurea phosphate is a salt of phosphoric acid and guanylurea, and phosphoric acid is phosphoric acid in which m is 1 in the general formula (1).
(B8) The flame retardant polyphosphoric acid melamine, melam, and melem composed of polyphosphoric acid melamine, melam, and melem is a salt (double salt) of polyphosphoric acid and melamine, melam, and melem, and polyphosphoric acid is a general formula. (1) Polyphosphoric acid in which m in (1) is 3 or more.

(C) Organophosphorus compound (C1) Phosphonate-pentaerythritol ester flame retardant (flame retardant in which X ¹ and X ² are benzyl groups (phenylmethyl groups) in the general formula (2))
(C2) Phosphonate-pentaerythritol ester flame retardant (flame retardant in which X ¹ and X ² are phenylethyl groups in the general formula (2))
(C3) Phosphonate-pentaerythritol ester flame retardant (flame retardant in which X ¹ and X ² are phenylpropyl groups in the general formula (2))
(C4) Phosphonate-pentaerythritol ester flame retardant (flame retardant in which X ¹ and X ² are phenylbutyl groups in the general formula (2))
(C5) Phosphonate-pentaerythritol ester flame retardant (flame retardant in which X ¹ and X ² are phenylpentyl groups in the general formula (2))
(C6) Phosphonate-pentaerythritol ester flame retardant (flame retardant in which X ¹ and X ² are phenylisopropyl groups in the general formula (2))
(C7) Phosphonate-pentaerythritol ester flame retardant (flame retardant in which X ¹ and X ² are naphthylmethyl groups in the general formula (2))
(C8) Phosphonate-pentaerythritol ester flame retardant (flame retardant in which X ¹ and X ² are anthrylmethyl groups in the general formula (2))
(C9) Phosphonate-pentaerythritol ester flame retardant (in the general formula (2), X ¹ is a phenylmethyl group and X ² is a naphthylmethyl group)

(D) Ester compound (D1) Pentaerythritol monostearate (melting point: 52 ° C.)
(D2) Sorbitan monostearate (melting point: 51.5 ° C)
(D3) Glycerol monostearate (melting point: 64 ° C.)
(D4) Dipentaerythritol adipate (melting point: 180 ° C)
(D5) Mixture of dipentaerythritol adipate and pentaerythritol adipate (melting point: 180 ° C.)

(D *) Non-ester compound (D1 *) Calcium stearate (D2 *) Stearic acid amide (D3 *) Pentaerythritol (D4 *) Pentaerythritol Tetrapalmitate

(E) Fluorine-based drip inhibitor (E1) Acid-modified polytetrafluoroethylene particles (modified PTFE)
(E2) Unmodified polytetrafluoroethylene particles (non-denatured PTFE)

The flame-retardant resin compositions of Examples 1 to 52 and Comparative Examples 1 to 8 obtained as described above are evaluated for flame retardancy, processability, bloom suppressing effect, and specific density as follows. rice field.

<Flame retardant>
A UL94 vertical combustion test (V-0 test) was performed on a 4.0 mm thick sheet obtained by hot-pressing the flame-retardant resin compositions of Examples 1 to 52 and Comparative Examples 1 to 8 at 180 ° C. The flame retardancy was evaluated according to the grade at that time. The results are shown in Tables 1-11. In Tables 1 to 11, the flame-retardant pass / fail criteria are as follows.

(Pass / Fail Criteria)
Pass ... V-0, V-1 or V-2
Fail ... burned down

For the examples of Examples 1 to 52 having a grade of V-0, a UL94 5V test was further performed in order to investigate the difference in flame retardancy between these examples. The UL94 5V test consists of a strip test and a flat plate test. In the strip test, a strip-shaped test piece (length 125 mm x width 13 mm x thickness 2 mm) is used, and in the flat plate test, a flat plate is used. A test piece (length 150 mm × width 150 mm × thickness 2 mm) was used.

Then, the examples that passed both the strip test and the flat plate test were judged as "5VA", and the examples that passed only the strip test and failed the flat plate test were judged as "5VB". However, if the strip test and the flat plate test were not passed, it was judged as "burned down". The results are shown in Tables 1-11. Among the examples in which the grade is V-0, the example determined to be "5VA" has higher flame retardancy than the example determined to be "5VB", and is determined to be "5VB". The examples will have higher flame retardancy than the examples determined to be "burned down". Further, in Tables 1 to 11, "-" means that the UL94 5V test has not been performed.

<Workability>
The flame-retardant resin compositions of Examples 1 to 52 and Comparative Examples 1 to 8 were measured for MFR under the conditions of a temperature of 230 ° C. and a load of 2.16 kgf according to JIS K7210. Then, from this MFR value and the MFR value (MFR value of the reference comparison example) of the reference comparative example (reference comparison example), the MFR increase rate is calculated using the following formula, and this MFR increase rate is processed. It was used as an index of sex. The results are shown in Tables 1-11.

MFR increase rate (%)
= 100 × (MFR value-MFR value of standard comparison example) / MFR value of standard comparison example

Comparative Example 4 was used as the reference comparative example. The reason why Comparative Example 4 is used as a reference comparative example is that the blending amount of the organic phosphorus compound is 0 parts by mass, which corresponds to Patent Document 1. In Tables 1 to 11, the unit of MFR is g / 10 min. The acceptance criteria for workability are as follows.

