JP6918408B2 - Oil and fat manufacturing method - Google Patents

Oil and fat manufacturing method Download PDF

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JP6918408B2
JP6918408B2 JP2015186448A JP2015186448A JP6918408B2 JP 6918408 B2 JP6918408 B2 JP 6918408B2 JP 2015186448 A JP2015186448 A JP 2015186448A JP 2015186448 A JP2015186448 A JP 2015186448A JP 6918408 B2 JP6918408 B2 JP 6918408B2
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雅典 川原
雅典 川原
祐三 山田
祐三 山田
竜一郎 野上
竜一郎 野上
茂雄 竹内
茂雄 竹内
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株式会社J−オイルミルズ
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Description

本発明は、食品の異風味の抑制、または、食品の甘味の増強をする油脂の製造方法に関する。 The present invention relates to a method for producing fats and oils that suppresses the off-flavor of foods or enhances the sweetness of foods.

魚類等の水産動物には、ドコサヘキサエン酸(DHA)やエイコサペンタエン酸(EPA)等の高度不飽和脂肪酸が含まれている。これらの高度不飽和脂肪酸は、さまざまな生理活性を有することで注目されている。一方、魚類等の水産物は、これら高度不飽和脂肪酸や低級アミン等に由来すると考えられている特有の不快臭(魚臭)を有している。そのため、魚類等の水産物を含む食品では魚臭が問題となっている。
また、大豆タンパク質を含む食肉使用食品(ハンバーグやミートボール等)では、大豆タンパク質由来の不快な臭いや風味が問題となっている。
Aquatic animals such as fish contain highly unsaturated fatty acids such as docosahexaenoic acid (DHA) and eicosapentaenoic acid (EPA). These highly unsaturated fatty acids are attracting attention because they have various physiological activities. On the other hand, marine products such as fish have a peculiar unpleasant odor (fish odor) which is considered to be derived from these highly unsaturated fatty acids and lower amines. Therefore, fish odor has become a problem in foods containing marine products such as fish.
Further, in meat-based foods containing soybean protein (hamburger steak, meatballs, etc.), an unpleasant odor and flavor derived from soybean protein have become a problem.

上記課題を解決するために、特許文献1(特開2001−131575)では、ショウガオイルやショウガ調香料を水産動物油脂に添加することで臭気をマスキングすることが提案されている。また、特許文献2(特開2011−4699)では、大豆タンパク質を含む食肉使用食品に天然甘味料であるソーマチンを添加することで大豆タンパク質の不快な味をマスキングできることが開示されている。 In order to solve the above problems, Patent Document 1 (Japanese Patent Laid-Open No. 2001-131575) proposes masking odor by adding ginger oil or ginger flavoring agent to aquatic animal fats and oils. Further, Patent Document 2 (Japanese Unexamined Patent Publication No. 2011-4499) discloses that the unpleasant taste of soybean protein can be masked by adding thaumatin, which is a natural sweetener, to a meat-using food containing soybean protein.

一方、レシチンは大豆等から油脂を精製する際に副産物として抽出される。レシチンは離型性を有する乳化剤である。そのため、レシチンを油脂に配合することで、離型性を高めた炒め用の油脂組成物等を作ることができる(特許文献3、4)。 On the other hand, lecithin is extracted as a by-product when refining fats and oils from soybeans and the like. Lecithin is an emulsifier with releasability. Therefore, by blending lecithin with fats and oils, it is possible to prepare a fats and oils composition for stir-fry with improved releasability (Patent Documents 3 and 4).

このように、魚類等の水産動物や大豆タンパク質等を含む食品において、魚臭や大豆タンパク臭等の異風味を抑制することは試みられているが、レシチンを加工することにより、これらの異風味を抑制できること、また、甘味を増強できることは、これまで報告されていなかった。 As described above, attempts have been made to suppress off-flavors such as fish odor and soy protein odor in aquatic animals such as fish and foods containing soy protein, but these off-flavors are produced by processing lecithin. It has not been reported so far that it can suppress soybeans and enhance sweetness.

特開2001−131575号公報Japanese Unexamined Patent Publication No. 2001-131575 特開2011−4699号公報Japanese Unexamined Patent Publication No. 2011-4699 特開2009−39021号公報Japanese Unexamined Patent Publication No. 2009-39021 特開2013−81475号公報Japanese Unexamined Patent Publication No. 2013-81475

このように、魚類等の水産動物の魚臭等、大豆タンパク質のタンパク臭、静菌剤などに由来する酸臭等あるいはレトルト食品のレトルト臭等の異風味は食品の価値を貶める。そこで、本発明では、食品の異風味の抑制、または、食品の甘味の増強、をする油脂の製造方法を提供することを目的とする。 As described above, the fish odor of aquatic animals such as fish, the protein odor of soy protein, the acid odor derived from bacteriostatic agents, and the unusual flavor such as the retort odor of retort pouch foods detract from the value of the food. Therefore, an object of the present invention is to provide a method for producing fats and oils, which suppresses the off-flavor of foods or enhances the sweetness of foods.

本発明者らは、鋭意研究の結果、レシチン含有油脂を加熱処理することにより得られる油脂が食品の異風味を抑制でき、また、食品の甘味を増強できることを見出した。 As a result of diligent research, the present inventors have found that the fat and oil obtained by heat-treating the lecithin-containing fat and oil can suppress the off-flavor of the food and enhance the sweetness of the food.

すなわち、本発明は、レシチン含有油脂を加熱して得られる油脂の製造方法であって、レシチン含有油脂を70℃以上160℃以下の温度で加熱処理する加熱工程を含む前記製造方法である。 That is, the present invention is a method for producing a fat or oil obtained by heating a lecithin-containing fat or oil, which comprises a heating step of heat-treating the lecithin-containing fat or oil at a temperature of 70 ° C. or higher and 160 ° C. or lower.

さらに、前記加熱工程の加熱処理する時間が、0.5時間以上240時間以下であることが好ましい。 Further, the heat treatment time in the heating step is preferably 0.5 hours or more and 240 hours or less.

さらに、前記レシチン含有油脂の加熱処理後の400nmの吸光度から加熱処理前の400nmの吸光度を引いた値が0.1以上4以下であることが好ましい。 Further, it is preferable that the value obtained by subtracting the absorbance at 400 nm before the heat treatment from the absorbance at 400 nm after the heat treatment of the lecithin-containing fat and oil is 0.1 or more and 4 or less.

さらに、前記レシチン含有油脂のレシチン含有量が0.01質量%以上20質量%以下であることが好ましい。 Further, the lecithin content of the lecithin-containing fat and oil is preferably 0.01% by mass or more and 20% by mass or less.

さらに、食用油脂にレシチンを添加し、レシチン含有油脂を調製する工程を含むことが好ましい。 Further, it is preferable to include a step of adding lecithin to edible fats and oils to prepare lecithin-containing fats and oils.

また、本発明は、レシチン含有油脂を70℃以上160℃以下の温度で加熱処理する加熱工程を含む製造方法で得られた油脂を食用油脂に添加する工程を含む、油脂組成物の製造方法である。 Further, the present invention is a method for producing an oil / fat composition, which comprises a step of adding an oil / fat obtained by a production method including a heating step of heat-treating a lecithin-containing oil / fat at a temperature of 70 ° C. or higher and 160 ° C. or lower to an edible oil / fat. be.

さらに、加熱処理前のレシチンが0.01質量%以上20質量%以下になるように前記油脂を添加することが好ましい。 Further, it is preferable to add the fats and oils so that the lecithin before the heat treatment is 0.01% by mass or more and 20% by mass or less.

