JP6869204B2 - Heat transpiration agent - Google Patents
Heat transpiration agent Download PDFInfo
- Publication number
- JP6869204B2 JP6869204B2 JP2018079296A JP2018079296A JP6869204B2 JP 6869204 B2 JP6869204 B2 JP 6869204B2 JP 2018079296 A JP2018079296 A JP 2018079296A JP 2018079296 A JP2018079296 A JP 2018079296A JP 6869204 B2 JP6869204 B2 JP 6869204B2
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- JP
- Japan
- Prior art keywords
- weight
- heat
- agent
- odor
- linalool
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 230000005068 transpiration Effects 0.000 title claims description 59
- 239000003795 chemical substances by application Substances 0.000 claims description 84
- 239000003205 fragrance Substances 0.000 claims description 58
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 claims description 34
- PSQYTAPXSHCGMF-BQYQJAHWSA-N β-ionone Chemical compound CC(=O)\C=C\C1=C(C)CCCC1(C)C PSQYTAPXSHCGMF-BQYQJAHWSA-N 0.000 claims description 30
- 230000007794 irritation Effects 0.000 claims description 25
- 241000607479 Yersinia pestis Species 0.000 claims description 24
- 239000002917 insecticide Substances 0.000 claims description 19
- 238000010438 heat treatment Methods 0.000 claims description 18
- KVWWIYGFBYDJQC-UHFFFAOYSA-N methyl dihydrojasmonate Chemical compound CCCCCC1C(CC(=O)OC)CCC1=O KVWWIYGFBYDJQC-UHFFFAOYSA-N 0.000 claims description 18
- 230000001603 reducing effect Effects 0.000 claims description 18
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 claims description 17
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 claims description 17
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 claims description 17
- -1 azodicarboxylic amide Chemical class 0.000 claims description 17
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 claims description 17
- 229930007744 linalool Natural products 0.000 claims description 17
- 229940116411 terpineol Drugs 0.000 claims description 17
- 238000001704 evaporation Methods 0.000 claims description 16
- SFEOKXHPFMOVRM-UHFFFAOYSA-N (+)-(S)-gamma-ionone Natural products CC(=O)C=CC1C(=C)CCCC1(C)C SFEOKXHPFMOVRM-UHFFFAOYSA-N 0.000 claims description 15
- RIWRBSMFKVOJMN-UHFFFAOYSA-N 2-methyl-1-phenylpropan-2-ol Chemical compound CC(C)(O)CC1=CC=CC=C1 RIWRBSMFKVOJMN-UHFFFAOYSA-N 0.000 claims description 13
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 claims description 12
- YHQGMYUVUMAZJR-UHFFFAOYSA-N α-terpinene Chemical compound CC(C)C1=CC=C(C)CC1 YHQGMYUVUMAZJR-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- XHXUANMFYXWVNG-ADEWGFFLSA-N (-)-Menthyl acetate Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(C)=O XHXUANMFYXWVNG-ADEWGFFLSA-N 0.000 claims description 10
- 239000004156 Azodicarbonamide Substances 0.000 claims description 10
- 235000019399 azodicarbonamide Nutrition 0.000 claims description 10
- 239000002728 pyrethroid Substances 0.000 claims description 9
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 8
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims description 7
- 239000006200 vaporizer Substances 0.000 claims description 7
- XHXUANMFYXWVNG-UHFFFAOYSA-N D-menthyl acetate Natural products CC(C)C1CCC(C)CC1OC(C)=O XHXUANMFYXWVNG-UHFFFAOYSA-N 0.000 claims description 6
- WSTYNZDAOAEEKG-UHFFFAOYSA-N Mayol Natural products CC1=C(O)C(=O)C=C2C(CCC3(C4CC(C(CC4(CCC33C)C)=O)C)C)(C)C3=CC=C21 WSTYNZDAOAEEKG-UHFFFAOYSA-N 0.000 claims description 6
- 239000001605 (5-methyl-2-propan-2-ylcyclohexyl) acetate Substances 0.000 claims description 5
- WCPAKWJPBJAGKN-UHFFFAOYSA-N oxadiazole Chemical compound C1=CON=N1 WCPAKWJPBJAGKN-UHFFFAOYSA-N 0.000 claims description 5
- 235000019645 odor Nutrition 0.000 description 55
- 239000000126 substance Substances 0.000 description 36
- 239000000779 smoke Substances 0.000 description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 239000000203 mixture Substances 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 13
- 230000000694 effects Effects 0.000 description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 9
- 238000011156 evaluation Methods 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- 238000005192 partition Methods 0.000 description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- 239000008187 granular material Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000004088 foaming agent Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000001027 hydrothermal synthesis Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 4
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 4
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
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- 229910052742 iron Inorganic materials 0.000 description 4
- 230000000873 masking effect Effects 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 229920000881 Modified starch Polymers 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 3
- 239000000292 calcium oxide Substances 0.000 description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
- 239000012295 chemical reaction liquid Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000007884 disintegrant Substances 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 230000003054 hormonal effect Effects 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- XAOGXQMKWQFZEM-UHFFFAOYSA-N isoamyl propanoate Chemical compound CCC(=O)OCCC(C)C XAOGXQMKWQFZEM-UHFFFAOYSA-N 0.000 description 3
- WDAXFOBOLVPGLV-UHFFFAOYSA-N isobutyric acid ethyl ester Natural products CCOC(=O)C(C)C WDAXFOBOLVPGLV-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000004745 nonwoven fabric Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- GNEPLYVYORHREW-UHFFFAOYSA-N 1,1,3,3,6-pentamethyl-7-nitro-2h-inden-5-amine Chemical compound CC1=C(N)C=C2C(C)(C)CC(C)(C)C2=C1[N+]([O-])=O GNEPLYVYORHREW-UHFFFAOYSA-N 0.000 description 2
- BBMCTIGTTCKYKF-UHFFFAOYSA-N 1-heptanol Chemical compound CCCCCCCO BBMCTIGTTCKYKF-UHFFFAOYSA-N 0.000 description 2
- RXGUIWHIADMCFC-UHFFFAOYSA-N 2-Methylpropyl 2-methylpropionate Chemical compound CC(C)COC(=O)C(C)C RXGUIWHIADMCFC-UHFFFAOYSA-N 0.000 description 2
- KEBDNKNVCHQIJU-UHFFFAOYSA-N 2-Methylpropyl 3-methylbutanoate Chemical compound CC(C)COC(=O)CC(C)C KEBDNKNVCHQIJU-UHFFFAOYSA-N 0.000 description 2
- RCSBILYQLVXLJG-UHFFFAOYSA-N 2-Propenyl hexanoate Chemical compound CCCCCC(=O)OCC=C RCSBILYQLVXLJG-UHFFFAOYSA-N 0.000 description 2
- HHYIHEISKNFHJZ-UHFFFAOYSA-N 2-[(4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl)oxy]ethyl thiocyanate Chemical compound C1CC2(C)C(OCCSC#N)CC1C2(C)C HHYIHEISKNFHJZ-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- PRNCMAKCNVRZFX-UHFFFAOYSA-N 3,7-dimethyloctan-1-ol Chemical compound CC(C)CCCC(C)CCO PRNCMAKCNVRZFX-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VZRKEAFHFMSHCD-UHFFFAOYSA-N Ethyl 3-(N-butylacetamido)propionate Chemical compound CCCCN(C(C)=O)CCC(=O)OCC VZRKEAFHFMSHCD-UHFFFAOYSA-N 0.000 description 2
- WEEGYLXZBRQIMU-UHFFFAOYSA-N Eucalyptol Chemical compound C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- ZYEMGPIYFIJGTP-UHFFFAOYSA-N O-methyleugenol Chemical compound COC1=CC=C(CC=C)C=C1OC ZYEMGPIYFIJGTP-UHFFFAOYSA-N 0.000 description 2
- 235000019502 Orange oil Nutrition 0.000 description 2
