JP6570605B2 - Flavor improving ingredients - Google Patents

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JP6570605B2
JP6570605B2 JP2017234242A JP2017234242A JP6570605B2 JP 6570605 B2 JP6570605 B2 JP 6570605B2 JP 2017234242 A JP2017234242 A JP 2017234242A JP 2017234242 A JP2017234242 A JP 2017234242A JP 6570605 B2 JP6570605 B2 JP 6570605B2
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flavor improving
reifolin
sweetness
ppm
methyloxan
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JP2018038427A (en
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ジェラン ジャン−リュック
ジェラン ジャン−リュック
ドゥラトル マキシム
ドゥラトル マキシム
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Firmenich SA
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/20Synthetic spices, flavouring agents or condiments
    • A23L27/205Heterocyclic compounds
    • A23L27/2052Heterocyclic compounds having oxygen or sulfur as the only hetero atoms
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23FCOFFEE; TEA; THEIR SUBSTITUTES; MANUFACTURE, PREPARATION, OR INFUSION THEREOF
    • A23F5/00Coffee; Coffee substitutes; Preparations thereof
    • A23F5/24Extraction of coffee; Coffee extracts; Making instant coffee
    • A23F5/36Further treatment of dried coffee extract; Preparations produced thereby, e.g. instant coffee
    • A23F5/40Further treatment of dried coffee extract; Preparations produced thereby, e.g. instant coffee using organic additives, e.g. milk, sugar
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/02Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation containing fruit or vegetable juices
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • A23L2/56Flavouring or bittering agents
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • A23L2/60Sweeteners
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/10Natural spices, flavouring agents or condiments; Extracts thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/10Natural spices, flavouring agents or condiments; Extracts thereof
    • A23L27/12Natural spices, flavouring agents or condiments; Extracts thereof from fruit, e.g. essential oils
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/10Natural spices, flavouring agents or condiments; Extracts thereof
    • A23L27/12Natural spices, flavouring agents or condiments; Extracts thereof from fruit, e.g. essential oils
    • A23L27/13Natural spices, flavouring agents or condiments; Extracts thereof from fruit, e.g. essential oils from citrus fruits
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/30Artificial sweetening agents
    • A23L27/33Artificial sweetening agents containing sugars or derivatives
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/86Addition of bitterness inhibitors
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/88Taste or flavour enhancing agents
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Food Science & Technology (AREA)
  • Nutrition Science (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Seasonings (AREA)
  • Tea And Coffee (AREA)
  • Non-Alcoholic Beverages (AREA)
  • Fats And Perfumes (AREA)

Description

本発明は、風味改良成分に関する。本発明は、さらに、食料品における風味改良成分の使用、及び風味改良成分を含有する風味改良組成物に関する。   The present invention relates to a flavor improving ingredient. The present invention further relates to the use of a flavor improving ingredient in a food product and a flavor improving composition containing the flavor improving ingredient.

糖は、人間用の食品調製物における一般的な甘味添加剤である。糖に関しては、スクロースが理解されるが、しかし他の慣用的に使用されるカロリーが豊富な甘味添加剤、例えばグルコース、フルクトース、及び高フルクトースコーンシロップも理解される。糖の過剰消費が、齲歯及び肥満を含む最も一般的である健康に対する種々の逆効果の公知の原因であることがよく確立されているにもかかわらず、一般的な栄養補給は、糖の過剰消費を示す傾向がある。   Sugar is a common sweetening additive in human food preparations. With respect to sugar, sucrose is understood, but other commonly used calorie rich sweeteners such as glucose, fructose, and high fructose corn syrup are also understood. Despite well established that sugar overconsumption is a known cause of various adverse health effects, including caries and obesity, general nutritional supplementation There is a tendency to show consumption.

今日までに、種々の生成物が、これらの問題に対処するために提案されている。例えば、非常に低い投与量で甘味を提供する人工の高濃度の甘味料が開発されている。既に市場に存在する高濃度の甘味料のうち、スクラロース(登録商標)、アスパルテーム、アセスルファムカリウム、シクラメート、サッカリンが、周知の代替物として挙げられる。しかしながら、増え続ける消費者数によって、天然の又は天然由来の生成物がその人工対応物よりも強く望まれる。従って、この消費者の要求を満たす生成物を提供することが強く望まれる。   To date, various products have been proposed to address these problems. For example, artificially high concentrations of sweeteners have been developed that provide sweetness at very low dosages. Among the high-concentration sweeteners already on the market, sucralose®, aspartame, acesulfame potassium, cyclamate, saccharin are well known alternatives. However, with the ever increasing number of consumers, natural or naturally derived products are more desirable than their artificial counterparts. It is therefore highly desirable to provide a product that meets this consumer demand.

