JP6832033B1 - Eye makeup cosmetics - Google Patents
Eye makeup cosmetics Download PDFInfo
- Publication number
- JP6832033B1 JP6832033B1 JP2020121824A JP2020121824A JP6832033B1 JP 6832033 B1 JP6832033 B1 JP 6832033B1 JP 2020121824 A JP2020121824 A JP 2020121824A JP 2020121824 A JP2020121824 A JP 2020121824A JP 6832033 B1 JP6832033 B1 JP 6832033B1
- Authority
- JP
- Japan
- Prior art keywords
- meth
- polymer
- acrylate
- acrylic
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 38
- 239000000835 fiber Substances 0.000 claims abstract description 67
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 53
- 230000002209 hydrophobic effect Effects 0.000 claims description 38
- 229920001296 polysiloxane Polymers 0.000 claims description 30
- 150000001875 compounds Chemical class 0.000 claims description 17
- 229920003067 (meth)acrylic acid ester copolymer Polymers 0.000 claims description 13
- 238000010586 diagram Methods 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 37
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 33
- 229920001577 copolymer Polymers 0.000 description 30
- 210000000720 eyelash Anatomy 0.000 description 21
- 239000000203 mixture Substances 0.000 description 18
- -1 polypropylene Polymers 0.000 description 15
- 239000000178 monomer Substances 0.000 description 12
- 239000002904 solvent Substances 0.000 description 12
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 11
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 10
- 238000001035 drying Methods 0.000 description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 9
- 210000004709 eyebrow Anatomy 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 210000004209 hair Anatomy 0.000 description 7
- 125000003545 alkoxy group Chemical group 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 2
- ZVYGIPWYVVJFRW-UHFFFAOYSA-N 3-methylbutyl prop-2-enoate Chemical compound CC(C)CCOC(=O)C=C ZVYGIPWYVVJFRW-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 2
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000001641 gel filtration chromatography Methods 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 229920005604 random copolymer Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 239000012756 surface treatment agent Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- QPQANCNBWQXGTQ-UHFFFAOYSA-N trihydroxy(trimethylsilylperoxy)silane Chemical compound C[Si](C)(C)OO[Si](O)(O)O QPQANCNBWQXGTQ-UHFFFAOYSA-N 0.000 description 2
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 1
- DJHVICOPLAQAGI-UHFFFAOYSA-N 18-methylnonadecan-1-amine Chemical compound CC(C)CCCCCCCCCCCCCCCCCN DJHVICOPLAQAGI-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 1
- WXBXVVIUZANZAU-UHFFFAOYSA-N 2-decenoic acid Chemical compound CCCCCCCC=CC(O)=O WXBXVVIUZANZAU-UHFFFAOYSA-N 0.000 description 1
- XUDBVJCTLZTSDC-UHFFFAOYSA-N 2-ethenylbenzoic acid Chemical compound OC(=O)C1=CC=CC=C1C=C XUDBVJCTLZTSDC-UHFFFAOYSA-N 0.000 description 1
- 125000006176 2-ethylbutyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(C([H])([H])*)C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- 125000004493 2-methylbut-1-yl group Chemical group CC(C*)CC 0.000 description 1
- FSVQAZDYQRQQKH-UHFFFAOYSA-N 2-methylbutan-2-yl prop-2-enoate Chemical compound CCC(C)(C)OC(=O)C=C FSVQAZDYQRQQKH-UHFFFAOYSA-N 0.000 description 1
- MVCQCVRQBYRRMY-UHFFFAOYSA-N 2-methylidenedecanoic acid Chemical compound CCCCCCCCC(=C)C(O)=O MVCQCVRQBYRRMY-UHFFFAOYSA-N 0.000 description 1
- 125000005916 2-methylpentyl group Chemical group 0.000 description 1
- MICGRWJJZLKTMU-UHFFFAOYSA-N 3,3,5-trimethylhexyl prop-2-enoate Chemical compound CC(C)CC(C)(C)CCOC(=O)C=C MICGRWJJZLKTMU-UHFFFAOYSA-N 0.000 description 1
- SKKHNUKNMQLBTJ-UHFFFAOYSA-N 3-bicyclo[2.2.1]heptanyl 2-methylprop-2-enoate Chemical compound C1CC2C(OC(=O)C(=C)C)CC1C2 SKKHNUKNMQLBTJ-UHFFFAOYSA-N 0.000 description 1
- FXTXRXXCMFFRTL-UHFFFAOYSA-N 4-ethyl-2-methylideneoctanoic acid Chemical compound CCCCC(CC)CC(=C)C(O)=O FXTXRXXCMFFRTL-UHFFFAOYSA-N 0.000 description 1
- CKUYHOSTLVBVQP-UHFFFAOYSA-N 8-methyl-2-methylidenenonanoic acid Chemical compound CC(C)CCCCCC(=C)C(O)=O CKUYHOSTLVBVQP-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 239000001692 EU approved anti-caking agent Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000003212 astringent agent Substances 0.000 description 1
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000004067 bulking agent Substances 0.000 description 1
- RNOOHTVUSNIPCJ-UHFFFAOYSA-N butan-2-yl prop-2-enoate Chemical compound CCC(C)OC(=O)C=C RNOOHTVUSNIPCJ-UHFFFAOYSA-N 0.000 description 1
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 238000010538 cationic polymerization reaction Methods 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003707 hexyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000004491 isohexyl group Chemical group C(CCC(C)C)* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000002463 lignoceryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 125000005439 maleimidyl group Chemical group C1(C=CC(N1*)=O)=O 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- SEEYREPSKCQBBF-UHFFFAOYSA-N n-methylmaleimide Chemical compound CN1C(=O)C=CC1=O SEEYREPSKCQBBF-UHFFFAOYSA-N 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000002560 nitrile group Chemical group 0.000 description 1
- 239000000346 nonvolatile oil Substances 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940065472 octyl acrylate Drugs 0.000 description 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000003538 pentan-3-yl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004115 pentoxy group Chemical group [*]OC([H])([H])C([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000004626 polylactic acid Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- KQFAFFYKLIBKDE-UHFFFAOYSA-M sodium;ethanesulfonate Chemical compound [Na+].CCS([O-])(=O)=O KQFAFFYKLIBKDE-UHFFFAOYSA-M 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- FZGFBJMPSHGTRQ-UHFFFAOYSA-M trimethyl(2-prop-2-enoyloxyethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCOC(=O)C=C FZGFBJMPSHGTRQ-UHFFFAOYSA-M 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 238000009777 vacuum freeze-drying Methods 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
Abstract
【課題】新規なアイメイクアップ化粧料を提供すること。【解決手段】アクリル系ポリマーを含有する皮膜を表面に有する繊維を含有するアイメイクアップ化粧料によって上記課題を解決できる。【選択図】なしPROBLEM TO BE SOLVED: To provide a new eye makeup cosmetic. The above problem can be solved by an eye make-up cosmetic containing fibers having a film containing an acrylic polymer on the surface. [Selection diagram] None
Description
本発明はアイメイクアップ化粧料に関する。 The present invention relates to eye makeup cosmetics.
従来、睫毛、眉毛に用いられるアイメイクアップ化粧料は毛の流れや形を整えてより美しくみせる効果があり、特に睫毛用化粧料に求められる機能としては、例えば、目をより大きく見せるために睫毛の長さ、ボリューム、及び／又はカール力をアップさせることが挙げられる。よりロングラッシュ感を出すために種々の繊維が配合されることがある。 Conventionally, eye makeup cosmetics used for eyelashes and eyebrows have the effect of adjusting the flow and shape of hair to make them look more beautiful. Especially, the function required for eyelash cosmetics is to make the eyes look bigger, for example. Increasing the length, volume, and / or curling force of the eyelashes can be mentioned. Various fibers may be blended to give a longer rush feeling.
