JP6444257B2 - Livestock litter - Google Patents

Livestock litter Download PDF

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JP6444257B2
JP6444257B2 JP2015096078A JP2015096078A JP6444257B2 JP 6444257 B2 JP6444257 B2 JP 6444257B2 JP 2015096078 A JP2015096078 A JP 2015096078A JP 2015096078 A JP2015096078 A JP 2015096078A JP 6444257 B2 JP6444257 B2 JP 6444257B2
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foam
litter
bedding
alkaline substance
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豊 上原
豊 上原
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豊和直 株式会社
豊和直 株式会社
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/70Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in livestock or poultry

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Description

本発明は、家畜の疾病予防を目的として使用される家畜用敷料に関する。   The present invention relates to a livestock bedding used for the purpose of preventing disease of livestock.

従来、牛舎、豚舎、厩舎等家畜舎において、快適かつ清潔な環境下で家畜を飼育すべく、家畜の飼育に供される床面に、家畜用敷料が用いられてきた。
かかる家畜用敷料としては、稲わら、麦桿、おが屑、籾殻、木材チップ、バーク、樹皮、紙、ヤシ殻チップ、リサイクル堆肥、砂、パルプスラッジ等の各種材料が用いられているが、家畜の糞尿等により汚染され、大腸菌群等の微生物が増殖し、下痢等の疾病を誘発する場合がある。
大腸菌群等による下痢等の発生は、特に養豚業において生産性の悪化につながる。
Conventionally, livestock litter has been used on the floor surface for raising livestock in livestock houses such as cowsheds, pig houses, stables, etc., in order to raise livestock in a comfortable and clean environment.
As such livestock litter, various materials such as rice straw, wheat straw, sawdust, rice husk, wood chips, bark, bark, paper, coconut shell chips, recycled compost, sand and pulp sludge are used. Contaminated by manure, etc., microorganisms such as coliforms may grow and cause diseases such as diarrhea.
Occurrence of diarrhea due to coliforms and the like leads to deterioration of productivity particularly in the pig farming industry.

また、コロナウイルス等のウイルスによる疾病の発生も、問題となる。たとえば、豚流行性下痢(PED)は、2013年10月に沖縄県で、11月に茨城県で発見されて以来、今日まで流行が続いている。外国でも、米国をはじめカナダなどで、多大な感染被害が報告されている。PEDは、コロナウイルス科(Coronaviridae)アルファコロナウイルス属(Alphacoronavirus)に属するPEDウイルスが病原体で、主に糞便を介して経口感染し、汚染器具を介した感染もあるといわれる。PEDには、すべての日齢の豚が罹患するが、特に若齢豚で症状が重篤化しやすく、哺乳豚での死亡率は100%に達することがある。若齢豚におけるPEDの全国規模の流行は、養豚業の経営を圧迫する。   In addition, the occurrence of diseases caused by viruses such as coronavirus is also a problem. For example, swine epidemic diarrhea (PED) has been in fashion since it was discovered in Okinawa Prefecture in October 2013 and in Ibaraki Prefecture in November. Even in foreign countries, significant infection damage has been reported in the United States, Canada, and other countries. PED is a pathogen of PED virus belonging to the genus Coronaviridae (Alphacoronavirus). It is said that PED is orally infected mainly through stool and is also infected through contaminated devices. PED affects pigs of all ages, but symptoms are particularly severe in young pigs, and mortality in suckling pigs can reach 100%. The national epidemic of PED in young pigs puts pressure on the pig farming business.

牛、馬、豚などの家畜は、生まれてから1〜2ヶ月の期間が非常に大事であり、この時期に健康を維持させることができれば、生産効率が非常に高くなる。このような事案に即刻対応できるものはないか、様々な角度から研究開発がなされている。   Livestock such as cattle, horses, and pigs is very important for a period of 1 to 2 months from birth. If health can be maintained at this time, production efficiency will be very high. R & D is being conducted from various angles to see if there is anything that can respond immediately to such a case.

大腸菌群等の細菌に対する抗菌作用を付与した家畜用敷料としては、たとえば、コーヒー抽出粕と、水分含量が20%以下のおが屑を含有する家畜飼育用敷料(特許文献1)や、敷料基材に、キトサンと抗菌性銀とを含浸させた動物飼育用消臭抗菌敷料(特許文献2)が提案されており、ウイルス感染防止効果を付与した家畜用敷料としては、多孔構造を有する無機酸化物の粒子の表面及び細孔に、光触媒機能を有する微粒子が担持されてなる砂状粒子から構成される家畜・家禽用敷料(特許文献3)が提案されている。   Examples of livestock litter that has been given antibacterial action against bacteria such as coliform bacteria include, for example, coffee-extracted straw and livestock breeding litter containing 20% or less of sawdust with a moisture content of less than 20%. In addition, a deodorizing antibacterial litter for animal breeding impregnated with chitosan and antibacterial silver (Patent Document 2) has been proposed, and as a livestock litter imparted with a virus infection preventing effect, an inorganic oxide having a porous structure A litter for livestock and poultry (Patent Document 3) composed of sand-like particles in which fine particles having a photocatalytic function are supported on the surface and pores of the particles is proposed.

しかし、家畜の糞尿等の吸収性に優れ、皮膚等に対する刺激性が低いとともに、粉じんの発生等、取扱いにおける問題が少なく、さらに、大腸菌等の細菌やウイルスに対して、十分な抗菌作用および抗ウイルス作用を示し、簡便かつ安価に調製できる家畜用敷料が望まれている。   However, it excels in absorbability of livestock manure, etc., has low irritation to skin, etc., has few problems in handling such as generation of dust, and has sufficient antibacterial and antibacterial activity against bacteria and viruses such as E. coli. There is a demand for a livestock litter that exhibits a virus action and can be prepared easily and inexpensively.

特開2005−287369号公報JP 2005-287369 A 特開2009−124952号公報JP 2009-124952 A 特開2013−106561号公報JP 2013-106561 A

そこで、本発明は、大腸菌等の細菌に対する抗菌活性および抗ウイルス活性に優れ、特に子豚等、若齢期の家畜の疾病による肥育効率の低下を飛躍的に改善し得る家畜用敷料を提供することを目的とする。   Therefore, the present invention provides a livestock litter that is excellent in antibacterial activity and antiviral activity against bacteria such as Escherichia coli, and can dramatically improve the reduction in fattening efficiency due to diseases of young animals such as piglets. For the purpose.

本発明者は、火山噴出物発泡体および無機アルカリ性物質を含有する機能性材料組成物が、二酸化炭素および揮発性有機化合物吸着能や調湿機能を有することをすでに開示している(特開2013−63866号公報)。今回、上記課題を解決すべく鋭意研究した結果、火山噴出物発泡体と無機アルカリ性物質との混合重量比を1:0.01〜1:0.5とした組成物を家畜用敷料に用いることにより、大腸菌等の細菌やウイルスを除去する機能が高まることを見出し、本発明を完成するに至った。   The present inventor has already disclosed that a functional material composition containing a volcanic ejecta foam and an inorganic alkaline substance has a carbon dioxide and volatile organic compound adsorption ability and a humidity control function (Japanese Patent Laid-Open No. 2013). -63866). As a result of diligent research to solve the above problems, a composition in which the mixing weight ratio of the volcanic ejecta foam and the inorganic alkaline substance is 1: 0.01 to 1: 0.5 is used for the livestock litter. Thus, the inventors have found that the function of removing bacteria such as Escherichia coli and viruses is enhanced, and have completed the present invention.