- QURFFFCYNQXLCU-UHFFFAOYSA-N Pentyl 3-methylbutanoate Chemical compound CCCCCOC(=O)CC(C)C QURFFFCYNQXLCU-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- MOYAFQVGZZPNRA-UHFFFAOYSA-N Terpinolene Chemical compound CC(C)=C1CCC(C)=CC1 MOYAFQVGZZPNRA-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- VXSIXFKKSNGRRO-MXOVTSAMSA-N [(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate;[(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-3-[(e)-3-methoxy-2-methyl-3-oxoprop-1-enyl Chemical class CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1.CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VXSIXFKKSNGRRO-MXOVTSAMSA-N 0.000 description 2
- KGEKLUUHTZCSIP-HOSYDEDBSA-N [(1s,4s,6r)-1,7,7-trimethyl-6-bicyclo[2.2.1]heptanyl] acetate Chemical compound C1C[C@]2(C)[C@H](OC(=O)C)C[C@H]1C2(C)C KGEKLUUHTZCSIP-HOSYDEDBSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- IGODOXYLBBXFDW-UHFFFAOYSA-N alpha-Terpinyl acetate Chemical compound CC(=O)OC(C)(C)C1CCC(C)=CC1 IGODOXYLBBXFDW-UHFFFAOYSA-N 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
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- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 2
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- 150000002148 esters Chemical class 0.000 description 2
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 2
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- 235000019634 flavors Nutrition 0.000 description 2
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- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- AOGQPLXWSUTHQB-UHFFFAOYSA-N hexyl acetate Chemical compound CCCCCCOC(C)=O AOGQPLXWSUTHQB-UHFFFAOYSA-N 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
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- 239000000077 insect repellent Substances 0.000 description 2
- 229910000358 iron sulfate Inorganic materials 0.000 description 2
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- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 description 2
- RGFNRWTWDWVHDD-UHFFFAOYSA-N isobutyl butyrate Chemical compound CCCC(=O)OCC(C)C RGFNRWTWDWVHDD-UHFFFAOYSA-N 0.000 description 2
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- 239000001301 oxygen Substances 0.000 description 2
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- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 description 2
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- DTUQWGWMVIHBKE-UHFFFAOYSA-N phenylacetaldehyde Chemical compound O=CCC1=CC=CC=C1 DTUQWGWMVIHBKE-UHFFFAOYSA-N 0.000 description 2
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- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 2
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- 150000003456 sulfonamides Chemical class 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
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- PHXATPHONSXBIL-UHFFFAOYSA-N xi-gamma-Undecalactone Chemical compound CCCCCCCC1CCC(=O)O1 PHXATPHONSXBIL-UHFFFAOYSA-N 0.000 description 2
- YKFLAYDHMOASIY-UHFFFAOYSA-N γ-terpinene Chemical compound CC(C)C1=CCC(C)=CC1 YKFLAYDHMOASIY-UHFFFAOYSA-N 0.000 description 2
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- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
- SFEOKXHPFMOVRM-BQYQJAHWSA-N γ-ionone Chemical compound CC(=O)\C=C\C1C(=C)CCCC1(C)C SFEOKXHPFMOVRM-BQYQJAHWSA-N 0.000 description 1
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Description
本発明は、加熱蒸散剤を加熱して蒸散させる際に発生する、煙臭、薬剤臭といった臭気や、煙や薬剤による刺激を軽減することができる加熱蒸散剤、加熱蒸散剤を加熱する時に発生する臭気および刺激の軽減方法、加熱蒸散剤を加熱する時に発生する臭気および刺激の軽減剤に関する。 The present invention is generated when heating an odor such as smoke odor or chemical odor generated when the heated transpiration agent is heated and evaporated, or a heat transpiration agent or a heat transpiration agent capable of reducing irritation caused by smoke or chemicals. The present invention relates to a method for reducing odor and irritation, and a method for reducing odor and irritation generated when a heated transpiration agent is heated.
従来から害虫防除剤を含む加熱蒸散剤は、屋内の害虫駆除のためによく使用されており、製剤中には害虫防除剤の蒸散性、拡散性を高めるために、アゾジカルボンアミド等の有機発泡剤が含有されている。これは、使用時に有機発泡剤を燃焼または分解させて発生するガスおよび煙粒子により、製剤中の蒸散成分を短時間のうちに空気中に蒸散および拡散させて、害虫防除剤を空間の隅々まで十分に行きわたらせて、優れた害虫駆除効果を得るものである。
このような加熱蒸散剤は、酸化カルシウムと水との水和反応による反応熱を利用して加熱することが多く、この水和反応熱が高温（約２５０〜４００℃）になることから、加熱蒸散剤や容器等が高温に晒されることにより焦げるような臭い（焦げ臭）が発生し、この焦げ臭は使用者の不快感を招く原因となっていた。特許文献１には、この焦げ臭を防止し、使用感を改善するために、焦げ臭防止剤として、特定の吸油量の鉱物性物質を加熱蒸散剤中に存在させる技術が報告されている。
Conventionally, heat transpiration agents containing pest control agents are often used for indoor pest control, and organic foaming agents such as azodicarbonamide are used in the preparations in order to enhance the transpiration and diffusivity of the pest control agents. Contains the agent. This is because the gas and smoke particles generated by burning or decomposing the organic foaming agent during use evaporate and diffuse the evaporative components in the formulation into the air in a short time, and the pest control agent is applied to every corner of the space. It is possible to obtain an excellent pest control effect by sufficiently spreading it.
Such a heat vaporizer is often heated by utilizing the heat of reaction due to the hydration reaction between calcium oxide and water, and the heat of the hydration reaction becomes high temperature (about 250 to 400 ° C.). When the vaporizer, the container, or the like is exposed to a high temperature, a burning odor (burning odor) is generated, and this burning odor causes discomfort to the user.
しかしながら、上記特許文献１等に記載された技術では、多くの使用者が満足する十分な臭気抑制効果が得られるとまではいい難く、さらなる改善が求められていた。
そこで、本発明は、加熱蒸散剤を加熱して蒸散させる際に発生する、煙臭、薬剤臭といった臭気や、煙や薬剤による刺激を軽減することができる加熱蒸散剤、加熱蒸散剤を加熱する時に発生する臭気および刺激の軽減方法、加熱蒸散剤を加熱するときに発生する臭気および刺激の軽減剤を提供することを目的としている。
However, it is difficult to say that the technique described in
Therefore, the present invention heats a heat transpiration agent and a heat transpiration agent that can reduce odors such as smoke odor and chemical odor generated when the heat transpiration agent is heated and evaporated, and irritation caused by smoke and chemicals. It is an object of the present invention to provide a method for reducing the odor and irritation that sometimes occurs, and a method for reducing the odor and irritation that occurs when the heat transpiration agent is heated.
本発明者は、上記課題を解決するために鋭意研究を重ねた結果、ある特定の香料を含有する加熱蒸散剤が、加熱して蒸散させる際に発生する、煙臭、薬剤臭といった臭気や、煙や薬剤による刺激を軽減することができることを見出し、本発明を完成するに至った。
従来の加熱蒸散剤において、香料を配合することは知られていた（例えば、特許文献２）が、本発明は特定の香料を配合することにより、加熱蒸散時の臭気のみならず、煙や薬剤による刺激を軽減できるという今までにない、新たな効果が得られることを見出し、上記課題を解決するに至ったものである。
As a result of intensive research to solve the above problems, the present inventor has generated odors such as smoke odor and chemical odor generated when a heat transpiration agent containing a specific fragrance is heated and evaporated. We have found that irritation caused by smoke and chemicals can be reduced, and have completed the present invention.
It has been known that a fragrance is blended in a conventional heat transpiration agent (for example, Patent Document 2), but in the present invention, by blending a specific fragrance, not only the odor at the time of heat transpiration but also smoke and chemicals are added. We have found that a new effect that has never been seen before can reduce the irritation caused by transpiration, and have solved the above-mentioned problems.
