JP6965583B2 - Fixing member, fixing device, process cartridge, and image forming device - Google Patents

Description

The present invention relates to a fixing member, a fixing device, a process cartridge, and an image forming device.

In an image forming apparatus using an electrophotographic method (copier, facsimile, printer, etc.), an unfixed toner image formed on a recording material is fixed by the fixing apparatus to form an image.

Here, Patent Document 1 states that "a fixing member used in a process of heating a toner image on a recording medium to fix it on the recording medium, the outermost layer of which is formed of an elastic body, and a peeling stress of 20 N /. A fixing member having a size of ^{cm 2 or less ”is disclosed.}

Further, Patent Document 2 states that "vinyl alkoxysilane is introduced into a plasma excitation gas and the inner surface of the tube is plasma-treated, and the arithmetic mean roughness Ra of the inner surface of the tube to be plasma-treated and the roughness curve element. A fixing member having a fluororesin tube having an average length RSm of Ra <0.08 μm and RSm <25 μm as a surface member ”is disclosed.

Japanese Unexamined Patent Publication No. 2013-03419 Japanese Unexamined Patent Publication No. 2016-037597

The surface of an elastic layer containing a polymer of a first polysiloxane having a hydrogen-bonded silyl group (-SiH) in which a hydrogen atom is bonded to a silicon atom and a second polysiloxane having a vinyl group (-CH = CH _2). In the fixing member provided with the surface layer directly on the surface, the surface layer and the elastic layer may be separated from each other when compression deformation and release are repeated.

Therefore, an object of the present invention is to contact an elastic layer and an elastic layer containing a polymer of a first polysiloxane having a hydrogen-bonded silyl group in which a hydrogen atom is bonded to a silicon atom and a second polysiloxane having a vinyl group. In a fixing member having a surface layer to be formed, compressive deformation and release are performed as compared with the case where the surface of the surface layer on the side in contact with the elastic layer does not have a reactive group forming a covalent bond with a functional group in the elastic layer. It is an object of the present invention to provide a fixing member in which peeling between a surface layer and an elastic layer is suppressed even if it is repeated.
Hereinafter, "the peeling between the surface layer and the elastic layer is suppressed even if compression deformation and release are repeated" is also referred to as "excellent adhesion durability between the elastic layer and the surface layer".

The above problem is solved by the following means. That is,
The invention according to <1 > is
Base material,
An elastic layer arranged on the substrate and containing a polymer of a first polysiloxane having a hydrogen-bonded silyl group in which a hydrogen atom is bonded to a silicon atom and a second polysiloxane having a vinyl group, and
A surface layer that is arranged in contact with the elastic layer and has a hydrogen-bonded silyl group on the surface on the side that contacts the elastic layer.
With
A fixing member having a covalent bond at the interface between the elastic layer and the surface layer, in which a vinyl group of the elastic layer and a hydrogen-bonded silyl group of the surface layer have reacted.

The invention according to <2 > is
The fixing member according to < 1 > , wherein the surface layer is a resin layer containing a fluororesin.
The invention according to <3 > is
The fixing member according to < 2 > , wherein the surface layer is a layer in which a resin cylinder containing the fluororesin is covered with the elastic layer.

The invention according to <4 > is
Any one of < 1 > to < 3 > in which the content of the vinyl group [v (mol)] is larger than the content of the hydrogen-bonded silyl group [s (mol)] before the polymer is formed. a fixing member according to One.
The invention according to <5 > is
The ratio [s: v (mol ratio)] of the content [s (mol)] of the hydrogen-bonded silyl group to the content [v (mol)] of the vinyl group before becoming the polymer is 1: The fixing member according to < 4 > , which is in the range of 1.4 to 1: 2.2.

The invention according to <6 > is
Any one of < 1 > to < 3 > in which the content [s (mol)] of the hydrogen-bonded silyl group is larger than the content [v (mol)] of the vinyl group before the polymer is formed. a fixing member according to One.
The invention according to <7 > is
The ratio [v: s (mol ratio)] of the vinyl group content [v (mol)] to the hydrogen-bonded silyl group content [s (mol)] before the polymer is formed is 1: The fixing member according to < 6 > , which is in the range of 1.1 to 1: 2.2.

The invention according to <8 > is
A first rotating body and a second rotating body arranged in contact with the outer surface of the first rotating body are provided.
Wherein at least one of the first rotary member and the second rotary member is a fixing member according to any one of <1> to <7>,
This is a fixing device for fixing the toner image by inserting a recording medium having a toner image formed on the surface into a contact portion between the first rotating body and the second rotating body.

The invention according to <9 > is
Equipped with the fixing device described in < 8 >
It is a process cartridge that is attached to and detached from the image forming apparatus.

The invention according to <10 > is
Image holder and
A charging means for charging the surface of the image holder and
An electrostatic latent image forming means for forming an electrostatic latent image on the surface of the charged image holder,
A developing means for developing an electrostatic latent image formed on the surface of the image holder with a developer containing toner to form a toner image, and a developing means.
A transfer means for transferring the toner image to the surface of a recording medium, and
A fixing means for fixing the toner image on the recording medium, the fixing means having the fixing device according to < 8 >, and the fixing means.
It is an image forming apparatus provided with.

According to the invention according to < 1 > , < 2 > , or < 3 > , a first polysiloxane having a hydrogen-bonded silyl group in which a hydrogen atom is bonded to a silicon atom and a second polysiloxane having a vinyl group A fixing member having an elastic layer containing a polymer and a surface layer in contact with the elastic layer has a reactive group forming a covalent bond with a functional group in the elastic layer on the surface of the surface layer on the side in contact with the elastic layer. A fixing member having excellent adhesive durability between the elastic layer and the surface layer is provided as compared with the case where there is no adhesive layer.
According to the invention according to < 4 > or < 5 > , the content [s (mol)] of hydrogen-bonded silyl groups is higher than the content [v (mol)] of vinyl groups before becoming a polymer. A fixing member having excellent adhesive durability between the elastic layer and the surface layer is provided as compared with the case where the number is large.
According to the invention according to < 6 > or < 7 > , the vinyl group content [v (mol)] is higher than the hydrogen bond silyl group content [s (mol)] before the polymer is formed. A fixing member having excellent unevenness tracking property of the recording medium is provided as compared with the case where the number is large.
According to the invention according to < 8 > , < 9 > , or < 10 > , a first polysiloxane having a hydrogen-bonded silyl group in which a hydrogen atom is bonded to a silicon atom and a second polysiloxane having a vinyl group Fixation having an elastic layer containing a polymer and a surface layer in contact with the elastic layer, and having no reactive group forming a covalent bond with a functional group in the elastic layer on the surface of the surface layer on the side in contact with the elastic layer. A fixing device, a process cartridge, or an image forming device including a fixing member having excellent adhesion durability between the elastic layer and the surface layer as compared with the case where the member is provided is provided.

It is a schematic cross-sectional view which shows an example of the fixing member which concerns on this embodiment. It is a schematic block diagram which shows an example of the fixing device which concerns on 1st Embodiment. It is a schematic block diagram which shows an example of the fixing device which concerns on 2nd Embodiment. It is a schematic block diagram which shows an example of the image forming apparatus which concerns on this embodiment.

Hereinafter, embodiments that are an example of the present invention will be described.
Members having substantially the same function may be given the same code throughout the drawings, and overlapping description may be omitted as appropriate.

[Fixing member]
The fixing member according to this embodiment will be described.
FIG. 1 is a schematic cross-sectional view showing an example of a fixing member according to the present embodiment.

The fixing member 110 according to the present embodiment is, for example, as shown in FIG. 1, a base material 110A, an elastic layer 110B provided on the base material 110A, and a surface layer 110C provided so as to come into contact with the elastic layer 110B. And have.

The elastic layer 110B is a polymer of a first polysiloxane having a hydrogen-bonded silyl group (-SiH) in which a hydrogen atom is bonded to a silicon atom and a second polysiloxane having a vinyl group (-CH = CH ₂ ). include.
The surface layer 110C has a hydrogen-bonded silyl group (-SiH) on the surface on the side in contact with the elastic layer 110B.
Then, at the interface between the elastic layer 110B and the surface layer 110C _{, there is a covalent bond in which the vinyl group (-CH = CH 2} ) of the elastic layer 110B and the hydrogen bond silyl group (-SiH) of the surface layer 110C have reacted. There is. That is, the elastic layer 110B and the surface layer 110C are _{adhered to each other by the reaction between the vinyl group (-CH = CH 2} ) of the elastic layer 110B and the hydrogen-bonded silyl group (-SiH) of the surface layer 110C.