すなわち本発明は、以下の通りである。
[1](A)火山噴出物発泡体および(B)無機アルカリ性物質を、(A)と(B)の重量比[(A):(B)]が1:0.01〜1:0.5となるように含有する組成物を含有してなる、家畜用敷料。
[2]火山噴出物発泡体が、シラス発泡体、黒曜石発泡体および真珠岩発泡体からなる群より選択される少なくとも1種である、[1]に記載の家畜用敷料。
[3]無機アルカリ性物質が、水酸化ナトリウム、水酸化カリウム、水酸化マグネシウム、水酸化カルシウム、ケイ酸ナトリウム、ケイ酸カリウム、ケイ酸マグネシウム、ケイ酸カルシウム、炭酸ナトリウム、炭酸カリウム、炭酸マグネシウムおよび炭酸カルシウムからなる群より選択される少なくとも1種である、[1]または[2]に記載の家畜用敷料。
[4](A)火山噴出物発泡体および(B)無機アルカリ性物質を含有する組成物が、二酸化炭素により固化されている、[1]〜[3]のいずれかに記載の家畜用敷料。
[5](A)火山噴出物発泡体および(B)無機アルカリ性物質を含有する組成物が粉状または粒状である、[1]〜[4]のいずれかに記載の家畜用敷料。
[6](A)火山噴出物発泡体および(B)無機アルカリ性物質を含有する組成物の平均粒子径が50μm〜1,000μmである、[5]に記載の家畜用敷料。
[7]分娩舎、保温箱および肥育舎の少なくとも1箇所において使用される、[1]〜[6]のいずれかに記載の家畜用敷料。
That is, the present invention is as follows.
[1] The weight ratio [(A) :( B)] between (A) and (B) of (A) volcanic ejecta foam and (B) inorganic alkaline substance is 1: 0.01-1: 0. A livestock bedding comprising a composition that is contained to be 5.
[2] The livestock litter according to [1], wherein the volcanic ejecta foam is at least one selected from the group consisting of shirasu foam, obsidian foam, and nacreous foam.
[3] The inorganic alkaline substance is sodium hydroxide, potassium hydroxide, magnesium hydroxide, calcium hydroxide, sodium silicate, potassium silicate, magnesium silicate, calcium silicate, sodium carbonate, potassium carbonate, magnesium carbonate and carbonic acid. The livestock litter according to [1] or [2], which is at least one selected from the group consisting of calcium.
[4] The livestock litter according to any one of [1] to [3], wherein the composition containing (A) a volcanic ejecta foam and (B) an inorganic alkaline substance is solidified with carbon dioxide.
[5] The livestock litter according to any one of [1] to [4], wherein the composition containing (A) a volcanic ejecta foam and (B) an inorganic alkaline substance is powdery or granular.
[6] The livestock litter according to [5], wherein an average particle size of the composition containing (A) a volcanic ejecta foam and (B) an inorganic alkaline substance is 50 μm to 1,000 μm.
[7] The livestock litter according to any one of [1] to [6], which is used in at least one place of a delivery house, a heat insulation box, and a fattening house.

本発明によれば、大腸菌等の病原性細菌に対する抗菌活性および抗ウイルス活性に優れ、家畜の疾病の予防効果が高く、吸水性および揮発性有機化合物等の吸着性が良好で、臭気の抑制効果にも優れる家畜用敷料を提供することができる。
また本発明の家畜用敷料は、簡便に製造でき、火山噴出物を使用するため安価に提供することができる。
さらに、本発明の家畜用敷料は、堆肥化を阻害しないため、堆肥としての再利用にも適する。
According to the present invention, it has excellent antibacterial activity and antiviral activity against pathogenic bacteria such as Escherichia coli, is highly effective in preventing diseases of livestock, has good absorbency of water absorption and volatile organic compounds, etc., and suppresses odor It is also possible to provide an excellent livestock bedding.
In addition, the livestock litter of the present invention can be easily produced and can be provided at low cost because it uses volcanic ejecta.
Furthermore, since the livestock litter of the present invention does not inhibit composting, it is also suitable for reuse as compost.

図1は、実施例2の家畜用敷料に用いられる組成物について、二酸化炭素吸着性の評価結果を示す図である。FIG. 1 is a graph showing the carbon dioxide adsorptivity evaluation results for the composition used for the livestock bedding of Example 2. FIG. 図2は、実施例2の家畜用敷料に用いられる組成物について、揮発性有機化合物吸着性の評価結果を示す図である。FIG. 2 is a diagram showing the evaluation results of the volatile organic compound adsorptivity for the composition used in the livestock litter of Example 2.

本発明の家畜用敷料は、(A)火山噴出物発泡体および(B)無機アルカリ性物質を、(A)と(B)の重量比([A]:[B])が1:0.01〜1:0.5となるように含有する組成物(以下、「本発明の敷料用組成物」と称することもある)を含有してなる。   The livestock litter of the present invention comprises (A) a volcanic product foam and (B) an inorganic alkaline substance, wherein the weight ratio ([A]: [B]) of (A) and (B) is 1: 0.01. A composition containing ˜1: 0.5 (hereinafter sometimes referred to as “the composition for a bedding of the present invention”) is contained.

本発明の敷料用組成物において用いる(A)火山噴出物発泡体は、火山噴出物の細粒や粉末を700℃〜1,100℃程度、好ましくは850℃〜1,000℃程度に加熱して発泡させることにより得られる。
上記火山噴出物発泡体の調製に用いる火山噴出物は、火山活動の際に地表に噴出した物質であり、火山灰、火山礫等の火山砕屑物などが含まれる。本発明の目的には、火山噴出物として、シラス、軽石、ボラ土、黒曜石、真珠岩等が好ましく用いられる。なかでもシラス、黒曜石、真珠岩がより好ましい。
The (A) volcanic ejecta foam used in the composition for a litter of the present invention is obtained by heating fine particles and powder of the volcanic ejecta to about 700 ° C. to 1,100 ° C., preferably about 850 ° C. to 1,000 ° C. Obtained by foaming.
The volcanic ejecta used for the preparation of the above volcanic ejecta foam is a substance ejected to the ground surface during volcanic activity, and includes volcanic debris such as volcanic ash and volcanic gravel. For the purposes of the present invention, shirasu, pumice, mullet, obsidian, nacre, etc. are preferably used as volcanic ejecta. Of these, shirasu, obsidian, and pearlite are more preferred.

本発明においては、(A)火山噴出物発泡体として、上記した火山噴出物の細粒や粉末の発泡体より1種または2種以上を選択して用いることができるが、なかでもシラスを発泡させたシラス発泡体(シラスバルーン)、黒曜石の発泡体(パーライト)および真珠岩の発泡体(パーライト)が好ましく、敷料用組成物の多孔性を保持するための強度に優れる点で、シラス発泡体がより好ましい。   In the present invention, as (A) volcanic ejecta foam, one or two or more types can be selected from the above-mentioned volcanic ejector fine particles and powdered foams. Shirasu foam (shirasu balloon), obsidian foam (perlite) and nacreous foam (perlite) are preferred, and shirasu foam is superior in strength for maintaining the porosity of the composition for bedding. Is more preferable.

