JP6631990B2 - Fluid oil composition - Google Patents

Fluid oil composition Download PDF

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JP6631990B2
JP6631990B2 JP2013230145A JP2013230145A JP6631990B2 JP 6631990 B2 JP6631990 B2 JP 6631990B2 JP 2013230145 A JP2013230145 A JP 2013230145A JP 2013230145 A JP2013230145 A JP 2013230145A JP 6631990 B2 JP6631990 B2 JP 6631990B2
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JP2015089350A (en
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村田 浩彦
浩彦 村田
祐介 滝波
祐介 滝波
隆太 小中
隆太 小中
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Adeka Corp
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本発明は、低温域〜高温域での広い温度範囲で、安定した流動性と固液分離耐性を有する流動状油脂組成物に関する。   The present invention relates to a fluid fat composition having stable fluidity and solid-liquid separation resistance in a wide temperature range from a low temperature range to a high temperature range.

バタースポンジケーキ等に用いられるケーキ練込用油脂や、大量生産のために機械化されたラインでパンを製造する際に用いられる製パン練込用油脂には、古くから、常温で固形を呈する可塑性油脂組成物ではなく、また液状油でもなく、一定の量の固形脂や乳化剤を液状油や微水添油に分散させた、常温で流動性を呈する流動状油脂組成物(例えば特許文献1、非特許文献1参照)が使用されている。   The fats and oils for kneading cakes used for butter sponge cakes and the fats and oils for kneading bread used when bread is manufactured on a mechanized line for mass production have long been known as plastics that exhibit solids at room temperature. It is not a fat or oil composition, nor a liquid oil, but a fluid oil or fat composition exhibiting fluidity at room temperature, in which a certain amount of solid fat or emulsifier is dispersed in liquid oil or slightly hydrogenated oil (for example, Patent Document 1, Non-Patent Document 1) is used.

また、この流動状油脂組成物は、上記用途以外に、ソフトな食感を有するディップクリーム、シュガークリーム、バタークリーム、焼き残りクリーム等のクリーム状食品練込用油脂としても、広く使用されるようになってきている。   In addition, this fluid oil composition is widely used as a fat and oil for kneading creamy foods such as dip creams, sugar creams, butter creams and unbaked creams having a soft texture in addition to the above uses. It is becoming.

さらに、流動状油脂組成物のその他の用途として、脂肪分の少ない魚肉の赤身部分と混合したり、ピックルするなどの方法で、脂肪分の多いトロ様の魚肉加工食品を製造することも行われている。   Furthermore, as another use of the fluid oil composition, it is also possible to mix a lean portion of a lean fish meat with a lean portion or to pickle it to produce a fat-rich toro-like processed fish meat food. ing.

しかし、この流動状油脂組成物は、普通に固形脂や乳化剤を液状油や微水添油に分散させただけでは、保存条件によっては、経日的に固形脂の油脂結晶が粗大化して、固形脂が沈殿したり、液状油が表面に分離する等して、固液分離を起こし流動状油脂組成物としての機能を失ってしまう。   However, in this fluid oil composition, solid fats and emulsifiers are simply dispersed in liquid oil or slightly hydrogenated oil, depending on storage conditions, fat crystals of the solid fat are coarsened over time, The solid fat precipitates, the liquid oil separates on the surface, and the like, causing solid-liquid separation and losing the function as the fluid fat composition.

さらに、このような固液分離しやすい流動状油脂組成物を用いると、バターケーキ等では、生地製造時の起泡性が悪化することに加え、ケーキ表面に粒状の模様が発生してしまう等の問題を生じ、また、パンでは、練り込まれにくくなることに加え、パンの体積減少、パンが老化しやすい等の問題を生じ、また、特にクリーム状食品では、固液分離に加え、耐熱性の低下、さらには、白色化、食感のざらつきを生じる等の問題があり、魚肉加工食品では魚肉とのなじみが悪く、油脂の染み出しやドリップが発生しやすい等の問題があった。   Furthermore, when such a fluid oil / fat composition that is easily solid-liquid separated is used, in the case of butter cake, etc., in addition to the deterioration of the foaming property at the time of dough production, a granular pattern is generated on the cake surface, etc. In addition, in bread, it becomes difficult to knead the bread, and in addition, the bread volume is reduced and the bread is easily aged. In addition, there are problems such as lowering of properties, whitening, and rough texture, and the processed fish meat has poor compatibility with fish meat, and oil and fat are likely to exude or drip.

このため、固液分離し難い流動状油脂組成物を得るために、様々な改良が行なわれてきた。例えば、異性化水添した油脂と極度硬化油脂とをエステル交換した機能性油脂を配合した油脂組成物(例えば特許文献2参照)、ナタネ微水添油、パーム中融点部及び極度硬化油脂からなる油脂組成物(例えば特許文献3参照)等のトランス脂肪酸の機能を利用した改良が行われてきた。   For this reason, various improvements have been made in order to obtain a fluid oil / fat composition that is difficult to perform solid-liquid separation. For example, it comprises a fat or oil composition (for example, see Patent Document 2) in which a functional fat or oil obtained by transesterifying an isomerized and hydrogenated fat and an extremely hardened fat or oil, a rapeseed slightly hydrogenated oil, a palm middle melting point part, and an extremely hardened fat or oil. Improvements utilizing functions of trans fatty acids, such as oil and fat compositions (for example, see Patent Document 3), have been made.

しかし、特許文献2及び3それぞれに記載の油脂組成物は、固液分離耐性に乏しいことに加え、特許文献2に記載の油脂組成物は、異性化水添とエステル交換とを組み合わせて製造するため、製造方法が煩雑であるという問題があった。また、特許文献3に記載の流動状油脂組成物は、広い温度域では物性の変化がやや大きく、特に低温域(10℃以下)では使用し難いという問題があった。   However, the oil and fat compositions described in Patent Documents 2 and 3 each have poor solid-liquid separation resistance, and the oil and fat compositions described in Patent Document 2 are produced by combining isomerization hydrogenation and transesterification. Therefore, there is a problem that the manufacturing method is complicated. In addition, the fluid oil and fat composition described in Patent Document 3 has a problem that physical properties are slightly changed in a wide temperature range, and particularly difficult to use in a low temperature range (10 ° C. or lower).

また、特許文献2及び3それぞれに記載の油脂組成物は、いずれも1〜12%のトランス脂肪酸を含むものであるが、近年では、実質的にトランス脂肪酸を含まない油脂組成物であって、適切なコンシステンシーを有する流動状油脂組成物が望まれている。   Further, the oil and fat compositions described in Patent Documents 2 and 3 each contain 1 to 12% of trans fatty acid, but in recent years, the oil and fat composition substantially does not contain trans fatty acid, and There is a need for a fluid fat composition having consistency.

そのため、パーム軟部油をエステル交換して得られた油脂を主体とした流動状油脂組成物(例えば特許文献4参照)が提案された。   Therefore, a fluid fat composition mainly comprising a fat obtained by transesterifying palm soft oil (for example, see Patent Document 4) has been proposed.

しかし、特許文献4に記載の油脂組成物は、飽和酸の含量がやや高いため、低温域での十分な流動性を確保するためには該エステル交換油に加えて液状油を多く添加することが必要となり、その場合高温域での保管や使用時に固液分離が発生しやすいという問題があった。   However, since the fat and oil composition described in Patent Document 4 has a slightly high content of saturated acid, in order to ensure sufficient fluidity in a low temperature range, a large amount of liquid oil is added in addition to the transesterified oil. In such a case, there is a problem that solid-liquid separation easily occurs during storage or use in a high temperature range.

そのため、低温域〜高温域での広い温度範囲で、安定した流動性と固液分離耐性を有する流動状油脂組成物が求められていた。   Therefore, a fluid fat composition having stable fluidity and solid-liquid separation resistance in a wide temperature range from a low temperature range to a high temperature range has been demanded.

特開昭59−17937号公報JP-A-59-17937 特開平07−203847号公報JP-A-07-203847 特開昭56−110798号公報JP-A-56-110798 特開2006−115724号公報JP 2006-115724 A

「食用固形油脂」柳原昌一、昭和50年12月15日刊、P262〜272"Edible solid fat" Shoichi Yanagihara, published December 15, 1975, pp. 262 to 272

よって、本発明の目的は、低温域〜高温域での広い温度範囲で安定した流動性と固液分離耐性を有する流動状油脂組成物を提供することにある。
また、本発明のさらなる目的は、ソフトで、口溶けが良好でありながら、耐熱性も良好なクリーム状食品、さらには魚肉に混合またはピックルする際に、魚肉とのなじみがよく、液状油の染み出しやドリップの発生が抑制され、風味が良好な魚肉加工食品を提供することにある。
Therefore, an object of the present invention is to provide a fluid fat composition having stable fluidity and solid-liquid separation resistance in a wide temperature range from a low temperature range to a high temperature range.
Further, a further object of the present invention is a creamy food which is soft, has a good melting property in the mouth, and also has a good heat resistance, and further, when mixed or pickled with fish meat, has good affinity with fish meat, and stains of liquid oil. An object of the present invention is to provide a processed fish meat food having a good flavor, in which the occurrence of drip and drip is suppressed.

本発明者等は、上記目的を達成すべく種々検討した結果、特定のエステル交換油脂を使用することにより、上記目的を解決し得ることを知見し、本発明を完成させた。
即ち、本発明は、下記の(1)〜(3)の全てを満たすエステル交換油脂を油相中に、該油相中の全油脂量基準で50〜100質量%含有し、且つ、該油相のSFCが、10℃で5〜20%であり、20℃で1〜10%であって、該油相を80〜100質量%(組成物基準)含有することを特徴とする流動状油脂組成物、さらには、該流動状油脂組成物を含有することを特徴とするクリーム状食品及び魚肉加工食品を提供するものである。
(1)液状油と極度硬化油をエステル交換したエステル交換油脂である。
(2)SFC(固体脂含量)が、0℃で5〜25%、20℃で1〜5%、40℃で0〜2%である。
(3)30℃において流動状である。
The present inventors have conducted various studies to achieve the above object, and as a result, have found that the above object can be solved by using a specific transesterified fat and oil, and completed the present invention.
That is, the present invention comprises a transesterified oil and fat satisfying all of the following (1) to (3) in an oil phase in an amount of 50 to 100% by mass based on the total amount of the oil and fat in the oil phase. A fluid fat or oil characterized by having an SFC of 5 to 20% at 10 ° C and 1 to 10% at 20 ° C and containing the oil phase in an amount of 80 to 100% by mass (composition basis). It is intended to provide a creamy food and a processed fish meat food characterized by containing the composition, and further, the fluid oil composition.
(1) A transesterified fat obtained by transesterifying a liquid oil and an extremely hardened oil.
(2) SFC (solid fat content) is 5 to 25% at 0 ° C, 1 to 5% at 20 ° C, and 0 to 2% at 40 ° C.
(3) It is fluid at 30 ° C.

本発明によれば、特に液状油を多く配合することなく、またトランス脂肪酸を含有せずとも、高温域で保管時や使用時に経日的に、固形脂が沈殿したり、液状油が表面に分離する等の固液分離を起こすことがなく、低温域〜高温までの広い温度域で安定した流動性を有する流動状油脂組成物を提供することができる。また、該流動状油脂組成物を使用したディップクリーム、シュガークリーム、バタークリーム、焼き残りクリーム等のクリーム状食品は、口溶けが良好でありながら、耐熱性も良好である。さらに、該流動状油脂組成物を使用した魚肉加工食品は、脂肪分の少ないたん白な風味の魚肉を使用していながら風味と食感が改善され、油脂の染み出しやドリップの発生が抑制され、品質価値が向上している。   According to the present invention, particularly without blending a large amount of liquid oil, and even without trans fatty acids, during storage or use at high temperatures over time, solid fat precipitates or liquid oil is deposited on the surface A fluid fat composition having stable fluidity in a wide temperature range from a low temperature to a high temperature without causing solid-liquid separation such as separation can be provided. Further, creamy foods such as dip cream, sugar cream, butter cream, unbaked cream and the like using the fluid oil composition have good mouth melting and good heat resistance. Furthermore, the processed fish meat using the fluid oil composition has improved flavor and texture while using low-fat, protein-flavored fish meat, and suppresses the exudation and drip of oils and fats. , The quality value is improving.