The fixing member 110 according to the present embodiment is a fixing member having excellent adhesive durability between the elastic layer 100B and the surface layer 110C due to the above configuration. That is, even if compression deformation and release are repeated, the fixing member is suppressed from peeling between the elastic layer 100B and the surface layer 110C. The reason is presumed as follows.

Conventionally, as a fixing device for an image forming device, a fixing device including a first rotating body and a second rotating body which are members having a roll-shaped or belt-shaped shape has been known. This fixing device is driven to rotate in a state where both rotating bodies are brought into contact with each other to form a sandwiching region N (nip portion) which is a contact portion, and the sandwiching region formed by the first rotating body and the second rotating body. A recording medium on which a toner image is formed on the surface is inserted through N (nip portion) to fix the toner image. Then, as at least one of the first rotating body and the second rotating body, an elastic layer composed of a base material, a silicone-based elastic member (silicone rubber) containing a polymer of polysiloxane, and a surface layer are provided. As the fixing member having in this order, the fixing member in which the elastic layer and the surface layer are directly in contact with each other and laminated is used.

However, in such a fixing device, when the first rotating body and the second rotating body are compressed and deformed in the sandwiching region N (nip portion) and then pass through the sandwiching region N (nip portion) with the rotation drive, the compression is performed. The state of being released and returning to the original shape is repeated. Therefore, the surface layer and elastic layer of the fixing member are also repeatedly compressed and deformed and released from compression, and a load is repeatedly applied to the interface between the surface layer and the elastic layer. Then, due to repeated loading, the surface layer and the elastic layer may be separated from each other.

On the other hand, in the fixing member 110 according to the present embodiment, the elastic layer 110B has a first polysiloxane having a hydrogen-bonded silyl group (−SiH) and a second polysiloxane having a vinyl group (−CH = CH ₂ ). Contains a polymer of siloxane. That is, the elastic layer 110B is a silicone-based polymer (silicone rubber) having a polymer structure formed by bonding a hydrogen-bonded silyl group in the first polysiloxane and a vinyl group in the second polysiloxane. include. Then, in the elastic layer 110B containing the silicone-based polymer (silicone rubber), there is a vinyl group that does not form a bond with the coexisting hydrogen-bonded silyl group, that is, an unreacted vinyl group. There is.
On the other hand, the surface layer 110C has a hydrogen-bonded silyl group on the surface on the side in contact with the elastic layer 110B. Then, the hydrogen-bonded silyl group of the surface layer 110C reacts with the vinyl group of the elastic layer 110B to form a covalent bond. As a result, the adhesive force at the interface between the surface layer 110C and the elastic layer 110B is increased.
In particular, since the reaction between the hydrogen-bonded silyl group and the vinyl group is an addition reaction, no by-product (for example, gas) is generated, and the adhesive force at the interface between the surface layer 110C and the elastic layer 110B due to the by-product No decrease is seen.

Here, the existence of a covalent bond formed at the interface between the surface layer 110C and the elastic layer 110B, which is formed by the reaction of the hydrogen-bonded silyl group and the vinyl group, is confirmed as follows. Hereinafter, this confirmation method is also referred to as "a confirmation method of a covalent bond formed at the interface between the surface layer and the elastic layer".
That is, the fixing member 110 according to the present embodiment is stored at high temperature and high humidity (for example, 95 ° C., 100% RH) for 24 hours (hours).
The presence or absence of peeling of the surface layer 110C from the elastic layer 110B was confirmed on the fixing member 110 after storage by using the following method.
That is, after storage at high temperature and high humidity, moisture is wiped off, only the surface layer 110C is forcibly cut out, and the cut out surface layer 110C is cut out in the direction of 90 degrees with respect to the surface while holding the elastic layer 110B and the surface layer 110C. A peeling test is performed by pulling.
When a covalent bond is not formed at the interface between the surface layer 110C and the elastic layer 110B (for example, the bond formed between the surface layer 110C and the elastic layer 110B is an ionic bond, a hydrogen bond, or the like. Case), the surface layer 110C is peeled off from the elastic layer 110B due to the influence of the temperature and humidity during storage. On the other hand, since the covalent bond is not easily affected by the temperature and humidity during storage, if the peeling of the surface layer 110C from the elastic layer 110B cannot be confirmed by the above method, the covalent bond is formed at the interface between the surface layer 110C and the elastic layer 110B. It can be said that a covalent bond is formed.

From the above, it is presumed that the fixing member 110 according to the present embodiment has excellent adhesive durability between the elastic layer 110B and the surface layer 110C.

Conventionally, a technique has been known in which a primer layer (adhesive layer) is interposed between the elastic layer 110B and the surface layer 110C to bond both layers. However, the fixing member 110 according to the present embodiment is excellent in adhesive durability between the elastic layer 110B and the surface layer 110C without interposing a primer layer (adhesive layer). That is, a fixing member having excellent adhesive durability between the elastic layer 110B and the surface layer 110C can be obtained even if it is simple and low cost.

(First aspect)
The fixing member 110 according to the present embodiment has a vinyl group content [v (mol)] rather than a hydrogen bond silyl group content [s (mol)] before becoming a polymer in the elastic layer 110B. The first aspect is often mentioned.
In this first aspect, since there are many vinyl groups (unreacted vinyl groups) present in the elastic layer, the amount of reaction between the vinyl group of the elastic layer and the hydrogen-bonded silyl group of the surface layer increases, and as a result, , The number of covalent bonds formed at the interface between both layers also increases. Therefore, in the first aspect, the adhesive durability at the interface between the elastic layer 110B and the surface layer 110C is likely to be improved.
From the viewpoint of improving the adhesive durability between the elastic layer 110B and the surface layer 110C, the ratio [s: v] of the hydrogen-bonded silyl group content [s (mol)] to the vinyl group content [v (mol)]. (Mol ratio)] is preferably in the range of 1: 1.4 to 1: 2.2, more preferably in the range of 1: 1.45 to 1: 2.1, and 1: 1.5 to 1: 2. The range of 0 is more preferable.

(Second aspect)
The fixing member 110 according to the present embodiment has a hydrogen-bonded silyl group content [s (mol)] rather than a vinyl group content [v (mol)] before it becomes a polymer in the elastic layer 110B. The second aspect is often mentioned.
In this second aspect, although a covalent bond is formed by the reaction of the vinyl group (unreacted vinyl group) remaining in the elastic layer 101B and the hydrogen bond silyl group of the surface layer, the reaction amount is the first. Less than aspect. When the reaction amount of the hydrogen-bonded silyl group between the vinyl group of the elastic layer 110B and the surface layer 110C increases, the hardness of the interface between the elastic layer 110B and the surface layer 110C also tends to increase. Flexibility is obtained at the interface between the layer 110B and the surface layer 110C. As described above, when the interface between the elastic layer 110B and the surface layer 110C is flexible, the ability to follow the unevenness of the recording medium is improved.
That is, in this second aspect, the unevenness-following property of the recording medium is improved while increasing the adhesive durability between the elastic layer 110B and the surface layer 110C. By using a fixing member having a high unevenness-following property of the recording medium, the fixing property in the concave portion can be improved even when a recording medium having a large unevenness is used.
From the viewpoint of improving the adhesion durability between the elastic layer 110B and the surface layer 110C and improving the unevenness followability of the recording medium, the vinyl group content [v (mol)] and the hydrogen bond silyl group content [s ( The ratio [v: s (mol ratio)] to [mol)] is preferably in the range of 1: 1.1 to 1: 2.2, more preferably in the range of 1: 1.15 to 1: 2.2. The range of 1: 1.25 to 1: 2.2 is more preferable.

In each embodiment, the difference between the vinyl group content [v (mol)] and the hydrogen-bonded silyl group content [s (mol)] before the polymer in the elastic layer 110B is formed. Within the above range, the decrease in breaking strength caused by the low degree of cross-linking of the silicone rubber in the elastic layer 110B is likely to be suppressed.