また、本発明は、レシチン含有油脂を70℃以上160℃以下の温度で加熱処理する加熱工程を含む製造方法で得られた油脂を食品に添加する工程を含む、食品の製造方法である。 Further, the present invention is a method for producing a food product, which comprises a step of adding the fat or oil obtained by a production method including a heating step of heat-treating a lecithin-containing fat or oil at a temperature of 70 ° C. or higher and 160 ° C. or lower to a food product.

さらに、加熱処理前のレシチンが0.01ppm以上5000ppm以下になるように前記油脂を食品に添加することが好ましく、0.05ppm以上4000ppm以下がより好ましい。 Further, it is preferable to add the fat and oil to the food so that the lecithin before the heat treatment is 0.01 ppm or more and 5000 ppm or less, and more preferably 0.05 ppm or more and 4000 ppm or less.

また、本発明は、レシチン含有油脂を70℃以上160℃以下の温度で加熱処理する加熱工程を含む製造方法で得られた油脂を食品に添加することを特徴とする食品の異風味を抑制する方法である。 Further, the present invention suppresses the off-flavor of foods, which is characterized by adding fats and oils obtained by a production method including a heating step of heat-treating lecithin-containing fats and oils at a temperature of 70 ° C. or higher and 160 ° C. or lower. The method.

さらに、前記異風味が魚臭、タンパク臭、酸味、酸臭およびレトルト臭のいずれか1種又は2種以上であることが好ましい。なお、レトルト臭とは、食品を密封容器に入れ加圧加熱殺菌処理を行った際に生じる不快臭のことである。 Further, it is preferable that the off-flavor is any one or more of fish odor, protein odor, acidity, acid odor and retort odor. The retort odor is an unpleasant odor generated when food is placed in a sealed container and subjected to pressure heat sterilization treatment.

また、本発明は、レシチン含有油脂を70℃以上160℃以下の温度で加熱処理する加熱工程を含む製造方法で得られた油脂を食品に添加することを特徴とする食品の甘味を増強する方法である。 Further, the present invention is a method for enhancing the sweetness of a food, which comprises adding the fat or oil obtained by a production method including a heating step of heat-treating the lecithin-containing fat or oil at a temperature of 70 ° C. or higher and 160 ° C. or lower to the food. Is.

本発明の製造方法で得られる油脂は、魚臭、タンパク臭、酸味、酸臭及びレトルト臭等の異風味を抑制し、また、食品の甘味を増強することができる。 The fats and oils obtained by the production method of the present invention can suppress unusual flavors such as fish odor, protein odor, acidity, acid odor and retort odor, and can enhance the sweetness of foods.

本発明において用いられるレシチンとしては、食品または食品添加物の分野で慣用的に用いられているレシチンを総称するものであって、大豆、菜種、コーン、ヒマワリ、パーム、落花生、米糠などを原料とした植物油精製時の副産物(例えば、脱ガム工程で発生する水和物)や卵黄などの粗原料から調製したペースト状レシチンや、この粗原料を溶剤で分別して得た分別レシチン、さらにこの粗原料を酵素処理して得た酵素分解レシチンなど、リン脂質を主成分とした混合物からなるレシチンである。好ましくはペースト状レシチンおよび分別レシチンから選ばれる1種または2種であり、より好ましくはペースト状レシチンである。
また、原料は特に問わないが、好ましくは大豆または米糠由来のレシチンであり、より好ましくは大豆由来のレシチンである。
また、レシチンの酸価は10以上40以下が好ましく、10以上35以下がより好ましく、10以上30以下がさらに好ましい。ここでいう酸価は、社団法人日本油化学会制定・基準油脂分析試験法(2.3.1−1996 酸価)に準じて測定されたものである。
The lecithin used in the present invention is a general term for lecithin commonly used in the field of foods or food additives, and is made from soybeans, rapeseed, corn, sunflower, palm, peanuts, rice bran and the like. Paste-like lecithin prepared from crude materials such as by-products (for example, hydrate generated in the degumming step) and egg yolk during purification of vegetable oil, fractionated lecithin obtained by separating this crude material with a solvent, and further this crude material. It is a lecithin composed of a mixture containing phospholipid as a main component, such as an enzymatically decomposed lecithin obtained by enzymatically treating. It is preferably one or two selected from paste-like lecithin and fractionated lecithin, and more preferably paste-like lecithin.
The raw material is not particularly limited, but is preferably soybean or rice bran-derived lecithin, and more preferably soybean-derived lecithin.
The acid value of lecithin is preferably 10 or more and 40 or less, more preferably 10 or more and 35 or less, and further preferably 10 or more and 30 or less. The acid value referred to here is measured according to the standard oil and fat analysis test method (2.3.1-1996 acid value) established by the Japan Oil Chemists' Society.

本発明で使用される食用油脂には、その種類には特に限定がなく食用油として用いられるものであればよい。具体例として、大豆油、菜種油、パーム油、コーン油、紅花油、ヒマワリ油、綿実油、米油、パーム核油、ヤシ油、オリーブ油、ごま油などの植物油脂並びに牛脂、豚脂等の動物脂、並びにこれらに分別、水素添加、エステル交換等を施した加工油脂の単品又は、これらの2種以上を混合したものが挙げられる。 The type of edible oil and fat used in the present invention is not particularly limited as long as it is used as edible oil. Specific examples include vegetable oils such as soybean oil, rapeseed oil, palm oil, corn oil, safflower oil, sunflower oil, cottonseed oil, rice oil, palm kernel oil, palm oil, olive oil and sesame oil, and animal fats such as beef tallow and lard. In addition, processed oils and fats that have been separated, hydrogenated, ester-exchanged, etc., or a mixture of two or more of these can be mentioned.

レシチン含有油脂の油脂としては、特に限定はなく、食用油として用いられるものであればよいが、大豆油、菜種油、コーン油、パーム油とその分別油、及び、綿実油のいずれか1種または2種以上が好ましく、大豆油、菜種油、コーン油、及び、パーム油とその分別油のいずれか1種または2種以上がより好ましく、大豆油、菜種油、及び、パームオレインのいずれか1種または2種以上がさらに好ましく、大豆油が最も好ましい。 The oil and fat of the lecithin-containing oil and fat is not particularly limited as long as it is used as an edible oil, but one or 2 of soybean oil, rapeseed oil, corn oil, palm oil and its fractionated oil, and cotton seed oil. Seeds or more are preferred, and any one or more of soybean oil, rapeseed oil, corn oil, and palm oil and its fractionated oil are more preferred, and any one or two of soybean oil, rapeseed oil, and palm olein. More than seeds are more preferred, and soybean oil is most preferred.

また、レシチン含有油脂は、食用油脂にレシチンを添加した油脂でもよく、レシチンが残存するように精製した油脂でもよい。レシチンの含有量の調整のしやすさの点で、好ましくは食用油脂にレシチンを添加したものがよい。レシチンの含有量は0.01質量%以上20質量%以下が好ましく、0.05質量%以上12質量%以下がより好ましく、0.05質量%以上10質量%以下がさらに好ましく、0.5質量%以上10質量%以下が特に好ましい。 Further, the lecithin-containing fat or oil may be a fat or oil obtained by adding lecithin to an edible fat or oil, or may be a fat or oil refined so that lecithin remains. From the viewpoint of ease of adjusting the content of lecithin, it is preferable to add lecithin to edible fats and oils. The content of lecithin is preferably 0.01% by mass or more and 20% by mass or less, more preferably 0.05% by mass or more and 12% by mass or less, further preferably 0.05% by mass or more and 10% by mass or less, and 0.5% by mass. % Or more and 10% by mass or less are particularly preferable.

