JP6743558B2 - Boiler chemical cleaning method - Google Patents

Boiler chemical cleaning method Download PDF

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JP6743558B2
JP6743558B2 JP2016151335A JP2016151335A JP6743558B2 JP 6743558 B2 JP6743558 B2 JP 6743558B2 JP 2016151335 A JP2016151335 A JP 2016151335A JP 2016151335 A JP2016151335 A JP 2016151335A JP 6743558 B2 JP6743558 B2 JP 6743558B2
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cleaning liquid
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達也 白石
達也 白石
建太 中安
建太 中安
眞一郎 梶田
眞一郎 梶田
勉 平岩
勉 平岩
等 大澤
等 大澤
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Kurita Engineering Co Ltd
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本発明はボイラの化学洗浄方法に係り、特に洗浄液を加温するボイラの化学洗浄方法に関する。 The present invention relates to a chemical cleaning method for a boiler, and more particularly to a chemical cleaning method for a boiler that heats a cleaning liquid.

ボイラの蒸発管の内面には長年の運転に伴って酸化鉄スケールが成長し、熱効率を悪化させる要因となっている。そのため定期的な化学洗浄によりスケールの溶解除去が行われており、この化学洗浄時に洗浄液温度を保持または上昇させる必要がある(特許文献1)。 Iron oxide scale grows on the inner surface of the evaporation tube of the boiler over many years, which is a factor that deteriorates the thermal efficiency. Therefore, the scale is dissolved and removed by periodic chemical cleaning, and it is necessary to maintain or raise the temperature of the cleaning liquid during this chemical cleaning (Patent Document 1).

特許文献1には、洗浄液に蒸気を吹き込んで加温することが記載されている(0013段落)。 Patent Document 1 describes that steam is blown into the cleaning liquid to heat it (paragraph 0013).

特開平11−141804号公報JP, 11-141804, A

洗浄液に蒸気を注入することによる直接加温方式による昇温および温度保持では、蒸気注入により下記の課題が生じていた。
(1) 蒸気ドレンによる洗浄液の希釈が発生し、スケール溶解能力が低下する。
(2) 洗浄液の希釈分を考慮して洗浄液濃度を高目に設定すると、洗浄薬品量が増加する。
(3) 薬品量が増加すると、排水処理への負担が増加する。
In the temperature rise and temperature maintenance by the direct heating method by injecting steam into the cleaning liquid, the following problems were caused by steam injection.
(1) Dilution of the cleaning liquid by steam drain occurs, and the scale dissolving ability decreases.
(2) If the concentration of the cleaning liquid is set to a high value in consideration of the diluted amount of the cleaning liquid, the amount of cleaning chemicals increases.
(3) When the amount of chemicals increases, the burden on wastewater treatment increases.

本発明は、ボイラの洗浄液を蒸気の注入のみで行うのではなく、加温の少なくとも一部を蒸気式熱交換器によって行うことにより上記の課題を解決したボイラの化学洗浄方法を提供することを目的とする。 The present invention provides a chemical cleaning method for a boiler that solves the above-mentioned problems by performing at least a part of heating with a steam heat exchanger, instead of performing only the injection of steam for cleaning the boiler. To aim.

本発明のボイラの化学洗浄方法は、ボイラ蒸発管に洗浄液を通水して洗浄するボイラの化学洗浄方法であって、該洗浄液を加温するボイラの化学洗浄方法において、洗浄液の加温の少なくとも一部を蒸気式熱交換器により行うことを特徴とする。 A chemical cleaning method for a boiler according to the present invention is a chemical cleaning method for a boiler in which cleaning liquid is passed through a boiler evaporation pipe for cleaning, and in the chemical cleaning method for heating the cleaning liquid, at least heating of the cleaning liquid is performed. It is characterized in that a part is performed by a steam heat exchanger.

本発明の一態様では、洗浄液に蒸気を注入する直接加温と、蒸気式熱交換器を使用した間接加温とを併用して洗浄液を加温する。 In one aspect of the present invention, the cleaning liquid is heated by using both direct heating in which steam is injected into the cleaning liquid and indirect heating using a steam heat exchanger.

本発明の一態様では、ボイラに洗浄水を循環させながら洗浄水に蒸気を注入して洗浄水の水温を所定温度まで上昇させる工程と、その後、洗浄水に洗浄薬品を添加して洗浄液をボイラに循環させると共に、この洗浄液を蒸気式熱交換器により加温する工程とを行う。 In one aspect of the present invention, a step of injecting steam into the cleaning water to raise the temperature of the cleaning water to a predetermined temperature while circulating the cleaning water in the boiler, and then adding a cleaning chemical to the cleaning water to supply the cleaning liquid to the boiler. And the step of heating the cleaning liquid with a steam heat exchanger.

