JP6783073B2 - A method for preventing a heating element for the human body and a heating composition solidified by the heat generation from giving a feeling of strangeness to the human body. - Google Patents

A method for preventing a heating element for the human body and a heating composition solidified by the heat generation from giving a feeling of strangeness to the human body. Download PDF

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JP6783073B2
JP6783073B2 JP2016107444A JP2016107444A JP6783073B2 JP 6783073 B2 JP6783073 B2 JP 6783073B2 JP 2016107444 A JP2016107444 A JP 2016107444A JP 2016107444 A JP2016107444 A JP 2016107444A JP 6783073 B2 JP6783073 B2 JP 6783073B2
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heating element
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均 臼井
均 臼井
坂本 光浩
光浩 坂本
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本発明は人体用発熱体に関し、特に、発熱によって固化した発熱組成物が人体に与える違和感を緩和させることができる人体用の発熱体に関する。 The present invention relates to a heating element for the human body, and more particularly to a heating element for the human body which can alleviate the discomfort given to the human body by the heat-generating composition solidified by the heat generation.

従来から、鉄粉等の金属粉を主成分とする発熱組成物と空気中の酸素とを反応させて得られる反応熱を利用した発熱体が知られており、かかる発熱体を人体と接触させて人体に熱を供給する方法が利用されている。 Conventionally, a heating element using the heat of reaction obtained by reacting an exothermic composition containing a metal powder such as iron powder as a main component with oxygen in the air has been known, and the heating element is brought into contact with the human body. A method of supplying heat to the human body is used.

例えば、足の甲に貼付するための使い捨てカイロが特許第4405437号公報に開示されているが、この使い捨てカイロは、通気性の扁平状袋に、鉄等の酸化性金属を主成分とする発熱組成物が封入されたものであり、この扁平状袋は、一方が通気性合成樹脂フィルムおよび/または不織布からなる通気層と、他方が合成樹脂積層フィルムとからなる袋である。 For example, a disposable body warmer for attaching to the instep is disclosed in Japanese Patent No. 4405437. This disposable body warmer is a breathable flat bag and generates heat containing an oxidizing metal such as iron as a main component. The composition is encapsulated, and the flat bag is a bag made of a breathable layer made of a breathable synthetic resin film and / or a non-woven fabric on one side and a synthetic resin laminated film on the other side.

また、足部の甲側と裏側に対向して配設される一対の扁平な温熱剤収容部を有する足用温熱体が特許第4628699号公報に開示されているが、温熱剤としては鉄粉等のような酸化反応により発熱する発熱剤が用いられ、収容部としては、一方の面が通気性シートであり、他方の面が最外層にナイロンを用い、その内側にポリエチレンフィルム等を積層したシートである袋が用いられ、他方の面の最外層に粘着部が設けられた足用温熱体が開示されている。 Further, a foot thermal body having a pair of flat thermal agent accommodating portions arranged to face the instep side and the back side of the foot is disclosed in Japanese Patent No. 4628699, but iron powder is used as the thermal agent. A heat-generating agent that generates heat due to an oxidation reaction such as, etc. is used, and as an accommodating portion, one surface is a breathable sheet, the other surface uses nylon as the outermost layer, and a polyethylene film or the like is laminated on the inside thereof. A foot warmer in which a bag, which is a sheet, is used and an adhesive portion is provided on the outermost layer of the other surface is disclosed.

特許第4405437号公報Japanese Patent No. 4405437 特許第4628699号公報Japanese Patent No. 4628669

このような金属粉と酸素との酸化反応を利用した発熱体は、酸化反応の進行に伴って金属粉が凝結して固化し、柔軟性が低下する。そのため、発熱後、長時間熱を供給し続けた発熱体は、発熱体と接触する人体表面にゴワゴワした感触を与えるという問題があり、上記使い捨てカイロや上記足用温熱体などはかかる問題を有するものであった。 In a heating element utilizing such an oxidation reaction between metal powder and oxygen, the metal powder condenses and solidifies as the oxidation reaction progresses, and the flexibility is reduced. Therefore, a heating element that continues to supply heat for a long time after heat generation has a problem of giving a rugged feel to the surface of the human body in contact with the heating element, and the disposable body warmer and the heating element for feet have such a problem. It was a thing.

例えば発熱体を足の甲部に使用する場合には、上記問題は特に顕著に表われた。すなわち、特に足の甲部には骨が表面に出ていて複雑な凹凸が存在するので、酸化反応の進行により金属粉が凝結し固化した発熱体が接触すると、体表面の凹凸になじみ難く追従し難くなって、ゴワゴワ感が更に過敏に感じられるようになり、痛さすら感じる場合もある。 For example, when a heating element is used on the instep, the above problem is particularly remarkable. That is, since bones are exposed on the surface of the instep and complicated irregularities exist, when a heating element in which metal powder is condensed and solidified due to the progress of the oxidation reaction comes into contact with the heating element, it does not easily adapt to the irregularities on the body surface and follows. It becomes more difficult to do, and the feeling of stiffness becomes more sensitive, and it may even be painful.

本発明は上記問題点を解決するためになされたものであり、本発明は人体に熱を供給しつつ、発熱反応によって固化した発熱組成物のゴワゴワ感を緩和する方法、および、この方法に好適な人体用発熱体を提供することを目的とする。 The present invention has been made to solve the above problems, and the present invention is suitable for a method for alleviating the stiff feeling of an exothermic composition solidified by an exothermic reaction while supplying heat to the human body, and for this method. The purpose is to provide a heating element for the human body.

本発明の人体用発熱体は、人体に熱を供給するための発熱体であって、
該発熱体が、
少なくとも一部が通気性の積層体からなる扁平状袋体と、
該扁平状袋体の内部に封入された、空気の存在によって発熱する発熱組成物と、
該扁平状袋体外面の少なくとも一部に積層された粘着層とからなり、
人体に当てられる面と上記発熱組成物との間に弾性層を有することを特徴とする。
The heating element for the human body of the present invention is a heating element for supplying heat to the human body.
The heating element
A flat bag made of at least a part of a breathable laminate,
A heat-generating composition that generates heat due to the presence of air, which is enclosed inside the flat bag body,
It is composed of an adhesive layer laminated on at least a part of the outer surface of the flat bag body.
It is characterized by having an elastic layer between the surface to be applied to the human body and the heat generating composition.