レシチン含有油脂の加熱処理の温度は70℃以上160℃以下であり、好ましくは80℃以上140℃以下であり、より好ましくは90℃以上140℃以下であり、さらに好ましくは105℃以上140℃以下である。
また、加熱処理の時間は、好ましくは0.5時間以上240時間以下であり、より好ましくは2.5時間以上120時間以下であり、さらに好ましくは4時間以上80時間以下であり、最も好ましくは4.5時間以上50時間以下である。
The temperature of the heat treatment of the lecithin-containing fat and oil is 70 ° C. or higher and 160 ° C. or lower, preferably 80 ° C. or higher and 140 ° C. or lower, more preferably 90 ° C. or higher and 140 ° C. or lower, and further preferably 105 ° C. or higher and 140 ° C. or lower. Is.
The heat treatment time is preferably 0.5 hours or more and 240 hours or less, more preferably 2.5 hours or more and 120 hours or less, still more preferably 4 hours or more and 80 hours or less, and most preferably. It is 4.5 hours or more and 50 hours or less.

また、レシチン含有油脂の加熱処理は、レシチン含有油脂の400nmの吸光度に基づいておこなうことが好ましい。加熱処理後の400nmの吸光度から加熱処理前の400nmの吸光度を引いた値(加熱処理後の吸光度−加熱処理前の吸光度)が0.1以上4以下になるようにすることが好ましく、0.2以上4以下がより好ましく、0.3以上4以下がさらに好ましい。 Further, the heat treatment of the lecithin-containing fat or oil is preferably performed based on the absorbance of the lecithin-containing fat or oil at 400 nm. The value obtained by subtracting the absorbance at 400 nm before the heat treatment from the absorbance at 400 nm after the heat treatment (absorbance after the heat treatment-absorbance before the heat treatment) is preferably 0.1 or more and 4 or less. It is more preferably 2 or more and 4 or less, and further preferably 0.3 or more and 4 or less.

また、レシチン含有油脂の加熱方法は特に限定されず、通常油脂等の加熱に使用される方法を用いればよい。例えば、直火、電熱器、IHヒーター、オイルバス、蒸気、恒温槽などで加熱をすることができる。加熱時にレシチン含有油脂を撹拌することは必須ではないが、均一に加熱できるため撹拌することが好ましい。また、消泡を目的としてシリコーンを添加しても良い。 The method for heating the lecithin-containing fat or oil is not particularly limited, and the method usually used for heating the fat or oil may be used. For example, it can be heated by an open flame, an electric heater, an IH heater, an oil bath, steam, a constant temperature bath, or the like. It is not essential to stir the lecithin-containing fats and oils during heating, but it is preferable to stir because the lecithin-containing fats and oils can be heated uniformly. Further, silicone may be added for the purpose of defoaming.

また、レシチンの沈降防止として、ポリグリセリン縮合リシノレイン酸エステルやショ糖脂肪酸エステルを含有することが好ましい。 Further, in order to prevent the precipitation of lecithin, it is preferable to contain a polyglycerin condensed ricinoleic acid ester or a sucrose fatty acid ester.

本発明の油脂組成物の油脂含有量は、特に限定されないが、好ましくは50質量%以上であり、より好ましくは60質量%以上であり、さらに好ましくは80質量%以上である。特に上限はないが、レシチンと油脂の合計が100質量%以下である。前記油脂組成物は、レシチン含有油脂を加熱処理して得られる油脂を含有するが、レシチン含有油脂を加熱処理して得られる前記油脂の含有量は特に限定されず、100質量%であってもよい。
また、前記油脂組成物は、加熱処理前のレシチンが0.01質量%以上20質量%以下になるようにレシチン含有油脂を加熱処理して得られる前記油脂を含有することが好ましく、0.05質量%以上12質量%以下がより好ましく、0.05質量%以上8質量%以下がさらに好ましく、0.5質量%以上5質量%以下が特に好ましい。
The fat and oil content of the fat and oil composition of the present invention is not particularly limited, but is preferably 50% by mass or more, more preferably 60% by mass or more, and further preferably 80% by mass or more. There is no particular upper limit, but the total of lecithin and fats and oils is 100% by mass or less. The fat and oil composition contains a fat and oil obtained by heat-treating a lecithin-containing fat and oil, but the content of the fat and oil obtained by heat-treating the lecithin-containing fat and oil is not particularly limited and may be 100% by mass. good.
Further, the fat and oil composition preferably contains the fat and oil obtained by heat-treating the lecithin-containing fat and oil so that the lecithin before the heat treatment is 0.01% by mass or more and 20% by mass or less, preferably 0.05. It is more preferably mass% or more and 12 mass% or less, further preferably 0.05 mass% or more and 8 mass% or less, and particularly preferably 0.5 mass% or more and 5 mass% or less.

本発明の食品は、特に限定されないが、例えば、魚等の海産物、大豆タンパク質、酢、酸味料、pH調整剤、調味料等の異風味を生じやすいものを含む食品やレトルト食品である。また、甘味を有する食品である。例えば、魚等の海産物を含む食品としては、魚、イカ等の缶詰;焼魚、煮魚、蒸魚、揚魚、刺身およびそれらを含む食品などである。大豆タンパク質を含む食品としては、ハンバーグ、焼売、餃子、ハム、ソーセージ、蒲鉾、竹輪、菓子、パン、ミートソースなどである。また、酢、酸味料、pH調整剤、調味料を含む食品としては、米飯、炒飯、おにぎり等の米飯類;ドレッシング、マヨネーズ等のドレッシング類;マリネ;うどん、ラーメン等の麺類;サラダ;フィリング;パスタソースなどである。レトルト食品としてはレトルトカレー、レトルトパスタソース、レトルトおかゆなどである。 The food of the present invention is not particularly limited, and is, for example, a food or a retort food containing marine products such as fish, soy protein, vinegar, acidulants, pH adjusters, seasonings, and the like that are likely to cause off-flavors. It is also a food having a sweet taste. For example, foods containing marine products such as fish include canned fish, squid, etc .; grilled fish, boiled fish, steamed fish, fried fish, sashimi, and foods containing them. Foods containing soy protein include hamburgers, dumplings, dumplings, ham, sausages, kamaboko, chikuwa, sweets, bread, and meat sauce. Foods containing vinegar, acidulants, pH adjusters, and seasonings include rice such as rice, fried rice, and rice balls; dressings such as dressings and mayonnaise; marine; noodles such as udon and ramen; salads; fillings; Such as pasta sauce. Retort foods include retort curry, retort pasta sauce, and retort porridge.

本発明の製造方法で得られる油脂を食品に添加する場合、その添加方法は特に限定されない。また、前記油脂を食品に添加するタイミングも特に限定されず、食品の製造のいずれの工程でも良い。なお、非加熱のレシチン含有油脂を炒め油として用いた場合には、本発明の効果は得られない。
また、本発明の食品中の前記油脂の含有量は、加熱処理前のレシチンが0.01ppm以上5000ppm以下であることが好ましく、0.05ppm以上4000ppm以下であることがより好ましい。
When the fat or oil obtained by the production method of the present invention is added to a food, the addition method is not particularly limited. Further, the timing of adding the fat and oil to the food is not particularly limited, and any step of food production may be used. When unheated lecithin-containing fats and oils are used as stir-fry oil, the effect of the present invention cannot be obtained.
The content of the fats and oils in the food of the present invention is preferably 0.01 ppm or more and 5000 ppm or less, and more preferably 0.05 ppm or more and 4000 ppm or less for lecithin before heat treatment.

また、本発明では、効果に影響のない範囲で通常食用として使用するものを添加できる。 Further, in the present invention, those usually used for food can be added as long as the effect is not affected.

以下に、本発明の実施例および比較例を示すが、本発明の主旨はこれらに限定されるものではない。なお、「部」は「質量部」を意味する。 Examples and comparative examples of the present invention are shown below, but the gist of the present invention is not limited thereto. In addition, "part" means "mass part".

実施に際しては、以下のものを使用した。 In carrying out, the following were used.