本発明のボイラの化学洗浄方法では、洗浄液温度の保持または上昇のための加温の少なくとも一部に蒸気式熱交換器を用いる。これにより、洗浄液加温の際に蒸気を注入することによる洗浄液の希釈を防止又は抑制することができる。 In the method for chemically cleaning a boiler of the present invention, a steam heat exchanger is used for at least a part of heating for maintaining or raising the temperature of the cleaning liquid. This makes it possible to prevent or suppress the dilution of the cleaning liquid due to the injection of steam when the cleaning liquid is heated.

本発明の一態様では、ボイラ洗浄に際しては、作業者はボイラ蒸発管化学洗浄の洗浄液循環系統内に蒸気式熱交換器を組み込み、間接加温可能なように配管を敷設しておく。そして、昇温工程中は洗浄液を蒸気注入により直接加温し、所定の洗浄温度まで昇温する。その後薬品を注入し、化学洗浄工程を行う。この化学洗浄工程では、洗浄液温度を保持するために蒸気式熱交換器による間接加温を行う。 According to one aspect of the present invention, when cleaning a boiler, an operator installs a steam heat exchanger in a cleaning liquid circulation system for chemical cleaning of a boiler evaporation pipe, and lays piping so as to allow indirect heating. Then, during the temperature raising step, the cleaning liquid is directly heated by steam injection to raise the temperature to a predetermined cleaning temperature. Then, a chemical is injected and a chemical cleaning process is performed. In this chemical cleaning step, indirect heating by a steam heat exchanger is performed in order to maintain the cleaning liquid temperature.

このようにすれば、所定温度までの昇温を蒸気注入による直接加熱により短時間で行うことができる。その後、洗浄薬品を添加すると共に、蒸気式熱交換器による間接加温を行ってボイラを化学洗浄する。この場合、洗浄薬品を添加した後は蒸気を注入しないので、蒸気ドレンによる洗浄液の希釈が発生せず、洗浄液のスケール溶解能力が低下しない。 By doing so, the temperature can be raised to the predetermined temperature in a short time by direct heating by steam injection. Then, a cleaning chemical is added, and the boiler is chemically cleaned by performing indirect heating with a steam heat exchanger. In this case, since the steam is not injected after the cleaning chemical is added, the cleaning liquid is not diluted by the steam drain, and the scale dissolving ability of the cleaning liquid does not decrease.

また、洗浄液の希釈が生じないので、洗浄薬品濃度を高目に設定することが不要であり、洗浄薬品量の増加が防止される。また、排水処理の負荷も増加しない。 Further, since the cleaning liquid is not diluted, it is not necessary to set the cleaning chemical concentration to a high value, and the increase of the cleaning chemical amount can be prevented. In addition, the load of wastewater treatment does not increase.

本発明のボイラの化学洗浄方法を示す概略系統図である。It is a schematic system diagram which shows the chemical cleaning method of the boiler of this invention.

以下、図1を参照して実施の形態について説明する。 Hereinafter, an embodiment will be described with reference to FIG.

ボイラ1の蒸発管を化学洗浄するために、循環ポンプ2、循環送り配管3、循環戻り配管4、蒸気式熱交換器5及び循環戻り配管6よりなる循環ラインがボイラ1の蒸発管に接続されている。 In order to chemically clean the evaporation pipe of the boiler 1, a circulation line consisting of a circulation pump 2, a circulation feed pipe 3, a circulation return pipe 4, a steam heat exchanger 5 and a circulation return pipe 6 is connected to the evaporation pipe of the boiler 1. ing.

循環送り配管3には、洗浄薬品又は純水の注入配管14がバルブVを介して接続されている。 A cleaning chemical or pure water injection pipe 14 is connected to the circulation feed pipe 3 via a valve V 1 .

蒸気式熱交換器5を迂回して配管4,6を接続するように配管7、ミキシングヒータ8及び配管9よりなるバイパスラインが設けられている。配管4、蒸気式熱交換器5及び配管6の流れと、これを迂回するバイパス流れとを切り替えるために、配管4,6,7,9にそれぞれバルブV〜Vが設けられている。 A bypass line including a pipe 7, a mixing heater 8 and a pipe 9 is provided so as to bypass the steam heat exchanger 5 and connect the pipes 4 and 6. Valves V 2 to V 5 are provided in the pipes 4, 6, 7 and 9 respectively to switch the flow of the pipe 4, the steam heat exchanger 5 and the pipe 6 and the bypass flow bypassing the flow.

