JP6441719B2 - Taste improving agent for water-in-oil type fat composition - Google Patents

Taste improving agent for water-in-oil type fat composition Download PDF

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JP6441719B2
JP6441719B2 JP2015055502A JP2015055502A JP6441719B2 JP 6441719 B2 JP6441719 B2 JP 6441719B2 JP 2015055502 A JP2015055502 A JP 2015055502A JP 2015055502 A JP2015055502 A JP 2015055502A JP 6441719 B2 JP6441719 B2 JP 6441719B2
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宏樹 松浦
宏樹 松浦
晋哉 山根
晋哉 山根
憲 古瀬
憲 古瀬
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Riken Vitamin Co Ltd
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本発明は、油中水型油脂組成物に用いる食味改善剤に関する。   The present invention relates to a taste improver for use in a water-in-oil type oil and fat composition.

マーガリン、ファットスプレッド等の油中水型油脂組成物は、従来製菓・製パン・調理用油脂等として広く用いられている。これら油中水型油脂組成物の中でも、特に製菓・製パンの用途においては、他の食材の風味を損なわないため、食塩(塩化ナトリウム)等の呈味成分を添加していない製品が好まれる。一方、トーストへの塗布や調理用油脂として用いる製品としては、予め各種呈味成分を添加することにより、油中水型油脂組成物自体のコク味を引き立てたり、他の食品の風味を付与したものが製造・販売されている。   BACKGROUND ART Conventionally, water-in-oil type oil and fat compositions such as margarine and fat spread are widely used as confectionery, bread making, cooking fats and oils, and the like. Among these water-in-oil type oil and fat compositions, products that do not contain a taste ingredient such as sodium chloride (sodium chloride) are preferred in order to preserve the flavor of other ingredients, particularly in confectionery and bread making applications. . On the other hand, as a product to be applied to toast and used as cooking fats and oils, by adding various taste components in advance, the richness of the water-in-oil type oil composition itself is enhanced, or the flavor of other foods is given. Things are manufactured and sold.

このような呈味成分を添加した油中水型油脂組成物において、その呈味成分の多くは水相に含有されている。しかし、油中水型油脂組成物は水相が油相に覆われた構造をとることから、水相に由来する呈味は口腔内で知覚されにくい。従って、十分な呈味を得るためには呈味成分を多量に添加する必要がある。   In the water-in-oil type oil and fat composition to which such a taste component is added, most of the taste components are contained in the aqueous phase. However, since the water-in-oil type oil and fat composition has a structure in which the water phase is covered with the oil phase, the taste derived from the water phase is hardly perceived in the oral cavity. Therefore, in order to obtain a sufficient taste, it is necessary to add a large amount of taste ingredients.

一方で、近年、高血圧・心臓病・高脂血症・糖尿病予防等の健康上の理由により、減塩タイプや低糖質タイプの食品が求められている。このことから、油中水型油脂組成物においてもより少ない呈味成分の添加量で十分な呈味を得られるよう、水相由来の呈味を口腔内で明瞭に発現させるための方法がいくつか提案されてきた。   On the other hand, in recent years, for health reasons such as prevention of hypertension, heart disease, hyperlipidemia, and diabetes, foods of reduced salt type and low sugar type have been demanded. Therefore, there are several methods for clearly expressing the taste derived from the aqueous phase in the oral cavity so that a sufficient taste can be obtained with a smaller amount of the taste component in the water-in-oil type oil / fat composition. Has been proposed.

例えば、1種類の油相に、少なくとも2種類以上の水相を別々に乳化した後、急冷し、練りを加えてなることを特徴とする油中水型乳化組成物(特許文献1)等が開示されている。しかしながら、この方法は製造条件に特徴があることから、製造設備や工程の制約があり、簡便性の点で問題がある。   For example, a water-in-oil emulsion composition (Patent Document 1) or the like obtained by emulsifying at least two or more aqueous phases separately in one type of oil phase, and then rapidly cooling and kneading. It is disclosed. However, since this method is characterized by manufacturing conditions, there are limitations on manufacturing equipment and processes, and there is a problem in terms of simplicity.

また、製造設備等の制約を受けない方法としては、例えば、食塩を0.4重量%以上1.0重量%未満含有する油脂組成物であって、35℃における導電率上昇において、平衡値の50%に達するまでの時間が50秒以内であることを特徴とする油中水型油脂組成物(特許文献2)、油脂及び具材からなる油脂組成物であって、油脂含量が30重量%以上、具材含量が固形分換算で0.01〜35重量%、塩味成分含量が0.1重量%以上、水分含量が5重量%以下、HLB値11以上の乳化剤含量が0.01重量%以上であることを特徴とする油脂組成物(特許文献3)、等が開示されているが、これらの方法では呈味改善効果が十分でなく、実用上満足し得るものとは言えない。   In addition, as a method not subject to restrictions such as manufacturing equipment, for example, an oil and fat composition containing sodium chloride in an amount of 0.4 wt% or more and less than 1.0 wt%, A water-in-oil type oil / fat composition (Patent Document 2) characterized in that the time until it reaches 50% is within 50 seconds, an oil / fat composition comprising oil and fat and ingredients, and the oil / fat content is 30% by weight The ingredients content is 0.01 to 35% by weight in terms of solid content, the salty ingredient content is 0.1% by weight or more, the water content is 5% by weight or less, and the emulsifier content with an HLB value of 11 or more is 0.01% by weight. Although the oil and fat composition (Patent Document 3) characterized by the above is disclosed, these methods are not sufficient in taste improvement effect and cannot be said to be practically satisfactory.

このため、製造設備等の制約を受けず、かつ呈味の発現性により優れた油中水型油脂組成物を得るための方法が求められていた。   For this reason, the method for obtaining the water-in-oil type oil-fat composition which was not received by restrictions of manufacturing equipment etc. and was excellent by the expression property of taste was calculated | required.

特開2010−148478号公報JP 2010-148478 A 特開2012−175949号公報JP 2012-175949 A 特開2000−228947号公報JP 2000-228947 A

本発明は、油中水型油脂組成物において、水相に含まれる呈味成分の呈味を口腔内で明瞭に発現させ、かつ該油中水型油脂組成物の食感を良好にすることを可能にする食味改善剤を提供することを目的とする。   In the water-in-oil type oil / fat composition, the present invention clearly expresses the taste of a taste component contained in the aqueous phase in the oral cavity and improves the texture of the water-in-oil type oil / fat composition. It aims at providing the taste improving agent which makes it possible.

本発明者らは、前記課題を解決するため鋭意研究を重ねた結果、油中水型油脂組成物に、構成脂肪酸が不飽和脂肪酸であるグリセリンコハク酸脂肪酸エステルを添加することにより、該油中水型油脂組成物の水相に含まれる呈味成分の呈味、特に塩味が口腔内で明瞭に発現し、かつ該油中水型油脂組成物の食感が良好になることを見出し、この知見に基づいて本発明を成すに至った。   As a result of intensive studies to solve the above problems, the present inventors have added a glycerin succinic acid fatty acid ester whose constituent fatty acid is an unsaturated fatty acid to a water-in-oil type oil / fat composition. It has been found that the taste of the taste component contained in the aqueous phase of the water-based oil / fat composition, particularly the saltiness, is clearly expressed in the oral cavity, and the texture of the water-in-oil oil / fat composition is improved. The present invention has been made based on the findings.