本発明の人体用発熱体は、人体に熱を供給するための発熱体であって、
該発熱体が、通気性の積層体および非通気性の積層体で構成された扁平状袋体と、
該扁平状袋体の内部に封入された、空気の存在によって発熱する発熱組成物と、
該扁平状袋体の該通気性の積層体側外面の少なくとも一部に積層された粘着層とからなり、
上記通気性の積層体が、通気性部および弾性層を有することが好ましい。
The heating element for the human body of the present invention is a heating element for supplying heat to the human body.
The heating element is a flat bag body composed of a breathable laminated body and a non-breathable laminated body.
A heat-generating composition that generates heat due to the presence of air, which is enclosed inside the flat bag body,
It is composed of an adhesive layer laminated on at least a part of the outer surface of the flat bag body on the side of the breathable laminate.
It is preferable that the breathable laminate has a breathable portion and an elastic layer.

本発明においては、上記弾性層が、発泡ポリウレタンからなることが好ましい。 In the present invention, the elastic layer is preferably made of foamed polyurethane.

また、本発明の人体用発熱体は、さらに不織布を有することが好ましく、通気性フィルム、弾性層および不織布をこの順に有する通気性の積層体、または、通気性フィルム、不織布および弾性層をこの順に有する通気性の積層体を備えることができる。 Further, the heating element for the human body of the present invention preferably further has a non-woven fabric, and is a breathable laminate having a breathable film, an elastic layer and a non-woven fabric in this order, or a breathable film, a non-woven fabric and an elastic layer in this order. It can be provided with a breathable laminate having.

また、上記弾性層は、発熱後に固化する発熱組成物のゴワゴワ感を緩和し、ソフト感を持続させるものであることが好ましい。 Further, it is preferable that the elastic layer is one that alleviates the stiff feeling of the heat-generating composition that solidifies after heat generation and maintains the soft feeling.

また、上記人体用発熱体は、該粘着層が足部の甲側に貼付されることが好ましい。 Further, in the above heating element for human body, it is preferable that the adhesive layer is attached to the instep side of the foot.

また、本発明の人体用発熱体は、上記人体用発熱体を人体に適用した際に、発熱組成物が有する温度の影響を緩和させることができる弾性層を有することが好ましい。 Further, the heating element for a human body of the present invention preferably has an elastic layer capable of alleviating the influence of the temperature of the heating composition when the heating element for a human body is applied to the human body.

本発明の方法は、少なくとも一部が通気性の積層体からなる扁平状袋体と、該扁平状袋体の内部に封入された、空気の存在によって発熱する発熱組成物とからなる人体用発熱体を人体に適用する際に、
人体に当てる面と、上記発熱組成物との間に弾性層を設けておき、発熱によって固化した発熱組成物が人体に違和感を与えることを防止する方法である。
The method of the present invention generates heat for the human body, which comprises a flat bag body made of at least a part of a breathable laminated body and a heat generating composition which is enclosed inside the flat bag body and generates heat due to the presence of air. When applying the body to the human body
This is a method in which an elastic layer is provided between the surface to be exposed to the human body and the heat-generating composition to prevent the heat-generating composition solidified by heat generation from giving a sense of discomfort to the human body.

また、本発明の方法は、通気性の積層体および非通気性の積層体で構成された扁平状袋体と、該扁平状袋体の内部に封入された、空気の存在によって発熱する発熱組成物とからなる人体用発熱体を人体に適用する際に、
上記通気性の積層体に、通気性部および弾性層を設けておき、人体用発熱体の該通気性の積層体側を人体表面に直接接触または間接接触させて人体に熱を供給しつつ、発熱によって固化した発熱組成物が人体に違和感を与えることを防止する方法であることが好ましい。
Further, the method of the present invention has a flat bag body composed of a breathable laminated body and a non-breathable laminated body, and a heat generating composition enclosed in the flat bag body and generating heat due to the presence of air. When applying a heating element for the human body consisting of objects to the human body
A breathable portion and an elastic layer are provided in the breathable laminate, and the breathable laminate side of the heat generating body for the human body is brought into direct or indirect contact with the surface of the human body to supply heat to the human body while generating heat. It is preferable that the method is a method for preventing the exothermic composition solidified by the above from giving a feeling of strangeness to the human body.

ここで、上記人体用発熱体が適用される人体は、足甲部であることが好ましい。 Here, the human body to which the above-mentioned heat generating body for the human body is applied is preferably the instep.

本発明の方法は、上記人体用発熱体が、上記通気性の積層体の表面の少なくとも一部に粘着層を有することが好ましい。 In the method of the present invention, it is preferable that the heating element for a human body has an adhesive layer on at least a part of the surface of the breathable laminate.

また、本発明の人体用発熱体は、人体に熱を供給するための発熱体であって、該発熱体が、少なくとも一部が通気性の積層体で構成された扁平状袋体と、
該扁平状袋体の内部に封入された、空気の存在によって発熱する発熱組成物とからなり、
人体に当てる面と上記発熱組成物との間に弾性層を有することを特徴とする。
Further, the heating element for the human body of the present invention is a heating element for supplying heat to the human body, and the heating element is a flat bag body formed of at least a part of a breathable laminated body.
It is composed of a heat-generating composition that generates heat due to the presence of air, which is enclosed inside the flat bag body.
It is characterized by having an elastic layer between the surface to be exposed to the human body and the heat generating composition.

本発明によれば、人体に熱を供給しつつ、発熱反応によって固化した発熱組成物のゴワゴワ感を緩和する方法を実現することができた。また、発熱により固化した発熱組成物を有する発熱体が人体に与えるゴワゴワ感を緩和することができる人体用発熱体を実現することができた。特に、本発明によれば、足甲部に熱を供給するための発熱体として好適な人体用発熱体を実現することができた。また、換言すれば、本発明の人体用発熱体を用いれば、長時間、人体、特に足甲部に、ゴワゴワ感を与えることなく、人体に熱を与え続けることができた。 According to the present invention, it has been possible to realize a method of alleviating the stiff feeling of the exothermic composition solidified by the exothermic reaction while supplying heat to the human body. In addition, it was possible to realize a heating element for the human body that can alleviate the stiff feeling given to the human body by the heating element having the heat generating composition solidified by heat generation. In particular, according to the present invention, it was possible to realize a heating element for the human body suitable as a heating element for supplying heat to the instep. In other words, by using the heating element for the human body of the present invention, it was possible to continue to apply heat to the human body for a long time without giving a feeling of stiffness to the human body, particularly the instep.

