JP6882661B2 - Laminate peeling container - Google Patents

Laminate peeling container Download PDF

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JP6882661B2
JP6882661B2 JP2016227195A JP2016227195A JP6882661B2 JP 6882661 B2 JP6882661 B2 JP 6882661B2 JP 2016227195 A JP2016227195 A JP 2016227195A JP 2016227195 A JP2016227195 A JP 2016227195A JP 6882661 B2 JP6882661 B2 JP 6882661B2
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outside air
introduction hole
air introduction
inner bag
outer shell
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JP2018083646A (en
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真輔 樽野
真輔 樽野
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Kyoraku Co Ltd
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Kyoraku Co Ltd
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Description

本発明は、積層剥離容器に関する。 The present invention relates to a laminated stripping container.

従来、外殻と内袋とを有し且つ内容物の減少に伴って内袋が外殻から剥離し収縮する容器本体と、外殻と内袋の間の中間空間と容器本体の外部空間との間の空気の出入りを調節する逆止弁とを備える積層剥離容器が知られている(例えば、特許文献1〜2)。
特許文献1では、容器本体の口部に取り付けるキャップに弁が内蔵されている。
特許文献2では、外殻の胴部の内側に弁が設けられている。
Conventionally, a container body having an outer shell and an inner bag and the inner bag peeling off from the outer shell and shrinking as the contents decrease, and an intermediate space between the outer shell and the inner bag and an outer space of the container body. Laminated stripping containers are known that include a check valve that regulates the inflow and outflow of air between them (for example, Patent Documents 1 and 2).
In Patent Document 1, a valve is built in a cap attached to the mouth of the container body.
In Patent Document 2, a valve is provided inside the body of the outer shell.

特開2013−35557号公報Japanese Unexamined Patent Publication No. 2013-35557 特開平4−267727号公報Japanese Unexamined Patent Publication No. 4-267727

特許文献1の構成では、キャップの構造が複雑になってしまうため、生産コストの増大に繋がる。特許文献2の構成では、外殻の胴部の内側に逆止弁を接着するという面倒な工程が必要であり、生産コストの増大に繋がる。 In the configuration of Patent Document 1, the structure of the cap becomes complicated, which leads to an increase in production cost. The configuration of Patent Document 2 requires a troublesome process of adhering a check valve to the inside of the body of the outer shell, which leads to an increase in production cost.

本発明はこのような事情に鑑みてなされたものであり、生産性に優れた積層剥離容器の製造方法を提供するものである。 The present invention has been made in view of such circumstances, and provides a method for manufacturing a laminated stripping container having excellent productivity.

本発明によれば、外殻と内袋とを有する容器本体を形成する容器本体形成工程と、前記容器本体の、内容物を収容する収容部において前記外殻のみを貫通する外気導入孔を形成する外気導入孔形成工程と、前記外気導入孔の前記内袋側の縁部を押圧する押圧工程と、前記外気導入孔を開閉可能な弁部材を前記外殻に装着する弁部材装着工程を備える、積層剥離容器の製造方法が提供される。 According to the present invention, a container body forming step of forming a container body having an outer shell and an inner bag, and an outside air introduction hole penetrating only the outer shell are formed in a storage portion of the container body for accommodating the contents. A step of forming an outside air introduction hole, a pressing step of pressing the edge of the outside air introduction hole on the inner bag side, and a valve member mounting step of mounting a valve member capable of opening and closing the outside air introduction hole on the outer shell are provided. , A method for manufacturing a laminated peeling container is provided.

本発明者は鋭意検討を行ったところ、外殻に外気導入孔を形成し、外殻の外側から、外殻の外気導入孔に弁部材を押し込むことによって弁部材を外殻に装着できるようにした。このような構成によれば、キャップには逆止弁を設ける必要がなく、且つ弁部材を容易に取り付け可能であるので、構造がシンプルであり、生産性が高い。 As a result of diligent studies, the present inventor has formed an outside air introduction hole in the outer shell so that the valve member can be attached to the outer shell by pushing the valve member into the outside air introduction hole of the outer shell from the outside of the outer shell. did. According to such a configuration, it is not necessary to provide a check valve on the cap, and the valve member can be easily attached, so that the structure is simple and the productivity is high.

また、さらに詳細に検討を行ったところ、外殻に外気導入孔を形成する際に、外気導入孔にバリが発生し、弁部材と干渉してしまう場合があることが分かった。 Further, as a result of further detailed examination, it was found that when the outside air introduction hole is formed in the outer shell, burrs may be generated in the outside air introduction hole and may interfere with the valve member.

このような問題に対する対策を検討したところ、外気導入孔の内袋側の縁部を外気導入孔の径方向外側に向かって押圧する押圧工程を、弁部材装着工程の前に行っておくことによって、バリが外気導入孔に対して外側に傾斜し、弁部材と干渉することを防ぐことが可能であることを見出し、本発明の完成に到った。 When countermeasures against such problems were examined, a pressing step of pressing the edge of the outside air introduction hole on the inner bag side toward the outside in the radial direction of the outside air introduction hole was performed before the valve member mounting step. , It has been found that it is possible to prevent the burr from inclining outward with respect to the outside air introduction hole and interfering with the valve member, and the present invention has been completed.

以下、本発明の種々の実施形態を例示する。以下に示す実施形態は互いに組み合わせ可能である。 Hereinafter, various embodiments of the present invention will be illustrated. The embodiments shown below can be combined with each other.

好ましくは、前記押圧工程において、前記外気導入孔の前記内袋側の縁部は、前記外気導入孔に挿入する挿入具により押圧される。 Preferably, in the pressing step, the edge of the outside air introduction hole on the inner bag side is pressed by an insertion tool inserted into the outside air introduction hole.

好ましくは、前記挿入具は前記外気導入孔よりも径の大きい膨径部を有し、前記縁部は前記膨径部が前記外気導入孔に挿入されることにより押圧される。 Preferably, the inserter has a bulging portion having a diameter larger than that of the outside air introduction hole, and the edge portion is pressed by inserting the bulging portion into the outside air introduction hole.

好ましくは、前記挿入具は前記膨径部の先端側に前記膨径部よりも径の小さい先端部を有し、当該先端部により前記内袋を前記容器本体の内側に押し込むことによって、前記膨径部が前記外気導入孔に挿入される前に前記内袋を前記外殻から離間させる。 Preferably, the inserter has a tip portion having a diameter smaller than that of the bulging portion on the tip end side of the bulging portion, and the swelling is performed by pushing the inner bag into the inside of the container body by the tip portion. The inner bag is separated from the outer shell before the diameter portion is inserted into the outside air introduction hole.

好ましくは、前記膨径部の先端側及び基端側はそれぞれテーパ状に形成され、前記膨径部の基端側の傾斜は前記膨径部の先端側の傾斜よりもなだらかに形成される。 Preferably, the tip end side and the proximal end side of the bulging portion are formed in a tapered shape, and the inclination of the proximal end side of the bulging portion is formed more gently than the inclination of the distal end side of the bulging portion.

また、本発明によれば、外殻と内袋とを有し且つ内容物の減少に伴って前記内袋が前記外殻から収縮する容器本体と、前記外殻のみを貫通する外気導入孔を開閉可能な弁部材とを備える積層剥離容器であって、前記弁部材は、前記外気導入孔に挿通され且つ前記外気導入孔に対してスライド移動可能な軸部と、前記軸部の前記内袋側に設けられ且つ前記軸部よりも断面積が大きい蓋部とを備えており、前記外気導入孔の前記内袋側の縁部に形成されるバリが、前記外気導入孔に対し外側に向かって傾斜している、積層剥離容器が提供される。 Further, according to the present invention, a container body having an outer shell and an inner bag and the inner bag shrinking from the outer shell as the contents decrease, and an outside air introduction hole penetrating only the outer shell are provided. A laminated peeling container including a valve member that can be opened and closed, the valve member having a shaft portion that is inserted into the outside air introduction hole and slidable with respect to the outside air introduction hole, and an inner bag of the shaft portion. It is provided with a lid portion provided on the side and having a larger cross-sectional area than the shaft portion, and burrs formed on the edge portion of the outside air introduction hole on the inner bag side face outward with respect to the outside air introduction hole. A laminated stripping container that is tilted is provided.

好ましくは、前記蓋部は、前記軸部側に向かって傾斜し且つ前記外気導入孔の前記内袋側の縁部と当接する傾斜面を有しており、前記バリの傾斜角が、前記傾斜面の傾斜角と略同一又は前記傾斜面の傾斜角よりも大きくなるよう形成される。 Preferably, the lid portion has an inclined surface that is inclined toward the shaft portion side and is in contact with the edge portion of the outside air introduction hole on the inner bag side, and the inclination angle of the burr is the inclination. It is formed so as to be substantially the same as the inclination angle of the surface or larger than the inclination angle of the inclined surface.