すなわち、本発明は、
(1)グリセリンコハク酸不飽和脂肪酸エステルを有効成分とすることを特徴とする油中水型油脂組成物用食味改善剤、
(2)前記(1)記載の油中水型油脂組成物用食味改善剤を含有する油中水型油脂組成物、
(3)前記(1)記載の油中水型油脂組成物用食味改善剤を油中水型油脂組成物に添加することを特徴とする油中水型油脂組成物の食味改善方法、
から成っている。
That is, the present invention
(1) A taste improver for water-in-oil type oil and fat compositions characterized by comprising glycerin succinic unsaturated fatty acid ester as an active ingredient,
(2) A water-in-oil oil / fat composition containing the taste improver for water-in-oil oil / fat composition according to (1),
(3) A method for improving the taste of a water-in-oil oil / fat composition, comprising adding the taste improver for a water-in-oil oil / fat composition according to (1) to a water-in-oil oil / fat composition,
Consists of.

本発明の油中水型油脂組成用食味改善剤は、これを油中水型油脂組成物に添加するだけで簡便に、該油中水型油脂組成物の水相に含まれる呈味成分の呈味、特に塩味及び甘味を明瞭に発現させることができる。このため、本発明の油中水型油脂組成物用食味改善剤を添加した油中水型油脂組成物においては、呈味成分の添加量が少なくても十分な呈味を得ることができる。
また、本発明の油中水型油脂組成物用食味改善剤を添加した油中水型油脂組成物は、なめらかさや口どけといった食感が改善されており、食味が良好である。
The taste improver for water-in-oil type oil / fat composition of the present invention can be simply added to the water-in-oil type oil / fat composition to simply add the taste component contained in the water phase of the water-in-oil type oil / fat composition. Taste, particularly salty taste and sweetness can be clearly expressed. Therefore, in the water-in-oil type oil / fat composition to which the taste improver for water-in-oil type oil / fat composition of the present invention is added, sufficient taste can be obtained even if the amount of the taste component added is small.
Moreover, the water-in-oil type oil-fat composition which added the taste improving agent for water-in-oil type oil-fat compositions of this invention has improved texture, such as smoothness and a mouthfeel, and its taste is good.

本発明の油中水型油脂組成物用食味改善剤(以下、本発明の食味改善剤ともいう)は、グリセリンコハク酸不飽和脂肪酸エステルを有効成分とする。   The taste improver for water-in-oil type oil / fat compositions of the present invention (hereinafter also referred to as the taste improver of the present invention) contains glycerin succinic unsaturated fatty acid ester as an active ingredient.

本発明に用いられるグリセリンコハク酸不飽和脂肪酸エステル(以下、不飽和SMGともいう)とは、グリセリンとコハク酸と不飽和脂肪酸のエステル化生成物である。該不飽和SMGは、通常グリセリンモノ不飽和脂肪酸エステルと無水コハク酸(又はコハク酸)との反応、若しくはグリセリンとコハク酸と不飽和脂肪酸との反応等自体公知の方法により得ることができる。その製法の概略を以下に示す。   The glycerin succinic unsaturated fatty acid ester (hereinafter also referred to as unsaturated SMG) used in the present invention is an esterification product of glycerin, succinic acid and unsaturated fatty acid. The unsaturated SMG can be obtained by a method known per se, such as a reaction of glycerin monounsaturated fatty acid ester with succinic anhydride (or succinic acid) or a reaction of glycerin, succinic acid and unsaturated fatty acid. The outline of the production method is shown below.

例えば、グリセリンモノ不飽和脂肪酸エステルを溶融し、これに無水コハク酸を加え、温度110〜130℃で90分間反応する。グリセリンモノ不飽和脂肪酸エステルと無水コハク酸との比率は質量比で7:1〜4:1が好ましい。さらに、反応中は生成物の着色、臭気を防止するために、反応器内を不活性ガスで置換する方が好ましい。得られたグリセリンモノ不飽和脂肪酸エステルと無水コハク酸との反応物は、不飽和SMGの他に、コハク酸、未反応のグリセリンモノ不飽和脂肪酸エステル等を含む混合物である。   For example, glycerin monounsaturated fatty acid ester is melted, succinic anhydride is added thereto, and reacted at a temperature of 110 to 130 ° C. for 90 minutes. The ratio of glycerin monounsaturated fatty acid ester to succinic anhydride is preferably 7: 1 to 4: 1 by mass ratio. Furthermore, in order to prevent product coloring and odor during the reaction, it is preferable to replace the inside of the reactor with an inert gas. The obtained reaction product of glycerin monounsaturated fatty acid ester and succinic anhydride is a mixture containing succinic acid, unreacted glycerin monounsaturated fatty acid ester and the like in addition to unsaturated SMG.

不飽和SMGを構成する不飽和脂肪酸は、食用可能な動植物油脂を起源とし、炭素原子間の結合に一以上の二重結合を含む不飽和脂肪酸であれば特に制限はなく、例えば、パルミトオレイン酸、オレイン酸、エライジン酸、リノール酸、γ−リノレン酸、α−リノレン酸、アラキドン酸、リシノール酸、縮合リシノール酸等が挙げられる。これら不飽和脂肪酸は一種類のみを単独で用いても良いし、二種類以上を任意に組み合わせて用いても良い。とりわけ、オレイン酸及び/又はリノール酸を80質量%以上含有する脂肪酸混合物を用いるのが好ましい。   The unsaturated fatty acid constituting the unsaturated SMG is not particularly limited as long as it is an unsaturated fatty acid that originates from edible animal and vegetable oils and contains one or more double bonds in the bond between carbon atoms. For example, palmitoolein Examples include acids, oleic acid, elaidic acid, linoleic acid, γ-linolenic acid, α-linolenic acid, arachidonic acid, ricinoleic acid, condensed ricinoleic acid and the like. These unsaturated fatty acids may be used alone or in any combination of two or more. In particular, it is preferable to use a fatty acid mixture containing 80% by mass or more of oleic acid and / or linoleic acid.

本発明の食味改善剤は、不飽和SMGのみをそのまま用いても良く、あるいは少なくとも不飽和SMGを含有する組成物として調製しても良い。本発明の食味改善剤をこのような組成物として調製する場合、不飽和SMG以外に、本発明の効果を阻害しない範囲で他の任意の成分を配合することができる。例えば、賦形剤(デキストリン、乳糖等)、旨味調味料(L−グルタミン酸ナトリウム等)、不飽和SMG以外の乳化剤等を配合することができる。   The taste improver of the present invention may be used as it is as unsaturated SMG, or may be prepared as a composition containing at least unsaturated SMG. When preparing the taste improving agent of this invention as such a composition, other arbitrary components can be mix | blended in the range which does not inhibit the effect of this invention other than unsaturated SMG. For example, excipients (dextrin, lactose, etc.), umami seasonings (L-sodium glutamate, etc.), emulsifiers other than unsaturated SMG, etc. can be blended.