天然に生じる甘味料の分類内で、ますます多くの生成物が使用可能になっている。例えば、タウマチン、羅漢果、ブラゼイン、クルクリン、グリチルリチン及びステビアを含む。   Within the category of naturally occurring sweeteners, more and more products are available. For example, thaumatin, Luohan fruit, brazein, curculin, glycyrrhizin and stevia.

ロイフォリンは、シトラス・ベルガミア(ベルガモット)の果汁中に見出される化合物である。我々の知る限り、この化合物は、甘味を増加させるための風味改良成分としてこれまでに定義されていない。   Reifolin is a compound found in the juice of citrus bergamia (bergamot). To the best of our knowledge, this compound has not been previously defined as a flavor improving ingredient to increase sweetness.

ある食料品及び飲料の苦味を減少させることも望まれる。我々の知る限り、ロイフォリンは、苦味を減少させるための風味改良成分としてこれまでに定義されていない。   It is also desirable to reduce the bitterness of certain food products and beverages. To the best of our knowledge, reifolin has never been defined as a flavor improving ingredient to reduce bitterness.

従って、本発明に従って、風味改良成分として、7−[4,5−ジヒドロキシ−6−(ヒドロキシメチル)−3−(3,4,5−トリヒドロキシ−6−メチルオキサン−2−イル)オキシオキサン−2−イル]オキシ−5−ヒドロキシ−2−(4−ヒドロキシフェニル)クロメン−4−オンの使用が提供される。   Therefore, according to the present invention, 7- [4,5-dihydroxy-6- (hydroxymethyl) -3- (3,4,5-trihydroxy-6-methyloxan-2-yl) oxyoxane-2 as a flavor improving ingredient Use of -yl] oxy-5-hydroxy-2- (4-hydroxyphenyl) chromen-4-one is provided.

本発明の目的のために、7−[4,5−ジヒドロキシ−6−(ヒドロキシメチル)−3−(3,4,5−トリヒドロキシ−6−メチルオキサン−2−イル)オキシオキサン−2−イル]オキシ−5−ヒドロキシ−2−(4−ヒドロキシフェニル)クロメン−4−オンは、本明細書において“ロイフォリン”ともいわれる。   For purposes of the present invention, 7- [4,5-dihydroxy-6- (hydroxymethyl) -3- (3,4,5-trihydroxy-6-methyloxan-2-yl) oxyxan-2-yl] Oxy-5-hydroxy-2- (4-hydroxyphenyl) chromen-4-one is also referred to herein as “reifolin”.

本発明は、さらに、有効量のロイフォリンを含有する風味改良組成物を提供する。   The present invention further provides a flavor improving composition containing an effective amount of reifolin.

本発明は、食料品又は飲料の苦味を、それらにロイフォリン添加することによって低減させる又は隠す方法も提供する。   The present invention also provides a method for reducing or concealing the bitter taste of foodstuffs or beverages by adding leuforin to them.

本発明は、食料品又は飲料の甘味を、それらにロイフォリン添加することによって増加させる方法も提供する。   The present invention also provides a method for increasing the sweetness of a food product or beverage by adding leuforin to them.

食料品又は飲料において、ロイフォリンは、5〜300ppmの範囲内の量で存在してよい。   In food products or beverages, leuforin may be present in an amount in the range of 5 to 300 ppm.

好ましくは、ロイフォリンは、5〜200ppm、より好ましくは5〜150ppm、最も好ましくは10〜100ppmの濃度で存在する。   Preferably, leuporin is present at a concentration of 5-200 ppm, more preferably 5-150 ppm, and most preferably 10-100 ppm.

ロイフォリンは市販されており、かつ例えばInterquim(Spain)社から購入できる。   Reifolin is commercially available and can be purchased from, for example, Interquim (Spain).

