JP6415905B2 - Non-aerosol foamer - Google Patents

Description

  The present invention relates to a hair styling agent in a non-aerosol foamer container.

  The hair styling composition has various objectives and performance aspects, such as the hairstyle to be stipulated, improved touch after styling, maintaining the hairstyle, and re-styling properties once the hairstyle has collapsed. Proposals have been made so far. Specific dosage forms of the hair styling agent include a mist-like hair styling agent, a foamy hair styling agent, and a wax-like or gel-like hair styling agent. Among these, the foam-like hair styling agent has a large specific volume and is a dosage form that is easily accepted by users in terms of ease of application to hair.

For example, Patent Document 1 contains polyoxyalkylene alkyl glucoside, a hair fixing polymer compound (film-forming polymer) and polyethylene glycol, and has good hair styling, and can impart smoothness and good touch to hair. A hair styling agent is described, and as an example, an aerosol-type foam hair styling agent is disclosed (Example 2).
On the other hand, from the viewpoint of being environmentally friendly, in recent years, a non-aerosol foam-like hair styling agent has also been developed. For example, Patent Document 2 describes a non-aerosol foam hair styling agent containing a film-forming polymer, a polyethylene glycol having a specific molecular weight and a foaming surfactant.

  In addition, Patent Document 3 describes a state before improving the foam quality such as ease of conforming to dry hair, holding of foam, and the bulkiness of the foam, and disturbing the wave of hair that has been disturbed after wave perm is applied. A non-aerosol foamed container hair styling agent containing polyoxypropylene alkyl glucoside, a film-forming polymer, and a surfactant in a certain ratio is described as a foam hair styling agent that has an excellent effect of recovering the hair.

  Further, Patent Document 4 discloses that hair that is not squeezed into dry hair and is well-familiar with hair and that is disturbed by going to bed after applying wave perm, before the wave curls and bundles are disturbed. As a hair styling agent excellent in the effect of recovering to this state, a hair styling agent in which a specific organopolysiloxane and a specific alkylene oxide addition polymer are blended is described.

JP-A-3-261713 JP 2012-6915 A JP 2013-253046 A JP 2013-253045 gazette

  A non-aerosol foam-like hair styling agent generally forms bubbles by passing it through a bubble homogenizing part such as a net after mixing with gas and liquid. For this reason, adjustment of the foam quality discharged from the container is a big subject, and it is influenced by the compounding quantity of the component in a composition, the net hole size of a discharge mechanism, the environmental conditions at the time of discharge, etc. For example, the hair styling agent in a non-aerosol foamer container described in Patent Document 3 and Patent Document 4 becomes less foamy as the concentration of the film-forming polymer is increased, and the conformity to the hair is reduced. There was a problem that it was easy to attach partly. Further, as the net hole size of the foam discharge mechanism is increased, the foam quality and the foam persistence are deteriorated, and the foam quality particularly when discharged at a high temperature or low temperature is not sufficient.

  Therefore, the present invention can maintain a good foam quality even when the film-forming polymer is at a high concentration, and can be spread evenly over the entire hair, and the size of the net hole size of the non-aerosol foamer container, and the high or low temperature environment. The present invention relates to a hair styling agent that is not affected by the use underneath, has good foam quality and foam, is well-familiar with hair, and has an excellent effect of restoring the bundle of permawave bundles.

  The present inventors employ a specific acrylic polymer as a film-forming polymer, and fill a non-aerosol foamer container with a hairdressing composition containing a specific alkylene oxide addition polymer and a surfactant. It has been found that by adopting a form, all of the above requirements are satisfied.

That is, the present invention provides a hair styling agent in a non-aerosol foamer container containing the following components (A) to (C).
(A) Polymer obtained by copolymerizing monomer components containing monomer (a) and monomer (b)
(a) (meth) acrylate monomer represented by the general formula (1); 35 to 50% by mass

[Wherein, R ¹ represents a hydrogen atom or a methyl group, and R ² represents an alkyl group having 1 to 8 carbon atoms. ]
(b) an ethylene oxide group-containing (meth) acrylate monomer represented by the general formula (2); 50 to 65% by mass

[Wherein R ³ represents a hydrogen atom or a methyl group, R ⁴ represents an alkyl group having 1 to ⁴ carbon atoms, and p represents an integer of 20 to 90. ]
(B) an alkylene oxide addition polymer represented by the general formula (3)