本発明の食味改善剤は、油中水型油脂組成物に添加することにより、該油中水型油脂組成物の食味を改善するものである。なお、ここで言う食味とは該油中水型油脂組成物を喫食した際に感じられる呈味及び食感を総合した、食品としてのおいしさである。即ち、食味の改善とは、油中水型油脂組成物の呈味及び食感を同時に改善し、該油中水型油脂組成物の総合的なおいしさを向上させることを意味する。   The taste improver of the present invention improves the taste of the water-in-oil oil / fat composition by adding it to the water-in-oil oil / fat composition. In addition, the taste said here is the deliciousness as a foodstuff which put together the taste and texture which are felt when eating this water-in-oil type oil-fat composition. That is, improving the taste means improving the taste and texture of the water-in-oil oil / fat composition at the same time and improving the overall taste of the water-in-oil oil / fat composition.

本発明において呈味の改善とは、油中水型油脂組成物の水相に含まれる呈味成分に由来する呈味を口腔内で明瞭に発現させることを言う。本発明の食味改善剤が発現を明瞭化する呈味としては、例えば塩味、甘味、酸味、苦味及び旨味の基本5味、並びに辛味、渋味、コク味、その他食品素材の風味、香味等が挙げられるが、とりわけ塩味及び甘味が好ましい。また食感の改善とは、油中水型油脂組成物のなめらかさや口どけを良好にすることを言う。   In the present invention, “improvement of taste” means that taste derived from a taste component contained in the aqueous phase of the water-in-oil type oil-fat composition is clearly expressed in the oral cavity. Tastes that clarify the expression of the taste improver of the present invention include, for example, five basic tastes of salty taste, sweet taste, sour taste, bitter taste and umami taste, as well as pungent taste, astringency, rich taste, and other flavors and flavors of food materials. Among them, salty taste and sweetness are particularly preferable. Moreover, the improvement of food texture means making the smoothness and mouthfeel of a water-in-oil type oil and fat composition good.

本発明の食味改善剤を添加する対象の油中水型油脂組成物としては、油脂を主成分とする油相を連続相とし、前記油相中に水分を主成分とする水相を分散・混合させる乳化工程により得られる、油中水型乳化油脂組成物の形態の食品であれば特に制限はない。このような油中水型油脂組成物としては、例えばマーガリン、ファットスプレッド、バター、バタークリーム、クリームチーズ、ショートニング等が挙げられるが、特にマーガリン及びファットスプレッドが好ましい。ここで、マーガリンは油脂組成物中に占める油脂含有率が80質量%以上のものをいい、ファットスプレッドは80質量%未満のものをいう。またバタークリームとは、油相と水相とを起泡しながら乳化すること、又は一旦油中水型に乳化した油脂組成物をさらに起泡することにより得られる、気泡を含有する油中水型油脂組成物をいう。   As a water-in-oil type oil / fat composition to which the taste improver of the present invention is added, an oil phase mainly composed of fat / oil is used as a continuous phase, and a water phase mainly composed of water is dispersed in the oil phase / If it is a foodstuff of the form of the water-in-oil type emulsified fat composition obtained by the emulsification process to mix, there will be no restriction | limiting in particular. Examples of such a water-in-oil type oil and fat composition include margarine, fat spread, butter, butter cream, cream cheese, shortening and the like, and margarine and fat spread are particularly preferable. Here, margarine means that the fat content in the fat composition is 80% by mass or more, and fat spread means less than 80% by mass. The butter cream is water-in-oil containing bubbles, which is obtained by emulsifying an oil phase and an aqueous phase while foaming, or by further foaming an oil and fat composition once emulsified into a water-in-oil type. A type | mold oil-and-fat composition is said.

前記油中水型油脂組成物の油相を構成する油脂としては、一般に食品に用いられるものであれば特に制限はなく、例えばパーム油、パーム核油、菜種油、大豆油、ヒマワリ種子油、綿実油、落花生油、米糠油、コーン油、サフラワー油、オリーブ油、カポック油、ゴマ油、月見草油、シア脂、サル脂、カカオ脂、ヤシ油等の植物性油脂並びに乳脂、牛脂、ラード、魚油、鯨油等の動物性油脂あるいはそれらに硬化、分別、エステル交換等の処理を施した加工油脂が挙げられる。   The oil and fat constituting the oil phase of the water-in-oil type oil composition is not particularly limited as long as it is generally used in foods. For example, palm oil, palm kernel oil, rapeseed oil, soybean oil, sunflower seed oil, cottonseed oil , Peanut oil, rice bran oil, corn oil, safflower oil, olive oil, kapok oil, sesame oil, evening primrose oil, shea fat, monkey fat, cocoa butter, coconut oil and other vegetable oils and fats, beef fat, lard, fish oil, whale oil Animal fats and oils such as these, and processed fats and oils obtained by subjecting them to treatments such as hardening, fractionation and transesterification.

また、本発明の食味改善剤は油中水型油脂組成物の水相由来の呈味を明瞭に発現させることを目的とするものであるから、油中水型油脂組成物の中でも特に水溶性の各種呈味成分を含有するものに対して用いることが好ましい。   In addition, the taste improver of the present invention is intended to clearly express the taste derived from the aqueous phase of the water-in-oil oil composition, and is particularly water-soluble among water-in-oil oil compositions. It is preferable to use it for those containing various taste ingredients.