蒸気式熱交換器5は洗浄液を間接加温するためのものであり、ミキシングヒータ8は洗浄液を蒸気で直接に加温するためのものである。 The steam heat exchanger 5 is for indirectly heating the cleaning liquid, and the mixing heater 8 is for directly heating the cleaning liquid with steam.

蒸気源(例えば小型ボイラ)に連なる配管10からの蒸気が、バルブV、配管11を介してミキシングヒータ8に注入可能とされていると共に、バルブV、配管12を介して蒸気式熱交換器5の熱源流体側に導入可能とされている。蒸気式熱交換器5からのドレンは配管13を介して排水される。 The steam from the pipe 10 connected to the steam source (for example, a small boiler) can be injected into the mixing heater 8 via the valve V 6 and the pipe 11, and the steam heat exchange via the valve V 7 and the pipe 12. It can be introduced to the heat source fluid side of the container 5. The drain from the steam heat exchanger 5 is drained through the pipe 13.

循環戻り配管6には、バルブVを備えた洗浄廃液排出用配管15が接続されている。 To the circulation return pipe 6, a cleaning waste liquid discharge pipe 15 having a valve V 8 is connected.

本発明の第1態様では、洗浄液は間接加温のみによって加温される。この場合、バイパス用のバルブV,Vとミキシングヒータ8への蒸気供給用バルブVは閉とされる。また、バルブVも閉とされる。 In the first aspect of the present invention, the cleaning liquid is heated only by indirect heating. In this case, the valves V 4 and V 5 for bypass and the valve V 6 for supplying steam to the mixing heater 8 are closed. The valve V 8 is also closed.

洗浄液が配管14,3を介してボイラ1に供給される。十分な量の洗浄液が供給された後、バルブVを閉とし、循環ポンプ2を始動して洗浄液を循環させると共に、バルブVを開いて蒸気式熱交換器5に蒸気を供給し、洗浄液を加温する。洗浄液の温度が所定温度まで上昇した後は、蒸気式熱交換器5への蒸気供給量を制御し、洗浄液温度を所定温度に維持する。所定の洗浄時間が経過した後、バルブVを開とし、洗浄液を配管15を介して排出する。その後、バルブVを開とし、配管14,3を介してボイラ1に純水を供給し、残留する洗浄液やスケールを押し出す。 The cleaning liquid is supplied to the boiler 1 via the pipes 14 and 3. After a sufficient amount of the cleaning liquid is supplied, the valve V 1 is closed, the circulation pump 2 is started to circulate the cleaning liquid, and the valve V 7 is opened to supply the steam to the steam heat exchanger 5 to supply the cleaning liquid. To warm. After the temperature of the cleaning liquid has risen to a predetermined temperature, the amount of steam supplied to the steam heat exchanger 5 is controlled to maintain the cleaning liquid temperature at the predetermined temperature. After the lapse of a predetermined cleaning time, the valve V 8 is opened and the cleaning liquid is discharged through the pipe 15. Then, the valve V 1 is opened, pure water is supplied to the boiler 1 through the pipes 14 and 3, and the remaining cleaning liquid and scale are pushed out.

この第1態様では、蒸気の直接注入を行わないので、蒸気注入による振動や騒音が発生しない。また、蒸気ドレン生成に伴う洗浄液の一部ブローが不要であり、作業負担が軽減される。 In this first mode, since steam is not directly injected, vibration and noise due to steam injection do not occur. Further, it is not necessary to partially blow the cleaning liquid due to the vapor drain generation, and the work load is reduced.

