JP2020005609A - Production method of cooking liquor using sweet-sake lees - Google Patents

Production method of cooking liquor using sweet-sake lees Download PDF

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JP2020005609A
JP2020005609A JP2018132463A JP2018132463A JP2020005609A JP 2020005609 A JP2020005609 A JP 2020005609A JP 2018132463 A JP2018132463 A JP 2018132463A JP 2018132463 A JP2018132463 A JP 2018132463A JP 2020005609 A JP2020005609 A JP 2020005609A
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soybeans
mirin
koji
liquor
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JP7036403B2 (en
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幹夫 山田
Mikio Yamada
幹夫 山田
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Kankyo Brewery Co Ltd
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Abstract

To provide a production method of a cooking liquor using sweet-sake lees, effectively using sweet-sake lees which are forced to be disposed as animal feed or waste, containing a lot of delicious taste components, and having a low salinity concentration.SOLUTION: A cooking liquor is obtained by using soybeans or defatted processed soybeans, and sweet-sake lees as the raw materials, mixing a spirit liquid as the other raw material with rice malt obtained by making Aspergillus oryzae act on the raw materials, and compressing fermented unrefined sake. Salinity can be added so as to bring a salinity concentration to about 2%. A mass of soybeans or defatted processed soybeans is preferably 1-3 times of a mass of sweet-sake lees.SELECTED DRAWING: Figure 1

Description

本発明は、醤油と同様に調理に使用することができるみりん粕使用調理酒の製造方法に関するものである。   The present invention relates to a method for producing cooked sake using mirin lees, which can be used for cooking like soy sauce.

一般的な醤油は、大豆と小麦の混合物に麹菌を作用させた麹に塩水を加え、6か月程度発酵させて製造されている。麹菌由来の酵素により、大豆蛋白及び小麦蛋白がアミノ酸に分解され、うまみを感じさせる。しかし食塩の含有率が分析値で15〜20%と高いため、塩分を制限されている病人の食事には使用量が制限されるという問題がある。また原料に大豆や小麦、米などを使用するため、うまみの多い醤油は安価に提供できないという問題がある。   General soy sauce is produced by adding salt water to koji obtained by allowing a koji mold to act on a mixture of soybean and wheat, and fermenting it for about six months. The soybean protein and wheat protein are decomposed into amino acids by the enzymes derived from Aspergillus to give a taste. However, since the content of salt is as high as 15 to 20% as an analysis value, there is a problem that the amount of use is limited for the diet of a sick person whose salt content is restricted. In addition, since soybeans, wheat, rice, and the like are used as raw materials, there is a problem that soy sauce with a lot of flavor cannot be provided at low cost.

同じく麹菌を利用した調味料として、古くからみりんが知られている。みりんはもち米に麹菌を作用させた米麹を発酵させて製造されるもので、約40%〜50%の糖分と、約14%程度のアルコール分を含有している。みりんの製造工程において発生するみりん粕はうまみ成分であるアミノ酸を含有しているため、これまで奈良漬などに利用されてきた。しかし最近では食生活の変化により漬物の需要が減少し、みりん粕は家畜の飼料としたり産業廃棄物として処理せざるを得ない状況にある。   Mirin has long been known as a seasoning utilizing koji mold. Mirin is produced by fermenting rice koji obtained by reacting koji fungi with glutinous rice, and contains about 40% to 50% of sugar and about 14% of alcohol. Mirin lees generated in the process of producing mirin contain amino acids which are umami components, and thus have been used in Nara pickles and the like. Recently, however, the demand for pickles has decreased due to changes in dietary habits, and mirin cake has to be treated as livestock feed or industrial waste.

そこで特許文献1には、みりん粕を原料として調味料を製造する技術が提案されている。この特許文献1の調味料はみりん粕を発酵させ、アルコール濃度を4%未満、食塩濃度を11%以上としたものである。この調味料は小麦や大豆を原料としないため食物アレルギーがある人にも使用可能である。しかし塩分濃度が高いため、前記した醤油と同様の問題が残されている。   Therefore, Patent Document 1 proposes a technique for producing a seasoning using mirin cake as a raw material. The seasoning disclosed in Patent Document 1 is obtained by fermenting mirin lees and having an alcohol concentration of less than 4% and a salt concentration of 11% or more. Since this seasoning does not use wheat or soy as a raw material, it can be used by those who have food allergies. However, since the salt concentration is high, the same problem as the above-mentioned soy sauce remains.