本発明の第1実施形態の積層剥離容器1の斜視図である。It is a perspective view of the laminated peeling container 1 of 1st Embodiment of this invention. 図1の積層剥離容器1の口部9及び外気導入孔15付近の拡大断面図である。It is an enlarged cross-sectional view around the mouth portion 9 and the outside air introduction hole 15 of the laminated peeling container 1 of FIG. 弁部材5の拡大図であり、(a)は斜視図、(b)は側面図である。It is an enlarged view of the valve member 5, (a) is a perspective view, and (b) is a side view. 外層11及び内層13の層構成を示す断面図である。It is sectional drawing which shows the layer structure of the outer layer 11 and the inner layer 13. 図1の積層剥離容器1の製造工程を示す。The manufacturing process of the laminated peeling container 1 of FIG. 1 is shown. 図1の積層剥離容器1の、図5に続く製造工程を示し、特に、外気導入孔形成及び内層予備剥離工程を示す。The manufacturing process of the laminated peeling container 1 of FIG. 1 following FIG. 5 is shown, and in particular, the outside air introduction hole forming and the inner layer preliminary peeling step are shown. 図6において外気導入孔15の形成に利用される穴あけドリル30の構成を示し、(a)は正面図、(b)は左側面図、(c)はA−A断面図、(d)は領域Bの拡大図、(e)は領域Cの拡大図である。6A and 6B show the configuration of a drilling drill 30 used for forming the outside air introduction hole 15, where FIG. 6A is a front view, FIG. 6B is a left side view, FIG. 6C is a sectional view taken along the line AA, and FIG. 6D is a sectional view taken along the line AA. An enlarged view of the area B and (e) is an enlarged view of the area C. 図6において外気導入孔15の形成に利用される穴あけドリル30の別の構成を示し、(a)は正面図、(b)は左側面図である。6A and 6B show another configuration of the drilling drill 30 used for forming the outside air introduction hole 15, where FIG. 6A is a front view and FIG. 6B is a left side view. 図1の積層剥離容器1の、図6に続く製造工程を示し、特に、内袋離間工程及び押圧工程を示す。The manufacturing process of the laminated peeling container 1 of FIG. 1 following FIG. 6 is shown, and in particular, the inner bag separating step and the pressing step are shown. 図9の内袋離間工程及び押圧工程の説明図であり、(a)〜(c)は内袋離間工程、(c)〜(e)は押圧工程を示す。9 is an explanatory view of an inner bag separating step and a pressing step, where (a) to (c) show an inner bag separating step and (c) to (e) show a pressing step. 図10の押圧工程において、外気導入孔15に形成されるバリBrが変形する様子を示す説明図である。It is explanatory drawing which shows how the burr Br formed in the outside air introduction hole 15 is deformed in the pressing process of FIG. 弁部材5を外気導入孔15に装着した状態を示す図であり、(a)は側面図、(b)は(a)の要部拡大図である。It is a figure which shows the state which the valve member 5 is attached to the outside air introduction hole 15, (a) is a side view, (b) is an enlarged view of the main part of (a). 図1の積層剥離容器1の、図9に続く工程を示す。The process following FIG. 9 of the laminated peeling container 1 of FIG. 1 is shown. 図1の積層剥離容器1の使用方法を示す説明図である。It is explanatory drawing which shows the usage method of the laminated peeling container 1 of FIG. 図9の内袋離間工程及び押圧工程の別の方法を示す図であり、(a)〜(b)は内袋離間工程、(c)は押圧工程を示す。9 is a diagram showing another method of the inner bag separating step and the pressing step, in which FIGS. 9A to 9B show an inner bag separating step and FIG. 9C shows a pressing step.

以下、本発明の実施形態について説明する。以下に示す実施形態中で示した各種特徴事項は、互いに組み合わせ可能である。また、各特徴について独立して発明が成立する。 Hereinafter, embodiments of the present invention will be described. The various features shown in the embodiments shown below can be combined with each other. In addition, the invention is independently established for each feature.

図1に示すように、本発明の一実施形態の積層剥離容器1は、容器本体3と、弁部材5を備える。容器本体3は、内容物を収容する収容部7と、収容部7から内容物を吐出する口部9を備える。 As shown in FIG. 1, the laminated peeling container 1 according to the embodiment of the present invention includes a container body 3 and a valve member 5. The container body 3 includes an accommodating portion 7 for accommodating the contents and a mouth portion 9 for discharging the contents from the accommodating portion 7.

図2に示すように、容器本体3は、収容部7及び口部9において、外層11と内層13を備えており、外層11によって外殻12が構成され、内層13によって内袋14が構成される。内容物の減少に伴って内層13が外層11から剥離することによって、内袋14が外殻12から剥離して収縮する。 As shown in FIG. 2, the container body 3 includes an outer layer 11 and an inner layer 13 in the accommodating portion 7 and the mouth portion 9, the outer layer 11 constitutes the outer shell 12, and the inner layer 13 constitutes the inner bag 14. To. As the content is reduced, the inner layer 13 is peeled from the outer layer 11, so that the inner bag 14 is peeled from the outer shell 12 and contracts.

口部9は、雄ネジ部9dが設けられている。雄ネジ部9dには、雌ねじを有するキャップやポンプなどが取り付けられる。図2には、インナーリング25を有するキャップ23の一部を図示している。インナーリング25の外径は、口部9の内径と略同じであり、インナーリング25の外面が口部9の当接面9aに当接することによって内容物の漏れ出しが防がれる。 The mouth portion 9 is provided with a male screw portion 9d. A cap having a female screw, a pump, or the like is attached to the male screw portion 9d. FIG. 2 illustrates a part of the cap 23 having the inner ring 25. The outer diameter of the inner ring 25 is substantially the same as the inner diameter of the mouth portion 9, and the outer surface of the inner ring 25 comes into contact with the contact surface 9a of the mouth portion 9 to prevent leakage of the contents.

また、収容部7には、外殻12と内袋14の間の中間空間21と、容器本体3の外部空間Sとの間の空気の出入りを調節する弁部材5が設けられている。外殻12には、収容部7において中間空間21と外部空間Sを連通する外気導入孔15が設けられている。外気導入孔15は、外殻12にのみ設けられた貫通孔であり、内袋14には到達していない。図2及び図3に示すように、弁部材5は、外気導入孔15内に配置される軸部5aと、外気導入孔15を閉塞可能な形状を有し且つ中間空間21に配置される蓋部5cと、軸部5aの外部空間S側に設けられ且つ弁部材5が外殻12の内側に入り込むことを防ぐ係止部5bを備える。軸部5aの直径は、外気導入孔15の直径よりも小さく外気導入孔15に対してスライド移動可能である。また、蓋部5cの直径は、外気導入孔15の直径よりも大きく、軸部5aよりも断面積が大きくなっている。 Further, the accommodating portion 7 is provided with a valve member 5 for adjusting the inflow and outflow of air between the intermediate space 21 between the outer shell 12 and the inner bag 14 and the outer space S of the container body 3. The outer shell 12 is provided with an outside air introduction hole 15 that communicates the intermediate space 21 and the outer space S in the accommodating portion 7. The outside air introduction hole 15 is a through hole provided only in the outer shell 12, and does not reach the inner bag 14. As shown in FIGS. 2 and 3, the valve member 5 has a shaft portion 5a arranged in the outside air introduction hole 15 and a lid having a shape capable of closing the outside air introduction hole 15 and arranged in the intermediate space 21. A portion 5c and a locking portion 5b provided on the outer space S side of the shaft portion 5a and preventing the valve member 5 from entering the inside of the outer shell 12 are provided. The diameter of the shaft portion 5a is smaller than the diameter of the outside air introduction hole 15 and can be slidably moved with respect to the outside air introduction hole 15. Further, the diameter of the lid portion 5c is larger than the diameter of the outside air introduction hole 15, and the cross-sectional area is larger than that of the shaft portion 5a.

蓋部5cは、外殻12を圧縮した際に外気導入孔15を閉塞させるように構成され、軸部5aに近づくにつれて断面積が小さくなるようにテーパー面5dを備える。図3(b)に示すテーパー面5dの傾斜角θ1は、軸部5aが延びる方向Dに対して15〜45度であることが好ましく、20〜35度がさらに好ましい。傾斜角θ1が大きすぎるとエアー漏れが生じやすく、小さすぎると弁部材5が長くなってしまうからである。 The lid portion 5c is configured to close the outside air introduction hole 15 when the outer shell 12 is compressed, and is provided with a tapered surface 5d so that the cross-sectional area becomes smaller as it approaches the shaft portion 5a. The inclination angle θ1 of the tapered surface 5d shown in FIG. 3B is preferably 15 to 45 degrees with respect to the direction D in which the shaft portion 5a extends, and more preferably 20 to 35 degrees. This is because if the inclination angle θ1 is too large, air leakage is likely to occur, and if it is too small, the valve member 5 becomes long.

このような構成により、外殻12を圧縮すると、中間空間21内の圧力が外圧よりも高くなって、この圧力差によって蓋部5cが外気導入孔15に対してさらに強く押し付けられて、蓋部5cが外気導入孔15を閉塞する。蓋部5cにはテーパー面5dが設けられているので、蓋部5cが容易に外気導入孔15に嵌って外気導入孔15を閉塞する。 With such a configuration, when the outer shell 12 is compressed, the pressure in the intermediate space 21 becomes higher than the external pressure, and the lid portion 5c is pressed more strongly against the outside air introduction hole 15 by this pressure difference, and the lid portion 5c closes the outside air introduction hole 15. Since the lid portion 5c is provided with the tapered surface 5d, the lid portion 5c easily fits into the outside air introduction hole 15 and closes the outside air introduction hole 15.

この状態で外殻12をさらに圧縮すると、中間空間21内の圧力が高まり、その結果、内袋14が圧縮されて、内袋14内の内容物が吐出される。また、外殻12への圧縮力を解除すると、外殻12が自身の弾性によって復元しようとする。この際、蓋部5cが外気導入孔15から離れて、外気導入孔15の閉塞が解除されて、中間空間21内に外気が導入される。また、係止部5bが外気導入孔15を塞いでしまわないように、係止部5bには流通路5wが設けられており、係止部5bが外殻12に当接した状態でも、流通路5w及び外気導入孔15を通じて、外気が中間空間21内に導入可能になっている。 When the outer shell 12 is further compressed in this state, the pressure in the intermediate space 21 increases, and as a result, the inner bag 14 is compressed and the contents in the inner bag 14 are discharged. Further, when the compressive force on the outer shell 12 is released, the outer shell 12 tries to be restored by its own elasticity. At this time, the lid portion 5c is separated from the outside air introduction hole 15, the blockage of the outside air introduction hole 15 is released, and the outside air is introduced into the intermediate space 21. Further, the locking portion 5b is provided with a flow passage 5w so that the locking portion 5b does not block the outside air introduction hole 15, and even when the locking portion 5b is in contact with the outer shell 12, it can be distributed. The outside air can be introduced into the intermediate space 21 through the road 5w and the outside air introduction hole 15.