以下、本発明の流動状油脂組成物について、その好ましい実施形態に基づいて詳述する。
先ず、本発明で使用されるエステル交換油脂について述べる。
本発明の流動状油脂組成物に用いられるエステル交換油脂は、上記(1)〜(3)の通り、液状油と極度硬化油をエステル交換し、SFC(固体脂含量)を特定の値とし、30℃における物性を特定の性状としたエステル交換油脂である。
Hereinafter, the fluid fat composition of the present invention will be described in detail based on preferred embodiments.
First, the transesterified fat used in the present invention will be described.
The transesterified fat used in the fluid fat composition of the present invention, as described in (1) to (3) above, transesterifies the liquid oil and the extremely hardened oil, and sets SFC (solid fat content) to a specific value, It is a transesterified oil and fat whose physical properties at 30 ° C. have specific properties.

上記液状油としては、大豆油、菜種油(キャノーラ油)、コーン油、綿実油、オリーブ油、落花生油、米油、べに花油、ハイオレイックサフラワー油、ひまわり油、ハイオレイックひまわり油等の常温(25℃)で液状の油脂が挙げられるが、その他に、パーム油、パーム核油、ヤシ油、シア脂、サル脂、マンゴ脂、乳脂、牛脂、乳脂、豚脂、カカオ脂、魚油、鯨油等の常温で固体の油脂を分別することで得られた軟部油であって、常温で液状である油脂も使用することもできる。また、これらの油脂に対し、水素添加、分別、エステル交換等の物理的又は化学的処理の1種又は2種以上の処理を施した油脂についても、得られる加工油脂が常温で液状である範囲内において使用することもできる。本発明においては、これらの油脂を単独で用いることもでき、又は2種以上を組み合わせて用いることもできる。
本発明では、30℃における流動性の高いエステル交換油脂を得ることが容易であり、得られる油脂組成物の口溶けを良好なものとすることが可能な点から、上記液状油として、大豆油、菜種油(キャノーラ油)、コーン油、綿実油、オリーブ油、落花生油、米油、べに花油、ハイオレイックサフラワー油、ひまわり油、ハイオレイックひまわり油等の常温で液状の油脂のうちの1種又は2種以上を使用することが好ましい。
Examples of the liquid oil include room temperature (25 ° C.) such as soybean oil, rapeseed oil (canola oil), corn oil, cottonseed oil, olive oil, peanut oil, rice oil, beech flower oil, high oleic safflower oil, sunflower oil, and high oleic sunflower oil. ), Liquid oils and fats, and other normal temperatures such as palm oil, palm kernel oil, coconut oil, shea butter, monkey fat, mango fat, milk fat, beef fat, milk fat, lard, cocoa butter, fish oil, whale oil, etc. A soft oil obtained by separating solid fats and oils at room temperature can also be used. The fats and oils obtained by subjecting these fats and oils to one or more physical or chemical treatments such as hydrogenation, fractionation, and transesterification are also in a range in which the obtained processed fats and oils are liquid at room temperature. It can also be used within. In the present invention, these fats and oils can be used alone or in combination of two or more.
In the present invention, it is easy to obtain a transesterified oil and fat having a high fluidity at 30 ° C., and soybean oil, soybean oil, One or two kinds of oils and fats which are liquid at normal temperature such as rapeseed oil (canola oil), corn oil, cottonseed oil, olive oil, peanut oil, rice oil, beech flower oil, high oleic safflower oil, sunflower oil, high oleic sunflower oil, etc. It is preferable to use the above.

上記極度硬化油としては、食用油脂に対し、ヨウ素価が好ましくは5以下、更に好ましくは2以下、最も好ましくは1以下となるまで水素添加することによって得られる水素添加油脂を挙げることができる。水素添加に用いる食用油脂としては、大豆油、菜種油(キャノーラ油)、ハイエルシン菜種油、コーン油、綿実油、オリーブ油、落花生油、米油、べに花油、ハイオレイックサフラワー油、ひまわり油、ハイオレイックひまわり油、ひまわり油、からし油、パーム油、パーム核油、ヤシ油、シア脂、サル脂、マンゴ脂、乳脂、牛脂、乳脂、豚脂、カカオ脂、魚油、鯨油等の食用油脂、また、これらの油脂に対し水素添加、分別、エステル交換等の物理的又は化学的処理の1種又は2種以上の処理を施した油脂を使用することができる。本発明においては、上記水素添加に用いる油脂として、これらの油脂を単独で用いることもでき、又は2種以上を混合した混合油を用いることもできる。
また、上記極度硬化油として、上記のようにして得られた極度硬化油を単独で使用しても2種以上を併用してもよい。
Examples of the extremely hardened oil include hydrogenated oils and fats obtained by hydrogenating edible oils and fats to an iodine value of preferably 5 or less, more preferably 2 or less, and most preferably 1 or less. Edible oils and fats used for hydrogenation include soybean oil, rapeseed oil (canola oil), hayesin rapeseed oil, corn oil, cottonseed oil, olive oil, peanut oil, rice oil, beniflower oil, high oleic safflower oil, sunflower oil, high oleic sunflower oil Edible oils such as sunflower oil, mustard oil, palm oil, palm kernel oil, coconut oil, shea butter, monkey fat, mango fat, milk fat, beef fat, milk fat, lard, cocoa butter, fish oil, whale oil, etc. The fats and oils which have been subjected to one or more kinds of physical or chemical treatments such as hydrogenation, fractionation, transesterification and the like can be used. In the present invention, these fats and oils can be used alone or as a mixture of two or more kinds as the fats and oils used for the hydrogenation.
Further, as the extremely hardened oil, the extremely hardened oil obtained as described above may be used alone or in combination of two or more.

本発明では上記極度硬化油として、脂肪酸組成において、炭素数16の飽和脂肪酸含量が好ましくは10〜35質量%、より好ましくは15〜25質量%であり、且つ炭素数20以上の飽和脂肪酸含量が好ましくは15〜50質量%、より好ましくは25〜45質量%である極度硬化油を使用することが、クリーミング性と口溶けと耐熱保形性を併せ持つバタークリームや可塑性油脂が得られる点で好ましい。   In the present invention, the extremely hardened oil has a saturated fatty acid content of 16 carbon atoms in the fatty acid composition, preferably 10 to 35% by mass, more preferably 15 to 25% by mass, and a saturated fatty acid content of 20 or more carbon atoms. It is preferable to use an extremely hardened oil in an amount of preferably 15 to 50% by mass, more preferably 25 to 45% by mass, in order to obtain a butter cream or a plastic oil having both creaming properties, melting in the mouth, and heat-resistant shape retention.

上記特定の脂肪酸比を有する極度硬化油を得る方法としては、炭素数16の脂肪酸を多く含有する油脂の極度硬化油と、炭素数20以上の脂肪酸を多く含有する油脂の極度硬化油とを混合する方法や、炭素数16の脂肪酸を多く含有する油脂と炭素数20以上の脂肪酸を多く含有する油脂との混合油脂を水素添加により極度硬化油とする方法、更には、炭素数16の脂肪酸を多く含有する油脂と炭素数20以上の脂肪酸を多く含有する油脂とのエステル交換油脂を水素添加により極度硬化油とする方法が挙げられる。   As a method of obtaining an extremely hardened oil having the above specific fatty acid ratio, an extremely hardened oil of a fat and oil containing a large amount of fatty acids having 16 carbon atoms and an extremely hardened oil of a fat and oil containing a large amount of fatty acids having 20 or more carbon atoms are mixed. Or a method in which a mixed oil of an oil or fat containing a large amount of fatty acids having 16 carbon atoms and an oil or fat containing a large amount of fatty acids having 20 or more carbon atoms is converted into an extremely hardened oil by hydrogenation. There is a method in which a transesterified oil / fat of a fat / oil containing a large amount and a fat / oil containing a large amount of a fatty acid having 20 or more carbon atoms is extremely hardened by hydrogenation.

上記炭素数16の脂肪酸を多く含有する油脂としては、パーム油、或いはパーム油に対し水素添加、分別、エステル交換等の物理的又は化学的処理の1種又は2種以上の処理を施した油脂を挙げることができ、好ましくはパーム油及び/又はパーム分別硬部油を使用する。また、上記炭素数20以上の脂肪酸を多く含有する油脂としては、ハイエルシン菜種油、からし油、及びこれらの油脂に対し水素添加、分別、エステル交換等の物理的又は化学的処理の1種又は2種以上の処理を施した油脂を挙げることができ、好ましくはハイエルシン菜種油を使用する。   Examples of the fats and oils containing a large amount of the fatty acid having 16 carbon atoms include palm oil or fat or oil obtained by subjecting palm oil to one or more physical or chemical treatments such as hydrogenation, fractionation, and transesterification. Preference is given to using palm oil and / or palm fractionated hard part oil. Examples of the fats and oils containing a large amount of fatty acids having 20 or more carbon atoms include one or two of physical or chemical treatments such as hydrogenation, fractionation, and transesterification of these oils and fats. Oils and fats that have been subjected to more than one kind of treatment can be mentioned. Preferably, Hyercin rapeseed oil is used.

本発明の油脂を連続相とする油脂組成物においては、上記(1)の通り、上記液状油と上記極度硬化油をエステル交換したエステル交換油脂を使用するが、ここで、エステル交換前の液状油及び極度硬化油の配合割合は、良好な本発明の効果を得るためには、極度硬化油の配合割合が5〜35質量%であることが好ましく、より好ましくは12〜25質量%、更に好ましくは12〜20質量%である。ここで極度硬化油の配合割合が5質量%未満であると、得られるエステル交換油脂の融点が低すぎ本発明の効果が得られないおそれがあり、一方、35質量%を超えると、得られるエステル交換油脂の融点が高くなり、低融点油脂としての使用に適さなくなってしまうおそれがある。   In the fat and oil composition of the present invention in which the fat and oil is used as a continuous phase, as described in (1) above, a transesterified fat obtained by transesterifying the liquid oil and the extremely hardened oil is used. The mixing ratio of the oil and the extremely hardened oil is preferably 5 to 35% by mass, more preferably 12 to 25% by mass, more preferably 12 to 25% by mass, in order to obtain a good effect of the present invention. Preferably it is 12 to 20 mass%. Here, if the blending ratio of the extremely hardened oil is less than 5% by mass, the melting point of the obtained transesterified fat may be too low to obtain the effect of the present invention, while if it exceeds 35% by mass, it is obtained. The transesterified fat may have a high melting point, and may not be suitable for use as a low melting fat.

上記エステル交換の反応は、化学的触媒による方法でも、酵素による方法でもよく、また、ランダムエステル反応であっても、位置選択性のエステル交換反応であってもよいが、化学的触媒又は位置選択性のない酵素を用いた、ランダムエステル反応であることが好ましい。   The transesterification reaction may be a method using a chemical catalyst, a method using an enzyme, or a random ester reaction or a regioselective transesterification reaction. It is preferable that the reaction is a random ester reaction using an enzyme having no properties.

上記化学的触媒としては、例えば、ナトリウムメチラート等のアルカリ金属系触媒が挙げられ、また、上記酵素としては、位置選択性のない酵素、例えば、アルカリゲネス(Alcaligenes)属、リゾープス(Rhizopus)属、アスペルギルス(Aspergillus)属、ムコール(Mucor)属、ペニシリウム(Penicillium)属等に由来するリパーゼが挙げられる。尚、該リパーゼは、イオン交換樹脂或いはケイ藻土及びセラミック等の担体に固定化して、固定化リパーゼとして用いることもできるし、粉末の形態で用いることもできる。   Examples of the chemical catalyst include alkali metal-based catalysts such as sodium methylate. Examples of the enzyme include enzymes having no regioselectivity, for example, genus Alcaligenes, Rhizopus, Lipases derived from the genus Aspergillus, the genus Mucor, the genus Penicillium and the like can be mentioned. The lipase can be immobilized on a carrier such as an ion-exchange resin or diatomaceous earth and ceramic and used as an immobilized lipase, or can be used in a powder form.

上記エステル交換油脂は、上記(2)の通り、SFC(固体脂含量)が0℃で5〜25%、好ましくは5〜15%、より好ましくは10〜15%であり、20℃で1〜5%、好ましくは、1〜4%、より好ましくは1〜3%であり、40℃で0〜2%、好ましくは0〜1%、より好ましくは0%である。
SFCが0℃で5%未満又は20℃で1%未満であると、本発明の流動状油脂組成物に耐熱保形性を付与することができなくなる。一方、SFCが0℃で25%を超える、及び/又は20℃で5%を超えると、油性感が強くなり、更に、SFCが40℃で2%を超えると、口溶けが大幅に悪化してしまう。
The transesterified fat and oil has an SFC (solid fat content) of 5 to 25%, preferably 5 to 15%, more preferably 10 to 15% at 0 ° C, and 1 to 20 ° C, as described in (2) above. It is 5%, preferably 1-4%, more preferably 1-3%, and at 0C is 0-2%, preferably 0-1%, more preferably 0%.
If the SFC is less than 5% at 0 ° C. or less than 1% at 20 ° C., the fluid fat composition of the present invention cannot be provided with heat-resistant shape retention. On the other hand, if the SFC exceeds 25% at 0 ° C. and / or exceeds 5% at 20 ° C., the oily feeling becomes strong, and if the SFC exceeds 2% at 40 ° C., melting in the mouth deteriorates significantly. I will.