特開2017−85992号公報JP-A-2017-85992

従って本発明の目的は上記した従来技術の問題点を解決し、これまで飼料や廃棄物として処理せざるを得なかったみりん粕を有効利用し、うまみ成分を多く含有し、しかも塩分濃度が低いみりん粕使用調理酒の製造方法を提供することである。   Therefore, the object of the present invention is to solve the above-mentioned problems of the prior art, to effectively use mirin cake which had to be treated as feed or waste, contains a lot of umami components, and has a low salt concentration. An object of the present invention is to provide a method for producing cooked sake using mirin lees.

上記の課題を解決するためになされた本発明のみりん粕使用調理酒の製造方法は、大豆または脱脂加工大豆と、みりん粕とを原料とし、これらの原料に麹菌を作用させて得られた麹に他の原料である酒精液を混合し、発酵させたもろみを圧搾して調理酒を得ることを特徴とするものである。   In order to solve the above-mentioned problems, the present invention provides a method for producing cooked sake using mirin cake, using soybeans or defatted soybeans, and mirin cake as raw materials, and koji obtained by acting a koji mold on these raw materials. In addition, another ingredient, alcoholic semen is mixed and fermented moromi is pressed to obtain cooked liquor.

なお請求項2に記載したように、前記酒精液または酒精液と麹との混合物に塩分を添加し、塩分を含有する調理酒を得ることができる。   In addition, as described in claim 2, salt can be added to the alcoholic beverage or a mixture of alcoholic beverage and koji to obtain a cooked liquor containing a sodium.

また請求項3に記載したように、大豆または脱脂加工大豆の質量を、みりん粕の質量の1〜3倍とすることが好ましい。   Further, as described in claim 3, the mass of the soybean or the defatted soybean is preferably set to be 1 to 3 times the mass of the mirin cake.

さらに請求項4に記載したように、得られた調理酒のフォルモール窒素が0.8%以上であることが好ましい。   Furthermore, as described in claim 4, the obtained cooked liquor preferably has a formol nitrogen of 0.8% or more.

本発明のみりん粕使用調理酒の製造方法によれば、現状では飼料や廃棄物として処理せざるを得なかったみりん粕を原料の一部として有効活用し、うまみ成分が多く醤油の代替品として使用することができる調理酒を安価に提供することができる。この調理酒は塩分濃度が低いため、塩分を制限されている人の料理にも使用することができる。なお、塩分はゼロとすることができるが、酒税法の適用を避けるために2%程度の少量の塩分を含有させることも可能である。この場合にも塩分濃度は醤油よりもはるかに低くなる。   According to the method for producing cooked sake using only mirin cake of the present invention, mirin cake, which had to be treated as feed or waste at present, is effectively utilized as a part of the raw material, and as a substitute for soy sauce having a lot of umami components. Cooked liquor that can be used can be provided at low cost. Because this cooked liquor has a low salt concentration, it can also be used for cooking for those who have a limited salt content. Although the salt content can be set to zero, a small amount of salt content of about 2% can be contained in order to avoid the application of the liquor tax law. Again, the salt concentration will be much lower than in soy sauce.

本発明の第1の実施形態を示す工程説明図である。It is a process explanatory view showing a first embodiment of the present invention. 本発明の第2の実施形態を示す工程説明図である。It is a process explanatory view showing a second embodiment of the present invention.

以下に本発明の実施形態を説明する。第1の実施形態は請求項1に対応し、第2の実施形態は請求項2に対応するものである。   Hereinafter, embodiments of the present invention will be described. The first embodiment corresponds to claim 1, and the second embodiment corresponds to claim 2.