弁部材5は、蓋部5cが外気導入孔15を押し広げながら、蓋部5cを中間空間21内に挿入することによって容器本体3に装着することができる。そのため、蓋部5cの先端は、先細り形状になっていることが好ましい。このような弁部材5は、容器本体3の外側から蓋部5cを中間空間21内に押し込むだけで装着可能なので、生産性に優れている。また、弁部材5は、射出成形などによって成形される。 The valve member 5 can be attached to the container body 3 by inserting the lid portion 5c into the intermediate space 21 while the lid portion 5c expands the outside air introduction hole 15. Therefore, it is preferable that the tip of the lid portion 5c has a tapered shape. Since such a valve member 5 can be mounted by simply pushing the lid portion 5c into the intermediate space 21 from the outside of the container body 3, it is excellent in productivity. Further, the valve member 5 is molded by injection molding or the like.

収容部7は、弁部材5を取り付けた後にシュリンクフィルムで覆われる。この際に、弁部材5がシュリンクフィルムに干渉しないように、弁部材5は、収容部7に設けられた弁部材取付凹部7aに装着される。また、弁部材取付凹部7aがシュリンクフィルムで密閉されてしまわないように弁部材取付凹部7aから口部9の方向に延びる空気流通溝7bが設けられる(図1参照)。 The accommodating portion 7 is covered with a shrink film after the valve member 5 is attached. At this time, the valve member 5 is mounted in the valve member mounting recess 7a provided in the accommodating portion 7 so that the valve member 5 does not interfere with the shrink film. Further, an air flow groove 7b extending in the direction of the mouth portion 9 from the valve member mounting recess 7a is provided so that the valve member mounting recess 7a is not sealed with the shrink film (see FIG. 1).

次に、図4を用いて、容器本体3の層構成について説明する。容器本体3は、外層11と内層13を備える。外層11は、復元性が高くなるように、内層13よりも肉厚に形成される。 Next, the layer structure of the container body 3 will be described with reference to FIG. The container body 3 includes an outer layer 11 and an inner layer 13. The outer layer 11 is formed to be thicker than the inner layer 13 so as to have high resilience.

外層11は、例えば、低密度ポリエチレン、直鎖状低密度ポリエチレン、高密度ポリエチレン、ポリプロピレン、エチレン−プロピレン共重合体及びその混合物などで構成される。外層11は、複数層構成であってもよい。例えば、図4に示すように、リプロ層11cの両側をバージン材で形成した層11a、11bで挟んだ構成であってもよい。ここで、リプロ層とは、容器の成形時にでたバリをリサイクルして使用した層をいう。また、外層11は、復元性が高くなるように、内層13よりも肉厚に形成される。外層11は、プロピレンと別のモノマーとの間のランダム共重合体からなることが好ましい。プロピレンと共重合されるモノマーとしては、ポリプロピレンのホモポリマーに比べた場合のランダム共重合体の耐衝撃性を向上させるものであればよく、エチレンが特に好ましい。プロピレンとエチレンのランダム共重合体の場合、エチレンの含有量は、5〜30mol%が好ましい。ランダム共重合体の重量平均分子量は、10〜50万が好ましく、10〜30万がさらに好ましい。また、ランダム共重合体の引張弾性率は、400〜1600MPaが好ましく、1000〜1600MPaが好ましい。引張弾性率がこのような範囲の場合に、形状復元性が特に良好であるからである。容器が過度に硬いと、容器の使用感が悪くなるため、ランダム共重合体に、例えば、直鎖状低密度ポリエチレンなどの柔軟材料を混合して外層11を構成してもよい。 The outer layer 11 is composed of, for example, low-density polyethylene, linear low-density polyethylene, high-density polyethylene, polypropylene, an ethylene-propylene copolymer and a mixture thereof. The outer layer 11 may have a plurality of layers. For example, as shown in FIG. 4, both sides of the repro layer 11c may be sandwiched between layers 11a and 11b formed of a virgin material. Here, the repro layer refers to a layer obtained by recycling burrs generated during molding of a container. Further, the outer layer 11 is formed to be thicker than the inner layer 13 so as to have high resilience. The outer layer 11 is preferably made of a random copolymer between propylene and another monomer. As the monomer copolymerized with propylene, ethylene is particularly preferable as long as it improves the impact resistance of the random copolymer as compared with the homopolymer of polypropylene. In the case of a random copolymer of propylene and ethylene, the ethylene content is preferably 5 to 30 mol%. The weight average molecular weight of the random copolymer is preferably 100,000 to 500,000, more preferably 100,000 to 300,000. The tensile elastic modulus of the random copolymer is preferably 400 to 1600 MPa, preferably 1000 to 1600 MPa. This is because the shape resilience is particularly good when the tensile elastic modulus is in such a range. If the container is excessively hard, the usability of the container deteriorates. Therefore, a flexible material such as linear low-density polyethylene may be mixed with the random copolymer to form the outer layer 11.

内層13は、容器外面側に設けられたEVOH層13aと、EVOH層13aの容器内面側に設けられた内面層13bと、EVOH層13aと内面層13bの間に設けられた接着層13cを備える。EVOH層13aを設けることでガスバリア性、及び外層11からの剥離性を向上させることができる。 The inner layer 13 includes an EVOH layer 13a provided on the outer surface side of the container, an inner surface layer 13b provided on the inner surface side of the container of the EVOH layer 13a, and an adhesive layer 13c provided between the EVOH layer 13a and the inner surface layer 13b. .. By providing the EVOH layer 13a, the gas barrier property and the peelability from the outer layer 11 can be improved.

EVOH層13aは、エチレン−ビニルアルコール共重合体(EVOH)樹脂からなる層であり、エチレンと酢酸ビニル共重合物の加水分解により得られる。EVOH樹脂のエチレン含有量は、例えば25〜50mol%であり、酸素バリア性の観点から32mol%以下が好ましい。エチレン含有量の下限は、特に規定されないが、エチレン含有量が少ないほどEVOH層13aの柔軟性が低下しやすいので25mol%以上が好ましい。また、EVOH層13aは、酸素吸収剤を含有することが好ましい。酸素吸収剤をEVOH層13aに含有させることにより、EVOH層13aの酸素バリア性をさらに向上させることができる。 The EVOH layer 13a is a layer made of an ethylene-vinyl alcohol copolymer (EVOH) resin, and is obtained by hydrolysis of an ethylene-vinyl acetate copolymer. The ethylene content of the EVOH resin is, for example, 25 to 50 mol%, preferably 32 mol% or less from the viewpoint of oxygen barrier properties. The lower limit of the ethylene content is not particularly specified, but it is preferably 25 mol% or more because the flexibility of the EVOH layer 13a tends to decrease as the ethylene content decreases. Further, the EVOH layer 13a preferably contains an oxygen absorber. By containing the oxygen absorber in the EVOH layer 13a, the oxygen barrier property of the EVOH layer 13a can be further improved.

内面層13bは、積層剥離容器1の内容物に接触する層であり、例えば、低密度ポリエチレン、直鎖状低密度ポリエチレン、高密度ポリエチレン、ポリプロピレン、エチレン−プロピレン共重合体及びその混合物などのポリオレフィンからなり、低密度ポリエチレン又は直鎖状低密度ポリエチレンからなることが好ましい。内面層13bを構成する樹脂の引張弾性率は、50〜300MPaが好ましく、70〜200MPaが好ましい。引張弾性率がこのような範囲の場合に、内面層13bが特に柔軟であるからである。引張弾性率は、具体的には例えば、50、100、150、200、250、300Mpaであり、ここで例示した数値の何れか2つの間の範囲内であってもよい。 The inner surface layer 13b is a layer that comes into contact with the contents of the laminated stripping container 1, and is, for example, a polyolefin such as low density polyethylene, linear low density polyethylene, high density polyethylene, polypropylene, ethylene-propylene copolymer and a mixture thereof. It is preferably made of low density polyethylene or linear low density polyethylene. The tensile elastic modulus of the resin constituting the inner surface layer 13b is preferably 50 to 300 MPa, preferably 70 to 200 MPa. This is because the inner surface layer 13b is particularly flexible when the tensile elastic modulus is in such a range. Specifically, the tensile elastic modulus is, for example, 50, 100, 150, 200, 250, 300 Mpa, and may be within the range between any two of the numerical values exemplified here.

接着層13cは、EVOH層13aと内面層13bとを接着する機能を有する層であり、例えば上述したポリオレフィンにカルボキシル基を導入した酸変性ポリオレフィン(例:無水マレイン酸変性ポリエチレン)を添加したものや、エチレン酢酸ビニル共重合体(EVA)である。接着層13cの一例は、低密度ポリエチレン又は直鎖状低密度ポリエチレンと、酸変性ポリエチレンの混合物である。 The adhesive layer 13c is a layer having a function of adhering the EVOH layer 13a and the inner surface layer 13b. For example, an acid-modified polyolefin in which a carboxyl group is introduced into the above-mentioned polyolefin (eg, maleic anhydride-modified polyethylene) is added. , Ethylene Vinyl Acetate Copolymer (EVA). An example of the adhesive layer 13c is a mixture of low-density polyethylene or linear low-density polyethylene and acid-modified polyethylene.

次に、本実施形態の積層剥離容器1の製造方法の一例を説明する。 Next, an example of the manufacturing method of the laminated peeling container 1 of the present embodiment will be described.