本発明の人体用発熱体の一実施形態の構造を示す模式図であり、(a)はその平面図であり、(b)は断面図である。It is a schematic diagram which shows the structure of one Embodiment of the heating element for a human body of this invention, (a) is a plan view, (b) is a sectional view. 従来の発熱体の構造を示す模式図であり、(a)はその平面図であり、(b)は断面図である。It is a schematic view which shows the structure of the conventional heating element, (a) is a plan view, and (b) is a sectional view.

以下、本発明について詳細に説明する。
本発明は、発熱体を人体に適用する際に、人体に熱を供給しつつ、発熱によって固化した発熱組成物が人体に違和感を与えることを防止する方法である。本発明に用いられる人体用発熱体は、扁平状袋体と、この扁平状袋体の内部に封入された発熱組成物と、粘着層とから構成されており、この扁平状袋体は、少なくとも一部が通気性の積層体(以下「通気性積層体」と称すこともある)からなり、該通気性の積層体は人体側に配置される。本発明においては、扁平状袋体は 通気性の積層体(人体側積層体)および非通気性の積層体(以下「非通気性積層体」と称すこともある)で構成され、粘着層は、上記通気性の積層体の外面の少なくとも一部に積層されることが好ましい。
Hereinafter, the present invention will be described in detail.
The present invention is a method for preventing a heat-generating composition solidified by heat generation from giving a sense of discomfort to the human body while supplying heat to the human body when the heating element is applied to the human body. The heat-generating body for the human body used in the present invention is composed of a flat bag body, a heat-generating composition sealed inside the flat bag body, and an adhesive layer, and the flat bag body is at least A part is composed of a breathable laminate (hereinafter, also referred to as a "breathable laminate"), and the breathable laminate is arranged on the human body side. In the present invention, the flat bag body is composed of a breathable laminate (human body side laminate) and a non-breathable laminate (hereinafter sometimes referred to as "non-breathable laminate"), and the adhesive layer is , It is preferable to be laminated on at least a part of the outer surface of the breathable laminate.

本発明における扁平状袋体の通気性積層体は、人体と接触(直接または間接)する側の積層体であり、通気性部および弾性層からなる。通気性部は、少なくとも1層以上の通気性を有する層からなり、通気性を有する層としては、通気性フィルムや、その通気性フィルムに不織布、織布、紙等を積層したものなどが挙げられるが、これらに限定されるものではない。 The breathable laminate of the flat bag body in the present invention is a laminate on the side that comes into contact (directly or indirectly) with the human body, and is composed of a breathable portion and an elastic layer. The breathable portion is composed of at least one or more breathable layers, and examples of the breathable layer include a breathable film and a laminated non-woven fabric, woven cloth, paper, etc. on the breathable film. However, it is not limited to these.

本発明に好ましく用いられる通気性フィルムとしては、不織布、一軸または二軸延伸された多孔質フィルム、無孔フィルムに貫通孔をもうけたものなどが挙げられる。その多孔質フィルムは、その平均孔径が0.5〜1000μmの貫通孔を有することが好ましい。 Breathable films preferably used in the present invention include non-woven fabrics, uniaxially or biaxially stretched porous films, non-porous films with through holes, and the like. The porous film preferably has through holes having an average pore diameter of 0.5 to 1000 μm.

多孔質フィルムとしては、フィルムを一軸または二軸延伸することによって得られたものなどが好ましく使用される。そのフィルムの材料としては、合成樹脂等が用いられ、例えば、ポリエチレン、ポリプロピレン、ポリアミド、ポリエステル、ポリ塩化ビニル、ポリ塩化ビニリデン、ポリウレタン、ポリスチレン、エチレン−酢酸ビニル共重合ケン化物、エチレン−酢酸ビニル共重合体、ポリエチレンテレフタレートなどが挙げられ、これらの1種または2種以上混合した樹脂でもよい。 As the porous film, those obtained by stretching the film uniaxially or biaxially are preferably used. As the material of the film, synthetic resin or the like is used, for example, polyethylene, polypropylene, polyamide, polyester, polyvinyl chloride, polyvinylidene chloride, polyurethane, polystyrene, ethylene-vinyl acetate copolymer saponified product, ethylene-vinyl acetate. Examples thereof include a copolymer and polyethylene terephthalate, and one or a mixture of two or more of these may be used.

貫通孔の形成方法としては特に限定されるものではないが、例えば、フィルムに極細針(熱針を含む。)を貫通させて形成してもよく、あるいは、ダイヤモンド(人工のものを含む)や金属粉等を固着したドラムをフィルムに押圧して貫通孔を形成したもの、更にはレーザーによって貫通孔を形成したもの等が挙げられる。 The method for forming the through hole is not particularly limited, but for example, the film may be formed by penetrating an ultrafine needle (including a hot needle), or a diamond (including an artificial one) or the like. Examples thereof include a drum having a metal powder and the like fixed pressed against a film to form a through hole, and a drum having a through hole formed by a laser.

多孔質フィルムや、貫通孔を設けたフィルムの厚さは、特に限定されるものではないが、強度、貫通孔を形成する際の容易性、取扱性および経済性等の観点から、10〜500μmであることが好ましく、更に好ましくは15〜200μmである。 The thickness of the porous film or the film provided with the through holes is not particularly limited, but is 10 to 500 μm from the viewpoint of strength, ease of forming through holes, handleability, economy, and the like. It is preferably, more preferably 15 to 200 μm.

通気性積層体を構成する弾性層としては、発泡ポリウレタンなどが好ましく用いられる。弾性層は、単層でも複数層でもよい。 As the elastic layer constituting the breathable laminate, polyurethane foam or the like is preferably used. The elastic layer may be a single layer or a plurality of layers.

弾性層の厚みは特に限定されるものではないが、発熱によって固化した発熱組成物の違和感を緩和する観点から、500〜2000μmであることが好ましい。また、かかる厚み範囲の弾性層が人体と接触する側に配置されていれば、発熱体の発する熱をマイルドに伝達することができる。 The thickness of the elastic layer is not particularly limited, but is preferably 500 to 2000 μm from the viewpoint of alleviating the discomfort of the heat-generating composition solidified by heat generation. Further, if the elastic layer in such a thickness range is arranged on the side in contact with the human body, the heat generated by the heating element can be mildly transferred.

弾性層には、他の層が積層されていてもよく、例えば、不織布、織布(不織布、織布とも、メッシュ状のものを含む。)、ポリエチレン、ポリプロピレン、エチレン酢酸ビニル(EVA)等の熱可塑性樹脂フィルムなどが積層されていてもよい。不織布を積層すると、風合い、質感等を改良することができる。 Other layers may be laminated on the elastic layer, for example, non-woven fabric, woven fabric (both non-woven fabric and woven fabric include mesh-like ones), polyethylene, polypropylene, ethylene vinyl acetate (EVA) and the like. A thermoplastic resin film or the like may be laminated. By laminating the non-woven fabric, the texture, texture and the like can be improved.