油中水型油脂組成物に含有される水溶性の呈味成分としては、例えば食塩、塩化マグネシウム、リン酸塩等の塩類、ショ糖、ブドウ糖、麦芽糖、乳糖、果糖、還元澱粉糖化物、水飴、トレハロース、オリゴ糖、異性化液糖、グルコース、フルクトース、ガラクトース、ソルビトール、還元乳糖、キシロース、キシリトール、マルチトール、エリスリトール、マンニトール、フラクトオリゴ糖、大豆オリゴ糖、ガラクトオリゴ糖、乳果オリゴ糖、ラフィノース、ラクチュロース、パラチノースオリゴ糖等の糖類、アスパルテーム、アセスルファムカリウム、スクラロース、ステビア、サッカリン、甘草抽出物、蜂蜜、メープルシロップ等の甘味料、生乳、牛乳、特別牛乳、生山羊乳、殺菌山羊乳、生めん羊乳、部分脱脂乳、粉乳、加工乳、濃縮乳、濃縮ホエイ、脱脂濃縮乳、無糖練乳、無糖脱脂練乳、加糖練乳、加糖脱脂練乳、全粉乳、脱脂粉乳、クリームパウダー、ホエイパウダー、蛋白質濃縮ホエイパウダー、バターミルクパウダー、加糖粉乳、調製粉乳、発酵乳、乳酸菌飲料、乳飲料、チーズ等の乳製品、カゼインカルシウム、カゼインナトリウム、ホエープロテインコンセートレート等の乳蛋白、酢酸、乳酸、クエン酸、酒石酸、グルコン酸等の酸味料、胡椒、しょうが、にんにく、トウガラシ等の香辛料・香味野菜類、昆布だし、かつおだし、いりこだし等のだし類、L−アスパラギン酸ナトリウム、DL−アラニン、L−イソロイシン、5’−イノシン酸二ナトリウム、5’−ウリジル酸二ナトリウム、塩化カリウム、5’−グアニル酸二ナトリウム、クエン酸一カリウム、クエン酸三カリウム、クエン酸三ナトリウム、グリシン、L−グルタミン酸、L−グルタミン酸アンモニウム、L−グルタミン酸カリウム、L−グルタミン酸カルシウム、L−グルタミン酸ナトリウム、L−グルタミン酸マグネシウム、コハク酸、コハク酸一ナトリウム、コハク酸二ナトリウム、酢酸ナトリウム、5’−シチジル酸二ナトリウム、DL−酒石酸ナトリウム、L−酒石酸ナトリウム、L−テアニン、DL−トリプトファン、L−トリプトファン、DL−トレオニン、L−トレオニン、乳酸カリウム、乳酸ナトリウム、L−バリン、L−フェニルアラニン、フマル酸一ナトリウム、DL−メチオニン、L−メチオニン、L−リシンL−アスパラギン酸塩、L−リシン塩酸塩、L−リシンL−グルタミン酸塩、5’−リボヌクレオチドカルシウム、5’−リボヌクレオチドニナトリウム、硫酸カリウム、DL−リンゴ酸ナトリウム、蛋白加水分解物、核酸等の調味料、豆類、ごま類、野菜類、果実類、肉類、魚介類等の食品素材、酵母エキス、ポークエキス、チキンエキス、魚介エキス、野菜エキス、きのこエキス等の各種エキス類、魚醤、醤油、味噌、ソース、果汁、ナッツペースト、カカオマス、ココアパウダー、コーヒー及びコーヒー製品、酒類、トマト加工品、コーン加工品、豆乳、マスタード、塩麹、酢等が挙げられる。これらの中でも、特に塩類、糖類及び甘味料が好ましく、とりわけ食塩(塩化ナトリウム)及び異性化液糖が好ましい。   Examples of the water-soluble taste component contained in the water-in-oil type oil / fat composition include salts such as sodium chloride, magnesium chloride and phosphate, sucrose, glucose, maltose, lactose, fructose, reduced starch saccharified product, and starch syrup. , Trehalose, oligosaccharide, isomerized liquid sugar, glucose, fructose, galactose, sorbitol, reduced lactose, xylose, xylitol, maltitol, erythritol, mannitol, fructooligosaccharide, soybean oligosaccharide, galactooligosaccharide, dairy oligosaccharide, raffinose, Sugars such as lactulose and palatinose oligosaccharides, sweeteners such as aspartame, acesulfame potassium, sucralose, stevia, saccharin, licorice extract, honey, maple syrup, raw milk, milk, special milk, raw goat milk, pasteurized goat milk, raw sheep Milk, partially skimmed milk, powdered milk, processed milk, concentrated , Concentrated whey, defatted concentrated milk, unsweetened condensed milk, unsweetened defatted condensed milk, sweetened condensed milk, sweetened defatted condensed milk, whole powdered milk, defatted powdered milk, cream powder, whey powder, protein concentrated whey powder, buttermilk powder, sweetened powdered milk, prepared powdered milk Dairy products such as fermented milk, lactic acid bacteria beverages, milk beverages, cheese, milk proteins such as calcium caseinate, sodium caseinate, whey protein concentrate, acidulants such as acetic acid, lactic acid, citric acid, tartaric acid, gluconic acid, pepper Ginger, garlic, spices such as pepper, flavored vegetables, kombu dashi, bonito dashi, darikodashi dashi, L-aspartate sodium, DL-alanine, L-isoleucine, 5'-inosinic acid disodium, 5 ' -Disodium uridylate, potassium chloride, disodium 5'-guanylate, monopotassium citrate , Tripotassium citrate, trisodium citrate, glycine, L-glutamic acid, ammonium L-glutamate, potassium L-glutamate, calcium L-glutamate, sodium L-glutamate, magnesium L-glutamate, succinic acid, monosodium succinate, Disodium succinate, sodium acetate, disodium 5′-cytidylate, DL-sodium tartrate, sodium L-tartrate, L-theanine, DL-tryptophan, L-tryptophan, DL-threonine, L-threonine, potassium lactate, lactic acid Sodium, L-valine, L-phenylalanine, monosodium fumarate, DL-methionine, L-methionine, L-lysine L-aspartate, L-lysine hydrochloride, L-lysine L-glutamate, 5'-ribonuclease Food materials such as tide calcium, 5'-ribonucleotide disodium, potassium sulfate, DL-sodium malate, protein hydrolysates, nucleic acid seasonings, beans, sesame seeds, vegetables, fruits, meats, seafood, etc. Various extracts such as yeast extract, pork extract, chicken extract, seafood extract, vegetable extract, mushroom extract, fish sauce, soy sauce, miso, sauce, fruit juice, nut paste, cacao mass, cocoa powder, coffee and coffee products, alcoholic beverages, Examples include processed tomato products, processed corn products, soy milk, mustard, salted salmon, and vinegar. Among these, salts, saccharides and sweeteners are particularly preferable, and sodium chloride (sodium chloride) and isomerized liquid sugar are particularly preferable.

本発明の食味改善剤を添加して油中水型油脂組成物を製造する方法に特に制限はなく、慣用の装置を用いて、常法により製造することができる。以下に、本発明の食味改善剤を添加したマーガリン及びファットスプレッド、並びにバタークリームの製造方法の一例を示す。   There is no restriction | limiting in particular in the method of adding the taste improving agent of this invention, and manufacturing a water-in-oil type oil-fat composition, It can manufacture by a conventional method using a conventional apparatus. Below, an example of the manufacturing method of the margarine and fat spread which added the taste improving agent of this invention, and a butter cream is shown.

<マーガリン及びファットスプレッドの製造方法>
例えば、油脂及び本発明の食味改善剤を混合し、通常50〜90℃、好ましくは60〜80℃に加熱して溶解し、所望により酸化防止剤(例えば抽出トコフェロール等)、着色料(例えばβ−カロテン等)、香料(例えばミルクフレーバー等)、不飽和SMG以外の乳化剤(例えばポリグリセリン縮合リシノール酸エステル、レシチン等)等を添加して油相とする。一方、精製水に、所望により前記呈味成分等を加え、50〜60℃に加熱して溶解し水相とする。次に、前記油相と水相を通常の攪拌・混合槽を用いて混合し、得られた混合液を送液ポンプで急冷捏和装置に送液し、油脂の結晶化と練捏を連続的に行いマーガリン又はファットスプレッドを得る。また乳化工程をとらず、油相と水相をそれぞれ定量ポンプで急冷捏和装置に送液し、以下同様に処理しマーガリン又はファットスプレッドを得ることもできる。得られたマーガリン又はファットスプレッドは、更に、25〜30℃で12〜72時間テンパリングされるのが好ましい。
<Method for producing margarine and fat spread>
For example, the fats and oils and the taste improver of the present invention are mixed, and usually dissolved by heating to 50 to 90 ° C., preferably 60 to 80 ° C., if desired, an antioxidant (for example, extracted tocopherol, etc.), a colorant (for example, β -Carotene etc.), flavor (eg milk flavor etc.), emulsifiers other than unsaturated SMG (eg polyglycerin condensed ricinoleic acid ester, lecithin etc.) etc. are added to make an oil phase. On the other hand, if necessary, the above-described taste components and the like are added to purified water, and the mixture is heated to 50 to 60 ° C. to dissolve to obtain an aqueous phase. Next, the oil phase and the aqueous phase are mixed using a normal stirring / mixing tank, and the resulting liquid mixture is sent to a quenching and kneading device with a liquid feed pump, and crystallization of oil and fat and kneading are continuously performed. To get a margarine or fat spread. Also, without taking the emulsification step, the oil phase and the water phase can be respectively sent to a quenching and kneading device with a metering pump, and then treated in the same manner to obtain margarine or fat spread. The obtained margarine or fat spread is preferably tempered at 25-30 ° C. for 12-72 hours.