まず、図5(a)に示すように、製造すべき容器本体3に対応する積層構造(一例は、容器内面側から順に、PE層/接着層/EVOH層/PP層/リプロ層/PP層の積層構造)を備えた溶融状態の積層パリソンを押出し、この溶融状態の積層パリソンをブロー成形用の分割金型にセットし、分割金型を閉じる。次に、図5(b)に示すように、容器本体3の口部9側の開口部にブローノズルを挿入し、型締めを行った状態で分割金型のキャビティー内にエアーを吹き込む。 First, as shown in FIG. 5A, a laminated structure corresponding to the container body 3 to be manufactured (for example, PE layer / adhesive layer / EVOH layer / PP layer / repro layer / PP layer in order from the inner surface side of the container). The laminated polypropylene in the molten state having the laminated structure of the above) is extruded, the laminated polypropylene in the molten state is set in the split mold for blow molding, and the split mold is closed. Next, as shown in FIG. 5B, a blow nozzle is inserted into the opening on the mouth 9 side of the container body 3, and air is blown into the cavity of the split mold in a state where the mold is tightened.

次に、図5(c)に示すように、分割金型を開いて、ブロー成形品を取り出す。分割金型は、弁部材取付凹部7a、空気流通溝7b、底シール突出部27などの容器本体3の各種形状がブロー成形品に形成されるようなキャビティー形状を有する。また、分割金型には、底シール突出部27の下側にピンチオフ部が設けられており、底シール突出部27の下側の部分に下バリが形成されるので、これを除去する。以上の工程によって、外殻12と内袋14とを有する容器本体3が形成される(容器本体形成工程)。 Next, as shown in FIG. 5C, the split mold is opened and the blow-molded product is taken out. The split mold has a cavity shape such that various shapes of the container body 3 such as the valve member mounting recess 7a, the air flow groove 7b, and the bottom seal protrusion 27 are formed on the blow molded product. Further, the split mold is provided with a pinch-off portion on the lower side of the bottom seal protruding portion 27, and a lower burr is formed on the lower portion of the bottom seal protruding portion 27, and this is removed. By the above steps, the container body 3 having the outer shell 12 and the inner bag 14 is formed (container body forming step).

次に、図5(d)に示すように、取り出した容器本体3を整列させる。 Next, as shown in FIG. 5 (d), the taken-out container main body 3 is aligned.

次に、図6(a)〜(c)に示すように、穿孔装置2を用いて、容器本体3の外殻12に外気導入孔15を形成する(外気導入孔形成工程)。以下、この工程について詳細に説明する。 Next, as shown in FIGS. 6A to 6C, the outside air introduction hole 15 is formed in the outer shell 12 of the container body 3 by using the drilling device 2 (outside air introduction hole forming step). Hereinafter, this step will be described in detail.

まず、図6(a)に示すように、容器本体3を穿孔装置2に近接した位置にセットする。穿孔装置2は、本体部31と先端部32を有する穴あけドリル30と、伝達ベルト2bを通じて穴あけドリル30を回転駆動するモーター2cを備える。穿孔装置2は、サーボモータの回転によって穿孔装置2を単軸移動させるサーボシリンダ(図示せず)によって支持されており、図6(a)の矢印X1方向及び図6(c)の矢印X2方向に移動可能に構成されている。このような構成によって、穴あけドリル30を回転させながら、その先端部32を容器本体3の外殻12に押し付けることが可能になっている。また、穿孔装置2の位置と移動速度をサーボモータによって制御することによって、タクトタイムを短縮することが可能になっている。 First, as shown in FIG. 6A, the container body 3 is set at a position close to the drilling device 2. The drilling device 2 includes a drilling drill 30 having a main body portion 31 and a tip portion 32, and a motor 2c that rotationally drives the drilling drill 30 through a transmission belt 2b. The drilling device 2 is supported by a servo cylinder (not shown) that uniaxially moves the drilling device 2 by rotation of a servomotor, and is supported by an arrow X1 direction in FIG. 6 (a) and an arrow X2 direction in FIG. 6 (c). It is configured to be movable to. With such a configuration, it is possible to press the tip portion 32 of the drill 30 against the outer shell 12 of the container body 3 while rotating the drill 30. Further, by controlling the position and the moving speed of the drilling device 2 by the servomotor, it is possible to shorten the tact time.

穴あけドリル30には、本体部31から先端部32に渡って延びる空洞33が設けられており(図7、図8を参照)、空洞33に連通する通気パイプ2eが連結されている。通気パイプ2eは、図示しない吸排気装置に連結されている。これによって、穴あけドリル30内部からのエアー吸引及び穴あけドリル30内部へのエアーの吹込が可能になっている。 The drilling drill 30 is provided with a cavity 33 extending from the main body 31 to the tip 32 (see FIGS. 7 and 8), and a ventilation pipe 2e communicating with the cavity 33 is connected to the drill 30. The ventilation pipe 2e is connected to an intake / exhaust device (not shown). This makes it possible to suck air from the inside of the drill 30 and blow air into the drill 30.

穴あけドリル30の先端部32は、図7に示すように、断面C字状の筒状である。先端部32には、平坦面34と切欠部37が設けられており、切欠部37の側面が刃部38となっている。先端部32の側面32aは、図7に示すように、平坦面34に対して垂直になっていてもよく、図8に示すように、平坦面34に近づくにつれて中心に向かって傾斜するテーパー面になっていてもよい。後者の場合、形成される外気導入孔15の縁が外側に向かって拡がるテーパー面となるので、弁部材5を挿入しやすいという利点がある。 As shown in FIG. 7, the tip portion 32 of the drilling drill 30 has a tubular shape having a C-shaped cross section. The tip portion 32 is provided with a flat surface 34 and a notch 37, and the side surface of the notch 37 is a blade 38. As shown in FIG. 7, the side surface 32a of the tip portion 32 may be perpendicular to the flat surface 34, and as shown in FIG. 8, a tapered surface that inclines toward the center as it approaches the flat surface 34. It may be. In the latter case, since the edge of the formed outside air introduction hole 15 becomes a tapered surface that expands outward, there is an advantage that the valve member 5 can be easily inserted.

平坦面34の半径方向の幅Wは、0.1〜0.2mmが好ましく、0.12〜0.18mmがさらに好ましい。幅Wが小さすぎると穿孔時に内袋14が傷つきやすく、幅Wが大きすぎると刃部38が外殻12に接触しにくくなるので、穿孔をスムーズに行いにくい。切欠部37を設ける範囲は、60〜120度が好ましく、75〜105度がさらに好ましい。この範囲が大きすぎると穿孔時に内袋14が傷つきやすく、この範囲が小さすぎると穿孔をスムーズに行いにくい。刃部38における外接面P1に対する傾斜面P2の角度αは、30〜65度が好ましく、40〜55度がさらに好ましい。角度αが小さすぎると穿孔時に内袋14が傷つきやすく、角度αが大きすぎると穿孔をスムーズに行いにくい。 The width W of the flat surface 34 in the radial direction is preferably 0.1 to 0.2 mm, more preferably 0.12 to 0.18 mm. If the width W is too small, the inner bag 14 is easily damaged during drilling, and if the width W is too large, the blade portion 38 is difficult to contact the outer shell 12, so that it is difficult to perform drilling smoothly. The range in which the notch 37 is provided is preferably 60 to 120 degrees, more preferably 75 to 105 degrees. If this range is too large, the inner bag 14 is easily damaged during drilling, and if this range is too small, it is difficult to perform drilling smoothly. The angle α of the inclined surface P2 with respect to the circumscribed surface P1 of the blade portion 38 is preferably 30 to 65 degrees, more preferably 40 to 55 degrees. If the angle α is too small, the inner bag 14 is easily damaged during drilling, and if the angle α is too large, it is difficult to perform drilling smoothly.

また、先端部32の内面35には、先端に向かって広がるテーパー面36が設けられている。これによって、穿孔時に発生する切除片15a(図6(c)を参照)が容器本体3側に残らず、内面35側に移行しやすくなっている。平坦面34に対するテーパー面36の角度は、95〜110度が好ましく、95〜105度がさらに好ましい。言い換えると、図7(e)に示すように、穴あけドリル30の回転軸に平行な方向Xに対するテーパー面36の角度βは、5〜20度が好ましく、5〜15度がさらに好ましい。さらに、内面35には深さ0.05〜0.1mmで幅0.1〜0.2mmの凹形又はV形の略環状の溝39を、平坦面34に垂直な方向(穴あけドリル30の回転軸に平行な方向X)に0.2〜1mmピッチで施すことが好ましく、この場合、切除片15aがさらに内面35に移行しやすくなる。溝39のピッチは、さらに好ましくは、0.3〜0.7mmである。また、内面35にはブラスト処理が施すことが好ましく、切除片15aがさらに内面35に移行しやすくなる。 Further, the inner surface 35 of the tip portion 32 is provided with a tapered surface 36 that extends toward the tip. As a result, the excision piece 15a (see FIG. 6C) generated at the time of drilling does not remain on the container body 3 side, and easily moves to the inner surface 35 side. The angle of the tapered surface 36 with respect to the flat surface 34 is preferably 95 to 110 degrees, more preferably 95 to 105 degrees. In other words, as shown in FIG. 7E, the angle β of the tapered surface 36 with respect to the direction X parallel to the rotation axis of the drill 30 is preferably 5 to 20 degrees, more preferably 5 to 15 degrees. Further, the inner surface 35 is provided with a concave or V-shaped substantially annular groove 39 having a depth of 0.05 to 0.1 mm and a width of 0.1 to 0.2 mm in a direction perpendicular to the flat surface 34 (of the drilling drill 30). It is preferable to apply the cutting piece 15a in the direction X) parallel to the rotation axis at a pitch of 0.2 to 1 mm, and in this case, the cutting piece 15a is more likely to move to the inner surface 35. The pitch of the grooves 39 is more preferably 0.3 to 0.7 mm. Further, it is preferable that the inner surface 35 is blasted, and the excised piece 15a is more easily transferred to the inner surface 35.

