JP7036403B2 - How to make cooking sake using mirin lees - Google Patents

How to make cooking sake using mirin lees Download PDF

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JP7036403B2
JP7036403B2 JP2018132463A JP2018132463A JP7036403B2 JP 7036403 B2 JP7036403 B2 JP 7036403B2 JP 2018132463 A JP2018132463 A JP 2018132463A JP 2018132463 A JP2018132463 A JP 2018132463A JP 7036403 B2 JP7036403 B2 JP 7036403B2
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幹夫 山田
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甘強酒造株式会社
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本発明は、醤油と同様に調理に使用することができるみりん粕使用調理酒の製造方法に関するものである。 The present invention relates to a method for producing a cooking liquor using mirin lees, which can be used for cooking in the same manner as soy sauce.

一般的な醤油は、大豆と小麦の混合物に麹菌を作用させた麹に塩水を加え、6か月程度発酵させて製造されている。麹菌由来の酵素により、大豆蛋白及び小麦蛋白がアミノ酸に分解され、うまみを感じさせる。しかし食塩の含有率が分析値で15~20%と高いため、塩分を制限されている病人の食事には使用量が制限されるという問題がある。また原料に大豆や小麦、米などを使用するため、うまみの多い醤油は安価に提供できないという問題がある。 General soy sauce is produced by adding salt water to a mixture of soybeans and wheat and letting it act on it, and fermenting it for about 6 months. Soy protein and wheat protein are decomposed into amino acids by enzymes derived from Jiuqu, which makes you feel delicious. However, since the salt content is as high as 15 to 20% in the analysis value, there is a problem that the amount used is limited in the diet of the sick person whose salt content is restricted. In addition, since soybeans, wheat, rice, etc. are used as raw materials, there is a problem that soy sauce with a lot of umami cannot be provided at a low price.

同じく麹菌を利用した調味料として、古くからみりんが知られている。みりんはもち米に麹菌を作用させた米麹を発酵させて製造されるもので、約40%~50%の糖分と、約14%程度のアルコール分を含有している。みりんの製造工程において発生するみりん粕はうまみ成分であるアミノ酸を含有しているため、これまで奈良漬などに利用されてきた。しかし最近では食生活の変化により漬物の需要が減少し、みりん粕は家畜の飼料としたり産業廃棄物として処理せざるを得ない状況にある。 Mirin has long been known as a seasoning that also uses Jiuqu. Mirin is produced by fermenting rice cake made by reacting glutinous rice with Jiuqu, and contains about 40% to 50% sugar and about 14% alcohol. Mirin lees generated in the manufacturing process of mirin contains amino acids, which are umami ingredients, and have been used for Narazuke and the like. However, recently, the demand for pickles has decreased due to changes in eating habits, and mirin lees has no choice but to be treated as livestock feed or industrial waste.

そこで特許文献1には、みりん粕を原料として調味料を製造する技術が提案されている。この特許文献1の調味料はみりん粕を発酵させ、アルコール濃度を4%未満、食塩濃度を11%以上としたものである。この調味料は小麦や大豆を原料としないため食物アレルギーがある人にも使用可能である。しかし塩分濃度が高いため、前記した醤油と同様の問題が残されている。 Therefore, Patent Document 1 proposes a technique for producing a seasoning using mirin lees as a raw material. The seasoning of Patent Document 1 is made by fermenting mirin lees and having an alcohol concentration of less than 4% and a salt concentration of 11% or more. Since this seasoning is not made from wheat or soybeans, it can be used by people with food allergies. However, due to the high salt concentration, the same problems as the above-mentioned soy sauce remain.

特開2017-85992号公報JP-A-2017-85992

従って本発明の目的は上記した従来技術の問題点を解決し、これまで飼料や廃棄物として処理せざるを得なかったみりん粕を有効利用し、うまみ成分を多く含有し、しかも塩分濃度が低いみりん粕使用調理酒の製造方法を提供することである。 Therefore, an object of the present invention is to solve the above-mentioned problems of the prior art, effectively utilize mirin lees which has had to be treated as feed or waste, contain a large amount of umami component, and have a low salt concentration. It is to provide a method for producing a cooking liquor using mirin lees.