(Pass criteria) MFR increase rate is 10% or more

<Bloom suppression effect>
The 1.0 mm-thick sheets obtained by press-molding the flame-retardant resin compositions of Examples 1 to 52 and Comparative Examples 1 to 8 at 190 ° C. were oily and greasy, sticky, and powdery. I visually checked if there was any. Then, when oily and fat-like shine, stickiness, and powdery roughness were observed, it was determined that Bloom was "present", and when it was not observed, it was determined to be "absent". The results are shown in Tables 1-11.

<Relative density>
The flame-retardant resin compositions of Examples 1 to 52 and Comparative Examples 1 to 8 were measured for their specific densities using an electronic hydrometer (manufactured by Alpha Mirage). The results are shown in Tables 1-11.

From the results shown in Tables 1 to 11, it was found that Examples 1 to 52 satisfy the acceptance criteria in terms of flame retardancy and processability. On the other hand, it was found that Comparative Examples 1 to 8 did not satisfy the acceptance criteria in at least one of flame retardancy and processability.

From the above, it was confirmed that the flame-retardant resin composition of the present invention has excellent flame-retardant property and can improve processability.

1 ... Conductor 2 ... Insulation layer 3 ... Covering layer 4 ... Insulated electric wire 10 ... Cable 20 ... Optical fiber cable 24 ... Optical fiber 25 ... Covering part (insulator)

Claims (15)

Polyolefin resin (A) and
Phosphate compound (B) and
Organophosphorus compound (C) and
Including the ester compound (D)
The phosphate compound (B) is blended in a proportion of more than 0 parts by mass and less than 20 parts by mass with respect to 100 parts by mass of the polyolefin resin (A).
The phosphate compound (B) contains a salt of phosphoric acid represented by the following general formula (1) and an amine compound having at least one amino group in the molecule.
The organic phosphorus compound (C) is represented by the following general formula (2).
The ester compound (D) contains at least one selected from the group consisting of monoester compounds and diester compounds.
A flame-retardant resin composition in which the monoester compound and the diester compound have a hydroxyl group .

(In the above general formula (1), m represents an integer from 1 to 100.)

(In the above general formula (2), X ¹ and X ² are the same or different, and are represented by the following general formula (3).)

(In the above general formula (3), AL is a branched or linear aliphatic hydrocarbon group having 1 to 5 carbon atoms, and Ar is a phenyl group, a naphthyl group or anthryl which may have a substituent. It is a group and is bonded to any carbon atom in AL. N indicates an integer of 1 to 3). The flame-retardant resin composition according to claim 1, wherein the organic phosphorus compound (C) is blended in a proportion of more than 0 parts by mass and less than 50 parts by mass with respect to 100 parts by mass of the polyolefin resin (A). .. The flame-retardant resin composition according to claim 1 or 2, wherein the ester compound (D) is blended in a proportion of more than 0 parts by mass and less than 5 parts by mass with respect to 100 parts by mass of the polyolefin resin (A). thing. The flame-retardant resin composition according to any one of claims 1 to 3, wherein X ¹ and X ² in the general formula (2) are benzyl groups. In the general formula (1), m is 1 to 2, and the m is 1 to 2.
One of claims 1 to 4, wherein the amine compound is composed of an amine compound containing a triazine ring, a mixture of an amine compound containing a piperazine ring and an amine compound containing a triazine ring, ammonia, or guanidyl urea. The flame-retardant resin composition according to. The flame-retardant resin composition according to any one of claims 1 to 5, wherein the amine compound is composed of a mixture of an amine compound containing a piperazine ring and an amine compound containing a triazine ring. The flame-retardant resin composition according to any one of claims 1 to 6, wherein the ester compound (D) has a melting point of 50 ° C. or higher and 180 ° C. or lower. The one according to any one of claims 1 to 7, wherein the fluorine-based drip inhibitor (E) is further blended in a proportion of more than 0 parts by mass and less than 10 parts by mass with respect to 100 parts by mass of the polyolefin resin (A). Flame-retardant resin composition. The flame-retardant resin composition according to any one of claims 1 to 8, wherein the polyolefin resin (A) contains a polypropylene resin. The flame-retardant resin composition according to any one of claims 1 to 9, wherein the polyolefin resin (A) contains an elastomer. The flame-retardant resin composition according to claim 10, wherein the content of the elastomer in the polyolefin resin (A) is 60% by mass or less. A molded product containing the flame-retardant resin composition according to any one of claims 1 to 11. With the conductor
With an insulating layer covering the conductor,
An insulated wire in which the insulating layer is made of the flame-retardant resin composition according to any one of claims 1 to 11. A conductor and an insulated wire having an insulating layer covering the conductor,
It is provided with a coating layer that covers the insulated wire.
A cable in which at least one of the insulating layer and the coating layer is made of the flame-retardant resin composition according to any one of claims 1 to 11. With optical fiber
It is provided with a covering portion for covering the optical fiber.
The covering portion has an insulator that covers the optical fiber, and the covering portion has an insulator that covers the optical fiber.
An optical fiber cable in which the insulator is made of the flame-retardant resin composition according to any one of claims 1 to 11.

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