ロイフォリンは、苦味を減少させること及び/又は甘味を増加させることが望まれる多くの生成物中で使用できる。その例としては、限定されずに、茶、コーヒー、フルーツジュース及びフルーツ味の飲料、ジャム及びゼリー、ピーナッツバター、パイ、プリン、シリアル、飴、アイスクリーム、ヨーグルト、ベーカリー製品;ヘルスケア製品、例えば歯磨き粉、洗口剤、咳止めドロップ、咳止めシロップ;チューイングガム;並びに糖代替物を含む。   Reifolin can be used in many products where it is desired to reduce bitterness and / or increase sweetness. Examples include, but are not limited to, tea, coffee, fruit juices and fruit flavored beverages, jams and jelly, peanut butter, pie, pudding, cereals, strawberries, ice cream, yogurt, bakery products; health care products such as Includes toothpaste, mouthwash, cough drop, cough syrup; chewing gum; and sugar substitute.

本発明を、次の実施例に関連して説明する。全ての量は、特に明記されない限り質量%である。   The invention will now be described in connection with the following examples. All amounts are weight percent unless otherwise specified.

実施例1
グレープフルーツジュース中でのロイフォリンの適用
種々の試料を、以下の表において示した成分を使用して製造した(量は質量%である)。
Example 1
Application of Reifolin in Grapefruit Juice Various samples were made using the ingredients shown in the table below (quantities in weight percent).

Figure 0006570605
Figure 0006570605

ロイフォリンを、十分なプロピレングリコール(PG)中に秤量し、完全に溶解させ、そして40℃で30分間水浴中で、ロイフォリンが完全に可溶化するまで加熱した。そして、グレープフルーツジュースを、ロイフォリン溶液と混合し、そしてその混合物を室温で1時間維持して、感能検査を実施した。   Reifolin was weighed into enough propylene glycol (PG), completely dissolved and heated in a water bath at 40 ° C. for 30 minutes until the reifolin was completely solubilized. Grapefruit juice was then mixed with a reifolin solution, and the mixture was maintained at room temperature for 1 hour to perform a sensitivity test.

感能検査を、以下のように実施した:
6人の訓練したパネリストに、ブラインド条件下で、5点の強度の評定尺度(0は強度がないことを示し、かつ5は著しい強度を示す)を使用して、前記で製造した試料の甘味、苦味及びフレーバー強度を評価させた。
The sensitivity test was performed as follows:
Six trained panelists were asked to use the 5-point intensity rating scale (0 indicates no intensity and 5 indicates significant intensity) under blind conditions using the sweetness of the sample prepared above. Bitterness and flavor strength were evaluated.

平均強度の点数を、FIZZ統計ソフトウェアを使用して、平均比較Duncan試験について処理した。   Average intensity scores were processed for the average comparative Duncan test using FIZZ statistical software.

結果を以下の表において示す:

Figure 0006570605
The results are shown in the following table:
Figure 0006570605

この結果は、ロイフォリンの添加が、苦味を減少させ、かつ甘味を増加させた一方で、フレーバー強度は、実質的に変化しないままであったことを証明する。   This result demonstrates that the addition of reifolin decreased bitterness and increased sweetness, while the flavor intensity remained substantially unchanged.

実施例2
スクロースを有さないコーヒー生成物中でのロイフォリンの適用
種々の試料を、以下の表において示した成分を使用して製造した(量は質量%である)。
Example 2
Application of reifolin in coffee products without sucrose Various samples were made using the ingredients shown in the table below (quantities in weight percent).

Figure 0006570605
Figure 0006570605

ロイフォリンを、十分なプロピレングリコール(PG)中に秤量し、完全に溶解させ、そして40℃で30分間水浴中で、ロイフォリンが完全に可溶化するまで加熱した。インスタントコーヒーを秤量し、そして水中に導入した。室温で可溶化した。   Reifolin was weighed into enough propylene glycol (PG), completely dissolved and heated in a water bath at 40 ° C. for 30 minutes until the reifolin was completely solubilized. Instant coffee was weighed and introduced into the water. Solubilized at room temperature.

その混合物を室温で1時間維持して、感能検査を実施した。   The mixture was maintained at room temperature for 1 hour and a sensitivity test was performed.