何れの実施形態においても、本発明で使用する原料は、大豆または脱脂加工大豆と、みりん粕と酒精液である。脱脂加工大豆は油分が抽出された後の大豆であるため、大豆よりも安価に入手することができ、しかも油分以外の大豆蛋白はそのまま残存しているため、大豆を使用した場合に比較して得られた調理酒のうまみが減少することはない。   In any of the embodiments, the raw materials used in the present invention are soybeans or defatted soybeans, mirin cake and sake semen. Since defatted soybeans are soybeans from which oil has been extracted, they can be obtained at a lower cost than soybeans, and since soybean proteins other than oils remain as they are, compared to the case of using soybeans The taste of the obtained cooked liquor does not decrease.

図1に示すように、大豆または脱脂加工大豆を10分から1時間程度加圧蒸煮したうえ、常温付近まで冷却する。同様にみりん粕を10分程度加圧蒸煮したうえ、常温付近まで冷却し、両者を混合する。この混合物に麹菌を種付けし、例えば48時間程度麹菌を増殖させ、麹を得る。みりん粕はもち米を加圧蒸煮して発酵させたものであるから、大豆または脱脂加工大豆よりも、加圧蒸煮時間を短縮することができる。   As shown in FIG. 1, soybeans or defatted soybeans are steamed under pressure for about 10 minutes to 1 hour, and then cooled to around room temperature. Similarly, the mirin cake is steamed under pressure for about 10 minutes, cooled to around room temperature, and mixed. This mixture is seeded with koji mold, and the koji mold is grown, for example, for about 48 hours to obtain koji. Since mirin lees are made by fermenting glutinous rice by steaming under pressure, the steaming time under pressure can be shortened compared to soybeans or defatted soybeans.

このように、大豆または脱脂加工大豆とみりん粕との混合物に麹菌を作用させる方法のほかに、大豆または脱脂加工大豆に麹菌を作用させた麹と、みりん粕に麹菌を作用させた麹とを混合することもできる。   Thus, in addition to the method of causing koji mold to act on a mixture of soybeans or defatted soybeans and mirin cake, koji obtained by allowing koji molds to act on soybeans or defatted soybeans, and koji by allowing koji molds to act on mirin cakes. They can also be mixed.

何れの場合にも、みりん粕よりも大豆または脱脂加工大豆の比率を大きくした方が大豆蛋白由来のアミノ酸が増加するため、うまみが出る。このため、大豆または脱脂加工大豆の質量を、みりん粕の質量の1〜3倍とすることが好ましい。大豆または脱脂加工大豆の比率がこれよりも小さくなるとうまみが少なくなり、逆に大豆または脱脂加工大豆の比率をこの範囲よりも大きくすると相対的にみりん粕の使用量が減少し、みりん粕の有効利用という本発明の目的が達成できなくなるからである。   In any case, when the ratio of soybeans or defatted soybeans is larger than that of mirin lees, the amount of amino acids derived from soybean protein increases, and umami is produced. For this reason, it is preferable that the mass of the soybean or the defatted soybean is 1 to 3 times the mass of the mirin cake. If the ratio of soybeans or defatted soybeans is smaller than this, umami will be reduced, and if the ratio of soybeans or defatted soybeans is larger than this range, the use of mirin cake will decrease relatively, and the effectiveness of mirin cake will be reduced. This is because the purpose of the present invention of utilization cannot be achieved.

得られた麹は、酒精液と混合される。酒精液としては、例えばアルコール濃度が20%以上のものを用いることができる。これによって、麹菌の分解、酵素作用を阻害する雑菌の繁殖を防止することができる。麹に酒精液を加えて混合するが、この際に十分に混錬して均一化するとともに、麹を細かく破砕しておくことが、次工程の発酵に有利である。なお酒精液の量は、例えば麹の質量の2倍程度とすればよいが、その比率は適宜調整すればよい。   The obtained koji is mixed with alcoholic semen. As the alcoholic semen, for example, one having an alcohol concentration of 20% or more can be used. As a result, it is possible to prevent decomposition of the koji mold and propagation of various bacteria that inhibit the enzyme action. The alcoholic semen is added to the koji and mixed. At this time, it is advantageous that the koji is sufficiently kneaded and homogenized, and the koji is finely crushed for the fermentation in the next step. In addition, the amount of the alcoholic beverage may be about twice the mass of the koji, for example, and the ratio may be appropriately adjusted.