しかしながら、繊維の睫毛及び眉毛への付着は偶発的要素に頼る部分が大きく、使用者の塗布回数や繊維の性質によってはほとんどロングラッシュ感が出ない。また塗布時に繊維が毛の流れに沿わず不均一に付着すると、枝分かれ状になるなど外観上の美しさが損なわれてしまっていた。そのため、繊維の分散性を向上させる試みは繊維への表面処理や配合原料により続けられてきたが、これは不均一な付着の改善には効果的であるものの、繊維をより毛へ付着させるという点でのアプローチとしては不十分であり、ロングラッシュ効果を高めるとは言えなかった。 However, the adhesion of fibers to the eyelashes and eyebrows largely depends on accidental factors, and depending on the number of times the user applies the fibers and the properties of the fibers, a long rush feeling is hardly obtained. In addition, if the fibers adhere unevenly without following the flow of hair during application, the appearance is impaired, such as branching. Therefore, attempts to improve the dispersibility of the fibers have been continued by surface treatment on the fibers and compounding raw materials, and although this is effective in improving non-uniform adhesion, it is said that the fibers are more adhered to the hair. It was not sufficient as a point approach and could not be said to enhance the long rush effect.
上記のように既知のアイメイクアップ化粧料にはまだ改善する余地があり、本願は、睫毛等への付着性を向上した繊維を含有するアイメイクアップ化粧料を提供することを目的とする。 As described above, there is still room for improvement in known eye makeup cosmetics, and an object of the present application is to provide eye makeup cosmetics containing fibers having improved adhesion to eyelashes and the like.
上記課題を解決するため、本発明者は鋭意研究を重ねた結果、アクリル系ポリマーで表面を処理した繊維が、睫毛等への付着性を向上することを見いだし、本発明を完成させた。 In order to solve the above problems, the present inventor has completed the present invention by finding that the fiber whose surface is treated with an acrylic polymer improves the adhesion to eyelashes and the like as a result of intensive research.
すなわち本発明は、以下に関するが、それに限定されない。
［発明１］
アクリル系ポリマーを含有する皮膜を表面に有する繊維を含有する、アイメイクアップ化粧料。
［発明２］
前記皮膜が疎水性シリコーン化合物を含有する、発明１に記載のアイメイクアップ化粧料。
［発明３］
前記皮膜が、前記アクリル系ポリマーとして、疎水性（メタ）アクリル酸エステル（共）重合体及び親水性（メタ）アクリル酸エステル（共）重合体を含有する、発明１又は２に記載のアイメイクアップ化粧料。
That is, the present invention relates to, but is not limited to, the following.
[Invention 1]
An eye makeup cosmetic containing fibers having a film containing an acrylic polymer on the surface.
[Invention 2]
The eye makeup cosmetic according to Invention 1, wherein the film contains a hydrophobic silicone compound.
[Invention 3]
The eye makeup according to Invention 1 or 2, wherein the film contains a hydrophobic (meth) acrylic acid ester (co) polymer and a hydrophilic (meth) acrylic acid ester (co) polymer as the acrylic polymer. Up cosmetics.
本発明のアイメイクアップ化粧料は、睫毛又は眉毛への付着性に優れる。 The eye makeup cosmetic of the present invention has excellent adhesion to eyelashes or eyebrows.
本発明には種々の代替形態が可能であるが、本明細書では本発明の特定の態様について詳述する。しかしながら、本明細書における特定の態様の詳述は、本発明を特定の態様に限定しようと意図するものではなく、本発明は特許請求の範囲に規定した本発明の真意及び範囲に含まれる全ての代替形態を包含する。
本明細書において、数値と共に使用される用語「以上」及び「以下」は、その数値を含む数値範囲として理解されるだけでなく、その数値を含まない数値範囲に読み替えることが可能であり、別の言い方をすると、上記用語をそれぞれ「超」及び「未満」に読み替えることが可能である。
Although various alternative forms are possible in the present invention, this specification details specific aspects of the present invention. However, the details of a particular aspect herein are not intended to limit the invention to a particular aspect, and the invention is included in the true meaning and scope of the invention as defined in the claims. Includes alternative forms of.
In the present specification, the terms "greater than or equal to" and "less than or equal to" used together with a numerical value are not only understood as a numerical range including the numerical value, but can also be read as a numerical range not including the numerical value. In other words, the above terms can be read as "super" and "less than", respectively.
アイメイクアップ化粧料
アイメイクアップ化粧料とは、目の周りに用いる化粧料を意味し、好ましくは睫毛用化粧料、及び、眉毛用化粧料を意味する。睫毛（まつげ）用化粧料とは、マスカラとも呼ばれ、睫毛を濃く、長く、及び／又はカールしているように見せるためのものである。眉毛用化粧料とは、アイブロウとも呼ばれ、眉毛の流れや形を整え、時には色を重ねて眉色を変えるためのものである。
Eye make-up cosmetics Eye make-up cosmetics mean cosmetics used around the eyes, preferably eyelash cosmetics and eyebrow cosmetics. Eyelash cosmetics, also called mascara, are intended to make the eyelashes look thicker, longer, and / or curled. Eyebrow cosmetics, also called eyebrows, are used to regulate the flow and shape of eyebrows, and sometimes to layer colors to change the color of the eyebrows.
本発明のアイメイクアップ化粧料（以下、「本発明の化粧料」という）は、アクリル系ポリマーを含有する皮膜を表面に有する繊維を含有する。本発明の化粧料の形態は特に限定されない。例えば液状、乳液状、ジェル状、クリーム状、固形状等が挙げられる。 The eye makeup cosmetics of the present invention (hereinafter referred to as "cosmetics of the present invention") contain fibers having a film having a film containing an acrylic polymer on the surface. The form of the cosmetic of the present invention is not particularly limited. For example, liquid, milky liquid, gel-like, cream-like, solid-like and the like can be mentioned.
繊維
アクリル系ポリマーを含有する皮膜を表面に形成させる繊維としては、例えば、ナイロン、ポリプロピレン、ポリエステル、ポリ乳酸等の合成繊維；セルロース、綿、絹、羊毛等の天然繊維；レーヨン等の再生繊維等が挙げられるが、化粧品上許容されるものならば、特に限定されない。繊維の太さについては特に限定されないが、１〜１３デニール（以下Ｄと記す）が好ましく、４〜８Ｄがより好ましい。繊維の長さについては特に限定されないが、０．２〜６ｍｍが好ましく、１〜３ｍｍがより好ましい。これらの繊維は材質、太さ又は長さにおいて１種又は２種以上を組み合わせて用いることができる。
Fibers Examples of fibers that form a film containing an acrylic polymer on the surface include synthetic fibers such as nylon, polypropylene, polyester, and polylactic acid; natural fibers such as cellulose, cotton, silk, and wool; and recycled fibers such as rayon. However, there is no particular limitation as long as it is cosmetically acceptable. The thickness of the fiber is not particularly limited, but 1 to 13 denier (hereinafter referred to as D) is preferable, and 4 to 8D is more preferable. The length of the fiber is not particularly limited, but is preferably 0.2 to 6 mm, more preferably 1 to 3 mm. These fibers may be used alone or in combination of two or more in terms of material, thickness or length.
皮膜
繊維の表面に形成させる皮膜は、繊維の一部に形成されていてもよいし、全体に形成されていてもよい。当該皮膜はアクリル系ポリマーを含む組成物で繊維の表面を処理することにより形成される。
The film to be formed on the surface of the fiber may be formed on a part of the fiber or may be formed on the whole. The film is formed by treating the surface of the fiber with a composition containing an acrylic polymer.