<レシチン>
AY:レシチンAY(株式会社J−オイルミルズ社製;ペースト状レシチン、大豆由来、酸価 19.8)
FA:レシチンFA(株式会社J−オイルミルズ社製;ペースト状レシチン、大豆由来、酸価 23.7)
CL:レシチンCL(株式会社J−オイルミルズ社製;ペースト状レシチン、大豆由来、酸価 26.1)
BE:ベネコート(花王株式会社製;酵素分解レシチン、大豆由来)
SA:SLP−パウダーA(辻製油株式会社製;分別レシチン、大豆由来)
RL:ライスレシチンオイル(築野食品工業株式会社製;ペースト状レシチン、米糠由来)
<油脂>
大豆油(製品名:J 大豆白絞油NS、株式会社J−オイルミルズ社製)
菜種油(製品名:AJINOMOTO さらさらキャノーラ油、株式会社J−オイルミルズ社製)
コーン油(製品名:AJINOMOTO 胚芽の恵みコーン油、株式会社J−オイルミルズ社製)
綿実油(製品名:J 綿実油NS、株式会社J−オイルミルズ社製)
パームオレイン(ヨウ素価67、株式会社J−オイルミルズ社製)

<その他>
PGPR:ポリグリセリン縮合リシノレイン酸エステル(SYグリスター CR−ED、阪本薬品工業株式会社製)
SE:ショ糖エルカ酸エステル(リョートーシュガーエステル ER−290、三菱化学フーズ株式会社製)
<Lecithin>
AY: Lecithin AY (manufactured by J-Oil Mills Co., Ltd .; paste-like lecithin, derived from soybean, acid value 19.8)
FA: Lecithin FA (manufactured by J-Oil Mills Co., Ltd .; paste-like lecithin, derived from soybeans, acid value 23.7)
CL: Lecithin CL (manufactured by J-Oil Mills Co., Ltd .; paste-like lecithin, derived from soybean, acid value 26.1)
BE: Benecoat (manufactured by Kao Corporation; enzymatically decomposed lecithin, derived from soybean)
SA: SLP-Powder A (manufactured by Tsuji Oil Co., Ltd .; separated lecithin, derived from soybeans)
RL: Rice lecithin oil (manufactured by Tsukino Food Industry Co., Ltd .; paste-like lecithin, derived from rice bran)
<Fat and oil>
Soybean oil (Product name: J Soybean white squeezed oil NS, manufactured by J-Oil Mills Co., Ltd.)
Rapeseed oil (Product name: AJINOMOTO Sarasara Canola Oil, manufactured by J-Oil Mills Co., Ltd.)
Corn oil (Product name: AJINOMOTO Germ blessing Corn oil, manufactured by J-Oil Mills Co., Ltd.)
Cottonseed oil (Product name: J Cottonseed oil NS, manufactured by J-Oil Mills Co., Ltd.)
Palm olein (iodine value 67, manufactured by J-Oil Mills Co., Ltd.)

<Others>
PGPR: Polyglycerin condensed ricinoleic acid ester (SY Glycer CR-ED, manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.)
SE: Sucrose erucic acid ester (Ryoto Sugar Ester ER-290, manufactured by Mitsubishi Chemical Foods Co., Ltd.)

下記方法により、異風味の抑制効果の評価をおこなった。 The effect of suppressing the off-flavor was evaluated by the following method.

<酸味・酸臭抑制の評価>
炊飯した米飯100部に対し、酢(醸造酢、株式会社ミツカン社製)3部添加しよく混ぜ合わせて酢配合米飯を得た。その後下記の材料で炒めて炒飯を作った。調理した炒飯99部に対して油脂組成物1部を添加し混ぜ合わせた。電子レンジで温めた後、食して、酸味・酸臭の抑制効果及び異臭の有無について評価した。

(材料)
酢配合米飯 200g
卵 50g
長ネギ 10g
塩 少々
胡椒 少々
醤油 2g
菜種油15g
<Evaluation of acidity and acid odor suppression>
To 100 parts of cooked rice, 3 parts of vinegar (brewed vinegar, manufactured by Mizkan Co., Ltd.) was added and mixed well to obtain vinegar-blended cooked rice. After that, it was fried with the following ingredients to make fried rice. One part of the oil and fat composition was added to 99 parts of the cooked fried rice and mixed. After warming in a microwave oven, it was eaten and evaluated for its effect of suppressing acidity and acid odor and the presence or absence of offensive odor.

(material)
Rice with vinegar 200g
Egg 50g
Long onion 10g
A little salt, a little pepper, a little soy sauce 2g
Canola oil 15g

<魚臭抑制の評価>
鯖の水煮缶詰(Lawson select さば水煮、株式会社マルハニチロ社製)から固形部(鯖)を取り出し、水を切った。得られた鯖98部に対し、油脂組成物2部を添加し混ぜ合わせた。電子レンジで温めた後、食して、魚臭の抑制効果について評価した。
<Evaluation of fish odor suppression>
The solid part (mackerel) was taken out from the canned mackerel boiled in water (Lawson select mackerel boiled in water, manufactured by Maruha Nichiro Co., Ltd.) and drained. To 98 parts of the obtained mackerel, 2 parts of the oil and fat composition were added and mixed. After warming in a microwave oven, it was eaten and evaluated for its effect of suppressing fish odor.

<大豆タンパク臭抑制の評価>
下記に示した配合のハンバーグ生地98部に対し、油脂組成物を2部添加して混ぜ合わせた。フライパンで表裏各2分間焼目をつけた。200℃に予熱したオーブンにて8分間焼成した。粗熱を取った後-20℃冷凍庫で保存した。電子レンジで温めた後、食して、タンパク臭の抑制効果について評価した。

(ハンバーグ生地の配合)
合い挽肉 46g
水戻し粒状大豆蛋白(フジニックエース400、不二製油株式会社製) 10g
玉ねぎ 10g
生パン粉 10g
コーンスターチ 0.7g
卵白 7.5g
食塩 少々
胡椒 少々
ナツメグ 少々
<Evaluation of soy protein odor suppression>
Two parts of the oil and fat composition were added to 98 parts of the hamburger dough having the composition shown below and mixed. Bake for 2 minutes each on the front and back with a frying pan. It was baked in an oven preheated to 200 ° C. for 8 minutes. After removing the rough heat, it was stored in a freezer at -20 ° C. After warming in a microwave oven, it was eaten and evaluated for its effect of suppressing protein odor.

(Mixed hamburger dough)
Minced meat 46g
Water-rehydrated granular soy protein (Fuji Nick Ace 400, manufactured by Fuji Oil Co., Ltd.) 10 g
Onion 10g
Raw bread crumbs 10g
Cornstarch 0.7g
Egg white 7.5g
A little salt, a little pepper, a little nutmeg, a little

(抑制効果の評価基準)
◎:効果が強い
○:効果がある
△:効果が弱い
×:効果なし
(Evaluation criteria for suppression effect)
◎: Strong effect ○: Effective △: Weak effect ×: No effect

<異臭の確認>
食した際に、添加した油脂組成物の香りを感じた場合は異臭と判定した。

(異臭の評価基準)
◎:感じない
○:僅かに感じる
△:弱く感じる
×:強く感じる
<Confirmation of offensive odor>
When the scent of the added oil / fat composition was felt when eating, it was judged to have an offensive odor.

(Evaluation criteria for offensive odor)
◎: Do not feel ○: Slightly feel △: Feel weak ×: Feel strong

<加熱処理の方法>
レシチン含有油脂を三口フラスコに加え、撹拌しながらオイルバスによる加熱をおこなった。所定温度になるまで加熱した後一定時間保温した。保温後、冷却して加熱処理レシチン含有油脂を得た。
<Heat treatment method>
Lecithin-containing fats and oils were added to a three-necked flask and heated with an oil bath while stirring. After heating to a predetermined temperature, it was kept warm for a certain period of time. After keeping warm, it was cooled to obtain a heat-treated lecithin-containing oil and fat.