感能検査を、以下のように実施した:
6人の訓練したパネリストに、ブラインド条件下で、5点の強度の評定尺度(0は強度がないことを示し、かつ5は著しい強度を示す)を使用して、前記で製造した試料の甘味、苦味及びコーヒーの強度を評価させた。
The sensitivity test was performed as follows:
Six trained panelists were asked to use the 5-point intensity rating scale (0 indicates no intensity and 5 indicates significant intensity) under blind conditions using the sweetness of the sample prepared above. Bitterness and coffee strength were evaluated.

平均強度の点数を、FIZZ統計ソフトウェアを使用して、平均比較Duncan試験について処理した。   Average intensity scores were processed for the average comparative Duncan test using FIZZ statistical software.

結果を以下の表において示す:

Figure 0006570605
The results are shown in the following table:
Figure 0006570605

この結果は、5ppmより多くのロイフォリンが、ある適用のために存在することが好ましいことを証明する。   This result demonstrates that it is preferred that more than 5 ppm of reifolin be present for certain applications.

Claims (3)

風味改良成分としての、7−[4,5−ジヒドロキシ−6−(ヒドロキシメチル)−3−(3,4,5−トリヒドロキシ−6−メチルオキサン−2−イル)オキシオキサン−2−イル]オキシ−5−ヒドロキシ−2−(4−ヒドロキシフェニル)クロメン−4−オンの使用であって、7−[4,5−ジヒドロキシ−6−(ヒドロキシメチル)−3−(3,4,5−トリヒドロキシ−6−メチルオキサン−2−イル)オキシオキサン−2−イル]オキシ−5−ヒドロキシ−2−(4−ヒドロキシフェニル)クロメン−4−オンが、10〜100ppmの量で存在し、前記風味改良が、苦味を減少させる及び/又は甘味を増加させることを含む、前記使用。 7- [4,5-dihydroxy-6- (hydroxymethyl) -3- (3,4,5-trihydroxy-6-methyloxan-2-yl) oxyoxan-2-yl] oxy- as a flavor improving ingredient Use of 5-hydroxy-2- (4-hydroxyphenyl) chromen-4-one comprising 7- [4,5-dihydroxy-6- (hydroxymethyl) -3- (3,4,5-trihydroxy -6-methyloxan-2-yl) oxyoxan-2-yl] oxy-5-hydroxy-2- (4-hydroxyphenyl) chromen-4-one is present in an amount of 10 to 100 ppm , the flavor improvement is Said use comprising reducing bitterness and / or increasing sweetness . 7−[4,5−ジヒドロキシ−6−(ヒドロキシメチル)−3−(3,4,5−トリヒドロキシ−6−メチルオキサン−2−イル)オキシオキサン−2−イル]オキシ−5−ヒドロキシ−2−(4−ヒドロキシフェニル)クロメン−4−オンを10〜100ppm含む風味改良組成物であって、前記風味改良が、苦味を減少させる及び/又は甘味を増加させることを含む、前記風味改良組成物7- [4,5-Dihydroxy-6- (hydroxymethyl) -3- (3,4,5-trihydroxy-6-methyloxan-2-yl) oxyoxan-2-yl] oxy-5-hydroxy-2- A flavor improving composition comprising 10 to 100 ppm of (4-hydroxyphenyl) chromen-4-one , wherein the flavor improving comprises reducing bitterness and / or increasing sweetness . 食料品又は飲料に7−[4,5−ジヒドロキシ−6−(ヒドロキシメチル)−3−(3,4,5−トリヒドロキシ−6−メチルオキサン−2−イル)オキシオキサン−2−イル]オキシ−5−ヒドロキシ−2−(4−ヒドロキシフェニル)クロメン−4−オンを10〜100ppm添加することによって、食料品又は飲料の苦味を減少させる又は隠す、及び/又は食料品又は飲料の甘味を増加させる方法。   7- [4,5-dihydroxy-6- (hydroxymethyl) -3- (3,4,5-trihydroxy-6-methyloxan-2-yl) oxyoxan-2-yl] oxy-5 for food or beverage A method for reducing or concealing the bitter taste of a food or beverage and / or increasing the sweetness of a food or beverage by adding 10-100 ppm of hydroxy-2- (4-hydroxyphenyl) chromen-4-one .
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