JP6755996B2 - Sample water analyzer - Google Patents
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- JP6755996B2 JP6755996B2 JP2019067933A JP2019067933A JP6755996B2 JP 6755996 B2 JP6755996 B2 JP 6755996B2 JP 2019067933 A JP2019067933 A JP 2019067933A JP 2019067933 A JP2019067933 A JP 2019067933A JP 6755996 B2 JP6755996 B2 JP 6755996B2
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 253
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 61
- 239000001301 oxygen Substances 0.000 claims description 61
- 229910052760 oxygen Inorganic materials 0.000 claims description 61
- 238000006243 chemical reaction Methods 0.000 claims description 51
- 239000007788 liquid Substances 0.000 claims description 48
- 238000007254 oxidation reaction Methods 0.000 claims description 48
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 46
- 239000012855 volatile organic compound Substances 0.000 claims description 46
- 230000004308 accommodation Effects 0.000 claims description 34
- 238000004458 analytical method Methods 0.000 claims description 33
- 230000003647 oxidation Effects 0.000 claims description 26
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 25
- 229910052799 carbon Inorganic materials 0.000 claims description 25
- 239000003795 chemical substances by application Substances 0.000 claims description 19
- 239000000126 substance Substances 0.000 claims description 18
- 239000007800 oxidant agent Substances 0.000 claims description 17
- 230000001590 oxidative effect Effects 0.000 claims description 17
- 238000001556 precipitation Methods 0.000 claims description 16
- 238000005259 measurement Methods 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 11
- 239000005416 organic matter Substances 0.000 claims description 11
- 238000007599 discharging Methods 0.000 claims description 7
- 230000002378 acidificating effect Effects 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 230000009471 action Effects 0.000 claims description 2
- 230000001376 precipitating effect Effects 0.000 claims 2
- 239000003643 water by type Substances 0.000 claims 1
- 239000000047 product Substances 0.000 description 22
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000001514 detection method Methods 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- 239000001569 carbon dioxide Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 238000003915 air pollution Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000001745 non-dispersive infrared spectroscopy Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
Classifications
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/18—Water
- G01N33/1826—Organic contamination in water
- G01N33/1846—Total carbon analysis
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/28—Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Description
本願は、試料水中の全有機炭素の含有量を分析可能な試料水分析装置に関する。 The present application relates to a sample water analyzer capable of analyzing the total organic carbon content in sample water.
人々が環境を重視するに伴い、各国政府は、汚水や廃水による環境への汚染を減らすために、汚水や廃水等の試料水中の全有機炭素（Ｔｏｔａｌ Ｏｒｇａｎｉｃ Ｃａｒｂｏｎ、ＴＯＣと略す）の含有量を規制している。そのため、業界の全有機炭素分析装置も、試料水中の全有機炭素の含有量を分析するために広く使用されている。全有機炭素分析装置は、通常、試料水中の有機物を酸化させて、非分散型赤外線分析計（Ｎｏｎ−Ｄｉｓｐｅｒｓｉｏｎ Ｉｎｆｒａｒｅｄ Ａｎａｌｙｚｅｒ、ＮＤＩＲと略す）で、試料水中の全有機炭素の濃度を測るようにしている。 As people attach great importance to the environment, governments have decided to reduce the content of total organic carbon (abbreviated as TOC) in sample water such as sewage and wastewater in order to reduce pollution to the environment by sewage and wastewater. It is regulated. Therefore, the industry's total organic carbon analyzer is also widely used to analyze the total organic carbon content in the sample water. The total organic carbon analyzer usually oxidizes the organic matter in the sample water and measures the concentration of total organic carbon in the sample water with a non-dispersion infrared analyzer (abbreviated as NDIR). There is.
ところが、現在市販されているＴＯＣ分析計の大多数は、実際にはＮＰＯＣ分析計としか呼ぶことができない。その理由は、これらの機器が、試料水に析出されている不揮発性有機物（ＮＰＯＣ）だけを分析するものになっており、試料水に含まれている揮発性有機物（ＰＯＣ）についての分析検出操作に関わらないからである。 However, the majority of TOC analyzers currently on the market can only be called NPOC analyzers in practice. The reason is that these devices analyze only the non-volatile organic compounds (NPOC) deposited in the sample water, and the analysis and detection operation for the volatile organic compounds (POC) contained in the sample water. Because it doesn't matter.
また、市場には、試料水中のＮＰＯＣの分析結果を出力可能な分析計もわずかに出ているが、それらは、換算という方式で分析結果を得るようにしている。Ｂｉｏｔｅｃｔｏｒ ｂ７０００分析計を例にすると、この分析計の分析方法は、主に以下の通りとなる。先ず、酸化のために、試料水にアルカリ剤（ＮａＯＨ）及びオゾンを添加し、次いで、試料水中の全炭素（ＴＣ）の含有量を得るために、酸性剤を添加して試料水中の二酸化炭素を全て吹き出し、その後、酸剤を添加することで試料水中の全無機炭素（ＴＩＣ）を吹き出し、更に、酸化のためにＮａＯＨ及びオゾンを添加し、再び酸剤を添加して試料水中の二酸化炭素を吹き出して、不揮発性有機物（ＮＰＯＣ）を得て、最後に、計算式ＴＣ−ＴＩＣ−ＮＰＯＣ＝ＰＯＣ（ＶＯＣ）により、試料水中のＰＯＣの含有量を算出する。 In addition, there are a few analyzers on the market that can output the analysis results of NPOC in the sample water, but they try to obtain the analysis results by a method called conversion. Taking the Biotector b7000 analyzer as an example, the analysis method of this analyzer is mainly as follows. First, an alkaline agent (NaOH) and ozone are added to the sample water for oxidation, and then an acidic agent is added to obtain the total carbon (TC) content in the sample water to obtain carbon dioxide in the sample water. After that, all inorganic carbon (TIC) in the sample water is blown out by adding an acid agent, NaOH and ozone are added for oxidation, and an acid agent is added again to carbon dioxide in the sample water. To obtain a non-volatile organic substance (NPOC), and finally, the content of POC in the sample water is calculated by the formula TC-TIC-NPOC = POC (VOC).
上述したＢｉｏｔｅｃｔｏｒ ｂ７０００分析計の欠点は、以下の通りである。１、ＶＯＣ（ＰＯＣ）は、プログラムによって算出されているが、ＮＰＯＣの検知限界は、０．０６ｐｐｍのレベルにしか達することができないという原因につき、ＶＯＣの検知限界も、ｐｐｍのレベルにしか達することができない。２、Ｂｉｏｔｅｃｔｏｒ ｂ７０００分析計では、異なる検出プロセスに対して、試料水の採水を実行するタイミングが同じタイミングではなく、その採水タイミングの差が６．５分間に及ぶ可能性もあり、これは、分析結果の正確性に影響を与えてしまう。 The drawbacks of the Biotector b7000 analyzer described above are as follows. 1. VOC (POC) is calculated by the program, but the detection limit of NPOC can only reach the level of 0.06ppm, so the detection limit of VOC also reaches only the level of ppm. Can't. 2. In the Biotector b7000 analyzer, the timing of sampling the sample water for different detection processes may not be the same, and the difference in the sampling timing may be up to 6.5 minutes. , Affects the accuracy of the analysis results.
以上のことから、水試料中のＶＯＣ（ＰＯＣ）分析結果の正確さ及び精確さを向上させるために上記の様々な問題をどのように解決するかは、本願の主な技術的思想である。 From the above, how to solve the above-mentioned various problems in order to improve the accuracy and accuracy of VOC (POC) analysis results in water samples is the main technical idea of the present application.
本願は、料水中の全有機炭素の含有量の分析結果の精確さ及び正確性を向上させるための試料水分析装置を提供する。 The present application provides a sample water analyzer for improving the accuracy and accuracy of the analysis result of the total organic carbon content in the water.