<吸光度の測定方法>
吸光度の測定には紫外可視分光光度計(UV−2450;島津製作所社製、1cmガラスセル)を用いた。
<Measurement method of absorbance>
An ultraviolet-visible spectrophotometer (UV-2450; manufactured by Shimadzu Corporation, 1 cm glass cell) was used for the measurement of the absorbance.

(加熱時間1)
表1に示す濃度になるようレシチンAYを大豆油に添加し、レシチン含有油脂を調製した。各レシチン含有油脂を表1に示す条件で加熱し、加熱処理レシチン含有油脂を得た。表1に示すレシチン濃度となるように、加熱処理レシチン含有油脂を必要に応じて菜種油で希釈した油脂組成物を用いて、異風味の抑制効果の評価をした。また、異臭の確認をおこなった。なお、油脂組成物のレシチン濃度とは、加熱処理前のレシチンを基準とした(以下同じ)。その結果を表1に示す。また、実施例1−4のレシチン含有油脂の加熱処理後の吸光度(400nm)から加熱処理前の吸光度(400nm)を引いた値は0.952であった。
(Heating time 1)
Lecithin AY was added to soybean oil so as to have the concentrations shown in Table 1 to prepare lecithin-containing fats and oils. Each lecithin-containing fat and oil was heated under the conditions shown in Table 1 to obtain a heat-treated lecithin-containing fat and oil. The effect of suppressing the off-flavor was evaluated using an oil / fat composition obtained by diluting the heat-treated lecithin-containing oil / fat with rapeseed oil as necessary so as to obtain the lecithin concentration shown in Table 1. In addition, a strange odor was confirmed. The lecithin concentration of the fat and oil composition was based on the lecithin before the heat treatment (the same applies hereinafter). The results are shown in Table 1. Further, the value obtained by subtracting the absorbance (400 nm) before the heat treatment from the absorbance (400 nm) after the heat treatment of the lecithin-containing fats and oils of Examples 1-4 was 0.952.

Figure 0006918408
Figure 0006918408

表1に示したように、レシチン含有油脂を加熱処理することで、酸臭等の抑制効果が得られることが判った。特に加熱処理を3時間以上にすることで異風味の抑制効果が高くなり、5時間以上にすることで、異風味の抑制効果が顕著となった。一方、加熱処理していないレシチン含有油脂では、異風味の抑制効果がないことが判った(比較例1−1、1−2)。 As shown in Table 1, it was found that the effect of suppressing acid odor and the like can be obtained by heat-treating the lecithin-containing fats and oils. In particular, when the heat treatment was carried out for 3 hours or more, the effect of suppressing the off-flavor became high, and when the heat treatment was carried out for 5 hours or more, the effect of suppressing the off-flavor became remarkable. On the other hand, it was found that the lecithin-containing fats and oils that had not been heat-treated had no effect of suppressing the off-flavor (Comparative Examples 1-1 and 1-2).

(加熱処理時のレシチン濃度)
表2、3に示す濃度になるようレシチンAYを大豆油に添加し、レシチン含有油脂を調製した。各レシチン含有油脂を表2、3に示す条件で加熱し、加熱処理レシチン含有油脂を得た。表2、3に示すレシチン濃度となるように加熱処理レシチン含有油脂を必要に応じて菜種油で希釈した油脂組成物を用いて、異風味の抑制効果の評価をした。また、異臭の確認をおこなった。その結果を表2、3に示す。また、実施例3−3のレシチン含有油脂の加熱処理後の吸光度(400nm)から加熱処理前の吸光度(400nm)を引いた値は3.787であった。
(Lecithin concentration during heat treatment)
Lecithin AY was added to soybean oil so as to have the concentrations shown in Tables 2 and 3, and lecithin-containing fats and oils were prepared. Each lecithin-containing fat and oil was heated under the conditions shown in Tables 2 and 3 to obtain a heat-treated lecithin-containing fat and oil. The effect of suppressing the off-flavor was evaluated using an oil / fat composition obtained by diluting the heat-treated lecithin-containing oil / fat with rapeseed oil as necessary so as to have the lecithin concentration shown in Tables 2 and 3. In addition, a strange odor was confirmed. The results are shown in Tables 2 and 3. Further, the value obtained by subtracting the absorbance (400 nm) before the heat treatment from the absorbance (400 nm) after the heat treatment of the lecithin-containing fat and oil of Example 3-3 was 3.787.

Figure 0006918408
Figure 0006918408

Figure 0006918408
Figure 0006918408

表2、3に示したように、加熱時のレシチン含有量に関係なく、異風味の抑制効果が得られることが判った。特に油脂組成物のレシチン濃度が1質量%以上になると異風味の抑制効果が高いことが判った。 As shown in Tables 2 and 3, it was found that the effect of suppressing the off-flavor can be obtained regardless of the lecithin content at the time of heating. In particular, it was found that when the lecithin concentration of the oil / fat composition is 1% by mass or more, the effect of suppressing the off-flavor is high.

(加熱温度)
表4に示す濃度になるようレシチンAYを大豆油に添加し、レシチン含有油脂を調製した。各レシチン含有油脂を表4に示す条件で加熱し、加熱処理レシチン含有油脂を得た。表4に示すレシチン濃度となるように加熱処理レシチン含有油脂を必要に応じて菜種油で希釈した油脂組成物を用いて、異風味の抑制効果の評価をした。また、異臭の確認をおこなった。その結果を表4に示す。
(Heating temperature)
Lecithin AY was added to soybean oil so as to have the concentration shown in Table 4, and lecithin-containing fats and oils were prepared. Each lecithin-containing fat and oil was heated under the conditions shown in Table 4 to obtain a heat-treated lecithin-containing fat and oil. The effect of suppressing the off-flavor was evaluated using an oil / fat composition obtained by diluting the heat-treated lecithin-containing oil / fat with rapeseed oil as necessary so as to have the lecithin concentration shown in Table 4. In addition, a strange odor was confirmed. The results are shown in Table 4.

Figure 0006918408
Figure 0006918408

表4に示したように、レシチン含有油脂を80℃〜140℃で加熱処理することで、酸臭等の異風味の抑制効果が得られることが判った。特に加熱処理温度を110℃以上とすることで、異風味の抑制効果がより高く、特に120℃以上でその効果が顕著であった。 As shown in Table 4, it was found that the effect of suppressing off-flavors such as acid odor can be obtained by heat-treating the lecithin-containing fats and oils at 80 ° C. to 140 ° C. In particular, when the heat treatment temperature was set to 110 ° C. or higher, the effect of suppressing the off-flavor was higher, and the effect was particularly remarkable at 120 ° C. or higher.

(加熱時間2)
表5に示す濃度になるようレシチンAYを大豆油に添加し、レシチン含有油脂を調製した。各レシチン含有油脂を表5に示す条件で加熱し、加熱処理レシチン含有油脂を得た。また、各レシチン含有油脂の加熱処理前後の吸光度(400nm)を測定した。表5に示すレシチン濃度となるように加熱処理レシチン含有油脂を必要に応じて菜種油で希釈した油脂組成物を用いて、異風味の抑制効果の評価をした。また、異臭の確認をおこなった。その結果を表5に示す。
(Heating time 2)
Lecithin AY was added to soybean oil so as to have the concentration shown in Table 5, and lecithin-containing fats and oils were prepared. Each lecithin-containing fat and oil was heated under the conditions shown in Table 5 to obtain a heat-treated lecithin-containing fat and oil. In addition, the absorbance (400 nm) of each lecithin-containing fat before and after the heat treatment was measured. The effect of suppressing the off-flavor was evaluated using an oil / fat composition obtained by diluting the heat-treated lecithin-containing oil / fat with rapeseed oil as necessary so as to have the lecithin concentration shown in Table 5. In addition, a strange odor was confirmed. The results are shown in Table 5.