アクリル系ポリマー
上記繊維に形成させる皮膜に含まれるアクリル系ポリマーは、繊維の表面処理に用いられ、繊維の表面に皮膜を形成する。アクリル系ポリマーとは下式（１）で表される構造を有する（共）重合体を意味する。式（１）中、Ｒ１は水素原子又はメチル基を表す。式（１）中、Ｒ２はカルボキシ基、アルコキシカルボニル基、アミノカルボニル基、ニトリル基等を表すが、これらに制限されるものではない。なお、アクリル系ポリマーは、ナトリウム塩やカリウム塩等のアルカリ金属塩であってもよい。アルコキシカルボニル基におけるアルコキシ基は、炭素数１〜２０のアルコキシ基であれば特に制限されるものではないが、炭素数１〜１０のアルコキシ基が好ましく、炭素数１〜６のアルコキシ基がより好ましい。炭素数１〜６のアルコキシ基としては、例えば、メトキシ基、エトキシ基、プロポキシ基、ブトキシ基、ペンチルオキシ基、ヘキシルオキシ基等が挙げられる。なお、本明細書において、「（共）重合体」とは、単重合体及び共重合体の両方を意味する。「（メタ）アクリル」はアクリル及びメタクリルの両方を意味する。「（メタ）アクリロ」、「（メタ）アクリロイル」、及び「（メタ）アクリレート」についても同様に、アクリロとメタクリロ、アクリロイルとメタクリロイル、及びアクリレートとメタクリレートをそれぞれ意味する。
Acrylic polymer The acrylic polymer contained in the film formed on the fiber is used for the surface treatment of the fiber and forms a film on the surface of the fiber. The acrylic polymer means a (co) polymer having a structure represented by the following formula (1). In formula (1), R 1 represents a hydrogen atom or a methyl group. In the formula (1), R 2 represents a carboxy group, an alkoxycarbonyl group, an aminocarbonyl group, a nitrile group and the like, but is not limited thereto. The acrylic polymer may be an alkali metal salt such as a sodium salt or a potassium salt. The alkoxy group in the alkoxycarbonyl group is not particularly limited as long as it is an alkoxy group having 1 to 20 carbon atoms, but an alkoxy group having 1 to 10 carbon atoms is preferable, and an alkoxy group having 1 to 6 carbon atoms is more preferable. .. Examples of the alkoxy group having 1 to 6 carbon atoms include a methoxy group, an ethoxy group, a propoxy group, a butoxy group, a pentyloxy group, a hexyloxy group and the like. In addition, in this specification, a "(co) polymer" means both a homopolymer and a copolymer. "(Meta) acrylic" means both acrylic and methacrylic. Similarly, "(meth) acrylo", "(meth) acryloyl", and "(meth) acrylate" mean acrylo and methacrylo, acryloyl and methacryloyl, and acrylate and methacrylate, respectively.
アクリル系ポリマーとしては、例えば、疎水性のアクリル系ポリマー、親水性のアクリル系ポリマー等が挙げられる。より具体的には、疎水性の（メタ）アクリル酸（共）重合体又はその塩、親水性の（メタ）アクリル酸（共）重合体又はその塩、疎水性の（メタ）アクリル酸エステル（共）重合体、親水性の（メタ）アクリル酸エステル（共）重合体、疎水性の（メタ）アクリル酸アミド（共）重合体、親水性の（メタ）アクリル酸アミド（共）重合体、疎水性の（メタ）アクリロニトリル（共）重合体、親水性の（メタ）アクリロニトリル（共）重合体等が挙げられる。アクリル系ポリマーの分子量は特に限定されない。アクリル系ポリマーのガラス転移温度（Ｔｇ）は特に限定されないが２５℃以下が好ましく、より好ましくは０℃以下であり、さらに好ましくは−４０℃以下である。これらのポリマーは、１種を単独で用いてもよいし、２種以上を組み合わせて用いてもよい。なお、２種以上のアクリル系ポリマーを組み合わせて繊維の表面処理に用いる場合には、疎水性のアクリル系ポリマーと親水性のアクリル系ポリマーを組み合わせて用いることが好ましい。 Examples of the acrylic polymer include a hydrophobic acrylic polymer and a hydrophilic acrylic polymer. More specifically, a hydrophobic (meth) acrylic acid (co) polymer or a salt thereof, a hydrophilic (meth) acrylic acid (co) polymer or a salt thereof, a hydrophobic (meth) acrylic acid ester ( Co) polymer, hydrophilic (meth) acrylic acid ester (co) polymer, hydrophobic (meth) acrylic acid amide (co) polymer, hydrophilic (meth) acrylic acid amide (co) polymer, Examples thereof include a hydrophobic (meth) acrylonitrile (co) polymer and a hydrophilic (meth) acrylonitrile (co) polymer. The molecular weight of the acrylic polymer is not particularly limited. The glass transition temperature (Tg) of the acrylic polymer is not particularly limited, but is preferably 25 ° C. or lower, more preferably 0 ° C. or lower, and further preferably −40 ° C. or lower. One of these polymers may be used alone, or two or more of these polymers may be used in combination. When two or more kinds of acrylic polymers are used in combination for surface treatment of fibers, it is preferable to use a hydrophobic acrylic polymer and a hydrophilic acrylic polymer in combination.
より具体的には、疎水性の（メタ）アクリル酸（共）重合体又はその塩と、親水性の（メタ）アクリル酸（共）重合体又はその塩との組み合わせ；疎水性の（メタ）アクリル酸（共）重合体又はその塩と、親水性の（メタ）アクリル酸エステル（共）重合体との組み合わせ；疎水性の（メタ）アクリル酸（共）重合体又はその塩と、親水性の（メタ）アクリル酸アミド（共）重合体との組み合わせ；疎水性の（メタ）アクリル酸（共）重合体又はその塩と、親水性の（メタ）アクリロニトリル（共）重合体との組み合わせ；疎水性の（メタ）アクリル酸エステル（共）重合体と、親水性の（メタ）アクリル酸（共）重合体又はその塩との組み合わせ；疎水性の（メタ）アクリル酸エステル（共）重合体と、親水性の（メタ）アクリル酸エステル（共）重合体との組み合わせ；疎水性の（メタ）アクリル酸エステル（共）重合体と、親水性の（メタ）アクリル酸アミド（共）重合体との組み合わせ；疎水性の（メタ）アクリル酸エステル（共）重合体と、親水性の（メタ）アクリロニトリル（共）重合体との組み合わせ；疎水性の（メタ）アクリル酸アミド（共）重合体と、親水性の（メタ）アクリル酸（共）重合体又はその塩との組み合わせ；疎水性の（メタ）アクリル酸アミド（共）重合体と、親水性の（メタ）アクリル酸エステル（共）重合体との組み合わせ；疎水性の（メタ）アクリル酸アミド（共）重合体と、親水性の（メタ）アクリル酸アミド（共）重合体との組み合わせ；疎水性の（メタ）アクリル酸アミド（共）重合体と、親水性の（メタ）アクリロニトリル（共）重合体との組み合わせ；疎水性の（メタ）アクリロニトリル（共）重合体と、親水性の（メタ）アクリル酸（共）重合体又はその塩との組み合わせ；疎水性の（メタ）アクリロニトリル（共）重合体と、親水性の（メタ）アクリル酸エステル（共）重合体との組み合わせ；疎水性の（メタ）アクリロニトリル（共）重合体と、親水性の（メタ）アクリル酸アミド（共）重合体との組み合わせ；疎水性の（メタ）アクリロニトリル（共）重合体と、親水性の（メタ）アクリロニトリル（共）重合体との組み合わせ；等が挙げられる。 More specifically, a combination of a hydrophobic (meth) acrylic acid (co) polymer or a salt thereof and a hydrophilic (meth) acrylic acid (co) polymer or a salt thereof; a hydrophobic (meth) Combination of acrylic acid (co) polymer or salt thereof and hydrophilic (meth) acrylic acid ester (co) polymer; hydrophobic (meth) acrylic acid (co) polymer or salt thereof and hydrophilic Combination with (meth) acrylic acid amide (co) polymer; combination of hydrophobic (meth) acrylic acid (co) polymer or salt thereof and hydrophilic (meth) acrylonitrile (co) polymer; A combination of a hydrophobic (meth) acrylic acid ester (co) polymer and a hydrophilic (meth) acrylic acid (co) polymer or a salt thereof; a hydrophobic (meth) acrylic acid ester (co) polymer And a hydrophilic (meth) acrylic acid ester (co) polymer; a hydrophobic (meth) acrylic acid ester (co) polymer and a hydrophilic (meth) acrylic acid amide (co) polymer. Combination with; Hydrophilic (meth) acrylic acid ester (co) polymer and hydrophilic (meth) acrylonitrile (co) polymer; Hydrophilic (meth) acrylic acid amide (co) polymer And a combination of a hydrophilic (meth) acrylic acid (co) polymer or a salt thereof; a hydrophobic (meth) acrylic acid amide (co) polymer and a hydrophilic (meth) acrylic acid ester (co). Combination with polymer; Hydrophilic (meth) acrylic acid amide (co) polymer and hydrophilic (meth) acrylic acid amide (co) polymer; Hydrophilic (meth) acrylic acid amide ( Combination of co) polymer and hydrophilic (meth) acrylonitrile (co) polymer; hydrophobic (meth) acrylonitrile (co) polymer and hydrophilic (meth) acrylic acid (co) polymer or Combination with the salt; Combination of hydrophobic (meth) acrylonitrile (co) polymer and hydrophilic (meth) acrylic acid ester (co) polymer; Hydrophilic (meth) acrylonitrile (co) polymer And a hydrophilic (meth) acrylic acid amide (co) polymer; a combination of a hydrophobic (meth) acrylonitrile (co) polymer and a hydrophilic (meth) acrylonitrile (co) polymer; And so on.