また、上記エステル交換油脂は、上記(3)の通り、30℃において流動状であることが必要である。
30℃において流動状でない場合、流動状油脂組成物への使用に適さなくなってしまうことに加え、更には、口溶けも悪くなるおそれがある。
Further, the transesterified fat or oil needs to be in a fluid state at 30 ° C. as described in (3) above.
If the composition is not fluid at 30 ° C., the composition may not be suitable for use in a fluid oil composition, and furthermore, dissolution in the mouth may be poor.

本発明の流動状油脂組成物は、上記の(1)〜(3)の全てを満たすエステル交換油脂を油相中に、該油相中の全油脂量基準で50〜100質量%、好ましくは70〜100質量%、より好ましくは80〜100質量%含有する。   The fluid oil / fat composition of the present invention contains the transesterified oil / fat satisfying all of the above (1) to (3) in an oil phase in an amount of 50 to 100% by mass, preferably 50 to 100% by mass, based on the total amount of the oil in the oil phase. 70 to 100% by mass, more preferably 80 to 100% by mass.

また、本発明の流動状油脂組成物は、油相中に、極度硬化油脂を油相基準で1〜10質量%、好ましくは1〜5質量%含有することにより、保管温度又は使用温度が高温域、たとえば25℃を超える場合における耐熱保形性を向上させることができる。   In addition, the fluid oil composition of the present invention contains an extremely hardened oil in the oil phase in an amount of 1 to 10% by mass, preferably 1 to 5% by mass, based on the oil phase, so that the storage temperature or the use temperature is high. Region, for example, when the temperature exceeds 25 ° C., the heat-resistant shape retention can be improved.

上記極度硬化油脂は、原料油脂に対し、ヨウ素価が好ましくは10以下、さらに好ましくは5以下、最も好ましくは1未満となるまで水素添加し、実質的に構成成分である不飽和脂肪酸をほぼ完全に飽和することによって得られる油脂であって、その融点は、好ましくは50℃以上、より好ましくは55℃以上である。
また、上記極度硬化油脂は、上記極度硬化油脂を更に分別した硬部油、あるいは1種又は2種以上の極度硬化油脂をエステル交換したものであってもよく、また、極度硬化油脂と、飽和脂肪酸や、飽和脂肪酸を主体とする部分グリセリド等とをエステル交換したものであってもよい。本発明では、これら全てを極度硬化油脂として扱う。
The extremely hardened fat and oil is hydrogenated with respect to the raw fat and oil until the iodine value is preferably 10 or less, more preferably 5 or less, and most preferably less than 1. It is an oil or fat obtained by saturating to a temperature of preferably 50 ° C. or higher, more preferably 55 ° C. or higher.
The extremely hardened fat may be hard oil obtained by further separating the extremely hardened fat, or one obtained by transesterifying one or more hardened fats or oils. Fatty acids and transesterified fatty acids and partial glycerides mainly composed of saturated fatty acids may be used. In the present invention, all of these are treated as extremely hardened fats and oils.

本発明の流動状油脂組成物においては、上記極度硬化油脂の中でも、微細結晶が得られ、固液分離耐性が特に優れている点において、以下の(1)〜(5)のいずれかの極度硬化油脂を使用することが好ましい。
(1)「牛脂、豚脂、乳脂等の奇数酸を多く含む動物油脂や、ハイエルシン菜種油、魚油等の長鎖脂肪酸を多く含有する油脂」を原料油脂とした極度硬化油脂。
(2)「構成脂肪酸の平均鎖長が異なる2種又は3種以上の油脂からなる油脂配合物を、化学的あるいは酵素的にエステル交換して、構成脂肪酸の鎖長をばらつかせた油脂配合物」を原料油脂とした極度硬化油脂。
(3)「1種又は2種以上の油脂に、該油脂と構成脂肪酸の平均鎖長が異なる飽和脂肪酸又は該飽和脂肪酸を主体とする部分グリセリドを添加してなる油脂配合物を、化学的あるいは酵素的にエステル交換して、構成脂肪酸の鎖長をばらつかせた油脂」を原料油脂とした極度硬化油脂。
(4)構成脂肪酸の平均鎖長が異なる2種以上の極度硬化油脂をエステル交換した油脂。
(5)「1種又は2種以上の極度硬化油脂に、該極度硬化油脂と構成脂肪酸の平均鎖長が異なる飽和脂肪酸又は該飽和脂肪酸を主体とする部分グリセリドを添加してなる油脂配合物」を、化学的あるいは酵素的にエステル交換して、構成脂肪酸の鎖長をばらつかせた油脂。
In the fluid fat composition of the present invention, among the extremely hardened fats and oils, fine crystals are obtained and the solid-liquid separation resistance is particularly excellent, which is one of the following extremes (1) to (5). It is preferable to use hardened fats and oils.
(1) Extremely hardened fats and oils containing "animal fats and oils containing a lot of odd acids such as beef tallow, lard and milk fat, and fats and oils containing a lot of long-chain fatty acids such as Hyersin rapeseed oil and fish oil".
(2) "A fat or oil composition obtained by chemically or enzymatically transesterifying a fat or oil composition comprising two or more kinds of fats or oils having different average chain lengths of constituent fatty acids to vary the chain length of the constituent fatty acids. Extremely hardened fats and oils using "things" as raw material fats.
(3) A fat or oil blend obtained by adding a saturated fatty acid or a partial glyceride mainly composed of the saturated fatty acid having a different average chain length from the fat or oil to one or more fats or oils, chemically or chemically. Extremely hardened fats and oils that use enzymatic transesterification to vary the chain length of the constituent fatty acids.
(4) Fats and oils obtained by transesterifying two or more types of extremely hardened fats and oils having different average chain lengths of constituent fatty acids.
(5) "A fat or oil composition comprising one or more extremely hardened fats and oils and a saturated fatty acid having a different average chain length from the extremely hardened fat and fatty acid or a partial glyceride mainly containing the saturated fatty acid". Is a fat or oil obtained by chemically or enzymatically transesterifying a product to vary the chain length of constituent fatty acids.

本発明では、これらの中でも、ハイエルシン菜種油の極度硬化油脂、魚油の極度硬化油脂等、長鎖脂肪酸を多く含む油脂を原料油脂とした極度硬化油脂が、高温域での固液分離が特に少ない流動状油脂組成物を得られる点で好ましく使用される。   In the present invention, among these, extremely hardened fats and oils containing high long-chain fatty acids, such as extremely hardened fats of Hyersin rapeseed oil, extremely hardened fats of fish oil, and the like, the solid-liquid separation in a high temperature region is particularly low. It is preferably used in that a fat-and-oil composition can be obtained.

本発明の流動状油脂組成物は、油相のSFCが、10℃で5〜20%であり、20℃で1〜10%となる範囲において、その他の油脂を使用することができる。   In the fluid fat composition of the present invention, other fats and oils can be used as long as the SFC of the oil phase is 5 to 20% at 10 ° C and 1 to 10% at 20 ° C.

上記その他の油脂としては、食用に適する油脂であればよく、その代表例としては、大豆油、菜種油、コーン油、綿実油、オリーブ油、落花生油、米油、べに花油、ひまわり油等の常温で液体の油脂が挙げられるが、その他に、パーム油、パーム核油、ヤシ油、サル脂、マンゴ脂、乳脂、牛脂、乳脂、豚脂、カカオ脂、魚油、鯨油等の常温で固体の油脂も用いることができ、更に、これらの食用油脂に水素添加、分別、エステル交換等の物理的又は化学的処理の1種又は2種以上の処理を施した油脂を使用することもできる。本発明においては、これらの油脂を単独で用いることもでき、又は2種以上を組み合わせて用いることもできる。
ただし、本発明の流動状油脂組成物では、上記その他の油脂として、上記の常温で液体である油脂を使用すると、特に20℃を超える環境において固液分離しやすくなるため、これについては使用しないことが好ましい。
As the above-mentioned other fats and oils, any edible fats and oils may be used, and typical examples thereof include liquids at room temperature such as soybean oil, rapeseed oil, corn oil, cottonseed oil, olive oil, peanut oil, rice oil, beech flower oil, and sunflower oil. Oils and fats, but in addition, palm oil, palm kernel oil, coconut oil, monkey fat, mango fat, milk fat, tallow, milk fat, lard, cocoa fat, fish oil, whale oil, and other solid fats and oils at room temperature are also used. It is also possible to use fats and oils which have been subjected to one or more physical or chemical treatments such as hydrogenation, fractionation and transesterification of these edible fats and oils. In the present invention, these fats and oils can be used alone or in combination of two or more.
However, in the fluid fats and oils composition of the present invention, when the above-mentioned fats and oils which are liquid at ordinary temperature are used as the other fats and oils, solid-liquid separation is easily performed particularly in an environment exceeding 20 ° C. Is preferred.

また、本発明の流動状油脂組成物は、トランス脂肪酸を実質的に含有しないことが好ましい。ここで、「トランス脂肪酸を実質的に含有しない」とは、油脂組成物の使用油脂の全構成脂肪酸中、トランス脂肪酸含量が好ましくは10質量%未満、更に好ましくは5質量%以下、最も好ましくは2質量%未満であることをいう。   Moreover, it is preferable that the fluid fat composition of this invention does not contain trans fatty acid substantially. Here, “substantially free of trans fatty acids” means that the trans fatty acid content is preferably less than 10% by mass, more preferably 5% by mass or less, and most preferably the total constituent fatty acids of the fats and oils used in the fat and oil composition. It means that it is less than 2% by mass.

水素添加は、油脂の融点を上昇させる典型的な方法であるが、部分水素添加油脂は、通常構成脂肪酸中にトランス脂肪酸が10〜50質量%程度含まれている。一方、天然油脂中にはトランス脂肪酸が殆ど存在せず、反芻動物由来の油脂に10質量%未満含まれているにすぎない。近年、上述のように、化学的な処理、特に水素添加に付されていない油脂組成物、即ち実質的にトランス脂肪酸を含まない油脂組成物であって、適切なコンシステンシーを有するものも要求されている。
本発明の流動状油脂組成物に用いられる上記エステル交換油脂、及び、上記極度硬化油脂は、トランス脂肪酸を実質的に含有しないため、その他の油脂に部分水素添加油脂を使用しないことにより、トランス脂肪酸を含まずとも適切なコンステンシーを有する、バタークリームや可塑性油脂組成物とすることができる。
Hydrogenation is a typical method for increasing the melting point of fats and oils, but partially hydrogenated fats and oils usually contain about 10 to 50% by mass of trans fatty acids in the constituent fatty acids. On the other hand, trans fatty acids are scarcely present in natural fats and oils, and are contained in ruminant-derived fats and oils in less than 10% by mass. In recent years, as described above, fats and oils compositions that have not been subjected to chemical treatment, particularly hydrogenation, that is, fats and oils compositions that are substantially free of trans fatty acids and that have an appropriate consistency have also been required. ing.
The transesterified fat and oil used in the fluid fat composition of the present invention, and the extremely hardened fat and oil do not substantially contain a trans fatty acid. And a butter cream or a plastic fat composition having an appropriate consistency.

本発明の流動状油脂組成物における上記の他の油脂の配合量は、油相中に、油相基準で好ましくは0〜50質量%、より好ましくは0〜30質量%である。   The blending amount of the other fats and oils in the fluid fat composition of the present invention is preferably 0 to 50% by mass, more preferably 0 to 30% by mass, based on the oil phase in the oil phase.