Figure 0006918408
Figure 0006918408

表5に示したように、レシチン含有油脂を80℃で24〜120時間加熱処理することで、異風味である酸味・酸臭の抑制効果が得られることが判った。さらに、処理時間を長くすることで、異風味の抑制効果がより高くなることが判った。また、レシチン含有油脂の加熱前後の吸光度差(400nm)が0.165以上になるよう加熱処理することで異風味の抑制効果が得られることが判った。 As shown in Table 5, it was found that by heat-treating the lecithin-containing fats and oils at 80 ° C. for 24 to 120 hours, the effect of suppressing the acidity and acid odor, which are unusual flavors, can be obtained. Furthermore, it was found that the effect of suppressing the off-flavor was further enhanced by lengthening the treatment time. Further, it was found that the effect of suppressing the off-flavor can be obtained by heat-treating the lecithin-containing fats and oils so that the difference in absorbance (400 nm) before and after heating is 0.165 or more.

(ベース油脂)
表6に示す濃度になるようレシチンAYを大豆油等に添加し、レシチン含有油脂を調製した。各レシチン含有油脂を表6に示す条件で加熱し、加熱処理レシチン含有油脂を得た。表6に示すレシチン濃度となるように加熱処理レシチン含有油脂を必要に応じて菜種油で希釈した油脂組成物を用いて、異風味の抑制効果の評価をした。また、異臭の確認をおこなった。その結果を表6に示す。
(Base oil)
Lecithin AY was added to soybean oil and the like so as to have the concentrations shown in Table 6 to prepare lecithin-containing fats and oils. Each lecithin-containing fat and oil was heated under the conditions shown in Table 6 to obtain a heat-treated lecithin-containing fat and oil. The effect of suppressing the off-flavor was evaluated using an oil / fat composition obtained by diluting the heat-treated lecithin-containing oil / fat with rapeseed oil as necessary so as to have the lecithin concentration shown in Table 6. In addition, a strange odor was confirmed. The results are shown in Table 6.

Figure 0006918408
Figure 0006918408

表6に示したように、レシチンを添加する油脂は大豆油、菜種油、パームオレイン、コーン油、綿実油のいずれでも、異風味である酸味・酸臭の抑制効果が得られることが判った。特に異風味の抑制の効果の高さと異臭の観点から、レシチンを添加する油脂として大豆油が好ましいことが判った。 As shown in Table 6, it was found that any of the fats and oils to which lecithin was added, soybean oil, rapeseed oil, palm olefin, corn oil, and cottonseed oil, had an effect of suppressing acidity and acid odor, which are unusual flavors. In particular, it was found that soybean oil is preferable as the fat and oil to which lecithin is added from the viewpoint of high effect of suppressing off-flavor and off-flavor.

(レシチンの種類)
表7に示す濃度になるよう種々のレシチンを大豆油に添加し、レシチン含有油脂を調製した。各レシチン含有油脂を表7に示す条件で加熱し、加熱処理レシチン含有油脂を得た。表7に示すレシチン濃度となるように加熱処理レシチン含有油脂を必要に応じて菜種油で希釈した油脂組成物を用いて、異風味の抑制効果の評価をした。また、異臭の確認をおこなった。その結果を表7に示す。
(Type of lecithin)
Various lecithins were added to soybean oil so as to have the concentrations shown in Table 7, and lecithin-containing fats and oils were prepared. Each lecithin-containing fat and oil was heated under the conditions shown in Table 7 to obtain a heat-treated lecithin-containing fat and oil. The effect of suppressing the off-flavor was evaluated using an oil / fat composition obtained by diluting the heat-treated lecithin-containing oil / fat with rapeseed oil as necessary so as to have the lecithin concentration shown in Table 7. In addition, a strange odor was confirmed. The results are shown in Table 7.

Figure 0006918408
Figure 0006918408

表7に示したいずれのレシチンも異風味の抑制効果が得られることが判った。特にAY、FA、CLおよびSAで異風味の抑制効果が高く、特にAYでその効果が顕著であった。 It was found that all of the lecithins shown in Table 7 had an effect of suppressing an unusual flavor. In particular, AY, FA, CL and SA had a high effect of suppressing an abnormal flavor, and AY in particular had a remarkable effect.

(乳化剤添加)
表8に示す濃度になるようレシチンAYを大豆油に添加し、レシチン含有油脂を調製した。各レシチン含有油脂を表8に示す条件で加熱し、加熱処理レシチン含有油脂を得た。加熱処理レシチン含有油脂に表8に記載の乳化剤を添加し、乳化剤配合加熱処理レシチン含有油脂を得た。表8に示すレシチン濃度となるように乳化剤配合加熱処理レシチン含有油脂を必要に応じて菜種油で希釈した油脂組成物を用いて、異風味の抑制効果の評価をした。また、異臭の確認をおこなった。その結果を表8に示す。
(Add emulsifier)
Lecithin AY was added to soybean oil so as to have the concentrations shown in Table 8 to prepare lecithin-containing fats and oils. Each lecithin-containing fat and oil was heated under the conditions shown in Table 8 to obtain a heat-treated lecithin-containing fat and oil. The emulsifiers shown in Table 8 were added to the heat-treated lecithin-containing fats and oils to obtain heat-treated lecithin-containing fats and oils containing an emulsifier. An oil / fat composition obtained by diluting a heat-treated lecithin-containing oil / fat containing an emulsifier with rapeseed oil so as to have the lecithin concentration shown in Table 8 was used to evaluate the effect of suppressing an off-flavor. In addition, a strange odor was confirmed. The results are shown in Table 8.

Figure 0006918408
Figure 0006918408

表8に示したしたように加熱処理レシチン含有油脂に乳化剤を添加しても異風味の抑制効果が阻害されることはなかった。 As shown in Table 8, even if an emulsifier was added to the heat-treated lecithin-containing fats and oils, the effect of suppressing the off-flavor was not impaired.

実施例9:野菜マリネ
下記に示した配合の野菜マリネ98.5部に対し、実施例1−4の油脂組成物1.5部を添加し、混ぜ合わせた。対照として、実施例1−4の油脂組成物の代わりに菜種油を添加したものを作成した。得られた野菜マリネを食して、酸味、酸臭の抑制効果を評価したところ、菜種油と比較して、実施例1−4の油脂組成物は酸味、酸臭を抑制することが確認できた。また、酢角が取れて、甘味を強く感じた。

(野菜マリネの配合)
玉ねぎ 50g
人参 5g
醸造酢 30g
塩 1g
胡椒 0.1g
菜種油 48g
Example 9: Vegetable marinade To 98.5 parts of the vegetable marinade having the composition shown below, 1.5 parts of the oil and fat composition of Example 1-4 was added and mixed. As a control, a product in which rapeseed oil was added instead of the oil and fat composition of Examples 1-4 was prepared. When the obtained vegetable marinade was eaten and the effect of suppressing acidity and acid odor was evaluated, it was confirmed that the oil and fat composition of Example 1-4 suppresses acidity and acid odor as compared with rapeseed oil. Also, the vinegar was removed and the sweetness was strongly felt.

(Mixed vegetable marinade)
Onion 50g
Carrot 5g
Brewed vinegar 30g
1 g of salt
Pepper 0.1g
Canola oil 48g

実施例10:ドレッシング1
下記に示した配合の自家製ドレッシング96.7部に対し、実施例1−4の油脂組成物3.3部を添加し、混ぜ合わせた。対照として、実施例1−4の油脂組成物の代わりに菜種油を添加したものを作成した。得られた自家製ドレッシングを食して、酸味、酸臭の抑制効果を評価したところ、菜種油と比較して実施例1−4の油脂組成物は酸味、酸臭を抑制することが確認できた。

(自家製ドレッシングの配合)
リンゴ酢(株式会社ミツカン社製) 10g
菜種油 19g
Example 10: Dressing 1
To 96.7 parts of the homemade dressing having the composition shown below, 3.3 parts of the oil and fat composition of Example 1-4 was added and mixed. As a control, a product in which rapeseed oil was added instead of the oil and fat composition of Examples 1-4 was prepared. When the obtained homemade dressing was eaten and the effect of suppressing acidity and acid odor was evaluated, it was confirmed that the oil and fat composition of Example 1-4 suppressed acidity and acid odor as compared with rapeseed oil.