疎水性のアクリル系ポリマーと親水性のアクリル系ポリマーとを組み合わせて用いる場合には、疎水性のアクリル系ポリマーの質量（ｏ）と、親水性のアクリル系ポリマーの質量（ｗ）の比［ｗ／ｏ］が、０．０５以上であることが好ましく、０．１０以上であることがより好ましく、０．２５以上であることが特に好ましい。また、比［ｗ／ｏ］は、４．００以下であることが好ましく、２．００以下であることがより好ましく、１．００以下であることが特に好ましい。 When a hydrophobic acrylic polymer and a hydrophilic acrylic polymer are used in combination, the ratio of the mass (o) of the hydrophobic acrylic polymer to the mass (w) of the hydrophilic acrylic polymer [w]. / O] is preferably 0.05 or more, more preferably 0.10 or more, and particularly preferably 0.25 or more. The ratio [w / o] is preferably 4.00 or less, more preferably 2.00 or less, and particularly preferably 1.00 or less.
各種共重合体としては、式（１）で表される構造を２種以上有するものであってもよいし、少なくとも１種の式（１）で表される構造と、少なくとも１種の他の重合性不飽和結合含有モノマーの残基を有するものであってもよい。これらの共重合体は、２種以上の、式（１）で表される構造を有するモノマー（以下、「アクリルモノマー」という）を用いて重合したり、少なくとも１種のアクリルモノマーと、少なくとも１種の他の重合性不飽和結合含有モノマーとを用いて重合したりすることにより製造することができる。共重合体の製造に用いられうる各モノマーの比率は特に限定されない。なお、各種単重合体は、アクリルモノマーを重合することにより製造することができる。 The various copolymers may have two or more types of structures represented by the formula (1), a structure represented by at least one type (1), and at least one other type. It may have a residue of a polymerizable unsaturated bond-containing monomer. These copolymers may be polymerized using two or more kinds of monomers having a structure represented by the formula (1) (hereinafter, referred to as "acrylic monomer"), or at least one kind of acrylic monomer and at least one. It can be produced by polymerizing with other polymerizable unsaturated bond-containing monomers of the species. The ratio of each monomer that can be used in the production of the copolymer is not particularly limited. Various homopolymers can be produced by polymerizing an acrylic monomer.
アクリル系ポリマーの製造に用いられるアクリルモノマーとしては、特に限定されるものではないが、例えば、（メタ）アクリル酸又はその塩、（メタ）アクリル酸エステル、（メタ）アクリル酸アミド、（メタ）アクリロニトリルが挙げられる。（メタ）アクリル酸エステルとしては、例えば、炭素数１〜２０のアルキル（メタ）アクリレート；ヒドロキシ基、カルボキシ基、アミノ基、リン酸基、スルホ基等の親水基を有する炭素数１〜２０のアルキル（メタ）アクリレート；等が挙げられる。より具体的には、（メタ）アクリル酸メチル、（メタ）アクリル酸エチル、（メタ）アクリル酸プロピル、（メタ）アクリル酸イソプロピル、（メタ）アクリル酸ブチル、（メタ）アクリル酸イソブチル、（メタ）アクリル酸ｓ−ブチル、（メタ）アクリル酸ｔ−ブチル、（メタ）アクリル酸ペンチル、（メタ）アクリル酸ｓ−ペンチル、（メタ）アクリル酸１−エチルプロピル、（メタ）アクリル酸２−メチルブチル、（メタ）アクリル酸イソペンチル、（メタ）アクリル酸ｔ−ペンチル、（メタ）アクリル酸３−メチルブチル、（メタ）アクリル酸ネオペンチル、（メタ）アクリル酸ヘキシル、（メタ）アクリル酸２−メチルペンチル、（メタ）アクリル酸４−メチルペンチル、（メタ）アクリル酸２−エチルブチル、（メタ）アクリル酸シクロペンチル、（メタ）アクリル酸シクロヘキシル、（メタ）アクリル酸ヘプチル、（メタ）アクリル酸２−ヘプチル、（メタ）アクリル酸３−ヘプチル、（メタ）アクリル酸オクチル、（メタ）アクリル酸２−オクチル、（メタ）アクリル酸２−エチルヘキシル、（メタ）アクリル酸イソオクチル、（メタ）アクリル酸ノニル、（メタ）アクリル酸３，３，５−トリメチルヘキシル、（メタ）アクリル酸デシル、（メタ）アクリル酸ウンデシル、（メタ）アクリル酸ラウリル、（メタ）アクリル酸セチル、（メタ）アクリル酸ステアリル、（メタ）アクリル酸エイコシル、（メタ）アクリル酸ドコシル、（メタ）アクリル酸テトラコシル、（メタ）アクリル酸メチルシクロヘキシル、（メタ）アクリル酸イソボルニル、（メタ）アクリル酸ノルボルニル、（メタ）アクリル酸ベンジル、（メタ）アクリル酸フェネチル、（メタ）アクリル酸２−ヒドロキシエチル、（メタ）アクリル酸２−ヒドロキシプロピル、（メタ）アクリル酸２，３−ジヒドロキシプロピル、（（メタ）アクリロイルオキシ）酢酸、コハク酸１−［２−（（メタ）アクリロイルオキシ）エチル］、（メタ）アクリル酸ジメチルアミノエチル、（メタ）アクリロイルオキシエチルトリメチルアンモニウムクロライド、［２−（（メタ）アクリロイルオキシ）エチル］ホスファート、２−（（メタ）アクリロイルオキシ）エタンスルホン酸ナトリウム等が挙げられる。 The acrylic monomer used in the production of the acrylic polymer is not particularly limited, but for example, (meth) acrylic acid or a salt thereof, (meth) acrylic acid ester, (meth) acrylic acid amide, (meth). Acrylonitrile can be mentioned. The (meth) acrylic acid ester is, for example, an alkyl (meth) acrylate having 1 to 20 carbon atoms; having a hydrophilic group such as a hydroxy group, a carboxy group, an amino group, a phosphoric acid group, or a sulfo group and having 1 to 20 carbon atoms. Alkyl (meth) acrylate; and the like. More specifically, methyl (meth) acrylate, ethyl (meth) acrylate, propyl (meth) acrylate, isopropyl (meth) acrylate, butyl (meth) acrylate, isobutyl (meth) acrylate, (meth). ) S-butyl acrylate, t-butyl (meth) acrylate, pentyl (meth) acrylate, s-pentyl (meth) acrylate, 1-ethylpropyl (meth) acrylate, 2-methylbutyl (meth) acrylate , (Meta) isopentyl acrylate, (meth) t-pentyl acrylate, (meth) 3-methylbutyl acrylate, neopentyl (meth) acrylate, hexyl (meth) acrylate, 2-methylpentyl (meth) acrylate, 4-Methylpentyl (meth) acrylate, 2-ethylbutyl (meth) acrylate, cyclopentyl (meth) acrylate, cyclohexyl (meth) acrylate, heptyl (meth) acrylate, 2-heptyl (meth) acrylate, ( 3-Heptyl Acrylic Acid, (Meta) Octyl Acrylate, 2-Octyl Acrylic Acid (Meta), 2-Ethylhexyl Acrylic Acid (Meta), Isooctyl Acrylic Acid, Nonyl (Meta) Acrylic Acid, (Meta) 3,3,5-trimethylhexyl acrylate, decyl (meth) acrylate, undecyl (meth) acrylate, lauryl (meth) acrylate, cetyl (meth) acrylate, stearyl (meth) acrylate, (meth) acrylic Eikosyl acid, docosyl (meth) acrylate, tetracosyl (meth) acrylate, methylcyclohexyl (meth) acrylate, isobornyl (meth) acrylate, norbornyl (meth) acrylate, benzyl (meth) acrylate, (meth) acrylic Penetyl acid, 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 2,3-dihydroxypropyl (meth) acrylate, (meth) acryloyloxy) acetic acid, 1-[2] succinate -((Meta) acryloyloxy) ethyl], (meth) dimethylaminoethyl acrylate, (meth) acryloyloxyethyl trimethylammonium chloride, [2-((meth) acryloyloxy) ethyl] phosphate, 2-((meth) Acryloyloxy) Sodium ethanesulfonate and the like can be mentioned.