次に、図6(b)に示すように、穴あけドリル30を回転させながら平坦面34を外殻12に押し付ける。この際に、平坦面34が外殻12に少しめり込む。その結果、外殻12が部分的に切欠部37に入り込んで、刃部38が外殻12に接触して、外殻12が切り込まれる。平坦面34が外殻12と内袋14の境界に到達すると、外殻12が円形にくり抜かれて丸穴状の外気導入孔15が形成される。この際、穴あけドリル30の内部のエアーを吸引することによって、外殻12がくり抜かれて形成される切除片15aが、穴あけドリル30の空洞33内に吸引される。 Next, as shown in FIG. 6B, the flat surface 34 is pressed against the outer shell 12 while rotating the drilling drill 30. At this time, the flat surface 34 is slightly recessed into the outer shell 12. As a result, the outer shell 12 partially enters the notch 37, the blade portion 38 comes into contact with the outer shell 12, and the outer shell 12 is cut. When the flat surface 34 reaches the boundary between the outer shell 12 and the inner bag 14, the outer shell 12 is hollowed out in a circular shape to form a round hole-shaped outside air introduction hole 15. At this time, by sucking the air inside the drill 30, the cut piece 15a formed by hollowing out the outer shell 12 is sucked into the cavity 33 of the drill 30.

平坦面34が外殻12と内袋14の境界に到達した後に、平坦面34を内袋14に対して押し付けると、内袋14は外殻12から剥離されて容器本体3の内側に向かって容易に変形するので、平坦面34が内袋14にめり込むことがなく、内袋14には刃部38が接触せず、内袋14が傷つけられることが抑制される。 When the flat surface 34 is pressed against the inner bag 14 after the flat surface 34 reaches the boundary between the outer shell 12 and the inner bag 14, the inner bag 14 is peeled off from the outer shell 12 and toward the inside of the container body 3. Since it is easily deformed, the flat surface 34 does not sink into the inner bag 14, the blade portion 38 does not come into contact with the inner bag 14, and the inner bag 14 is prevented from being damaged.

本実施形態では、穴あけドリル30は加熱せずに用いており、これによって外気導入孔15の縁が溶融されず、縁がシャープに形成されるという利点がある。また、穴あけドリル30と外殻12との摩擦によって発生する熱による影響を抑制するために、穴あけドリル30は、熱伝導率が高い(例:20℃で35W/(m・℃)以上)材質で形成することが好ましい。なお、穿孔をより容易にするために、穴あけドリル30を加熱してもよい。この場合、穴あけドリル30の熱によって内袋14が溶融しないように、内袋14の最外層を構成する樹脂の融点は、外殻12の最内層を構成する樹脂の融点よりも高いことが好ましい。 In the present embodiment, the drilling drill 30 is used without heating, which has an advantage that the edge of the outside air introduction hole 15 is not melted and the edge is formed sharply. Further, in order to suppress the influence of heat generated by the friction between the drill 30 and the outer shell 12, the drill 30 is made of a material having high thermal conductivity (example: 35 W / (m · ° C) or more at 20 ° C.). It is preferable to form with. The drilling drill 30 may be heated to facilitate drilling. In this case, the melting point of the resin constituting the outermost layer of the inner bag 14 is preferably higher than the melting point of the resin forming the innermost layer of the outer shell 12 so that the inner bag 14 is not melted by the heat of the drilling drill 30. ..

なお、穴あけドリル30によって外部空間S側から外殻12に孔15をあけると、内袋14側、すなわち中間空間21側にバリBrが発生する。このバリBrは、図10(a)、(b)及び図11(a)に示すように、穴あけドリル30の挿入される方向、すなわち外殻12に対して略垂直に延びるよう形成される。なお、図11等において、バリBrは直線状に記載しているが、これはバリBrの形成される向きを示すために便宜的に描いたものであり、実際の形状を表すものではない。実際には、バリBrは製品ごとに不規則に発生する。このような状態で外気導入孔15に弁部材5を取り付けると、バリBrが弁部材5と干渉して、正常に弁部材5が動作しないおそれがあるため、本実施形態では、後述する押圧工程(バリ処理工程)によってバリBrが弁部材5と干渉しないようにしている。 When a hole 15 is drilled in the outer shell 12 from the outer space S side by the drilling drill 30, burr Br is generated on the inner bag 14 side, that is, the intermediate space 21 side. As shown in FIGS. 10 (a), 10 (b) and 11 (a), the burr Br is formed so as to extend in the direction in which the drill 30 is inserted, that is, substantially perpendicular to the outer shell 12. Although the burr Br is shown in a straight line in FIG. 11 and the like, it is drawn for convenience to indicate the direction in which the burr Br is formed, and does not represent the actual shape. In reality, Bali Br occurs irregularly for each product. If the valve member 5 is attached to the outside air introduction hole 15 in such a state, the burr Br may interfere with the valve member 5 and the valve member 5 may not operate normally. (Bali treatment step) prevents the burr Br from interfering with the valve member 5.

次に、図6(c)に示すように、穿孔装置2を矢印X2方向に後退させ、穴あけドリル30の空洞33内にエアーを吹き込むことによって、切除片15aを穴あけドリル30の先端から放出させる。
以上の工程で、外殻12への外気導入孔15の形成が完了する。
Next, as shown in FIG. 6C, the drilling device 2 is retracted in the direction of arrow X2, and air is blown into the cavity 33 of the drilling drill 30 to release the cutting piece 15a from the tip of the drilling drill 30. ..
By the above steps, the formation of the outside air introduction hole 15 in the outer shell 12 is completed.

次に、図6(d)に示すように、ブロアー48を用いて、外気導入孔15を通じて外殻12と内袋14の間にエアーを吹き込むことによって内袋14を外殻12から予備剥離させる(予備剥離工程)。また、外気導入孔15を通じたエアー漏れが無いようにしつつ、規定量のエアーを吹き込むことによって、内袋14の予備剥離の制御が容易になる。予備剥離は、収容部7の全体に対して行ってもよく、収容部7の一部に対して行ってもよいが、予備剥離されていない部位では内袋14のピンホールの有無のチェックができないので、収容部7の略全体において、内袋14を外殻12から予備剥離させることが好ましい。なお、エアーは、別の方法で外殻12と内袋14の間に吹き込んでもよい。例えば、図6(d)に示す上部筒状部41において外殻12に設けた開口部を通じて外殻12と内袋14の間にエアーを吹き込むことができる。 Next, as shown in FIG. 6D, the inner bag 14 is preliminarily peeled from the outer shell 12 by blowing air between the outer shell 12 and the inner bag 14 through the outside air introduction hole 15 using the blower 48. (Preliminary peeling step). Further, by blowing a specified amount of air while preventing air leakage through the outside air introduction hole 15, it becomes easy to control the preliminary peeling of the inner bag 14. The preliminary peeling may be performed on the entire accommodating portion 7 or a part of the accommodating portion 7, but the presence or absence of pinholes in the inner bag 14 is checked at the portion where the pre-peeling is not performed. Therefore, it is preferable that the inner bag 14 is preliminarily peeled from the outer shell 12 in substantially the entire accommodating portion 7. The air may be blown between the outer shell 12 and the inner bag 14 by another method. For example, air can be blown between the outer shell 12 and the inner bag 14 through the opening provided in the outer shell 12 in the upper tubular portion 41 shown in FIG. 6 (d).

次に、図6(e)に示すように、底シール突出部27に熱風を当てて薄肉部27aを軟化させて、底シール突出部27を折り曲げる。 Next, as shown in FIG. 6E, hot air is applied to the bottom seal protruding portion 27 to soften the thin-walled portion 27a, and the bottom seal protruding portion 27 is bent.

次に、図9(a)、(b)に示すように、挿入具42を矢印X1方向で示すように移動させて挿入具42を外気導入孔15から挿入する。そして、挿入具42で内袋14を容器本体3の内側に押し込むことによって内袋14を外殻12から離間させる(内袋離間工程)。この方法によれば、内袋14を局所的に外殻12から大きく離間させることができる。また、これに続いて、挿入具42を矢印X2方向で示すように移動させ、挿入具42に形成された膨径部45(図9(a)、図10参照)により、外気導入孔15の内袋14側の縁部を外気導入孔15の径方向外側に向かって押圧する(押圧工程、ただし、以下ではバリ処理工程とも呼ぶ)。この工程により、外気導入孔形成工程によって外気導入孔15の縁部に形成されたバリBrを弁部材5と干渉しないよう処理することができる。以下、挿入具42を用いた内袋離間工程及び押圧工程(バリ処理工程)について詳細に説明する。 Next, as shown in FIGS. 9A and 9B, the insertion tool 42 is moved as shown in the direction of the arrow X1 to insert the insertion tool 42 through the outside air introduction hole 15. Then, the inner bag 14 is pushed into the inside of the container body 3 by the insertion tool 42 to separate the inner bag 14 from the outer shell 12 (inner bag separation step). According to this method, the inner bag 14 can be locally largely separated from the outer shell 12. Further, following this, the insertion tool 42 is moved as shown in the direction of the arrow X2, and the outside air introduction hole 15 is formed by the enlarged diameter portion 45 (see FIGS. 9A and 10) formed in the insertion tool 42. The edge portion on the inner bag 14 side is pressed toward the outside in the radial direction of the outside air introduction hole 15 (pressing step, but also referred to as a burr treatment step below). By this step, the burr Br formed at the edge of the outside air introduction hole 15 by the outside air introduction hole forming step can be treated so as not to interfere with the valve member 5. Hereinafter, the inner bag separating step and the pressing step (burr processing step) using the inserter 42 will be described in detail.