本発明の流動状油脂組成物においては、油相のSFCが、10℃で5〜20%であり、20℃で1〜10%である。
ここで、油相のSFCが、10℃で5%未満及び/又は20℃で1%未満であると、流動性が高すぎて、飲食品に練り込まれにくい流動状油脂組成物となってしまい、特にクリーム状食品に使用した場合には、耐熱性に乏しいものとなってしまう。また、経時的あるいは温度変動等によって液状成分が分離しやすく、その場合には流動状油脂組成物としての機能を失してしまう。
また、油相のSFCが、10℃で20%超及び/又は20℃で10%超であると、経時的にあるいは温度変動等によって固化しやすく、その場合には流動状を呈さなくなってしまう。
In the fluid fat composition of the present invention, the SFC of the oil phase is 5 to 20% at 10 ° C and 1 to 10% at 20 ° C.
Here, when the SFC of the oil phase is less than 5% at 10 ° C and / or less than 1% at 20 ° C, a fluid oil composition having too high fluidity and difficult to be kneaded into food or drink is obtained. In particular, when used for creamy foods, heat resistance is poor. Further, the liquid component is easily separated due to aging or temperature fluctuation, and in that case, the function as the fluid fat composition is lost.
If the SFC of the oil phase is more than 20% at 10 ° C. and / or more than 10% at 20 ° C., it tends to solidify over time or due to temperature fluctuations, in which case it will not exhibit fluidity. .

尚、上記SFCは、次のようにして測定する。即ち、先ず、油相を60℃に30分保持して完全に融解した後、0℃に30分保持して固化させる。次いで、25℃に30分保持し、テンパリングを行い、その後、0℃に30分保持する。これをSFCの各測定温度に順次30分保持後、SFCを測定する。   The SFC is measured as follows. That is, first, the oil phase is kept at 60 ° C. for 30 minutes to completely melt it, and then kept at 0 ° C. for 30 minutes to solidify. Next, it is kept at 25 ° C. for 30 minutes to perform tempering, and then kept at 0 ° C. for 30 minutes. After maintaining this at each measurement temperature of the SFC for 30 minutes, the SFC is measured.

本発明の流動状油脂組成物における油相含量は、80〜100質量%、好ましくは90〜100質量%、より好ましくは99質量%〜100質量%である。   The oil phase content in the fluid fat composition of the present invention is 80 to 100% by mass, preferably 90 to 100% by mass, and more preferably 99 to 100% by mass.

また、本発明の流動状油脂組成物における水相含量は、20質量%未満、好ましくは10質量%未満、より好ましくは1質量%未満である。
油相含量が80質量%未満、すなわち水相成分が20質量%以上であると、温度変動等によって固化してしまい、その場合には流動状を呈さなくなってしまう。
Further, the content of the aqueous phase in the fluid fat composition of the present invention is less than 20% by mass, preferably less than 10% by mass, and more preferably less than 1% by mass.
If the oil phase content is less than 80% by mass, that is, if the aqueous phase component is 20% by mass or more, it will solidify due to temperature fluctuation or the like, and in that case, it will not exhibit fluidity.

本発明の流動状油脂組成物は、10〜30℃の全ての温度において、粘度が、20,000mPa・s以上、特に40,000mPa・s以上であることが好ましく、200,000mPa・s以下、特に150,000mPa・s以下であることが好ましい。
10〜30℃のいずれかの温度において粘度が20,000mPa・s未満であると、経日的に固液分離を起こしやすい。また、そのような油脂組成物を使用して得られたクリーム状食品も固液分離を起こしやすく、さらに耐熱性に乏しいものとなってしまうおそれがある。
一方、10〜30℃のいずれかの温度において粘度が200,000mPa・sを超えると、流動性に乏しくなる。また、そのような油脂組成物を使用して得られたクリーム状食品は、ソフト性に乏しいものとなってしまう。
The fluid oil composition of the present invention has a viscosity of preferably 20,000 mPa · s or more, particularly preferably 40,000 mPa · s or more at all temperatures of 10 to 30 ° C., and 200,000 mPa · s or less. In particular, the pressure is preferably 150,000 mPa · s or less.
If the viscosity is less than 20,000 mPa · s at any temperature of 10 to 30 ° C., solid-liquid separation is likely to occur over time. Also, creamy foods obtained using such an oil / fat composition may easily undergo solid-liquid separation, and may have poor heat resistance.
On the other hand, if the viscosity exceeds 200,000 mPa · s at any temperature of 10 to 30 ° C., the fluidity becomes poor. In addition, creamy foods obtained using such an oil or fat composition have poor softness.

また、本発明の流動状油脂組成物には、その他の成分を含有させることができる。その他の成分としては、例えば、水、乳化剤、増粘安定剤、食塩や塩化カリウム等の塩味剤、クエン酸、酢酸、乳酸、グルコン酸等の酸味料、牛乳・練乳・脱脂粉乳・カゼイン・ホエーパウダー・バター・クリーム・ナチュラルチーズ・プロセスチーズ・発酵乳等の乳や乳製品、蔗糖・液糖・はちみつ・ブドウ糖・麦芽糖・オリゴ糖・水飴・ソルビトール・還元水飴・モラセス等の糖類や糖アルコール類、デキストリン類、ステビア・アスパルテーム等の甘味料、β―カロチン・カラメル・紅麹色素等の着色料、トコフェロール・茶抽出物等の酸化防止剤、小麦蛋白や大豆蛋白等の植物蛋白、卵及び各種卵加工品、着香料、調味料、pH調整剤、食品保存料、日持ち向上剤、果実、果汁、コーヒー、ナッツペースト、香辛料、カカオマス、ココアパウダー、穀類、豆類、野菜類、肉類、魚介類等の食品素材や食品添加物が挙げられる。   Further, the fluid oil composition of the present invention can contain other components. Other components include, for example, water, emulsifiers, thickeners, salting agents such as salt and potassium chloride, acidulants such as citric acid, acetic acid, lactic acid and gluconic acid, milk, condensed milk, skim milk powder, casein and whey. Milk and dairy products such as powder, butter, cream, natural cheese, processed cheese, and fermented milk; sugars and sugar alcohols such as sucrose, liquid sugar, honey, glucose, maltose, oligosaccharides, starch syrup, sorbitol, reduced starch syrup, molasses, etc. , Dextrins, sweeteners such as stevia and aspartame, coloring agents such as β-carotene, caramel and red yeast oil, antioxidants such as tocopherol and tea extract, plant proteins such as wheat protein and soybean protein, eggs and various types Egg processed products, flavorings, seasonings, pH adjusters, food preservatives, shelf life improvers, fruit, fruit juice, coffee, nut paste, spices, cacao mass, coco A powder, grains, beans, vegetables, meat, food materials and food additives such as seafood and the like.

上記乳化剤としては、グリセリン脂肪酸エステル、蔗糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、グリセリン有機酸脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、ステアロイル乳酸カルシウム、ステアロイル乳酸ナトリウム、ポリオキシエチレン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、レシチン、酵素処理レシチン、サポニン類等が挙げられ、これらの中から選ばれた1種又は2種以上を用いることができる。上記乳化剤の配合量は、特に制限はないが、本発明の流動状油脂組成物中、好ましくは0〜3質量%、更に好ましくは0〜1.5質量%である。   Examples of the emulsifier include glycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, glycerin organic acid fatty acid ester, polyglycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester, calcium stearoyl lactate, sodium stearoyl lactate, polyoxy Examples thereof include ethylene fatty acid esters, polyoxyethylene sorbitan fatty acid esters, lecithin, enzyme-treated lecithin, saponins and the like, and one or more selected from these can be used. The blending amount of the emulsifier is not particularly limited, but is preferably 0 to 3% by mass, more preferably 0 to 1.5% by mass in the fluid fat composition of the present invention.

上記増粘安定剤としては、グアーガム、ローカストビーンガム、カラギーナン、アラビアガム、アルギン酸類、ペクチン、キサンタンガム、プルラン、タマリンドシードガム、サイリウムシードガム、結晶セルロース、カルボキシメチルセルロース、メチルセルロース、寒天、グルコマンナン、ゼラチン、澱粉、化工澱粉等が挙げられ、これらの中から選ばれた1種又は2種以上を用いることができる。上記増粘安定剤の配合量は、特に制限はないが、本発明の流動状油脂組成物中、好ましくは0〜10質量%、更に好ましくは0〜5質量%である。   As the thickening stabilizer, guar gum, locust bean gum, carrageenan, gum arabic, alginic acids, pectin, xanthan gum, pullulan, tamarind seed gum, psyllium seed gum, crystalline cellulose, carboxymethyl cellulose, methyl cellulose, agar, glucomannan, gelatin , Starch, modified starch, etc., and one or more selected from these can be used. The amount of the thickening stabilizer is not particularly limited, but is preferably 0 to 10% by mass, more preferably 0 to 5% by mass, in the fluid fat composition of the present invention.

本発明の流動状油脂組成物中において、上記その他の成分の使用量は、それらの成分の使用目的等に応じて適宜選択することができ、特に制限されるものではないが、好ましくは全油脂分100質量部に対して合計で50質量部以下とする。   In the fluid oil composition of the present invention, the amounts of the above-mentioned other components can be appropriately selected according to the purpose of use of those components, and are not particularly limited. The total amount is 50 parts by mass or less based on 100 parts by mass.

次に、本発明の流動状油脂組成物の好ましい製造方法について説明する。本発明の流動状油脂組成物は、下記の(1)〜(3)の全てを満たすエステル交換油脂を、該油相中の全油脂量基準で50〜100質量%含有し、且つ、SFCが、10℃で5〜20%であり、20℃で1〜10%とした油相を溶解した後、冷却し、結晶化させることにより製造することができる。
(1)液状油と極度硬化油をエステル交換したエステル交換油脂である。
(2)SFC(固体脂含量)が、0℃で5〜25%、20℃で1〜5%、40℃で0〜2%である。
(3)30℃において流動状である。
Next, a preferred method for producing the fluid fat composition of the present invention will be described. The fluid oil / fat composition of the present invention contains a transesterified oil / fat satisfying all of the following (1) to (3) in an amount of 50 to 100% by mass based on the total amount of the oil and fat in the oil phase, and has an SFC It can be produced by dissolving an oil phase at 5% to 20% at 10 ° C. and 1% to 10% at 20 ° C., followed by cooling and crystallization.
(1) A transesterified fat obtained by transesterifying a liquid oil and an extremely hardened oil.
(2) SFC (solid fat content) is 5 to 25% at 0 ° C, 1 to 5% at 20 ° C, and 0 to 2% at 40 ° C.
(3) It is fluid at 30 ° C.

具体的には、先ず、上記油相に、必要により水相を混合乳化する。そして次に殺菌処理するのが望ましい。殺菌方法はタンクでのバッチ式でも、プレート型熱交換機や掻き取り式熱交換機を用いた連続式でも構わない。次に、上記油相を冷却し、結晶化させる。好ましくは冷却可塑化する。冷却条件は、好ましくは−0.5℃/分以上、更に好ましくは−5℃/分以上とする。この際、徐冷却より急速冷却の方が好ましい。冷却に用いる機器としては、密閉型連続式チューブ冷却機、例えばボテーター、コンピネーター、パーフェクター等のマーガリン製造機やプレート型熱交換機等が挙げられ、また、開放型のダイアクーラーとコンプレクターの組み合わせが挙げられる。   Specifically, first, a water phase is mixed and emulsified with the above oil phase, if necessary. Then, it is desirable to sterilize. The sterilization method may be a batch type in a tank or a continuous type using a plate type heat exchanger or a scraping type heat exchanger. Next, the oil phase is cooled and crystallized. Preferably, it is plasticized by cooling. The cooling conditions are preferably at least -0.5 ° C / min, more preferably at least -5 ° C / min. At this time, rapid cooling is preferable to slow cooling. Examples of equipment used for cooling include a closed-type continuous tube cooler, such as a margarine making machine such as a voter, a compinator, and a perfector, a plate-type heat exchanger, and the like, and a combination of an open-type diacooler and a complexor. Is mentioned.

尚、上記その他の成分を使用する場合は基本的には油溶性成分は油相に、水溶性成分は水相に添加して製造することができるが、だまになることを避ける等の目的で、水溶性成分を油相に分散させて製造することもでき、油溶性成分を水相に分散して製造することもできる。   In addition, when using the above-mentioned other components, the oil-soluble component can be basically added to the oil phase and the water-soluble component can be added to the aqueous phase for production. Alternatively, it can be produced by dispersing a water-soluble component in an oil phase, or can be produced by dispersing an oil-soluble component in an aqueous phase.

また、本発明の流動状油脂組成物を製造する際のいずれかの工程で、窒素、空気等を含気させてもよいが、本発明の流動状油脂組成物は、気相を含有することにより粘度が高くなり、特に低温度域での流動性が失われるおそれがあることから、気相は含有させないことが好ましい。   In any step of producing the fluid oil composition of the present invention, nitrogen, air, etc. may be aerated, but the fluid oil composition of the present invention contains a gas phase. Therefore, it is preferable not to contain a gaseous phase since the viscosity may be increased, and fluidity in a low temperature range may be lost.