重合性不飽和結合含有モノマーとしては、例えば、エチレン、プロピレン、１，３−ブタジエン等の末端に重合性不飽和結合を有する炭化水素化合物；マレイン酸、フマル酸等のα，β−不飽和多価カルボン酸、無水マレイン酸等のα，β−不飽和カルボン酸無水物；Ｎ−メチルマレイミド等のマレイミド基含有化合物；スチレン、ビニル安息香酸等の芳香族ビニル化合物；等が挙げられる。 Examples of the polymerizable unsaturated bond-containing monomer include hydrocarbon compounds having a polymerizable unsaturated bond at the terminal such as ethylene, propylene and 1,3-butadiene; α, β-unsaturated polycarbonate such as maleic acid and fumaric acid. Examples thereof include α, β-unsaturated carboxylic acid anhydrides such as valent carboxylic acid and maleic anhydride; maleimide group-containing compounds such as N-methylmaleimide; and aromatic vinyl compounds such as styrene and vinyl benzoic acid.
アクリル系ポリマーが共重合体である場合、それはブロック共重合体でもランダム共重合体でもよい。共重合体中にブロック共重合部分及びランダム共重合部分の両方が存在してもよい。 When the acrylic polymer is a copolymer, it may be a block copolymer or a random copolymer. Both a block copolymer and a random copolymer may be present in the copolymer.
本明細書において、アクリル系ポリマーのガラス転移温度［Ｔｇ（Ｋ：ケルビン）］は、Ｆｏｘの式（１／Ｔｇ＝Σ（Ｗｉ／Ｔｇｉ））によって算出される値を示す（式中、ｉは１以上の整数であり、Ｗｉ（ｉ＝１、２、・・・ｉ）は各モノマーの質量分率、Ｔｇｉ（ｉ＝１、２、・・・ｉ）は各モノマーのｉホモポリマーのガラス転移温度（ケルビン）を示す。）。 In the present specification, the glass transition temperature [Tg (K: Kelvin)] of the acrylic polymer indicates a value calculated by the Fox formula (1 / Tg = Σ (Wi / Tgi)) (in the formula, i is). It is an integer of 1 or more, Wi (i = 1, 2, ... I) is the mass fraction of each monomer, and Tgi (i = 1, 2, ... i) is the glass of the i homopolymer of each monomer. The transition temperature (Kelvin) is shown.).
アクリル系ポリマーの製造において、各種モノマーの重合は、ラジカル重合、カチオン重合、アニオン重合等の方法によって行われる。なお、重合後に変性剤を用いてアクリル系ポリマーを変性させてもよい。重合反応温度は特に制限されるものではないが、通常７０℃以上２００℃以下の範囲内である。反応時間は特に制限されるものではないが、通常１０分間以上２４時間以内の範囲内である。 In the production of acrylic polymers, the polymerization of various monomers is carried out by methods such as radical polymerization, cationic polymerization and anionic polymerization. The acrylic polymer may be modified with a modifier after the polymerization. The polymerization reaction temperature is not particularly limited, but is usually in the range of 70 ° C. or higher and 200 ° C. or lower. The reaction time is not particularly limited, but is usually in the range of 10 minutes or more and 24 hours or less.
溶媒
溶媒としては、化粧品上許容されるものであれば限定されず、例えば、水、イソドデカン等の揮発性油剤、不揮発性油剤、及びそれらの任意の組み合わせが挙げられる。
Solvent The solvent is not limited as long as it is cosmetically acceptable, and examples thereof include water, volatile oils such as isododecane, non-volatile oils, and any combinations thereof.
上記組成物は、アクリル系ポリマーの他に、溶媒、疎水性シリコーン化合物、添加剤等の他の成分を含んでもよい。 The composition may contain other components such as a solvent, a hydrophobic silicone compound, and an additive in addition to the acrylic polymer.
疎水性シリコーン化合物
上記組成物は、睫毛又は眉毛に対する繊維の付着性、付着均一性、及び／又は分散性を向上又は調整するために、１種又は２種以上の疎水性シリコーン化合物を含んでもよい。疎水性シリコーン化合物としては、例えば、メチルハイドロジェンポリシロキサン、環状メチルハイドロジェンポリシロキサン、ジメチルポリシロキサン，環状ジメチルポリシロキサン、メチルフェニルポリシロキサン等のオルガノポリシロキサン；アミノ変性シリコーン、エポキシ変性シリコーン、カルボキシル変性シリコーン、カルビノール変性シリコーン、メタクリル変性シリコーン、メルカプト変性シリコーン、フェノール変性シリコーン、ポリエーテル変性シリコーン、メチルスチリル変性シリコーン、アルキル変性シリコーン、高級脂肪酸エステル変性シリコーン、高級アルコール変性シリコーン、アクリル酸アルキル・メチルシロキサン共重合体等の変性シリコーンもしくはオルガノシロキサン共重合体、トリメチルシロキシケイ酸等のシリコーン樹脂；架橋型メチルポリシロキサンが挙げられる。これらのうち１種又は２種以上が任意に選択できるが、それに限定されずその誘導体でも構わない。
Hydrophobic Silicone Compounds The composition may contain one or more hydrophobic silicone compounds in order to improve or adjust the adhesion, uniformity and / or dispersibility of the fibers to the eyelashes or eyebrows. .. Examples of the hydrophobic silicone compound include organopolysiloxanes such as methylhydrogenpolysiloxane, cyclic methylhydrogenpolysiloxane, dimethylpolysiloxane, cyclic dimethylpolysiloxane, and methylphenylpolysiloxane; amino-modified silicone, epoxy-modified silicone, and carboxyl. Modified silicones, carbinol-modified silicones, methacryl-modified silicones, mercapto-modified silicones, phenol-modified silicones, polyether-modified silicones, methylstyryl-modified silicones, alkyl-modified silicones, higher fatty acid ester-modified silicones, higher alcohol-modified silicones, alkyl-methyl acrylates Modified silicones such as siloxane copolymers or organosiloxane copolymers, silicone resins such as trimethylsiloxysilicic acid; crosslinked methylpolysiloxanes can be mentioned. One or more of these can be arbitrarily selected, but the present invention is not limited to this, and a derivative thereof may be used.
