JP6434465B2 - Method for producing fuel diluted with water - Google Patents

Description

The present invention provides a fuel (hydrofuel) obtained by diluting an oil obtained by adding an additive and water improved by an additive and a natural or artificial ore to a fuel oil brought into contact with the additive and a natural or artificial ore with water. It is about the method.

In recent years, prevention of global warming has become a global issue, and various proposals have been made regarding techniques for reducing carbon dioxide (CO2) emitted by consumption of fossil fuels.

Under these circumstances, as a method to reduce environmental impact and reduce costs while taking advantage of the features of fossil fuels, the oil produced by mixing conventional fuel oil, water, and surfactants is diluted with water. The technology related to the fuel has been reviewed. As such a prior art, there is one described in Patent Document 1 below.

In the technique of Patent Document 1, natural ore or artificial ore is brought into contact with oily water to which an enzyme has been added, and at the same time, stirred and mixed while applying ultrasonic vibration, and further, fuel oil and water that have been stirred and mixed are heated to 30 ° C to 150 ° C. This is a method for producing an emulsion fuel that is heated to ° C. and pressurized at a pressure of 1.5 Pa (atmospheric pressure) to 20 Pa. This manufacturing method can prevent the oil-water separation phenomenon of the emulsion fuel having a water content ratio of 50% or more, and the oil-water can be highly fused and transparent even in the emulsion state, and a stable high-calorie fuel is realized.

Japanese Patent No. 4682287

However, in the invention described in Patent Document 1, there is a limit to the period during which the oil / water separation phenomenon can be prevented, and the oil / water separation phenomenon may occur after a few months. In addition, there is a problem that the transparency of a fuel obtained by diluting oil with water is lower than that of oil.

The present invention has been made in view of the circumstances described above, and its purpose is that once it is synthesized, it is never separated into water and oil, it is highly transparent, and can be distinguished from ordinary oil. It is to provide a method for producing a fuel in which not much oil is diluted with water.

That method of manufacturing a fuel oil of the present invention was diluted with water, in order to achieve the above object, the oil for mixing the fuel oil and water in the manufacturing method of a fuel dilution with water, the molecular aggregates of water alone An ionization process for fragmenting and ionizing;
Desirably, an additive charging step of adding sodium, magnesium chloride, and magnesium as additives to water, and fuel oil is charged into a stirring and mixing tank, and the fuel oil is circulated by a mixer while the ionized and additive is added. A stirring and mixing step of mixing and stirring the charged water;
A fusion step of repeating the agitation and mixing step for at least 10 to 30 minutes with a temperature of 15 to 80 ° C. and an atmospheric pressure of 1.5 to 9 Pa applied to the fuel oil and water that have been agitated and mixed. Features.

In this method, water is greatly improved by the ionization step and the additive charging step, so that the affinity with the fuel oil is improved and the fuel oil can be increased.

In the ionization step, water is irradiated with ultrasonic waves of 15 kHz to 35 kHz.
Moreover, in this ionization process, it is an object to subdivide the molecular aggregate of water.
Further, in the additive charging step, 0.004 wt% to 2 wt% may be added to the volume of water, or the sodium and magnesium chloride are less than 0.001 wt% with respect to water. You may add 0.1weight%. Any quantity of magnesium can be input.

According to the present invention, a fuel obtained by diluting an oil with water so that it is not separated from water and oil once and is highly transparent and indistinguishable from ordinary oil is realized once synthesized. Is done. In addition, the fuel obtained by diluting the oil of the present invention with water has a calorific value per unit amount equal to or higher than that of the existing fuel oil, and further, compared with the existing fuel oil, the combustion chamber and exhaust pipe after combustion There is an effect that there is little deterioration and corrosion. In addition, the fuel obtained by diluting the oil of the present invention with water has various effects such as excellent complete combustibility, difficulty in generating carbon monoxide, and low emission of carbon dioxide.

It is a flowchart explaining the manufacturing method of the fuel which diluted the oil which concerns on the 1st Embodiment of this invention with water.

(Embodiment 1)
FIG. 1 is a flowchart for explaining a method for producing a fuel obtained by diluting oil with water according to a first embodiment of the present invention. As shown in this figure, the method for producing a fuel obtained by diluting the oil of the present invention with water comprises an ionization step (water reforming step) 1 for subdividing a molecular aggregate of water alone as a raw material, and preferably water. An additive charging process 2 for adding an additive to the water, a stirring and mixing process 3 for mixing and stirring water and fuel oil (hereinafter simply referred to as oil), and a fusion process 4 for fusing the stirred water and oil. Have.