上記の課題を解決するためになされた本発明のみりん粕使用調理酒の製造方法は、大豆または脱脂加工大豆と、みりん粕とを原料とし、これらの原料に麹菌を作用させて得られた麹に他の原料である酒精液を混合し、発酵させたもろみを圧搾して調理酒を得ることを特徴とするものである。 The method for producing a cooked liquor using mirin lees of the present invention, which has been made to solve the above problems, uses soybeans or defatted soybeans and mirin lees as raw materials, and the koji obtained by reacting these raw materials with aspergillus. It is characterized in that liquor semen, which is another raw material, is mixed with liquor and fermented mash is squeezed to obtain cooked liquor.

なお請求項2に記載したように、前記酒精液または酒精液と麹との混合物に塩分を添加し、塩分を含有する調理酒を得ることができる。 As described in claim 2, a cooking liquor containing salt can be obtained by adding salt to the liquor semen or a mixture of liquor semen and jiuqu.

また請求項3に記載したように、大豆または脱脂加工大豆の質量を、みりん粕の質量の1~3倍とすることが好ましい。 Further, as described in claim 3, it is preferable that the mass of soybean or defatted soybean is 1 to 3 times the mass of mirin lees.

さらに請求項4に記載したように、得られた調理酒のフォルモール窒素が0.8%以上であることが好ましい。 Further, as described in claim 4, the formol nitrogen of the obtained cooking liquor is preferably 0.8% or more.

本発明のみりん粕使用調理酒の製造方法によれば、現状では飼料や廃棄物として処理せざるを得なかったみりん粕を原料の一部として有効活用し、うまみ成分が多く醤油の代替品として使用することができる調理酒を安価に提供することができる。この調理酒は塩分濃度が低いため、塩分を制限されている人の料理にも使用することができる。なお、塩分はゼロとすることができるが、酒税法の適用を避けるために2%程度の少量の塩分を含有させることも可能である。この場合にも塩分濃度は醤油よりもはるかに低くなる。 According to the method for producing cooking liquor using mirin lees of the present invention, mirin lees, which had to be treated as feed or waste at present, is effectively utilized as a part of the raw material, and has a lot of delicious components as a substitute for soy sauce. It is possible to provide a cooking liquor that can be used at a low price. Since this cooking liquor has a low salt concentration, it can also be used for cooking by people with limited salt content. Although the salt content can be set to zero, it is also possible to contain a small amount of salt content of about 2% in order to avoid the application of the Liquor Tax Law. Again, the salinity is much lower than soy sauce.

本発明の第1の実施形態を示す工程説明図である。It is a process explanatory drawing which shows the 1st Embodiment of this invention. 本発明の第2の実施形態を示す工程説明図である。It is a process explanatory drawing which shows the 2nd Embodiment of this invention.

以下に本発明の実施形態を説明する。第1の実施形態は請求項1に対応し、第2の実施形態は請求項2に対応するものである。 An embodiment of the present invention will be described below. The first embodiment corresponds to claim 1, and the second embodiment corresponds to claim 2.

何れの実施形態においても、本発明で使用する原料は、大豆または脱脂加工大豆と、みりん粕と酒精液である。脱脂加工大豆は油分が抽出された後の大豆であるため、大豆よりも安価に入手することができ、しかも油分以外の大豆蛋白はそのまま残存しているため、大豆を使用した場合に比較して得られた調理酒のうまみが減少することはない。 In any of the embodiments, the raw materials used in the present invention are soybean or defatted soybean, mirin lees and liquor semen. Since defatted soybeans are soybeans after oil has been extracted, they can be obtained at a lower cost than soybeans, and soybean proteins other than oils remain as they are, so compared to the case of using soybeans. The taste of the resulting cooking liquor does not decrease.