上記疎水性シリコーン化合物は、１分子中に−ＳｉＲ１Ｒ２Ｒ３（式中、Ｒ１、Ｒ２及びＲ３は互いに独立に、炭素数１〜４のアルキル基、アルコキシ基、又は水酸基を表す）で示される官能基（ａ）を２個以上有しているが、この官能基（ａ）の１個あたりの分子量（重量平均分子量／官能基数）が１００〜５０００の範囲内にあるものが好ましい。なお、上記重量平均分子量は、ゲルろ過クロマトグラフィー（ＧＦＣ）により測定でき、ポリエチレングリコールで換算した値である。 The above-mentioned hydrophobic silicone compound contains −SiR 1 R 2 R 3 (in the formula, R 1 , R 2 and R 3 independently of each other, an alkyl group having 1 to 4 carbon atoms, an alkoxy group, or a hydroxyl group in one molecule. It has two or more functional groups (a) represented by (represented), and the molecular weight (weight average molecular weight / number of functional groups) per functional group (a) is in the range of 100 to 5000. Is preferable. The weight average molecular weight can be measured by gel filtration chromatography (GFC) and is a value converted with polyethylene glycol.
添加剤
添加剤としては、例えば、界面活性剤、ジメチルステアリルアンモニウムヘクトライト等の増粘剤、パルミチン酸デキストリン等のゲル化剤、抗ケーキング剤、乳化剤、分散化剤、安定剤、保湿剤、炭酸プロピレン等の粘度調節剤、ミツロウ・セレシン等の固形化剤、結合剤、タルク等の増量剤、不透明化剤、滑沢剤、顔料、紫外線散乱剤、紫外線吸収剤、ｐＨ調整剤、抗酸化剤、抗菌剤、防腐剤、スキンケア剤、潤滑剤、収斂剤、エモリエント剤、ツヤ出し剤、光沢剤、消泡剤、トリメチルシロキシケイ酸等の撥水性皮膜剤、保護剤等が挙げられるが、化粧品上許容されるものであれば特に制限されない。これら２つ以上の用途・効果が重複しているものを含有してもよい。
Additives Examples of additives include surfactants, thickeners such as dimethylstearylammonium hectrite, gelling agents such as dextrin palmitate, anti-caking agents, emulsifiers, dispersants, stabilizers, moisturizers, and carbonic acid. Viscosity modifiers such as propylene, solidifying agents such as Mitsurou and selecin, binders, bulking agents such as talc, opaque agents, lubricants, pigments, UV scatterers, UV absorbers, pH adjusters, antioxidants , Antibacterial agents, preservatives, skin care agents, lubricants, astringents, emollients, polishes, brighteners, antifoaming agents, water-repellent film agents such as trimethylsiloxysilicic acid, protective agents, etc. The above is not particularly limited as long as it is permissible. It may contain those having two or more uses / effects overlapping.
繊維表面の皮膜成分として、アクリル系ポリマーの含有量は、皮膜に含有される成分の総量に対して５０質量％以上が好ましく、より好ましくは６０質量％以上であり、さらに好ましくは７０質量％以上であり、特に好ましくは８０質量％以上である。アクリル系ポリマーの含有量は、１００質量％以下であり、好ましくは９７質量％以下であり、より好ましくは９５質量％以下であり、さらに好ましくは９２質量％以下であり、特に好ましくは９０質量％以下である。アクリル系ポリマーとして疎水性のアクリル系ポリマーと親水性のアクリル系ポリマーとが皮膜に含有される場合には、親水性のアクリル系ポリマーの含有量は、アクリル系ポリマーの総量に対して５質量％以上が好ましく、より好ましくは１０質量％以上であり、さらに好ましくは１５質量％以上である。親水性のアクリル系ポリマーの含有量は、８５質量％以下が好ましく、より好ましくは７５質量％以下であり、さらに好ましくは６５質量％以下である。疎水性シリコーン化合物が皮膜に含有される場合には、疎水性シリコーン化合物の含有量は、皮膜に含有される成分の総量に対して３質量％以上が好ましく、より好ましくは５質量％以上であり、さらに好ましくは８質量％以上であり、特に好ましくは１０質量％以上である。疎水性シリコーン化合物の含有量は、５０質量％以下が好ましく、より好ましくは４０質量％以下であり、さらに好ましくは３０質量％以下であり、特に好ましくは２０質量％以下である。 The content of the acrylic polymer as the film component on the fiber surface is preferably 50% by mass or more, more preferably 60% by mass or more, still more preferably 70% by mass or more, based on the total amount of the components contained in the film. It is particularly preferably 80% by mass or more. The content of the acrylic polymer is 100% by mass or less, preferably 97% by mass or less, more preferably 95% by mass or less, still more preferably 92% by mass or less, and particularly preferably 90% by mass. It is as follows. When a hydrophobic acrylic polymer and a hydrophilic acrylic polymer are contained in the film as the acrylic polymer, the content of the hydrophilic acrylic polymer is 5% by mass with respect to the total amount of the acrylic polymer. The above is preferable, more preferably 10% by mass or more, still more preferably 15% by mass or more. The content of the hydrophilic acrylic polymer is preferably 85% by mass or less, more preferably 75% by mass or less, and further preferably 65% by mass or less. When the hydrophobic silicone compound is contained in the film, the content of the hydrophobic silicone compound is preferably 3% by mass or more, more preferably 5% by mass or more, based on the total amount of the components contained in the film. , More preferably 8% by mass or more, and particularly preferably 10% by mass or more. The content of the hydrophobic silicone compound is preferably 50% by mass or less, more preferably 40% by mass or less, further preferably 30% by mass or less, and particularly preferably 20% by mass or less.
本発明の化粧料において、アクリル系ポリマーを含有する皮膜を表面に有する繊維の配合量は、繊維の種類によっても異なるが、好ましくは０．０１〜１０質量％であり、より好ましくは０．１〜５質量％である。繊維の表面に形成される皮膜中のアクリル系ポリマーの量（質量）は、付着性の点から、アクリル系ポリマーを含有する皮膜を表面に形成させる繊維の量（質量）に対して０．００３５％以上が好ましく、また、分散性の点から、アクリル系ポリマーを含有する皮膜を表面に形成させる繊維の量に対して２０％以下が好ましい。すなわち、繊維表面に形成される皮膜中のアクリル系ポリマーの量は、好ましくは、アクリル系ポリマーを含有する皮膜を表面に形成させる繊維の量に対して０．００３５〜２０％であり、より好ましくは０．００５〜５％であり、さらに好ましくは０．００７〜０．２％である。 In the cosmetic of the present invention, the blending amount of the fiber having a film containing an acrylic polymer on the surface varies depending on the type of fiber, but is preferably 0.01 to 10% by mass, more preferably 0.1. ~ 5% by mass. The amount (mass) of the acrylic polymer in the film formed on the surface of the fiber is 0.0035 with respect to the amount (mass) of the fiber forming the film containing the acrylic polymer on the surface from the viewpoint of adhesion. % Or more is preferable, and from the viewpoint of dispersibility, 20% or less is preferable with respect to the amount of fibers forming a film containing an acrylic polymer on the surface. That is, the amount of the acrylic polymer in the film formed on the fiber surface is preferably 0.0035 to 20% with respect to the amount of the fiber forming the film containing the acrylic polymer on the surface, which is more preferable. Is 0.005 to 5%, more preferably 0.007 to 0.2%.