本発明に用いられる不織布(又は織布)としては、例えば、天然繊維または人造繊維で形成されたものなどが挙げられる。 Examples of the non-woven fabric (or woven fabric) used in the present invention include those formed of natural fibers or artificial fibers.

天然繊維としては、特に限定されるものではないが、具体的には、例えば木綿、カポック、マニラ麻、サイザル麻、絹、羊毛、モヘア、カシミヤ、ラクダ、アルパカなどが挙げられる。 The natural fiber is not particularly limited, and specific examples thereof include cotton, kapok, Manila hemp, sisal hemp, silk, wool, mohair, cashmere, camel, and alpaca.

また、人造繊維としては再生繊維、半合成繊維、合成繊維などが挙げられる。再生繊維としては、例えばビスコースレーヨンまたは銅アンモニアレーヨンなどが挙げられ、半合成繊維としては、例えばアセテートなどが挙げられ、合成繊維としては、例えばポリアミド系合成繊維、ポリエステル系合成繊維、ポリビニルアルコール系合成繊維、ポリ塩化ビニル系合成繊維、ポリ塩化ビニリデン系合成繊維、アクリル系合成繊維、モダクリル系合成繊維、ポリオレフィン系合成繊維、フルオロカーボン系合成繊維又はポリウレタン系合成繊維等が挙げられる。 In addition, examples of artificial fibers include regenerated fibers, semi-synthetic fibers, and synthetic fibers. Examples of the regenerated fiber include viscose rayon and copper ammonia rayon, examples of the semi-synthetic fiber include acetate and the like, and examples of the synthetic fiber include polyamide-based synthetic fiber, polyester-based synthetic fiber, and polyvinyl alcohol-based fiber. Examples thereof include synthetic fibers, polyvinyl chloride-based synthetic fibers, polyvinylidene chloride-based synthetic fibers, acrylic-based synthetic fibers, modacryl-based synthetic fibers, polyolefin-based synthetic fibers, fluorocarbon-based synthetic fibers, and polyurethane-based synthetic fibers.

不織布の目付は特に限定されるものではないが、例えば、20〜70g/mであることが好ましく、20〜50g/mであることが更に好ましい。 Although the basis weight is not particularly limited nonwoven, for example, it is preferably from 20 to 70 g / m 2, and still more preferably from 20 to 50 g / m 2.

本発明において、通気性積層体は、発熱組成物に近い方から、通気性フィルム、弾性層および不織布をこの順に有するか、あるいは、通気性フィルム、不織布、弾性層をこの順に有することが好ましい。 In the present invention, the breathable laminate preferably has a breathable film, an elastic layer and a non-woven fabric in this order, or has a breathable film, a non-woven fabric and an elastic layer in this order, from the side closest to the heat generating composition.

本発明における扁平状袋体の他方側を構成する非通気性積層体は、例えば、ポリエチレン、ポリプロピレン、ポリアミド、ポリエステル、ポリ塩化ビニル、ポリ塩化ビニリデン、ポリウレタン、ポリスチレン、エチレン−酢酸ビニル共重合ケン化物、エチレン−酢酸ビニル共重合体、ポリエチレンテレフタレートなどからなる非通気性のフィルムやシートが挙げられ、これらのフィルム等の単層または2以上積層した積層体でもよい。また、非通気性積層体には、不織布が積層されていてもよく、この場合には、最外層として積層されることが好ましい。 The non-breathable laminate constituting the other side of the flat bag body in the present invention is, for example, polyethylene, polypropylene, polyamide, polyester, polyvinyl chloride, polyvinylidene chloride, polyurethane, polystyrene, ethylene-vinyl acetate copolymer saponified product. , Non-breathable films and sheets made of ethylene-vinyl acetate copolymer, polyethylene terephthalate and the like, and may be a single layer such as these films or a laminated body in which two or more are laminated. Further, the non-woven fabric may be laminated on the non-breathable laminate, and in this case, it is preferably laminated as the outermost layer.

通気性積層体を構成する各層および非通気性積層体の各層は、接着剤等の方法によって積層されていてもよいし、他の方法によって積層されていてもよい。また、通気性積層体および非通気性積層体の端部を接合して袋体を形成する方法としては、熱融着、接着剤等による方法や、一般的な方法が使用される。 Each layer constituting the breathable laminate and each layer of the non-breathable laminate may be laminated by a method such as an adhesive, or may be laminated by another method. Further, as a method of joining the ends of the breathable laminate and the non-breathable laminate to form a bag body, a method using heat fusion, an adhesive or the like, or a general method is used.

本発明においては、開放部のない扁平状袋体の内部に発熱組成物が封入されている。本発明に用いられる発熱組成物は、空気の存在下で発熱反応を起こすものであれば特に限定されるものではないが、具体的には、鉄粉等の金属粉と、この金属粉に酸化反応を起こさせたり、pHの調整及び触媒作用を有する活性炭、金属粉表面の酸化被膜を破壊し、金属粉の酸化反応を円滑に進行させるための塩化物、更に水、および該水によるベトツキをなくするために用いられる保水剤からなるものが好ましい。 In the present invention, the heat generating composition is enclosed inside a flat bag body having no open portion. The exothermic composition used in the present invention is not particularly limited as long as it causes an exothermic reaction in the presence of air, but specifically, it is oxidized to a metal powder such as iron powder and this metal powder. Activated carbon that causes a reaction, adjusts the pH and acts as a catalyst, chloride that destroys the oxide film on the surface of the metal powder and facilitates the oxidation reaction of the metal powder, water, and stickiness due to the water. Those consisting of a water-retaining agent used to eliminate it are preferable.

発熱組成物としては、安全性、経済性、長時間にわたる温熱効果および保存性等の観点から、金属粉として鉄粉を用い、成分比率が鉄40〜75重量%、活性炭1〜10重量%、塩化物1〜10重量%、水10〜40重量%、保水剤1〜40重量%からなるものが好ましい。 As the heat-generating composition, iron powder is used as the metal powder from the viewpoints of safety, economy, long-term thermal effect, storage stability, etc., and the component ratio is iron 40 to 75% by weight, activated charcoal 1 to 10% by weight, It is preferably composed of 1 to 10% by weight of chloride, 10 to 40% by weight of water, and 1 to 40% by weight of a water retention agent.