The amount ratio of the hydrogen-bonded silyl group to the vinyl group is controlled, for example, the amount ratio of the first polysiloxane to the second polysiloxane as a raw material, the amount of the hydrogen-bonded silyl group in the first polysiloxane, And by adjusting the amount of vinyl groups in the second polysiloxane.

Here, the method for measuring the contents of the hydrogen-bonded silyl group and the vinyl group is as follows.
The measurement of the content of the hydrogen-bonded silyl group (-SiH) and the vinyl group (-CH = CH ₂ ) before the polymer is formed is a step before the polymerization, that is, before the formation of the elastic layer 110B (for example, the formation of the elastic layer described later). The first polysiloxane and the second polysiloxane in the step of preparing the coating liquid for use) are carried out by using NMR spectroscopy. Specifically, the solution containing the first polysiloxane and the solution containing the second polysiloxane are each diluted 5-fold with n-hexane, centrifuged, and the filtrate is separated. Then, the solvent is removed _{, dissolved in deuterated chloroform (CDCl 3} ), and analyzed by NMR (manufactured by Varian, product name: UNITY-300) to obtain the respective contents (mol).

Next, the components of the fixing member 110 according to the present embodiment will be described in detail. The reference numerals will be omitted.

(Shape of fixing member)
The fixing member according to the present embodiment may be in the shape of a roll or in the shape of a belt. Further, it may be a heat fixing member having a heat source inside or outside, or a pressure fixing member having no heat source.

(Base material)
When the fixing member is in the form of a roll, examples of the base material include a cylindrical body made of a metal (aluminum, SUS, iron, copper, etc.), an alloy, ceramics, FRM (fiber reinforced metal), or the like.
When the fixing member is in a roll shape, the outer diameter and thickness of the base material are often, for example, an outer diameter of 10 mm or more and 50 mm or less, and for example, if it is made of aluminum, the thickness is 0.5 mm or more and 4 mm or less, SUS ( If it is made of stainless steel) or iron, the thickness is preferably 0.1 mm or more and 2 mm or less.

On the other hand, when the fixing member has a belt shape, the base material may be, for example, a metal belt (for example, a metal belt such as nickel, aluminum or stainless steel) or a resin belt (for example, polyimide, polyamideimide, polyphenylene sulfide, or polyetheretherketone). , Resin belts such as polybenzimidazole).
The volume resistivity may be controlled by adding and dispersing a conductive agent or the like to the resin belt. Specifically, examples of the resin belt include a polyimide belt in which carbon black is added and dispersed to control the volume resistivity.
Further, as the resin belt, for example, a belt-shaped belt can be mentioned in which both ends of a long polyimide sheet are combined in a puzzle shape and thermocompression-bonded using a thermocompression-bonding member.

When the fixing member has a belt shape, the thickness of the base material is preferably, for example, 20 μm or more and 200 μm or less, preferably 30 μm or more and 150 μm or less, and more preferably 40 μm or more and 130 μm or less.

An adhesive may be applied to the outer peripheral surface of the base material. That is, the base material and the elastic layer may be laminated via the adhesive layer.

(Elastic layer)
The elastic layer is a polymer of a first polysiloxane having a hydrogen-bonded silyl group (-SiH) in which a hydrogen atom is bonded to a silicon atom and a second polysiloxane having a vinyl group (-CH = CH ₂ ). including.

-First Polysiloxane The first polysiloxane having a hydrogen-bonded silyl group (-SiH) is not particularly limited, and a known material can be used. In the first polysiloxane, the hydrogen-bonded silyl group (-SiH) may be present at the end of the main chain or at the side chain of the main chain.

_{As the first polysiloxane, for example, an organopolysiloxane having two} ^{-SiH (R 1} ) groups at both ends or one end of the main chain (Note that R ¹ represents a hydrogen atom or an organic group, and a methyl group is preferable. The two R ^1s may be the same or different), and a hydrogen atom is bonded to the Si atom constituting the main chain (that is,-[O-Si (-H) (-R ^{2) in the main chain.} )] - structure with) an organohydrogenpolysiloxane (Note the, R ² represents a hydrogen atom or an organic group, preferably a methyl group) can be mentioned.

More specifically, both-terminal trimethylsiloxy group-blocking methylhydrogenpolysiloxane, both-terminal trimethylsiloxy group-blocking dimethylsiloxane / methylhydrogensiloxane copolymer, both-terminal dimethylhydrogensiloxy group-blocking dimethylpolysiloxane, both-terminal dimethyl Hydrogensiloxy group-blocked dimethylsiloxane / methylhydrogensiloxane copolymer, both-terminal trimethylsiloxy group-blocked methylhydrogensiloxane / diphenylsiloxane copolymer, both-terminal trimethylsiloxy group-blocked methylhydrogensiloxane / diphenylsiloxane / dimethylsiloxane Examples thereof include organohydrogenpolysiloxanes such as polymers.
These first polysiloxanes may be used alone or in combination of two or more.

-Second polysiloxane The second polysiloxane having a vinyl group (-CH = CH ₂ ) is not particularly limited, and a known material can be used. In the second polysiloxane, the vinyl group may be present at the end of the main chain or at the side chain of the main chain.

_{The second polysiloxane includes, for example, an organopolysiloxane in which a vinyl group (-CH = CH 2} ) is bonded to a silicon atom (Si) at both ends or one end of the main chain, and a side to the Si atom constituting the main chain. Organopolysiloxane can be mentioned in which a vinyl group (-CH = CH ₂ ) is bonded so as to form a chain.

More specifically, trimethylsiloxy group-blocked methylvinylpolysiloxane at both ends of the molecular chain, trimethylsiloxy group-blocked dimethylsiloxane / methylvinylsiloxane copolymer at both ends of the molecular chain, and trimethylsiloxy group-blocked dimethylsiloxane / methylvinyl at both ends of the molecular chain. Siloxane / methylphenylsiloxane copolymer, dimethylvinylsiloxy group-blocked dimethylpolysiloxane at both ends of the molecular chain, dimethylvinylsiloxy group-blocked methylvinylpolysiloxane at both ends of the molecular chain, dimethylvinylsiloxy group-blocked dimethylsiloxane / methylvinyl at both ends of the molecular chain Siloxane copolymer, dimethylvinylsiloxy group blockade at both ends of the molecular chain dimethylsiloxane / methylvinylsiloxane / methylphenylsiloxane copolymer, divinylmethylsiloxy group blockade at both ends of the molecular chain dimethylpolysiloxane, divinylmethylsiloxy group blockade at both ends of the molecular chain Examples thereof include organopolysiloxanes such as dimethylsiloxane / methylvinylsiloxane copolymer, trivinylsiloxy group-blocked dimethylpolysiloxane at both ends of the molecular chain, and trivinylsiloxy group-blocked dimethylsiloxane / methylvinylsiloxane copolymer at both ends of the molecular chain.
These second polysiloxanes may be used alone or in combination of two or more.

Hydrogen-bonded silyls by adjusting the amount of hydrogen-bonded silyl groups and vinyl groups in the first polysiloxane and the second polysiloxane, and adjusting the amount ratio of the first polysiloxane to the second polysiloxane, and the like. The ratio [s: v (mol ratio)] of the group content [s (mol)] to the vinyl group content [v (mol)] is controlled within the above range.

The elastic layer may contain various additives in addition to the above-mentioned polymer.
Examples of additives include reinforcing agents (carbon black, etc.), fillers (calcium carbonate, etc.), softening agents (paraffin-based, etc.), processing aids (stearic acid, etc.), antiaging agents (amine-based, etc.), and additions. Examples thereof include vulcanizing agents (sulfur, metal oxides, peroxides, etc.), functional fillers (alumina, etc.) and the like.

The thickness of the elastic layer is, for example, preferably 30 μm or more and 1 mm or less, and preferably 100 μm or more and 500 μm or less.

(Surface layer)
The surface layer has a hydrogen-bonded silyl group (-SiH) on the surface on the side in contact with the elastic layer.

As a method of allowing the hydrogen-bonded silyl group to exist on the surface of the surface layer on the side in contact with the elastic layer, there is a method of introducing a hydrogen-bonded silyl group by applying a surface treatment to the surface of the surface layer on the elastic layer side. Be done.
A method of using a material having a hydrogen-bonded silyl group as the material itself constituting the surface layer is also conceivable. Hydrogen-bonded silyl groups are selected from the viewpoints of maintaining the functions required of the surface layer, allowing hydrogen-bonded silyl groups to exist on the surface on the side in contact with the elastic layer, availability of materials, and ease of production. A method of introducing a hydrogen-bonded silyl group by surface treatment is more preferable on the surface of the surface layer made of a material that does not have the material that comes into contact with the elastic layer.