本発明は、具体的には次の事項を要旨とする。
１．（Ａ）ピレスロイド系殺虫剤およびオキサジアゾール系殺虫剤から選択される１種以上の害虫防除剤５．０〜３０．０重量％、（Ｂ）アゾジカルボンアミド、（Ｃ）香料成分０．００１〜０．０５重量％を含有し、（Ｃ）香料成分として、ジヒドロジャスモン酸メチル、リナロール、テルピネオール、β−イオノン、α，α−ジメチルフェネチルアルコール、メンチルアセテート、メチルアセテート、α−テルピネンのいずれか１種以上を含有することを特徴とする加熱蒸散剤（ただし、テルピネオール０．０００５重量％と、リナロール０．００４重量％または０．００１５重量％、若しくは、テルピネオール０．００２重量％とリナロール０．０１重量％を含有する加熱蒸散剤は除く）。
２．（Ｃ）香料成分として、β−イオノンまたはα，α−ジメチルフェネチルアルコールのいずれかを必須成分として含有することを特徴とする１．に記載の加熱蒸散剤。
３．（Ｃ）香料成分として、ジヒドロジャスモン酸メチル、リナロール、テルピネオール、β−イオノン、α，α−ジメチルフェネチルアルコール、メンチルアセテート、メチルアセテート、α−テルピネンのいずれか１種以上を、加熱蒸散剤に対して０．００１〜０．０５重量％含有することを特徴とする、（Ａ）ピレスロイド系殺虫剤およびオキサジアゾール系殺虫剤から選択される１種以上の害虫防除剤を５．０〜３０．０重量％、（Ｂ）アゾジカルボンアミドを含有する加熱蒸散剤（ただし、テルピネオール０．０００５重量％と、リナロール０．００４重量％または０．００１５重量％、若しくは、テルピネオール０．００２重量％とリナロール０．０１重量％を含有する加熱蒸散剤は除く）を加熱する時に発生する臭気および刺激の軽減方法。
４．（Ｃ）香料成分として、β−イオノンを必須成分として含有することを特徴とする、３．に記載の（Ａ）害虫防除剤、（Ｂ）アゾジカルボンアミドを含有する加熱蒸散剤を加熱する時に発生する臭気および刺激の軽減方法。
Specifically, the gist of the present invention is as follows.
1. 1. (A) One or more pest control agents selected from pyrethroid insecticides and oxadiazole insecticides 5.0 to 30.0% by weight, (B) azodicarboxylic amide, (C) fragrance component 0.001 It contains ~ 0.05% by weight, and (C) any of methyl dihydrojasmonate, linalool, terpineol, β-ionone, α, α-dimethylphenethyl alcohol, menthyl acetate, methyl acetate, and α-terpinene as fragrance components. A heat-evaporating agent containing one or more of them (however, terpineol 0.0005% by weight and linalool 0.004% by weight or 0.0015% by weight, or terpineol 0.002% by weight and linalool 0. Excluding heat-evaporating agents containing 01% by weight).
2. (C) The fragrance component is characterized by containing either β-ionone or α, α-dimethylphenethyl alcohol as an essential component. The heat transpiration agent described in.
3. 3. (C) As a fragrance component, one or more of methyl dihydrojasmonate, linalool, terpineol, β-ionone, α, α-dimethylphenethyl alcohol, menthyl acetate, methyl acetate, and α-terpinene should be added to the heat vaporizer. 5.0 to 30. One or more pest control agents selected from (A) pyrethroid insecticides and oxadiazole insecticides, which are characterized by containing 0.001 to 0.05% by weight. Heat-evaporating agent containing 0% by weight, (B) azodicarboxylic amide (however, 0.0005% by weight of terpineol and 0.004% by weight or 0.0015% by weight of linalool, or 0.002% by weight of terpineol and linalool. A method for reducing odor and irritation generated when heating (excluding heat-evaporating agents containing 0.01% by weight).
4. (C) The fragrance component contains β-ionone as an essential component. A method for reducing odor and irritation generated when a heat transpiration agent containing (A) a pest control agent and (B) an azodicarbonamide is heated.
本発明の加熱蒸散剤は、含有する特定の（Ｃ）香料成分により、加熱蒸散剤を加熱蒸散する際に発生する、煙臭、薬剤臭といった臭気をマスキングして臭気による不快感を軽減することができる。
また、本発明の加熱蒸散剤は、含有する特定の（Ｃ）香料成分の機能により、加熱蒸散剤を加熱蒸散する際に発生する、煙や薬剤により喉や鼻の奥がイガイガするような刺激感も軽減することができる。
これらにより、本発明の加熱蒸散剤は、使用後に臭気や刺激等の不快感を感じることが少なく、屋内空間において好適に使用でき、効果的に害虫を駆除することができる。
The heat transpiration agent of the present invention masks odors such as smoke odor and chemical odor generated when the heat transpiration agent is transpiration by heating with the specific (C) fragrance component contained therein, and reduces discomfort due to the odor. Can be done.
In addition, the heat transpiration agent of the present invention causes irritation to the back of the throat and nose due to smoke and chemicals, which is generated when the heat transpiration agent is heat transpiration due to the function of the specific (C) fragrance component contained therein. The feeling can also be reduced.
As a result, the heat transpiration agent of the present invention is less likely to cause discomfort such as odor and irritation after use, can be suitably used in an indoor space, and can effectively exterminate pests.
以下、本発明の加熱蒸散剤、加熱蒸散剤を加熱する時に発生する臭気および刺激の軽減方法、加熱蒸散剤を加熱する時に発生する臭気および刺激の軽減剤について詳細に説明する。 Hereinafter, the heat transpiration agent of the present invention, a method for reducing odor and irritation generated when the heat transpiration agent is heated, and an odor and irritation reducing agent generated when the heat transpiration agent is heated will be described in detail.
＜（Ａ）害虫防除剤＞
本発明の加熱蒸散剤は、（Ａ）害虫防除剤を含有するものである。
本発明の（Ａ）害虫防除剤としては、殺虫剤、防虫剤、忌避剤等が挙げられる。これらは、有機発泡剤である（Ｂ）アゾジカルボンアミドの熱分解ガスと一緒に揮散するものであればよく、特に限定されない。
殺虫剤としては、例えば、天然ピレトリン、ピレトリン、アレスリン、フタルスリン、レスメトリン、フラメトリン、ペルメトリン、フェノトリン、シフェノトリン、プラレトリン、ビフェントリン、トランスフルトリン、メトフルトリン、プロフルトリン、イミプロトリン、エムペントリン、エトフェンプロックス、シラフルオフェン等のピレスロイド系殺虫剤；プロポクスル、カルバリル等のカーバメイト系殺虫剤；フェニトロチオン、ＤＤＶＰ等の有機リン系殺虫剤；メトキサジアゾン等のオキサジアゾール系殺虫剤；フィプロニル等のフェニルピラゾール系殺虫剤；イミダクロプリド、ジノテフラン等のネオニコチノイド系殺虫剤；アミドフルメト等のスルホンアミド系殺虫剤；クロルフェナピル等のピロール系化合物；メトプレン、ハイドロプレン等の昆虫幼若ホルモン様化合物；プレコセン等の抗幼若ホルモン様化合物；エクダイソン等の脱皮ホルモン様化合物；クロルフルアズロン、ジフルベンズロン、ヘキサフルムロン、ブプロフェジン等のキチン合成阻害剤、フィトンチッド、薄荷油、オレンジ油、桂皮油、丁子油等の精油類；イソボルニルチオシアノアセテート（ＩＢＴＡ）、イソボルニルチオシアノエチルエーテル（ＩＢＴＥ）、四級アンモニウム塩、サリチル酸ベンジル等の１種又は２種以上が挙げられる。
中でもピレスロイド系殺虫剤、カーバメイト系殺虫剤、オキサジアゾール系殺虫剤およびスルホンアミド系殺虫剤が、揮散がより向上されるので好ましく、特に、フェノトリン、シフェノトリン、ペルメトリン、メトキサジアゾン、プロポクスル、アミドフルメト、エトフェンプロックスが好ましい。
防虫剤、忌避剤としては、例えば、ディート、ジ−ｎ−ブチルサクシネート、ヒドロキシアニソール、ロテノン、エチル−ブチルアセチルアミノプロピオネート、イカリジン（ピカリジン）、３−（Ｎ−ｎ−ブチル−Ｎ−アセチル）アミノプロピオン酸エチルエステル（ＩＲ３５３５）等の１種又は２種以上が挙げられる。
本発明の（Ａ）害虫防除剤は、加熱蒸散剤に対して０．５〜３０．０重量％、好ましくは３．０〜２７．０重量％、特に好ましくは５．０〜２５．０重量％となるように配合すればよい。
<(A) Pest control agent>
The heat transpiration agent of the present invention contains (A) a pest control agent.
Examples of the (A) pest control agent of the present invention include insecticides, insect repellents, repellents and the like. These are not particularly limited as long as they volatilize together with the thermal decomposition gas of the organic foaming agent (B) azodicarbonamide.