図1に示すように、大豆または脱脂加工大豆を10分から1時間程度加圧蒸煮したうえ、常温付近まで冷却する。同様にみりん粕を10分程度加圧蒸煮したうえ、常温付近まで冷却し、両者を混合する。この混合物に麹菌を種付けし、例えば48時間程度麹菌を増殖させ、麹を得る。みりん粕はもち米を加圧蒸煮して発酵させたものであるから、大豆または脱脂加工大豆よりも、加圧蒸煮時間を短縮することができる。 As shown in FIG. 1, soybeans or defatted soybeans are steamed under pressure for about 10 minutes to 1 hour, and then cooled to around room temperature. Similarly, mirin lees is steamed under pressure for about 10 minutes, cooled to around room temperature, and both are mixed. Jiuqu is seeded in this mixture, and the Jiuqu is grown for about 48 hours, for example, to obtain Jiuqu. Since mirin lees is fermented by pressure-steaming glutinous rice, the pressure-steaming time can be shortened as compared with soybeans or defatted soybeans.

このように、大豆または脱脂加工大豆とみりん粕との混合物に麹菌を作用させる方法のほかに、大豆または脱脂加工大豆に麹菌を作用させた麹と、みりん粕に麹菌を作用させた麹とを混合することもできる。 In this way, in addition to the method of allowing aspergillus to act on a mixture of soybeans or defatted soybeans and mirin lees, assortment of soybeans or defatted soybeans with aspergillus and mirin lees with aspergillus may be used. It can also be mixed.

何れの場合にも、みりん粕よりも大豆または脱脂加工大豆の比率を大きくした方が大豆蛋白由来のアミノ酸が増加するため、うまみが出る。このため、大豆または脱脂加工大豆の質量を、みりん粕の質量の1~3倍とすることが好ましい。大豆または脱脂加工大豆の比率がこれよりも小さくなるとうまみが少なくなり、逆に大豆または脱脂加工大豆の比率をこの範囲よりも大きくすると相対的にみりん粕の使用量が減少し、みりん粕の有効利用という本発明の目的が達成できなくなるからである。 In either case, increasing the proportion of soybeans or defatted soybeans rather than mirin lees increases the amount of amino acids derived from soybean protein, resulting in umami. Therefore, it is preferable that the mass of soybean or defatted soybean is 1 to 3 times the mass of mirin lees. If the ratio of soybeans or defatted soybeans is smaller than this, the taste will be less, and conversely, if the ratio of soybeans or defatted soybeans is larger than this range, the amount of mirin lees used will be relatively reduced, and mirin lees will be effective. This is because the object of the present invention of utilization cannot be achieved.

得られた麹は、酒精液と混合される。酒精液としては、例えばアルコール濃度が20%以上のものを用いることができる。これによって、麹菌の分解、酵素作用を阻害する雑菌の繁殖を防止することができる。麹に酒精液を加えて混合するが、この際に十分に混錬して均一化するとともに、麹を細かく破砕しておくことが、次工程の発酵に有利である。なお酒精液の量は、例えば麹の質量の2倍程度とすればよいが、その比率は適宜調整すればよい。 The obtained Jiuqu is mixed with sake semen. As the liquor semen, for example, one having an alcohol concentration of 20% or more can be used. This makes it possible to prevent the decomposition of Jiuqu and the propagation of various germs that inhibit the enzymatic action. Sake semen is added to the jiuqu and mixed. At this time, it is advantageous to sufficiently knead and homogenize the jiuqu and to crush the jiuqu into small pieces for fermentation in the next step. The amount of liquor semen may be, for example, about twice the mass of the jiuqu, but the ratio may be appropriately adjusted.