本発明の化粧料において、上記皮膜が疎水性シリコーン化合物を含有する場合、その量（質量）は、滑らかな使用感が得られる点から、アクリル系ポリマーを含有する皮膜を表面に形成させる繊維の量（質量）に対して０．０００５％以上が好ましく、付着性及び／又は付着均一性の点から、アクリル系ポリマーを含有する皮膜を表面に形成させる繊維の量に対して５％以下が好ましい。すなわち、好ましくは０．０００５〜５％であり、より好ましくは０．０００５〜１％であり、さらに好ましくは０．０００９〜０．１％である。また、繊維表面に形成される皮膜中の疎水性シリコーン化合物の量と、繊維表面に形成される皮膜中のアクリル系ポリマーの量との質量比（疎水性シリコーン化合物の量／アクリル系ポリマーの量）で決定してもよく、好ましくは０．０４〜２であり、より好ましくは０．０５〜１であり、さらに好ましくは０．０６〜０．５であり、一層さらに好ましくは０．１〜０．３である。 In the cosmetic of the present invention, when the film contains a hydrophobic silicone compound, the amount (mass) of the film is such that a film containing an acrylic polymer is formed on the surface from the viewpoint of obtaining a smooth feeling of use. 0.0005% or more is preferable with respect to the amount (mass), and 5% or less is preferable with respect to the amount of fibers forming a film containing an acrylic polymer on the surface from the viewpoint of adhesion and / or adhesion uniformity. .. That is, it is preferably 0.0005 to 5%, more preferably 0.0005 to 1%, and even more preferably 0.009 to 0.1%. Further, the mass ratio of the amount of the hydrophobic silicone compound in the film formed on the fiber surface to the amount of the acrylic polymer in the film formed on the fiber surface (amount of hydrophobic silicone compound / amount of acrylic polymer). ), It is preferably 0.04 to 2, more preferably 0.05 to 1, still more preferably 0.06 to 0.5, and even more preferably 0.1 to 1. It is 0.3.
製造方法
本発明の化粧料は、当業者の技術常識に従い慣用の処方例に従って製造出来る。各成分を配合する方法、順序等は当業者の技術常識に従い任意である。例えば、溶媒及びアクリル系ポリマーを混合し、必要に応じて、疎水性シリコーン化合物、添加剤等をさらに混合した組成物を調製し、当該組成物を繊維に接触させた後、溶媒等を乾燥し、所定の皮膜を有する繊維を得る。次いで、得られた、所定の皮膜を有する繊維と、溶媒、添加剤等の他の化粧料成分とを配合することにより本発明の化粧料を製造することができる。なお、疎水性シリコーン化合物は、アクリル系ポリマーを含有する組成物に含ませないで、アクリル系ポリマーを含有する組成物を繊維へ接触させる前又は接触させた後、疎水性シリコーン化合物を含有する組成物を当該繊維へ接触させてもよい。
Manufacturing Method The cosmetic of the present invention can be manufactured according to a conventional prescription example according to the common general technical knowledge of those skilled in the art. The method, order, etc. of blending each component are arbitrary according to the common general technical knowledge of those skilled in the art. For example, a solvent and an acrylic polymer are mixed to prepare a composition in which a hydrophobic silicone compound, an additive and the like are further mixed, if necessary, the composition is brought into contact with the fiber, and then the solvent and the like are dried. , To obtain a fiber having a predetermined film. Next, the cosmetic of the present invention can be produced by blending the obtained fiber having a predetermined film with other cosmetic components such as a solvent and an additive. The hydrophobic silicone compound is not included in the composition containing the acrylic polymer, but the composition containing the hydrophobic silicone compound before or after the composition containing the acrylic polymer is brought into contact with the fiber. The object may be brought into contact with the fiber.
組成物と繊維との接触方法としては、特に制限されるものではなく、組成物を塗布又は噴霧する方法、それらを混合する方法（浸漬方法を含む）等が挙げられる。 The method of contacting the composition with the fiber is not particularly limited, and examples thereof include a method of applying or spraying the composition, a method of mixing them (including a dipping method), and the like.
組成物と繊維との接触前に、任意に、繊維表面の油分や汚れを除去する目的で、繊維に前処理を施してもよい。前処理を施すことにより繊維表面を清浄化でき、それにより、組成物によって繊維表面が均一に濡れやすくなる。
なお、前処理の方法としては、特に限定されず、湯洗、溶媒洗浄、脱脂洗浄等の方法が挙げられる。
Prior to contact between the composition and the fiber, the fiber may optionally be pretreated for the purpose of removing oil and dirt on the fiber surface. The pretreatment can clean the fiber surface, which makes it easier for the composition to uniformly wet the fiber surface.
The pretreatment method is not particularly limited, and examples thereof include hot water washing, solvent washing, and degreasing washing.
繊維に対する組成物の接触温度及び接触時間は、均一に繊維表面に当該組成物を接触できれば特に制限されず、繊維の種類や形状、使用される組成物中の溶媒や成分の種類等によって適宜最適な条件が選択される。
接触温度は、例えば、１０〜４０℃であってもよい。
接触時間は、例えば、０．１秒〜１０分であってもよい。
The contact temperature and contact time of the composition with respect to the fiber are not particularly limited as long as the composition can be uniformly contacted with the fiber surface, and are appropriately optimized depending on the type and shape of the fiber, the type of solvent and components in the composition used, and the like. Conditions are selected.
The contact temperature may be, for example, 10 to 40 ° C.
The contact time may be, for example, 0.1 seconds to 10 minutes.
前記接触後、前記乾燥前に、任意に、繊維に対して中間処理を施してもよい。中間処理としては、特に限定されず、例えば洗浄が挙げられる。前記洗浄の方法としては、特に限定されず、例えば、湯洗、溶媒洗浄等の方法が挙げられる。 After the contact and before the drying, the fibers may be optionally subjected to an intermediate treatment. The intermediate treatment is not particularly limited, and examples thereof include cleaning. The cleaning method is not particularly limited, and examples thereof include hot water washing and solvent washing.
溶媒等の乾燥温度、乾燥方法、及び乾燥時間は、溶媒等が揮発し、アクリル系ポリマーを含有する皮膜を形成できる条件であれば特に制限されず、繊維の種類や形状、使用される組成物中の溶媒や成分の種類等によって適宜最適な条件が選択される。
乾燥方法としては、例えば、自然乾燥、風乾、加熱乾燥、減圧乾燥、凍結乾燥、及びこれらの任意の組み合わせ等が挙げられる。
加熱方法としては、例えば、熱風、インダクションヒーター、赤外線、近赤外線等が挙げられる。
乾燥温度は、例えば、２５〜２５０℃であってもよい。
乾燥時間は、例えば、１秒〜１時間であってもよい。
The drying temperature, drying method, and drying time of the solvent or the like are not particularly limited as long as the solvent or the like volatilizes and a film containing an acrylic polymer can be formed, and the type and shape of the fiber and the composition used are not particularly limited. Optimal conditions are appropriately selected depending on the type of solvent and components inside.
Examples of the drying method include natural drying, air drying, heat drying, vacuum drying, freeze drying, and any combination thereof.
Examples of the heating method include hot air, an induction heater, infrared rays, near infrared rays, and the like.
The drying temperature may be, for example, 25 to 250 ° C.
The drying time may be, for example, 1 second to 1 hour.
以下、具体例を挙げて本発明を更に詳細に説明するが、これらの実施例は本発明の技術的範囲を何ら限定するものではない。当業者は要求される耐久性、カール力、その他の条件に応じて適宜配合を調整できる。なお、以下の実施例及び比較例における配合量（含有量）は全て質量％である。 Hereinafter, the present invention will be described in more detail with reference to specific examples, but these examples do not limit the technical scope of the present invention in any way. Those skilled in the art can appropriately adjust the formulation according to the required durability, curling force, and other conditions. The blending amount (content) in the following Examples and Comparative Examples is all mass%.