<バタークリームの製造方法>
例えば、油脂及び本発明の食味改善剤を混合し、通常50〜90℃、好ましくは60〜80℃に加熱して溶解し、所望により酸化防止剤(例えば抽出トコフェロール等)、着色料(例えばβ−カロテン等)、香料(例えばミルクフレーバー等)、不飽和SMG以外の乳化剤(例えばポリグリセリン縮合リシノール酸エステル、レシチン等)等を添加する。得られた溶液を送液ポンプで予冷器を通して急冷捏和装置に送液し、油脂の結晶化と練捏を連続的に行い油脂組成物を得る。得られた油脂組成物は、更に、25〜30℃で12〜72時間テンパリングされるのが好ましい。
前記油脂組成物を油相とし、通常10〜30℃、好ましくは15〜25℃に調温してミキサーで起泡する。ここに水相として前記呈味成分をそのまま、又は精製水に溶解して加え、任意の比重になるまでさらに起泡してバタークリームを得る。
<Method for producing butter cream>
For example, the fats and oils and the taste improver of the present invention are mixed, and usually dissolved by heating to 50 to 90 ° C., preferably 60 to 80 ° C., if desired, an antioxidant (for example, extracted tocopherol, etc.), a colorant (for example, β -Carotene etc.), fragrance (eg milk flavor etc.), emulsifiers other than unsaturated SMG (eg polyglycerin condensed ricinoleic acid ester, lecithin etc.) etc. are added. The obtained solution is sent to a quenching kneader through a precooler with a liquid feed pump, and oil and fat crystallization and kneading are continuously performed to obtain an oil and fat composition. It is preferable that the obtained oil and fat composition is further tempered at 25 to 30 ° C. for 12 to 72 hours.
The oil / fat composition is used as an oil phase, and the temperature is usually adjusted to 10 to 30 ° C., preferably 15 to 25 ° C., and foamed with a mixer. The said taste component is added as it is or melt | dissolved in refined water here as an aqueous phase, and it foams further until it becomes arbitrary specific gravity, and obtains a butter cream.

本発明の食味改善剤の油中水型油脂組成物への添加量は、油中水型油脂組成物における油相と水相の比率、油中水型油脂組成物に含まれる食品原材料、呈味成分の量等によって異なるが、油中水型油脂組成物100質量部に対して、不飽和SMGが好ましくは0.05〜3質量部、より好ましくは0.1〜2質量部となるように添加することが、良好な食味を得る上で効果的である。   The amount of the taste improver of the present invention added to the water-in-oil oil / fat composition is the ratio of the oil phase to the water phase in the water-in-oil oil / fat composition, the food ingredients contained in the water-in-oil oil / fat composition, Although it varies depending on the amount of the taste component, etc., the unsaturated SMG is preferably 0.05 to 3 parts by mass, more preferably 0.1 to 2 parts by mass with respect to 100 parts by mass of the water-in-oil type oil / fat composition. It is effective to add good to the taste.

以下、実施例をもって本発明を具体的に説明するが、本発明はこれらに限定されるものではない。   Hereinafter, the present invention will be specifically described with reference to examples, but the present invention is not limited thereto.

[製造例1]
[グリセリンコハク酸不飽和脂肪酸エステルの調製]
グリセリンモノ不飽和脂肪酸エステル(商品名:エマルジーOL−100H;構成脂肪酸:オレイン酸;理研ビタミン社製)724.5g、無水コハク酸(商品名:リカシッド;新日本理化社製)175.5g、を仕込み、80℃から20℃/時間で110℃まで攪拌しながら昇温し、110℃で30分間エステル化反応を行わせた。得られた反応混合物を冷却し、グリセリンコハク酸不飽和脂肪酸エステル(試作品1)を得た。
[Production Example 1]
[Preparation of glycerin succinic unsaturated fatty acid ester]
724.5 g of glycerin monounsaturated fatty acid ester (trade name: Emulgie OL-100H; constituent fatty acid: oleic acid; manufactured by Riken Vitamin Co., Ltd.), 175.5 g of succinic anhydride (trade name: Ricacid; manufactured by Shin Nippon Rika Co., Ltd.) The temperature was raised while stirring from 80 ° C. to 110 ° C. at 20 ° C./hour, and an esterification reaction was performed at 110 ° C. for 30 minutes. The obtained reaction mixture was cooled to obtain a glycerin succinic unsaturated fatty acid ester (prototype 1).

[製造例2]
[グリセリンコハク酸飽和脂肪酸エステルの調製]
グリセリンモノ飽和脂肪酸エステル(商品名:エマルジーP−100;構成脂肪酸:パルミチン酸;理研ビタミン社製)720g、無水コハク酸(商品名:リカシッド;新日本理化社製)180gを仕込み、80℃から20℃/時間で110℃まで攪拌しながら昇温し、110℃で30分間エステル化反応を行わせた。得られた反応混合物を冷却し、グリセリンコハク酸飽和脂肪酸エステル(試作品2;以下、飽和SMGともいう)を得た。
[Production Example 2]
[Preparation of glycerin succinic acid saturated fatty acid ester]
Glycerin mono-saturated fatty acid ester (trade name: Emulsy P-100; constituent fatty acid: palmitic acid; manufactured by Riken Vitamin Co., Ltd.) 720 g, succinic anhydride (trade name: Ricacid; manufactured by Shin Nippon Rika Co., Ltd.) The temperature was raised to 110 ° C. with stirring at a temperature of 110 ° C./hour, and an esterification reaction was carried out at 110 ° C. for 30 minutes. The obtained reaction mixture was cooled to obtain a glycerin succinic acid saturated fatty acid ester (prototype 2; hereinafter also referred to as saturated SMG).

[マーガリンによる評価]
(1)原材料
1)菜種硬化油(商品名:HR−35;横関油脂工業社製)
2)菜種白絞油(商品名:ナタネサラダ油;ボーソー油脂社製)
3)イオン交換水
4)食塩(日本食塩製造社製)
5)供試乳化剤
5−1)不飽和SMG(試作品1)
5−2)飽和SMG(試作品2)
5−3)グリセリン飽和脂肪酸エステル(商品名:エマルジーMS;構成脂肪酸:ステアリン酸;理研ビタミン社製)
5−4)レシチン(商品名:大豆レシチンA;リノール油脂社製)
[Evaluation by margarine]
(1) Raw materials 1) Hardened rapeseed oil (trade name: HR-35; manufactured by Yokoseki Yushi Kogyo Co., Ltd.)
2) Rapeseed white squeezed oil (trade name: rapeseed salad oil; manufactured by Borso Oil & Fats)
3) Ion-exchanged water 4) Salt (manufactured by Nippon Salt Manufacturing Co., Ltd.)
5) Test emulsifier 5-1) Unsaturated SMG (Prototype 1)
5-2) Saturated SMG (Prototype 2)
5-3) Glycerin saturated fatty acid ester (trade name: Emergy MS; constituent fatty acid: stearic acid; manufactured by Riken Vitamin Co., Ltd.)
5-4) Lecithin (trade name: soybean lecithin A; manufactured by Linoleum Yushi Co., Ltd.)