本発明の敷料用組成物に用いる(A)火山噴出物発泡体の平均粒子径は、通常シラス発泡体で5μm〜300μm、黒曜石発泡体で50μm〜3,000μm、真珠岩発泡体で50μm〜3,000μmであり、好ましくはシラス発泡体で30μm〜200μm、黒曜石発泡体で50μm〜300μm、真珠岩発泡体で50μm〜300μmである。
なお、上記平均粒子径は、後述する篩い分け法で測定し、算出した値である。
The average particle size of (A) volcanic product foam used in the laying composition of the present invention is usually 5 μm to 300 μm for shirasu foam, 50 μm to 3,000 μm for obsidian foam, and 50 μm to 3 for nacreous foam. 1,000 μm, preferably 30 μm to 200 μm for shirasu foam, 50 μm to 300 μm for obsidian foam, and 50 μm to 300 μm for nacreous foam.
In addition, the said average particle diameter is the value calculated and measured by the sieving method mentioned later.

本発明の敷料用組成物において用いる(B)無機アルカリ性物質としては、水酸化ナトリウム、水酸化カリウム等のアルカリ金属の水酸化物、水酸化マグネシウム、水酸化カルシウム等のアルカリ土類金属の水酸化物、ケイ酸ナトリウム、ケイ酸カリウム等のケイ酸のアルカリ金属塩、ケイ酸マグネシウム、ケイ酸カルシウム等のケイ酸のアルカリ土類金属塩、炭酸ナトリウム、炭酸カリウム等の炭酸のアルカリ金属塩、炭酸マグネシウム、炭酸カルシウム等の炭酸のアルカリ土類金属塩等が挙げられ、これらより、1種を選択して単独で、または2種以上を混合して用いてもよい。
本発明の目的には、(B)無機アルカリ性物質として、ケイ酸のアルカリ金属塩が好ましく用いられ、ケイ酸ナトリウムおよびケイ酸カリウムがより好ましく用いられる。
なお、(B)無機アルカリ性物質は、粉末の状態で用いてもよく、水溶液として用いてもよい。
Examples of the inorganic alkaline substance (B) used in the composition for bedding according to the present invention include hydroxides of alkali metals such as sodium hydroxide and potassium hydroxide, and hydroxides of alkaline earth metals such as magnesium hydroxide and calcium hydroxide. , Alkali metal salts of silicic acid such as sodium silicate and potassium silicate, alkaline earth metal salts of silicic acid such as magnesium silicate and calcium silicate, alkali metal salts of carbonic acid such as sodium carbonate and potassium carbonate, carbonic acid Examples thereof include alkaline earth metal salts of carbonic acid such as magnesium and calcium carbonate. One of these may be selected and used alone or in admixture of two or more.
For the purpose of the present invention, as the (B) inorganic alkaline substance, an alkali metal salt of silicic acid is preferably used, and sodium silicate and potassium silicate are more preferably used.
In addition, (B) inorganic alkaline substance may be used in the state of a powder, and may be used as aqueous solution.

本発明の敷料用組成物は、(A)火山噴出物発泡体および(B)無機アルカリ性物質を、(A)と(B)の重量比([A]:[B])が1:0.01〜1:0.5となるように含有する。前記(A)と(B)の重量比([A]:[B])は、1:0.02〜1:0.4であることが好ましく、1:0.02〜1:0.3であることがより好ましい。
(A)火山噴出物発泡体に対する(B)無機アルカリ性物質の重量比([B]/[A])が0.01よりも小さいと、抗菌活性および抗ウイルス活性が低下し、好ましくない。一方、(A)火山噴出物発泡体に対する(B)無機アルカリ性物質の重量比([B]/[A])が0.5よりも大きいと、家畜用敷料を食べた家畜に食欲不振や腸への悪影響が生じるおそれがあり、また、コストアップになり、経済性の面で好ましくない。
The composition for litter of the present invention comprises (A) a volcanic ejecta foam and (B) an inorganic alkaline substance, wherein the weight ratio ([A]: [B]) between (A) and (B) is 1: 0. It contains so that it may become 01-1: 0.5. The weight ratio ([A]: [B]) of (A) and (B) is preferably 1: 0.02 to 1: 0.4, and is 1: 0.02 to 1: 0.3. It is more preferable that
(A) When the weight ratio ([B] / [A]) of the (B) inorganic alkaline substance to the volcanic ejecta foam is smaller than 0.01, the antibacterial activity and the antiviral activity are lowered, which is not preferable. On the other hand, if the weight ratio of (B) inorganic alkaline substance to (A) volcanic ejecta foam ([B] / [A]) is greater than 0.5, the livestock that ate the livestock litter may have anorexia There is a risk of adverse effects on the product, and the cost is increased, which is not preferable in terms of economy.

本発明の敷料用組成物には、本発明の特徴を損なわない範囲で、さらに活性炭、木炭、竹炭等の吸着剤等を添加することができる。
また、本発明の敷料用組成物は、容器、袋体等に投入、密封し、炭酸ガスを注入して固化させたものでもよい。
本発明の敷料用組成物は、粒状、粉末状、顆粒状、ゲル状等の固形状の形態とすることが好ましく、粒状または粉末状とすることがより好ましい。
粒状または粉末状である敷料用組成物の平均粒子径は、後述する篩い分け法により測定し算出した値で通常50μm〜1,000μmであり、好ましくは100μm〜500μmであり、より好ましくは150μm〜300μmである。
An adsorbent such as activated carbon, charcoal, bamboo charcoal and the like can be further added to the bedding composition of the present invention as long as the characteristics of the present invention are not impaired.
Moreover, the composition for bedding according to the present invention may be charged into a container, bag, etc., sealed, and solidified by injecting carbon dioxide.
The composition for a bedding according to the present invention is preferably in a solid form such as granular, powdery, granular or gel, and more preferably in granular or powdery form.
The average particle size of the composition for bedding which is granular or powdery is usually 50 μm to 1,000 μm, preferably 100 μm to 500 μm, more preferably 150 μm to 150 μm, as measured and calculated by a sieving method described later. 300 μm.

本発明の敷料用組成物は、(A)火山噴出物発泡体と(B)無機アルカリ性物質とを、上記重量比にて混合し、場合により他の吸着剤等の添加成分を添加、混合した後、必要に応じて乾燥、粉砕、造粒、整粒等を行って調製することができる。   The composition for litter of the present invention is a mixture of (A) a volcanic ejecta foam and (B) an inorganic alkaline substance at the above weight ratio, and optionally added and mixed with additional components such as other adsorbents. Thereafter, it can be prepared by drying, pulverizing, granulating, sizing or the like, if necessary.