次に、本発明の流動状油脂組成物の用途について説明する。
本発明の流動状油脂組成物は、固液分離を起こすことがなく、広い温度域で良好な流動性を有するものであり、スプレッド用をはじめ、ソフトな食感を有するバタースポンジケーキ等に用いる練込用や、あるいは大量生産のために機械化されたラインでパンを製造する際に用いる製パン練込用、あるいは、ディップクリーム、シュガークリーム、バタークリーム、焼き残りクリーム等のクリーム状食品練込用等に、さらには脂肪分の少ない食肉や魚肉の赤身部分との混合あるいはピックル用等に、特に好適に使用することができる。
Next, the use of the fluid fat composition of the present invention will be described.
The fluid fat composition of the present invention does not cause solid-liquid separation, has good fluidity in a wide temperature range, and is used for, for example, a spread butter butter sponge cake having a soft texture. For kneading, or for kneading bread used when making bread on a mechanized line for mass production, or kneading creamy foods such as dip cream, sugar cream, butter cream, unbaked cream, etc. It can be used particularly preferably for use in meats and fish meats with a low fat content, and for pickles and the like.

本発明のクリーム状食品について以下に述べる。
本発明のクリーム状食品は、本発明の流動状油脂組成物を含有してなるものであり、ソフトで、口溶けがよく、適度のチキソトロピー性を有しながら、耐熱性も良好であるという特徴を有する。
本発明のクリーム状食品における本発明の流動状油脂組成物の使用量は、好ましくは5〜80質量%、より好ましくは30〜70質量%である。
The cream food of the present invention will be described below.
The creamy food of the present invention contains the fluid oil or fat composition of the present invention, and is characterized by being soft, well-melting in the mouth, having a suitable thixotropy, and having good heat resistance. Have.
The use amount of the fluid fat composition of the present invention in the creamy food of the present invention is preferably 5 to 80% by mass, more preferably 30 to 70% by mass.

本発明のクリーム状食品は、従来のクリーム状食品を製造する際に使用する油脂組成物の一部又は全部を、本発明の流動状油脂組成物に置換して製造すればよい。
つまり、本発明の流動状油脂組成物を使用し、各種糖類、脱脂粉乳や全粉乳等の乳製品、食塩等の塩味剤、β−カロチン等の着色料、小麦蛋白や大豆蛋白といった植物蛋白、卵及び各種卵加工品、着香料、調味料、乾燥果実、粉末果汁、粉末コーヒー、ナッツペースト、香辛料、ココアマス、ココアパウダー、穀類、豆類、野菜類等の食品素材や食品添加物を加え、常法に従って加工することにより、本発明のクリーム状食品を得ることができる。
The creamy food of the present invention may be produced by substituting a part or all of the fat or oil composition used for producing a conventional creamy food with the fluid fat or oil composition of the present invention.
That is, using the fluid oil composition of the present invention, various sugars, dairy products such as skim milk powder and whole milk powder, salting agents such as salt, coloring agents such as β-carotene, vegetable proteins such as wheat protein and soy protein, Add food ingredients and food additives such as eggs and processed egg products, flavorings, seasonings, dried fruits, powdered juice, powdered coffee, nut paste, spices, cocoa mass, cocoa powder, grains, beans, vegetables, etc. By processing according to the method, the creamy food of the present invention can be obtained.

本発明のクリーム状食品は、サンドクリーム、フィリングクリーム、トッピングクリーム、ディップクリームとして、ベーカリー食品、惣菜食品、畜肉食品等の各種食品に用いることができる。また、本発明のクリーム状食品を各種のベーカリー生地、惣菜生地、畜肉生地等に、サンド、フィリング、トッピング、包餡成形等した後に焼成してもよい。   The creamy food of the present invention can be used as various kinds of foods such as bakery foods, prepared foods, livestock meat foods, etc. as sand creams, filling creams, topping creams, and dip creams. Further, the creamy food of the present invention may be baked after being subjected to sanding, filling, topping, encrusting and the like on various types of bakery dough, prepared food dough, livestock meat dough and the like.

次に、本発明の魚肉加工食品について述べる。
本発明の魚肉加工食品は、本発明の流動状油脂組成物を含有してなるものであり、脂肪分の少ないたん白な風味の魚肉を使用していながら風味と食感が改善され、油脂の染み出しやドリップの発生が抑制され、品質価値が向上しているものである。
本発明の魚肉加工食品における本発明の流動状油脂組成物の使用量は、好ましくは5〜80質量%、より好ましくは10〜50質量%、さらに好ましくは10〜30質量%である。
なお、本発明の魚肉加工食品用油脂組成物は、魚肉以外にも、牛、豚、鶏、馬、羊、鹿、猪等の畜肉に対して同様に使用することももちろん可能である。
Next, the processed fish meat food of the present invention will be described.
The processed fish meat food of the present invention contains the fluid oil composition of the present invention, and the flavor and texture are improved while using a low-fat protein-flavored fish meat. The occurrence of oozing and drip is suppressed, and the quality value is improved.
The use amount of the fluid fat composition of the present invention in the processed fish meat food of the present invention is preferably 5 to 80% by mass, more preferably 10 to 50% by mass, and still more preferably 10 to 30% by mass.
The oil / fat composition for processed fish meat food of the present invention can of course be used in the same manner for meat of cattle, pigs, chickens, horses, sheep, deers, boars and the like, in addition to fish meat.

以下に、実施例と比較例とを共に挙げて更に本発明を説明するが、本発明はこれらの実施例等に限定されるものではない。
尚、下記実施例等において、脂肪酸含量は、特に断りのない限り、構成脂肪酸組成における脂肪酸含量を示す。
Hereinafter, the present invention will be further described with reference to Examples and Comparative Examples, but the present invention is not limited to these Examples and the like.
In the following examples, the fatty acid content indicates the fatty acid content in the constituent fatty acid composition unless otherwise specified.

<エステル交換油脂の製造>
〔製造例1〕エステル交換油脂Aの製造
菜種油(キャノーラ油)80質量部に、極度硬化油として、パーム油の極度硬化油と、ハイエルシンナタネ油の極度硬化油とを50:50の質量比で混合した混合油脂(炭素数16の飽和脂肪酸含量が24質量%、且つ炭素数20以上の飽和脂肪酸含量が30質量%)20質量部を添加し、溶解した油脂配合物に、ナトリウムメチラートを触媒として非選択的エステル交換反応を行った後、脱色(白土3%、85℃、9.3×102Pa以下の減圧下)、脱臭(250℃、60分間、水蒸気吹き込み量5%、4.0×102Pa以下の減圧下)を行ない、SFC(固体脂含量)が0℃で15%、20℃で3%、40℃で0%であり30℃において流動状であるエステル交換油脂Aを得た。
<Production of transesterified fats and oils>
[Production Example 1] Production of transesterified oil A A mass ratio of an extremely hardened oil of palm oil and an extremely hardened oil of Hyercinna rapeseed oil to 80 parts by mass of rapeseed oil (canola oil) was 50:50. 20 parts by mass of a mixed fat / oil (the content of saturated fatty acids having 16 carbon atoms is 24% by mass and the content of saturated fatty acids having 20 or more carbon atoms is 30% by mass) is added, and sodium methylate is added to the dissolved fat / oil mixture. After performing a non-selective transesterification reaction as a catalyst, decolorization (white clay 3%, 85 ° C., under a reduced pressure of 9.3 × 10 2 Pa or less), deodorization (250 ° C., 60 minutes, steam blowing 5%, 4% Under reduced pressure of 0.0 × 10 2 Pa or less), and the transesterified fats and oils which are 15% at 0 ° C., 3% at 20 ° C., 0% at 40 ° C. and fluid at 30 ° C. A was obtained.

〔製造例2〕エステル交換油脂Bの製造
菜種油(キャノーラ油)80質量部に、パーム油の極度硬化油(炭素数16の飽和脂肪酸含量が44質量%、且つ炭素数20以上の飽和脂肪酸含量が0質量%)20質量部を添加し、溶解した油脂配合物に、ナトリウムメチラートを触媒として非選択的エステル交換反応を行った後、脱色(白土3%、85℃、9.3×102Pa以下の減圧下)、脱臭(250℃、60分間、水蒸気吹き込み量5%、4.0×102Pa以下の減圧下)を行ない、SFC(固体脂含量)が0℃で13%、20℃で2%、40℃で0%であり30℃において流動状であるエステル交換油脂Bを得た。
[Production Example 2] Production of transesterified oil / fat B 80 parts by mass of rapeseed oil (canola oil) was mixed with extremely hardened oil of palm oil (the content of saturated fatty acids having 16 carbon atoms was 44% by mass and the content of saturated fatty acids having 20 or more carbon atoms was 44% by mass). (0% by mass), 20 parts by mass of the dissolved oil and fat mixture were subjected to a non-selective transesterification reaction using sodium methylate as a catalyst, and then decolorized (3% clay, 85 ° C., 9.3 × 10 2). Decompression (at 250 ° C., 60 minutes, steam blowing rate 5%, under a reduced pressure of 4.0 × 10 2 Pa or less) and SFC (solid fat content) at 0 ° C. 13%, 20% A transesterified fat B which was 2% at 0 ° C., 0% at 40 ° C. and fluid at 30 ° C. was obtained.

〔製造例3〕エステル交換油脂Cの製造
菜種油(キャノーラ油)80質量部に、ハイエルシンナタネ油の極度硬化油(炭素数16の飽和脂肪酸含量が3質量%、且つ炭素数20以上の飽和脂肪酸含量が59質量%)20質量部を添加し、溶解した油脂配合物に、ナトリウムメチラートを触媒として非選択的エステル交換反応を行った後、脱色(白土3%、85℃、9.3×102Pa以下の減圧下)、脱臭(250℃、60分間、水蒸気吹き込み量5%、4.0×102Pa以下の減圧下)を行ない、SFC(固体脂含量)が0℃で17%、20℃で4%、40℃で0%であり30℃において流動状であるエステル交換油脂Cを得た
[Production Example 3] Production of transesterified oil / fat C 80 parts by mass of rapeseed oil (canola oil) was mixed with an extremely hardened oil of Hyerin rapeseed oil (saturated fatty acid having 16 carbon atoms and having a saturated fatty acid content of 3% by mass and having 20 or more carbon atoms). After adding 20 parts by mass of the dissolved oil and fat mixture and performing a non-selective transesterification reaction using sodium methylate as a catalyst, decolorization (white clay 3%, 85 ° C., 9.3 ×) SFC (solid fat content) is 17% at 0 ° C. under reduced pressure of 10 2 Pa or less and deodorizing (250 ° C., 60 minutes, steam blowing amount 5%, 4.0 × 10 2 Pa or less reduced pressure). , 4% at 20 ° C., 0% at 40 ° C., and a transesterified fat C which was fluid at 30 ° C. was obtained.

〔製造例4〕エステル交換油脂Dの製造
菜種油(キャノーラ油)88質量部に、ハイエルシンナタネ油の極度硬化油とを50:50の質量比で混合した混合油脂(炭素数16の飽和脂肪酸含量が24質量%、且つ炭素数20以上の飽和脂肪酸含量が30質量%)12質量部を添加し、溶解した油脂配合物に、ナトリウムメチラートを触媒として非選択的エステル交換反応を行った後、脱色(白土3%、85℃、9.3×102Pa以下の減圧下)、脱臭(250℃、60分間、水蒸気吹き込み量5%、4.0×102Pa以下の減圧下)を行ない、SFC(固体脂含量)が0℃で7%、20℃で2%、40℃で0%であり30℃において流動状であるエステル交換油脂Dを得た
[Production Example 4] Production of transesterified oil / fat D Mixed oil / fat (saturated fatty acid content having 16 carbon atoms) in which 88 parts by mass of rapeseed oil (canola oil) was mixed with an extremely hardened oil of Hyercinus rapeseed oil at a mass ratio of 50:50. Is 24% by mass, and the content of saturated fatty acids having 20 or more carbon atoms is 30% by mass), and the non-selective transesterification reaction is performed on the dissolved oil and fat mixture using sodium methylate as a catalyst. Decolorization (white clay 3%, 85 ° C, reduced pressure of 9.3 × 10 2 Pa or less), and deodorization (250 ° C., 60 minutes, 5% steam blowing rate, reduced pressure of 4.0 × 10 2 Pa or less) The transesterified fat D having a solid fat content of 7% at 0 ° C., 2% at 20 ° C. and 0% at 40 ° C. and being fluid at 30 ° C. was obtained.