(2)原材料の配合
前記原材料を用いて調製したマーガリン1〜4の配合組成を表1に示した。この内、マーガリン1は、食味改善剤として不飽和SMGを添加した実施例である。また、マーガリン2〜4は、食味改善剤として不飽和SMG以外の乳化剤を添加した比較例である。なお、表1の配合割合は、供試乳化剤を除いた原材料の合計が100質量部となるように表記し、各マーガリンは当該原材料の合計が200gとなる分量で調製した。
(2) Blending of raw materials Table 1 shows blending compositions of margarines 1 to 4 prepared using the raw materials. Among these, Margarine 1 is an example in which unsaturated SMG was added as a taste improver. Margarines 2 to 4 are comparative examples in which an emulsifier other than unsaturated SMG was added as a taste improver. In addition, the compounding ratio of Table 1 was described so that the total of raw materials excluding the test emulsifier was 100 parts by mass, and each margarine was prepared in an amount such that the total of the raw materials was 200 g.

Figure 0006441719
Figure 0006441719

(3)マーガリンの調製方法
1)ビーカーに菜種硬化油、菜種白絞油及び各供試乳化剤を所定量入れ、80℃で溶融混合し、油相部となる混合油脂を得た。
2)一方、別のビーカーにイオン交換水及び食塩を所定量入れ、60℃で混合し、水相部となる食塩水を得た。
3)前記混合油脂を、TKホモミキサー(商品名;型式:M型;プライミクス社製)を用いて約10000rpmで撹拌しながら、60℃に保温しておいた前記食塩水を少量ずつ加え、3分間撹拌して油中水型乳化液を得た。
4)撹拌終了後すぐにビーカーを10℃の恒温槽に投入し、前記油中水型乳化液をガラス棒で撹拌しながら15℃まで冷却した。
5)前記油中水型乳化液をプラスチック製容器に移し替え、冷蔵庫で5℃に急冷して油中水型乳化油脂組成物の形態のマーガリン1〜4を得た。
(3) Method for preparing margarine 1) Predetermined amounts of rapeseed oil, rapeseed white oil and each test emulsifier were placed in a beaker, and melted and mixed at 80 ° C. to obtain a mixed oil and fat that became an oil phase part.
2) On the other hand, a predetermined amount of ion-exchanged water and sodium chloride were put in another beaker and mixed at 60 ° C. to obtain a sodium chloride aqueous solution.
3) While stirring the above-mentioned mixed fats and oils at about 10000 rpm using a TK homomixer (trade name; model: M type; manufactured by Primics), the above-mentioned saline kept at 60 ° C. is added little by little. Stirring for a minute gave a water-in-oil emulsion.
4) Immediately after the stirring, the beaker was put into a 10 ° C. thermostatic bath, and the water-in-oil emulsion was cooled to 15 ° C. while stirring with a glass rod.
5) The water-in-oil emulsion was transferred to a plastic container and rapidly cooled to 5 ° C. in a refrigerator to obtain margarines 1 to 4 in the form of a water-in-oil emulsified fat composition.

(4)官能評価
得られたマーガリン1〜4の塩味及びなめらかさについて、官能評価を行った。評価は表2の評価基準により、10名のパネラーで行った。結果はそれぞれ10名の評点の平均値を求め、下記基準にて記号化した。結果を表3に示す。
◎:極めて良好 平均値3.5以上
○:良好 平均値2.5以上、3.5未満
△:やや悪い 平均値1.5以上、2.5未満
×:悪い 平均値1.5未満
(4) Sensory evaluation Sensory evaluation was performed about the salty taste and smoothness of the obtained margarines 1-4. Evaluation was performed by 10 panelists according to the evaluation criteria shown in Table 2. The results were obtained by averaging the scores of 10 people each and symbolizing them according to the following criteria. The results are shown in Table 3.
◎: Very good Average value 3.5 or more ○: Good Average value 2.5 or more, less than 3.5 △: Slightly bad Average value 1.5 or more, less than 2.5 ×: Bad Average value less than 1.5

Figure 0006441719
Figure 0006441719

Figure 0006441719
Figure 0006441719

表3の結果から明らかなように、本発明の実施例であるマーガリン1は、塩味が強く感じられ、食感もなめらかで良好な食味が得られた。一方、比較例であるマーガリン2〜4は、いずれも塩味やなめらかさが劣っていた。特に、マーガリン4は食味改善効果がほぼ得られていないことが確認された。   As is apparent from the results in Table 3, the margarine 1 which is an example of the present invention felt a strong salty taste, a smooth texture and a good taste. On the other hand, margarines 2 to 4 as comparative examples were all inferior in salty taste and smoothness. In particular, it was confirmed that margarine 4 has almost no taste improvement effect.

(5)電気伝導度の測定
官能評価の結果、一定の呈味改善効果が得られたマーガリン1〜3について、呈味の発現性を定量的に表すため、下記の測定方法により電気伝導度を測定した。
(5) Measurement of electrical conductivity In order to quantitatively express the expression of taste for margarines 1 to 3, which obtained a certain taste improvement effect as a result of sensory evaluation, the electrical conductivity was measured by the following measurement method. It was measured.

[電気伝導度の測定方法]
1)ビーカーにイオン交換水800gを加え、循環式恒温槽にて40℃まで加温する。
2)冷蔵(5℃)しておいた各マーガリン8gを前記イオン交換水に投入し、マグネチックスターラー(型式:SR−350;アドバンテック東洋社製)を用いて150rpmで撹拌しながら溶解させていく。
3)電気伝導度計(型式:ES−71;堀場製作所社製)を用いて、経時的に電気伝導度を測定する。
[Measurement method of electrical conductivity]
1) Add 800 g of ion-exchanged water to a beaker and heat to 40 ° C. in a circulating thermostat.
2) 8 g of each margarine that has been refrigerated (5 ° C.) is added to the ion-exchanged water, and dissolved with stirring at 150 rpm using a magnetic stirrer (model: SR-350; manufactured by Advantech Toyo Co., Ltd.). .
3) Using a conductivity meter (model: ES-71; manufactured by HORIBA, Ltd.), measure the conductivity over time.

マーガリン投入からの経過時間が200秒、400秒、600秒のそれぞれの時点における電気伝導度の測定結果を表4に示した。   Table 4 shows the measurement results of the electrical conductivity at the time points of 200 seconds, 400 seconds and 600 seconds after the introduction of margarine.