Examples of insecticides include natural pyrethrins, pyrethrins, alesulins, phthalthrins, resmethrins, flamethrins, permethrins, phenothrins, ciphenotrins, prarethrins, bifenthrins, transfluthrins, metoflutrins, profluthrins, imiprothrins, empentrins Pyrethroid insecticides; carbamate insecticides such as propoxul and carbalyl; organic phosphorus insecticides such as fenitrothione and DDVP; oxaziazole insecticides such as methoxadiazone; phenylpyrazole insecticides such as fipronil; imidacloprid, dinotefuran and the like Neonicotinoid insecticides; sulfonamide insecticides such as amide flumeth; pyrethroid compounds such as chlorphenapir; insect immature hormone-like compounds such as metoprene and hydroprene; anti-young hormone-like compounds such as plecosene; dehulling such as ecdison Hormone-like compounds; chitin synthesis inhibitors such as chlorfluazuron, diflubenzurone, hexaflumuron, buprofezin, essential oils such as phytonchid, lightly loaded oil, orange oil, cinnamon oil, clove oil; isobornylthiocyanoacetate (IBTA) , Isobornylthiocyanoethyl ether (IBTE), quaternary ammonium salt, benzyl salicylate and the like, or two or more thereof.
Among them, pyrethroid insecticides, carbamate insecticides, oxadiazole insecticides and sulfonamide insecticides are preferable because they improve volatilization, and in particular, phenothrin, cyphenothrin, permethrin, methoxadiazone, propoxul, amidoflumeth and eth. Fenprox is preferred.
Examples of insect repellents and repellents include DEET, di-n-butyl succinate, hydroxyanisole, rotenone, ethyl-butyl acetylaminopropionate, icaridin (picaridin), 3- (N-n-butyl-N-). One or more kinds such as acetyl) aminopropionate ethyl ester (IR3535) and the like can be mentioned.
The pest control agent (A) of the present invention is 0.5 to 30.0% by weight, preferably 3.0 to 27.0% by weight, particularly preferably 5.0 to 25.0% by weight, based on the heat transpiration agent. It may be blended so as to be%.
＜（Ｂ）アゾジカルボンアミド＞
本発明の（Ｂ）アゾジカルボンアミドは、有機発泡剤として加熱蒸散剤に配合する。これは、加熱により分解して多量の熱を発生するとともにガスを発生し、（Ａ）害虫防除剤を揮散させる効果を奏する。
本発明の加熱蒸散剤は、（Ｂ）アゾジカルボンアミドを５０〜９７重量％、好ましくは６０〜９０重量％、さらに好ましくは７０〜８５重量％含有すると、（Ａ）害虫防除剤が効率よく揮散する。（Ｂ）アゾジカルボンアミドの含有量が９７重量％を超えると、例えば顆粒など、成形するために別途溶剤などが必要となるため、好ましくない。
本発明の（Ｂ）アゾジカルボンアミドは、２００℃前後で熱分解してガスを発生するものが好ましく、例えば、ユニフォームＡＺ（大塚化学社製）や、セルマイク（三協化成社製）等が挙げられる。
<(B) Azodicarbonamide>
The (B) azodicarbonamide of the present invention is blended with a heat transpiration agent as an organic foaming agent. This has the effect of decomposing by heating to generate a large amount of heat and generating gas, and (A) volatilizing the pest control agent.
When the heat transpiration agent of the present invention contains (B) azodicarbonamide in an amount of 50 to 97% by weight, preferably 60 to 90% by weight, more preferably 70 to 85% by weight, the (A) pest control agent volatilizes efficiently. To do. If the content of (B) azodicarbonamide exceeds 97% by weight, a separate solvent or the like is required for molding, for example, granules, which is not preferable.
The (B) azodicarbonamide of the present invention is preferably one that thermally decomposes at around 200 ° C. to generate gas, and examples thereof include uniform AZ (manufactured by Otsuka Chemical Co., Ltd.) and cell microphone (manufactured by Sankyo Kasei Co., Ltd.). Be done.
＜（Ｃ）香料成分＞
本発明の加熱蒸散剤は、（Ｃ）香料成分として、ジヒドロジャスモン酸メチル、リナロール、テルピネオール、β−イオノン、α，α−ジメチルフェネチルアルコール、メンチルアセテート、メチルアセテート、ベンジルアセテート、α−テルピネンのいずれか１種以上を含有する。
本発明の（Ｃ）香料成分は、加熱蒸散剤そのものの香りをよくし、加熱蒸散時に香りを付与するものであり、加熱蒸散時に生じる煙臭、薬剤臭といった臭気をマスキングする効果を有する。さらに、加熱蒸散後に残る煙や薬剤により、喉や鼻の奥がイガイガするような刺激も軽減する効果を奏する。特に、（Ｃ）香料成分として、β−イオノンまたはα，α−ジメチルフェネチルアルコールのいずれかを必須成分として含有することが、マスキング効果や刺激軽減効果を得るために好ましい。
本発明の（Ｃ）香料成分は、加熱蒸散剤に対して０．００１〜５．０重量％の範囲で含有することができ、好ましくは０．０１〜１重量％、さらに好ましくは０．０５〜０．５重量％含有すると、加熱蒸散剤を加熱蒸散した時や加熱蒸散後の香気が良好であり、さらに焦げ臭や薬剤刺激臭のマスキング効果にも優れる。また、上記（Ｃ）香料成分以外に、効果を奏する限り他の香料成分や、香料成分と溶剤、香料安定化剤などを混合した香料組成物として使用しても良い。
なお、本発明の（Ｃ）香料成分である、ジヒドロジャスモン酸メチル、リナロール、テルピネオール、β−イオノン、α，α−ジメチルフェネチルアルコールを全て含有する香料組成物を、本明細書では「香料製品」と称する。
<(C) Fragrance ingredient>
The heat vaporizer of the present invention has (C) any of methyl dihydrojasmonate, linalool, terpineol, β-ionone, α, α-dimethylphenethyl alcohol, menthyl acetate, methyl acetate, benzyl acetate, and α-terpinene as fragrance components. Or contains one or more.
The fragrance component (C) of the present invention enhances the scent of the heat transpiration itself and imparts the scent during heat transpiration, and has the effect of masking odors such as smoke odor and chemical odor generated during heat transpiration. In addition, the smoke and chemicals that remain after heat transpiration have the effect of reducing irritation that causes the back of the throat and nose to irritate. In particular, it is preferable to contain either β-ionone or α, α-dimethylphenethyl alcohol as an essential component as the (C) fragrance component in order to obtain a masking effect and an irritation reducing effect.
The fragrance component (C) of the present invention can be contained in the range of 0.001 to 5.0% by weight with respect to the heat transpiration agent, preferably 0.01 to 1% by weight, and more preferably 0.05. When it is contained in an amount of ~ 0.5% by weight, the fragrance at the time of heat evaporation of the heat vaporizer and after the heat evaporation is good, and further, the masking effect of the burnt odor and the chemical stimulating odor is also excellent. Further, in addition to the above-mentioned (C) fragrance component, other fragrance components, or a fragrance composition in which a fragrance component, a solvent, a fragrance stabilizer and the like are mixed may be used as long as the effect is exhibited.
In addition, the fragrance composition containing all of the fragrance component (C) of the present invention, methyl dihydrojasmonate, linalool, terpineol, β-ionone, α, α-dimethylphenethyl alcohol, is referred to as “fragrance product” in the present specification. It is called.
（Ｃ）以外の香料成分としては、様々な植物や動物から抽出された天然香料や、化学的に合成される合成香料、さらにはこれらの香料成分を多数混合して作られる調合香料等が挙げられる。
香料は様々な文献、例えば、「Ｐｅｒｆｕｍｅ ａｎｄ Ｆｌａｖｏｒ Ｍａｔｅｒｉａｌｓ ｏｆ Ｎａｔｕｒａｌ Ｏｒｉｇｉｎ」，Ｓｔｅｆｆｅｎ Ａｒｃｔａｎｄｅｒ，Ａｌｌｕｒｅｄ Ｐｕｂ．Ｃｏ．（１９６０）、「香りの百科」，日本香料協会編，朝倉書店（１９８９）、「Ｆｌｏｗｅｒ ｏｉｌｓ ａｎｄ Ｆｌｏｒａｌ Ｃｏｍｐｏｕｎｄｓ Ｉｎ Ｐｅｒｆｕｍｅｒｙ」，Ｄａｎｕｔｅ Ｐａｊａｕｊｉｓ Ａｎｏｎｉｓ，Ａｌｌｕｒｅｄ Ｐｕｂ．Ｃｏ．（１９９３）、「Ｐｅｒｆｕｍｅ ａｎｄ Ｆｌａｖｏｒ Ｃｈｅｍｉｃａｌｓ（ａｒｏｍａ ｃｈｅｍｉｃａｌｓ）」，Ｖｏｌｓ．Ｉ ａｎｄ ＩＩ，Ｓｔｅｆｆｅｎ Ａｒｃｔａｎｄｅｒ，Ａｌｌｕｒｅｄ Ｐｕｂ．Ｃｏ．（１９９４）、「香料と調香の基礎知識」, 中島基貴編著,産業図書（１９９５）、「合成香料 化学と商品知識」，印藤元一著，化学工業日報社（１９９６）、「香りの百科事典」、谷田貝光克編，丸善（２００５）に記載の香料が使用できる。それぞれを引用することにより本明細書の開示の一部とする。以下に香料の代表例を具体的に挙げるが、これらに限定されるものではない。
Examples of fragrance components other than (C) include natural fragrances extracted from various plants and animals, chemically synthesized synthetic fragrances, and compound fragrances made by mixing a large number of these fragrance components. Be done.