麹と酒精液との混合物は、常温で適宜の期間にわたりタンク内で発酵させる。この期間は季節にもよるが、例えば一か月程度である。この期間中に麹菌由来の酵素により大豆蛋白がアミノ酸に分解され発酵液中に溶出する。またみりん粕中に残存していた蛋白質も同様に分解されるとともに、残存していたアミノ酸が発酵液中に溶出する。このようにして得られたもろみを圧搾して固形分を分離し、発酵液を抽出して調理酒を得る。   The mixture of koji and sake semen is fermented in a tank at room temperature for an appropriate period. This period depends on the season, but is, for example, about one month. During this period, the soybean protein is decomposed into amino acids by the enzyme derived from Aspergillus and eluted into the fermentation broth. The protein remaining in the mirin cake is similarly degraded, and the remaining amino acids are eluted into the fermentation broth. The mash thus obtained is squeezed to separate solids, and the fermented liquid is extracted to obtain cooked liquor.

例えば、脱脂加工大豆200gr、みりん粕200gr、20%酒精液800mLを原料とした場合、アルコール分が約15%の調理酒600mLを製造することができる。得られた調理酒のフォルモール窒素は0.8%以上であり、濃口醤油と同様の多くのアミノ酸を含有している。   For example, when 200 gr of defatted soybeans, 200 gr of mirin lees, and 800 mL of 20% alcoholic semen are used as raw materials, 600 mL of cooked liquor with an alcohol content of about 15% can be produced. The resulting cooked liquor contains 0.8% or more formol nitrogen, and contains many amino acids similar to concentrated soy sauce.

フォルモール窒素の測定は全アミノ酸の定量法の一つであり、清酒のアミノ酸度の測定にも採用されている。アミノ酸がホルマリンと反応して酸としての性質をもつ化合物に変ることを利用したもので、中和後の清酒に中性ホルマリンを加え、これをアルカリで滴定してアミノ酸量を測定する方法である。日本醤油研究所のデータによれば、特選、本醸造の濃口醤油のフォルモール窒素は0.87%〜0・90%程度、超特選、本醸造の濃口醤油のフォルモール窒素は1.05%程度、淡口醤油では0.62%〜0・70%、特選、淡口醤油では0・85%程度である。本発明により製造された調理酒は後記する実施例に示すように0.800%と0・938%であり、特選醤油と同等のアミノ酸を含有していることが確認されている。   Measurement of formol nitrogen is one of the methods for quantifying total amino acids, and is also used for measuring the amino acid content of sake. This method utilizes the fact that an amino acid reacts with formalin to change into a compound having the properties of an acid.This is a method of adding neutral formalin to neutralized sake and titrating it with alkali to measure the amount of amino acids. . According to data from the Japan Soy Sauce Research Institute, the formol nitrogen of the specialty, brewed dark soy sauce is about 0.87% to 0.90%, and the formal nitrogen of the super specialty, honjou made rich soy sauce is 1.05%. About 0.62% to 0.70% for fresh soy sauce and about 0.85% for specialty and soy sauce. The cooked liquor produced according to the present invention is 0.800% and 0.938% as shown in the examples described later, and it has been confirmed that it contains an amino acid equivalent to that of special soy sauce.

上記した第1の実施形態の方法で製造された調理酒は約15%のアルコール分を含有し、このアルコール分が防腐剤として機能するため、室温において保存しても変質することはない。また醤油とは異なり塩分を含有しないので、塩分を制限されている人の料理にも使用することができる。ところがこの調理酒はリキュールとみなされ、酒税法の適用を受けて酒税が掛かることとなる。   The cooked liquor manufactured by the method of the first embodiment described above contains about 15% of alcohol, and since this alcohol functions as a preservative, it does not deteriorate even when stored at room temperature. Further, unlike soy sauce, since it does not contain salt, it can be used for cooking for people with limited salt. However, this cooked liquor is regarded as a liqueur and is subject to liquor tax under the Liquor Tax Law.