(A)火山噴出物発泡体と(B)無機アルカリ性物質、あるいはさらに他の添加成分の混合は、粉粒体の混合に用いられる一般的な混合方法により行うことができ、水平円筒型混合機、V型混合機、二重円錐型混合機、揺動回転型混合機、単軸リボン型混合機、複軸パドル型混合機、回転働型混合機、円錐スクリュー型混合機等の各種混合機、混合攪拌機等を用いて行う。   The mixing of (A) volcanic ejecta foam and (B) inorganic alkaline substance, or other additional components can be performed by a general mixing method used for mixing granular materials, and a horizontal cylindrical mixer , V type mixers, double cone type mixers, oscillating rotary type mixers, single axis ribbon type mixers, double axis paddle type mixers, rotary working type mixers, conical screw type mixers, etc. Use a mixing stirrer or the like.

上記混合物の粉砕は、一般的な粉砕方法により行うことができ、混合時における(B)無機アルカリ性物質の状態により、乾式粉砕、湿式粉砕のいずれをも用いることができる。すなわち、(B)無機アルカリ性物質を固体状で混合する場合には、乾式粉砕が好ましく採用され、水溶液の状態で混合する場合には、湿式粉砕が好ましく採用される。
乾式粉砕としては、ジェットミル粉砕およびメカノケミカル粉砕が挙げられ、湿式粉砕としては、コロイドミル粉砕が挙げられる。
The mixture can be pulverized by a general pulverization method, and either dry pulverization or wet pulverization can be used depending on the state of the inorganic alkaline substance (B) at the time of mixing. That is, when (B) the inorganic alkaline substance is mixed in a solid state, dry pulverization is preferably employed, and when mixed in the form of an aqueous solution, wet pulverization is preferably employed.
Examples of dry pulverization include jet mill pulverization and mechanochemical pulverization. Examples of wet pulverization include colloid mill pulverization.

上記混合物の造粒は、一般的な造粒方法により行うことができ、混合時における(B)無機アルカリ性物質の状態により、乾式造粒、湿式造粒のいずれをも用いることができる。すなわち、(B)無機アルカリ性物質を固体状で混合する場合には、乾式造粒が好ましく採用され、水溶液の状態で混合する場合には、湿式造粒が好ましく採用される。
乾式造粒としては、スラッグ法、ローラーコンパクター法等が挙げられ、湿式造粒としては、撹拌混合造粒法、噴霧乾燥造粒法、流動層造粒法、転動造粒法、転動流動層造粒法、押し出し造粒法等が挙げられる。
Granulation of the mixture can be performed by a general granulation method, and either dry granulation or wet granulation can be used depending on the state of (B) the inorganic alkaline substance at the time of mixing. That is, when the inorganic alkaline substance (B) is mixed in a solid state, dry granulation is preferably employed, and when it is mixed in an aqueous solution, wet granulation is preferably employed.
Examples of the dry granulation include a slug method and a roller compactor method, and examples of the wet granulation include a stirring and mixing granulation method, a spray drying granulation method, a fluidized bed granulation method, a rolling granulation method, and a rolling fluidization method. Examples include layer granulation method and extrusion granulation method.

上記混合物の整粒についても、一般的な整粒方法を採用することができる。かかる整粒方法としては、摩砕整粒、分級機能付解砕整粒、破砕整粒、湿式連続整粒、回転式遠心砕塊整粒、高速又は低速回転型整粒、球形整粒等が挙げられる。   For the sizing of the mixture, a general sizing method can be adopted. Such sizing methods include grinding sizing, pulverization sizing with classification function, pulverization sizing, wet continuous sizing, rotary centrifugal crushed sizing, high speed or low speed rotary sizing, spherical sizing, etc. Can be mentioned.

上記混合物の乾燥は、風乾、天日乾燥等、自然乾燥により行うことが好ましい。   The mixture is preferably dried by natural drying such as air drying or sun drying.

本発明の敷料用組成物の上記調製方法において、(A)火山噴出物発泡体および(B)無機アルカリ性物質、ならびに必要に応じて他の添加成分を混合し、必要により乾燥、粉砕、造粒等を行った後、プラスチック製等の容器や袋体等に投入して密閉し、炭酸ガスを注入して反応させることにより、固化させることができる。
特に、(B)無機アルカリ性物質として、ケイ酸ナトリウム、ケイ酸カリウム等のケイ酸のアルカリ金属塩を、水溶液の状態で用いた場合には、(A)火山噴出物発泡体との混合物を炭酸ガスと反応させて固化させることにより、敷料用組成物の強度および分散性が向上し、他の敷料材との混合も容易となるため、好ましい。
In the above method for preparing the composition for a litter of the present invention, (A) a volcanic ejecta foam and (B) an inorganic alkaline substance, and other additive components as necessary are mixed, and if necessary, dried, pulverized and granulated. After performing the above, it can be solidified by putting it in a plastic container or bag, sealing it, and injecting carbon dioxide to react it.
In particular, when (B) an alkali metal salt of silicic acid such as sodium silicate or potassium silicate is used in the form of an aqueous solution as an inorganic alkaline substance, (A) a mixture with a volcanic ejecta foam is carbonated. By reacting with gas and solidifying, the strength and dispersibility of the bedding composition are improved, and mixing with other bedding materials is facilitated, which is preferable.

本発明の敷料用組成物は、そのままで、またはおが屑、木材チップ、籾殻、稲わら等の他の敷料材と混合して、家畜用敷料とすることができる。
本発明においては、家畜用敷料を用いる場所により、敷料用組成物の形態を適宜選択することができる。たとえば、分娩舎や保温箱では粉末状の敷料用組成物を用い、肥育舎では、粉じんの発生を抑制して作業性を向上させるべく、粒状の敷料用組成物の使用割合を増やす等である。
The composition for bedding according to the present invention can be used as a bedding for livestock as it is or by mixing with other bedding materials such as sawdust, wood chips, rice husks and rice straw.
In the present invention, the form of the bedding composition can be appropriately selected depending on the place where the livestock bedding is used. For example, a delivery composition or a heat insulation box uses a powdered composition for a litter, and a fattening house increases the use ratio of a granular composition for the purpose of suppressing the generation of dust and improving workability. .

本発明の家畜用敷料における上記敷料用組成物の含有量は、家畜用敷料の全量に対し、好ましくは70重量%〜100重量%であり、より好ましくは90重量%〜100重量%である。   The content of the composition for bedding in the livestock bedding of the present invention is preferably 70% by weight to 100% by weight and more preferably 90% by weight to 100% by weight with respect to the total amount of the livestock bedding.

本発明の家畜用敷料は、家畜全般、たとえばウシ、ブタ、ヒツジ、ヤギ、ウサギ等の食肉用に飼育される哺乳動物;アヒル、ニワトリ、ガチョウ、七面鳥、ウズラ等の食肉用または採卵用に飼育される鳥類;イヌ、ネコ、ハムスター、モルモット、シマリス等の愛玩動物;アルパカ、ウマ、ラバ、ラクダ、ロバ等の労働用に飼育される哺乳動物等に用いることができ、なかでも、食肉用の家畜に好適に用いることができ、特に疾病の予防の必要な分娩期、哺乳期および離乳期の動物、ならびに肥育動物に好適に用いることができる。   The livestock litter of the present invention is a mammal bred for livestock in general, for example, cattle, pigs, sheep, goats, rabbits and other meats; Can be used for pets such as dogs, cats, hamsters, guinea pigs, chipmunks; mammals reared for labor such as alpaca, horse, mule, camel, donkey, etc. It can be suitably used for livestock, and can be particularly suitably used for animals in the delivery period, feeding period and weaning period, and fattening animals in need of disease prevention.