Fragrances are described in various sources, such as "Perfume and Flavor Materials of Natural Origin", Stephen Arctander, Allured Pub. Co. (1960), "Encyclopedia of Fragrances", edited by Japan Fragrance Association, Asakura Shoten (1989), "Flower oils and Floral Compounds In Performance", Danute Pajaujis Anonys, Allured Pub. Co. (1993), "Perfume and Flavor Chemicals (aroma chemicals)", Vols. I and II, Stephen Arctander, Allured Pub. Co. (1994), "Basic knowledge of fragrances and fragrances", edited by Motoki Nakajima, Sangyo Tosho (1995), "Synthetic fragrance chemistry and product knowledge", Motokazu Indo, The Chemical Daily (1996), "Encyclopedia of fragrances" The fragrances described in "Encyclopedia", edited by Mitsukatsu Tanida, and Maruzen (2005) can be used. Each is incorporated herein by reference. Specific examples of fragrances are given below, but the present invention is not limited to these.
天然香料としては、例えば、オレンジ油、レモン油、ラベンダー油、ラバンジン油、ベルガモット油、パチュリ油、シダーウッド油、ペパーミント油等の天然精油等が挙げられる。
合成香料としては、例えば、α−ピネン、β−ピネン、ｐ−サイメン、テルピノレン、γ−テルピネン、α−フェランドレン、ミルセン、カンフェン、オシメン等の炭化水素テルペン；ヘプタナール、オクタナール、デカナール、ベンズアルデヒド、サリチルアルデヒド、フェニルアセトアルデヒド、シトロネラール、ハイドロキシシトロネラール、ハイドロトロピックアルデヒド、リグストラール、シトラール、α−ヘキシルシンナミックアルデヒド、α−アミルシンナミックアルデヒド、リリアール、シクラメンアルデヒド、リラール、ヘリオトロピン、アニスアルデヒド、ヘリオナール、バニリン、エチルバニリン等のアルデヒド類；エチルフォーメート、エチルアセテート、メチルプロピオネート、メチルイソブチレート、エチルイソブチレート、エチルブチレート、プロピルブチレート、イソブチルアセテート、イソブチルイソブチレート、イソブチルブチレート、イソブチルイソバレレート、エチル−２−メチルバレレート、イソアミルアセテート、テルピニルアセテート、イソアミルプロピオネート、アミルプロピオネート、アミルイソブチレート、アミルブチレート、アミルイソバレレート、アリルヘキサノエート、エチルアセトアセテート、エチルヘプチレート、ヘプチルアセテート、メチルベンゾエート、エチルベンゾエート、エチルオクチレート、スチラリルアセテート、ノニルアセテート、ボルニルアセテート、リナリルアセテート、オルト−ｔｅｒ−ブチルシクロヘキシルアセテート、安息香酸リナリル、ベンジルベンゾエート、トリエチルシトレート、エチルシンナメート、メチルサリシレート、ヘキシルサリシレート、ヘキシルアセテート、ヘキシルブチレート、アニシルアセテート、フェニルエチルイソブチレート、ジャスモン酸メチル、エチレンブラシレート、γ−ウンデカラクトン、γ−ノニルラクトン、シクロペンタデカノライド、クマリン等のエステル・ラクトン類；アニソール、ｐ−クレジルメチルエーテル、ジメチルハイドロキノン、メチルオイゲノール、β−ナフトールメチルエーテル、β−ナフトールエチルエーテル、アネトール、ジフェニルオキサイド、ローズオキサイド、ガラクソリド、アンブロックス等のエーテル類；イソプロピルアルコール、ｃｉｓ−３−ヘキセノール、ヘプタノール、２−オクタノール、ジメトール、ジヒドロミルセノール、ベンジルアルコール、シトロネロール、ゲラニオール、ネロール、テトラハイドロゲラニオール、セドロール、サンタロール、チモール、アニスアルコール、フェニルエチルアルコール、ヘキサノール等のアルコール類；ジアセチル、メントン、イソメントン、チオメントン、アセトフェノン、α−又はβ−ダマスコン、α−又はβ−ダマセノン、α−又はγ−イオノン、α−、β−又はγ−メチルイオノン、メチル−β−ナフチルケトン、ベンゾフェノン、テンタローム、アセチルセドレン、α−又はβ−イソメチルイオノン、α−、β−又はγ−イロン、マルトール、エチルマルトール、ｃｉｓ−ジャスモン、ジヒドロジャスモン、ｌ−カルボン、ジヒドロカルボン、メチルアミルケトン等のケトン類、１，８−シネオール、アリルアミルグリコレートアリルカプロエートなどが挙げられる。これらの香料は、１種単独で使用されても、また２種以上を任意に組み合わせて、調合香料として使用することもできる。
Examples of the natural fragrance include natural essential oils such as orange oil, lemon oil, lavender oil, lavandin oil, bergamot oil, patchouli oil, cedar wood oil and peppermint oil.
Examples of synthetic fragrances include hydrocarbon terpenes such as α-pinene, β-pinene, p-cymen, terpinolene, γ-terpinene, α-ferandrene, milsen, camphen and osimene; heptanal, octanal, decanal, benzaldehyde and salicyl. Aldehyde, phenylacetaldehyde, citroneral, hydroxycitroneral, hydrotropic aldehyde, ligstral, citral, α-hexyl cinnamic aldehyde, α-amyl cinnamic aldehyde, lilial, cyclamen aldehyde, lylar, heliotropin, anisaldehyde, helional, vanillin , Ethylvanillin and other aldehydes; ethylformate, ethylacetate, methylpropionate, methylisobutyrate, ethylisobutyrate, ethylbutyrate, propylbutyrate, isobutylacetate, isobutylisobutyrate, isobutylbutyrate, Isobutyl isovalerate, ethyl-2-methylvalerate, isoamyl acetate, terpinyl acetate, isoamyl propionate, amyl propionate, amyl isobutyrate, amyl butyrate, amyl isovalerate, allyl hexanoate, Ethylacetacetate, ethylheptylate, heptylacetate, methylbenzoate, ethylbenzoate, ethyloctylate, styralylacetate, nonylacetate, bornylacetate, linarylacetate, ortho-ter-butylcyclohexylacetate, linaryl benzoate, benzylbenzoate , Triethyl citrate, ethyl cinnamate, methyl salicylate, hexyl salicylate, hexyl acetate, hexyl butyrate, anisyl acetate, phenylethyl isobutyrate, methyl jasmonate, ethylene brush rate, γ-undecalactone, γ-nonyl lactone , Cyclopentadecanolides, coumarins and other ester lactones; anisole, p-credylmethyl ether, dimethylhydroquinone, methyleugenol, β-naphtholmethyl ether, β-naphthol ethyl ether, anetol, diphenyloxide, rose oxide, Ethers such as galaxolide and ambrox; isopropyl alcohol, cis-3-hexenol, heptanol, 2-octanol, dimethol, dihydromilsenol, benzylarco Alcohols such as ole, citronellol, geraniol, nerol, tetrahydrogeraniol, sedrol, santa roll, timole, anis alcohol, phenylethyl alcohol, hexanol; diacetyl, menton, isomenton, thiomentone, acetophenone, α- or β-damascon, α- or β-damasenone, α- or γ-ionone, α-, β- or γ-methylionone, methyl-β-naphthylketone, benzophenone, tentalome, acetylsedrene, α- or β-isomethylionone, α Ketones such as −, β- or γ-iron, maltor, ethyl maltor, cis-jasmon, dihydrojasmon, l-carboxylic, dihydrocarboxylic, methylamylketone, 1,8-cineole, allylamylglycolate allylcaproate And so on. These fragrances may be used alone or in any combination of two or more as a blended fragrance.