[Wherein, R ⁵ and R ⁶ each represent a hydrogen atom or a linear or branched alkyl or alkenyl group having 1 to 24 carbon atoms, m represents an integer of 1 or more, and n represents an integer of 0 or more. . However, R ⁵ and R ⁶ are not simultaneously hydrogen atoms. ]
(C): Surfactant other than component (B)

  The hair styling agent with a non-aerosol foamer container of the present invention is easy to spread evenly over the entire hair while maintaining a good foam quality in a wide concentration range of the film-forming polymer. It is not affected by the use of large or small, high temperature or low temperature environment, has good foam quality and foaminess, is well-familiar with hair, and has an excellent effect of restoring the bundle of perm waves It is.

[Component (A): Polymer obtained by copolymerizing monomer (a) and monomer (b)]
Component (A) is a film-forming polymer, and is a component that contributes to hair styling performance.
The monomer (a) used in the present invention is a (meth) acrylate monomer represented by the general formula (1).

In the general formula (1), R ¹ represents a hydrogen atom or a methyl group, and R ² represents an alkyl group having 1 to 8 carbon atoms. The alkyl group may be either a straight chain or branched chain, and specifically includes a straight chain such as a methyl group, an ethyl group, an n-propyl group, an n-butyl group, an n-hexyl group, and an n-octyl group. Examples include a branched alkyl group such as a chain alkyl group, isopropyl group, isobutyl group, tert-butyl group, and isohexyl group. R ² is more preferably a linear or branched alkyl group having 1 to 6 carbon atoms from the viewpoint of hair elasticity, keeping power, and re-styling, and linear or branched alkyl groups having 1 to 4 carbon atoms. More preferred is an alkyl group. Specific examples of the monomer (a) include methyl methacrylate, butyl methacrylate, isobutyl methacrylate, tert-butyl methacrylate, methyl acrylate, and isobutyl acrylate. The monomer (a) can be used alone or in combination of two or more.

  The monomer (b) used in the present invention is an ethylene oxide group-containing (meth) acrylate monomer represented by the general formula (2).

In general formula (2), R ³ represents a hydrogen atom or a methyl group, and R ⁴ represents an alkyl group having 1 to ⁴ carbon atoms. Specific examples of the alkyl group include linear alkyl groups such as a methyl group, an ethyl group, and an n-propyl group, and a methyl group is particularly preferable. p represents the number of added moles of ethylene oxide groups, and is an integer of 20 to 90, preferably an integer of 23 to 90, from the viewpoint of obtaining good hair setting, keeping power and re-styling. Specific examples of the monomer (b) include methoxy PEG acrylate (23), methoxy PEG PEG (23), methoxy methacrylic PEG (45), and methoxy methacrylic PEG (90). A monomer (b) can be used individually or in combination of 2 or more types. The monomer (b) can be obtained, for example, by reacting acrylic acid chloride or methacrylic acid chloride with polyethylene glycol methyl ether.

  The polymer of component (A) used in the present invention is a nonionic polymer obtained by copolymerizing a monomer component containing monomer (a) and monomer (b). The content of the monomer (a) in the monomer component is 35% by mass or more, preferably 38% by mass, based on the total amount of monomers, from the viewpoint of obtaining excellent hair conditioning properties, setability, keeping power and re-styling properties. % Or more, and 50% by mass or less, preferably 47% by mass or less. Similarly, the content of the monomer (b) in the monomer component is 50% by mass or more based on the total amount of monomers, preferably from the viewpoint of obtaining excellent hair conditioning properties, setting properties, keeping power and re-styling properties, It is 53% by mass or more, and 65% by mass or less, preferably 62% by mass or less. By setting the contents of the monomer (a) and the monomer (b) within these ranges, the hairdressing agent of the present invention that blends the obtained polymer can exhibit excellent effects. Even if it is a monomer other than the monomer (a) and the monomer (b), it may be copolymerized and may be appropriately contained in the monomer component as long as it does not impair the effects of the present invention. Then, the total amount of the monomer (a) and the monomer (b) is preferably 85% by mass or more, more preferably 90% by mass or more, and still more preferably 95% by mass or more of the total amount of monomers. The polymer of component (A) is a nonionic polymer, and it is preferable that the monomer component other than monomer (a) and monomer (b) does not contain an ionic monomer.