本発明の敷料用組成物は、吸湿・吸水性、二酸化炭素、ホルムアルデヒド等揮発性有機化合物に対する吸着性を有し、アンモニア、メチルメルカプタン、硫化水素、硫化メチル、トリメチルアミン等の悪臭原因物質等に対し吸着性を示す。また、優れた抗菌活性および抗ウイルス活性を有する。
従って、かかる敷料用組成物を含有してなる本発明の家畜用敷料は、糞尿等の吸収性、悪臭抑制効果に優れ、家畜の飼育環境の改善に資するとともに、病原性細菌に対する抗菌活性や抗ウイルス活性に優れることから、家畜の疾病の予防効果に優れる。
よって、本発明の家畜用敷料は、分娩舎、保温箱および肥育舎等、疾病予防が最も要求される哺乳期および離乳期の家畜、ならびに離乳後の幼若期の家畜の各飼育施設において、敷料として好ましく使用することができる。
また、本発明の敷料用組成物は、敷料材中の常在菌による堆肥化を妨げるものではないので、本発明の家畜用敷料を堆肥として再利用することも可能である。
The composition for bedding according to the present invention has absorptivity to volatile organic compounds such as moisture absorption, water absorption, carbon dioxide, formaldehyde, etc., and against odor-causing substances such as ammonia, methyl mercaptan, hydrogen sulfide, methyl sulfide, and trimethylamine. Adsorbability is shown. It also has excellent antibacterial and antiviral activities.
Therefore, the livestock litter of the present invention comprising such a litter composition is excellent in absorbability of feces and urine and the like, and is effective in suppressing the foul odor, contributes to the improvement of the livestock rearing environment, and has antibacterial activity and antibacterial activity against pathogenic bacteria. Because of its excellent virus activity, it is excellent in preventing diseases of livestock.
Therefore, the litter for livestock of the present invention, such as a delivery house, a heat insulation box and a fattening house, in each of the breeding facilities of suckling and weaning animals that are most required for disease prevention, and juvenile livestock after weaning, It can be preferably used as a bedding.
Moreover, since the composition for bedding according to the present invention does not prevent composting by resident bacteria in the bedding material, the bedding for livestock according to the present invention can be reused as compost.

次に、実施例により本発明をさらに具体的に説明する。   Next, the present invention will be described more specifically with reference to examples.

平均粒子径の測定方法
本明細書に記載した(A)火山噴出物発泡体、および本発明の敷料用組成物の平均粒子径の測定は、以下の方法(篩い分け法)により行った。
電磁式ふるい振とう機(アズワン株式会社製)に標準ふるいを5段〜10段装着し、試料をふるい振とうすることで分級して、各粒度区分の重量比により測定した。すなわち、標準ふるいを目開きの大きいものを上にして順次重ね、上段に試料20gを入れ15分間ふるい振とうさせ、各ふるい上に残存する試料の重量を測定し、粒度分布を求めた。
次いで、各ふるい毎に篩い分けられた試料について、試料全量に対する割合(重量%)を算出し、各ふるい毎の前記割合(重量%)を上段から順に足していき、試料重量の割合の合計が50重量%を超える前の前記合計値(重量%)を[d]、50重量%を超えた後の前記合計値(重量%)を[e]とし、試料重量の割合の合計が50重量%を超えない粒子径区分のアンダー値(μmまたはmm)を[a]とする。そして、試料重量の割合の合計が50重量%を超える粒子径を含む区分を特定し、その粒子径区分のオーバー値(μmまたはmm)を[b]、アンダー値(μmまたはmm)を[c]として、下記式(I)より重量平均粒子径を求めた。
平均粒子径(μmまたはmm)=a−〔(b−c)×{(50−d)/e}〕・・・(I)
Measuring method of average particle diameter The average particle diameter of the (A) volcanic ejecta foam described in the present specification and the composition for a litter of the present invention was measured by the following method (sieving method).
5 to 10 stages of standard sieves were mounted on an electromagnetic sieve shaker (manufactured by ASONE Co., Ltd.), and the samples were classified by shaking and measured according to the weight ratio of each particle size category. That is, the standard sieves were stacked one on top of the other with a large mesh opening, 20 g of the sample was placed in the upper stage, shaken for 15 minutes, the weight of the sample remaining on each sieve was measured, and the particle size distribution was determined.
Next, for the sample sieved for each sieve, the ratio (% by weight) with respect to the total amount of the sample is calculated, and the ratio (% by weight) for each sieve is added in order from the top. The total value (% by weight) before exceeding 50% by weight is [d], the total value (% by weight) after exceeding 50% by weight is [e], and the total ratio of the sample weight is 50% by weight. The under value (μm or mm) of the particle size category that does not exceed is [a]. Then, the classification including the particle diameter in which the total ratio of the sample weight exceeds 50% by weight is specified, the over value (μm or mm) of the particle diameter classification is [b], and the under value (μm or mm) is [c The weight average particle diameter was determined from the following formula (I).
Average particle diameter (μm or mm) = a − [(bc) × {(50−d) / e}] (I)

[実施例1]家畜用敷料
混合撹拌機(「モルタルミキサー」、株式会社東海機械製作所製)にシラス発泡体(「シラスバルーン」:平均粒子径=40μm、豊和直株式会社製)1,000gを投入し、次いで水ガラス(「ケイ酸ソーダ3号」、日本化学工業株式会社製)100gを噴霧器で散布しながら混合攪拌し、ポリ袋に入れ密封してから、炭酸ガス30gを注入して反応させて敷料用組成物(平均粒子径=100μm)を得、家畜用敷料とした。
[Example 1] Livestock litter 1,000 g of shirasu foam ("Shirasu Balloon": average particle size = 40 µm, manufactured by Nao Toyowa Co., Ltd.) was added to a mixing stirrer ("Mortar mixer", manufactured by Tokai Machinery Co., Ltd.). Then, 100 g of water glass (“Sodium silicate 3”, manufactured by Nippon Chemical Industry Co., Ltd.) is mixed and stirred while spraying with a sprayer, sealed in a plastic bag, and then reacted by injecting 30 g of carbon dioxide. Thus, a bedding composition (average particle size = 100 μm) was obtained and used as a livestock bedding.

[実施例2]家畜用敷料
混合撹拌機(「モルタルミキサー」、株式会社東海機械製作所製)にシラス発泡体(「シラスバルーン」:平均粒子径=150μm、豊和直株式会社製)1,000gを投入し、次いでケイ酸カリウム水溶液(二酸化ケイ素(SiO)濃度=27重量%〜29重量%、酸化カリウム(KO)濃度=21重量%〜23重量%、日本化学工業株式会社製)100gを噴霧器で散布しながら混合攪拌し、ポリ袋に入れ密封してから、炭酸ガス30gを注入して反応させて敷料用組成物(平均粒子径=300μm)を得、家畜用敷料とした。
[Example 2] Livestock litter 1,000 g of shirasu foam ("Shirasu balloon": average particle size = 150 μm, manufactured by Towa Naoshi Co., Ltd.) is added to a mixing stirrer ("Mortar mixer", manufactured by Tokai Machinery Co., Ltd.). Then, potassium silicate aqueous solution (silicon dioxide (SiO 2 ) concentration = 27 wt% to 29 wt%, potassium oxide (K 2 O) concentration = 21 wt% to 23 wt%, manufactured by Nippon Chemical Industry Co., Ltd.) 100 g Was mixed and stirred while sprayed with a sprayer, sealed in a plastic bag, injected with 30 g of carbon dioxide gas, reacted to obtain a composition for bedding (average particle size = 300 μm), and used as a bedding for livestock.