本発明の加熱蒸散剤は、その形態は特に限定されず、例えば、顆粒状、塊状、粒状、粉状、錠剤等の固形状等任意の形態とすることができる。
固形状の加熱蒸散剤とする場合は、各成分を公知の造粒機や成形機を用いて所望の形状に成形すればよい。
本発明の加熱蒸散剤を製造するには、成分（Ａ）〜（Ｃ）が所定量となるように混合し、結合剤や溶剤等を用いて造粒、乾燥させて、顆粒剤、粉末剤、微細粒剤等とすればよい。これらを造粒する際には、例えば、顆粒剤であれば粒径を約１〜５ｍｍ、長さを約１〜１５ｍｍとするのがよい。
造粒の際に用いる結合剤として、例えば、カルボキシメチルセルロース、ヒドロキシメチルセルロース、ヒドロキシプロピルメチルセルロース等のセルロース類；α化デンプン、β化デンプン、デキストリン、スターチ等のデンプン系、アラビアゴム等の天然系高分子化合物；ポリビニルアルコール、ポリビニルピロリドン等の合成高分子化合物等の１種又は２種以上が挙げられる。
これらの結合剤は、加熱蒸散剤に対して０．５〜５．０重量％となるように配合すればよい。
溶剤としては、例えば、水、エタノール、プロパノール、ベンジルアルコール等のアルコール類、エチレングリコール、ジエチレングリコール、ジプロピレングリコール、グリセリン、１，３−ブタンジオール等の多価アルコール、エチレングリコールモノメチルエーテル、エチレングリコールモノエチルエーテル、エチレングリコールモノプロピルエーテル、エチレングリコールモノブチルエーテル、ジエチレングリコールモノメチルエーテル、ジエチレングリコールモノエチルエーテル、ジエチレングリコールモノプロピルエーテル、ジエチレングリコールモノブチルエーテル、ジエチレングリコールモノイソブチルエーテル、トリエチレングリコールモノブチルエーテル、プロピレングリコールモノメチルエーテル、プロピレングリコールジメチルエーテル、ジプロピレングリコールモノメチルエーテル、トリプロピレングリコールモノメチルエーテル、トリプロピレングリコールモノブチルエーテル、プロピレングリコールモノプロピルエーテル、ジプロピレングリコールモノプロピルエーテル、プロピレングリコールモノブチルエーテル、プロピレングリコール−ｔｅｒｔ−ブチルエーテル、ジプロピレングリコールモノブチルエーテル、ジプロピレングリコールジメチルエーテル、フェニルカルビトール、フェニルセロソルブ、ベンジルカルビトール等のグリコールエーテル類、流動パラフィン、ｎ−パラフィン等のパラフィン類、ジエチルフタレート、ベンジルベンゾエート、トリエチルシトレート、ミリスチン酸イソプロピル等のエステル類、その他３−メチル−４−メトキシブタノール、Ｎ−メチルピロリドン、炭酸プロピレン等が挙げられる。これらの溶剤は、１種単独で使用されても、また２種以上を任意に組み合わせて使用することもできる。また、上記香料成分とともに混合し、香料組成物として使用することもできる。 なお、本発明の（Ａ）害虫防除剤は、造粒時に混合、練り込む以外にも、造粒後に噴霧、浸漬させて保持させることもできる。
The form of the heat transpiration agent of the present invention is not particularly limited, and may be in any form such as granules, lumps, granules, powders, and solids such as tablets.
When a solid heat transpiration agent is used, each component may be molded into a desired shape using a known granulator or molding machine.
In order to produce the heat transpiration agent of the present invention, the components (A) to (C) are mixed so as to have a predetermined amount, granulated and dried using a binder, a solvent, etc., and then granules and powders are prepared. , Fine granules and the like. When granulating these, for example, in the case of granules, the particle size is preferably about 1 to 5 mm and the length is preferably about 1 to 15 mm.
As a binder used in granulation, for example, celluloses such as carboxymethyl cellulose, hydroxymethyl cellulose and hydroxypropyl methyl cellulose; starch-based polymers such as pregelatinized starch, β-modified starch, dextrin and starch, and natural polymers such as Arabic rubber. Compounds: One or more of synthetic polymer compounds such as polyvinyl alcohol and polyvinylpyrrolidone can be mentioned.
These binders may be blended in an amount of 0.5 to 5.0% by weight based on the heat transpiration agent.
Examples of the solvent include water, alcohols such as ethanol, propanol and benzyl alcohol, polyhydric alcohols such as ethylene glycol, diethylene glycol, dipropylene glycol, glycerin and 1,3-butanediol, ethylene glycol monomethyl ether and ethylene glycol mono. Ethyl ether, ethylene glycol monopropyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, diethylene glycol monoisobutyl ether, triethylene glycol monobutyl ether, propylene glycol monomethyl ether, propylene glycol Diethyl ether, dipropylene glycol monomethyl ether, tripropylene glycol monomethyl ether, tripropylene glycol monobutyl ether, propylene glycol monopropyl ether, dipropylene glycol monopropyl ether, propylene glycol monobutyl ether, propylene glycol-tert-butyl ether, dipropylene glycol monobutyl ether , Glycol ethers such as dipropylene glycol dimethyl ether, phenylcarbitol, phenylcellosolve, benzylcarbitol, liquid paraffin, paraffins such as n-paraffin, esters such as diethylphthalate, benzylbenzoate, triethylcitrate, isopropyl myristate, etc. , Other examples include 3-methyl-4-methoxybutanol, N-methylpyrrolidone, propylene carbonate and the like. These solvents may be used alone or in any combination of two or more. It can also be mixed with the above fragrance components and used as a fragrance composition. In addition to mixing and kneading the pest control agent (A) of the present invention at the time of granulation, it can also be sprayed, immersed and held after granulation.
本発明の加熱蒸散剤には、本発明の効果を奏する限り、任意の成分を含んでいてもよい。その他の任意成分としては、例えば、蒸散補助剤、崩壊剤、防錆剤、安定化剤、賦形剤、色素等を用いることができる。
蒸散補助剤としては、例えば、ステアリン酸亜鉛、ステアリン酸アルミニウム、ステアリン酸バリウム、ステアリン酸カルシウム、酸化亜鉛、炭酸亜鉛、炭酸カルシウム、二酸化チタン、カーボンブラック、三酸化アンチモン、デカブロモジフェニレンオキサイド、無水トリメリット酸、無水マレイン酸、ベンゾトリアゾール、４，４’−オキシビス（ベンゼンスルホニルヒドラジド）、尿素等が挙げられる。これらを併用することで、害虫防除剤の揮散効率を調整することができる。
崩壊剤としては、例えば、パラオキシ安息香酸エステル、ステアリン酸エステル、乳酸エチル、サリチル酸クロロフェニル等の有機酸エステル；乳酸、リンゴ酸、フマル酸、酒石酸、アジピン酸、コハク酸等の有機酸、リン酸等の無機酸等が挙げられる。崩壊剤を含有すると、加熱による製剤の崩壊が促進され、害虫防除剤の揮散効率を高めることができる。
防錆剤としては、例えば、１，２，３−ベンゾトリアゾール、ジシクロヘキシルアンモニウムナイトライト等が挙げられる。
安定化剤としては、例えば、ジブチルヒドロキシトルエン、ブチルヒドロキシアニソール、トコフェロール等が挙げられる。
賦形剤としては、例えば、パーライト、タルク、珪藻土、クレイ、ベントナイト、粘土鉱物などの鉱物、ショ糖、ブドウ糖などの糖、マルチトール、ソルビトール、キシリトールなどの糖アルコール等が挙げられる。
さらに必要であれば、各種界面活性剤、効力増強剤等を配合することができる。
The heat transpiration agent of the present invention may contain any component as long as the effects of the present invention are exhibited. As other optional components, for example, transpiration aids, disintegrants, rust inhibitors, stabilizers, excipients, pigments and the like can be used.