本願に係る試料水分析装置は、試料水中の全有機炭素の含有量を分析するための試料水分析装置であって、第一反応容器、第二反応容器、酸化反応モジュール及び試料水分析計を含む。第一反応容器は、第一定量の試料水を収容するための第一収容空間を有し、試料水から揮発性有機物を析出させて送り出す。酸化反応モジュールは、第一反応容器から送り出された揮発性有機物を酸化させて、第一酸化生成物を生成して送り出す。第二反応容器は、第二定量の試料水を収容するための第二収容空間を有し、試料水から不揮発性有機物を析出させ、不揮発性有機物を酸化させて第二酸化生成物を生成して送り出す。試料水分析計は、試料水中の揮発性有機物及び不揮発性有機物の含有量が分析されるように、第一酸化生成物及び第二酸化生成物をそれぞれ受け取って測定し、第一酸化生成物及び第二酸化生成物の測定結果を出力する。 The sample water analyzer according to the present application is a sample water analyzer for analyzing the content of total organic carbon in the sample water, and includes a first reaction vessel, a second reaction vessel, an oxidation reaction module, and a sample water analyzer. Including. The first reaction vessel has a first storage space for storing a first fixed amount of sample water, and volatile organic compounds are precipitated from the sample water and sent out. The oxidation reaction module oxidizes the volatile organic compounds delivered from the first reaction vessel to generate and deliver the first oxidation product. The second reaction vessel has a second storage space for accommodating a second amount of sample water, precipitates non-volatile organic matter from the sample water, and oxidizes the non-volatile organic matter to produce a second dioxide product. Send out. The sample water analyzer receives and measures the primary oxidation product and the dioxide product, respectively, so that the contents of the volatile organic compounds and the non-volatile organic compounds in the sample water are analyzed. The measurement result of the dioxide product is output.
好ましくは、本願において、酸化反応モジュール及び第二反応容器に選択的に連通し、酸化反応モジュール及び第二反応容器にオゾンをそれぞれ供給するためのオゾン供給モジュールを更に含む。 Preferably, the present application further includes an ozone supply module for selectively communicating with the oxidation reaction module and the second reaction vessel to supply ozone to the oxidation reaction module and the second reaction vessel, respectively.
好ましくは、本願において、第一酸素供給手段及び第一実行手段を更に含む。第一酸素供給手段は、第一収容空間に酸素を供給するためのものであり、第一実行手段は、揮発性有機物析出作業を実行することで、第一収容空間へ酸素を第一酸素供給手段に供給させ、試料水中の揮発性有機物を析出させて送り出す。 Preferably, in the present application, the first oxygen supply means and the first execution means are further included. The first oxygen supply means is for supplying oxygen to the first storage space, and the first execution means supplies oxygen to the first storage space by executing the volatile organic compound precipitation operation. It is supplied to the means to precipitate and send out volatile organic compounds in the sample water.
好ましくは、本願において、酸化反応モジュールは、スクリュー管を含み、酸化反応モジュールへオゾンをオゾン供給モジュールに供給させるとともに、オゾンと、第一反応容器から送り出された揮発性有機物とをスクリュー管内で酸化反応させて第一酸化生成物を生成する。 Preferably, in the present application, the oxidation reaction module includes a screw tube, supplies ozone to the ozone supply module to the oxidation reaction module, and oxidizes ozone and volatile organic substances delivered from the first reaction vessel in the screw tube. The reaction produces the first oxidation product.
好ましくは、本願において、第一酸素供給手段は、オゾン供給モジュールに更に連通しており、オゾン供給モジュールが酸素を反応させてオゾンを生成するように、オゾン供給モジュールに酸素を供給するためのものである。 Preferably, in the present application, the primary oxygen supply means further communicates with the ozone supply module to supply oxygen to the ozone supply module so that the ozone supply module reacts with oxygen to generate ozone. Is.
好ましくは、本願において、それぞれ第二収容空間に連通する酸性剤供給手段、酸化剤供給手段、第二酸素供給手段、第三酸素供給手段、ＵＶ光供給手段及び第二実行手段を更に含む。酸性剤供給手段は、酸性剤を供給するためのものである。酸化剤供給手段は、酸化剤を供給するためのものである。第二酸素供給手段は、第一流量の酸素を供給するためのものである。第三酸素供給手段は、第二流量の酸素を供給するためのものである。ＵＶ光供給手段は、ＵＶ光を供給するためのものである。第二実行手段は、全有機炭素析出作業及び不揮発性有機物酸化作業を順番に実行する。第二実行手段による全無機炭素析出作業の実行時には、試料水中の全無機炭素を析出させるために、第二収容空間へ酸性剤を酸性剤供給手段に供給させるとともに、第二収容空間へ第一流量の酸素を第二酸素供給手段に供給させる。第二実行手段による不揮発性有機物酸化作業の実行時には、試料水中の第二酸化生成物を析出させて送り出すために、第二収容空間へオゾンをオゾン供給モジュールに供給させ、更に第二収容空間へ酸化剤を酸化剤供給手段に供給させ、その後、オゾンと酸化剤とが混合された試料水を、第二収容空間とＵＶ光供給手段との間で循環流動させることで、試料水中の不揮発性有機物を酸化させて第二酸化生成物を生成し、次いで、第二収容空間へ第一流量よりも小さくなる第二流量の酸素を第三酸素供給手段に供給させる。 Preferably, in the present application, the acid agent supply means, the oxidant supply means, the second oxygen supply means, the third oxygen supply means, the UV light supply means and the second execution means communicating with the second storage space are further included. The acid agent supply means is for supplying the acid agent. The oxidant supply means is for supplying the oxidant. The second oxygen supply means is for supplying the first flow rate of oxygen. The third oxygen supply means is for supplying a second flow rate of oxygen. The UV light supply means is for supplying UV light. The second execution means sequentially executes the total organic carbon precipitation operation and the non-volatile organic substance oxidation operation. When performing the all-inorganic carbon precipitation operation by the second executing means, the acidic agent is supplied to the second accommodating space to the second accommodating space and the first to the second accommodating space in order to precipitate all inorganic carbon in the sample water. The flow of oxygen is supplied to the secondary oxygen supply means. When the non-volatile organic substance oxidation work is performed by the second execution means, ozone is supplied to the ozone supply module to the second storage space in order to precipitate and send out the dioxide product in the sample water, and the ozone is further oxidized to the second storage space. The agent is supplied to the oxidant supply means, and then the sample water in which ozone and the oxidant are mixed is circulated and flowed between the second storage space and the UV light supply means, whereby a non-volatile organic substance in the sample water is formed. Is oxidized to produce the ozone product, and then a second flow rate of oxygen smaller than the first flow rate is supplied to the second storage space to the third oxygen supply means.
好ましくは、本願において、第二実行手段は、揮発性有機物析出作業を更に実行する。第二実行手段による揮発性有機物析出作業の実行時には、試料水中の揮発性有機物を析出させるために、第二収容空間へ第一流量の酸素を第二酸素供給手段に供給させる。 Preferably, in the present application, the second action means further carries out the volatile organic compound precipitation operation. At the time of executing the volatile organic compound precipitation work by the second execution means, the second oxygen supply means is supplied with the first flow rate of oxygen in order to precipitate the volatile organic compounds in the sample water.