処方
表２の各成分を水に混合し、表面処理剤を作製した。各表面処理剤に、ナイロンファイバー（以下繊維）を５〜１０分間浸漬した。その後、繊維を取り出し、オーブンにて繊維の表面を十分乾燥させた。表面処理を行った、又は未処理の、繊維、及び表１に示す原料を用いて化粧料を調製した。表２に記載の割合は、繊維表面に形成された皮膜に含有する全ての成分の総量に対する各成分の質量％を示す。
Each component of the formulation Table 2 was mixed with water to prepare a surface treatment agent. Nylon fiber (hereinafter referred to as “fiber”) was immersed in each surface treatment agent for 5 to 10 minutes. Then, the fiber was taken out and the surface of the fiber was sufficiently dried in an oven. Cosmetics were prepared using surface-treated or untreated fibers and the raw materials shown in Table 1. The ratio shown in Table 2 indicates the mass% of each component with respect to the total amount of all the components contained in the film formed on the fiber surface.
評価
各実施例若しくは比較例の化粧料、又は各実施例で用いた繊維について、以下の方法で評価した。
Evaluation The cosmetics of each example or comparative example, or the fibers used in each example were evaluated by the following methods.
付着性
睫毛化粧料を使用し、５人のパネラーにより付着性（睫毛への繊維の付着のしやすさ）の官能評価を１（とても悪い）〜５（とても良い）で判定し、その平均値を以下の基準で評価した。その結果を表３に示す。
◎：４．０以上
○：３．０以上４．０未満
△：２．０以上３．０未満
×：２．０未満
Adhesive eyelash cosmetics are used, and the sensory evaluation of adhesiveness (easiness of fiber adhesion to eyelashes) is judged by 5 panelists from 1 (very bad) to 5 (very good), and the average value. Was evaluated according to the following criteria. The results are shown in Table 3.
⊚: 4.0 or more ○: 3.0 or more and less than 4.0 Δ: 2.0 or more and less than 3.0 ×: less than 2.0
表３から明らかなように、本発明のアイメイクアップ化粧料は、繊維の付着性において特に優れたものであることが実証された。 As is clear from Table 3, the eye makeup cosmetics of the present invention have been demonstrated to be particularly excellent in fiber adhesion.
付着均一性
睫毛化粧料を使用し、５人のパネラーにより付着均一性（毛の流れに沿って偏りなく付着しているか）の官能評価を１（とても悪い）〜５（とても良い）で判定し、その平均値を以下の基準で評価した。その結果を表４に示す。
○：３．５以上
△：２．０以上３．５未満
×：２．０未満
Adhesion uniformity Using eyelash cosmetics, the sensory evaluation of adhesion uniformity (whether it adheres evenly along the flow of hair) is judged by 5 panelists from 1 (very bad) to 5 (very good). , The average value was evaluated according to the following criteria. The results are shown in Table 4.
◯: 3.5 or more Δ: 2.0 or more and less than 3.5 ×: less than 2.0
繊維の分散性
水、イソドデカン２０ｍｌそれぞれに繊維０．１ｇを分散させ、５人のパネラーにより分散の度合いを１（とても悪い）〜５（とても良い）で判定し、その平均値を以下の基準で評価した。その結果を表４に示す。
◎：４．５以上
〇：３．０以上４．５未満
△：２．０以上３．０未満
×：２．０未満
Dispersion of fibers 0.1 g of fibers are dispersed in 20 ml of water and 20 ml of isododecane, and the degree of dispersion is judged by 5 panelists from 1 (very bad) to 5 (very good), and the average value is based on the following criteria. evaluated. The results are shown in Table 4.
⊚: 4.5 or more 〇: 3.0 or more and less than 4.5 Δ: 2.0 or more and less than 3.0 ×: less than 2.0
ロングラッシュ効果
つけ睫毛（ガールズシークレット０１、発売元（株）エリザベス）を用意し、デジタルマイクロスコープ（ＶＨＸ−７０００、（株）キーエンス）を用いて、つけ睫毛を撮影した。次に、つけ睫毛に実施例６の睫毛化粧料を３０回塗布した。５分乾燥ののち、再度３０回塗布し完全に乾燥させた。塗布前と同様に、塗布後のつけ睫毛を撮影した。つけ睫毛から無作為に６ヶ所を選び、デジタルマイクロスコープを用いて、塗布前及び塗布後の毛の長さを測定した。その後、睫毛化粧料を除去し、同様の測定を２回（計３回）行い、塗布前と塗布後の毛の長さの平均値を求め、伸長値を求めた。同様に、比較例１の睫毛化粧料についても塗布前と塗布後の毛の長さの差の平均値を求めた。測定結果を表５に示す。
Long rush effect We prepared eyelashes (Girls Secret 01, distributor Elizabeth Co., Ltd.) and photographed the eyelashes using a digital microscope (VHX-7000, Keyence Co., Ltd.). Next, the eyelash cosmetics of Example 6 were applied to the eyelashes 30 times. After drying for 5 minutes, it was applied again 30 times and completely dried. The eyelashes after application were photographed in the same manner as before application. Six locations were randomly selected from the lashes, and the length of the hair before and after application was measured using a digital microscope. After that, the eyelash cosmetics were removed, and the same measurement was performed twice (three times in total) to obtain the average value of the hair length before and after application, and the elongation value was determined. Similarly, for the eyelash cosmetics of Comparative Example 1, the average value of the difference in hair length before and after application was determined. The measurement results are shown in Table 5.
Claims (3)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2020121824A JP6832033B1 (en) | 2020-07-16 | 2020-07-16 | Eye makeup cosmetics |
| KR1020237001220A KR20230040985A (en) | 2020-07-16 | 2021-07-06 | eye makeup cosmetics |
| PCT/JP2021/025401 WO2022014399A1 (en) | 2020-07-16 | 2021-07-06 | Eye makeup cosmetic |
| CN202180045814.5A CN115734807A (en) | 2020-07-16 | 2021-07-06 | Cosmetic material for eye makeup |
| TW110125080A TW202216114A (en) | 2020-07-16 | 2021-07-08 | Eye-makeup cosmetic composition |
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|---|---|---|---|
| JP2020121824A JP6832033B1 (en) | 2020-07-16 | 2020-07-16 | Eye makeup cosmetics |
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| JP2022018606A JP2022018606A (en) | 2022-01-27 |
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| JP (1) | JP6832033B1 (en) |
| KR (1) | KR20230040985A (en) |
| CN (1) | CN115734807A (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3409192B2 (en) * | 1993-11-12 | 2003-05-26 | 株式会社コーセー | Eye makeup cosmetics for eyelashes or eyebrows |
| JP3403491B2 (en) * | 1994-04-15 | 2003-05-06 | 株式会社ノエビア | Temperature-sensitive powder and powder cosmetic containing the same |
| JPH11130632A (en) * | 1997-10-29 | 1999-05-18 | Kose Corp | Eye makeup cosmetic |
| JP4063440B2 (en) * | 1999-03-17 | 2008-03-19 | 株式会社コーセー | Eye makeup cosmetics |
| JP2002255745A (en) * | 2001-02-28 | 2002-09-11 | Noevir Co Ltd | Eye makeup cosmetic |
| KR20100040048A (en) * | 2008-10-09 | 2010-04-19 | (주)아모레퍼시픽 | Mascara composition |
| JP2016041673A (en) * | 2014-08-13 | 2016-03-31 | 大東化成工業株式会社 | Eyelash cosmetic |
| JP6871264B2 (en) * | 2015-11-17 | 2021-05-12 | イーエルシー マネージメント エルエルシー | Mascara composition and method |
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| WO2022014399A1 (en) | 2022-01-20 |
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