〔比較製造例1〕エステル交換油脂Eの製造
ヨウ素価65のパーム分別軟部油にナトリウムメチラートを触媒として非選択的エステル交換反応を行った後、脱色(白土3%、85℃、9.3×102Pa以下の減圧下)、脱臭(250℃、60分間、水蒸気吹き込み量5%、4.0×102Pa以下の減圧下)を行ない、SFC(固体脂含量)が0℃で32%、20℃で16%、40℃で2%であり30℃において固体であり流動状を示さず融点が33℃であるエステル交換油脂Eを得た。
[Comparative Production Example 1] Production of transesterified oil / fat E Non-selective transesterification reaction of a palm fractionated soft oil having an iodine value of 65 with sodium methylate as a catalyst was carried out, followed by decolorization (white clay 3%, 85 ° C, 9.3). (Under reduced pressure of 10 × 10 2 Pa or less), deodorization (250 ° C., 60 minutes, 5% of steam blown under a reduced pressure of 4.0 × 10 2 Pa or less), and SFC (solid fat content) of 32 ° C. at 0 ° C. %, 16% at 20 ° C., 2% at 40 ° C., and a transesterified fat E having a melting point of 33 ° C. which was solid at 30 ° C. and did not show fluidity.

〔比較製造例2〕エステル交換油脂Fの製造
菜種油(キャノーラ油)70質量部に、ハイエルシンナタネ油の極度硬化油(炭素数16の飽和脂肪酸含量が3質量%、且つ炭素数20以上の飽和脂肪酸含量が59質量%)30質量部を添加し、溶解した油脂配合物に、ナトリウムメチラートを触媒として非選択的エステル交換反応を行った後、脱色(白土3%、85℃、9.3×102Pa以下の減圧下)、脱臭(250℃、60分間、水蒸気吹き込み量5%、4.0×102Pa以下の減圧下)を行ない、SFC(固体脂含量)が0℃で34%、20℃で12%、40℃で2%であり30℃において固体であり流動状を示さず融点が39℃であるエステル交換油脂Fを得た。
[Comparative Production Example 2] Production of transesterified oil / fat 70 parts by mass of rapeseed oil (canola oil) was added to an extremely hardened oil of Hyercinna rapeseed oil (the saturated fatty acid content of 16 carbon atoms was 3% by mass and the saturated number of carbon atoms was 20 or more) After adding 30 parts by mass of a fatty acid content (59% by mass) and performing a non-selective transesterification reaction on the dissolved oil and fat mixture using sodium methylate as a catalyst, decolorization (white clay 3%, 85 ° C., 9.3) (Under reduced pressure of 10 × 10 2 Pa or less), deodorization (250 ° C., 60 minutes, 5% of steam blown under a reduced pressure of 4.0 × 10 2 Pa or less), and SFC (solid fat content) of 34 ° C. at 0 ° C. %, 12% at 20 ° C., 2% at 40 ° C., and a transesterified fat F which was solid at 30 ° C., did not show fluidity, and had a melting point of 39 ° C. was obtained.

〔比較製造例3〕エステル交換油脂Gの製造
菜種油(キャノーラ油)96質量部に、極度硬化油として、パーム油の極度硬化油と、ハイエルシンナタネ油の極度硬化油とを50:50の質量比で混合した混合油脂(炭素数16の飽和脂肪酸含量が24質量%、且つ炭素数20以上の飽和脂肪酸含量が30質量%)4質量部を添加し、溶解した油脂配合物に、ナトリウムメチラートを触媒として非選択的エステル交換反応を行った後、脱色(白土3%、85℃、9.3×102Pa以下の減圧下)、脱臭(250℃、60分間、水蒸気吹き込み量5%、4.0×102Pa以下の減圧下)を行ない、SFC(固体脂含量)が0℃で3%、20℃で0%、40℃で0%であり30℃において流動状であるエステル交換油脂Gを得た。
[Comparative Production Example 3] Production of transesterified fat G In 96 parts by mass of rapeseed oil (canola oil), as hardened oil, an extremely hardened oil of palm oil and an extremely hardened oil of Hyer cinnamon oil were mixed in a mass of 50:50. 4 parts by mass of the mixed fats and oils (the content of saturated fatty acids having 16 carbon atoms is 24% by mass and the content of saturated fatty acids having 20 or more carbon atoms is 30% by mass) were added to the dissolved fat mixture, and sodium methylate was added. After performing a non-selective transesterification reaction using as a catalyst, decolorization (white clay 3%, 85 ° C., under a reduced pressure of 9.3 × 10 2 Pa or less), deodorization (250 ° C., 60 minutes, steam blowing amount 5%, (Under a reduced pressure of 4.0 × 10 2 Pa or less), and the SFC (solid fat content) is 3% at 0 ° C., 0% at 20 ° C., 0% at 40 ° C., and is transesterified which is fluid at 30 ° C. Fat G was obtained.

<流動状油脂組成物の製造>
〔実施例1〕
エステル交換油A97質量部及びハイエルシンナタネ油の極度硬化油3質量部からなる油相を、70℃まで加温して完全に溶解し混合した後、−30℃/分の冷却速度で急冷可塑化し、ショートニングタイプの流動状油脂組成物Aを作成した。得られた流動状油脂組成物Aの油相のSFCは10℃で8%、20℃で6%であり、トランス脂肪酸含量は2質量%未満であり、実質的にトランス脂肪酸を含有していなかった。
得られた流動状油脂組成物Aは、ビスコメーター(TOKIMEC社製、6号ローター使用)で粘度を測定したところ、10℃から30℃の全ての温度において、粘度が20,000mPa・s〜200,000mPa・sであり、良好な流動性を呈していた。
また、得られた流動状油脂組成物Aを直径90mmのシャーレに50g投入し、20℃に12時間と40℃に12時間との温度サイクルで放置テストを行った。1週間放置後に固液分離の状況を観察したところ、液状成分の染みだしは全く見られず、またザラの発生も見られなかった。
<Production of fluid oil composition>
[Example 1]
An oil phase consisting of 97 parts by weight of transesterified oil A and 3 parts by weight of an extremely hardened oil of Hyel rapeseed oil is heated to 70 ° C., completely dissolved and mixed, and then quenched at a cooling rate of −30 ° C./min. And a shortening type fluid oil composition A was prepared. The SFC of the oil phase of the obtained fluid oil composition A is 8% at 10 ° C., 6% at 20 ° C., the trans fatty acid content is less than 2% by mass, and substantially no trans fatty acid is contained. Was.
The viscosity of the obtained fluid oil / fat composition A was measured with a viscometer (manufactured by TOKIMEC, using a No. 6 rotor), and the viscosity was 20,000 mPa · s to 200 m at all temperatures from 10 ° C. to 30 ° C. 2,000 mPa · s, and exhibited good fluidity.
Further, 50 g of the obtained fluid oil / fat composition A was put into a petri dish having a diameter of 90 mm, and a standing test was performed at a temperature cycle of 12 hours at 20 ° C. and 12 hours at 40 ° C. When the state of solid-liquid separation was observed after standing for one week, no seepage of the liquid component was observed, and no generation of grain was observed.

[実施例2]
エステル交換油脂Aをエステル交換油脂Bに変更した以外は、実施例1の配合・製法と同様にして、流動状油脂組成物Bを得た。得られた流動状油脂組成物Bの油相のSFCは10℃で7、20℃で4であり、トランス脂肪酸含量は2質量%未満であり、実質的にトランス脂肪酸を含有していなかった。
得られた流動状油脂組成物Bは、ビスコメーター(TOKIMEC社製、6号ローター使用)で粘度を測定したところ、10℃から30℃の全ての温度において、粘度が20,000mPa・s〜200,000mPa・sであり、良好な流動性を呈していた。
また、得られた流動状油脂組成物Bを直径90mmのシャーレに50g投入し、20℃に12時間と40℃に12時間との温度サイクルで放置テストを行った。1週間放置後に固液分離の状況を観察したところ、液状成分の染みだしは全く見られず、またザラの発生も見られなかった。
[Example 2]
A fluid fat composition B was obtained in the same manner as in Example 1 except that the transesterified fat A was changed to the transesterified fat B. The SFC of the oil phase of the obtained fluid oil / fat composition B is 7 % at 10 ° C., 4 % at 20 ° C., the trans fatty acid content is less than 2% by mass, and substantially no trans fatty acid is contained. Was.
The viscosity of the obtained fluid oil-and-fat composition B was measured with a viscometer (manufactured by TOKIMEC, using a No. 6 rotor). The viscosity was 20,000 mPa · s to 200 at all temperatures from 10 ° C. to 30 ° C. 2,000 mPa · s, and exhibited good fluidity.
In addition, 50 g of the obtained fluid oil / fat composition B was put into a Petri dish having a diameter of 90 mm, and a standing test was performed at a temperature cycle of 20 ° C. for 12 hours and 40 ° C. for 12 hours. When the state of solid-liquid separation was observed after standing for one week, no seepage of the liquid component was observed, and no generation of grain was observed.

[実施例3]
エステル交換油脂Aをエステル交換油脂Cに変更した以外は、実施例1の配合・製法と同様にして、流動状油脂組成物Cを得た。得られた流動状油脂組成物Cの油相のSFCは10℃で9%、20℃で4%であり、トランス脂肪酸含量は2質量%未満であり、実質的にトランス脂肪酸を含有していなかった。
得られた流動状油脂組成物Cは、ビスコメーター(TOKIMEC社製、6号ローター使用)で粘度を測定したところ、10℃から30℃の全ての温度において、粘度が20,000mPa・s〜200,000mPa・sであり、良好な流動性を呈していた。
また、得られた流動状油脂組成物Cを直径90mmのシャーレに50g投入し、20℃に12時間と40℃に12時間との温度サイクルで放置テストを行った。1週間放置後に固液分離の状況を観察したところ、液状成分の染みだしは全く見られず、またザラの発生も見られなかった。
[Example 3]
A fluid oil composition C was obtained in the same manner as in Example 1, except that the transesterified oil A was changed to the transesterified oil C. The SFC of the oil phase of the obtained fluid fat composition C is 9% at 10 ° C. and 4% at 20 ° C., the trans fatty acid content is less than 2% by mass, and substantially no trans fatty acid is contained. Was.
The viscosity of the obtained fluid oil / fat composition C was measured with a viscometer (manufactured by TOKIMEC, using a No. 6 rotor), and the viscosity was 20,000 mPa · s to 200 m at all temperatures from 10 ° C. to 30 ° C. 2,000 mPa · s, and exhibited good fluidity.
In addition, 50 g of the obtained fluid oil / fat composition C was put into a petri dish having a diameter of 90 mm, and a standing test was performed at a temperature cycle of 12 hours at 20 ° C and 12 hours at 40 ° C. When the state of solid-liquid separation was observed after standing for one week, no seepage of the liquid component was observed, and no generation of grain was observed.

[実施例4]
エステル交換油脂Aをエステル交換油脂Dに変更した以外は、実施例1の配合・製法と同様にして、流動状油脂組成物Dを得た。得られた流動状油脂組成物Dの油相のSFCは10℃で5%、20℃で5%であり、トランス脂肪酸含量は2質量%未満であり、実質的にトランス脂肪酸を含有していなかった。
得られた流動状油脂組成物Dは、ビスコメーター(TOKIMEC社製、6号ローター使用)で粘度を測定したところ、10℃から30℃の全ての温度において、粘度が20,000mPa・s〜200,000mPa・sであり、良好な流動性を呈していた。
また、得られた流動状油脂組成物Dを直径90mmのシャーレに50g投入し、20℃に12時間と40℃に12時間との温度サイクルで放置テストを行った。1週間放置後に固液分離の状況を観察したところ、液状成分の染みだしは全く見られず、またザラの発生も見られなかった。
[Example 4]
A fluid fat composition D was obtained in the same manner as in the blending and production method of Example 1, except that the transesterified fat A was changed to the transesterified fat D. The SFC of the oil phase of the obtained fluid oil / fat composition D is 5% at 10 ° C and 5% at 20 ° C, the trans fatty acid content is less than 2% by mass, and substantially no trans fatty acid is contained. Was.
The viscosity of the obtained fluid oil / fat composition D was measured with a viscometer (manufactured by TOKIMEC, using a No. 6 rotor). The viscosity was 20,000 mPa · s to 200 m at all temperatures from 10 ° C. to 30 ° C. 2,000 mPa · s, and exhibited good fluidity.
In addition, 50 g of the obtained fluid oil / fat composition D was put into a petri dish having a diameter of 90 mm, and a standing test was performed at a temperature cycle of 12 hours at 20 ° C and 12 hours at 40 ° C. When the state of solid-liquid separation was observed after standing for one week, no seepage of the liquid component was observed, and no generation of grain was observed.