Ionization process (water reforming process)
In the ionization step (water reforming step) 1, the molecular aggregate of water as a raw material is subdivided by various methods. Along with the subdivision, the water is waved so that water molecules are radical and molecular migration is likely to occur. As a first method, there is a method of subdividing a molecular assembly of water by irradiating water and natural ore with ultrasonic waves. In this method, a porous ionized material, natural or artificial ore, and an ion generating material are placed in water so that the material is brought into contact with water in accordance with the convection of the water. Then, the generation of natural or artificial ore and ions is activated by irradiating ultrasonic waves. The redox potential ORP (mv) of water obtained by irradiating this ultrasonic wave is preferably 100 mv to -900 mv or less. Incidentally, the oxidation-reduction potential ORP (mv) of normal tap water is generally 500 mV to 600 mv. In the step of irradiating ultrasonic waves, ultrasonic waves of 15 kHz to 35 kHz are irradiated. In addition, one of the effects of irradiating with ultrasonic waves is that oxygen is released at the time of ultrasonic irradiation and the hydrogen content is improved.
In addition, natural ores used for water reforming include those that emit far-infrared rays and waves, so that water subdivision and water resemble a subcritical state in water reforming. An effect is obtained.
In addition, it is desirable that the oxidation-reduction potential (ORP) of water be −000 mV to −900 mv by adding an additive for adding sodium, magnesium chloride, and magnesium as additives to this water.

Water reforming process procedure First, tap water in Japan is introduced into the reforming tank, and water is brought into contact with natural ore. The temperature is changed several times a day, and water is circulated in the tank while maintaining a constant water flow.
The temperature change means that water is repeatedly raised or lowered from the lower limit of 10 ° C. to the upper limit of 100 ° C. or more.
It is desirable to do this several times a day.
Then, the time required for water reforming is set from one day to one month to determine whether the water is changing. Care must also be taken in the indoor environment where water is reformed. The indoor temperature is preferably 20 ° C. and the humidity is preferably around 30%.
In order to judge the change of water reforming, the values of PH (PH) and ORP are measured and judged. It is necessary to confirm that the change of the numerical value is largely changed based on the tap water. If PH, it changes to weak alkali, or it changes to weak acidity depending on the composition of natural ore. Either change is acceptable. ORP is preferably oxidized and reduced from the tap water at the time of input, and the ORP value is preferably lowered.
After the water is reformed, an additive to be added to the water is added.

As an additive, sodium is added to water. Addition of sodium sufficiently exhibits the role as an additive at an addition amount of less than 0.001 wt% to 1 wt% with respect to water. Add magnesium chloride as an additive. Addition of magnesium sufficiently exhibits the role as an additive at an arbitrary addition amount with respect to water. 0.01% by weight to 1% by weight is a standard, but may be more.
Each additive is added by adding the additive to a stirrable container or tank after the water reforming process in which reforming, ionization and water fragmentation are performed as described above, and stirring and mixing the mixture. Run.
In the additive charging step, the enzyme is added in an amount of 0.004 wt% to 2 wt% with respect to the respective volumes of fuel oil and water.
In the additive charging step, the aqueous hydrogen peroxide solution is added to less than 0.001% by weight to 0.1% by weight with respect to water.

After adding the water reforming process additive, the values of PH and ORP change further. PH goes in either direction of both poles.
The numerical value of ORP is lower than before the additive is added.
The water reforming process is carried out for several days even after the additive is added while repeating the water so that the temperature becomes low and high several times a day.
As a measure of completion of the water reforming process, it is necessary to confirm that the pH gradually returns to a neutral value.
In addition, it is necessary to confirm that the ORP is lowered by −500 mv or more.
The above two conditions can be met and the process proceeds to the next step.

Stabilization of water reforming After water reforming up to the previous section, when the unmodified water is added up to 30% by weight of the reformed water, the water acts as a catalyst, The newly introduced water, so-called tap water, causes a reaction that water is instantly reformed.
The modified water causes a radical reaction and the potential becomes unstable. When new water is added thereto, the introduced water immediately merges with the reformed water and shows the same numerical value as the state of both the PH and ORP reformed water.
Ultrasonic waves are irradiated toward the natural ore that has been put into the reformed water.
Natural ore is excited and emits waves, far-infrared rays, and ultra high-quality hertz bands that the stone can carry. The ultra high-quality hertz band refers to a frequency band of several hundred kHz or more, which is a normal ultrasonic band.
For example, irradiation with a terahertz band frequency is also effective.
Ultrasonic waves, far infrared rays, high frequency band sound waves, high frequency band light rays, etc. are emitted to the modified water to generate an atmosphere in which the properties of water simulate a subcritical point state.
The water becomes hydrophilic with oil that satisfies certain conditions, and its interfacial tension is lost.
The temperature condition for making the modified water effective for oil-water fusion is 4 ° C to 70 ° C.
The pressure condition that makes the modified water effective for oil-water fusion is 1 Pa to 5 Pa.

Stirring and mixing step Next, the stirring and mixing step will be described. In this stirring and mixing step, the water modified as described above is mixed with water and oil after adding a special additive. The operation is performed as follows. First, only the oil is put into the stirring and mixing tank, and this oil is circulated through the stirring and mixing tank OHR mixer. The modified water and the water charged with the additive are added and mixed little by little. At that time, the pressure to the OHR mixer needs to be 1 Pa (atmospheric pressure) or more. The temperature of the oil and water, the environment in the tank, and the OHR mixer are set to 15 ° C to 80 ° C.