麹と酒精液との混合物は、常温で適宜の期間にわたりタンク内で発酵させる。この期間は季節にもよるが、例えば一か月程度である。この期間中に麹菌由来の酵素により大豆蛋白がアミノ酸に分解され発酵液中に溶出する。またみりん粕中に残存していた蛋白質も同様に分解されるとともに、残存していたアミノ酸が発酵液中に溶出する。このようにして得られたもろみを圧搾して固形分を分離し、発酵液を抽出して調理酒を得る。 The mixture of Jiuqu and sake semen is fermented in a tank at room temperature for an appropriate period of time. This period depends on the season, but is, for example, about one month. During this period, soybean protein is decomposed into amino acids by an enzyme derived from Jiuqu and eluted in the fermented liquor. In addition, the protein remaining in the mirin lees is also decomposed in the same manner, and the remaining amino acids are eluted in the fermentation broth. The mash thus obtained is squeezed to separate the solid content, and the fermented liquid is extracted to obtain cooking liquor.

例えば、脱脂加工大豆200gr、みりん粕200gr、20%酒精液800mLを原料とした場合、アルコール分が約15%の調理酒600mLを製造することができる。得られた調理酒のフォルモール窒素は0.8%以上であり、濃口醤油と同様の多くのアミノ酸を含有している。 For example, when 200 ml of degreased soybean, 200 gr of mirin lees, and 800 mL of 20% liquor semen are used as raw materials, 600 mL of cooking liquor having an alcohol content of about 15% can be produced. The formol nitrogen of the obtained cooking liquor is 0.8% or more, and contains many amino acids similar to those of dark soy sauce.

フォルモール窒素の測定は全アミノ酸の定量法の一つであり、清酒のアミノ酸度の測定にも採用されている。アミノ酸がホルマリンと反応して酸としての性質をもつ化合物に変ることを利用したもので、中和後の清酒に中性ホルマリンを加え、これをアルカリで滴定してアミノ酸量を測定する方法である。日本醤油研究所のデータによれば、特選、本醸造の濃口醤油のフォルモール窒素は0.87%~0・90%程度、超特選、本醸造の濃口醤油のフォルモール窒素は1.05%程度、淡口醤油では0.62%~0・70%、特選、淡口醤油では0・85%程度である。本発明により製造された調理酒は後記する実施例に示すように0.800%と0・938%であり、特選醤油と同等のアミノ酸を含有していることが確認されている。 The measurement of formol nitrogen is one of the methods for quantifying all amino acids, and is also used for measuring the amino acid content of sake. It utilizes the fact that amino acids react with formalin to change into compounds with acid properties. It is a method of adding neutral formalin to neutralized sake and titrating it with an alkali to measure the amount of amino acids. .. According to the data of the Japan Soy Sauce Research Institute, the formol nitrogen of the specially selected, brewed dark soy sauce is about 0.87% to 0.90%, and the super-specialized, brewed concentrated soy sauce formal nitrogen is 1.05%. The degree is 0.62% to 0.70% for light soy sauce, and about 0.85% for specialty and light soy sauce. The cooking liquor produced by the present invention is 0.800% and 0.938% as shown in Examples described later, and it is confirmed that the cooking liquor contains amino acids equivalent to those of the special soy sauce.

上記した第1の実施形態の方法で製造された調理酒は約15%のアルコール分を含有し、このアルコール分が防腐剤として機能するため、室温において保存しても変質することはない。また醤油とは異なり塩分を含有しないので、塩分を制限されている人の料理にも使用することができる。ところがこの調理酒はリキュールとみなされ、酒税法の適用を受けて酒税が掛かることとなる。 The cooking liquor produced by the method of the first embodiment described above contains about 15% alcohol content, and since this alcohol content functions as a preservative, it does not deteriorate even when stored at room temperature. Also, unlike soy sauce, it does not contain salt, so it can be used for cooking by people with limited salt content. However, this cooking liquor is regarded as liqueur, and liquor tax is levied under the application of the liquor tax law.