〔実施例5〕
エステル交換油A97質量部を100質量部に変更し、更に極度硬化油を無添加とした以外は、実施例1の配合・製法と同様にして、流動状油脂組成物Eを得た。得られた流動状油脂組成物Eの油相のSFCは10℃で5%、20℃で3%であり、トランス脂肪酸含量は2質量%未満であり、実質的にトランス脂肪酸を含有していなかった。
得られた流動状油脂組成物Eは、ビスコメーター(TOKIMEC社製、6号ローター使用)で粘度を測定したところ、10℃から30℃の全ての温度において、粘度が20,000mPa・s〜200,000mPa・sであり、良好な流動性を呈していた。
また、得られた流動状油脂組成物Eを直径90mmのシャーレに50g投入し、20℃に12時間と40℃に12時間との温度サイクルで放置テストを行った。1週間放置後に固液分離の状況を観察したところ、液状成分の染みだしは全く見られず、またザラの発生も見られなかった。
[Example 5]
A fluid oil composition E was obtained in the same manner as in Example 1, except that 97 parts by mass of the transesterified oil A was changed to 100 parts by mass, and the extremely hardened oil was not added. The SFC of the oil phase of the obtained fluid oil / fat composition E is 5% at 10 ° C., 3% at 20 ° C., the trans fatty acid content is less than 2% by mass, and substantially no trans fatty acid is contained. Was.
The viscosity of the obtained fluid oil / fat composition E was measured with a viscometer (manufactured by TOKIMEC, using a No. 6 rotor), and the viscosity was 20,000 mPa · s to 200 m at all temperatures from 10 ° C. to 30 ° C. 2,000 mPa · s, and exhibited good fluidity.
In addition, 50 g of the obtained fluid oil / fat composition E was put into a petri dish having a diameter of 90 mm, and a standing test was performed at a temperature cycle of 20 ° C. for 12 hours and 40 ° C. for 12 hours. When the state of solid-liquid separation was observed after standing for one week, no seepage of the liquid component was observed, and no generation of grain was observed.

〔実施例6〕
エステル交換油A97質量部を94質量部に変更し、更に極度硬化油を3質量部から6質量部に変更した以外は、実施例1の配合・製法と同様にして、流動状油脂組成物Fを得た。得られた流動状油脂組成物Fの油相のSFCは10℃で11%、20℃で9%であり、トランス脂肪酸含量は2質量%未満であり、実質的にトランス脂肪酸を含有していなかった。
得られた流動状油脂組成物Fは、ビスコメーター(TOKIMEC社製、6号ローター使用)で粘度を測定したところ、10℃においてやや硬いものの、10℃から30℃の全ての温度において、粘度が20,000mPa・s〜200,000mPa・sであり、良好な流動性を呈していた。
また、得られた流動状油脂組成物Fを直径90mmのシャーレに50g投入し、20℃に12時間と40℃に12時間との温度サイクルで放置テストを行った。1週間放置後に固液分離の状況を観察したところ、液状成分の染みだしは全く見られず、またザラの発生も見られなかった。
[Example 6]
Except that 97 parts by mass of transesterified oil A was changed to 94 parts by mass, and that of the extremely hardened oil was changed from 3 parts by mass to 6 parts by mass, the fluid oil composition F was prepared in the same manner as in the blending and production method of Example 1. Got. The SFC of the oil phase of the obtained fluid fat composition F is 11% at 10 ° C. and 9% at 20 ° C., the trans fatty acid content is less than 2% by mass, and substantially no trans fatty acid is contained. Was.
The viscosity of the obtained fluid fat composition F was measured with a viscometer (manufactured by TOKIMEC, using a No. 6 rotor). As a result, the viscosity was slightly hard at 10 ° C, but at all temperatures from 10 ° C to 30 ° C. It was 20,000 mPa · s to 200,000 mPa · s, and exhibited good fluidity.
Further, 50 g of the obtained fluid oil / fat composition F was put into a petri dish having a diameter of 90 mm, and a standing test was carried out at a temperature cycle of 12 hours at 20 ° C. and 12 hours at 40 ° C. When the state of solid-liquid separation was observed after standing for one week, no seepage of the liquid component was observed, and no generation of grain was observed.

〔実施例7〕
エステル交換油A97質量部を、72質量部に変更し、更にナタネ液状油を25質量部添加した以外は、実施例1の配合・製法と同様にして、流動状油脂組成物Gを得た。得られた流動状油脂組成物Gの油相のSFCは10℃で7%、20℃で5%であり、トランス脂肪酸含量は2質量%未満であり、実質的にトランス脂肪酸を含有していなかった。
得られた流動状油脂組成物Gは、ビスコメーター(TOKIMEC社製、6号ローター使用)で粘度を測定したところ、10℃から30℃の全ての温度において、粘度が20,000mPa・s〜200,000mPa・sであり、良好な流動性を呈していた。
また、得られた流動状油脂組成物Gを直径90mmのシャーレに50g投入し、20℃に12時間と40℃に12時間との温度サイクルで放置テストを行った。1週間放置後に固液分離の状況を観察したところ、液状成分の染みだしはほとんど見られず、またザラの発生も見られなかった。
[Example 7]
A fluid oil composition G was obtained in the same manner as in Example 1, except that 97 parts by mass of the transesterified oil A was changed to 72 parts by mass and 25 parts by mass of rapeseed liquid oil was further added. The SFC of the oil phase of the obtained fluid oil composition G is 7% at 10 ° C. and 5% at 20 ° C., the trans fatty acid content is less than 2% by mass, and substantially no trans fatty acid is contained. Was.
The viscosity of the obtained fluid fat composition G was measured with a viscometer (manufactured by TOKIMEC, using a No. 6 rotor). As a result, the viscosity was 20,000 mPa · s to 200 at all temperatures from 10 ° C. to 30 ° C. 2,000 mPa · s, and exhibited good fluidity.
In addition, 50 g of the obtained fluid oil / fat composition G was put into a petri dish having a diameter of 90 mm, and a standing test was performed at a temperature cycle of 12 hours at 20 ° C and 12 hours at 40 ° C. Observation of the state of solid-liquid separation after standing for one week showed that almost no seepage of the liquid component was observed, and no generation of grain was observed.

[比較例1]
エステル交換油脂A97質量部を、エステル交換油脂E50質量部及びナタネ液状油47質量部に変更した以外は、実施例1の配合・製法と同様にして、流動状油脂組成物Hを得た。得られた流動状油脂組成物Hの油相のSFCは10℃で14%、20℃で11%であり、トランス脂肪酸含量は2質量%未満であり、実質的にトランス脂肪酸を含有していなかった。
得られた流動状油脂組成物Hは、ビスコメーター(TOKIMEC社製、6号ローター使用)で粘度を測定したところ、10℃から30℃の全ての温度において、粘度が20,000mPa・s〜200,000mPa・sであり、良好な流動性を呈していた。
また、得られた流動状油脂組成物Hを直径90mmのシャーレに50g投入し、15℃に12時間と35℃に12時間との温度サイクルで放置テストを行った。1週間放置後に固液分離の状況を観察したところ、液状成分の染みだしが見られた。
[Comparative Example 1]
A fluid fat composition H was obtained in the same manner as in Example 1, except that the transesterified fat A97 was changed to the transesterified fat E50 and the rapeseed liquid oil 47, respectively. The SFC of the oil phase of the obtained fluid fat composition H is 14% at 10 ° C. and 11% at 20 ° C., the trans fatty acid content is less than 2% by mass, and substantially no trans fatty acid is contained. Was.
The viscosity of the obtained fluid fat composition H was measured with a viscometer (manufactured by TOKIMEC, using a No. 6 rotor). As a result, the viscosity was 20,000 mPa · s to 200 at all temperatures from 10 ° C. to 30 ° C. 2,000 mPa · s, and exhibited good fluidity.
In addition, 50 g of the obtained fluid oil / fat composition H was put into a petri dish having a diameter of 90 mm, and a standing test was performed at a temperature cycle of 12 hours at 15 ° C and 12 hours at 35 ° C. When the state of solid-liquid separation was observed after standing for one week, seepage of the liquid component was observed.

[比較例2]
エステル交換油脂A97質量部を、エステル交換油脂F50質量部及びナタネ液状油47質量部に変更した以外は、実施例1の配合・製法と同様にして、流動状油脂組成物Iを得た。得られた流動状油脂組成物Iの油相のSFCは10℃で13%、20℃で9%であり、トランス脂肪酸含量は2質量%未満であり、実質的にトランス脂肪酸を含有していなかった。
得られた流動状油脂組成物Iは、ビスコメーター(TOKIMEC社製、6号ローター使用)で粘度を測定したところ、粘度は10℃において400,000mPa・s、30℃において200,000mPa・sであり、10℃における流動性が極めて悪かった。
また、得られた流動状油脂組成物Iを直径90mmのシャーレに50g投入し、15℃に12時間と35℃に12時間との温度サイクルで放置テストを行った。1週間放置後に固液分離の状況を観察したところ、液状成分の染みだしが見られた。
[Comparative Example 2]
A fluid oil composition I was obtained in the same manner as in Example 1, except that the transesterified oil A 97 parts by mass was changed to the transesterified oil F 50 parts by mass and the rapeseed liquid oil 47 parts by mass. The SFC of the oil phase of the obtained fluid oil / fat composition I is 13% at 10 ° C., 9% at 20 ° C., the trans fatty acid content is less than 2% by mass, and substantially no trans fatty acid is contained. Was.
The viscosity of the obtained fluid oil / fat composition I was measured with a viscometer (manufactured by TOKIMEC, using a No. 6 rotor). The viscosity was 400,000 mPa · s at 10 ° C. and 200,000 mPa · s at 30 ° C. And the fluidity at 10 ° C. was extremely poor.
In addition, 50 g of the obtained fluid oil / fat composition I was put into a petri dish having a diameter of 90 mm, and a standing test was performed at a temperature cycle of 15 ° C. for 12 hours and 35 ° C. for 12 hours. When the state of solid-liquid separation was observed after standing for one week, seepage of the liquid component was observed.

[比較例3]
エステル交換油脂Aをエステル交換油脂Gに変更した以外は、実施例1の配合・製法と同様にして、流動状油脂組成物Jを得た。得られた流動状油脂組成物Jの油相のSFCは10℃で4%、20℃で3%であり、トランス脂肪酸含量は2質量%未満であり、実質的にトランス脂肪酸を含有していなかった。
得られた流動状油脂組成物Jは、ビスコメーター(TOKIMEC社製、6号ローター使用)で粘度を測定したところ、10℃から30℃の全ての温度において、粘度が20,000mPa・s〜200,000mPa・sであり、良好な流動性を呈していた。しかし、該流動状油脂組成物Jを、35℃に調温後、50mlビーカーに30g投入し、これを30℃の恒温槽に保管し、1週間後に固液分離の状況を観察したところ、液状成分の染みだしが極めて多く見られた。
また、得られた流動状油脂組成物Jを直径90mmのシャーレに50g投入し、15℃に12時間と35℃に12時間との温度サイクルで放置テストを行った。1週間放置後に固液分離の状況を観察したところ、液状成分の染みだしが極めて多く見られた。
[Comparative Example 3]
A fluid oil composition J was obtained in the same manner as in Example 1, except that the transesterified oil A was changed to the transesterified oil G. The SFC of the oil phase of the obtained fluid oil / fat composition J is 4% at 10 ° C., 3% at 20 ° C., the trans fatty acid content is less than 2% by mass, and substantially no trans fatty acid is contained. Was.
The viscosity of the obtained fluid oil / fat composition J was measured with a viscometer (manufactured by TOKIMEC, using a No. 6 rotor). The viscosity was 20,000 mPa · s to 200 at all temperatures from 10 ° C. to 30 ° C. 2,000 mPa · s, and exhibited good fluidity. However, after adjusting the temperature of the fluid oil / fat composition J to 35 ° C., 30 g was put into a 50 ml beaker, and this was stored in a thermostat at 30 ° C .. After one week, the state of solid-liquid separation was observed. The exudation of the components was extremely large.
In addition, 50 g of the obtained fluid oil / fat composition J was put into a petri dish having a diameter of 90 mm, and a standing test was performed at a temperature cycle of 12 hours at 15 ° C and 12 hours at 35 ° C. When the state of solid-liquid separation was observed after standing for one week, exudation of the liquid component was extremely large.