好ましくは、本願において、第一収容空間に連通し、第一収容空間へ試料水を送り込むための第一入液モジュールと、第一収容空間に連通し、第一収容空間内の過量の試料水を排出するための第一過量排液モジュールと、第一収容空間に連通し、第一収容空間に第一定量の試料水が収容されるように、第一収容空間内の一部の試料水を排出するための第一定量排液モジュールと、試料水が第一収容空間を経由して第二収容空間に入り込むように、第一収容空間と第二収容空間との双方の底部にそれぞれ連通する第二入液モジュールと、第二収容空間に連通し、第二収容空間内の過量の試料水を排出するための第二過量排液モジュールと、第二収容空間に連通し、第二収容空間に第二定量の試料水が収容されるように、第二収容空間内の一部の試料水を排出するための第二定量排液モジュールと、第二収容空間の底部に連通し、第二収容空間内の試料水を排出するための排液モジュールと、を更に含む。入液作業の実行時には、第一入液モジュール、第二入液モジュール、第一過量排液モジュール及び第二過量排液モジュールをオンして、第一入液モジュールによって、第一収容空間へ試料水を送るとともに、第二入液モジュールによって、試料水を、第一収容空間を経由して第二収容空間内に入り込ませ、第一収容空間内の過量の試料水が第一過量排液モジュールによって排出され、且つ第二収容空間内の過量の試料水が第二過量排液モジュールによって排出されると、第一入液モジュール及び第二入液モジュールをオフし、その後、第一収容空間に第一定量の試料水が収容され、且つ第二収容空間に第二定量の試料水が収容されるように、第一定量排液モジュール及び第二定量排液モジュールをオンして、第一収容空間内の一部の試料水及び第二収容空間内の一部の試料水をそれぞれ排出する。排液作業の実行時には、第二入液モジュール及び排液モジュールをオンして、第二入液モジュールによって、第一収容空間内に収容された試料水を第二収容空間内に入り込ませると共に、排液モジュールによって、第二収容空間内の試料水を排出する。 Preferably, in the present application, a first liquid input module for sending sample water to the first storage space by communicating with the first storage space and an excessive amount of sample water communicating with the first storage space and communicating with the first storage space. A part of the sample in the first storage space so that the first amount of sample water is stored in the first storage space by communicating with the first excess drainage module for draining the water. At the bottom of both the first and second containment spaces so that the first quantitative drainage module for draining water and the sample water enter the second containment space via the first containment space. A second inlet module that communicates with each other, a second excess liquid drainage module that communicates with the second accommodation space and discharges an excess amount of sample water in the second accommodation space, and a second excess liquid discharge module that communicates with the second accommodation space. (2) Communicate with the second quantitative drainage module for draining a part of the sample water in the second accommodation space and the bottom of the second accommodation space so that the second quantitative sample water is accommodated in the second accommodation space. , A drainage module for draining sample water in the second containment space, and the like. When executing the liquid filling work, the first liquid filling module, the second liquid filling module, the first excess liquid draining module and the second excessive liquid draining module are turned on, and the sample is input to the first storage space by the first liquid filling module. Along with sending water, the sample water is allowed to enter the second storage space via the first storage space by the second liquid input module, and the excess sample water in the first storage space is discharged from the first excess liquid discharge module. When the excess sample water in the second storage space is discharged by the second excess liquid discharge module, the first liquid input module and the second liquid input module are turned off, and then the first liquid storage space is entered. Turn on the first quantitative effluent module and the second quantitative effluent module so that the first quantitative sample water is accommodated and the second quantitative sample water is accommodated in the second accommodation space. A part of the sample water in the first storage space and a part of the sample water in the second storage space are discharged. When executing the drainage work, the second liquid entry module and the drainage module are turned on, and the sample water contained in the first storage space is allowed to enter the second storage space by the second liquid storage module. The drainage module drains the sample water in the second storage space.
好ましくは、本願において、第一反応容器及び第二反応容器へ標準試料水を供給するための標準試料水供給モジュールを更に含み、標準試料水の析出気体が試料水分析計によって分析され、標準試料水の分析結果に基づいて、試料水中揮発性有機物及び不揮発性有機物の含有量が分析される。 Preferably, in the present application, the standard sample water supply module for supplying the standard sample water to the first reaction vessel and the second reaction vessel is further included, and the precipitated gas of the standard sample water is analyzed by the sample water analyzer and the standard sample is analyzed. Based on the analysis result of water, the contents of volatile organic substances and non-volatile organic substances in the sample water are analyzed.
好ましくは、本願において、標準試料水の分析結果に基づいて、試料水分析計が不正確であるかを判断し、試料水分析計が不正確である場合、標準試料水の分析結果に基づいて、試料水分析計を較正する較正モジュールを更に含む。 Preferably, in the present application, it is determined whether the sample water analyzer is inaccurate based on the analysis result of the standard sample water, and if the sample water analyzer is inaccurate, based on the analysis result of the standard sample water. Also includes a calibration module to calibrate the sample water analyzer.
従来技術に比べると、本願の試料水分析装置は、第一反応容器及び第二反応容器を設けることで、試料水中の揮発性有機物及び不揮発性有機物の含有量をそれぞれ検出するとともに、該第一、第二反応容器が同一タイミングで試料水を採集しているため、試料水中の全有機炭素の含有量の分析結果の精確さ及び正確性が効果的に向上する。 Compared with the prior art, the sample water analyzer of the present application detects the contents of volatile organic compounds and non-volatile organic compounds in the sample water by providing the first reaction vessel and the second reaction vessel, respectively, and the first reaction vessel. Since the second reaction vessel collects the sample water at the same timing, the accuracy and accuracy of the analysis result of the total organic carbon content in the sample water are effectively improved.
しかも、標準試料水供給モジュールを設けて標準試料水を供給することで、較正モジュールは、該標準試料水の分析結果に基づいて試料水分析計を較正しているため、検出結果の正確性が更に向上する。 Moreover, by providing the standard sample water supply module and supplying the standard sample water, the calibration module calibrates the sample water analyzer based on the analysis result of the standard sample water, so that the accuracy of the detection result can be improved. Further improvement.
以下、図面を参照しながら、特定の実施例により本願の技術内容を説明する。当業者であれば、本明細書に開示される内容から本願の他の利点及び効果を容易に理解することができる。本願は、他の異なる実施例により実施又は応用することもできる。本明細書における各細部も本願の構想に反しない前提で、異なる視点と応用に基づき、各種の修正と変更を行わせることができる。特に、図面における各部品に関する比例関係及び相対位置は、例示的な説明用だけであり、本願の実施の実際状況を示すものではない。 Hereinafter, the technical contents of the present application will be described with reference to the drawings according to specific examples. One of ordinary skill in the art can easily understand the other advantages and effects of the present application from the contents disclosed in the present specification. The present application may also be implemented or applied by other different embodiments. Various modifications and changes can be made based on different viewpoints and applications on the premise that each detail in the present specification does not contradict the concept of the present application. In particular, the proportional relationships and relative positions of the parts in the drawings are for illustrative purposes only and do not indicate the actual situation of implementation of the present application.
本願は、試料水中の全有機炭素の含有量を分析するための試料水分析装置１を提供しており、図１に示すように、試料水分析装置１は、主に、第一反応容器１１、酸化反応モジュール１２、第二反応容器１３及び試料水分析計１４を含む。 The present application provides a sample water analyzer 1 for analyzing the total organic carbon content in the sample water, and as shown in FIG. 1, the sample water analyzer 1 mainly includes the first reaction vessel 11. , Oxidation reaction module 12, second reaction vessel 13, and sample water analyzer 14.
第一反応容器１１は、第一定量の試料水を収容するための第一収容空間１１１を有する。採集された試料水が多いほど、試料水に析出された揮発性有機物が多くなる。これは、後続の該揮発性有機物の酸化によって生じる二酸化炭素も多くなり、試料水分析計１４が該揮発性有機物から生じた二酸化炭素を介して試料水中の揮発性有機物の含有量を分析可能であることが確保されることを意味するため、第一定量の試料水が多いほど、本願の分析に役立つ。好ましくは、第一定量の試料水が２０ｍｌの定量の試料水である。 The first reaction vessel 11 has a first storage space 111 for storing a first fixed amount of sample water. The more sample water collected, the more volatile organic compounds are deposited in the sample water. This means that the amount of carbon dioxide generated by the subsequent oxidation of the volatile organic compound also increases, and the sample water analyzer 14 can analyze the content of the volatile organic compound in the sample water via the carbon dioxide generated from the volatile organic compound. The more first quantitative sample water, the more useful for the analysis of the present application, as it means that it is ensured. Preferably, the first quantitative sample water is 20 ml of the quantitative sample water.
図１〜図５に示すように、試料水分析装置１は、第一入液モジュール２５、第一過量排液モジュール２６及び第一定量排液モジュール２７を更に含む。 As shown in FIGS. 1 to 5, the sample water analyzer 1 further includes a first inlet module 25, a first excess drainage module 26, and a first quantitative drainage module 27.
第一入液モジュール２５は、第一反応容器１１における第一収容空間１１１の底部に連通し、第一収容空間１１１へ試料水を送り込むためのものである。好ましくは、第一入液モジュール２５に弁体Ｖ１及びポンプＰ１が更に設けられており、弁体Ｖ１を開いてポンプＰ１をオンして、試料水を下から上に向かって第一収容空間１１１に入り込ませることが可能である。 The first liquid input module 25 communicates with the bottom of the first storage space 111 in the first reaction vessel 11 to feed the sample water into the first storage space 111. Preferably, the first liquid input module 25 is further provided with the valve body V1 and the pump P1, and the valve body V1 is opened to turn on the pump P1 to allow the sample water to flow from the bottom to the top in the first storage space 111. It is possible to get in.