  The copolymerization of the monomer (a) and the monomer (b) may be performed according to a conventional method.For example, a monomer solution in which the monomer (a) and the monomer (b) are dissolved in an appropriate solvent is used as an appropriate polymerization initiator. It can be carried out by heating in the presence and causing a polymerization reaction. Examples of the polymerization initiator include 2,2′-azobisisobutyronitrile. Moreover, it is also possible to use a commercially available raw material as the component (A), for example, plus size L-188K (manufactured by Kyogo Chemical Industry Co., Ltd.).

  The content of the component (A) in the hair styling agent of the present invention is the effect of aligning the phase of the wave for each small hair bundle, and restoring the alignment of the bundle of perma waves, the point of adaptability to dry hair From the viewpoint of obtaining a more excellent effect, it is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, further preferably 0.2% by mass or more, further preferably 0.5% by mass or more, and further preferably 1% by mass or more. In addition, it is preferably 6% by mass or less, more preferably 5% by mass or less, further preferably 4% by mass or less, and further preferably 3% by mass or less. The specific range is preferably 0.01 to 5% by mass, more preferably 0.1 to 5% by mass, and still more preferably 0.2 to 3% by mass.

[Component (B): alkylene oxide addition polymer]
The hair styling agent of the present invention contains an alkylene oxide addition polymer represented by the following general formula (3) as the component (B). Ingredient (B) contributes to the improvement of the foam quality such as the holding of the foam discharged from the non-aerosol foamer container and the bulkiness.

In general formula (3), R ⁵ and R ⁶ each represent a hydrogen atom, or a linear or branched alkyl or alkenyl group having 1 to 24 carbon atoms, and R ⁵ and R ⁶ are simultaneously a hydrogen atom and Never become. m is an integer of 1 or more, and n is an integer of 0 or more, but m ≧ n is preferable in terms of a set shape and a feeling of unity. N is preferably 1 or more. m + n is preferably 3 or more, preferably 20 to 200, more preferably 30 to 200, further preferably 30 to 150, and further preferably 30 to 60 in terms of setability and unity. Furthermore, from the viewpoint of foaminess, the alkyl group or alkenyl group of R ⁵ and R ⁶ preferably has 1 to 16, more preferably 1 to 14, and more preferably 1 to 12 carbon atoms.

  Specific examples of component (B) include, for example, polyoxypropylene (30) butyl ether, polyoxypropylene (33) butyl ether, polyoxypropylene (40) butyl ether, polyoxypropylene (52) butyl ether, polyoxypropylene (30) oleyl Polyoxypropylene alkyl ethers such as ether, polyoxypropylene (40) ricinoyl ether, polyoxypropylene (30) isocetyl ether; polyoxyethylene (17) polyoxypropylene (17) butyl ether, polyoxyethylene (30) poly Oxypropylene (30) butyl ether, polyoxyethylene (38) polyoxypropylene (37) butyl ether, polyoxyethylene (3) polyoxypropylene (35) stearyl ether, polyoxyethylene (3) polyoxypropylene (20) cetyl ether , Polyoxyethylene (5) polyoxypropylene (40) polyoxyethylene polyoxypropylene alkyl ethers such as behenyl ether; polyoxyethylene (14) polyoxypropylene (7) Polyoxyethylene polyoxypropylene dialkyl ethers such as dimethyl ether.

  The above alkylene oxide addition polymers are commercially available, for example, Adeka Pluronic L series sold by ADEKA Co., Ltd., New Pole PE series sold by Sanyo Chemical Industries, Ltd., and Nippon Oil & Fats Co., Ltd. Use commercially available products such as the UNILOVE 10MS series, UNISafe series, UNILOVE 50MB series, Bepol series sold by Toho Chemical Co., Ltd., and Macbio Obride E series sold by NOF America. be able to

  The alkylene oxide addition polymer of component (B) can be used alone or in combination of two or more. The content of the component (B) in the hair styling agent of the present invention is preferably 0.1% by mass or more, more preferably 0.2% by mass or more, and further preferably 0.5% by mass from the viewpoint of making the foam more compatible with hair. Further, it is preferably 10% by mass or less, more preferably 8% by mass or less, further preferably 5% by mass or less, and further 2.5% by mass or less.