実施例2で得た敷料用組成物について、成分分析を行った結果を表1に示す。また、二酸化炭素吸着性、および揮発性有機化合物としてホルムアルデヒドの吸着性を評価し、結果を図1、2に示した。
成分分析は、鹿児島県工業技術センターに委託し、蛍光X線分析法(使用機器:「蛍光X線分析装置 RIX−3000」、株式会社リガク製、検量線法)により行った。なお、表1中に示した強熱減量は、重量分析法(電気マッフル炉(株式会社伊藤製作所製)にて試料を1,000℃で1時間強熱した際の重量の減少率から算出)により測定した。
二酸化炭素吸着性およびホルムアルデヒド吸着性は、実施例2で得た敷料用組成物10gを試料とし、対照としてケイ酸ナトリウムを用いて、特開2013−063866号公報に記載された方法により評価した。
Table 1 shows the results of component analysis of the bedding composition obtained in Example 2. Moreover, the carbon dioxide adsorptivity and the adsorptivity of formaldehyde as a volatile organic compound were evaluated, and the results are shown in FIGS.
Component analysis was entrusted to the Kagoshima Prefectural Industrial Technology Center, and was performed by fluorescent X-ray analysis (equipment used: “X-ray fluorescence analyzer RIX-3000”, manufactured by Rigaku Corporation, calibration curve method). The ignition loss shown in Table 1 is a gravimetric analysis method (calculated from the weight reduction rate when the sample is ignited at 1,000 ° C. for 1 hour in an electric muffle furnace (manufactured by Ito Manufacturing Co., Ltd.)). It was measured by.
Carbon dioxide adsorptivity and formaldehyde adsorptivity were evaluated by the method described in JP2013-063866A using 10 g of the composition for bedding obtained in Example 2 as a sample and using sodium silicate as a control.

表1より、実施例2で得られた敷料用組成物は、二酸化ケイ素および酸化アルミニウムを主成分とするセラミクス組成物であることが示された。   From Table 1, it was shown that the composition for bedding obtained in Example 2 is a ceramic composition mainly composed of silicon dioxide and aluminum oxide.

図1および図2に示されるように、実施例2で得られた敷料用組成物には、良好な二酸化炭素吸着性およびホルムアルデヒド吸着性が認められた。
従って、実施例2の家畜用敷料は、家畜の排出する二酸化炭素の吸着、家畜舎におけるホルムアルデヒド等揮発性有機化合物の吸着効果を有し、家畜舎における悪臭の抑制効果が期待できる。
As shown in FIG. 1 and FIG. 2, good carbon dioxide adsorptivity and formaldehyde adsorptivity were recognized in the composition for a bedding obtained in Example 2.
Therefore, the livestock litter of Example 2 has an effect of adsorbing carbon dioxide discharged from livestock and an effect of adsorbing volatile organic compounds such as formaldehyde in the livestock house, and can be expected to suppress malodor in the livestock house.

[試験例1]抗菌試験
実施例2の家畜用敷料について、以下の通り大腸菌に対する抗菌試験を実施した。
(1)試験方法
(i)試験菌として、大腸菌(Escherichia coli NBRC 12734)を用いた。
(ii)試験菌をレシチン・ポリソルベート80加ソイビーン・カゼイン・ダイジェスト(SCDLP)ブイヨン培地(栄研化学株式会社製)に接種して35±1℃で培養し、培養液を約10個/mLとなるように滅菌生理食塩水で希釈調製し、菌原液とした。
(iii)1,000mLのガラスビーカーに、滅菌生理食塩水600mLを入れ、上記菌原液1mLを添加して、1mLあたりの菌数が約10個台となるようにした溶液に、実施例2の家畜用敷料50gを浸漬し、試験液とした。
一方、1,000mLの共栓メジウム瓶に滅菌生理食塩水600mLを入れ、上記菌原液1mLを添加して、1mLあたりの菌数が約10個台となるようにした溶液を対照液とした。
(iv)上記試験液および対照液について、混釈培養法により、調製時ならびに、室温で15分、30分および60分静置した後の生菌数を測定した。なお、培養は、標準寒天培地(栄研化学株式会社製)を用い、35±1℃で24時間行った。
(2)評価結果
評価結果を下記表2に示した。
[Test Example 1] Antibacterial test The livestock bedding of Example 2 was subjected to an antibacterial test against Escherichia coli as follows.
(1) Test method (i) Escherichia coli NBRC 12734 was used as a test bacterium.
(Ii) The test bacteria are inoculated into lecithin polysorbate 80 added soy bean casein digest (SCDLP) bouillon medium (Eiken Chemical Co., Ltd.) and cultured at 35 ± 1 ° C., and the culture solution is about 10 7 cells / mL. As a result, it was diluted with sterile physiological saline to prepare a bacterial stock solution.
Glass beaker (iii) 1,000 mL, placed in sterile physiological saline 600 mL, was added to the cells stock solution 1mL, the solution to the number of bacteria per 1mL of about 10 4 stand, Example 2 Was immersed in 50 g of livestock litter to prepare a test solution.
On the other hand, 600 mL of sterilized physiological saline was added to a 1,000 mL stoppered medium bottle, and 1 mL of the above bacterial stock solution was added so that the number of bacteria per mL was about 10 4 units. .
(Iv) About the said test solution and control solution, the viable cell count was measured at the time of preparation and after leaving still at room temperature for 15 minutes, 30 minutes, and 60 minutes by the pour culture method. The culture was performed at 35 ± 1 ° C. for 24 hours using a standard agar medium (manufactured by Eiken Chemical Co., Ltd.).
(2) Evaluation results The evaluation results are shown in Table 2 below.

表2において、対照液中の大腸菌は60分経過後にも全く減少していないのに対し、本発明の実施例2の家畜用敷料を浸漬した試験液では、経時的に大腸菌は減少し、60分経過後には、調製時の約1/1,000にまで減少しており、実施例2の飼料用添加剤が大腸菌に対して抗菌活性を有することが認められた。   In Table 2, E. coli in the control solution did not decrease at all even after 60 minutes, whereas in the test solution in which the livestock bedding of Example 2 of the present invention was immersed, E. coli decreased with time. After a lapse of time, the amount decreased to about 1/1000 at the time of preparation, and it was confirmed that the feed additive of Example 2 had antibacterial activity against E. coli.