第一過量排液モジュール２６は、第一収容空間１１１の上部に連通し、第一収容空間１１１内の過量の試料水を排出する。つまり、第一過量排液モジュール２６は、第一収容空間１１１内の第一過量排液モジュール２６に対応する水位よりも高くなる試料水を排出するためのものであり、好ましくは、第一過量排液モジュール２６に弁体Ｖ２が設けられている。 The first excess liquid drainage module 26 communicates with the upper part of the first storage space 111 and discharges the excess sample water in the first storage space 111. That is, the first excess drainage module 26 is for draining sample water that is higher than the water level corresponding to the first excess drainage module 26 in the first storage space 111, and is preferably the first excess drainage module 26. A valve body V2 is provided on the drainage module 26.
第一定量排液モジュール２７は、第一収容空間１１１に連通し、且つ第一定量排液モジュール２７の第一収容空間１１１内での水位が、第一過量排液モジュール２６の第一収容空間１１１内での水位よりも低くなっている。第一定量排液モジュール２７は、第一収容空間１１１に第一定量の試料水が収容されるように、第一収容空間１１１内の一部の試料水を排出する。つまり、第一定量排液モジュール２７は、第一収容空間１１１内の第一定量排液モジュール２７に対応する水位よりも高くなる試料水を排出するためのものである。好ましくは、第一定量排液モジュール２７が試料水を排出するためのポンプＰ２を更に有する。 The first quantitative drainage module 27 communicates with the first storage space 111, and the water level in the first storage space 111 of the first quantitative drainage module 27 is the first of the first excess drainage module 26. It is lower than the water level in the accommodation space 111. The first quantitative drainage module 27 discharges a part of the sample water in the first storage space 111 so that the first fixed amount of sample water is stored in the first storage space 111. That is, the first quantitative drainage module 27 is for discharging the sample water that is higher than the water level corresponding to the first quantitative drainage module 27 in the first accommodation space 111. Preferably, the first quantitative drainage module 27 further comprises a pump P2 for draining the sample water.
第一収容空間１１１内に第一定量の試料水が収容されるようになると、第一反応容器１１は、次に第一定量の試料水から揮発性有機物を析出させる。 When the first fixed amount of sample water is contained in the first storage space 111, the first reaction vessel 11 then precipitates volatile organic compounds from the first fixed amount of sample water.
具体的に、試料水分析装置１は、第一収容空間１１１へ酸素を供給するための第一酸素供給手段１６を更に含む。本実施例において、弁体Ｖ３の開閉によって、第一酸素供給手段１６による第一収容空間１１１への酸素の供給が制御される。供給された酸素は、第一収容空間１１１内の試料水と反応し、試料水から揮発性有機物を析出させるために用いられる（図２に示す）。 Specifically, the sample water analyzer 1 further includes a primary oxygen supply means 16 for supplying oxygen to the first storage space 111. In this embodiment, the supply of oxygen to the first accommodation space 111 by the first oxygen supply means 16 is controlled by opening and closing the valve body V3. The supplied oxygen reacts with the sample water in the first storage space 111 and is used to precipitate volatile organic compounds from the sample water (shown in FIG. 2).
その後、第一反応容器１１は、試料水から析出された揮発性有機物を、弁体Ｖ４を介して酸化反応モジュール１２に送り出し、酸化反応モジュール１２は、該揮発性有機物を酸化させ、第一酸化生成物を生成して送り出す。 After that, the first reaction vessel 11 sends the volatile organic compounds precipitated from the sample water to the oxidation reaction module 12 via the valve body V4, and the oxidation reaction module 12 oxidizes the volatile organic compounds to make the first oxidation. Generate and send out the product.
なお、上述した第一反応容器１１内の揮発性有機物析出作業は、第一実行手段３５によって制御及び実行されてよい。具体的には、第一実行手段３５による揮発性有機物析出作業の実行時には、先ず、弁体Ｖ３を開いて、第一収容空間１１１へ酸素を第一酸素供給手段１６に供給させることで試料水中の揮発性有機物を析出させ、その後、弁体Ｖ４を開いて、析出された揮発性有機物を送り出す。 The volatile organic compound precipitation operation in the first reaction vessel 11 described above may be controlled and executed by the first execution means 35. Specifically, when the volatile organic compound precipitation operation is executed by the first executing means 35, the valve body V3 is first opened to supply oxygen to the first accommodating space 111 to the first oxygen supply means 16 so that the sample water is supplied. The volatile organic compounds of the above are precipitated, and then the valve body V4 is opened to send out the precipitated volatile organic compounds.
本実施例において、試料水分析装置１は、弁体Ｖ１１を介して酸化反応モジュール１２に連通し、酸化反応モジュール１２へオゾンを供給するオゾン供給モジュール１５を更に含む。具体的には、第一酸素供給手段１６は、更に、弁体Ｖ１２を介してオゾン供給モジュール１５に連通し、オゾン供給モジュール１５へ酸素を供給するために用いられることが可能であり、オゾン供給モジュール１５は、酸素を反応させることで、送り込まれた酸素をオゾンに転化させて、酸化反応モジュール１２に送り出す。 In this embodiment, the sample water analyzer 1 further includes an ozone supply module 15 that communicates with the oxidation reaction module 12 via the valve body V11 and supplies ozone to the oxidation reaction module 12. Specifically, the first oxygen supply means 16 can be further communicated with the ozone supply module 15 via the valve body V12 and used to supply oxygen to the ozone supply module 15 and supply ozone. By reacting oxygen, the module 15 converts the sent oxygen into ozone and sends it out to the oxidation reaction module 12.
しかも、本願の酸化反応モジュール１２は、スクリュー管を含んでおり、オゾン供給モジュール１５から酸化反応モジュール１２に供給されたオゾンと、第一反応容器１１から送り出された揮発性有機物とは、スクリュー管内で流動して混合することで、酸化反応を十分にし、更に第一酸化生成物を生成することができる。 Moreover, the oxidation reaction module 12 of the present application includes a screw tube, and the ozone supplied from the ozone supply module 15 to the oxidation reaction module 12 and the volatile organic matter sent out from the first reaction vessel 11 are contained in the screw tube. By flowing and mixing with, the oxidation reaction can be made sufficient and a primary oxidation product can be further produced.
生成された第一酸化生成物は、例えばＣＯ２であり、酸化反応モジュール１２から試料水分析計１４に送られてもよい。本実施例において、試料水分析計１４は、例えば非分散型紅外線分析計であり、試料水中の揮発性有機物の含有量が分析されるように、第一酸化生成物に対して測定を行い、対応する測定結果を出力するために用いられる。 The first oxidation product produced is, for example, CO 2 , and may be sent from the oxidation reaction module 12 to the sample water analyzer 14. In this example, the sample water analyzer 14 is, for example, a non-dispersive infrared analyzer, which measures the primary oxidation product so that the content of volatile organic compounds in the sample water is analyzed. It is used to output the corresponding measurement result.
第二反応容器１３は、第二定量の試料水を収容するための第二収容空間１３１を有する。本実施例において、試料水分析装置１は、第二入液モジュール２８、第二過量排液モジュール２９、第二定量排液モジュール３０及び排液モジュール３１を更に含む。 The second reaction vessel 13 has a second storage space 131 for storing a second amount of sample water. In this embodiment, the sample water analyzer 1 further includes a second inlet module 28, a second excess drainage module 29, a second quantitative drainage module 30, and a drainage module 31.