本発明の第2態様では、洗浄液は直接加熱と間接加温とによって加温される。直接加熱の場合、洗浄液を、配管3、ボイラ1、配管4,7、ミキシングヒータ8、配管9,6、循環ポンプ2のループを循環させる。ミキシングヒータ8に蒸気が注入されるため、洗浄水は急速に加温される。なお、必要に応じ、バルブVを開き、蒸気ドレン水量に見合った水量を配管15から排出する。間接加熱の場合、バイパス用のバルブV,Vとミキシングヒータ8への蒸気供給用バルブVは閉とされる。バルブVも閉とされる。また、バルブV,V,Vを開とする。これにより、蒸気式熱交換器5に配管10,12を介して蒸気が供給され、循環洗浄液が所定の温度に保持される。その他は、第1態様と同様である。 In the second aspect of the present invention, the cleaning liquid is heated by direct heating and indirect heating. In the case of direct heating, the cleaning liquid is circulated through the loop of the pipe 3, the boiler 1, the pipes 4 and 7, the mixing heater 8, the pipes 9 and 6, and the circulation pump 2. Since the steam is injected into the mixing heater 8, the cleaning water is rapidly heated. If necessary, the valve V 8 is opened and the amount of water commensurate with the amount of steam drain water is discharged from the pipe 15. In the case of indirect heating, the bypass valves V 4 and V 5 and the vapor supply valve V 6 to the mixing heater 8 are closed. The valve V 8 is also closed. Further, the valves V 2 , V 3 and V 7 are opened. As a result, steam is supplied to the steam heat exchanger 5 through the pipes 10 and 12, and the circulating cleaning liquid is maintained at a predetermined temperature. Others are the same as the first aspect.

本発明の第3態様では、まず洗浄薬品を含まない洗浄水(例えば純水)で循環ラインを構成する配管3、4、6、循環ポンプ2、及び蒸気式熱交換器5と、バイパスラインを構成する配管7,9及びミキシングヒータ8とをそれぞれ満たしておく。 In the third aspect of the present invention, first, the pipes 3, 4, and 6, the circulation pump 2, the steam heat exchanger 5, and the bypass line, which form a circulation line with cleaning water containing no cleaning chemical (for example, pure water). The constituent pipes 7 and 9 and the mixing heater 8 are respectively filled.

そして、バルブV,V,V,V,Vを閉とし、バルブVを開とし、循環ポンプ2を作動させ、洗浄水を配管3、ボイラ1、配管4,7、ミキシングヒータ8、配管9,6、循環ポンプ2のループを循環させる。ミキシングヒータ8には蒸気が注入されるため、洗浄水は急速に加温される。なお、必要に応じ、バルブVを開き、蒸気ドレン水量に見合った水量を配管15から排出する。 Then, the valves V 1 , V 2 , V 3 , V 7 , and V 8 are closed, the valve V 6 is opened, the circulation pump 2 is operated, and cleaning water is supplied to the pipe 3, the boiler 1, the pipes 4, 7, and mixing. The heater 8, the pipes 9 and 6, and the loop of the circulation pump 2 are circulated. Since steam is injected into the mixing heater 8, the cleaning water is rapidly heated. If necessary, the valve V 8 is opened and the amount of water commensurate with the amount of steam drain water is discharged from the pipe 15.

水温が所定の化学洗浄温度にまで上昇したならば、バルブV,V,Vを閉、バルブV,V,Vを開とする。また、配管14から洗浄薬品を注入する。これにより、洗浄薬品が溶解した洗浄液がボイラ1に循環通水され、ボイラ1の化学洗浄が行われる。この間、蒸気式熱交換器5に配管10,12を介して蒸気が供給され、循環洗浄液が所定の温度に保持される。 If the water temperature rises to a predetermined chemical cleaning temperature, the valve V 4, V 5, V 6 closed, and the valves V 2, V 3, V 7 opens. Further, a cleaning chemical is injected from the pipe 14. As a result, the cleaning liquid in which the cleaning chemicals are dissolved is circulated through the boiler 1, and the boiler 1 is chemically cleaned. During this time, steam is supplied to the steam heat exchanger 5 through the pipes 10 and 12, and the circulating cleaning liquid is maintained at a predetermined temperature.

所定時間この化学洗浄を行った後、上記第1態様と同様に、バルブVを開とし、洗浄液を配管15を介して排出する。その後、バルブVを開とし、配管14,3を介してボイラ1に純水を供給し、残留する洗浄液やスケールを押し出す。 After performing this chemical cleaning for a predetermined time, the valve V 8 is opened and the cleaning liquid is discharged through the pipe 15 as in the first embodiment. Then, the valve V 1 is opened, pure water is supplied to the boiler 1 through the pipes 14 and 3, and the remaining cleaning liquid and scale are pushed out.

第2及び第3態様でも、蒸気の直接注入が従来に比べて短時間であるので、蒸気注入による振動や騒音が軽減される。また、蒸気ドレン生成に伴う洗浄液の一部ブローが少なく、作業負担が軽減される。 Also in the second and third aspects, since the direct injection of steam is shorter than that in the conventional case, vibration and noise due to the injection of steam are reduced. Further, a part of the cleaning liquid is not blown due to the generation of steam drain, and the work load is reduced.

以下に実施例1,2を挙げて本発明の効果をより具体的に説明する。 Hereinafter, the effects of the present invention will be described more specifically with reference to Examples 1 and 2.