The surface layer is required to have heat resistance and releasability, for example. From this point of view, it is preferable to use a heat-resistant release material as the material constituting the surface layer, and specific examples thereof include fluororubber, fluororesin, silicone resin, and polyimide resin.
Among these, fluororesin is preferable as the heat-resistant mold release material. That is, the surface layer is preferably a resin layer containing a fluororesin.
Specific examples of such fluororesins include tetrafluoroethylene / perfluoroalkyl vinyl ether copolymer (PFA), polytetrafluoroethylene (PTFE), tetrafluoroethylene / hexafluoropropylene copolymer (FEP), and polyethylene. / Tetrafluoroethylene copolymer (ETFE), polyvinylidene fluoride (PVDF), polychlorotrifluoroethylene (PCTFE), vinyl fluoride (PVF) and the like can be mentioned.

As the surface layer, as described above, a method of introducing a hydrogen-bonded silyl group by surface treatment is preferable, and a hydrogen-bonded silyl group can be easily introduced into a target region. Therefore, a resin tubular body is used. Is preferable.
That is, the surface layer is preferably a layer in which a preformed resin tubular body is covered with an elastic layer. More specifically, the surface layer is preferably a layer in which the elastic layer is covered with a resin tubular body in which a hydrogen-bonded silyl group is introduced into at least the surface on the side in contact with the elastic layer after surface treatment. ..

-Surface treatment The surface treatment for introducing a hydrogen-bonded silyl group into the surface of the surface layer on the side in contact with the elastic layer may be a wet treatment or a dry treatment.
Specifically, for example, the surface layer is brought into contact with a compound having a reactive group reacting with a heat-resistant mold-removing material constituting the surface layer and a hydrogen-bonded silyl group, and the compound and the heat resistance constituting the surface layer are formed. A method of reacting with a release material, a method of generating an active point in the surface layer by an excimer laser treatment under reduced pressure, and a method of reacting a compound having a hydrogen-bonded silyl group at this active point, and a method of performing plasma treatment under reduced pressure to perform hydrogen-bonded silyl. Examples thereof include a method of binding a compound having a group.

Here, a method of introducing a hydrogen-bonded silyl group into the surface layer by plasma treatment will be described with an example.
As a compound having a hydrogen-bonded silyl group used for plasma treatment,
For example, monosilane (SiH ₄ ), monochlorosilane (SiH ₃ Cl), dichlorosilane (SiH ₂ Cl ₂ ), trichlorosilane (SiHCl ₃ ) and the like can be mentioned.

Hereinafter, plasma treatment when dichlorosilane is used as the compound having a hydrogen-bonded silyl group will be described. The present embodiment is not limited to this.
For example, a method of introducing dichlorosilane into a plasma excitation gas under reduced pressure (2 × 10 ⁴ Pa) and plasma-treating the inner surface of the surface layer (the surface on the side in contact with the elastic layer) can be mentioned.

A mixed gas of plasma excitation gas and dichlorosilane, which is easily converted into plasma, is supplied between the surface layer and the discharge electrode, and a voltage is applied to the discharge electrode to generate plasma. As the higher voltage is applied, the lines of electric force reach farther from the electrode surface, the lines of electric force in the space between the surface layer and the discharge electrode increase, and the plasma density increases.
As a result, the plasma comes into contact with the inner surface of the surface layer, and radicals are generated in the fluororesin constituting the surface layer. The radical of the fluororesin reacts radically with the SiH group of dichlorosilane, and the SiH group binds to the fluororesin.

Here, specific examples of the plasma excitation gas include hydrogen; a rare gas such as helium and argon; and nitrogen, and one or more kinds of excitation gases are used.
Further, the compound having a hydrogen bond silyl group used together with the plasma excitation gas may be one kind or two or more kinds.

-Physical Properties by Surface Treatment As for the roughness of the inner surface of the surface layer (the surface on the side in contact with the elastic layer), the arithmetic average roughness Ra is preferably less than 0.08 μm, and more preferably Ra 0.07 μm or less.
Further, the average length RSm of the roughness curve element is preferably less than 15 μm, and more preferably RSm 14 μm or less.

The Ra and RSm are measured according to JIS B 0601.
Specifically, a confocal microscope (OPTELICS H1200) manufactured by Lasertec Co., Ltd. is used to measure the surface shape of the inner surface of the surface layer with a resolution of 0.01 μm in the height direction. An evaluation length of 150 μm is taken from an arbitrary position of the obtained surface shape in the longitudinal direction of the surface layer, curvature is corrected by a quadratic function, and then the surface roughness is measured based on JIS B 0601. The surface roughness is measured with a cutoff value of 0.0025 mm when creating a cross-sectional curve from the cross-sectional curve of the actual surface and 0.08 mm as a cutoff value when creating a roughness curve from the cross-sectional curve.

Here, as a method for confirming whether or not a SiH group has been introduced into the inner surface of the surface layer, for example, a method of analyzing and detecting the Si element on the inner surface of the surface layer by X-ray photoelectron spectroscopy (XPS) can be mentioned.
Here, as the XPS device, a JPS9000MX device manufactured by JEOL Ltd. is used, and the measurement conditions are an acceleration voltage of 10 kV and a current value of 30 mA.

The thickness of the surface layer is preferably 100 μm or less, more preferably 5 μm or more and 50 μm or less, and further preferably 10 μm or more and 40 μm or less.

(Manufacturing method of fixing member)
Next, a method of manufacturing the fixing member will be described.
As a method for manufacturing the fixing member, for example, there are the following methods.
First, a coating liquid for forming an elastic layer containing the above-mentioned first polysiloxane and second polysiloxane is applied onto a base material, and the polymer is synthesized and cured by heating to form an elastic layer. .. Here, from the viewpoint of enhancing the adhesiveness between the elastic layer and the surface layer, the heating conditions are preferably 100 ° C. or higher and 150 ° C. or lower for 0.5 minutes or longer and 60 minutes or shorter. An adhesive layer may be interposed between the base material and the elastic layer. In that case, a coating liquid for forming the elastic layer is applied on the adhesive layer.
Next, a resin tubular body produced using the above-mentioned heat-resistant mold release material is prepared, and the above-mentioned surface treatment is applied to the resin tubular inner surface to introduce a hydrogen-bonded silyl group, and then the resin is placed on the elastic layer. Cover the tubular body. By firing (150 ° C or higher, 230 ° C or lower, 0.5 hours or longer and 8 hours or shorter) after coating the resin tubular body, the reaction between the hydrogen-bonded silyl group in the surface layer and the vinyl group in the elastic layer can be promoted. The curing reaction of the coating liquid for forming the elastic layer may be further advanced.
As described above, the resin tubular body becomes a surface layer, and a fixing member is manufactured.

(Use of fixing member)
The fixing member according to the present embodiment is applied to, for example, a heating roll, a pressure roll, a heating belt, a pressure belt, and the like. Examples of the heat source in the heating roll and the heating belt include a method of heating from an external heat source, a method of heating by an electromagnetic induction method, and the like.

[Fixing device]
The fixing device according to the present embodiment has various configurations, and includes, for example, a first rotating body and a second rotating body arranged in contact with the outer surface of the first rotating body. Then, the fixing member according to the present embodiment is applied as at least one of the first rotating body and the second rotating body.

Hereinafter, as the first and second embodiments, a fixing device including a heating belt and a pressure roll will be described. Then, in the first and second embodiments, the fixing member according to the present embodiment can be applied to both the heating belt and the pressure roll.
The fixing device according to the present embodiment is not limited to the first and second embodiments, and may be a fixing device provided with a heating roll or a heating belt and a pressure belt. The fixing member according to the present embodiment can be applied to any of a heating roll, a heating belt, and a pressure belt.
Further, the fixing device according to the present embodiment is not limited to the first and second embodiments, and may be an electromagnetic induction heating type fixing device.

(First Embodiment of fixing device)
The fixing device according to the first embodiment will be described. FIG. 2 is a schematic view showing an example of the fixing device according to the first embodiment.