[比較例4]
エステル交換油脂Aをナタネ液状油に変更した以外は、実施例1の配合・製法と同様にして、流動状油脂組成物Kを得た。得られた流動状油脂組成物Kの油相のSFCは10℃で3%、20℃で3%であり、トランス脂肪酸含量は2質量%未満であり、実質的にトランス脂肪酸を含有していなかった。
得られた流動状油脂組成物Kは、ビスコメーター(TOKIMEC社製、6号ローター使用)で粘度を測定したところ、10℃から30℃の全ての温度において、粘度が20,000mPa・s〜200,000mPa・sであり、良好な流動性を呈していた。
また、得られた流動状油脂組成物Iを直径90mmのシャーレに50g投入し、15℃に12時間と35℃に12時間との温度サイクルで放置テストを行った。1週間放置後に固液分離の状況を観察したところ、液状成分の染みだしが極めて多く見られた。
[Comparative Example 4]
A fluid oil composition K was obtained in the same manner as in Example 1, except that the transesterified oil A was changed to rapeseed liquid oil. The SFC of the oil phase of the obtained fluid oil composition K is 3% at 10 ° C., 3% at 20 ° C., the trans fatty acid content is less than 2% by mass, and substantially no trans fatty acid is contained. Was.
The viscosity of the obtained fluid oil / fat composition K was measured with a viscometer (manufactured by TOKIMEC, using a No. 6 rotor), and the viscosity was 20,000 mPa · s to 200 m at all temperatures from 10 ° C. to 30 ° C. 2,000 mPa · s, and exhibited good fluidity.
In addition, 50 g of the obtained fluid oil / fat composition I was put into a petri dish having a diameter of 90 mm, and a standing test was performed at a temperature cycle of 15 ° C. for 12 hours and 35 ° C. for 12 hours. When the state of solid-liquid separation was observed after standing for one week, exudation of the liquid component was extremely large.

<クリーム状食品の製造>
得られた流動状油脂組成物A〜Kを使用して、下記の配合・製法に従い実施例8〜14及び比較例5〜8のシュガークリームを製造し、下記の評価基準に従って評価を行った。その結果を表1に記載した。
〔シュガークリームの配合・製法〕
流動状油脂組成物45質量部に、チーズパウダー20質量部、脱脂粉乳15質量部、コーンスターチ10質量部及び砂糖10質量部を混合して、シュガークリームを製造した。
<Manufacture of creamy foods>
Using the obtained fluid fat compositions A to K, sugar creams of Examples 8 to 14 and Comparative Examples 5 to 8 were produced according to the following formulation and production method, and evaluated according to the following evaluation criteria. The results are shown in Table 1.
[Sugar cream formulation and manufacturing method]
20 parts by mass of cheese powder, 15 parts by mass of skim milk powder, 10 parts by mass of corn starch and 10 parts by mass of sugar were mixed with 45 parts by mass of the fluid oil composition to prepare a sugar cream.

〔シュガークリームの評価〕
実施例8〜14及び比較例5〜8で得られたシュガークリームについて、口溶け、固液分離性及び耐熱保型性に関する評価を実施した。
口溶けは、25℃の品温に1晩調温したサンプルを用い、下記評価基準に従って4段階で評価した。
固液分離性は、35℃に調温したサンプルを50mlビーカーに30g投入し、これを30℃の恒温槽に保管し、1週間後に固液分離の状況を観察し、下記評価基準に従って4段階で評価した。
耐熱保型性は、サンプルを一旦25℃に調温し、これを絞り袋に入れ、菊型口金でシャーレに花型に絞り、蓋をし、これを5℃で60分調温後、20℃、25℃、30℃及び35℃の各恒温槽に一晩おき、ダレの状況を観察し、下記評価基準に従って4段階で評価した。
これらの結果を表1に示す。
[Evaluation of sugar cream]
The sugar creams obtained in Examples 8 to 14 and Comparative Examples 5 to 8 were evaluated for dissolution in the mouth, solid-liquid separation properties and heat-resistant mold retention properties.
The melting in the mouth was evaluated in four steps according to the following evaluation criteria using a sample whose temperature was adjusted to 25 ° C. overnight.
For solid-liquid separation, 30 g of a sample adjusted to 35 ° C. was put into a 50 ml beaker, and this was stored in a thermostat at 30 ° C., and one week later, the state of solid-liquid separation was observed. Was evaluated.
The heat-resistant mold retention was performed by temporarily adjusting the temperature of the sample to 25 ° C., placing the sample in a squeeze bag, squeezing the sample into a petri dish with a chrysanthemum die, closing the lid, and adjusting the temperature at 5 ° C. for 60 minutes. The samples were left overnight in a constant temperature bath at 25 ° C., 25 ° C., 30 ° C., and 35 ° C., the state of sagging was observed, and evaluated in four steps according to the following evaluation criteria.
Table 1 shows the results.

(口溶け評価基準)
◎ 大変良好
○ 良好
△ やや劣る
× 不良
(固液分離性評価基準)
◎ 液状成分の染みだしは全く見られなかった。
○ 若干の液状成分の染みだしが見られた。
△ かなりの液状成分の染みだしが見られ、またザラの発生も若干見られた。
× 液状成分の染みだし及びザラの発生がかなり見られた。
(耐熱保型性評価)
◎ ダレもなく、保型性は全く問題なし。
○ ややダレが見られるものの、形状は保っていた。
△ かなりのダレが見られ、保型性もやや悪い。
× ダレが激しく、保型性も悪い。
(Evaluation criteria for melting in mouth)
◎ Very good ○ Good △ Somewhat poor × Poor (Solid-liquid separation evaluation criteria)
染 No seepage of the liquid component was observed.
○ Some seepage of liquid components was observed.
Δ: A considerable amount of liquid components began to seep out, and some roughening was observed.
C: A considerable amount of seepage of liquid components and generation of grain were observed.
(Evaluation of heat retention)
◎ No sagging, no problem in shape retention.
○ Although some dripping was observed, the shape was maintained.
△ Significant sagging was observed and the shape retention was somewhat poor.
× Severe dripping and poor shape retention.

Figure 0006631990
Figure 0006631990

<魚肉加工食品の製造>
得られた流動状油脂組成物A〜Kを使用して、下記の配合・製法に従い実施例15〜21及び比較例9〜12のネギトロ様食品を製造し、下記の評価基準に従って評価を行った。その結果を表2に記載した。
<Manufacture of processed fish meat>
Using the obtained fluid oil / fat compositions A to K, the leek-like foods of Examples 15 to 21 and Comparative Examples 9 to 12 were produced according to the following formulation and production method, and evaluated according to the following evaluation criteria. . The results are shown in Table 2.

〔ネギトロ様食品の配合・製法〕
流動状油脂組成物15質量部に、ミンチ状の鮪赤身85質量部を混合し、ネギトロ様食品を製造した。
〔ネギトロ様食品の評価〕
実施例15〜21及び比較例9〜12で得られたネギトロ様食品について、下記の評価基準により、食感評価、風味評価及び物性評価を行い、結果を表2に記載した。
[Formulation and manufacturing method of negitro-like food]
85 parts by mass of minced tuna lean were mixed with 15 parts by mass of the fluid oil composition to produce a green onion-like food.
[Evaluation of negitro-like food]
With respect to the green onion-like foods obtained in Examples 15 to 21 and Comparative Examples 9 to 12, evaluation of texture, flavor and physical properties was performed according to the following evaluation criteria, and the results are shown in Table 2.

(食感の評価基準)
◎: 魚肉と油脂のなじみが大変良好で極めて良好な食感である。
○ :魚肉と油脂のなじみがよく、良好な食感である。
△:油脂がやや硬く若干の違和感のある食感である。
× :油脂が硬すぎ、違和感が強く不良な食感である。
×× :油脂が軟らかく、違和感が強く不良な食感である。
(風味の評価基準)
◎ 大変良好
○ 良好
△ やや劣る
× 不良
(物性の評価基準1)
◎ 液状油の染みだしは全く見られなかった。
○ 液状油の染みだしがわずかに見られた。
△ 若干の液状油の染みだしが見られた。
× かなりの液状油の染みだしが見られた。
(物性の評価基準2)
◎ ドリップの発生は全く見られなかった。
○ 若干のドリップが見られた。
△ ドリップがやや多く見られた。
× ドリップが多量に見られた。
(Evaluation criteria for texture)
◎: Fish and oils and fats blended very well and had a very good texture.
: Good compatibility between fish meat and oil and fat, and good texture.
Δ: The texture is slightly hard and slightly uncomfortable.
X: The fats and oils are too hard, the feeling of discomfort is strong and the texture is poor.
XX: The fats and oils are soft, the discomfort is strong, and the texture is poor.
(Flavor evaluation criteria)
◎ Very good ○ Good △ Somewhat poor × Poor (Evaluation criteria 1 for physical properties)
◎ No seepage of liquid oil was observed.
○ Slight seepage of liquid oil was observed.
Δ: Some seepage of liquid oil was observed.
C: Significant liquid oil seepage was observed.
(Evaluation criteria 2 for physical properties)
◎ No drip was observed.
○ Some drip was seen.
△ Some drip was seen.
D: A large amount of drip was observed.

Figure 0006631990
Figure 0006631990

Claims (5)

下記の(1)〜(3)の全てを満たすエステル交換油脂を油相中に、該油相中の全油脂量基準で50〜99質量%及び極度硬化油脂を油相基準で1〜5質量%含有し、且つ、該油相のSFCが、10℃で5〜20%であり、20℃で1〜10%であって、該油相を80〜100質量%(組成物基準)含有することを特徴とする、流動状油脂組成物。
(1)液状油と極度硬化油を、該液状油と該極度硬化油との合計量中の該極度硬化油の割合が12〜20質量%となるように配合してエステル交換したエステル交換油脂であって、該液状油が大豆油、菜種油、コーン油、綿実油、オリーブ油、落花生油、米油、べに花油、ハイオレイックサフラワー油、ひまわり油及びハイオレイックひまわり油からなる群から選択される1種又は2種以上であり、該極度硬化油がパーム油の極度硬化油及び/又はハイエルシンナタネ油の極度硬化油である。
(2)SFC(固体脂含量)が、0℃で5〜25%、20℃で1〜5%、40℃で0〜2%である。
(3)30℃において流動状である。
Transesterified fats and oils satisfying all of the following (1) to (3) are contained in an oil phase, and 50 to 99% by mass based on the total amount of fats and oils in the oil phase and 1 to 5% by mass of extremely hardened fats and oils based on the oil phase. %, And the SFC of the oil phase is 5 to 20% at 10 ° C and 1 to 10% at 20 ° C, and the oil phase contains 80 to 100% by mass (composition basis). A fluid oil or fat composition, characterized in that:
(1) Transesterified fats and oils obtained by blending a liquid oil and an extremely hardened oil such that the ratio of the extremely hardened oil to the total amount of the liquid oil and the extremely hardened oil is 12 to 20 % by mass. Wherein the liquid oil is selected from the group consisting of soybean oil, rapeseed oil, corn oil, cottonseed oil, olive oil, peanut oil, rice oil, potato flower oil, high oleic safflower oil, sunflower oil and high oleic sunflower oil Species or two or more kinds, wherein the extremely hardened oil is an extremely hardened oil of palm oil and / or an extremely hardened oil of Hyercinna rapeseed oil.
(2) SFC (solid fat content) is 5 to 25% at 0 ° C, 1 to 5% at 20 ° C, and 0 to 2% at 40 ° C.
(3) It is fluid at 30 ° C.
10〜30℃の全ての温度において、粘度が20,000〜200,000mPa・sであることを特徴とする請求項1に記載の流動状油脂組成物。   The fluid fat composition according to claim 1, wherein the viscosity is 20,000 to 200,000 mPa · s at all temperatures of 10 to 30 ° C. トランス脂肪酸が、油脂組成物の使用油脂の全構成脂肪酸中10質量%未満であることを特徴とする請求項1又は2に記載の流動状油脂組成物。   The fluid fat or oil composition according to claim 1 or 2, wherein the trans fatty acid is less than 10% by mass in all constituent fatty acids of the fat and oil used in the fat and oil composition. 請求項1〜3の何れか1項に記載の流動状油脂組成物を含有することを特徴とするクリーム状食品。   A creamy food comprising the fluid fat composition according to any one of claims 1 to 3. 請求項1〜3の何れか1項に記載の流動状油脂組成物を含有することを特徴とする魚肉加工食品。   A processed fish meat food comprising the fluid fat composition according to any one of claims 1 to 3.
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