  The mass ratio (B) / (A) of the component (B) to the component (A) in the hair styling agent of the present invention is from the viewpoint of foam retention, foam quality such as bulkiness, and familiarity with dry hair. , Preferably 0.05 or more, more preferably 0.1 or more, still more preferably 0.2 or more, still more preferably 0.5 or more, and preferably 25 or less, more preferably 15 or less, still more preferably 10 or less, still more preferably 5 It is as follows.

[(C): surfactant other than component (B)]
Component (C) surfactants include any of cationic surfactants, nonionic surfactants (except those corresponding to component (B)), amphoteric surfactants, and anionic surfactants. Can be used.

  Examples of the cationic surfactant include quaternary ammonium salts, and mono long chain alkyl quaternary ammonium salts are particularly preferable. Specific examples include cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, aralkyltrimethylammonium chloride, and behenyltrimethylammonium chloride. Stearyltrimethylammonium chloride and cetyltrimethylammonium chloride are particularly preferable.

  Nonionic surfactants other than component (B) include polyoxyalkylene alkyl ethers, polyoxyalkylene alkenyl ethers, higher fatty acid sucrose esters, polyglycerin fatty acid esters, higher fatty acid mono- or diethanolamides, polyoxyethylene hardened castor Examples thereof include oils, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene sorbite fatty acid esters, alkyl saccharide surfactants, alkyl amine oxides, and alkyl amide amine oxides. Of these, polyoxyalkylene alkyl ether and polyoxyethylene hydrogenated castor oil are preferable, and polyoxyethylene alkyl ether is particularly preferable.

  Examples of amphoteric surfactants include imidazoline series, carbobetaine series, amide betaine series, sulfobetaine series, hydroxysulfobetaine series, and amide sulfobetaine series.

  Anionic surfactants include alkylbenzene sulfonates, alkyl or alkenyl ether sulfates, alkyl or alkenyl sulfates, olefin sulfonates, alkane sulfonates, saturated or unsaturated fatty acid salts, alkyl or alkenyl ether carboxylates , Α-sulfo fatty acid salts, N-acyl amino acid type surfactants, phosphoric acid mono- or diester type surfactants, sulfosuccinic acid ester salts, and the like.

  Counter ions of the anionic residue of the anionic surfactant include alkali metal ions such as sodium ion and potassium ion; alkaline earth metal ions such as calcium ion and magnesium ion; ammonium ion; Examples include protonated products of alkanolamines having 1 to 3 alkanol groups (for example, monoethanolamine, diethanolamine, triethanolamine, triisopropanolamine, etc.). Examples of the counter ion of the cationic residue include halide ions such as chloride ion, bromide ion and iodide ion, methosulphate ion, ethosulphate ion and saccharinate ion.

  The component (C) surfactant can be used alone or in combination of two or more thereof, and one or two selected from the group consisting of nonionic surfactants and cationic surfactants other than component (B) It is preferable to contain two or more kinds of surfactants, more preferably two or more kinds of surfactants selected from the group, and further, at least a nonionic surfactant other than the component (B). It is preferable to contain at least one kind and one cationic surfactant.

  The content of the component (C) in the hairdressing agent of the present invention is capable of forming good foam while maintaining high wave reproducibility by the component (A) and other film-forming polymers, and the hairdressing agent. From the viewpoint of making the viscosity of the range that can be discharged from the non-aerosol container, preferably 0.1% by mass or more, more preferably 0.2% by mass or more, still more preferably 0.5% by mass or more, and preferably 10% by mass or less. More preferably, it is 8 mass% or less, More preferably, it is 5 mass% or less.

  The mass ratio (B) / (C) of the component (B) to the component (C) in the hair styling agent of the present invention is preferably from the viewpoint of reducing the squeakiness and stickiness and improving the familiarity with dry hair. Is 4.0 or less, more preferably 3.0 or less, still more preferably 2.0 or less, preferably 0.01 or more, more preferably 0.05 or more, still more preferably 0.1 or more.