第二入液モジュール２８は、第一収容空間１１１の底部及び第二反応容器１３の第二収容空間１３１にそれぞれ連通し、第一収容空間１１１内の試料水を、第二入液モジュール２８を経由して第二収容空間１３１に入り込ませるためのものである。本実施例において、第二入液モジュール２８は、ポンプＰ３を更に有する。本実施例において、試料水を下から上に向かって第二収容空間１３１に入り込ませるために、第二入液モジュール２８は、第二収容空間１３１の底部に連通している。 The second liquid input module 28 communicates with the bottom of the first storage space 111 and the second storage space 131 of the second reaction vessel 13, respectively, and the sample water in the first storage space 111 is transferred to the second liquid input module 28. The purpose is to allow the user to enter the second accommodation space 131 via the space. In this embodiment, the second liquid entry module 28 further includes a pump P3. In this embodiment, the second liquid input module 28 communicates with the bottom of the second storage space 131 in order to allow the sample water to enter the second storage space 131 from the bottom to the top.
第二過量排液モジュール２９は、第二収容空間１３１に連通し、第二収容空間１３１内の過量の試料水を排出する。つまり、第二過量排液モジュール２９は、第二収容空間１３１内の第二過量排液モジュール２９に対応する水位よりも高くなる試料水を排出するためのものである。好ましくは、第二過量排液モジュール２９に弁体Ｖ５が設けられている。 The second excess liquid drainage module 29 communicates with the second storage space 131 and discharges the excess sample water in the second storage space 131. That is, the second excess drainage module 29 is for draining the sample water that is higher than the water level corresponding to the second excess drainage module 29 in the second accommodation space 131. Preferably, the second excess drainage module 29 is provided with a valve body V5.
第二定量排液モジュール３０は、第二収容空間１３１に連通し、且つ第二定量排液モジュール３０の第二収容空間１３１内での水位が、第二過量排液モジュール２９の第二収容空間１３１内での水位よりも低くなっている。第二定量排液モジュール３０は、第二収容空間１３１に第二定量の試料水が収容されるように、第二収容空間１３１内の一部の試料水を排出する。つまり、第二定量排液モジュール３０は、第二収容空間１３１内の第二定量排液モジュール３０に対応する水位よりも高くなる試料水を排出するためのものである。好ましくは、第二定量排液モジュール３０に、試料水を排出するためのポンプＰ６が設けられている。 The second quantitative drainage module 30 communicates with the second storage space 131, and the water level in the second storage space 131 of the second quantitative drainage module 30 is the second storage space of the second excess drainage module 29. It is lower than the water level in 131. The second quantitative drainage module 30 discharges a part of the sample water in the second storage space 131 so that the second quantitative sample water is stored in the second storage space 131. That is, the second quantitative drainage module 30 is for discharging the sample water that is higher than the water level corresponding to the second quantitative drainage module 30 in the second storage space 131. Preferably, the second quantitative drainage module 30 is provided with a pump P6 for draining the sample water.
第二収容空間１３１内に第二定量の試料水が収容されるようになると、第二反応容器１３は、次に試料水から不揮発性有機物を析出させて該不揮発性有機物を酸化させ、第二酸化生成物を生成して送り出す。 When a second fixed amount of sample water is contained in the second storage space 131, the second reaction vessel 13 then precipitates a non-volatile organic substance from the sample water to oxidize the non-volatile organic substance, thereby producing dioxide. Generate and send out the product.
具体的に、試料水分析装置１は、それぞれ第二収容空間１３１に連通する酸性剤供給手段１８、酸化剤供給手段１９、第二酸素供給手段２０、第三酸素供給手段２１及びＵＶ光供給手段２２を更に含む。酸性剤供給手段１８は、ポンプＰ４を介して第二収容空間１３１へ酸性剤を供給する。酸化剤供給手段１９は、ポンプＰ５を介して第二収容空間１３１へ酸化剤を供給する。第二酸素供給手段２０は、弁体Ｖ７を介して第二収容空間１３１へ第一流量の酸素を供給する。第三酸素供給手段２１は、弁体Ｖ８を介して第二収容空間１３１へ第二流量の酸素を供給する、好ましくは、第一流量が第二流量よりも大きい。ポンプＰ７は、試料水を第二収容空間１３１とＵＶ光供給手段２２との間で循環流動させることで、ＵＶ光供給手段２２によって、循環流動されている試料水へＵＶ光を供給する。 Specifically, the sample water analyzer 1 includes an acid agent supply means 18, an oxidant supply means 19, a second oxygen supply means 20, a third oxygen supply means 21, and a UV light supply means that communicate with the second storage space 131, respectively. 22 is further included. The acid agent supply means 18 supplies the acid agent to the second accommodation space 131 via the pump P4. The oxidant supply means 19 supplies the oxidant to the second accommodation space 131 via the pump P5. The second oxygen supply means 20 supplies the first flow rate of oxygen to the second accommodation space 131 via the valve body V7. The third oxygen supply means 21 supplies a second flow rate of oxygen to the second accommodation space 131 via the valve body V8, preferably the first flow rate is larger than the second flow rate. The pump P7 circulates and flows the sample water between the second storage space 131 and the UV light supply means 22, so that the UV light supply means 22 supplies the UV light to the sample water that is circulated and flowed.
また、試料水分析装置１は、第二実行手段３６を更に含む。図３を参照すると、第二実行手段３６は、第二収容空間１３１内の試料水に対して、全無機炭素析出作業及び不揮発性有機物酸化作業を順番に実行するためのものである。先ず、ポンプＰ４をオンして、第二収容空間１３１へ酸性剤を酸性剤供給手段１８に供給させる。その後、弁体Ｖ７を開いて、第二収容空間１３１へ第一流量の酸素を第二酸素供給手段２０に供給させると同時に、弁体Ｖ５を開いて第二過量排液モジュール２９をオンすることで、添加された酸性剤及び酸素によって、試料水中の全無機炭素及び揮発性有機物が析出されるとともに、析出された全無機炭素及び揮発性有機物が、オンされている第二過量排液モジュール２９を介して、第二収容空間１３１から吹き出されることが可能である。この時、第二収容空間１３１内の試料水には、不揮発性有機物が残っている。 Further, the sample water analyzer 1 further includes a second execution means 36. Referring to FIG. 3, the second executing means 36 is for sequentially executing the all-inorganic carbon precipitation operation and the non-volatile organic substance oxidation operation on the sample water in the second accommodating space 131. First, the pump P4 is turned on to supply the acidic agent to the second accommodating space 131 to the acidic agent supply means 18. After that, the valve body V7 is opened to supply the first flow rate of oxygen to the second storage space 131 to the second oxygen supply means 20, and at the same time, the valve body V5 is opened to turn on the second excess drainage module 29. Then, the added acid agent and oxygen precipitate all-inorganic carbon and volatile organic compounds in the sample water, and the precipitated all-inorganic carbon and volatile organic compounds are turned on in the second excess drainage module 29. It is possible to blow out from the second accommodation space 131 via. At this time, a non-volatile organic substance remains in the sample water in the second storage space 131.
その後、第二実行手段３６は、不揮発性有機物酸化作業を実行する。図４〜５を参照すると、先ず、弁体Ｖ１１及び弁体Ｖ５を開いて、第二収容空間１３１へオゾンをオゾン供給モジュール１５に供給させる。その後、弁体Ｖ５を閉じてポンプＰ５をオンして、第二収容空間１３１へ酸化剤を酸化剤供給手段１９に供給させる。次いで、弁体Ｖ８及び弁体Ｖ６を同時に開いて、ポンプＰ７をオンし、ポンプＰ７によって、オゾンと酸化剤とが混合された試料水を第二収容空間１３１とＵＶ光供給手段２２との間で循環流動させ、ＵＶ光供給手段２２によって、試料水中の不揮発性有機物を酸化させて例えばＣＯ２である第二酸化生成物を生成し、第三酸素供給手段２１によって、第二収容空間１３１へ第二流量の酸素を供給して試料水中の第二酸化生成物を析出させ、析出された第二酸化生成物が弁体Ｖ６を介して試料水分析計１４に送り出される。試料水分析計１４は、第二酸化生成物に対して測定を行い、対応する測定結果を出力することで、試料水中の不揮発性有機物の含有量が分析される。ここで、試料水中の不揮発性有機物を十分に酸化させることを可能にするために、第二流量は、第一流量よりも小さい。 After that, the second execution means 36 executes the non-volatile organic substance oxidation work. Referring to FIGS. 4 to 5, first, the valve body V11 and the valve body V5 are opened to supply ozone to the second accommodation space 131 to the ozone supply module 15. After that, the valve body V5 is closed and the pump P5 is turned on to supply the oxidant to the second accommodating space 131 to the oxidant supply means 19. Next, the valve body V8 and the valve body V6 are opened at the same time, the pump P7 is turned on, and the sample water in which ozone and the oxidant are mixed is brought between the second accommodating space 131 and the UV light supply means 22 by the pump P7. The UV light supply means 22 oxidizes the non-volatile organic matter in the sample water to produce ozone product, which is, for example, CO 2 , and the third oxygen supply means 21 sends the sample water to the second storage space 131. Two flows of oxygen are supplied to precipitate the ozone product in the sample water, and the precipitated product of ozone is sent to the sample water analyzer 14 via the valve body V6. The sample water analyzer 14 measures the product of dioxide and outputs the corresponding measurement result to analyze the content of the non-volatile organic matter in the sample water. Here, the second flow rate is smaller than the first flow rate in order to enable sufficient oxidation of the non-volatile organic matter in the sample water.