[試験例2]飼育試験
実施例2で得られた家畜用敷料を用いて、飼育試験を行った。
永徳養豚場(鹿児島県)にて、平成24年12月から平成25年4月まで、実施例2の家畜用敷料を、分娩舎および保温箱のそれぞれに、最初に1,000gずつ敷き、延べ50頭の母豚とその子豚を離乳までの30日間飼育、観察した。また、肥育舎にも、最初に1,000gを敷き、離乳から40日間飼育、観察した。いずれの豚舎においても、家畜用敷料は、減った分だけ随時追加した。
なお、対照群として、延べ20頭の母豚とその子豚を、家畜用敷料としておが屑を用いた分娩舎および保温箱で離乳までの30日間飼育、観察した。
[Test Example 2] Breeding test Using the livestock bedding obtained in Example 2, a breeding test was conducted.
At Yeongdeung Pig Farm (Kagoshima Prefecture), from December 2012 to April 2013, the livestock litter of Example 2 was first laid on each of the delivery house and the heat insulation box in an amount of 1,000 g. 50 mother pigs and their piglets were raised and observed for 30 days until weaning. The fattening house was first laid with 1,000 g, and was grown and observed for 40 days after weaning. In each piggery, livestock litter was added from time to time as much as reduced.
In addition, as a control group, a total of 20 mother pigs and their piglets were raised and observed for 30 days until weaning in a delivery house and heat insulation box using sawdust as livestock bedding.

実施例2の家畜用敷料使用群、対照群ともにPEDの発生は見られず、死亡率には両群の間に差は見られなかったが、実施例2の家畜用敷料使用群の子豚は、対照群の子豚に比べて明らかに毛づやの良さが目立ち、健康に見えた。
ただし、離乳後は、両群の子豚が、実施例2の家畜用敷料を用いた肥育舎で飼育されたため、肥育日数の長短についてのデータはとれなかった。しかし、毛並みなどの比較から、両群において肥育日数にも明らかに差が生じることが推測された。
There was no occurrence of PED in both the livestock litter use group and the control group of Example 2, and there was no difference in mortality between the two groups. Compared with the control piglet, it was clearly healthy and looked healthy.
However, after weaning, since the piglets of both groups were bred in a fattening house using the livestock bedding of Example 2, data on the length of fattening days could not be obtained. However, it was speculated that there was a clear difference in the number of fattening days in both groups from comparison of the fur and the like.

[実施例3]家畜用敷料
混合撹拌機(「モルタルミキサー」、株式会社東海機械製作所製)にシラス発泡体(「シラスバルーン」:平均粒子径=150μm、豊和直株式会社製)100Kgを投入し、次いで、21重量%〜23重量%ケイ酸カリウム水溶液(日本化学工業株式会社製)30Kgを添加して混合攪拌し、ポリ袋に入れ密封してから、炭酸ガス300gを注入して反応させ、敷料用組成物(平均粒子径=300μm)を得、家畜用敷料とした。
[Example 3] Litter for livestock 100 kg of shirasu foam ("Shirasu Balloon": average particle diameter = 150 μm, manufactured by Towa Naoshi Co., Ltd.) was added to a mixing stirrer ("Mortar mixer", manufactured by Tokai Machinery Co., Ltd.). Next, 30 kg of a 21 wt% to 23 wt% potassium silicate aqueous solution (manufactured by Nippon Chemical Industry Co., Ltd.) was added, mixed and stirred, sealed in a plastic bag, and then reacted by injecting 300 g of carbon dioxide gas, A bedding composition (average particle size = 300 μm) was obtained and used as a livestock bedding.

実施例3で得られた敷料用組成物10gを、蒸留水50mLに入れ、30℃で攪拌し、1時間後にペンタイプpH計(株式会社佐藤計量器製作所製)でpHを測定したところ、pHは12.2であり、本発明の敷料用組成物は、強塩基性を示した。   10 g of the bedding composition obtained in Example 3 was placed in 50 mL of distilled water, stirred at 30 ° C., and measured for pH with a pen-type pH meter (manufactured by Sato Keiki Seisakusho Co., Ltd.) after 1 hour. Was 12.2, and the bedding composition of the present invention showed strong basicity.

[試験例3]PED発生状況の観察
実施例3の家畜用敷料を用いて、分娩から授乳期の豚を飼育し、PED発生の状況を観察した。
千葉県成田市のA養豚場にて、平成25年8月から12月まで、実施例3の家畜用敷料を、分娩舎および保温箱のそれぞれに、最初に1,000gずつ敷き、延べ100頭の母豚とその子豚1,061頭を離乳までの30日間飼育し、観察した。家畜用敷料は、減った分だけ随時追加した。
[Test Example 3] Observation of PED generation status Using the livestock bedding of Example 3, pigs were bred from parturition to lactation, and the status of PED generation was observed.
At the A pig farm in Narita, Chiba, from August to December 2013, the livestock litter of Example 3 was first spread in each of the delivery house and the heat insulation box, 1,000 g each, totaling 100 heads Mother pigs and 1061 piglets were raised and observed for 30 days until weaning. Livestock litter was added from time to time as much as it was reduced.

本試験を行った期間中、他の養豚場のほとんどでPEDの発生が見られたが、本養豚場で飼育した子豚1,061頭には、PEDの発生は全く見られなかった。   During the period of this test, the occurrence of PED was observed in most of the other pig farms, but no PED was observed in 1061 piglets raised in this pig farm.

[試験例4]飼育試験
鹿児島県鹿屋市のB養豚場にて、平成25年6月から9月まで、実施例3の家畜用敷料を、分娩舎および保温箱のそれぞれに、最初に1,000gずつ敷き、延べ40頭の母豚とその子豚416頭を離乳までの30日間飼育し、観察した。家畜用敷料は、減った分だけ随時追加した。
なお、対照群として、延べ20頭の母豚とその子豚を、家畜用敷料としておが屑を用いた分娩舎および保温箱で、離乳までの30日間飼育し、観察した。
[Test Example 4] Breeding test From June to September 2013, the livestock litter of Example 3 was first added to each of the delivery house and the heat insulation box at B pig farm in Kagoshima Prefecture, Kagoshima Prefecture. A total of 40 mother pigs and 416 piglets were bred for 30 days until weaning and observed. Livestock litter was added from time to time as much as it was reduced.
As a control group, a total of 20 mother pigs and their piglets were bred and observed for 30 days until weaning in a delivery house and heat insulation box using sawdust as a livestock bedding.

実施例3の家畜用敷料使用群、対照群ともにPEDの発生は見られず、両群の間で死亡率に差は見られなかった。しかし、実施例3の家畜用敷料使用群では、対照群に比べて、毛つやの良さが際立って認められた。   In the livestock bedding use group of Example 3 and the control group, no occurrence of PED was observed, and there was no difference in mortality between the two groups. However, in the livestock bedding use group of Example 3, the glossiness was significantly recognized as compared to the control group.