Fusion Process Next, the fusion process will be described. In this fusion step, the water and oil after stirring and mixing are fused as described above. The operation is performed as follows. That is, the stirring and mixing step is repeatedly performed on the mixed oil and water while heating (40 ° C. to 80 ° C.) and pressurization (1.5 Pa to 20 Pa) are added. The fuel obtained by diluting the obtained oil with water never separates into water and oil, and exhibits a function as a liquid fuel. This takes about 15 to 30 minutes.
Fusion Step Next, after stirring and mixing are performed as described above, the process proceeds to a step of circulating through the fusion tank, which is previously installed adjacent to the tank. The adjacent fusion tank is a cylindrical tube that needs to have a certain length and thickness. Like a filter, natural ore is laid in the tube and water and oil are reformed. It also serves to promote the reaction in the fusion process.
Oil and water are put into a fusion tank and stirred and circulated, and the agitation tank is stirred and circulated, and the piping path is passed through the cylindrical filter on which the natural ore is placed for 10 to 30 minutes, or The process is performed further.
Suitable temperature for the fusion process is 35 ° C-60 ° C.
Suitable for the fusion process, the pressure is 0.5 Pa to 20 Pa.

(Embodiment 2)
As a method different from the reforming step 1 in the first embodiment, condensed mineral extracted from natural ore is added to water as a raw material. By adding ore minerals contained in a plurality of fine components, reforming is promoted and water is refined. Since this ore mineral has the action of promoting the effect of oxygen deficiency for providing water refinement, ionization, and calorific value, it can be selected as one of effective means for ionizing and reforming water. In addition, the water produced | generated as mentioned above and distilled water have electroconductivity by addition of an ore mineral, whereas water does not normally energize.
And, by adding condensed mineral extracted from natural ore to water as raw material, if ionization of water can be sufficiently promoted without irradiating with ultrasonic waves, ionization by ultrasonic irradiation, The reforming process can be omitted.

In the present invention, a fuel obtained by diluting oil obtained by mixing oil and improved water with water does not separate into water and oil once synthesized, and has high transparency, and is a normal oil. It has characteristics that are indistinguishable from those of other fuels, and is useful for effective use of fossil fuels.

1 ionization process 2 additive charging process 3 stirring and mixing process 4 fusion process

Claims (9)

In a method for producing a fuel obtained by diluting an oil that mixes fuel oil and water with water, an ionization step of fragmenting and ionizing a molecular assembly of water alone ;
An agitation and mixing step of adding fuel oil to an agitation and mixing tank and mixing and agitating the ionized water with the additive added while circulating the fuel oil by a mixer;
And a fusion step of repeating the agitation and mixing step for at least 10 to 30 minutes in a state where a temperature of 15 to 80 ° C. and an atmospheric pressure of 1.5 Pa to 20 pa are applied to the fuel oil and water that have been agitated and mixed. A method for producing a fuel obtained by diluting a characteristic oil with water. In a method for producing a fuel obtained by diluting an oil that mixes fuel oil and water with water, an ionization step of fragmenting and ionizing a molecular assembly of water alone ;
An additive charging step of adding an enzyme, sodium hydroxide, potassium hydroxide, magnesium chloride, sodium, magnesium, aqueous hydrogen peroxide as an additive to water;
An agitation and mixing step of adding fuel oil to an agitation and mixing tank and mixing and agitating the ionized water added to the additive while circulating the fuel oil by a mixer; and
An oil characterized by comprising a fusion step of repeating a stirring and mixing step of at least 10 minutes to 30 minutes in a state where a temperature of 40 ° C. to 80 ° C. and an atmospheric pressure of 3 Pa are applied to fuel oil and water that are stirred and mixed A method for producing fuel diluted with water. In the ionization step, the molecular aggregate of water is subdivided by performing two irradiation operations of irradiating raw material water with ultrasonic waves of 10 kHz to 60 kHz and irradiating ultrasonic waves of 200 kHz or higher. A method for producing a fuel obtained by diluting the oil according to claim 1 or 2 with water. 4. The oil according to claim 1, wherein, in the ionization step, the molecular aggregate of water is subdivided by adding an SPG membrane emulsification technique to water as a raw material. Fuel production method. The method for producing a fuel obtained by diluting oil with water according to any one of claims 1 to 4, wherein condensed mineral extracted from natural ore is added to water as a raw material in the ionization step. 6. The ionization process according to claim 1, wherein negative ion water generated by mixing atomic carbon powder and water is used as a raw material or added to water as a raw material. A method for producing a fuel obtained by diluting any of the oils with water. 3. The fuel obtained by diluting oil according to claim 2, wherein the enzyme is added in an amount of 0.004 wt% to 2 wt% with respect to the respective volumes of the fuel oil and water in the additive charging step. Manufacturing method. 3. The production of fuel diluted with water according to claim 2, wherein the sodium hydroxide is added in an amount of less than 0.001 wt% to 0.1 wt% with respect to water in the additive charging step. Method. 3. The fuel according to claim 2, wherein the aqueous hydrogen peroxide solution is added in an amount of less than 0.001% by weight to 0.1% by weight with respect to water in the additive charging step. Production method.

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