好ましくは、試料水分析計１４による第一酸化生成物の測定分析作業と、第二反応容器１３による全無機炭素析出作業及揮発性有機物析出作業とが同期に実行され、試料水分析計１４による第一酸化生成物の測定分析作業が完了すると、弁体Ｖ６を開いて、第二反応容器１３から送り出された第二酸化生成物に対して測定分析を行う。即ち、試料水分析計１４は、第一酸化生成物及び第二酸化生成物の測定分析を別々に実行する。 Preferably, the measurement and analysis work of the primary oxidation product by the sample water analyzer 14 and the total inorganic carbon precipitation work and the volatile organic matter precipitation work by the second reaction vessel 13 are executed in synchronization, and the sample water analyzer 14 is used. When the measurement and analysis work of the first oxidation product is completed, the valve body V6 is opened and the measurement and analysis is performed on the dioxide product sent out from the second reaction vessel 13. That is, the sample water analyzer 14 separately performs the measurement and analysis of the first oxidation product and the second dioxide product.
また、試料水分析装置１は、第二収容空間１３１の底部に連通し、第二収容空間１３１内の試料水を排出するための排液モジュール３１を更に含む。好ましくは、排液モジュール３１が試料水を排出するためのポンプＰ８を更に有する。 Further, the sample water analyzer 1 further includes a drainage module 31 that communicates with the bottom of the second storage space 131 and discharges the sample water in the second storage space 131. Preferably, the drainage module 31 further comprises a pump P8 for draining the sample water.
好ましくは、試料水分析装置１は、入液作業を実行することで、第一入液モジュール２５をオンし（即ち、弁体Ｖ１を開き、ポンプＰ１をオンし）、第二入液モジュール２８（即ち、ポンプＰ３）をオンし、第一過量排液モジュール２６をオンし（即ち、弁体Ｖ２を開き）、第二過量排液モジュール２９をオンして（即ち、弁体Ｖ５を開いて）、第一収容空間１１１内の過量の試料水が第一過量排液モジュール２６によって排出され、且つ第二収容空間１３１内の過量の試料水が第二過量排液モジュール２９によって排出される（即ち、図１に示す状態になる）まで、第一入液モジュール２５によって、第一収容空間１１１へ試料水を送るとともに、第二入液モジュール２８によって、試料水を、第一収容空間１１１を経由して第二収容空間１３１内に入り込ませていくことが可能である。その後、第一入液モジュール２５をオフし（即ち、弁体Ｖ１を閉じ、ポンプＰ１をオフし）、第二入液モジュール２８をオフする（即ち、ポンプＰ３をオフする）。次いで、第一定量排液モジュール２７（即ち、ポンプＰ２）及び第二定量排液モジュール３０（即ち、ポンプＰ６）をオンして、第一収容空間１１１に第一定量の該試料水が収容され、且つ第二収容空間１３１に第二定量の該試料水が収容されるように、第一収容空間１１１内の一部の試料水及び第二収容空間１３１内の一部の試料水をそれぞれ排出する。このように、本願の第一反応容器１１と第二反応容器１３とは、試料水の採集操作を同期に実行することができる。 Preferably, the sample water analyzer 1 turns on the first liquid entry module 25 (that is, opens the valve body V1 and turns on the pump P1) by performing the liquid filling operation, and turns on the second liquid filling module 28. (That is, the pump P3) is turned on, the first overdrainage module 26 is turned on (that is, the valve body V2 is opened), and the second overdrainage module 29 is turned on (that is, the valve body V5 is opened). ), The excess sample water in the first storage space 111 is discharged by the first excess drainage module 26, and the excess sample water in the second storage space 131 is discharged by the second excess drainage module 29 (. That is, until the state shown in FIG. 1 is reached), the sample water is sent to the first storage space 111 by the first liquid input module 25, and the sample water is sent to the first storage space 111 by the second liquid storage module 28. It is possible to enter the second accommodation space 131 via the route. After that, the first liquid input module 25 is turned off (that is, the valve body V1 is closed and the pump P1 is turned off), and the second liquid input module 28 is turned off (that is, the pump P3 is turned off). Next, the first quantitative drainage module 27 (that is, pump P2) and the second quantitative drainage module 30 (that is, pump P6) are turned on, and the first quantitative amount of the sample water is filled in the first storage space 111. A part of the sample water in the first storage space 111 and a part of the sample water in the second storage space 131 are stored so that the second amount of the sample water is stored in the second storage space 131. Discharge each. As described above, the first reaction vessel 11 and the second reaction vessel 13 of the present application can simultaneously execute the sample water collection operation.
しかも、試料水分析装置１は、排液作業を実行することで、第二入液モジュール２８（即ち、ポンプＰ３）及び排液モジュール３１（即ち、ポンプＰ８）をオンして、第二入液モジュール２８によって、第一収容空間１１１内に収容された試料水を第二収容空間１３１内に入り込ませ、排液モジュール３１によって、第二収容空間１３１内の試料水を排出することが可能である。このように、本願の第一反応容器１１と第二反応容器１３とは、試料水の排出操作を同期に実行することができる。 Moreover, the sample water analyzer 1 turns on the second liquid input module 28 (that is, the pump P3) and the drainage module 31 (that is, the pump P8) by executing the drainage work, and the second liquid input module 1 is turned on. The module 28 allows the sample water contained in the first accommodation space 111 to enter the second accommodation space 131, and the drainage module 31 allows the sample water contained in the second accommodation space 131 to be discharged. .. As described above, the first reaction vessel 11 and the second reaction vessel 13 of the present application can simultaneously execute the sample water discharge operation.
好ましくは、試料水分析装置１は、標準試料水供給モジュール３２を更に含んでもよい。図１に示すように、標準試料水供給モジュール３２が、それぞれ弁体Ｖ９及びＶ１０を介して第一、第二反応容器１１、１３へ第一標準試料水及び第二標準試料水を供給することが可能である。これにより、試料水分析計１４は、上述した標準試料水の析出気体を分析することで、標準試料水の分析結果を得て、標準試料水の分析結果に基づいて、実際に採集された試料水中の揮発性有機物及び不揮発性有機物の含有量を分析することができる。 Preferably, the sample water analyzer 1 may further include a standard sample water supply module 32. As shown in FIG. 1, the standard sample water supply module 32 supplies the first standard sample water and the second standard sample water to the first and second reaction vessels 11 and 13 via the valve bodies V9 and V10, respectively. Is possible. As a result, the sample water analyzer 14 obtains the analysis result of the standard sample water by analyzing the precipitated gas of the standard sample water described above, and the sample actually collected based on the analysis result of the standard sample water. The contents of volatile and non-volatile organic substances in water can be analyzed.
好ましくは、試料水分析装置１は、上述した標準試料水の分析結果に基づいて、現在の試料水分析計１４の測定結果が不正確であるかを判断するための較正モジュール３３を更に含んでもよい。試料水分析計１４の測定結果が不正確であると判断した場合、較正モジュール３３は、試料水中の全有機炭素の含有量の分析結果の正確性を向上させるために、標準試料水の分析結果に基づいて、試料水分析計１４により出力された測定結果を較正してもよい。 Preferably, the sample water analyzer 1 may further include a calibration module 33 for determining whether the measurement result of the current sample water analyzer 14 is inaccurate based on the analysis result of the standard sample water described above. Good. If it is determined that the measurement result of the sample water analyzer 14 is inaccurate, the calibration module 33 analyzes the standard sample water in order to improve the accuracy of the analysis result of the total organic carbon content in the sample water. The measurement result output by the sample water analyzer 14 may be calibrated based on the above.