塩化物としては、塩化ナトリウム、塩化カリウム等のアルカリ金属の塩化物、塩化カルシウム、塩化マグネシウム等のアルカリ土類金属の塩化物等の金属塩化物が挙げられる。 Examples of the chloride include chlorides of alkali metals such as sodium chloride and potassium chloride, and metal chlorides such as chlorides of alkaline earth metals such as calcium chloride and magnesium chloride.

保水剤としては、保水性が高く、発熱組成物においてそのベトツキを無くするものであれば特に限定されるものではないが、例えば、バーミュライト、シリカ粉、木粉、吸水性ポリマーなどが挙げられる。 The water-retaining agent is not particularly limited as long as it has high water-retaining property and eliminates stickiness in the heat-generating composition, and examples thereof include vermulite, silica powder, wood powder, and water-absorbing polymer. Be done.

本発明の人体用発熱体は、扁平状袋体の通気性積層体に粘着層を有する。この粘着層に用いられる粘着層としては、特に限定されるものではないが、例えば、酢酸ビニル系粘着剤、ポリビニルアセタール系粘着剤、塩化ビニル系粘着剤、アクリル系粘着剤、ポリアミド系粘着剤、ポリエチレン系粘着剤、セルロース系粘着剤、クロロプレン(ネオプレン)系粘着剤、ニトリルゴム系粘着剤、ブチルゴム系粘着剤、シリコーンゴム系粘着剤などが挙げられる。 The heating element for human body of the present invention has an adhesive layer on a breathable laminated body of a flat bag body. The pressure-sensitive adhesive layer used for this pressure-sensitive adhesive layer is not particularly limited, and for example, vinyl acetate-based pressure-sensitive adhesive, polyvinyl acetal-based pressure-sensitive adhesive, vinyl chloride-based pressure-sensitive adhesive, acrylic-based pressure-sensitive adhesive, polyamide-based pressure-sensitive adhesive, and the like. Examples thereof include polyethylene-based adhesives, cellulose-based adhesives, chloroprene (neoprene) -based adhesives, nitrile rubber-based adhesives, butyl rubber-based adhesives, and silicone rubber-based adhesives.

なお、本発明においては、扁平状袋体を構成する通気性積層体側を、人体表面側に配置して使用するならば、粘着層はなくてもよい。 In the present invention, if the breathable laminated body side constituting the flat bag body is arranged on the human body surface side for use, the adhesive layer may not be provided.

本発明の人体用発熱体は、人体と接触する側に弾性部を有するので、発熱反応の進行に伴い発熱組成物が固化しても、これによるゴワゴワ感を緩和することができ、発熱反応開始時のソフト感を持続することができる。また、柔軟性の低下を防ぐことができるので、発熱体で発生した熱を効率よく人体に伝達することができる。さらにまた、人体と接触する側に弾性部を有するので、人体用発熱体が外気の冷気等により影響を受けた冷たい感覚や、発熱組成物の発熱反応により影響を受ける熱い感覚を緩和することができるので、人体の肌に対して優しく、使い心地の良い発熱体である。特に、本発明の人体用発熱体は、複雑な凹凸を有する足の甲部に対しても好ましく適用することができる。 Since the heating element for the human body of the present invention has an elastic portion on the side in contact with the human body, even if the exothermic composition solidifies as the exothermic reaction progresses, the stiff feeling due to this can be alleviated and the exothermic reaction starts. The soft feeling of time can be maintained. Further, since the decrease in flexibility can be prevented, the heat generated by the heating element can be efficiently transferred to the human body. Furthermore, since it has an elastic part on the side that comes into contact with the human body, it is possible to alleviate the cold sensation that the heat generating body for the human body is affected by the cold air of the outside air and the hot sensation that is affected by the exothermic reaction of the exothermic composition. Because it can be made, it is a heating element that is gentle on the human skin and is comfortable to use. In particular, the heating element for the human body of the present invention can be preferably applied to the instep portion having complicated irregularities.

以下に、本発明の実施形態の1つである足甲部に使用する実施例を用いて、本発明を詳細に説明するが、本発明はこれに限定されるものではない。 Hereinafter, the present invention will be described in detail with reference to an example used for the instep portion, which is one of the embodiments of the present invention, but the present invention is not limited thereto.

本発明の人体用発熱体の構造の一実施形態を、図1を用いて説明する。図1の(a)はその模式的平面図であり、(b)は模式的断面図である。図1の(a)および(b)において、1は本発明の人体用発熱体であり、この人体用発熱体1は、扁平状袋体2と、この扁平状袋体2の内部に封入された、発熱組成物3と、粘着層4とからなる。また、この扁平状袋体2は、一方の面が非通気性積層体5、他方の面が通気性積層体6で構成されていて、開放部のない扁平袋状に形成されている。粘着層4は通気性積層体6の外面に設けられている。 An embodiment of the structure of the heating element for the human body of the present invention will be described with reference to FIG. FIG. 1A is a schematic plan view thereof, and FIG. 1B is a schematic cross-sectional view thereof. In FIGS. 1A and 1B, 1 is a heating element for a human body of the present invention, and the heating element 1 for a human body is enclosed in a flat bag body 2 and the inside of the flat bag body 2. It is also composed of a heating composition 3 and an adhesive layer 4. Further, the flat bag body 2 is formed in a flat bag shape having no open portion, with one surface made of a non-breathable laminated body 5 and the other surface made of a breathable laminated body 6. The adhesive layer 4 is provided on the outer surface of the breathable laminate 6.

実施例で用いられる人体用発熱体1では、非通気性積層体5は、袋体の内側から、非通気性フィルム7としてポリエチレンフィルム(ジェイフィルム社製、厚み60μm)、および、不織布8としてポリエチレンテレフタレート不織布(東洋紡社製、厚み約0.2mm)が積層されている。 In the human body heating element 1 used in the examples, the non-breathable laminate 5 is a polyethylene film (manufactured by J-Film Co., Ltd., thickness 60 μm) as the non-breathable film 7 and polyethylene as the non-woven fabric 8 from the inside of the bag body. A terephthalate non-woven fabric (manufactured by Toyobo Co., Ltd., thickness about 0.2 mm) is laminated.