(Combining homemade dressing)
Apple cider vinegar (manufactured by Mizkan Co., Ltd.) 10 g
Canola oil 19g

実施例11:ドレッシング2
市販のドレッシング(GABANスパイスドレッシング「ハーブレモン」)100部に対し、実施例3−3の油脂組成物2部を添加し、混ぜ合わせた。対照として、実施例3−3の油脂組成物の代わりに菜種油を添加したものを作成した。得られたドレッシングを食して、酸味、酸臭の抑制効果を評価したところ、菜種油と比較して実施例3−3の油脂組成物は酸味、酸臭を抑制することが確認できた。また、酢角が取れて甘味を強く感じた。
Example 11: Dressing 2
To 100 parts of a commercially available dressing (GABAN spice dressing "herb lemon"), 2 parts of the fat and oil composition of Example 3-3 were added and mixed. As a control, a product in which rapeseed oil was added instead of the oil and fat composition of Example 3-3 was prepared. When the obtained dressing was eaten and the effect of suppressing acidity and acid odor was evaluated, it was confirmed that the oil and fat composition of Example 3-3 suppressed acidity and acid odor as compared with rapeseed oil. Also, the vinegar was removed and the sweetness was strongly felt.

実施例12:ドレッシング3
市販のドレッシング(GABANスパイスドレッシング「和風醤油&バルサミコ酢」)100部に対し、実施例3−3の油脂組成物2部を添加し、混ぜ合わせた。対照として、実施例3−3の油脂組成物の代わりに菜種油を添加したものを作成した。得られたドレッシングを食して、酸味、酸臭の抑制効果を評価したところ、菜種油と比較して実施例3−3の油脂組成物は酸味、酸臭を抑制することが確認できた。また、酢角が取れて甘味を強く感じた。
Example 12: Dressing 3
To 100 parts of a commercially available dressing (GABAN spice dressing "Japanese-style soy sauce & balsamic vinegar"), 2 parts of the fat and oil composition of Example 3-3 were added and mixed. As a control, a product in which rapeseed oil was added instead of the oil and fat composition of Example 3-3 was prepared. When the obtained dressing was eaten and the effect of suppressing acidity and acid odor was evaluated, it was confirmed that the oil and fat composition of Example 3-3 suppressed acidity and acid odor as compared with rapeseed oil. Also, the vinegar was removed and the sweetness was strongly felt.

実施例13:フィリング1
市販のミートソースフィリング(プチグルメ あらびきミートのボロネーゼ、ソントン食品工業株式会社製)100部に対し、実施例1−4の油脂組成物2部を添加し、混ぜ合わせた。対照として、実施例1−4の油脂組成物の代わりに菜種油を添加したものを作成した。得られたミートソースフィリングを食して、酸味、酸臭の抑制効果を評価したところ、菜種油と比較して実施例1−4の油脂組成物は酸味、酸臭を抑制することが確認できた。また、酢角が取れて、甘味を強く感じた。
Example 13: Filling 1
To 100 parts of a commercially available meat sauce filling (Petit Gourmet Arabiki Meat Bolognese, manufactured by Sonton Food Industry Co., Ltd.), 2 parts of the oil and fat composition of Example 1-4 was added and mixed. As a control, a product in which rapeseed oil was added instead of the oil and fat composition of Examples 1-4 was prepared. When the obtained meat sauce filling was eaten and the effect of suppressing acidity and acid odor was evaluated, it was confirmed that the oil and fat composition of Example 1-4 suppressed acidity and acid odor as compared with rapeseed oil. Also, the vinegar was removed and the sweetness was strongly felt.

実施例14:フィリング2
市販のカニクリームフィリング(プチグルメ 紅ズワイガニのカニクリーム、ソントン食品工業株式会社製)100部に対し、実施例1−4の油脂組成物2部を添加し、混ぜ合わせた。対照として、実施例1−4の油脂組成物の代わりに菜種油を添加したものを作成した。得られたカニクリームフィリングを食して、酸味、酸臭、魚介類の生臭さ及び雑味の抑制効果を評価したところ、菜種油と比較して実施例1−4の油脂組成物は酸味、酸臭、魚介類の生臭さ及び雑味を抑制することが確認できた。
Example 14: Filling 2
To 100 parts of a commercially available crab cream filling (petit gourmet red snow crab crab cream, manufactured by Sonton Food Industry Co., Ltd.), 2 parts of the oil and fat composition of Example 1-4 was added and mixed. As a control, a product in which rapeseed oil was added instead of the oil and fat composition of Examples 1-4 was prepared. When the obtained crab cream filling was eaten and the effect of suppressing acidity, acidity, fishy smell and miscellaneous taste of seafood was evaluated, the oil and fat composition of Example 1-4 was compared with rapeseed oil and had acidity and acidity. , It was confirmed that the fishy odor and miscellaneous taste of fish and shellfish were suppressed.

実施例15:フィリング3
市販の明太子フィリング(キユーピー株式会社製)100部に対し、実施例1−4の油脂組成物2部を添加し、混ぜ合わせた。対照として、実施例1−4の油脂組成物の代わりに菜種油を添加したものを作成した。得られた明太子フィリングを食して、酸味、酸臭及び魚介類の生臭さの抑制効果を評価したところ、菜種油と比較して実施例1−4の油脂組成物は酸味、酸臭及び魚介類の生臭さを抑制することが確認できた。
Example 15: Filling 3
To 100 parts of a commercially available mentaiko filling (manufactured by Kewpie Corp.), 2 parts of the oil and fat composition of Example 1-4 was added and mixed. As a control, a product in which rapeseed oil was added instead of the oil and fat composition of Examples 1-4 was prepared. When the obtained mentaiko filling was eaten and the effect of suppressing acidity, acidity and fishy odor was evaluated, the oil and fat composition of Example 1-4 was compared with rapeseed oil and had acidity, acidity and seafood. It was confirmed that the fishy odor was suppressed.

実施例16:フィリング4
市販のカルボナーラフィリング(具だくさんフィリング カルボナーラ、キユーピー株式会社製)100部に対し、実施例1−4の油脂組成物2部を添加し、混ぜ合わせた。対照として、実施例1−4の油脂組成物の代わりに菜種油を添加したものを作成した。得られたカルボナーラフィリングを食して、酸味、酸臭の抑制効果を評価したところ、菜種油と比較して実施例1−4の油脂組成物は酸味、酸臭を抑制することが確認できた。また、酢角が取れて、甘味を強く感じた。
Example 16: Filling 4
To 100 parts of a commercially available carbonara filling (filling with a lot of ingredients, manufactured by Kewpie Corp.), 2 parts of the oil and fat composition of Example 1-4 was added and mixed. As a control, a product in which rapeseed oil was added instead of the oil and fat composition of Examples 1-4 was prepared. When the obtained carbonara filling was eaten and the effect of suppressing acidity and acid odor was evaluated, it was confirmed that the oil and fat composition of Example 1-4 suppressed acidity and acid odor as compared with rapeseed oil. Also, the vinegar was removed and the sweetness was strongly felt.