挿入具42は、図10に示すように、治具に保持される基端部43と、基端部43と連続し、基端部43よりも直径の小さい接続部44と、接続部44と連続し、直径が最も大きい膨径部45と、膨径部45と連続し、先端が丸まった先端部46とを有する棒状の部材である。ここで、先端部46(と接続部44)は、外気導入孔15を押し広げることなく外気導入孔15に挿入可能な直径を有しており、その直径は外気導入孔15の直径と略同一であるか、又は外気導入孔15の直径よりも小さい。外気導入孔15の直径に対する先端部46の直径の比は、0.5〜1.0とするのが好ましく、0.6〜0.8とするのがより好ましく、0.70〜0.75とするのがさらに好ましい。この直径の比は、具体的には例えば、0.5、0.55、0.6、0.65、0.7、0.75、0.8、0.85、0.9、0.95、1.0であり、ここで例示した数値の何れか2つの間の範囲内であってもよい。また、膨径部45の最も径の大きい場所から先端部46の先端までの長さは、外殻12の厚みよりも十分長く、例えば10倍以上取ることが好ましい。 As shown in FIG. 10, the inserter 42 includes a base end portion 43 held by the jig, a connection portion 44 that is continuous with the base end portion 43 and has a diameter smaller than that of the base end portion 43, and a connection portion 44. It is a rod-shaped member having a continuous bulging portion 45 having the largest diameter and a continuous bulging portion 45 and a tip portion 46 having a rounded tip. Here, the tip portion 46 (and the connecting portion 44) has a diameter that can be inserted into the outside air introduction hole 15 without expanding the outside air introduction hole 15, and the diameter thereof is substantially the same as the diameter of the outside air introduction hole 15. Or smaller than the diameter of the outside air introduction hole 15. The ratio of the diameter of the tip portion 46 to the diameter of the outside air introduction hole 15 is preferably 0.5 to 1.0, more preferably 0.6 to 0.8, and 0.70 to 0.75. Is more preferable. Specifically, the ratio of the diameters is, for example, 0.5, 0.55, 0.6, 0.65, 0.7, 0.75, 0.8, 0.85, 0.9, 0. It is 95, 1.0, and may be within the range between any two of the numerical values exemplified here. Further, the length from the portion having the largest diameter of the bulging portion 45 to the tip of the tip portion 46 is sufficiently longer than the thickness of the outer shell 12, for example, preferably 10 times or more.

次に、膨径部45は、図11にも示すように、その先端側の面(挿入面45aとする)及び基端側の面(押圧面45bとする)がともに緩やかなテーパー形状となっており、それぞれ接続部44及び先端部46と滑らかに接続される。なお、ここでいうテーパー状の挿入面45a及び押圧面45bは、外殻12と当接する部分近傍を微視的に見たときの平面であり、巨視的に見た場合には、外側に凸となる円弧状になっていても良い。また、挿入面45aの傾斜は、押圧面45bの傾斜よりもなだらかに形成される。これは、挿入面45aの傾斜を急にすると、挿入具42の挿入時に外殻12と係合して外殻12に弾性エネルギーが蓄積し、膨径部45が外気導入孔15を通過した際に挿入具42にX1方向の力が加わってX1方向に急激に移動することを抑制するためである。 Next, as shown in FIG. 11, the bulging portion 45 has a gentle taper shape on both the front end side surface (referred to as the insertion surface 45a) and the proximal end side surface (referred to as the pressing surface 45b). They are smoothly connected to the connecting portion 44 and the tip portion 46, respectively. The tapered insertion surface 45a and pressing surface 45b referred to here are flat surfaces when the vicinity of the portion in contact with the outer shell 12 is viewed microscopically, and are convex outward when viewed macroscopically. It may be in the shape of an arc. Further, the inclination of the insertion surface 45a is formed more gently than the inclination of the pressing surface 45b. This is because when the insertion surface 45a is steeply inclined, it engages with the outer shell 12 when the insertion tool 42 is inserted, elastic energy is accumulated in the outer shell 12, and the enlarged diameter portion 45 passes through the outside air introduction hole 15. This is to prevent the insertion tool 42 from being subjected to a force in the X1 direction and suddenly moving in the X1 direction.

また、膨径部45の最も太い部分の直径は、外気導入孔15の直径よりも大きくなっており、外気導入孔15の直径に対する膨径部45の直径(最も太い部分)の比は、1.01〜1.06とするのが好ましく、1.02〜1.05とするのがより好ましく、1.03〜1.04とするのがさらに好ましい。また、この直径の比は、具体的には例えば、1.01、1.015、1.02、1.025、1.03、1.035、1.04、1.045、1.05、1.055、1.06であり、ここで例示した数値の何れか2つの間の範囲内であってもよい。膨径部45の直径は、小さすぎると、バリBrが弁部材5と干渉する位置に残ってしまい、大きすぎると、外気導入孔15が変形してしまうことになるが、上記の値とすることで、これらのことを防止することができる。 Further, the diameter of the thickest portion of the bulging portion 45 is larger than the diameter of the outside air introduction hole 15, and the ratio of the diameter of the bulging portion 45 (the thickest portion) to the diameter of the outside air introduction hole 15 is 1. It is preferably 0.01 to 1.06, more preferably 1.02 to 1.05, and even more preferably 1.03 to 1.04. Specifically, the ratio of the diameters is, for example, 1.01, 1.015, 1.02, 1.025, 1.03, 1.035, 1.04, 1.045, 1.05. It is 1.055 and 1.06, and may be within the range between any two of the numerical values exemplified here. If the diameter of the bulging portion 45 is too small, the burr Br will remain at a position where it interferes with the valve member 5, and if it is too large, the outside air introduction hole 15 will be deformed. By doing so, these things can be prevented.

内袋離間工程では、上記のような構成の挿入具42を、図10(a)〜図10(c)に示すように、矢印X1方向に移動させながら外気導入孔15に挿入することによって、図10(b)に示すように、外気導入孔15の近傍において内袋14を外殻12から離間させる。ここで、膨径部45は、外気導入孔15の直径よりも大きな直径を有しているが、膨径部45の先端部46側の挿入面45aが緩やかなテーパ形状をなしていることで、スムーズに外殻12の内側に挿入されるようになっている。また、外殻12は、図10(c)の想像線12aで示すように、外気導入孔15の縁部が内袋14の方向に弾性変形することで、膨径部45が外気導入孔15を通過できるようになっている。 In the inner bag separating step, as shown in FIGS. 10A to 10C, the insertion tool 42 having the above configuration is inserted into the outside air introduction hole 15 while moving in the direction of the arrow X1. As shown in FIG. 10B, the inner bag 14 is separated from the outer shell 12 in the vicinity of the outside air introduction hole 15. Here, the expanded diameter portion 45 has a diameter larger than the diameter of the outside air introduction hole 15, but the insertion surface 45a on the tip end portion 46 side of the expanded diameter portion 45 has a gentle taper shape. , It is designed to be smoothly inserted inside the outer shell 12. Further, in the outer shell 12, as shown by the imaginary line 12a in FIG. 10 (c), the edge portion of the outside air introduction hole 15 is elastically deformed in the direction of the inner bag 14, so that the enlarged diameter portion 45 becomes the outside air introduction hole 15. It is possible to pass through.

なお、内袋14は、復元力が小さいので、一旦、図10(b)に示すような状態になると、挿入具42を抜いても、図10(a)の状態には戻らない。また、図10(a)に示すように、外殻12と内袋14の間には、予備剥離工程によって隙間Gが形成されているので、挿入具42を内袋14に押し当てると、挿入具42からの負荷は広い範囲に分散されて内袋14に伝わることに加えて、内袋14は、容器本体3の内側に向かって容易に変形されるので、内袋14に傷が入ることがない。ただし、外殻12と内袋14の材質によっては、内袋14を外殻12から簡単に剥離させることができる。このような場合等には、予備剥離工程を省略し、内袋離間工程を行っても良い。 Since the inner bag 14 has a small restoring force, once it reaches the state shown in FIG. 10 (b), it does not return to the state shown in FIG. 10 (a) even if the inserter 42 is removed. Further, as shown in FIG. 10A, a gap G is formed between the outer shell 12 and the inner bag 14 by the preliminary peeling step, so that when the inserter 42 is pressed against the inner bag 14, it is inserted. In addition to the load from the tool 42 being distributed over a wide range and being transmitted to the inner bag 14, the inner bag 14 is easily deformed toward the inside of the container body 3, so that the inner bag 14 is damaged. There is no. However, depending on the materials of the outer shell 12 and the inner bag 14, the inner bag 14 can be easily peeled off from the outer shell 12. In such a case, the preliminary peeling step may be omitted and the inner bag separating step may be performed.

次に、内袋離間工程において挿入具42を外気導入孔15に挿入した後、バリ処理工程では、図10(c)〜図10(e)に示すように、挿入具42を、矢印X2方向に移動させながら外気導入孔15から引き抜くことによって、図11(a)に示す外気導入孔15の内袋14側の縁部に形成されるバリBrを、図11(b)に示すように外気導入孔15に対し外側に向かって傾斜させる。 Next, after inserting the inserter 42 into the outside air introduction hole 15 in the inner bag separating step, in the burr treatment step, as shown in FIGS. 10 (c) to 10 (e), the inserter 42 is inserted in the direction of arrow X2. The burr Br formed on the edge of the outside air introduction hole 15 on the inner bag 14 side shown in FIG. 11A by pulling out from the outside air introduction hole 15 while being moved to is shown in the outside air as shown in FIG. 11B. It is tilted outward with respect to the introduction hole 15.