そこで図2に示す第2の実施形態では、2.5%程度の塩分を配合した酒精液を使用し、その他の工程は第1の実施形態と同様にして、塩分が約2.0%の調理酒を製造した。このように塩分を含む調理酒は飲用に適さないため、酒税法の適用がなく、販売価格を引き下げることができる。なお塩分は必ずしも酒精液中に添加する必要はなく、麹と酒精液との混合物中に添加することも可能であるが、塩分を均一に分散させるためには酒精液中に添加することが好ましい。以下に本発明の実施例を示す。   Therefore, in the second embodiment shown in FIG. 2, alcohol semen mixed with about 2.5% salt is used, and the other steps are the same as in the first embodiment, and the salt content is about 2.0%. Cooked sake was manufactured. Since cooked liquor containing salt is not suitable for drinking as described above, the liquor tax law is not applied and the selling price can be reduced. Note that the salt does not necessarily need to be added to the alcoholic semen, and can be added to the mixture of koji and alcoholic semen, but is preferably added to the alcoholic semen in order to uniformly disperse the salt. . Hereinafter, examples of the present invention will be described.

(実施例1)
脱脂大豆400grを40分間加圧蒸煮し、またみりん粕400grを10分間加圧蒸煮した。これらを30℃まで冷却後に混合し、麹菌を種付けした。これを保管庫にて30℃で60時間保管し、麹を得た。この800grの麹にアルコール濃度が20%の酒精液1600mLを添加し、常温にて一か月間発酵させた。発酵期間中は、時々撹拌を行った。
(Example 1)
400 gr of defatted soybeans were steamed under pressure for 40 minutes, and 400 gr of mirin cake was steamed under pressure for 10 minutes. After cooling to 30 ° C., they were mixed and seeded with koji mold. This was stored at 30 ° C. for 60 hours in a storage to obtain koji. 1600 mL of alcoholic semen having an alcohol concentration of 20% was added to this 800 gr of koji, and fermented at room temperature for one month. During the fermentation period, stirring was performed occasionally.

得られたもろみ1800grを圧搾した結果、1248grの圧搾液と546grの絞り粕とが得られた。圧搾液は本発明のみりん粕使用調理酒であり、その成分を分析したところ、表1の通りであった。   As a result of squeezing 1800 gr of the obtained moromi, 1248 gr of a squeezed liquid and 546 gr of pomace were obtained. The squeezed liquid was cooked liquor using only phosphorus lees of the present invention, and the components thereof were analyzed.

(実施例2)
脱脂大豆400grを40分間加圧蒸煮し、またみりん粕400grを10分間加圧蒸煮した。これらを30℃まで冷却後に混合し、麹菌を種付けした。これを保管庫にて30℃で60時間保管し、麹を得た。この800grの麹にアルコール濃度が20%で、塩分3%の酒精液1600mLを添加し、常温にて一か月間発酵させた。発酵期間中は、時々撹拌を行った。
(Example 2)
400 gr of defatted soybeans were steamed under pressure for 40 minutes, and 400 gr of mirin cake was steamed under pressure for 10 minutes. After cooling to 30 ° C., they were mixed and seeded with koji mold. This was stored at 30 ° C. for 60 hours in a storage to obtain koji. To this 800 gr koji, 1600 mL of alcoholic semen having a 20% alcohol concentration and a 3% salt content was added, and fermented at room temperature for one month. During the fermentation period, stirring was performed occasionally.

得られたもろみ1800grを圧搾した結果、1200grの圧搾液と575grの絞り粕とが得られた。圧搾液は本発明の加塩されたみりん粕使用調理酒であり、その成分を分析したところ、表2の通りであった。この調理酒は塩分を含み飲用に適さないので、酒税が掛からない利点がある。   As a result of pressing 1800 gr of the obtained moromi, 1200 gr of a pressed liquid and 575 gr of pomace were obtained. The squeezed liquid was the cooked sake using salted mirin lees according to the present invention, and the components thereof were analyzed. Since this cooked liquor contains salt and is not suitable for drinking, there is an advantage that a liquor tax is not charged.