Examples of the evaporation aid include zinc stearate, aluminum stearate, barium stearate, calcium stearate, zinc oxide, zinc carbonate, calcium carbonate, titanium dioxide, carbon black, antimony trioxide, decabromodiphenylene oxide, and anhydrous tri. Examples thereof include merit acid, maleic anhydride, benzotriazole, 4,4'-oxybis (benzenesulfonyl hydrazide), urea and the like. By using these in combination, the volatilization efficiency of the pest control agent can be adjusted.
Examples of the disintegrant include organic acid esters such as paraoxybenzoic acid ester, stearic acid ester, ethyl lactate, and chlorophenyl salicylate; organic acids such as lactic acid, malic acid, fumaric acid, tartaric acid, adipic acid, and succinic acid, and phosphoric acid. Inorganic acid and the like. When the disintegrant is contained, the disintegration of the preparation by heating is promoted, and the volatilization efficiency of the pest control agent can be enhanced.
Examples of the rust preventive include 1,2,3-benzotriazole, dicyclohexylammonium nitrate and the like.
Examples of the stabilizer include dibutylhydroxytoluene, butylhydroxyanisole, tocopherol and the like.
Examples of excipients include minerals such as pearlite, talc, diatomaceous soil, clay, bentonite and clay minerals, sugars such as sucrose and glucose, and sugar alcohols such as maltitol, sorbitol and xylitol.
Further, if necessary, various surfactants, efficacy enhancers and the like can be blended.
本発明の加熱蒸散剤は、例えば、図１に示すような、自己発熱装置１の形態で使用される加熱蒸散剤７として使用することができる。
自己発熱装置１は、有底円筒状の容器２を備えており、その底部から側部にかけて加水発熱物質８が収容されている。容器２は、底部に複数の通水孔２１を有し、通水孔２１は通水性を有する部材、例えば不織布シート３によって塞がれている。また、容器２の内部は、仕切部材４により２つの空間に区画されている。仕切部材４は、円筒状で底部が略中空半球状を呈しており、その側壁が容器２の周壁と同心状に配置されている。
加水発熱物質８は、容器２の周壁、仕切部材４及び不織布シート３とで形成される空間に充填され、仕切部材４の内部には加熱蒸散剤７が収容される。また、容器２の上部開放面には、仕切部材４の上部開放面に相当する領域に複数の開口部が形成された蓋部材５が被冠されており、さらに蓋部材５の開口部は通気孔を有する熱溶融フィルム６によって塞がれている。
The heat transpiration agent of the present invention can be used as, for example, the
The self-
The
本発明の加熱蒸散剤の加熱温度としては仕切部材４の底部で測定した時に約２００〜５００℃、好ましくは約３００〜４００℃とするのがよい。
自己発熱装置１で用いる加水発熱物質８としては、加水発熱反応用液との反応により自己発熱する物質であり、例えば、酸化カルシウム、塩化マグネシウム、鉄粉と酸化剤との混合物、硫化ソーダと炭化鉄との混合物等が挙げられ、中でも、加水発熱反応用液と反応させたときの反応の速さ、入手の容易さの点から酸化カルシウムを用いるのが好ましい。加水発熱反応用液は、水あるいは水に各種添加剤を加えられた液が挙げられる。本発明において、加熱発熱物質と加水発熱反応用液は、良好に発熱させるのに質量比１：０．０１〜１：２で含有させるのがよい。さらに、加水発熱物質に対する加水発熱反応用液のモル比が０．２５〜２倍となるようにすることでより良好に発熱させることができる。
このような発熱システムにおいては、加熱蒸散剤７に対して加水発熱物質８を１〜１０重量倍を用いるのがよく、具体的には加熱蒸散剤７を５〜１００ｇに対して、加水発熱物質８は５０〜３００ｇを目安として用いるのがよい。さらに加水発熱物質８に対して水Ｗは０．０５〜２重量倍となるように加えればよい。
従って、使用に際して、自己発熱装置１を水Ｗが入った容器９に入れることにより、水Ｗが通水孔２１を通じて容器２に流入し、さらに不織布シート３を浸透して加水発熱物質８と接触し、そのとき発生した反応熱により加熱蒸散剤７が加熱されて、有機発泡剤である（Ｂ）アゾジカルボンアミドの熱分解ガスと一緒に薬剤である（Ａ）害虫防除剤が揮散して、熱溶融フィルム６の通気孔を通じて外部（室内等）に放出される。また、熱溶融フィルム６は加熱蒸散剤７からの放熱並びに揮散した薬剤との接触により熱溶融するため、蒸散の比較的早い時期から、揮散した薬剤である（Ａ）害虫防除剤は煙となって蓋部材５の開口部を通じて効率良く外部に放出される。
上記加水発熱システム以外の加熱手段としては、例えば、ニクロム線等の電熱線、平板状やリング状、さらに半導体を利用した加熱ヒーター等を用いた電気加熱システム；鉄粉と塩素酸アンモニウム等の酸化剤とを混合する、金属と該金属よりイオン化傾向の小さい金属酸化物又は酸化剤とを混合する、鉄と硫酸カリウム、硫酸鉄、金属塩化物、硫化鉄等の混合物を水や酸素と接触させる、鉄よりイオン化傾向が大きい金属と鉄よりイオン化傾向が小さい金属のハロゲン化物との混合物を水と接触させる、金属と重硫酸塩との混合物を水と接触させる、アルミニウムとアルカリ金属硝酸塩との混合物に水を加える、等の酸化反応により発熱するシステム；硫酸ソーダと炭化鉄との混合物を酸素と接触させる金属硫化物の酸化反応を利用して発熱するシステム等を用いて、加熱する方法が挙げられる。
The heating temperature of the heat transpiration agent of the present invention is preferably about 200 to 500 ° C., preferably about 300 to 400 ° C. when measured at the bottom of the partition member 4.
The
In such a heat generating system, it is preferable to use 1 to 10 times by weight of the
Therefore, at the time of use, by putting the self-
Examples of the heating means other than the water heating system include an electric heating system using a heating wire such as a nichrome wire, a flat plate or a ring, and a heating heater using a semiconductor; oxidation of iron powder and ammonium chlorate and the like. Mix the agent, mix the metal with a metal oxide or oxidizing agent that has a smaller ionization tendency than the metal, and bring a mixture of iron and potassium sulfate, iron sulfate, metal chloride, iron sulfide, etc. into contact with water or oxygen. , A mixture of a metal having a higher ionization tendency than iron and a halide of a metal having a lower ionization tendency than iron is brought into contact with water, a mixture of a metal and a bicarbonate is brought into contact with water, a mixture of aluminum and an alkali metal nitrate. A system that generates heat by an oxidation reaction such as adding water to a metal; a method of heating using a system that generates heat by utilizing an oxidation reaction of a metal sulfide that brings a mixture of sodium sulfate and iron carbide into contact with oxygen. Be done.
以下の実施例において本発明を具体的に説明するが、本発明は、これらの例に限定されるものではない。なお、実施例において、特に明記しない限り、部は重量部を意味する。 The present invention will be specifically described in the following examples, but the present invention is not limited to these examples. In the examples, unless otherwise specified, parts mean parts by weight.
＜実施例１〜１０、比較例１〜６＞
［試験検体の作製］
表１（実施例１〜１０）、表２（比較例１〜６）に記載の各成分（表１、２中の数字は重量％を意味している。）を混合し、造粒、乾燥し、顆粒状の試験検体となる加熱蒸散剤を作成した。加熱蒸散剤１粒あたりの粒径は約３ｍｍ、長さは約７ｍｍである。なお、比較例６は「香料成分」を含有しない加熱蒸散剤である。
<Examples 1 to 10, Comparative Examples 1 to 6>
[Preparation of test sample]
Each component shown in Table 1 (Examples 1 to 10) and Table 2 (Comparative Examples 1 to 6) (the numbers in Tables 1 and 2 mean% by weight) are mixed, granulated and dried. Then, a heat transpiration agent was prepared as a granular test sample. The particle size per grain of the heat transpiration agent is about 3 mm, and the length is about 7 mm. Comparative Example 6 is a heat transpiration agent that does not contain a “fragrance component”.