実施例17:春雨サラダ
下記に示した配合の自家製春雨サラダ95部に対し、実施例1−4の油脂組成物5部を添加し、混ぜ合わせた。対照として、実施例1−4の油脂組成物の代わりに菜種油を添加したものを作成した。得られた自家製春雨サラダを食して、酸味、酸臭の抑制効果を評価したところ、菜種油と比較して実施例1−4の油脂組成物は酸味、酸臭を抑制することが確認できた。また、酢角が取れて甘味を強く感じた。

(自家製春雨サラダの配合)
茹で春雨 45g
きゅうり 7.5g
人参 7.5g
醤油 10g
砂糖 2.5g
穀物酢 10g
菜種油 10g
Example 17: Vermicelli salad To 95 parts of the homemade vermicelli salad having the composition shown below, 5 parts of the oil and fat composition of Example 1-4 was added and mixed. As a control, a product in which rapeseed oil was added instead of the oil and fat composition of Examples 1-4 was prepared. When the obtained homemade vermicelli salad was eaten and the effect of suppressing acidity and acid odor was evaluated, it was confirmed that the oil and fat composition of Example 1-4 suppressed acidity and acid odor as compared with rapeseed oil. Also, the vinegar was removed and the sweetness was strongly felt.

(Combined with homemade vermicelli salad)
Boiled vermicelli 45g
Cucumber 7.5g
Carrot 7.5g
Salty sauce 10g
Sugar 2.5g
Grain vinegar 10g
Canola oil 10g

実施例18:マヨネーズ
下記に示した配合で自家製マヨネーズを作成した。対照として、実施例1−4の油脂組成物の代わりに菜種油を添加したものを作成した。得られたマヨネーズを食して、酸味、酸臭の抑制効果を評価したところ、菜種油と比較して実施例1−4の油脂組成物は酸味、酸臭を抑制することが確認できた。

(自家製マヨネーズの配合)
菜種油 195g
実施例1−4の油脂組成物 5g
穀物酢 15g
塩 1.5g
グルタミン酸ナトリウム 0.08g
Example 18: Mayonnaise Homemade mayonnaise was prepared with the formulation shown below. As a control, a product in which rapeseed oil was added instead of the oil and fat composition of Examples 1-4 was prepared. When the obtained mayonnaise was eaten and the effect of suppressing acidity and acid odor was evaluated, it was confirmed that the oil and fat composition of Example 1-4 suppressed acidity and acid odor as compared with rapeseed oil.

(Combined with homemade mayonnaise)
Canola oil 195g
Oil and fat composition of Examples 1-4 5 g
Grain vinegar 15g
Salt 1.5g
Monosodium glutamate 0.08g

実施例19:白米
生米(富山県産コシヒカリ、無洗米)を水に90分間浸漬した。その後、水を切り、炊飯釜に移し、生米100部に対し、醸造酢(株式会社ミツカン社製)を1.2部添加し、菜種油を0.76部添加し、実施例1−4の油脂組成物を0.04部添加し、加水し混ぜ合わせた。炊飯し、220部の白米を得た。対照として、実施例1−4の油脂組成物の代わりに菜種油を添加したものを作成した。
得られた白米を真空冷却器で23℃まで冷却した。小分けにした後、電子レンジで温めた後、食して、酸臭、酸味の抑制効果及び異臭の有無について評価したところ、菜種油と比較して実施例1−4の油脂組成物は酸味、酸臭を抑制することが確認できた。また、異臭はなかった。
Example 19: White rice Raw rice (Koshihikari from Toyama Prefecture, wash-free rice) was immersed in water for 90 minutes. After that, the water was drained, transferred to a rice cooker, 1.2 parts of brewed vinegar (manufactured by Mizkan Co., Ltd.) was added to 100 parts of raw rice, and 0.76 parts of rapeseed oil was added. 0.04 part of the oil / fat composition was added, and the mixture was added with water. Rice was cooked and 220 parts of white rice was obtained. As a control, a product in which rapeseed oil was added instead of the oil and fat composition of Examples 1-4 was prepared.
The obtained white rice was cooled to 23 ° C. with a vacuum condenser. After subdividing, heating in a microwave oven, and eating, the acid odor, the effect of suppressing acidity, and the presence or absence of offensive odor were evaluated. It was confirmed that it suppresses. In addition, there was no offensive odor.

実施例20:レトルト食品
市販のカレールウ(ゴールデンカレー 中辛、ヱスビー食品株式会社)22gをお湯150gに溶解させたもの100部に対し、実施例3−3の油脂組成物2部を添加し混ぜ合わせ、レトルトパウチに入れ、ヒートシーラーで封をした。対照として、実施例3−3の油脂組成物の代わりに菜種油を添加したものを作成した。
レトルト機にて120℃、20分の条件で加圧加熱殺菌処理を行った。得られたカレールウの入ったレトルトパウチを湯浴で温めた後、カレールウを食して、レトルト臭の抑制効果について評価したところ、菜種油と比較して実施例3−3の油脂組成物はレトルト臭を抑制することが確認できた。
Example 20: Retort foods To 100 parts of commercially available curry roux (golden curry medium spicy, S & B Foods Co., Ltd.) dissolved in 150 g of hot water, 2 parts of the fat and oil composition of Example 3-3 are added and mixed. , Put in a retort pouch and sealed with a heat sealer. As a control, a product in which rapeseed oil was added instead of the oil and fat composition of Example 3-3 was prepared.
The pressure heat sterilization treatment was carried out in a retort machine at 120 ° C. for 20 minutes. After warming the obtained retort pouch containing curry roux in a hot water bath, the curry roux was eaten and the effect of suppressing the retort odor was evaluated. It was confirmed that it was suppressed.

Claims (6)

レシチン含有油脂を加熱して得られる油脂の製造方法であって、
前記レシチン含有油脂のレシチン含有量が0.05質量%以上10質量%以下であり、前記レシチン含有油脂を80℃以上140℃以下の温度で3時間以上120時間以下加熱処理する加熱工程、
を含む、前記製造方法。
A method for producing fats and oils obtained by heating lecithin-containing fats and oils.
A heating step in which the lecithin-containing fat and oil has a lecithin content of 0.05% by mass or more and 10% by mass or less, and the lecithin-containing fat or oil is heat-treated at a temperature of 80 ° C. or higher and 140 ° C. or lower for 3 hours or longer and 120 hours or shorter.
The production method.
前記レシチン含有油脂の加熱処理後の400nmの吸光度から加熱処理前の400nmの吸光度を引いた値が0.1以上4以下である請求項1に記載の製造方法。 The production method according to claim 1, wherein the value obtained by subtracting the absorbance at 400 nm before the heat treatment from the absorbance at 400 nm after the heat treatment of the lecithin-containing fat and oil is 0.1 or more and 4 or less. 食用油脂にレシチンを添加し、レシチン含有油脂を調製する工程を含む、請求項1または2に記載の製造方法。 The production method according to claim 1 or 2 , which comprises a step of adding lecithin to edible fats and oils to prepare lecithin-containing fats and oils. 請求項1乃至のいずれか一項に記載の製造方法で得られた油脂を食用油脂に添加する工程を含む、油脂組成物の製造方法。 A method for producing an oil / fat composition, which comprises a step of adding the oil / fat obtained by the production method according to any one of claims 1 to 3 to an edible oil / fat. 加熱処理前のレシチンが0.05質量%以上5質量%以下になるように前記油脂を添加する、請求項に記載の製造方法。 The production method according to claim 4 , wherein the fats and oils are added so that the lecithin before the heat treatment is 0.05% by mass or more and 5% by mass or less. 請求項1乃至のいずれか一項に記載の製造方法で得られた油脂を食品に添加することを特徴とする食品の異風味を抑制する方法であって、前記異風味が酸味、酸臭である、前記方法
A method for suppressing an off-flavor of a food, which comprises adding an oil or fat obtained by the production method according to any one of claims 1 to 3 to a food, wherein the off-flavor is an acidity or an acid odor. The method .
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