以上に説明した通り、本発明のみりん粕使用調理酒の製造方法によれば、飼料や廃棄物として処理せざるを得なかったみりん粕を有効利用し、醤油と同様にうまみ成分を多く含有ししかも塩分濃度が低い調理酒を製造することができる。   As described above, according to the method for producing cooked sake using only phosphorus lees of the present invention, mirin lees that had to be treated as feed or waste are effectively used, and contain a lot of umami components like soy sauce. In addition, it is possible to produce cooked liquor having a low salt concentration.

Claims (4)

大豆または脱脂加工大豆と、みりん粕とを原料とし、これらの原料に麹菌を作用させて得られた麹に他の原料である酒精液を混合し、発酵させたもろみを圧搾して調理酒を得ることを特徴とするみりん粕使用調理酒の製造方法。   Using soybeans or defatted soybeans and mirin lees as raw materials, koji obtained by reacting koji molds with these raw materials, and the sperm semen, which is another raw material, are mixed, and the fermented moromi is pressed to produce cooked liquor. A method for producing cooked sake using mirin lees. 前記酒精液または酒精液と麹との混合物に塩分を添加し、塩分を含有する調理酒を得ることを特徴とする請求項1に記載のみりん粕使用調理酒の製造方法。   The method according to claim 1, wherein a salt is added to the liquor semen or a mixture of the liquor semen and the koji to obtain a liquor containing salt. 大豆または脱脂加工大豆の質量を、みりん粕の質量の1〜3倍とすることを特徴とする請求項1または2に記載のみりん粕使用調理酒の製造方法。   The method according to claim 1 or 2, wherein the mass of the soybean or the defatted soybean is 1 to 3 times the mass of the mirin cake. 得られた調理酒のフォルモール窒素が0.8%以上であることを特徴とする請求項1〜3の何れかに記載のみりん粕使用調理酒の製造方法。   The method according to any one of claims 1 to 3, wherein the formol nitrogen of the obtained cooked liquor is 0.8% or more.
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JPS62239965A (en) * 1986-04-10 1987-10-20 Kibun Kk Production of seasoning solution
JPH01181785A (en) * 1988-01-13 1989-07-19 Kikkoman Corp Seasoning of sweet rice wine fashion
JPH1146750A (en) * 1997-08-01 1999-02-23 Kikkoman Corp Flavor solution and synthetic sake with improved flavor
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JP2015033340A (en) * 2013-08-08 2015-02-19 キッコーマン株式会社 Spirit-containing seasoning and production method thereof
JP2017085992A (en) * 2015-11-11 2017-05-25 キッコーマン株式会社 Enzymatically decomposed seasoning
CN107212357A (en) * 2017-05-22 2017-09-29 安徽海神黄酒集团有限公司 A kind of preparation method of seasoning flavouring cooking wine

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62239965A (en) * 1986-04-10 1987-10-20 Kibun Kk Production of seasoning solution
JPH01181785A (en) * 1988-01-13 1989-07-19 Kikkoman Corp Seasoning of sweet rice wine fashion
JPH1146750A (en) * 1997-08-01 1999-02-23 Kikkoman Corp Flavor solution and synthetic sake with improved flavor
US20080044501A1 (en) * 2006-08-16 2008-02-21 Genebiotech Co. Ltd. Fermented soybean products and methods of producing them
JP2015033340A (en) * 2013-08-08 2015-02-19 キッコーマン株式会社 Spirit-containing seasoning and production method thereof
JP2017085992A (en) * 2015-11-11 2017-05-25 キッコーマン株式会社 Enzymatically decomposed seasoning
CN107212357A (en) * 2017-05-22 2017-09-29 安徽海神黄酒集团有限公司 A kind of preparation method of seasoning flavouring cooking wine

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