[Film-forming polymer other than component (A)]
In the present invention, in addition to the component (A), a film-forming polymer other than the component (A) generally used for aerosol hairdressing agents can be used. Specific examples of the film-forming polymer include poly (N-formylethyleneimine) organopolysiloxane, poly (N-acetylethyleneimine) organopolysiloxane, and poly (N-propionylethyleneimine) organopolysiloxane-9 An alkylacrylamide / acrylate / alkylaminoalkylacrylamide / polyethylene glycol methacrylate copolymer described in JP-A-2-809911; an alkylacrylamide / alkylaminoalkylacrylamide / polyethylene glycol methacrylate copolymer described in JP-A-8-291206; Polymer: (Methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer such as Yuka Former R205, M-75 (Mitsubishi Chemical Corporation), RAM Resin (Osaka Organic Chemical Co., Ltd.); Diaphor (Acrylates / lauryl acrylate / stearyl acrylate / ethylamine oxide oxide) copolymers such as Mer Z-712 (Mitsubishi Chemical); (Acrylates / stearyl acrylate / methacrylic) such as Diaformer Z-632 (Mitsubishi Chemical) Acid vinylamine oxide) copolymer; (vinylamine / vinyl alcohol) copolymer such as Diafix C-601 (Mitsubishi Chemical Corporation); acrylic resin alkanolamine liquid such as plus size L-9540B (Kohyo Chemical Industry Co., Ltd.); Ultrahold 8, etc. Acrylic acid / acrylic acid amide / ethyl alkylate copolymers such as Strong (above BASF); PEG / PPG-25 / 25 dimethicone / acrylates) copolymers such as Rubyflex Silk (BASF); Ruby Set Shape (BASF) Polyacrylate-22 such as Rubiset PUR (BASF) Tan-1; Polyurethanes such as Baicusan C1000 and C1001 (Bayer MaterialScience) -34; Polyurethanes such as Baicusan 1003 (Bayer MaterialScience) -32; Polyurethanes such as Baicusan 1004 (Bayer MaterialScience); 35; Lubiscor Polyvinylcaprolactam such as Plus (BASF); Alkyl acrylate copolymers such as Rubimer 100P and 30E (above, BASF); Amformer SH-701, 28-4910, LV-71, LV- (Octylacrylamide / hydroxypropyl acrylate / butylaminoethyl methacrylate) copolymers such as 47 (above Akzo Nobel); (alkyl acrylate / octyl acrylamide) copolymers such as Anformer V-42 (Akzo Nobel); Resin 28-2930 (Akzo Nobel), etc. (VA / crotonic acid / neo Vinyl acrylate) copolymer; Polyurethane-14 / AMP-acrylate copolymer such as Dynam X (Akzo Nobel); Polyquaternium-11 such as Guffcut 440 and 734 (Ashland); Guffcut HS-100 (Ashland) Polyquaternium-28 such as; Gantrez ES-225 (Ashland) and other (vinyl methyl ether / ethyl maleate) copolymers; Aquaflex SF-40 (Ashland) and the like (PVP / Vinyl caprolactam / Acrylic acid DMAPA) Copolymer; (Isobutylene / ethylmaleimide / hydroxyethylmaleimide) copolymer such as Aquaflex FX-64 (Ashland); Polyquaternium-55 such as Stylize W-20 (Ashland); Stylee CC-10 (Ashland) (Vinylpyrrolidone / DMAPA acrylic acid copolymer) such as P (Vinylpyrrolidone / VA) copolymers such as VP / VA735 (Ashland); Lubiscol K-12, 17, 30, 60, 80, 90 (above, BASF), PVP K-15, 30, 60, 90 Polyvinyl pyrrolidone such as (Ashland).

  Among the film-forming polymers other than the above component (A), from the viewpoint of obtaining a particularly good wave reproduction effect, Polysilicone-9; alkyl acrylamide / acrylate / alkyl aminoalkyl acrylamide / polyethylene glycol methacrylate copolymer; alkyl acrylamide / Alkylaminoalkylacrylamide / polyethylene glycol methacrylate copolymer; (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer; (acrylates / lauryl acrylate / stearyl acrylate / ethylamine oxide oxide) copolymers; (acrylates / stearyl acrylate / (Ethylamine oxide methacrylate) copolymer; (vinylamine / vinyl alcohol) copolymer; acrylic resin Acrylic acid / acrylic acid amide / ethyl alkylate copolymer; (PEG / PPG-25 / 25 dimethicone / acrylates) copolymer; Polyacrylate-22; Polyurethane-1; Polyurethane-34; Bicusan 1003 (Bayer Material Science) Polyurethane-32; polyurethane-35; polyvinyl caprolactam; alkyl acrylate copolymer; (octylacrylamide / hydroxypropyl acrylate / butylaminoethyl methacrylate) copolymer; (alkyl acrylate / octylacrylamide) copolymer; VA / crotonic acid / vinyl neodecanoate) copolymer; polyurethane-14 AMP-acrylate copolymer; polyquaternium-11; polyquaternium-28; (vinyl methyl ether / ethyl maleate) copolymer; Le caprolactam / DMAPA acrylate) copolymers; (isobutylene / ethylmaleimide / hydroxyethyl maleimide) copolymer; polyquaternium -55; (vinylpyrrolidone / DMAPA acrylate) copolymers; polyvinyl pyrrolidone are preferred.