また、実施例で用いられる人体用発熱体1では、通気性積層体6は、袋の内側から、通気性フィルム9として、多孔質フィルム(興人フィルム&ケミカルズ社製、厚み約70μm)、弾性層10として、発泡ポリウレタン(クラボウ社製、厚み1.8mm)、および、不織布11として、ポリエチレンテレフタレート不織布(東洋紡社製、厚み約0.15mm)であり、多孔質フィルム、発泡ポリウレタンおよびポリエチレンテレフタレート不織布はホットメルトスプレーラミされている。 Further, in the heat generating body 1 for human body used in the examples, the breathable laminate 6 is a porous film (manufactured by Kojin Film & Chemicals Co., Ltd., thickness about 70 μm) and elastic as a breathable film 9 from the inside of the bag. The layer 10 is a foamed polyurethane (manufactured by Kurabou Co., Ltd., thickness 1.8 mm), and the non-woven fabric 11 is a polyethylene terephthalate non-woven fabric (manufactured by Toyo Spinning Co., Ltd., thickness about 0.15 mm). Has been hot melt sprayed.

また、発熱組成物は、金属粉として鉄粉を用い、成分比率が鉄40〜75重量%、活性炭1〜10重量%、塩化物1〜10重量%、水10〜40重量%、保水剤1〜40重量%からなるものが用いられており、実施例で用いられる人体用発熱体1では、発熱組成物3として、成分比率が鉄60重量%、活性炭3重量%、塩化ナトリウム3重量%、水31重量%、保水剤3重量%からなるものが用いられた。さらにまた、発熱組成物3の充てん量が500〜7000g/mの範囲に調整された。 Further, the heat generating composition uses iron powder as the metal powder, and the component ratio is iron 40 to 75% by weight, activated charcoal 1 to 10% by weight, chloride 1 to 10% by weight, water 10 to 40% by weight, water retention agent 1. In the human body heating element 1 used in the examples, the exothermic composition 3 has a component ratio of 60% by weight of iron, 3% by weight of activated charcoal, 3% by weight of sodium chloride, and the like. A material consisting of 31% by weight of water and 3% by weight of a water retention agent was used. Furthermore, the filling amount of the exothermic composition 3 was adjusted to the range of 500 to 7000 g / m 2 .

扁平状袋体2は、非通気性積層体5と通気性積層体6の周縁部12がヒートシールによって熱融着されている。 In the flat bag body 2, the non-breathable laminated body 5 and the peripheral edge portion 12 of the breathable laminated body 6 are heat-sealed by heat sealing.

通気性積層体6の外側に粘着層4が設けられている。実施例では、粘着剤としてアクリル系粘着剤が使用され、縞模様の形状の粘着剤層(厚み19μm)が形成され、粘着層4の外側には、剥離紙13として、サンエー化研社製、厚み約40〜50μm)が積層された。 An adhesive layer 4 is provided on the outside of the breathable laminate 6. In the examples, an acrylic pressure-sensitive adhesive is used as the pressure-sensitive adhesive, a striped-shaped pressure-sensitive adhesive layer (thickness 19 μm) is formed, and on the outside of the pressure-sensitive adhesive layer 4, as a release paper 13, manufactured by Sun A. Kaken Co., Ltd. A thickness of about 40 to 50 μm) was laminated.

得られた人体用発熱体1は、気密性のある2軸延伸ポリプロピレン(OPP)フィルムにポリ塩化ビニリデン(PVDC)をコートした外袋に収納した。 The obtained heating element 1 for a human body was housed in an outer bag coated with polyvinylidene chloride (PVDC) on an airtight biaxially stretched polypropylene (OPP) film.

次に、比較例の足用発熱体を作製した。比較例の足用発熱体21の構造を図2に示すが、図2の(a)はその模式的平面図であり、(b)は模式的断面図である。すなわち、比較例の足用発熱体21は、扁平状袋体22と、この扁平状袋体22の内部に封入された、発熱組成物23と、粘着層24とからなる。また、この扁平状袋体22は、一方の面が非通気性積層体25、他方の面が通気性積層体26で構成されていて、開放部のない扁平状に形成されている。粘着層24は非通気性積層体25の外面に設けられている。 Next, a foot heating element of a comparative example was prepared. The structure of the foot heating element 21 of the comparative example is shown in FIG. 2, where FIG. 2A is a schematic plan view and FIG. 2B is a schematic cross-sectional view. That is, the foot heating element 21 of the comparative example is composed of a flat bag body 22, a heat generating composition 23 sealed inside the flat bag body 22, and an adhesive layer 24. Further, the flat bag body 22 is formed of a non-breathable laminated body 25 on one surface and a breathable laminated body 26 on the other surface, and is formed in a flat shape without an open portion. The adhesive layer 24 is provided on the outer surface of the non-breathable laminate 25.

通気性積層体26は、通気性フィルム27として、多孔質フィルム(興人フィルム&ケミカルズ社製、厚み約70μm)、および、不織布28を積層した。また、非通気性積層体25は、非通気性フィルムとしてポリエチレンフィルム(ジェイフィルム社製、厚み60μm)が用いられた。 In the breathable laminate 26, a porous film (manufactured by Kohjin Film & Chemicals Co., Ltd., thickness of about 70 μm) and a non-woven fabric 28 were laminated as the breathable film 27. Further, as the non-breathable laminate 25, a polyethylene film (manufactured by J-Film Co., Ltd., thickness 60 μm) was used as the non-breathable film.

また、発熱組成物23は、実施例で使用した発熱組成物3と同様のものを使用した。 Further, as the heat-generating composition 23, the same heat-generating composition 3 used in the examples was used.

扁平状袋体22は、通気性積層体26と非通気性積層体25の周縁部30がヒートシールによって熱融着されている。 In the flat bag body 22, the peripheral portion 30 of the breathable laminated body 26 and the non-breathable laminated body 25 is heat-sealed by heat sealing.

非通気性積層体25の外側に、実施例と同様にして粘着層24が設けられているが、粘着剤の種類、形状、粘着層の厚み等は実施例と同様にした。また、粘着層24の外側には、剥離紙29として実施例と同様のものが積層された。 The adhesive layer 24 is provided on the outside of the non-breathable laminate 25 in the same manner as in the examples, but the type and shape of the adhesive, the thickness of the adhesive layer, and the like are the same as in the examples. Further, on the outside of the adhesive layer 24, the same release paper 29 as in the examples was laminated.

得られた比較例の人体用発熱体21は、気密性のある2軸延伸ポリプロピレン(OPP)フィルムにポリ塩化ビニリデン(PVDC)をコートした外袋に収納した。 The obtained heating element 21 for the human body of the comparative example was housed in an outer bag coated with polyvinylidene chloride (PVDC) on an airtight biaxially stretched polypropylene (OPP) film.