As shown in FIG. 2, the fixing device 60 according to the first embodiment includes, for example, a heating roll 61 (an example of a first rotating body) driven to rotate, a pressure belt 62 (an example of a second rotating body), and a pressure belt 62 (an example of a second rotating body). It is configured to include a pressing pad 64 (an example of a pressing member) that presses the heating roll 61 via the pressurizing belt 62.
As for the pressing pad 64, for example, the pressure belt 62 and the heating roll 61 may be relatively pressurized. Therefore, the pressure belt 62 side may be pressurized to the heating roll 61, and the heating roll 61 side may be pressed to the heating roll 61.

A halogen lamp 66 (an example of heating means) is arranged inside the heating roll 61. The heating means is not limited to the halogen lamp, and other heat generating members that generate heat may be used.

On the other hand, for example, the temperature sensitive element 69 is arranged in contact with the surface of the heating roll 61. The lighting of the halogen lamp 66 is controlled based on the temperature measurement value by the temperature sensitive element 69, and the surface temperature of the heating roll 61 is maintained at a target set temperature (for example, 150 ° C.).

The pressure belt 62 is rotatably supported by, for example, a pressing pad 64 arranged inside and a belt traveling guide 63. Then, in the sandwiching region N (nip portion), the pressing pad 64 presses against the heating roll 61 and is arranged.

The pressing pad 64 is arranged inside the pressure belt 62 in a state of being pressed by the heating roll 61 via the pressure belt 62, and forms a sandwiching region N with the heating roll 61, for example. There is.
In the pressing pad 64, for example, a front sandwiching member 64a for securing a wide sandwiching region N is arranged on the inlet side of the sandwiching region N, and a peeling sandwiching member 64b for giving distortion to the heating roll 61 is provided. Is arranged on the exit side of the sandwiching area N.

In order to reduce the sliding resistance between the inner peripheral surface of the pressure belt 62 and the pressing pad 64, for example, a sheet-like sliding on the surface of the front sandwiching member 64a and the peeling sandwiching member 64b in contact with the pressure belt 62. A member 68 is provided. The pressing pad 64 and the sliding member 68 are held by the metal holding member 65.
The sliding member 68 is provided, for example, so that its sliding surface is in contact with the inner peripheral surface of the pressure belt 62, and is involved in the holding and supply of oil existing between the sliding member 68 and the pressure belt 62. ..

For example, a belt traveling guide 63 is attached to the holding member 65, and the pressure belt 62 is configured to rotate.

For example, the heating roll 61 is rotated in the arrow S direction by a drive motor (not shown), and the pressure belt 62 is rotated in the arrow R direction opposite to the rotation direction of the heating roll 61 in accordance with this rotation. That is, for example, the heating roll 61 rotates clockwise in FIG. 2, while the pressure belt 62 rotates counterclockwise.

Then, the paper K (an example of the recording medium) having the unfixed toner image is guided by, for example, the fixing inlet guide 56 and conveyed to the sandwiching region N. Then, when the paper K passes through the sandwiching region N, the unfixed toner image on the paper K is fixed by the pressure and heat acting on the sandwiching region N.

In the fixing device 60 according to the first embodiment, for example, the concave front sandwiching member 64a that imitates the outer peripheral surface of the heating roll 61 provides a wider sandwiching region N as compared with the configuration without the front sandwiching member 64a. Secured.

Further, in the fixing device 60 according to the first embodiment, for example, by arranging the peeling sandwiching member 64b so as to project from the outer peripheral surface of the heating roll 61, the heating roll 61 is distorted in the outlet region of the sandwiching region N. Is configured to grow locally.

If the peeling sandwiching member 64b is arranged in this way, for example, the paper K after fixing passes through the locally formed strain when passing through the peeling sandwiching region. Is easy to peel off from the heating roll 61.

As an auxiliary means for peeling, for example, a peeling member 70 is arranged on the downstream side of the sandwiching region N of the heating roll 61. The peeling member 70 is held by the holding member 72 in a state where the peeling claw 71 is close to the heating roll 61 in the direction facing the rotation direction (counter direction) of the heating roll 61, for example.

(Second Embodiment of Fixing Device)
The fixing device according to the second embodiment will be described. FIG. 3 is a schematic view showing an example of the fixing device according to the second embodiment.

As shown in FIG. 3, the fixing device 80 according to the second embodiment presses against, for example, a fixing belt module 86 including a heating belt 84 (an example of a first rotating body) and a heating belt 84 (fixing belt module 86). It is configured to include a pressure roll 88 (an example of a second rotating body) arranged so as to be. Then, for example, a sandwiching region N (nip portion) is formed at the contact portion between the heating belt 84 (fixing belt module 86) and the pressure roll 88. In the sandwiching region N, the paper K (an example of a recording medium) is pressurized and heated to fix the toner image.

In the fixing belt module 86, for example, an endless heating belt 84 and a heating belt 84 are wound on the pressure roll 88 side, and the heating belt 84 is rotationally driven by the rotational force of a motor (not shown) and the heating belt 84 is rotated around the inner circumference thereof. It includes a heating and pressing roll 89 that presses from the surface toward the pressing roll 88 side, and a supporting roll 90 that supports the heating belt 84 from the inside at a position different from that of the heating and pressing roll 89.
The fixing belt module 86 is, for example, a support roll 92 that is arranged outside the heating belt 84 and defines a circuit path thereof, and a posture correction roll 94 that corrects the posture of the heating belt 84 from the heating pressing roll 89 to the supporting roll 90. And a support roll 98 that applies tension to the heating belt 84 from the inner peripheral surface on the downstream side of the sandwiching region N formed by the heating belt 84 and the pressure roll 88.

The fixing belt module 86 is provided, for example, so that a sheet-shaped sliding member 82 is interposed between the heating belt 84 and the heating pressing roll 89.
The sliding member 82 is provided, for example, so that its sliding surface is in contact with the inner peripheral surface of the heating belt 84, and is involved in the holding and supply of oil existing between the sliding member 82 and the heating belt 84.
Here, the sliding member 82 is provided, for example, in a state where both ends thereof are supported by the support member 96.

Inside the heating pressing roll 89, for example, a halogen heater 89A (an example of heating means) is provided.

The support roll 90 is, for example, a cylindrical roll made of aluminum, and a halogen heater 90A (an example of heating means) is disposed inside, so that the heating belt 84 is heated from the inner peripheral surface side. It has become.
At both ends of the support roll 90, for example, spring members (not shown) that press the heating belt 84 outward are arranged.

The support roll 92 is, for example, a cylindrical roll made of aluminum, and a release layer made of a fluororesin having a thickness of 20 μm is formed on the surface of the support roll 92.
The release layer of the support roll 92 is formed, for example, to prevent toner and paper dust from the outer peripheral surface of the heating belt 84 from accumulating on the support roll 92.
For example, a halogen heater 92A (an example of heating means) is arranged inside the support roll 92 so that the heating belt 84 is heated from the outer peripheral surface side.

That is, for example, the heating belt 84 is heated by the heating pressing roll 89, the support roll 90, and the support roll 92.

The posture correction roll 94 is, for example, a columnar roll made of aluminum, and an end position measurement mechanism (not shown) for measuring the end position of the heating belt 84 is arranged in the vicinity of the posture correction roll 94. ing.
The posture correction roll 94 is provided with, for example, an axial displacement mechanism (not shown) that displaces the contact position of the heating belt 84 in the axial direction according to the measurement result of the end position measuring mechanism, and causes the heating belt 84 to meander. It is configured to control.

On the other hand, the pressure roll 88 is provided, for example, by being rotatably supported and by being pressed against a portion where the heating belt 84 is wound around the heating pressing roll 89 by an urging means such as a spring (not shown). As a result, as the heating belt 84 (heating pressing roll 89) of the fixing belt module 86 rotates in the direction of arrow S, the pressing roll 88 follows the heating belt 84 (heating pressing roll 89) and moves by arrow R. It is designed to rotate and move in the direction.

Then, the paper K having the unfixed toner image (not shown) is conveyed in the direction of the arrow P and guided to the sandwiching region N of the fixing device 80. Then, when the paper K passes through the sandwiching region N, the unfixed toner image on the paper K is fixed by the pressure and heat acting on the sandwiching region N.