Figure 0006441719
Figure 0006441719

ここで、一般に水は塩分濃度が高いほど電気伝導度も高くなる。即ち、イオン交換水における電気伝導度は、マーガリンからイオン交換水中に溶解した塩分の量に比例して上昇するため、前記測定結果は各マーガリンにおける塩分の溶出速度を表す。   Here, in general, the higher the salinity of water, the higher the electrical conductivity. That is, the electrical conductivity in ion-exchanged water increases in proportion to the amount of salt dissolved from margarine in ion-exchanged water, and thus the measurement result represents the elution rate of salt in each margarine.

表4の結果より、本発明の実施例であるマーガリン1は、マーガリン2及び3に比べて投入後600秒経過時点までの電気伝導度の上昇が速い。即ち、マーガリン1はこれらの中で最も塩分の溶出速度が速かった。このことから、食味改善剤として不飽和SMGを添加したマーガリンは、水相に含まれる呈味成分の溶出が速く、口腔内においてその呈味を感じやすいことがわかった。   From the results in Table 4, margarine 1 which is an example of the present invention has a quick increase in electrical conductivity up to 600 seconds after charging compared to margarines 2 and 3. That is, margarine 1 had the highest salt elution rate among them. From this, it was found that margarine to which unsaturated SMG was added as a taste improver had a fast dissolution of taste components contained in the aqueous phase, and it was easy to feel the taste in the oral cavity.

[ファットスプレッドによる評価]
(1)原材料
1)菜種硬化油(商品名:HR−35;横関油脂工業社製)
2)菜種白絞油(商品名:ナタネサラダ油;ボーソー油脂社製)
3)イオン交換水
4)食塩(日本食塩製造社製)
5)ポリグリセリン縮合リシノール酸エステル(商品名:SYグリスターCRS−75;阪本薬品工業社製)
6)レシチン(商品名:SLP−ペースト;辻製油社製)
7)供試乳化剤
7−1)不飽和SMG(試作品1)
7−2)グリセリン不飽和脂肪酸エステル(商品名:エマルジーHRO;構成脂肪酸:オレイン酸、リノール酸;理研ビタミン社製)
[Evaluation by fat spread]
(1) Raw materials 1) Hardened rapeseed oil (trade name: HR-35; manufactured by Yokoseki Yushi Kogyo Co., Ltd.)
2) Rapeseed white squeezed oil (trade name: rapeseed salad oil; manufactured by Borso Oil & Fats)
3) Ion-exchanged water 4) Salt (manufactured by Nippon Salt Manufacturing Co., Ltd.)
5) Polyglycerin condensed ricinoleic acid ester (trade name: SY Glyster CRS-75; manufactured by Sakamoto Pharmaceutical Co., Ltd.)
6) Lecithin (trade name: SLP-Paste; manufactured by Sakai Oil Co., Ltd.)
7) Test emulsifier 7-1) Unsaturated SMG (Prototype 1)
7-2) Glycerin unsaturated fatty acid ester (trade name: Emulsy HRO; constituent fatty acids: oleic acid, linoleic acid; manufactured by Riken Vitamin Co., Ltd.)

(2)原材料の配合
前記原材料を用いて調製したファットスプレッド1及び2の配合組成を表5に示した。この内、ファットスプレッド1は、食味改善剤として不飽和SMGを添加した実施例である。また、ファットスプレッド2は、食味改善剤として不飽和SMG以外の乳化剤を添加した比較例である。なお、各ファットスプレッドは前記原材料の合計が200gとなる分量で調製した。
(2) Blending of raw materials Table 5 shows blending compositions of fat spreads 1 and 2 prepared using the raw materials. Of these, fat spread 1 is an example in which unsaturated SMG was added as a taste improver. Fat spread 2 is a comparative example in which an emulsifier other than unsaturated SMG is added as a taste improver. Each fat spread was prepared in such an amount that the total of the raw materials was 200 g.

Figure 0006441719
Figure 0006441719

(3)ファットスプレッドの調製方法
1)ビーカーに菜種硬化油、菜種白絞油、ポリグリセリン縮合リシノール酸エステル、レシチン及び各供試乳化剤を所定量入れ、70℃で溶融混合し、油相部となる混合油脂を得た。
2)一方、別のビーカーにイオン交換水及び食塩を所定量入れ、60℃で混合し、水相部となる食塩水を得た。
3)前記混合油脂を、TKホモミキサー(商品名;型式:M型;プライミクス社製)を用いて約10000rpmで撹拌しながら、60℃に保温しておいた前記食塩水を少量ずつ加え、3分間撹拌して油中水型乳化液を得た。
4)撹拌終了後すぐにビーカーを10℃の恒温槽に投入し、前記油中水型乳化液をガラス棒で撹拌しながら15℃まで冷却した。
5)前記油中水型乳化液をプラスチック製容器に移し替え、冷蔵庫で5℃に急冷して油中水型乳化油脂組成物の形態のファットスプレッド1及び2を得た。
(3) Fat spread preparation method 1) A predetermined amount of hardened rapeseed oil, rapeseed white squeezed oil, polyglycerin condensed ricinoleic acid ester, lecithin and each test emulsifier is put into a beaker, melted and mixed at 70 ° C., and the oil phase part The resulting mixed oil was obtained.
2) On the other hand, a predetermined amount of ion-exchanged water and sodium chloride were put in another beaker and mixed at 60 ° C. to obtain a sodium chloride aqueous solution.
3) While stirring the above-mentioned mixed fats and oils at about 10000 rpm using a TK homomixer (trade name; model: M type; manufactured by Primics), the above-mentioned saline kept at 60 ° C. is added little by little. Stirring for a minute gave a water-in-oil emulsion.
4) Immediately after the stirring, the beaker was put into a 10 ° C. thermostatic bath, and the water-in-oil emulsion was cooled to 15 ° C. while stirring with a glass rod.
5) The water-in-oil emulsion was transferred to a plastic container and rapidly cooled to 5 ° C. in a refrigerator to obtain fat spreads 1 and 2 in the form of a water-in-oil emulsion fat composition.

(4)官能評価
得られたファットスプレッド1及び2の塩味及びなめらかさについて、官能評価を行った。評価は表6の評価基準により、10名のパネラーで行った。結果はそれぞれ10名の評点の平均値を求め、下記基準にて記号化した。結果を表7に示す。
◎:極めて良好 平均値3.5以上
○:良好 平均値2.5以上、3.5未満
△:やや悪い 平均値1.5以上、2.5未満
×:悪い 平均値1.5未満
(4) Sensory evaluation Sensory evaluation was performed about the salty taste and smoothness of the obtained fat spreads 1 and 2. Evaluation was performed by 10 panelists according to the evaluation criteria shown in Table 6. The results were obtained by averaging the scores of 10 people each and symbolizing them according to the following criteria. The results are shown in Table 7.
◎: Very good Average value 3.5 or more ○: Good Average value 2.5 or more, less than 3.5 △: Slightly bad Average value 1.5 or more, less than 2.5 ×: Bad Average value less than 1.5

Figure 0006441719
Figure 0006441719

Figure 0006441719
Figure 0006441719

表7の結果から明らかなように、本発明の実施例であるファットスプレッド1は、塩味が強く感じられ、食感もなめらかで良好な食味が得られた。一方、比較例であるファットスプレッド2は、塩味がほとんど感じられず、なめらかさにおいてもやや劣っていた。   As is clear from the results in Table 7, the fat spread 1 which is an example of the present invention felt a strong salty taste, a smooth texture, and a good taste. On the other hand, Fat Spread 2, which is a comparative example, was hardly inferior in saltiness and was slightly inferior in smoothness.