  Further, polysilicone-9; alkyl acrylamide / acrylate / alkyl aminoalkyl acrylamide / polyethylene glycol methacrylate copolymer; alkyl acrylamide / alkyl aminoalkyl acrylamide / polyethylene glycol methacrylate copolymer; (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) (Acrylates / Lauryl Acrylate / Stearyl Acrylate / Ethylamine Oxide Ethoxide) Copolymer; (Acrylates / Stearyl Acrylate / Ethylamine Oxide Methyl Oxide) Copolymer; Acrylic Resin Alkanolamine Liquid; (PEG / PPG-25 / 25 Dimethicone) / Acrylates) copolymer; polyacrylate-22; polyurethane-1; polyurethane-34; Polyurethane-32; Polyurethane-35; (VA / crotonic acid / vinyl neodecanoate) copolymer; Polyurethane-14 AMP-acrylate copolymer; Polyquaternium-11; Polyquaternium-55; (Vinyl) Pyrrolidone / DMAPA acrylic acid copolymer); polyvinylpyrrolidone is preferred.

  Furthermore, Polysilicone-9, alkylacrylamide / alkylaminoalkylacrylamide / polyethylene glycol methacrylate copolymer, (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer, (acrylates / stearyl acrylate / ethylamine methacrylate oxide) copolymer, Acrylic resin alkanolamine solution, polyacrylate-22, polyquaternium-11; polyvinylpyrrolidone is preferred.

  Two or more types of film-forming polymers other than these components (A) can be used in combination. The content of the comparatively formed polymer other than the component (A) in the hairdressing agent of the present invention ensures the effect of reproducing the wave, while keeping the viscosity of the hairdressing agent low to enable foam formation, From the viewpoint that the aerosol foamer container is not clogged and has good storage stability, it is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, further preferably 0.1% by mass or more, and preferably It is 5 mass% or less, More preferably, it is 3 mass% or less, More preferably, it is 2 mass% or less.

[Medium]
In the hairdressing agent of the present invention, water and, if necessary, an organic solvent other than the specific organic solvent are used as a medium. Examples of such organic solvents include lower alkanols such as ethanol and 2-propanol, polyols such as propylene glycol, 1,3-butanediol, diethylene glycol, dipropylene glycol, and glycerin, ethyl cellosolve, butyl cellosolve, and benzyl cellosolve. Examples include cellosolves, carbitols such as ethyl carbitol and butyl carbitol.

[Other ingredients]
The hairdressing agent of the present invention includes various components usually used in hairdressing agents, such as chelating agents, vitamins, proteins, amino acids, herbal medicines, coolness-imparting agents (such as menthol), antiseptics, ultraviolet absorbers, Antioxidants, colorants, fragrances and the like can be blended depending on the purpose.

〔viscosity〕
The viscosity of the hairdressing agent of the present invention is such that it is present in the non-aerosol container (in a liquid state before being discharged as foam) from the viewpoint that it can be suitably discharged as foam from the non-aerosol foamer container. ˜100 mPa · s, more preferably 2 to 30 mPa · s, and particularly preferably 3 to 20 mPa · s. The viscosity here is a B-type viscometer TVB-10M (Toki Sangyo Co., Ltd.), which is measured at 30 ° C. for 60 seconds using the following rotor and rotational speed.
Rotational speed is 30 rpm for viscosity up to 10 mPa · s, 60 rpm for 10-20 mPa · s, 30 rpm for 20 mPa · s or more, and the rotor is L / Adp, 10-100 mPa for viscosity up to 10 mPa · s.・ Use M1 rotors up to s, and M2 rotors from 200mPa · s to 1,000mPa · s.