それに、試料水分析装置１は、試料水分析計１４内の余分のオゾンを吸收して、酸素に転化してから排出し、大気汚染を防ぐための排ガス処理器３４を更に含む。 In addition, the sample water analyzer 1 further includes an exhaust gas treatment device 34 for absorbing excess ozone in the sample water analyzer 14, converting it into oxygen and then discharging it to prevent air pollution.
以上を纏めると、本願の試料水分析装置は、第一反応容器及び第二反応容器を設けることで、試料水中の揮発性有機物及び不揮発性有機物をそれぞれ検出しているため、現有技術に比べて、本願は、換算という方式ではなく、直接測定という方式で試料水中の揮発性有機物の含有量を分析することにより、試料水中の揮発性有機物の含有量の分析結果をｐｐｂレベルまで向上させることができる。 Summarizing the above, the sample water analyzer of the present application detects volatile organic compounds and non-volatile organic compounds in the sample water by providing the first reaction vessel and the second reaction vessel, respectively, and therefore, compared with the existing technology. In the present application, the analysis result of the content of volatile organic compounds in the sample water can be improved to the ppb level by analyzing the content of volatile organic compounds in the sample water by the method of direct measurement instead of the method of conversion. it can.
しかも、上述した第一、第二反応容器は、同一タイミングで試料水を採集することができるため、試料水中の全有機炭素の含有量の分析結果の精確さ及び正確性が効果的に向上する。また、上述した第一、第二反応容器は、同一タイミングで分析作業をそれぞれ行うことができるため、試料水の分析効率が向上する。 Moreover, since the sample water can be collected at the same timing in the above-mentioned first and second reaction vessels, the accuracy and accuracy of the analysis result of the total organic carbon content in the sample water are effectively improved. .. Further, since the above-mentioned first and second reaction vessels can perform the analysis work at the same timing, the analysis efficiency of the sample water is improved.
更に、本願の試料水分析装置は、標準試料水供給モジュール及び較正モジュールを設けることで、試料水分析計の現在の検出結果が不正確であるかを判断した上で較正することができるため、試料水の分析結果の正確性が向上する。 Further, the sample water analyzer of the present application can be calibrated after determining whether the current detection result of the sample water analyzer is inaccurate by providing the standard sample water supply module and the calibration module. The accuracy of the analysis result of the sample water is improved.
上記実施例は、本願の原理及び効果を例示的に説明するものに過ぎず、本願を制限するものではない。当業者であれば、本願の趣旨及び範囲内で上記実施例に修飾及び変更を加えることができる。したがって、本願の保護範囲は、本願の特許請求の範囲に従うべきである。 The above embodiment merely exemplifies the principles and effects of the present application, and does not limit the present application. Those skilled in the art can modify and modify the above embodiments within the spirit and scope of the present application. Therefore, the scope of protection of the present application should be in accordance with the scope of claims of the present application.
１：試料水分析装置
１１：第一反応容器
１１１：第一収容空間
１２：酸化反応モジュール
１３：第二反応容器
１３１：第二収容空間
１４：試料水分析計
１５：オゾン供給モジュール
１６：第一酸素供給手段
１８：酸性剤供給手段
１９：酸化剤供給手段
２０：第二酸素供給手段
２１：第三酸素供給手段
２２：ＵＶ光供給手段
２５：第一入液モジュール
２６：第一過量排液モジュール
２７：第一定量排液モジュール
２８：第二入液モジュール
２９：第二過量排液モジュール
３０：第二定量排液モジュール
３１：排液モジュール
３２：標準試料水供給モジュール
３３：較正モジュール
３４：排ガス処理器
３５：第一実行手段
３６：第二実行手段
Ｖ：弁体
Ｐ：ポンプ
1: Sample water analyzer 11: First reaction vessel 111: First storage space 12: Oxidization reaction module 13: Second reaction vessel 131: Second storage space 14: Sample water analyzer 15: Ozone supply module 16: First Ozone supply means 18: Acidizer supply means 19: Oxidizing agent supply means 20: Second oxygen supply means 21: Third oxygen supply means 22: UV light supply means 25: First liquid inlet module 26: First excess drainage module 27: First quantitative drainage module 28: Second inlet module 29: Second excess drainage module 30: Second quantitative drainage module 31: Drainage module 32: Standard sample water supply module 33: Calibration module 34: Exhaust gas treatment device 35: First execution means 36: Second execution means V: Valve body P: Pump
Claims (8)
第一定量の試料水を収容するための第一収容空間を有し、該試料水から揮発性有機物を析出させて送り出す第一反応容器と、
該第一反応容器から送り出された該揮発性有機物を酸化させて、第一酸化生成物を生成して送り出す酸化反応モジュールと、
第二定量の試料水を収容するための第二収容空間を有し、該試料水から不揮発性有機物を析出させ、該不揮発性有機物を酸化させて第二酸化生成物を生成して送り出す第二反応容器と、
該試料水中の該揮発性有機物及び該不揮発性有機物の含有量が分析されるように、該第一酸化生成物及び該第二酸化生成物をそれぞれ受け取って測定し、該第一酸化生成物及び該第二酸化生成物の測定結果を出力する試料水分析計と、を含み、
該酸化反応モジュール及び該第二反応容器に選択的に連通し、該酸化反応モジュール及び該第二反応容器にオゾンをそれぞれ供給するためのオゾン供給モジュールを更に含み、
該第二収容空間に連通し、酸性剤を供給するための酸性剤供給手段と、
該第二収容空間に連通し、酸化剤を供給するための酸化剤供給手段と、
該第二収容空間に連通し、第一流量の酸素を供給するための第二酸素供給手段と、
該第二収容空間に連通し、第二流量の酸素を供給するための第三酸素供給手段と、
該第二収容空間に連通し、ＵＶ光を供給するためのＵＶ光供給手段と、
全無機炭素析出作業及び不揮発性有機物酸化作業を順番に実行する第二実行手段と、を含み、
該第二実行手段による全無機炭素析出作業の実行時には、該試料水中の全無機炭素を析出させるために、該第二収容空間へ該酸性剤を該酸性剤供給手段に供給させるとともに、該第二収容空間へ該第一流量の酸素を該第二酸素供給手段に供給させ、
該第二実行手段による該不揮発性有機物酸化作業の実行時には、該試料水中の該第二酸化生成物を析出させて送り出すために、該第二収容空間へ該オゾンを該オゾン供給モジュールに供給させ、更に該第二収容空間へ該酸化剤を該酸化剤供給手段に供給させ、その後、該オゾンと該酸化剤とが混合された該試料水を、該第二収容空間と該ＵＶ光供給手段との間で循環流動させることで、該試料水中の該不揮発性有機物を酸化させて該第二酸化生成物を生成し、次いで、該第二収容空間へ該第一流量よりも小さくなる該第二流量の酸素を該第三酸素供給手段に供給させる試料水分析装置。 A sample water analyzer for analyzing the total organic carbon content in sample water.
A first reaction vessel having a first storage space for storing a first fixed amount of sample water and precipitating and sending out volatile organic compounds from the sample water.
An oxidation reaction module that oxidizes the volatile organic compounds delivered from the first reaction vessel to generate and deliver the first oxidation product.
A second reaction having a second accommodating space for accommodating a second amount of sample water, precipitating a non-volatile organic substance from the sample water, oxidizing the non-volatile organic substance to produce a second dioxide product, and sending it out. With the container
The first oxidation product and the first dioxide product are received and measured so that the contents of the volatile organic compound and the non-volatile organic matter in the sample water are analyzed, and the first oxidation product and the first oxidation product are measured. a sample water analyzer for outputting a measurement result of the second oxidation product, only including,
It further comprises an ozone supply module for selectively communicating with the oxidation reaction module and the second reaction vessel and supplying ozone to the oxidation reaction module and the second reaction vessel, respectively.