[バタークリームによる評価]
(1)原材料
1)菜種硬化油(商品名:HR−35;横関油脂工業社製)
2)果糖ブドウ糖液糖(商品名:ハイフラクトM;日本コーンスターチ社製)
3)供試乳化剤
3−1)不飽和SMG(試作品1)
3−2)飽和SMG(試作品2)
3−3)グリセリン飽和脂肪酸エステル(商品名:エマルジーMS;構成脂肪酸:ステアリン酸;理研ビタミン社製)
3−4)レシチン(商品名:SLP−ペースト;辻製油社製)
[Evaluation with butter cream]
(1) Raw materials 1) Hardened rapeseed oil (trade name: HR-35; manufactured by Yokoseki Yushi Kogyo Co., Ltd.)
2) Fructose dextrose liquid sugar (trade name: Hyfract M; manufactured by Nippon Cornstarch)
3) Test emulsifier 3-1) Unsaturated SMG (Prototype 1)
3-2) Saturated SMG (Prototype 2)
3-3) Glycerin saturated fatty acid ester (trade name: Emergy MS; constituent fatty acid: stearic acid; manufactured by Riken Vitamin Co., Ltd.)
3-4) Lecithin (trade name: SLP-paste; manufactured by Sakai Oil Co., Ltd.)

(2)油相の調製
1)ビーカーに菜種硬化油300gを入れ、ここに表8に示す分量の供試乳化剤をそれぞれ加えて60℃で溶融混合した。
2)ビーカーを2℃の恒温槽に投入し、ガラス棒で撹拌しながら前記混合物の流動性がなくなるまで冷却した。
3)ビーカーを恒温槽から取り出してさらに90秒撹拌した後、これを25℃で16時間テンパリングした。
4)テンパリング後、冷蔵庫で5℃に急冷してバタークリームの油相となる油脂組成物1〜3を得た。
(2) Preparation of oil phase 1) 300 g of rapeseed oil was put in a beaker, and the amounts of test emulsifiers shown in Table 8 were added thereto, and melt mixed at 60 ° C.
2) The beaker was put into a constant temperature bath at 2 ° C. and cooled with stirring with a glass rod until the fluidity of the mixture disappeared.
3) The beaker was taken out of the thermostat and stirred for another 90 seconds, and then tempered at 25 ° C. for 16 hours.
4) After tempering, oil compositions 1 to 3 were obtained that were rapidly cooled to 5 ° C. in a refrigerator to become the oil phase of butter cream.

Figure 0006441719
Figure 0006441719

(3)バタークリームの調製
1)予め20℃に調温した油脂組成物1〜3を、それぞれ180gずつ卓上型ミキサー(商品名:ケンミックスアイコープロKM−600;愛工舎製作所社製)に投入し、速度を「MAX」に設定して1分間ホイップした。
2)1分後、ミキサーを止めてヘラでかき混ぜ、再びミキサーで1分間ホイップした。この操作を、比重が0.4〜0.5g/mLになるまで繰り返した。
3)上記の比重になったところで、液糖120gをゆっくりと加えながらミキサーで1分間ホイップした。
4)1分後、ミキサーを止めてヘラでかき混ぜ、再びミキサーで1分間ホイップした。この操作を、比重が0.6g/mLになるまで繰り返した。
5)上記の比重になったところで、ポリ容器に移して冷蔵庫で5℃に急冷し、油中水型油脂組成物の形態のバタークリーム1〜3各300gを得た。
(3) Preparation of butter cream 1) Each of the oil and fat compositions 1 to 3 preliminarily adjusted to 20 ° C. is put into a desktop mixer (trade name: Kenmix Aiko Pro KM-600; manufactured by Aikosha Seisakusho). Then, the speed was set to “MAX” and whipped for 1 minute.
2) After 1 minute, the mixer was stopped, stirred with a spatula, and whipped again with the mixer for 1 minute. This operation was repeated until the specific gravity reached 0.4 to 0.5 g / mL.
3) When the above specific gravity was reached, 120 g of liquid sugar was slowly added while whipping with a mixer for 1 minute.
4) After 1 minute, the mixer was stopped, stirred with a spatula, and whipped again with the mixer for 1 minute. This operation was repeated until the specific gravity reached 0.6 g / mL.
5) When it became said specific gravity, it moved to the plastic container and rapidly cooled to 5 degreeC with the refrigerator, and obtained 300 g of butter cream 1-3 of the form of the water-in-oil type oil-fat composition.

(4)官能評価
得られたバタークリーム1〜3の甘味及び口どけについて、官能評価を行った。評価は表9の評価基準により、10名のパネラーで行った。結果はそれぞれ10名の評点の平均値を求め、下記基準にて記号化した。結果を表10に示す。
◎:極めて良好 平均値3.5以上
○:良好 平均値2.5以上、3.5未満
△:やや悪い 平均値1.5以上、2.5未満
×:悪い 平均値1.5未満
(4) Sensory evaluation Sensory evaluation was performed about the sweetness and mouthfeel of the obtained butter creams 1-3. Evaluation was carried out by 10 panelists according to the evaluation criteria shown in Table 9. The results were obtained by averaging the scores of 10 people each and symbolizing them according to the following criteria. The results are shown in Table 10.
◎: Very good Average value 3.5 or more ○: Good Average value 2.5 or more, less than 3.5 △: Slightly bad Average value 1.5 or more, less than 2.5 ×: Bad Average value less than 1.5

Figure 0006441719
Figure 0006441719

Figure 0006441719
Figure 0006441719

表10の結果から明らかなように、本発明の実施例であるバタークリーム1は、甘味が強く感じられ、口どけも良く良好な食味が得られた。一方、比較例であるバタークリーム2は甘味や口どけがやや劣っており、バタークリーム3は食味改善効果がほぼ得られていないことが確認された。   As is apparent from the results in Table 10, the butter cream 1 which is an example of the present invention felt strong in sweetness, had a good mouthfeel, and had a good taste. On the other hand, it was confirmed that the butter cream 2 which is a comparative example is slightly inferior in sweetness and mouthfeel, and the butter cream 3 has almost no effect of improving the taste.

Claims (3)

グリセリンコハク酸不飽和脂肪酸エステルを有効成分とすることを特徴とする油中水型油脂組成物用食味改善剤。   A taste improver for water-in-oil type oil and fat compositions, characterized by comprising glycerin succinic unsaturated fatty acid ester as an active ingredient. 請求項1記載の油中水型油脂組成物用食味改善剤を含有する油中水型油脂組成物。   The water-in-oil type oil-fat composition containing the taste improving agent for water-in-oil type oil-fat compositions of Claim 1. 請求項1記載の油中水型油脂組成物用食味改善剤を油中水型油脂組成物に添加することを特徴とする油中水型油脂組成物の食味改善方法。   A method for improving the taste of a water-in-oil oil / fat composition, comprising adding the taste improver for a water-in-oil oil / fat composition according to claim 1 to the water-in-oil oil / fat composition.
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