そこで図2に示す第2の実施形態では、2.5%程度の塩分を配合した酒精液を使用し、その他の工程は第1の実施形態と同様にして、塩分が約2.0%の調理酒を製造した。このように塩分を含む調理酒は飲用に適さないため、酒税法の適用がなく、販売価格を引き下げることができる。なお塩分は必ずしも酒精液中に添加する必要はなく、麹と酒精液との混合物中に添加することも可能であるが、塩分を均一に分散させるためには酒精液中に添加することが好ましい。以下に本発明の実施例を示す。 Therefore, in the second embodiment shown in FIG. 2, a liquor semen containing about 2.5% salt is used, and the other steps are the same as in the first embodiment, and the salt content is about 2.0%. Made cooking liquor. Since cooking liquor containing salt is not suitable for drinking, the liquor tax law does not apply and the selling price can be reduced. It should be noted that the salt content does not necessarily have to be added to the liquor semen, and it is possible to add it to the mixture of the jiuqu and the liquor semen, but it is preferable to add it to the liquor semen in order to uniformly disperse the salt content. .. Examples of the present invention are shown below.

(実施例1)
脱脂大豆400grを40分間加圧蒸煮し、またみりん粕400grを10分間加圧蒸煮した。これらを30℃まで冷却後に混合し、麹菌を種付けした。これを保管庫にて30℃で60時間保管し、麹を得た。この800grの麹にアルコール濃度が20%の酒精液1600mLを添加し、常温にて一か月間発酵させた。発酵期間中は、時々撹拌を行った。
(Example 1)
400 gr of defatted soybean was steamed under pressure for 40 minutes, and 400 gr of mirin lees was steamed under pressure for 10 minutes. These were cooled to 30 ° C. and then mixed and seeded with Jiuqu. This was stored in a storage at 30 ° C. for 60 hours to obtain Jiuqu. 1600 mL of liquor semen having an alcohol concentration of 20% was added to this 800 gr koji and fermented at room temperature for one month. During the fermentation period, stirring was occasionally performed.

得られたもろみ1800grを圧搾した結果、1248grの圧搾液と546grの絞り粕とが得られた。圧搾液は本発明のみりん粕使用調理酒であり、その成分を分析したところ、表1の通りであった。 As a result of squeezing the obtained mash 1800 gr, 1248 gr of the squeezed liquid and 546 gr of the squeezed lees were obtained. The pressed liquid was a cooking liquor using mirin lees of the present invention, and when its components were analyzed, it was as shown in Table 1.

Figure 0007036403000001
Figure 0007036403000001

(実施例2)
脱脂大豆400grを40分間加圧蒸煮し、またみりん粕400grを10分間加圧蒸煮した。これらを30℃まで冷却後に混合し、麹菌を種付けした。これを保管庫にて30℃で60時間保管し、麹を得た。この800grの麹にアルコール濃度が20%で、塩分3%の酒精液1600mLを添加し、常温にて一か月間発酵させた。発酵期間中は、時々撹拌を行った。
(Example 2)
400 gr of defatted soybean was steamed under pressure for 40 minutes, and 400 gr of mirin lees was steamed under pressure for 10 minutes. These were cooled to 30 ° C. and then mixed and seeded with Jiuqu. This was stored in a storage at 30 ° C. for 60 hours to obtain Jiuqu. 1600 mL of liquor semen having an alcohol concentration of 20% and a salt content of 3% was added to this 800 gr koji and fermented at room temperature for one month. During the fermentation period, stirring was occasionally performed.

得られたもろみ1800grを圧搾した結果、1200grの圧搾液と575grの絞り粕とが得られた。圧搾液は本発明の加塩されたみりん粕使用調理酒であり、その成分を分析したところ、表2の通りであった。この調理酒は塩分を含み飲用に適さないので、酒税が掛からない利点がある。 As a result of squeezing the obtained mash 1800 gr, 1200 gr of the squeezed liquid and 575 gr of the squeezed lees were obtained. The pressed liquid was the cooking liquor using salted mirin lees of the present invention, and when the components thereof were analyzed, it was shown in Table 2. This cooking liquor contains salt and is not suitable for drinking, so it has the advantage of not being subject to liquor tax.