具体的には、挿入具42を矢印X2の方向に移動させ、膨径部45の押圧面45bをバリBrと当接させ、この状態でさらに挿入具42を矢印X2の方向に移動させることで、バリBrを外気導入孔15の径方向外側に向かって押圧する。これにより、バリBrは、膨径部45の押圧面45bの傾斜と略同一の方向に傾斜することになる。ここで、膨径部45の押圧面45bと移動方向X2とのなす角をθ2(図11(a)参照)、バリBrの元々形成されていた方向と押圧による傾斜後の方向とのなす角をθ3(図11(b)参照)とすると、θ2とθ3は略同一となる。したがって、膨径部45の押圧面45bの移動方向X2とのなす角θ2、つまり膨径部45の押圧面45bの傾斜角θ2を、弁部材5の蓋部5cに形成されるテーパー面5d(図3(b)及び図12(b)参照)の傾斜角θ1と同一か又はθ1よりも大きく設定することで、バリBrの傾斜角θ3がテーパー面5dの傾斜角θ1と同一か又はθ1よりも大きくなる。このような形状のバリBrを有していることで、後述する弁部材装着工程において外気導入孔15も弁部材5を装着した際に、バリBrが弁部材5と干渉することを防止することができる。 Specifically, the inserter 42 is moved in the direction of the arrow X2, the pressing surface 45b of the bulging portion 45 is brought into contact with the burr Br, and the inserter 42 is further moved in the direction of the arrow X2 in this state. , The burr Br is pressed outward in the radial direction of the outside air introduction hole 15. As a result, the burr Br is inclined in a direction substantially the same as the inclination of the pressing surface 45b of the enlarged diameter portion 45. Here, the angle formed by the pressing surface 45b of the bulging portion 45 and the moving direction X2 is θ2 (see FIG. 11A), and the angle formed by the originally formed direction of the burr Br and the direction after tilting due to pressing. Is θ3 (see FIG. 11B), then θ2 and θ3 are substantially the same. Therefore, the angle θ2 formed by the pressing surface 45b of the bulging portion 45 with the moving direction X2, that is, the inclination angle θ2 of the pressing surface 45b of the bulging portion 45 is formed on the lid portion 5c of the valve member 5 by the tapered surface 5d ( By setting the inclination angle θ1 of FIG. 3B and FIG. 12B) to be the same as or larger than θ1, the inclination angle θ3 of the burr Br is the same as or greater than the inclination angle θ1 of the tapered surface 5d. Will also grow. By having the burr Br having such a shape, it is possible to prevent the burr Br from interfering with the valve member 5 when the valve member 5 is also mounted on the outside air introduction hole 15 in the valve member mounting step described later. Can be done.

なお、バリ処理工程において、膨径部45の押圧面45bがバリBrと当接してから、膨径部45が外気導入孔15を通過する際の挿入具42の引き抜く速度は、内袋離間工程における外気導入孔15に膨径部45を挿入する際を含む、他の場面における移動速度よりも遅くすることが好ましい。 In the burr treatment step, the speed at which the insertion tool 42 is pulled out when the bulging portion 45 passes through the outside air introduction hole 15 after the pressing surface 45b of the bulging portion 45 comes into contact with the burr Br is determined by the inner bag separating step. It is preferable that the moving speed is slower than the moving speed in other situations including when the enlarged diameter portion 45 is inserted into the outside air introduction hole 15 in the above.

次に、図13(a)〜(b)に示すように、ロボットアーム47で弁部材5を吸着した状態でロボットアーム47を矢印X1方向に移動させて弁部材5を外気導入孔15内に押し込むことによって、弁部材5を外殻12に装着する(弁部材装着工程)。具体的には、外殻12の外側から、弁部材5の蓋部5cを外気導入孔15に押し込んで挿通させることによって、図12(a)及ぶ13(b)に示すように、弁部材5を外殻12に装着する。蓋部5cは、外気導入孔15よりも直径が大きいので、蓋部5cが外気導入孔15を押し広げながら外気導入孔15を通過する。そして、蓋部5cが外気導入孔15を通過した直後に蓋部5cが容器本体3の内側に向かって勢いよく移動する。この際に蓋部5cが内袋14に衝突すると内袋14に傷がつく恐れがあるが、本実施形態では、内袋離間工程において内袋14が予め外殻12から離間されているので、蓋部5cは、ほとんど又は全く内袋14に接触せず、内袋14が傷つくことがない。一方、内袋離間工程を行わずに内袋14が外殻12に隣接している場合には、蓋部5cが外気導入孔15を通過した直後に勢いよく容器本体3の内部に向かって移動して内袋14に衝突して内袋14を損傷させる。従って、弁部材装着工程の前に内袋離間工程を行うことが重要である。なお、本実施形態では、外気導入孔15の縁と弁部材5の間の隙間を弁部材5の移動によって開閉することによって、弁部材5が外気導入孔15を開閉するように構成されているが、弁部材5自体に貫通孔と開閉可能な弁を設けて、この弁の働きによって貫通孔を開閉することによって、外気導入孔15を開閉するように構成してもよい。このような構成の弁部材5を用いる場合でも、弁部材5を外殻12の外側から外気導入孔15に押し込む際に内袋14を傷つけてしまう場合があるという問題が存在しているので、本実施形態と同様に、弁部材装着工程の前に予備剥離工程と内袋離間工程を行うことによって内袋14が傷つくことを防ぐことができる。 Next, as shown in FIGS. 13A to 13B, the robot arm 47 is moved in the direction of the arrow X1 while the valve member 5 is attracted by the robot arm 47, and the valve member 5 is placed in the outside air introduction hole 15. By pushing in, the valve member 5 is attached to the outer shell 12 (valve member attaching step). Specifically, by pushing the lid portion 5c of the valve member 5 into the outside air introduction hole 15 from the outside of the outer shell 12 and inserting it, as shown in FIGS. 12 (a) and 13 (b), the valve member 5 Is attached to the outer shell 12. Since the lid portion 5c has a larger diameter than the outside air introduction hole 15, the lid portion 5c passes through the outside air introduction hole 15 while expanding the outside air introduction hole 15. Then, immediately after the lid portion 5c has passed through the outside air introduction hole 15, the lid portion 5c vigorously moves toward the inside of the container body 3. At this time, if the lid portion 5c collides with the inner bag 14, the inner bag 14 may be damaged. However, in the present embodiment, the inner bag 14 is separated from the outer shell 12 in advance in the inner bag separating step. The lid portion 5c hardly or at all contacts the inner bag 14, and the inner bag 14 is not damaged. On the other hand, when the inner bag 14 is adjacent to the outer shell 12 without performing the inner bag separating step, the lid portion 5c vigorously moves toward the inside of the container body 3 immediately after passing through the outside air introduction hole 15. Then, it collides with the inner bag 14 and damages the inner bag 14. Therefore, it is important to perform the inner bag separating step before the valve member mounting step. In the present embodiment, the valve member 5 opens and closes the outside air introduction hole 15 by opening and closing the gap between the edge of the outside air introduction hole 15 and the valve member 5 by moving the valve member 5. However, the valve member 5 itself may be provided with a through hole and a valve that can be opened and closed, and the through hole may be opened and closed by the action of the valve to open and close the outside air introduction hole 15. Even when the valve member 5 having such a configuration is used, there is a problem that the inner bag 14 may be damaged when the valve member 5 is pushed into the outside air introduction hole 15 from the outside of the outer shell 12. Similar to the present embodiment, it is possible to prevent the inner bag 14 from being damaged by performing the preliminary peeling step and the inner bag separating step before the valve member mounting step.

次に、図13(c)に示すように、上部筒状部41をカットする。
次に、図13(d)に示すように、内袋14内にエアーを吹き込むことによって、内袋14を膨らませる。
次に、図13(e)に示すように、内袋14内に内容物を充填する。
次に、図13(f)に示すように、口部9にキャップ23を装着する。
次に、図13(g)に示すように、収容部7をシュリンクフィルムで覆い、製品が完成する。
Next, as shown in FIG. 13 (c), the upper tubular portion 41 is cut.
Next, as shown in FIG. 13D, the inner bag 14 is inflated by blowing air into the inner bag 14.
Next, as shown in FIG. 13E, the inner bag 14 is filled with the contents.
Next, as shown in FIG. 13 (f), the cap 23 is attached to the mouth portion 9.
Next, as shown in FIG. 13 (g), the accommodating portion 7 is covered with a shrink film to complete the product.

ここで示した各種工程の順序は、適宜入れ替え可能である。例えば、熱風曲げ工程は、外気導入孔開通工程の前や、内層予備剥離工程の前に行ってもよい。また、上部筒状部41をカットする工程は、外気導入孔15に弁部材5を挿入する前に行ってもよい。 The order of the various steps shown here can be changed as appropriate. For example, the hot air bending step may be performed before the outside air introduction hole opening step or before the inner layer preliminary peeling step. Further, the step of cutting the upper tubular portion 41 may be performed before inserting the valve member 5 into the outside air introduction hole 15.

次に、製造した製品の使用時の動作原理を説明する。
図14(a)〜(c)に示すように、内容物が充填された製品を傾けた状態で外殻12の側面を握って圧縮して内容物を吐出させる。使用開始時は、内袋14と外殻12の間に実質的に隙間がない状態であるので、外殻12に加えた圧縮力は、そのまま内袋14の圧縮力となり、内袋14が圧縮されて内容物が吐出される。
Next, the operating principle when the manufactured product is used will be described.
As shown in FIGS. 14A to 14C, the product filled with the contents is tilted and the side surface of the outer shell 12 is grasped and compressed to discharge the contents. At the start of use, there is substantially no gap between the inner bag 14 and the outer shell 12, so that the compressive force applied to the outer shell 12 becomes the compressive force of the inner bag 14 as it is, and the inner bag 14 is compressed. And the contents are discharged.