次に、以下のようにして官能試験を行った。
すなわち、外袋に収納した実施例の人体用発熱体1および比較例の人体用発熱体21を、温度4℃±2℃の環境下に2時間放置した。その後、温度20℃±3℃の環境下にて、外袋から人体用発熱体1を取り出し、すばやく剥離紙13をはがして粘着層4を被験者の左足の甲部に貼付し、ほぼ同時に比較例の人体用発熱体21を外袋から取り出し、剥離紙29をはがして粘着層24を該被験者の右足の甲部に貼付し、すぐに靴を履いた。人体用発熱体1,21を貼付した直後から1分までの間の温冷感について、官能評価を行った。
Next, a sensory test was performed as follows.
That is, the heating element 1 for the human body of the example and the heating element 21 for the human body of the comparative example stored in the outer bag were left for 2 hours in an environment of a temperature of 4 ° C. ± 2 ° C. Then, in an environment of a temperature of 20 ° C. ± 3 ° C., the heating element 1 for the human body was taken out from the outer bag, the release paper 13 was quickly peeled off, and the adhesive layer 4 was attached to the instep of the subject's left foot. The heating element 21 for the human body was taken out from the outer bag, the release paper 29 was peeled off, the adhesive layer 24 was attached to the instep of the right foot of the subject, and the shoes were immediately put on. A sensory evaluation was performed on the feeling of warmth and coldness from immediately after the attachment of the heating elements 1 and 21 for the human body to 1 minute.

温冷感の官能評価の評価基準は以下のとおりである。すなわち、実施例の発熱体1の方が比較例の発熱体21よりも温かく感じるか、もしくは比較例の発熱体21の方が実施例の発熱体1よりも冷たく感じた場合には記号「A」、実施例の発熱体1と比較例の発熱体21のどちらが温かいとも冷たいとも言えない場合には記号「B」、比較例の発熱体21の方が実施例の発熱体1よりも温かく感じた場合、もしくは実施例の発熱体1の方が比較例の発熱体21よりも冷たく感じた場合には記号「C」で示す。 The evaluation criteria for the sensory evaluation of the feeling of warmth and coldness are as follows. That is, when the heating element 1 of the example feels warmer than the heating element 21 of the comparative example, or the heating element 21 of the comparative example feels colder than the heating element 1 of the example, the symbol "A" is used. If neither the heating element 1 of the example nor the heating element 21 of the comparative example can be said to be warm or cold, the symbol "B" is used, and the heating element 21 of the comparative example feels warmer than the heating element 1 of the example. In this case, or when the heating element 1 of the example feels colder than the heating element 21 of the comparative example, it is indicated by the symbol “C”.

ただし、被験者は女性10人であり、各人、左足甲部と右足甲部とで、それぞれ2回ずつ官能試験を行った。その結果を表1に示す。 However, the subjects were 10 women, and each of them conducted a sensory test twice on each of the left instep and the right instep. The results are shown in Table 1.

また、使用終了時のソフト感についても以下に示す官能試験を行った。すなわち、上記温冷感の官能試験で官能評価を行った後、実施例の発熱体1および比較例の発熱体21を被験者の足甲部にセットしたまま、温度15℃±5℃の環境下にて、8時間使用した時点で、足甲部に感じるソフト感につき官能評価を行った。その結果を表1に併せて示す。 In addition, the following sensory test was conducted for the soft feeling at the end of use. That is, after performing a sensory evaluation in the above-mentioned sensory test of the feeling of warmth and coldness, the heating element 1 of the example and the heating element 21 of the comparative example are set on the instep of the subject in an environment of a temperature of 15 ° C. ± 5 ° C. After 8 hours of use, a sensory evaluation was performed on the soft feeling felt on the instep. The results are also shown in Table 1.

ソフト感の官能評価の評価基準は以下のとおりである。すなわち、実施例の発熱体1の方が比較例の発熱体21よりもソフトであると感じた場合には記号「A」、実施例の発熱体1と比較例の発熱体21のソフト感に差異が認められない場合には記号「B」、比較例の発熱体21の方が実施例の発熱体1よりもソフトであると感じた場合には記号「C」で示した。 The evaluation criteria for the sensory evaluation of softness are as follows. That is, when the heating element 1 of the example feels softer than the heating element 21 of the comparative example, the symbol "A" is used, and the heating element 1 of the example and the heating element 21 of the comparative example have a soft feeling. When no difference is observed, the symbol "B" is used, and when the heating element 21 of the comparative example is felt to be softer than the heating element 1 of the example, the symbol "C" is used.

Figure 0006783073
Figure 0006783073

表1から明らかなように、貼付時の温冷感試験において、比較例の発熱体21の方が実施例の発熱体1より温かく感じた、と答えた被験者は0人であった。また、比較例の発熱体21を足甲部に貼付した際にはかなり冷たさを感じるが、実施例の発熱体1を貼付した際には冷たさを感じず、むしろ温かさを感じる被験者も見受けられた。これは、実施例の発熱体1は、発熱組成物3と足甲部との間に弾性層10が介在しているため、冷たい環境下で保存されて冷たくなった発熱組成物3の冷たさが伝わりにくく、断熱効果が発揮されていると考えられる。したがって、冬場(4℃±2℃)に発熱体を貼付する場合でも、貼付時の冷感を抑制することができ、貼付後すぐにあまり冷たさを感じないまま発熱が開始され、発熱体により足甲部が温められる。すなわち、本発明の人体用発熱体は、人体へ適用して直ぐに、あまり冷たさを感じないまま発熱体による温熱感が保証されることが確認された。なお、本発明の発熱体は上記したように弾性層が介在しているので、発熱組成物の発熱が進み温度がかなり上昇したとしても、発熱した発熱組成物自体の熱さが直接足甲部に伝達されることはなく、マイルドな温感になると予想される。 As is clear from Table 1, in the heating / cooling sensation test at the time of application, 0 subjects answered that the heating element 21 of the comparative example felt warmer than the heating element 1 of the example. In addition, when the heating element 21 of the comparative example is attached to the instep, the subject feels considerably cold, but when the heating element 1 of the example is attached, some subjects do not feel the coldness but rather feel the warmth. Was done. This is because the heating element 1 of the embodiment has an elastic layer 10 interposed between the heating composition 3 and the instep portion, so that the heating composition 3 is cold because it is stored in a cold environment. Is difficult to convey, and it is thought that the heat insulating effect is exhibited. Therefore, even when the heating element is attached in winter (4 ° C ± 2 ° C), the feeling of coldness at the time of application can be suppressed, and immediately after application, heat generation is started without feeling too cold, and the heating element causes the heating element. The instep is warmed. That is, it was confirmed that the heating element for the human body of the present invention guarantees a feeling of warmth due to the heating element immediately after being applied to the human body without feeling too cold. Since the heating element of the present invention has an elastic layer interposed therebetween as described above, even if the heat generation of the heat generation composition progresses and the temperature rises considerably, the heat of the heat generation composition itself generated is directly applied to the instep. It is not transmitted and is expected to give a mild warmth.