Figure 0007036403000002
Figure 0007036403000002

以上に説明した通り、本発明のみりん粕使用調理酒の製造方法によれば、飼料や廃棄物として処理せざるを得なかったみりん粕を有効利用し、醤油と同様にうまみ成分を多く含有ししかも塩分濃度が低い調理酒を製造することができる。 As described above, according to the method for producing a cooking liquor using mirin lees of the present invention, mirin lees, which had to be treated as feed or waste, is effectively used and contains a large amount of umami components like soy sauce. Moreover, it is possible to produce cooking liquor having a low salt concentration.

Claims (4)

大豆または脱脂加工大豆と、みりん粕とを原料とし、これらの原料に麹菌を作用させて得られた麹に他の原料である酒精液を混合し、発酵させたもろみを圧搾して調理酒を得ることを特徴とするみりん粕使用調理酒の製造方法。 Using soybeans or defatted soybeans and mirin lees as raw materials, the koji obtained by reacting these raw materials with aspergillus is mixed with sake semen, which is another raw material, and fermented mash is squeezed to make cooked liquor. A method for producing a cooked liquor using mirin lees, which is characterized by obtaining. 前記酒精液または酒精液と麹との混合物に塩分を添加し、塩分を含有する調理酒を得ることを特徴とする請求項1に記載のみりん粕使用調理酒の製造方法。 The method for producing a cooking liquor using mirin lees according to claim 1, wherein salt is added to the liquor semen or a mixture of liquor semen and jiuqu to obtain a cooking liquor containing the salt content. 大豆または脱脂加工大豆の質量を、みりん粕の質量の1~3倍とすることを特徴とする請求項1または2に記載のみりん粕使用調理酒の製造方法。 The method for producing a cooking liquor using mirin lees according to claim 1 or 2, wherein the mass of soybeans or defatted soybeans is 1 to 3 times the mass of mirin lees. 得られた調理酒のフォルモール窒素が0.8%以上であることを特徴とする請求項1~3の何れかに記載のみりん粕使用調理酒の製造方法。 The method for producing a cooking liquor using mirin lees according to any one of claims 1 to 3, wherein the obtained cooking liquor has a formol nitrogen of 0.8% or more.
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US20080044501A1 (en) 2006-08-16 2008-02-21 Genebiotech Co. Ltd. Fermented soybean products and methods of producing them
JP2015033340A (en) 2013-08-08 2015-02-19 キッコーマン株式会社 Spirit-containing seasoning and production method thereof
JP2017085992A (en) 2015-11-11 2017-05-25 キッコーマン株式会社 Enzymatically decomposed seasoning
CN107212357A (en) 2017-05-22 2017-09-29 安徽海神黄酒集团有限公司 A kind of preparation method of seasoning flavouring cooking wine

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JPH01181785A (en) * 1988-01-13 1989-07-19 Kikkoman Corp Seasoning of sweet rice wine fashion
JPH1146750A (en) * 1997-08-01 1999-02-23 Kikkoman Corp Flavor solution and synthetic sake with improved flavor

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US20080044501A1 (en) 2006-08-16 2008-02-21 Genebiotech Co. Ltd. Fermented soybean products and methods of producing them
JP2015033340A (en) 2013-08-08 2015-02-19 キッコーマン株式会社 Spirit-containing seasoning and production method thereof
JP2017085992A (en) 2015-11-11 2017-05-25 キッコーマン株式会社 Enzymatically decomposed seasoning
CN107212357A (en) 2017-05-22 2017-09-29 安徽海神黄酒集团有限公司 A kind of preparation method of seasoning flavouring cooking wine

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