In the fixing device 80 according to the second embodiment, a mode in which a halogen heater (halogen lamp) is applied as an example of a plurality of heating means has been described, but the present invention is not limited to this, and a radiant lamp heating element (radiation) other than the halogen heater is described. A heating element that emits (infrared rays, etc.)) and a resistance heating element (heating element that generates Joule heat by passing an electric current through the resistor: for example, a ceramic substrate formed with a film having resistance and fired) are applied. You may.

[Image forming device]
Next, the image forming apparatus according to this embodiment will be described.
The image forming apparatus according to the present embodiment includes an image holder, a charging means for charging the surface of the image holder, and an electrostatic latent image forming means for forming an electrostatic latent image on the surface of the charged image holder. A developing means for developing an electrostatic latent image formed on the surface of an image holder with a developer containing toner to form a toner image, a transfer means for transferring the toner image to the surface of a recording medium, and a toner image. A fixing means for fixing to a recording medium is provided.
Then, as the fixing means, the fixing device according to the present embodiment is applied.

Here, in the image forming apparatus according to the present embodiment, the fixing device may be made into a cartridge so as to be attached to and detached from the image forming apparatus. That is, the image forming apparatus according to the present embodiment may include the fixing device according to the present embodiment as a constituent device of the process cartridge.

Hereinafter, the image forming apparatus according to the present embodiment will be described with reference to the drawings.
FIG. 4 is a schematic configuration diagram showing the configuration of the image forming apparatus according to the present embodiment.

As shown in FIG. 4, the image forming apparatus 100 according to the present embodiment is, for example, an intermediate transfer type image forming apparatus generally called a tandem type, and a plurality of toner images of each color component are formed by an electrophotographic method. Image forming units 1Y, 1M, 1C, 1K, and a primary transfer unit 10 for sequentially transferring (primary transfer) each color component toner image formed by each image forming unit 1Y, 1M, 1C, 1K to an intermediate transfer belt 15. , A secondary transfer unit 20 that collectively transfers (secondary transfer) the superimposed toner image transferred on the intermediate transfer belt 15 to paper K, which is a recording medium, and fixing that fixes the secondary transferred image on paper K. The device 60 and the like are provided. Further, the image forming apparatus 100 has a control unit 40 that controls the operation of each device (each unit).

The fixing device 60 is the fixing device 60 according to the first embodiment described above. The image forming apparatus 100 may be configured to include the fixing apparatus 80 according to the second embodiment described above.

Each image forming unit 1Y, 1M, 1C, 1K of the image forming apparatus 100 includes a photoconductor 11 that rotates in the direction of arrow A as an example of an image holder that holds a toner image formed on the surface.

A charger 12 for charging the photoconductor 11 is provided around the photoconductor 11 as an example of the charging means, and a laser exposure device for writing an electrostatic latent image on the photoconductor 11 as an example of the latent image forming means. 13 (the exposure beam in the figure is indicated by the reference numeral Bm) is provided.

Further, around the photoconductor 11, as an example of the developing means, a developer 14 in which each color component toner is accommodated and the electrostatic latent image on the photoconductor 11 is visualized by the toner is provided, and the photoconductor 11 is provided. A primary transfer roll 16 for transferring each color component toner image formed above to the intermediate transfer belt 15 by the primary transfer unit 10 is provided.

Further, a photoconductor cleaner 17 for removing residual toner on the photoconductor 11 is provided around the photoconductor 11, and a charger 12, a laser exposure device 13, a developing device 14, a primary transfer roll 16, and a photoconductor cleaner are provided. 17 electrophotographic devices are sequentially arranged along the rotation direction of the photoconductor 11. These image forming units 1Y, 1M, 1C, and 1K are arranged substantially linearly in the order of yellow (Y), magenta (M), cyan (C), and black (K) from the upstream side of the intermediate transfer belt 15. Has been done.

The intermediate transfer belt 15 which is an intermediate transfer body is composed of a film-shaped pressure belt in which a resin such as polyimide or polyamide is used as a base layer and an appropriate amount of an antistatic agent such as carbon black is contained. Then, the volume resistivity is formed so as to be 10 ⁶ [Omega] cm or more ^{10 14} [Omega] cm or less, a thickness of, for example, are configured in approximately 0.1 mm.

The intermediate transfer belt 15 is circulated (rotated) by various rolls in the B direction shown in FIG. 4 at a speed suitable for the purpose. These various rolls include a drive roll 31 that is driven by a motor (not shown) having excellent constant speed to rotate the intermediate transfer belt 15, and an intermediate transfer belt 15 that extends substantially linearly along the arrangement direction of each photoconductor 11. The support roll 32 that supports the intermediate transfer belt 15, the tension applying roll 33 that applies tension to the intermediate transfer belt 15 and functions as a correction roll that prevents the intermediate transfer belt 15 from meandering, the back roll 25 provided on the secondary transfer portion 20, and the back roll 25. The intermediate transfer belt 15 has a cleaning back roll 34 provided in a cleaning portion for scraping off residual toner.

The primary transfer unit 10 is composed of a primary transfer roll 16 arranged so as to face the photoconductor 11 with the intermediate transfer belt 15 interposed therebetween. The primary transfer roll 16 is composed of a core body and a sponge layer as an elastic layer fixed around the core body. The core body is a cylindrical rod made of a metal such as iron or SUS. The sponge layer is formed of a blended rubber of NBR, SBR, and EPDM containing a conductive agent such as carbon black, and is a sponge-like cylindrical roll having ^{a volume resistivity of 10 7.5} Ωcm or more and 10 ^{8.5 Ω cm or less.}

Then, the primary transfer roll 16 is pressure-welded to the photoconductor 11 with the intermediate transfer belt 15 interposed therebetween, and the primary transfer roll 16 has a voltage (primary) opposite to that of the toner charging polarity (minus polarity; the same applies hereinafter). Transfer bias) is applied. As a result, the toner images on the respective photoconductors 11 are sequentially electrostatically attracted to the intermediate transfer belt 15, and the superimposed toner images are formed on the intermediate transfer belt 15.

The secondary transfer unit 20 includes a back surface roll 25 and a secondary transfer roll 22 arranged on the toner image holding surface side of the intermediate transfer belt 15.

The back roll 25 is composed of a tube of EPDM and NBR blended rubber whose surface is dispersed with carbon, and EPDM rubber inside. Then, the surface resistivity is ^{formed to be 10 7} Ω / □ or more and 10 ¹⁰ Ω / □ or less, and the hardness is set to, for example, 70 ° (Asker C: manufactured by Polymer Instruments Co., Ltd., the same applies hereinafter). NS. The back surface roll 25 is arranged on the back surface side of the intermediate transfer belt 15 to form a counter electrode of the secondary transfer roll 22, and a metal feeding roll 26 to which the secondary transfer bias is stably applied is contact-arranged. ing.

On the other hand, the secondary transfer roll 22 is composed of a core body and a sponge layer as an elastic layer fixed around the core body. The core body is a cylindrical rod made of a metal such as iron or SUS. The sponge layer is formed of a blended rubber of NBR, SBR, and EPDM containing a conductive agent such as carbon black, and is a sponge-like cylindrical roll having ^{a volume resistivity of 10 7.5} Ωcm or more and 10 ^{8.5 Ω cm or less.}

Then, the secondary transfer roll 22 is pressure-welded to the back surface roll 25 with the intermediate transfer belt 15 interposed therebetween, and the secondary transfer roll 22 is grounded to form a secondary transfer bias with the back surface roll 25. The toner image is secondarily transferred onto the paper K conveyed to the next transfer unit 20.

Further, on the downstream side of the secondary transfer portion 20 of the intermediate transfer belt 15, an intermediate transfer belt that removes residual toner and paper dust on the intermediate transfer belt 15 after the secondary transfer and cleans the surface of the intermediate transfer belt 15. The cleaner 35 is provided so as to be detachable from the intermediate transfer belt 15.

The intermediate transfer belt 15, the primary transfer unit 10 (primary transfer roll 16), and the secondary transfer unit 20 (secondary transfer roll 22) correspond to an example of the transfer means.