[試験例5]敷料の堆肥化試験
(1)豚糞尿(永徳養豚場)20kgに、実施例3にて調製した敷料用組成物(平均粒子径=300μm)3.6kg(20L)を添加して混合攪拌し、含水率がおおむね60重量%となるように調整した。前記混合物を100Lのポリ容器に入れて、1日に1回攪拌(スコップで2分)し、6時間後に前記混合物の温度を測定した。また、前記混合物の臭いの変化を観察した。
その結果、混合物の温度は2日目に36℃に達し、5日目には57℃になり、12日目に全く無臭となった。
(2)豚糞尿(永徳養豚場)20kgに、実施例3にて調製した敷料用組成物(平均粒子径=300μm)20kg添加して混合攪拌し、含水率がおおむね60重量%となるように調整した。前記混合物を100Lのポリ容器に入れて、1日に1回攪拌(スコップで2分)し、6時間後に前記混合物の温度を測定した。また、前記混合物の臭いの変化を観察した。
その結果、混合物の温度は2日目に38℃に達し、5日目には59℃になり、10日目に全く無臭になった。
[Test Example 5] Composting test of bedding (1) To 20 kg of pig manure (Yongde pig farm), 3.6 kg (20 L) of the composition for bedding prepared in Example 3 (average particle size = 300 μm) was added. The mixture was stirred and adjusted so that the water content was approximately 60% by weight. The mixture was placed in a 100 L plastic container, stirred once a day (2 minutes with a scoop), and the temperature of the mixture was measured after 6 hours. Moreover, the change of the odor of the said mixture was observed.
As a result, the temperature of the mixture reached 36 ° C. on the second day, 57 ° C. on the fifth day, and completely odorless on the 12th day.
(2) To 20 kg of pig manure (Yongde pig farm), 20 kg of the composition for bedding prepared in Example 3 (average particle size = 300 μm) is added and mixed and stirred so that the water content is about 60% by weight. It was adjusted. The mixture was placed in a 100 L plastic container, stirred once a day (2 minutes with a scoop), and the temperature of the mixture was measured after 6 hours. Moreover, the change of the odor of the said mixture was observed.
As a result, the temperature of the mixture reached 38 ° C. on the second day, 59 ° C. on the fifth day, and became completely odorless on the tenth day.

上記の結果から、本発明の家畜用敷料は抗菌活性を示すが、通常の条件で家畜の糞尿と混合(たとえば、糞尿:家畜用敷料=1:0.1〜1:1の重量比で混合)して堆肥化を行う場合には、堆肥化を阻害しないことが認められた。   From the above results, the livestock litter of the present invention exhibits antibacterial activity, but is mixed with livestock manure under normal conditions (for example, manure: livestock litter = 1: 0.1 to 1: 1 mixed at a weight ratio) ) And composting was confirmed not to impede composting.

比較のため、実施例3にて調製した敷料用組成物の代わりにゼオライト、貝化石、シラス、軽石、ボラ土、砂、カオリンの各無機粉体を用いて、上記(1)、(2)と同様に堆肥化試験を行った。
その結果、糞尿と前記無機粉体との混合物では、いずれも経時的な温度の上昇は観察されず、14日目から腐敗臭が発生し、糞尿の堆肥化は促進されなかった。
For comparison, using the inorganic powders of zeolite, shell fossil, shirasu, pumice, borax, sand, and kaolin instead of the bedding composition prepared in Example 3, the above (1) and (2) A composting test was conducted in the same manner as above.
As a result, in any mixture of manure and the inorganic powder, no increase in temperature over time was observed, a rotting odor was generated from the 14th day, and manure composting was not promoted.

以上詳述したように、本発明によれば、大腸菌等の病原性細菌に対する抗菌活性および抗ウイルス活性に優れ、家畜の疾病の予防効果が高く、臭気の抑制効果にも優れる家畜用敷料を、安価かつ簡便に提供することができる。   As described in detail above, according to the present invention, a livestock bedding excellent in antibacterial activity and antiviral activity against pathogenic bacteria such as Escherichia coli, having high preventive effect on livestock diseases, and excellent in odor control effect, It can be provided inexpensively and easily.

Claims (7)

(A)火山噴出物発泡体および(B)無機アルカリ性物質を、(A)と(B)の重量比[(A):(B)]が1:0.01〜1:0.5となるように含有する組成物を含有してなる、家畜用敷料であって、無機アルカリ性物質が、アルカリ金属の水酸化物、アルカリ土類金属の水酸化物、ケイ酸のアルカリ金属塩、ケイ酸のアルカリ土類金属塩、炭酸のアルカリ金属塩および炭酸のアルカリ土類金属塩からなる群より選択される1種または2種以上である、家畜用敷料(A) Volcanic ejecta foam and (B) inorganic alkaline substance, (A) and (B) weight ratio [(A) :( B)] will be 1: 0.01-1: 0.5. A composition for a livestock bedding , wherein the inorganic alkaline substance is an alkali metal hydroxide, an alkaline earth metal hydroxide, an alkali metal salt of silicic acid, or silicic acid A livestock litter which is one or more selected from the group consisting of alkaline earth metal salts, alkali metal carbonates and alkaline earth metal carbonates . 火山噴出物発泡体が、シラス発泡体、黒曜石発泡体および真珠岩発泡体からなる群より選択される少なくとも1種である、請求項1に記載の家畜用敷料。   The litter for livestock according to claim 1, wherein the volcanic product foam is at least one selected from the group consisting of shirasu foam, obsidian foam, and nacreous foam. 無機アルカリ性物質が、水酸化ナトリウム、水酸化カリウム、水酸化マグネシウム、水酸化カルシウム、ケイ酸ナトリウム、ケイ酸カリウム、ケイ酸マグネシウム、ケイ酸カルシウム、炭酸ナトリウム、炭酸カリウム、炭酸マグネシウムおよび炭酸カルシウムからなる群より選択される少なくとも1種である、請求項1または2に記載の家畜用敷料。   Inorganic alkaline substance consists of sodium hydroxide, potassium hydroxide, magnesium hydroxide, calcium hydroxide, sodium silicate, potassium silicate, magnesium silicate, calcium silicate, sodium carbonate, potassium carbonate, magnesium carbonate and calcium carbonate The livestock litter according to claim 1 or 2, which is at least one selected from the group. (A)火山噴出物発泡体および(B)無機アルカリ性物質を含有する組成物が、二酸化炭素により固化されている、請求項1〜3のいずれか1項に記載の家畜用敷料。   The livestock litter according to any one of claims 1 to 3, wherein the composition containing (A) a volcanic ejecta foam and (B) an inorganic alkaline substance is solidified by carbon dioxide. (A)火山噴出物発泡体および(B)無機アルカリ性物質を含有する組成物が粉状または粒状である、請求項1〜4のいずれか1項に記載の家畜用敷料。   The livestock litter according to any one of claims 1 to 4, wherein the composition containing (A) a volcanic ejecta foam and (B) an inorganic alkaline substance is powdery or granular. (A)火山噴出物発泡体および(B)無機アルカリ性物質を含有する組成物の平均粒子径が50μm〜1,000μmである、請求項5に記載の家畜用敷料。   The livestock litter according to claim 5, wherein the average particle size of the composition containing (A) a volcanic ejecta foam and (B) an inorganic alkaline substance is 50 µm to 1,000 µm. 分娩舎、保温箱および肥育舎の少なくとも1箇所において使用される、請求項1〜6のいずれか1項に記載の家畜用敷料。   The litter for livestock according to any one of claims 1 to 6, which is used in at least one place of a delivery house, a heat insulation box and a fattening house.
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