キャップ23は、図示しない逆止弁を内蔵しており、内袋14内の内容物を吐出させることはできるが、内袋14内に外気を取り込むことはできない。そのため、内容物の吐出後に外殻12へ加えていた圧縮力を除くと、外殻12が自身の復元力によって元の形状に戻ろうとするが、内袋14はしぼんだままで外殻12だけが膨張することになる。そして、図14(d)に示すように、内袋14と外殻12の間の中間空間21内が減圧状態となり、外殻12に形成された外気導入孔15を通じて中間空間21内に外気が導入される。中間空間21が減圧状態になっている場合、蓋部5cは、外気導入孔15に押し付けられないので、外気の導入を妨げない。 The cap 23 has a built-in check valve (not shown), and although the contents in the inner bag 14 can be discharged, the outside air cannot be taken into the inner bag 14. Therefore, when the compressive force applied to the outer shell 12 after discharging the contents is removed, the outer shell 12 tries to return to its original shape by its own restoring force, but the inner bag 14 remains deflated and only the outer shell 12 remains deflated. It will expand. Then, as shown in FIG. 14D, the inside of the intermediate space 21 between the inner bag 14 and the outer shell 12 is in a depressurized state, and the outside air enters the intermediate space 21 through the outside air introduction hole 15 formed in the outer shell 12. be introduced. When the intermediate space 21 is in a reduced pressure state, the lid portion 5c is not pressed against the outside air introduction hole 15, so that the introduction of outside air is not hindered.

次に、図14(e)に示すように、再度、外殻12の側面を握って圧縮した場合、蓋部5cが外気導入孔15を閉塞することによって、中間空間21内の圧力が高まり、外殻12に加えた圧縮力は中間空間21を介して内袋14に伝達され、この力によって内袋14が圧縮されて内容物が吐出される。 Next, as shown in FIG. 14E, when the side surface of the outer shell 12 is gripped and compressed again, the lid portion 5c closes the outside air introduction hole 15, so that the pressure in the intermediate space 21 increases. The compressive force applied to the outer shell 12 is transmitted to the inner bag 14 via the intermediate space 21, and this force compresses the inner bag 14 to discharge the contents.

次に、図14(f)に示すように、内容物の吐出後に外殻12へ加えていた圧縮力を除くと、外殻12は、外気導入孔15から中間空間21に外気を導入しながら、自身の復元力によって元の形状に復元される。 Next, as shown in FIG. 14 (f), when the compressive force applied to the outer shell 12 after discharging the contents is removed, the outer shell 12 introduces the outside air from the outside air introduction hole 15 into the intermediate space 21. , It is restored to its original shape by its own restoring force.

なお、本発明は、以下の態様でも実施可能である。
・上述した実施形態では、外気導入孔15よりも直径の大きい膨径部45を有する挿入具42により、外気導入孔15の内袋14側の縁部を外側に向かって押圧し、バリBrを拡開するよう構成されていたが、図15に示すように、膨径部45を有さない挿入具42を用いてバリBrを処理することも可能である。具体的には、挿入具42に回転体を取り付けておき、図15(a)〜(b)の予備剥離工程の後、図15(c)に示すように、挿入具42を外気導入孔15を支点として挿入具42の先端が外気導入孔15の直径よりも大きな直径の円を描くように回転させることで、挿入具42の側面が外気導入孔15の内袋14側の縁部を外側に向かって押圧することができ、バリBrを拡開することができる。
・上述した実施形態では、内袋離間工程とバリ処理工程とを同一の挿入具42を用いて一連の動作により行っていたが、内袋離間工程とバリ処理工程とを別のタイミングで行うことや、別の器具を用いて行うことも可能である。また、弁部材5の挿入時に内袋14が損傷するおそれがない場合は、内袋離間工程を省略してバリ処理工程のみを行うことも可能である。
The present invention can also be implemented in the following aspects.
In the above-described embodiment, the insertion tool 42 having a bulging portion 45 having a diameter larger than that of the outside air introduction hole 15 presses the edge portion of the outside air introduction hole 15 on the inner bag 14 side toward the outside to push the burr Br. Although it was configured to expand, as shown in FIG. 15, it is also possible to treat the burr Br using an inserter 42 that does not have a bulging diameter portion 45. Specifically, a rotating body is attached to the insertion tool 42, and after the preliminary peeling steps of FIGS. 15A to 15B, the insertion tool 42 is inserted into the outside air introduction hole 15 as shown in FIG. 15C. By rotating the tip of the insertion tool 42 so as to draw a circle having a diameter larger than the diameter of the outside air introduction hole 15, the side surface of the insertion tool 42 makes the edge of the outside air introduction hole 15 on the inner bag 14 side outside. It can be pressed toward, and the burr Br can be expanded.
-In the above-described embodiment, the inner bag separating step and the burr treatment step are performed by a series of operations using the same insertion tool 42, but the inner bag separating step and the burr treatment step are performed at different timings. Alternatively, it can be performed using another device. Further, if there is no risk of the inner bag 14 being damaged when the valve member 5 is inserted, it is possible to omit the inner bag separating step and perform only the burr treatment step.

1 積層剥離容器
3 容器本体
5 弁部材
5a 軸部
5c 蓋部
7 収容部
9 口部
11 外層
12 外殻
13 内層
14 内袋
15 外気導入孔
21 中間空間
42 挿入具
45 膨径部
45a 挿入面
45b 押圧面
46 先端部
Br バリ
θ1〜θ3 傾斜角
1 Laminated peeling container 3 Container body 5 Valve member 5a Shaft part 5c Lid part 7 Storage part 9 Mouth part 11 Outer layer 12 Outer shell 13 Inner layer 14 Inner bag 15 Outside air introduction hole 21 Intermediate space 42 Insertor 45 Inflated part 45a Insertion surface 45b Pressing surface 46 Tip portion Br Bali θ1 to θ3 Tilt angle

Claims (5)

外殻と内袋とを有する容器本体を形成する容器本体形成工程と、
前記容器本体の、内容物を収容する収容部において前記外殻のみを貫通する外気導入孔を形成する外気導入孔形成工程と、
前記外気導入孔の前記内袋側の縁部を押圧する押圧工程と、
前記外気導入孔を開閉可能な弁部材を前記外殻に装着する弁部材装着工程を備え
前記押圧工程において、前記外気導入孔の前記内袋側の縁部は、前記外気導入孔に挿入する挿入具により押圧され、
前記挿入具は前記外気導入孔よりも径の大きい膨径部を有し、前記縁部は前記膨径部が前記外気導入孔から引き抜かれることにより押圧される、積層剥離容器の製造方法。
A container body forming step of forming a container body having an outer shell and an inner bag,
An outside air introduction hole forming step of forming an outside air introduction hole penetrating only the outer shell in the accommodating portion of the container body for accommodating the contents.
A pressing step of pressing the edge of the outside air introduction hole on the inner bag side, and
A valve member mounting process for mounting the valve member capable of opening and closing the outside air introduction hole on the outer shell is provided .
In the pressing step, the edge of the outside air introduction hole on the inner bag side is pressed by an insertion tool inserted into the outside air introduction hole.
The insert has a larger bulge diameter than the outside air introduction hole, the edges Ru is pressed by the bulge is withdrawn from the outside air introduction hole, a manufacturing method of a multilayer peeling vessel.
前記挿入具は前記膨径部の先端側に前記膨径部よりも径の小さい先端部を有し、当該先端部により前記内袋を前記容器本体の内側に押し込むことによって、前記膨径部が前記外気導入孔に挿入される前に前記内袋を前記外殻から離間させる、請求項1に記載の方法。 The inserter has a tip portion having a diameter smaller than that of the bulging portion on the tip end side of the bulging portion, and the bulging portion is pushed into the inside of the container body by the tip portion. The method according to claim 1 , wherein the inner bag is separated from the outer shell before being inserted into the outside air introduction hole. 前記膨径部の先端側及び基端側はそれぞれテーパ状に形成され、前記膨径部の先端側の傾斜は前記膨径部の基端側の傾斜よりもなだらかに形成される、請求項1又は請求項2に記載の方法。 The bulge distal side and the proximal side of the respective tapered, the slope of the front end side of the bulge is gently than the slope of the proximal end side of the bulge, claim 1 Or the method according to claim 2. 外殻と内袋とを有し且つ内容物の減少に伴って前記内袋が前記外殻から収縮する容器本体と、前記外殻のみを貫通する外気導入孔を開閉可能な弁部材とを備える積層剥離容器であって、
前記弁部材は、前記外気導入孔に挿通され且つ前記外気導入孔に対してスライド移動可能な軸部と、前記軸部の前記内袋側に設けられ且つ前記軸部よりも断面積が大きい蓋部とを備えており、
前記外気導入孔の前記内袋側の縁部に形成されるバリが、前記外気導入孔に対し外側に向かって傾斜している、積層剥離容器。
It has a container body having an outer shell and an inner bag, and the inner bag contracts from the outer shell as the contents decrease, and a valve member capable of opening and closing an outside air introduction hole penetrating only the outer shell. It is a laminated peeling container
The valve member has a shaft portion that is inserted into the outside air introduction hole and can slide with respect to the outside air introduction hole, and a lid that is provided on the inner bag side of the shaft portion and has a larger cross-sectional area than the shaft portion. It has a department and
A laminated peeling container in which burrs formed on the edge of the outside air introduction hole on the inner bag side are inclined outward with respect to the outside air introduction hole.
前記蓋部は、前記軸部側に向かって傾斜し且つ前記外気導入孔の前記内袋側の縁部と当接する傾斜面を有しており、前記バリの傾斜角が、前記傾斜面の傾斜角と略同一又は前記傾斜面の傾斜角よりも大きくなるよう形成される、請求項4に記載の積層剥離容器。 The lid portion has an inclined surface that is inclined toward the shaft portion side and is in contact with the edge portion of the outside air introduction hole on the inner bag side, and the inclination angle of the burr is the inclination of the inclined surface. The laminated peeling container according to claim 4 , which is formed so as to be substantially the same as the angle or larger than the inclination angle of the inclined surface.
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