An acid agent supply means for supplying the acid agent through the second storage space,
An oxidant supply means for supplying an oxidant through the second storage space,
A second oxygen supply means for supplying a first flow rate of oxygen through the second accommodation space,
A third oxygen supply means for supplying a second flow rate of oxygen through the second accommodation space,
A UV light supply means for supplying UV light through the second accommodation space,
Includes a second method of sequentially performing the all-inorganic carbon precipitation operation and the non-volatile organic matter oxidation operation.
At the time of executing the all-inorganic carbon precipitation operation by the second executing means, the acidic agent is supplied to the second accommodating space to the acidic agent supply means in order to precipitate the total inorganic carbon in the sample water, and the second performing means is used. (Ii) The first flow rate of oxygen is supplied to the accommodation space by the second oxygen supply means.
When the non-volatile organic substance oxidation work is performed by the second execution means, the ozone is supplied to the ozone supply module to the second storage space in order to precipitate and send out the second dioxide product in the sample water. Further, the oxidant is supplied to the second storage space by the oxidant supply means, and then the sample water in which the ozone and the oxidant are mixed is used in the second storage space and the UV light supply means. By circulating and flowing between the samples, the non-volatile organic matter in the sample water is oxidized to produce the ozone product, and then the second flow rate is smaller than the first flow rate in the second storage space. A sample water analyzer that supplies the oxygen of the above to the third oxygen supply means .
揮発性有機物析出作業を実行する第一実行手段を、更に含み、
該第一実行手段による該揮発性有機物析出作業の実行時には、該試料水中の該揮発性有機物を析出させて送り出すために、該第一収容空間へ該酸素を該第一酸素供給手段に供給させる
請求項１に記載の試料水分析装置。 A primary oxygen supply means for supplying oxygen to the first accommodation space,
Further including a first action means for carrying out the volatile organic compound precipitation operation,
When the volatile organic compound precipitation operation is performed by the first execution means, the oxygen is supplied to the first oxygen supply means to the first accommodation space in order to precipitate and send out the volatile organic compounds in the sample water. The sample water analyzer according to claim 1 .
該酸化反応モジュールへ該オゾンを該オゾン供給モジュールに供給させるとともに、該オゾンと、該第一反応容器から送り出された該揮発性有機物とを該スクリュー管内で酸化反応させて該第一酸化生成物を生成する
請求項２に記載の試料水分析装置。 The oxidation reaction module includes a screw tube.
The ozone is supplied to the ozone supply module to the oxidation reaction module, and the ozone and the volatile organic compound delivered from the first reaction vessel are oxidized in the screw tube to cause the first oxidation product. The sample water analyzer according to claim 2 .
請求項２に記載の試料水分析装置。 The primary oxygen supply means further communicates with the ozone supply module for supplying the oxygen to the ozone supply module so that the ozone supply module reacts with the oxygen to generate the ozone. The sample water analyzer according to claim 2 .
該第二実行手段による該揮発性有機物析出作業の実行時には、該試料水中の該揮発性有機物を析出させるために、該第二収容空間へ該第一流量の酸素を該第二酸素供給手段に供給させる
請求項１に記載の試料水分析装置。 The second execution means further carries out the volatile organic compound precipitation operation.
When the volatile organic compound precipitation operation is performed by the second execution means, the first flow rate of oxygen is supplied to the second oxygen supply means to the second storage space in order to precipitate the volatile organic compounds in the sample water. water sample analyzer according to claim 1 in which the supplied.
該第一収容空間に連通し、該第一収容空間内の過量の該試料水を排出するための第一過量排液モジュールと、
該第一収容空間に連通し、該第一収容空間に該第一定量の該試料水が収容されるように、該第一収容空間内の一部の該試料水を排出するための第一定量排液モジュールと、
該試料水が該第一収容空間を経由して該第二収容空間に入り込むように、該第一収容空間の底部及び該第二反応容器の該第二収容空間にそれぞれ連通する第二入液モジュールと、
該第二収容空間に連通し、該第二収容空間内の過量の該試料水を排出するための第二過量排液モジュールと、
該第二収容空間に連通し、該第二収容空間に該第二定量の該試料水が収容されるように、該第二収容空間内の一部の該試料水を排出するための第二定量排液モジュールと、
該第二収容空間の底部に連通し、該第二収容空間内の該試料水を排出するための排液モジュールと、を含み、
入液作業の実行時には、該第一入液モジュール、該第二入液モジュール、該第一過量排液モジュール、及び、該第二過量排液モジュールをオンして、該第一入液モジュールによって、該第一収容空間へ該試料水を送るとともに、該第二入液モジュールによって、該試料水を、該第一収容空間を経由して該第二収容空間内に入り込ませ、該第一収容空間内の過量の該試料水が該第一過量排液モジュールによって排出され、且つ該第二収容空間内の過量の該試料水が該第二過量排液モジュールによって排出されると、該第一入液モジュール及び該第二入液モジュールをオフし、その後、該第一収容空間に該第一定量の該試料水が収容され、且つ該第二収容空間に該第二定量の該試料水が収容されるように、該第一定量排液モジュール及び該第二定量排液モジュールをオンして、該第一収容空間内の過量の該試料水及び該第二収容空間内の過量の該試料水をそれぞれ排出し、
排液作業の実行時には、該第二入液モジュール及び該排液モジュールをオンして、該第二入液モジュールによって、該第一収容空間内に収容された該試料水を該第二収容空間内に入り込ませるとともに、該排液モジュールによって、該第二収容空間内の該試料水を排出する
請求項１に記載の試料水分析装置。 A first liquid input module for communicating with the first storage space of the first reaction vessel and feeding the sample water into the first storage space,
A first excess drainage module for communicating with the first accommodation space and discharging an excess amount of the sample water in the first accommodation space,
A second unit for discharging a part of the sample water in the first storage space so as to communicate with the first storage space and store the first fixed amount of the sample water in the first storage space. With a fixed amount of drainage module,
A second liquid inlet communicating with the bottom of the first storage space and the second storage space of the second reaction vessel so that the sample water enters the second storage space via the first storage space. Module and
A second excess drainage module for communicating with the second accommodation space and discharging an excess amount of the sample water in the second accommodation space,
A second for discharging a part of the sample water in the second storage space so as to communicate with the second storage space and store the second fixed amount of the sample water in the second storage space. Quantitative drainage module and
Includes a drainage module that communicates with the bottom of the second containment space and drains the sample water in the second containment space.
At the time of executing the liquid filling operation, the first liquid filling module, the second liquid filling module, the first excess liquid draining module, and the second excess liquid draining module are turned on, and the first liquid filling module is used. The sample water is sent to the first storage space, and the sample water is allowed to enter the second storage space via the first storage space by the second liquid input module, and the first storage is performed. When the excess amount of the sample water in the space is discharged by the first excess drainage module and the excess amount of the sample water in the second storage space is discharged by the second excess drainage module, the first The liquid entry module and the second liquid input module are turned off, and then the first amount of the sample water is contained in the first storage space, and the second amount of the sample water is contained in the second storage space. The first quantitative effluent module and the second quantitative effluent module are turned on so that the excess amount of the sample water in the first accommodation space and the excess amount in the second accommodation space are contained. Each of the sample waters is discharged,
At the time of executing the drainage work, the second liquid input module and the drainage module are turned on, and the sample water contained in the first storage space by the second liquid input module is transferred to the second storage space. The sample water analyzer according to claim 1, wherein the sample water in the second accommodating space is discharged by the drainage module while allowing the sample water to enter the inside.
請求項１に記載の試料水分析装置。 The first reaction vessel and the standard sample water supply module for supplying the standard sample water to the second reaction vessel are further included, and the precipitated gas of the standard sample water is analyzed by the sample water analyzer, and the standard sample water is analyzed. The sample water analyzer according to claim 1, wherein the content of the volatile organic substance and the non-volatile organic substance in the sample water is analyzed based on the analysis result of.
請求項７に記載の試料水分析装置。 Based on the analysis result of the standard sample water, it is determined whether the sample water analyzer is inaccurate, and if the sample water analyzer is inaccurate, the sample water analyzer is based on the analysis result of the standard sample water. The sample water analyzer according to claim 7 , further comprising a calibration module for calibrating the sample water analyzer.
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