表１に示す実施例１〜１０、表２に示す比較例１〜６の組成物の調製に際して、以下の化合物を使用した。
「アゾジカルボンアミド」：ユニフォームＡＺ（大塚化学社製）
「α化デンプン」：アミコールＨ（日澱化学社製）
「酸化亜鉛」：酸化亜鉛 １種（正同化学工業社製）
「香料製品」：香料として、ジヒドロジャスモン酸メチル、リナロール、テルピネオール、β−イオノン、α，α−ジメチルフェネチルアルコールを全て含有する香料組成物
「緑茶乾留エキス」：フレッシュＥ（白井松新薬社製）
The following compounds were used in the preparation of the compositions of Examples 1 to 10 shown in Table 1 and Comparative Examples 1 to 6 shown in Table 2.
"Azodicarbonamide": Uniform AZ (manufactured by Otsuka Chemical Co., Ltd.)
"Pregelatinized starch": Amicol H (manufactured by Nissho Chemical Co., Ltd.)
"Zinc oxide":
"Fragrance product": A fragrance composition containing all of methyl dihydrojasmonate, linalool, terpineol, β-ionone, α, α-dimethylphenethyl alcohol as a fragrance "Green tea carbonization extract": Fresh E (manufactured by Shiraimatsu Shinyakusha)
作製した実施例１〜１０、比較例１〜６の加熱蒸散剤をそれぞれ試験検体として、以下の試験方法で煙臭や薬剤臭の臭気の軽減効果と、煙や薬剤による刺激の軽減効果の評価を行った。
［評価試験方法］
天面に１５ｃｍ×１５ｃｍの開閉可能な通気口を開けた０．１９ｍ3（０．６５ｍ（縦）×０．５ｍ（横）×０．５７ｍ（高さ））の容器（ダンボール製）に、０．０６ｇの顆粒状の試験検体を図１の自己発熱装置を用いて加熱蒸散した。通気口以外から煙、臭気などが抜けないようにビニールテープで目張りをした。２時間後、容器天面の開口部を開口し、煙臭、薬剤臭、喉や鼻に感じる刺激感について、専門パネラー１０名により、次の基準で評価した。
［評価基準］
評価は各専門パネラーが煙臭、薬剤臭、喉や鼻に感じる刺激感を、「感じない（１点）」から「感じる（５点）」までの５段階で点数評価した。その評価点数から平均値を求め、比較例６（香料成分を含有しないブランク検体）に対する変化率を、以下の計算式で算出した。
「変化率（％）」＝（各試験検体の平均値−比較例６の平均値）／比較例６の平均値×１００
各試験検体の「煙臭」「薬剤臭」「刺激感」の各評価の変化率（香料成分を含有しないブランク検体である比較例６の平均値に比べてどれだけ増減したか）を、実施例については表３に、比較例については表４にそれぞれ数値を示し、図２には実施例と比較例の各評価をグラフに表した。
なお、この変化率（％）は、マイナス「−」の数値が大きいほど、「煙臭」「薬剤臭」「刺激感」が軽減されていることを表している。
Evaluation of the effect of reducing the odor of smoke and chemical odor and the effect of reducing irritation caused by smoke and chemicals by the following test methods using the prepared heat transpiration agents of Examples 1 to 10 and Comparative Examples 1 to 6 as test samples, respectively. Was done.
[Evaluation test method]
In a container (made of cardboard) of 0.19 m 3 (0.65 m (length) x 0.5 m (width) x 0.57 m (height)) with a 15 cm x 15 cm openable vent on the top surface. 0.06 g of the granular test sample was heated and evaporated using the self-heating device shown in FIG. The vinyl tape was used to prevent smoke and odors from escaping from other than the vents. Two hours later, the opening on the top surface of the container was opened, and the odor of smoke, the odor of chemicals, and the irritation felt in the throat and nose were evaluated by 10 specialized panelists according to the following criteria.
[Evaluation criteria]
The evaluation was based on a five-point scale from "not feeling (1 point)" to "feeling (5 points)" for the odor of smoke, chemical odor, and irritation felt in the throat and nose by each specialized panelist. The average value was obtained from the evaluation points, and the rate of change with respect to Comparative Example 6 (blank sample containing no fragrance component) was calculated by the following formula.
"Rate of change (%)" = (average value of each test sample-average value of Comparative Example 6) / average value of Comparative Example 6 x 100
The rate of change in each evaluation of "smoke odor", "drug odor", and "irritant feeling" of each test sample (how much it increased or decreased compared to the average value of Comparative Example 6 which is a blank sample containing no fragrance component) was carried out. Numerical values are shown in Table 3 for examples and in Table 4 for comparative examples, and FIG. 2 is a graph showing each evaluation of Examples and Comparative Examples.
The rate of change (%) indicates that the larger the value of minus "-", the less "smoke odor", "drug odor", and "irritant sensation".
表３、４および図２の結果より、ジヒドロジャスモン酸メチル、リナロール、テルピネオール、β−イオノン、α，α−ジメチルフェネチルアルコール、メンチルアセテート、メチルアセテート、ベンジルアセテート、α−テルピネンのいずれか１種以上を含有する実施例１〜１０の加熱蒸散剤は、香料を含有しない加熱蒸散剤（比較例６）はもとより、加熱蒸散剤に汎用されている香料、中でもメントール（比較例２）に比べても、煙臭、薬剤臭といった臭気を顕著に軽減することが明らかとなった。
特に、β−イオノンを含有する実施例４、α，α−ジメチルフェネチルアルコールを含有する実施例５、メンチルアセテートを含有する実施例７、メチルアセテートを含有する実施例８や、ジヒドロジャスモン酸メチル、リナロール、テルピネオール、β−イオノン、α，α−ジメチルフェネチルアルコールを全て含有する実施例６は、この臭気軽減効果や刺激感軽減効果に格別に優れた効果を奏する加熱蒸散剤であることも明らかとなった。
From the results of Tables 3 and 4 and FIG. 2, any one or more of methyl dihydrojasmonate, linalool, terpineol, β-ionone, α, α-dimethylphenethyl alcohol, menthol acetate, methyl acetate, benzyl acetate and α-terpinene. The heat-evaporating agents of Examples 1 to 10 containing the above are not only the heat-evaporating agents containing no fragrance (Comparative Example 6) but also the fragrances commonly used as the heat-dissipating agents, especially menthol (Comparative Example 2). , Smoke odor, chemical odor and other odors were found to be significantly reduced.
In particular, Example 4 containing β-ionone, Example 5 containing α, α-dimethylphenethyl alcohol, Example 7 containing mentyl acetate, Example 8 containing methyl acetate, and methyl dihydrojasmonate, It is also clear that Example 6 containing all of linalool, terpineol, β-ionone, α, α-dimethylphenethyl alcohol is a heat-evaporating agent that exerts an exceptionally excellent effect on this odor reducing effect and irritation reducing effect. became.
本発明の加熱蒸散剤は、特定の（Ｃ）香料成分を含有することにより、加熱蒸散する際に発生する、煙臭、薬剤臭といった臭気をマスキングして臭気による不快感を軽減する効果に優れている。また、本発明の加熱蒸散剤は、加熱蒸散する際に発生する、煙や薬剤により喉や鼻の奥がイガイガするような刺激感を顕著に軽減することができる。
これらの臭気軽減効果や刺激軽減効果により、本発明の加熱蒸散剤は、使用後に臭気や刺激等の不快感を感じることが少なく、屋内空間において好適に使用でき、効果的に害虫を駆除することができるため、有用である。
By containing a specific (C) fragrance component, the heat transpiration agent of the present invention has an excellent effect of masking odors such as smoke odor and chemical odor generated during heat transpiration and reducing discomfort due to odor. ing. In addition, the heat-transpiration agent of the present invention can remarkably reduce the irritation that occurs when heat-transpiration occurs, such as the back of the throat and nose being irritated by smoke or chemicals.
Due to these odor reducing effect and irritation reducing effect, the heat transpiration agent of the present invention is less likely to cause discomfort such as odor and irritation after use, can be suitably used in an indoor space, and effectively exterminates pests. It is useful because it can be used.
１ ：自己発熱装置
２ ：容器
３ ：不織布シート
４ ：仕切部材
５ ：蓋部材
６ ：熱溶融フィルム
７ ：加熱蒸散剤
８ ：加水発熱物質
９ ：容器
２１：通水孔
Ｗ ：水
1: Self-heating device 2: Container 3: Non-woven fabric sheet 4: Partition member 5: Lid member 6: Heat-melted film 7: Heat transpiration agent 8: Hydrothermal substance 9: Container 21: Water passage hole W: Water
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