On the other hand, on the upstream side of the yellow image forming unit 1Y, a reference sensor (home position sensor) 42 that generates a reference signal as a reference for taking the image forming timing in each image forming unit 1Y, 1M, 1C, 1K is provided. It is arranged. The reference sensor 42 recognizes a mark provided on the back side of the intermediate transfer belt 15 and generates a reference signal. According to an instruction from the control unit 40 based on the recognition of the reference signal, each image forming unit 1Y, 1M, 1C, 1K are configured to initiate image formation.
Further, an image density sensor 43 for adjusting the image quality is arranged on the downstream side of the black image forming unit 1K.

Further, in the image forming apparatus according to the present embodiment, as a transporting means for transporting the paper K, the paper accommodating unit 50 accommodating the paper K and the paper K accumulated in the paper accommodating unit 50 are taken out at a predetermined timing. The paper feed roll 51 that conveys the paper K, the transfer roll 52 that conveys the paper K fed by the paper feed roll 51, the transfer guide 53 that feeds the paper K conveyed by the transfer roll 52 to the secondary transfer unit 20, and the secondary transfer. It includes a transport belt 55 that transports the paper K that is secondarily transferred by the roll 22 to the fixing device 60, and a fixing inlet guide 56 that guides the paper K to the fixing device 60.

Next, the basic image forming process of the image forming apparatus according to the present embodiment will be described.
In the image forming apparatus according to the present embodiment, the image data output from an image reading device (not shown), a personal computer (PC) (not shown), or the like is subjected to image processing by an image processing device (not shown), and then the image forming unit 1Y. , 1M, 1C, 1K perform the image drawing work.

The image processing device performs image processing such as shading correction, position shift correction, brightness / color space conversion, gamma correction, frame erasing and color editing, and various image editing such as movement editing on the input reflectance data. Will be done. The image data that has undergone image processing is converted into color material gradation data of four colors Y, M, C, and K, and is output to the laser exposure device 13.

In the laser exposure device 13, for example, the exposure beam Bm emitted from the semiconductor laser is irradiated to each of the photoconductors 11 of the image forming units 1Y, 1M, 1C, and 1K according to the input color material gradation data. .. In each of the photoconductors 11 of the image forming units 1Y, 1M, 1C, and 1K, after the surface is charged by the charger 12, the surface is scanned and exposed by the laser exposure device 13, and an electrostatic latent image is formed. The formed electrostatic latent image is developed as a toner image of each color of Y, M, C, and K by the respective image forming units 1Y, 1M, 1C, and 1K.

The toner image formed on the photoconductors 11 of the image forming units 1Y, 1M, 1C, and 1K is transferred onto the intermediate transfer belt 15 in the primary transfer unit 10 in which each photoconductor 11 and the intermediate transfer belt 15 come into contact with each other. NS. More specifically, in the primary transfer unit 10, the primary transfer roll 16 applies a voltage (primary transfer bias) opposite to the charging polarity (minus polarity) of the toner to the base material of the intermediate transfer belt 15, and the toner image. Is sequentially superposed on the surface of the intermediate transfer belt 15 to perform the primary transfer.

After the toner image is sequentially primary-transferred to the surface of the intermediate transfer belt 15, the intermediate transfer belt 15 moves and the toner image is conveyed to the secondary transfer unit 20. When the toner image is conveyed to the secondary transfer unit 20, the transfer means rotates the paper feed roll 51 in accordance with the timing at which the toner image is conveyed to the secondary transfer unit 20, and the target is from the paper storage unit 50. Paper K of size is supplied. The paper K supplied by the paper feed roll 51 is conveyed by the transfer roll 52 and reaches the secondary transfer unit 20 via the transfer guide 53. Before reaching the secondary transfer unit 20, the paper K is temporarily stopped, and the alignment roll (not shown) rotates according to the movement timing of the intermediate transfer belt 15 on which the toner image is held, so that the paper K is formed. Is aligned with the position of the toner image.

In the secondary transfer unit 20, the secondary transfer roll 22 is pressed against the back roll 25 via the intermediate transfer belt 15. At this time, the paper K conveyed at the same timing is sandwiched between the intermediate transfer belt 15 and the secondary transfer roll 22. At that time, when a voltage (secondary transfer bias) having the same polarity as the charging polarity (minus polarity) of the toner is applied from the power feeding roll 26, a transfer electric field is formed between the secondary transfer roll 22 and the back surface roll 25. Will be done. Then, the unfixed toner image held on the intermediate transfer belt 15 is electrostatically transferred onto the paper K collectively in the secondary transfer unit 20 pressurized by the secondary transfer roll 22 and the back surface roll 25. NS.

After that, the paper K on which the toner image is electrostatically transferred is conveyed as it is in a state of being peeled off from the intermediate transfer belt 15 by the secondary transfer roll 22, and is provided on the downstream side of the secondary transfer roll 22 in the paper transfer direction. It is transported to the belt 55. The transport belt 55 transports the paper K to the fixing device 60 according to the optimum transport speed in the fixing device 60. The unfixed toner image on the paper K conveyed to the fixing device 60 is fixed on the paper K by being subjected to a fixing process by heat and pressure by the fixing device 60. Then, the paper K on which the fixed image is formed is conveyed to a paper ejection accommodating portion (not shown) provided in the ejection unit of the image forming apparatus.

On the other hand, after the transfer to the paper K is completed, the residual toner remaining on the intermediate transfer belt 15 is conveyed to the cleaning section as the intermediate transfer belt 15 rotates, and is conveyed by the cleaning back roll 34 and the intermediate transfer belt cleaner 35. It is removed from the intermediate transfer belt 15.

Although the present embodiment has been described above, the present embodiment is not limited to the above embodiment, and various modifications, changes, and improvements can be made.

Hereinafter, the present invention will be specifically described with reference to embodiments. However, the present invention is not limited to the following embodiments.

[Example 1]
-Preparation of base material A polyimide resin base material having a thickness of 65 μm and an outer diameter of 30.0 mm was prepared. Then, a product name: PRIMER-No32 manufactured by Shin-Etsu Chemical Co., Ltd. was prepared as an adhesive, and the polyimide resin base material provided with an adhesive layer was coated on the outer peripheral surface of the polyimide resin so as to have a thickness of 1.0 μm. Base material) was prepared.

-Elastic layer As a silicone rubber material, a second polysiloxane having a product name: X34-2086 solution A and solution B (solution A: vinyl group (-CH = CH ₂ )) manufactured by Shin-Etsu Chemical Co., Ltd., and a catalyst (platinum). ), Solution B: a first polysiloxane having a hydrogen-bonded silyl group (-SiH) and a second polysiloxane having a vinyl group (-CH = CH ₂ )) were prepared.
The liquid A and the liquid B were mixed at a ratio (liquid A: liquid B (mass ratio)) 1: 1 to obtain a coating liquid for forming an elastic layer. The amount ratio (mol ratio) of the vinyl group and the hydrogen-bonded silyl group in this coating liquid was measured by the above-mentioned method. The measurement results are shown in Table 1.
This coating liquid was applied to the surface of the polyimide resin base material (adhesive layer) and heated at 120 ° C. for 15 minutes to form an elastic layer.

-A fluororesin tube made from a surface layer PFA (451HP-J manufactured by Mitsui DuPont Fluorochemical Co., Ltd.) was molded by injection molding.
Next, the inner surface of the fluororesin tube was subjected to plasma treatment.
Specifically, an applied voltage of 10 kV, a frequency of 18 kHz, and a mixed gas of excitation gas (Ar) and dichlorosilane were used from the discharge electrode, and the flow rate was 1 L / min. Dichlorosilane was vaporized by bubbling and mixed with the excitation gas. The plasma treatment time was set to 10 seconds, and a fluororesin tube having an outer diameter of 29.3 mm and a wall thickness of 30 μm was obtained.

This fluororesin tube was coated on an elastic layer and fired at 200 ° C. for 2 hours to obtain a fixing belt.

[Example 2]
In Example 1, except that the ratio of liquid A and liquid B (liquid A: liquid B (mass ratio)) of liquid X34-2086 at the time of forming the elastic layer was changed to that shown in Table 1 below. A fixing belt of Example 2 was obtained in the same manner as in Example 1.