[実施例1]
実施例1はボイラ化学洗浄を上記第1態様によって実施した例である。洗浄液量は55mであり、蒸気式熱交換器は伝熱面積15mであり、洗浄温度は85℃とした。本発明の適用により、従来工法では蒸気による洗浄液の希釈が薬品濃度として0.6%発生したのに対し、この実施例1では蒸気を直接洗浄液へ封入しないため昇温による希釈はなかった。また、洗浄液の初期温度30℃から85℃まで4時間で昇温することが可能であった。その後の洗浄時間は6時間とした。
[Example 1]
Example 1 is an example in which chemical cleaning of a boiler is performed according to the first aspect. The amount of cleaning liquid was 55 m 3 , the heat transfer area of the steam heat exchanger was 15 m 2 , and the cleaning temperature was 85°C. By the application of the present invention, in the conventional method, the cleaning liquid was diluted with steam at a chemical concentration of 0.6%, whereas in Example 1, the steam was not directly enclosed in the cleaning liquid, so that there was no dilution by temperature rise. Further, it was possible to raise the initial temperature of the cleaning liquid from 30° C. to 85° C. in 4 hours. The subsequent cleaning time was 6 hours.

さらに加えて、当該ボイラで従来工法では問題となっていた騒音・振動問題が本発明工法を適用することにより解消された。 In addition, the problem of noise and vibration, which had been a problem in the conventional construction method for the boiler, was solved by applying the construction method of the present invention.

[実施例2]
実施例2は、上記第3態様によってボイラを化学洗浄した例である。洗浄水を85℃まで昇温させるためにミキシングヒータ8を使用した。この場合、初期温度30℃から85℃までの昇温時間は2.5時間であった。
[Example 2]
Example 2 is an example of chemically cleaning a boiler according to the third aspect. The mixing heater 8 was used to raise the temperature of the washing water to 85°C. In this case, the temperature rising time from the initial temperature of 30° C. to 85° C. was 2.5 hours.

その後、ミキシングヒータ8の使用を停止し、洗浄薬品注入及び蒸気式熱交換器5による洗浄液保温を行い、この洗浄液によるボイラ洗浄を6時間行った。 After that, the use of the mixing heater 8 was stopped, the cleaning chemicals were injected, the temperature of the cleaning liquid was kept warm by the steam heat exchanger 5, and the boiler was cleaned with this cleaning liquid for 6 hours.

この結果、トータルでは実施例1よりも短い8.5時間でボイラ1の化学洗浄が終了した。 As a result, the total chemical cleaning of the boiler 1 was completed in 8.5 hours, which was shorter than that in Example 1.

1 ボイラ
2 循環ポンプ
5 蒸気式熱交換器
8 ミキシングヒータ
1 Boiler 2 Circulation pump 5 Steam heat exchanger 8 Mixing heater

Claims (2)

ボイラ蒸発管に洗浄液を通水して洗浄するボイラの化学洗浄方法であって、該洗浄液を加温するボイラの化学洗浄方法において、洗浄液の加温の少なくとも一部を蒸気式熱交換器により行うボイラの化学洗浄方法であり、
ボイラに洗浄水を循環させながら洗浄水に蒸気を注入して洗浄水の水温を所定温度まで上昇させる工程と、
その後、洗浄水に洗浄薬品を添加して洗浄液をボイラに循環させると共に、この循環洗浄液を蒸気式熱交換器により加温する工程と
を有することを特徴とするボイラの化学洗浄方法。
A chemical cleaning method for a boiler, in which a cleaning liquid is passed through a boiler evaporation pipe for cleaning, wherein at least a part of heating of the cleaning liquid is performed by a steam heat exchanger in the chemical cleaning method for heating the cleaning liquid. A chemical cleaning method for boilers,
Injecting steam into the cleaning water while circulating the cleaning water in the boiler to raise the temperature of the cleaning water to a predetermined temperature;
After that, a cleaning chemical is added to the cleaning water to circulate the cleaning liquid in the boiler, and the circulating cleaning liquid is heated by a steam heat exchanger.
A method for chemically cleaning a boiler, comprising:
請求項1において、洗浄液に蒸気を注入する直接加温と、蒸気式熱交換器を使用した間接加温とを併用して洗浄液を加温することを特徴とするボイラの化学洗浄方法。 The chemical cleaning method for a boiler according to claim 1, wherein the cleaning liquid is heated by using both direct heating for injecting steam into the cleaning liquid and indirect heating using a steam heat exchanger.
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