また、表1における使用終了時のソフト感試験から明らかなように、使用終了時に実施例の発熱体1より比較例の発熱体21の方がソフトであると感じた、と答えた被験者は0人であった。実施例および比較例の発熱組成物3,23は、8時間使用後、いずれも固化する現象が認められた。しかしながら、実施例の発熱体1は固化した発熱組成物3と足甲部との間に弾性層10が介在しているので、固化して固くなった感触が足甲部には伝わりにくくなっており、ゴワゴワ感が緩和され、使用開始時のソフト感を持続することができた。一方、比較例の発熱体21は、発熱組成物23と足甲部との間に弾性層が介在していないので、固化して固くなった発熱組成物23の感触が足甲部にダイレクトに伝わり、被験者の足甲部に発熱組成物23のごつごつしたエッジ部が当たり、違和感が生じた。なお、実施例の発熱体1では、固化した発熱組成物3に起因する違和感を感じることなく、むしろ弾性層10自体の有するソフト感を感じる被験者も見受けられた。 Further, as is clear from the soft feeling test at the end of use in Table 1, 0 subjects answered that the heating element 21 of the comparative example felt softer than the heating element 1 of the example at the end of use. It was a person. The exothermic compositions 3 and 23 of Examples and Comparative Examples all showed a phenomenon of solidification after being used for 8 hours. However, in the heating element 1 of the example, since the elastic layer 10 is interposed between the solidified heat generating composition 3 and the instep portion, the feeling of solidification and hardening is not easily transmitted to the instep portion. The feeling of stiffness was alleviated, and the soft feeling at the start of use could be maintained. On the other hand, in the heating element 21 of the comparative example, since the elastic layer is not interposed between the heat generating composition 23 and the instep portion, the feel of the heat generating composition 23 solidified and hardened is directly applied to the instep portion. It was transmitted, and the rugged edge portion of the heating composition 23 hit the instep portion of the subject, causing a sense of discomfort. In the heating element 1 of the example, some subjects did not feel a sense of discomfort due to the solidified heating composition 3, but rather felt the soft feeling of the elastic layer 10 itself.

以上の結果から明らかなように、本発明により、人体に熱を供給しつつ、発熱反応によって固化した発熱組成物のゴワゴワ感を緩和する方法を実現することができた。特に、骨が表面に浮き出ていて複雑な凹凸を有する足甲部に適用してさえも、ゴワゴワ感を感じさせずに人体を温めることができた。また、本発明の人体用発熱体を用いれば、人体に熱を供給しつつ、発熱反応によって固化した発熱組成物が人体に与える違和感を緩和することができた。 As is clear from the above results, according to the present invention, it has been possible to realize a method for alleviating the stiff feeling of the exothermic composition solidified by the exothermic reaction while supplying heat to the human body. In particular, even when applied to the instep where the bones are raised on the surface and have complicated irregularities, the human body could be warmed without feeling stiff. Further, by using the heating element for the human body of the present invention, it was possible to alleviate the discomfort given to the human body by the exothermic composition solidified by the exothermic reaction while supplying heat to the human body.

1 人体用発熱体
2 扁平状袋体
3 発熱組成物
4 粘着層
5 非通気性積層体
6 通気性積層体
7 非通気性フィルム
8 不織布
9 通気性フィルム
10 弾性層
11 不織布
13 剥離紙
12,30 周縁部(ヒートシール)
21 比較例の人体用発熱体(足用発熱体)
22 扁平状袋体
23 発熱組成物
24 粘着層
25 非通気性積層体
26 通気性積層体
27 通気性フィルム
28 不織布
29 剥離紙
1 Heat-generating body for human body 2 Flat bag body 3 Heat-generating composition 4 Adhesive layer 5 Non-breathable laminate 6 Breathable laminate 7 Non-breathable film 8 Non-woven fabric 9 Breathable film 10 Elastic layer 11 Non-woven fabric 13 Release paper 12, 30 Peripheral part (heat seal)
21 Heating element for human body (heating element for feet) in Comparative Example
22 Flat bag 23 Heat-generating composition 24 Adhesive layer 25 Non-breathable laminate 26 Breathable laminate 27 Breathable film 28 Non-woven fabric 29 Release paper

Claims (3)

人体に熱を供給するための発熱体であって、
該発熱体が、
通気性の積層体および非通気性の積層体で構成された扁平状袋体と、
該扁平状袋体の内部に封入された、空気の存在によって発熱する発熱組成物と、
該扁平状袋体の該通気性の積層体側外面の少なくとも一部に積層された粘着層とからなり、
上記通気性の積層体が、通気性部および弾性層を有するとともに、
弾性層の厚みが500〜2,000μmであり、
該発熱体が、足の甲に熱を供給するためのものである
ことを特徴とする人体用発熱体。
A heating element for supplying heat to the human body
The heating element
A flat bag composed of a breathable laminate and a non-breathable laminate,
A heat-generating composition that generates heat due to the presence of air, which is enclosed inside the flat bag body,
It is composed of an adhesive layer laminated on at least a part of the outer surface of the flat bag body on the side of the breathable laminate.
The breathable laminate has a breathable portion and an elastic layer, and has a breathable layer.
The thickness of the elastic layer is Ri 500~2,000μm der,
A heating element for the human body, characterized in that the heating element is for supplying heat to the instep .
上記弾性層が、発泡ポリウレタンからなることを特徴とする請求項1に記載の人体用発熱体。 The heating element for a human body according to claim 1, wherein the elastic layer is made of foamed polyurethane. 通気性フィルム、弾性層および不織布をこの順に有する通気性の積層体、又は、通気性フィルム、不織布および弾性層をこの順に有する通気性の積層体を備えることを特徴とする請求項1または2に記載の人体用発熱体。
The first or second claim is characterized by comprising a breathable laminate having a breathable film, an elastic layer and a non-woven fabric in this order, or a breathable laminate having a breathable film, a non-woven fabric and an elastic layer in this order. The described heating element for the human body.
JP2016107444A 2016-05-30 2016-05-30 A method for preventing a heating element for the human body and a heating composition solidified by the heat generation from giving a feeling of strangeness to the human body. Active JP6783073B2 (en)

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