[Example 3 and Example 4]
In Example 1, solutions A and B of X34-2086 at the time of forming the elastic layer were used as solutions A and B of product name: X34-1053 manufactured by Shin-Etsu Chemical Co., Ltd. (Liquid A: vinyl group (-CH =). Liquid B containing a second polysiloxane having CH ₂ ) and a catalyst (platinum): having a first polysiloxane having a hydrogen-bonded silyl group (-SiH) and a vinyl group (-CH = CH ₂ ). In place of the second polysiloxane), the ratio of the liquid A and the liquid B (solution A: liquid B (mass ratio)) was set to the value shown in Table 1 below, except that the ratio was the same as that of Example 1. Similarly, the fixing belts of Examples 3 and 4 were obtained.

[Example 5]
In Example 3, the ratio of the liquid A and the liquid B (liquid A: liquid B (mass ratio)) of X34-1053 at the time of forming the elastic layer was changed to the value shown in Table 1 below, and further, the surface layer was further changed. A fixing belt of Example 5 was obtained in the same manner as in Example 3 except that the dichlorosilane used for the plasma treatment was replaced with trichlorosilane.

[Comparative Example 1]
A fixing belt of Comparative Example 1 was obtained in the same manner as in Example 5 except that the surface layer was not subjected to plasma treatment.

[evaluation]

(Presence / absence of SiH group)
For each of the inner surfaces of the surface layers obtained in Examples and Comparative Examples, the presence or absence of SiH groups was confirmed by the method described in the above-mentioned "Method for confirming whether or not SiH groups were introduced into the inner surface of the surface layer".

(Peeling test)
Each fixing belt obtained in Examples and Comparative Examples was stored in an environment of 90 ° C. and 85% RH for 5 days. Next, a 20 mm wide notch is made in the surface layer of the fixing belt in the circumferential direction, the surface layer and the elastic layer are held, and the surface layer is pulled toward the outside of the fixing belt (in the direction away from the core metal side) in the 90 ° direction. Therefore, a peeling test was carried out.
The degree of peeling at the interface between the elastic layer and the surface layer (ratio of the area of the peeled area to the total area (%)) was evaluated. More specifically, it was confirmed whether or not the elastic layer remained on the peeled surface layer, and the area where the elastic layer remained was calculated.
The evaluation criteria are as follows.
A (○): Peeling occurrence area less than 0.1% B (Δ): Peeling occurrence area 0.1% or more and less than 10% (substantially no problem level)
C (x): Peeling occurrence area 10% or more

(An endurance test)
Each fixing belt obtained in Examples and Comparative Examples was stored in an environment of 90 ° C. and 85% RH for 5 days. Next, the fixing belt was attached to the fixing device of the image forming apparatus "DocuCenter-VI C5571 PFS (manufactured by Fuji Xerox Co., Ltd.)".
Using this image forming apparatus, 1,000 halftone images having an image density of 50% were output on A4 cardboard (Ncolor 209 basis weight 209 g / square meter).
Then, the fixing belt was observed, and the presence or absence of peeling of the surface layer was visually observed.
The state of peeling of the surface layer was evaluated according to the following evaluation criteria.
A (○): No peeling of surface layer B (×): With peeling of surface layer

(Fixability test using uneven paper)
Each of the fixing belts obtained in Examples and Comparative Examples was attached to the fixing device of the image forming device "DocuCenter-VI C5571 PFS (manufactured by Fuji Xerox Co., Ltd.)".
Using this image forming apparatus, one halftone image with an image density of 50% is output on A4 concavo-convex paper (Rezac 66 basis weight: 151 grams / square meter), and the state of toner adhesion in the paper recesses is shown below with a microscope. It was evaluated according to the evaluation criteria of.
A (○): No toner missing in the paper recess B (△): Toner is present in the paper recess, but the concentration is low (substantially no problem)
C (x): Toner is clearly missing in the paper recess, and white is missing.

From the above results, it can be seen that in this example, as compared with the comparative example, peeling at the interface between the surface layer and the elastic layer is suppressed even if compression deformation and release are repeated.
In particular, since the peeling of the interface is suppressed as described above even after storage in a high temperature and high humidity environment, it can be seen that the fixing belt of this example has high adhesive resistance to humidity.
Further, it can be seen that Examples 1 and 2 are excellent in fixability when uneven paper is applied.

62 Pressurized belt 63 Belt running guide 64 Pressing pad 64a Front sandwiching member 64b Peeling pinching member 65 Holding member 66 Halogen lamp 68 Sliding member 69 Temperature sensitive element 70 Peeling member 71 Peeling claw 72 Holding member 80 Fixing device 82 Sliding Member 84 Heating belt 86 Fixing belt module 88 Pressurizing roll 89A Halogen heater 89 Heating pressing roll 90A Halogen heater 90 Supporting roll 92A Halogen heater 92 Supporting roll 94 Posture correction roll 96 Supporting member 98 Supporting roll 100 Image forming device 110 Fixing member 110A base Material 110B Elastic layer 110C Surface layer

Claims (10)

Base material,
An elastic layer arranged on the substrate and containing a polymer of a first polysiloxane having a hydrogen-bonded silyl group in which a hydrogen atom is bonded to a silicon atom and a second polysiloxane having a vinyl group, and
A surface layer that is arranged in contact with the elastic layer and has a hydrogen-bonded silyl group on the surface on the side that contacts the elastic layer.
With
The interface between the surface layer and the elastic layer, have a covalent bond with the vinyl group of the elastic layer and the hydrogen bond silyl groups of the surface layer has reacted,
The surface layer is a tetrafluoroethylene / perfluoroalkyl vinyl ether copolymer (PFA), polytetrafluoroethylene (PTFE), tetrafluoroethylene / hexafluoropropylene copolymer (FEP), polyethylene / tetrafluoroethylene copolymer. A fixing member , which is a resin layer containing a fluororesin selected from (ETFE), polyvinylidene fluoride (PVDF), polychlorotrifluoroethylene (PCTFE), and polyvinyl fluoride (PVF). The fixing member according to claim 1 , wherein the surface layer is a layer in which a resin tubular body containing the fluororesin is covered with the elastic layer. Base material,
An elastic layer arranged on the substrate and containing a polymer of a first polysiloxane having a hydrogen-bonded silyl group in which a hydrogen atom is bonded to a silicon atom and a second polysiloxane having a vinyl group, and
A surface layer that is arranged in contact with the elastic layer and has a hydrogen-bonded silyl group on the surface on the side that contacts the elastic layer.
With
The interface between the elastic layer and the surface layer has a covalent bond in which the vinyl group of the elastic layer and the hydrogen-bonded silyl group of the surface layer have reacted.
A fixing member in which the surface layer is a resin layer containing a fluororesin, and the elastic layer is covered with a resin tubular body containing the fluororesin. Any one of claims 1 to 3, wherein the content of the vinyl group [v (mol)] is larger than the content of the hydrogen-bonded silyl group [s (mol)] before the polymer is formed. The fixing member according to the section. The ratio [s: v (mol ratio)] of the content [s (mol)] of the hydrogen-bonded silyl group to the content [v (mol)] of the vinyl group before becoming the polymer is 1: The fixing member according to claim 4, which is in the range of 1.4 to 1: 2.2. Any one of claims 1 to 3 in which the content [s (mol)] of the hydrogen-bonded silyl group is larger than the content [v (mol)] of the vinyl group before becoming the polymer. The fixing member according to the section. The ratio [v: s (mol ratio)] of the vinyl group content [v (mol)] to the hydrogen-bonded silyl group content [s (mol)] before the polymer is formed is 1: The fixing member according to claim 6, which is in the range of 1.1 to 1: 2.2. A first rotating body and a second rotating body arranged in contact with the outer surface of the first rotating body are provided.
At least one of the first rotating body and the second rotating body is the fixing member according to any one of claims 1 to 7.
A fixing device for fixing the toner image by inserting a recording medium having a toner image formed on the surface into a contact portion between the first rotating body and the second rotating body. The fixing device according to claim 8 is provided.
A process cartridge that can be attached to and detached from the image forming device. Image holder and
A charging means for charging the surface of the image holder and
An electrostatic latent image forming means for forming an electrostatic latent image on the surface of the charged image holder,
A developing means for developing an electrostatic latent image formed on the surface of the image holder with a developer containing toner to form a toner image, and a developing means.
A transfer means for transferring the toner image to the surface of a recording medium, and
A fixing means for fixing the toner image to the recording medium, the fixing means having the fixing device according to claim 8.
An image forming apparatus comprising.

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