[Non-Aerosol Foamer Container]
In the present invention, the non-aerosol foamer container is used for mixing the hairdressing agent filled in the container with air without using a propellant and discharging the foamed foam. By using the former container, an effect of preventing scattering of the discharged agent can be obtained. In particular, a non-aerosol type container can manufacture a product at a lower cost than an aerosol type container and does not require a high-pressure gas propellant. Therefore, the product can be handled more safely in distribution.

  As the former container, a known pump former container having a foam discharge means, a squeeze foamer container, an electric frother, a pressure accumulating pump former container or the like can be used. More specifically, for example, food and containers (vol. 35, No. 10, p588 to 593 (1994); vol. 35, No. 11, p624 to 627 (1994); vol. 36, No. 3, p154 ~ 158 (1995)) Pump former E3 type, F2 type (above, Daiwa Steel Co., Ltd.), squeeze foamer (Daiwa Steel Co., Ltd.), electric whisk (Matsushita Electric Works), air spray for Mar (Air Spray International). As the former container used in the hair styling agent of the present invention, a pump former container and a squeeze foamer container are preferable because they are inexpensive and easy to use.

  The pump former container or the squeeze foamer container has a foam homogenizing portion such as a net, and preferably has a thin net from the viewpoint of preventing clogging. The hair styling composition of the present invention has a strong tendency to become poor quality bubbles such as coarse texture, low bulk, low shape retention, etc., even when using a net with a net hole size of 50 mesh to 120 mesh This is advantageous in that good foam quality can be obtained. Further, from the viewpoint of generating creamy foam, the net hole size of the net is preferably 50 to 400 mesh, more preferably 70 to 350 mesh, and even more preferably 80 to 320 mesh. Here, the unit of mesh is expressed by the number of eyes per inch. Moreover, as a material of such a net, nylon (registered trademark), polyester and the like can be preferably exemplified.

  In the non-aerosol foamer container used in the hair styling agent of the present invention, at least one, preferably a plurality of such nets are provided, particularly from the viewpoints of economy, fineness of foam, difficulty in clogging, and the like. Two are preferably provided.

Examples 1 to 7 and Comparative Examples 1 to 7
A hair styling composition shown in Table 1 was prepared, and a pump former container (manufactured by Yoshino Seisakusho Co., Ltd.) (the net part has two nets whose eye sizes are as shown in the table. The discharge amount of the agent was filled in 1.0 g), and performance evaluation was performed according to the following method and standard. The prepared composition had a viscosity of 20 mPa · s or less.
In the notation of mesh size in the following examples, “200/200” means that the composition is passed through a net having a net hole size of 200 mesh and then passed through a net having a net hole size of 200 mesh. “90/200” means that the composition is passed through a net having a net hole size of 90 mesh and then passed through a net having a net hole size of 200 mesh.

<Bubble height>
Seven panelists pressed the pump twice, and then the third bubble was discharged onto the palm and the appearance was visually observed. At that time, each panel was made to select one of “bulky” / “cannot say” / “not bulky” as compared with Comparative Example 1. Table 1 shows the number of people selected for each option. The evaluation was carried out for 1 day in each environment of normal temperature, 40 ° C., and 5 ° C., and then bubbles were discharged in that environment. There are two types of pump former containers: one that passes two nets with a 200 mesh net hole size, and one that pumps a 90 mesh net and a 200 mesh net hole size. Evaluation was performed using a pump former container.

<Fine fineness>
Seven panelists pressed the pump twice in a 40 ° C. environment, and then the third bubble was discharged onto the palm of the hand and the appearance was visually observed. At that time, each panelist was made to select one of “fine texture” / “neither” or “coarse” as compared with Comparative Example 1. Table 1 shows the number of people selected for each option.

<Goodness of foam>
Seven panelists pressed the pump twice in a 40 ° C. environment, and then discharged the third bubble onto the palm of the hand and visually observed the appearance after standing for 30 seconds. At that time, each panelist was made to select one of “a foam is good” / “it cannot be said” / “a foam is bad” as compared with Comparative Example 1. Table 1 shows the number of people selected for each option.

The following evaluation was performed using the following evaluation hair bundle.
Japanese hair perm hair with a weight of 15g, width of 5cm, and length of 25cm is washed with a model shampoo, dried with a towel, blown straight with a dryer and brush, and dried completely. This was used as an evaluation hair bundle.

・ Model shampoo prescription (mass%)
Polyoxyethylene (2.5) sodium lauryl ether sulfate 25% by weight aqueous solution 62.00
Lauric acid diethanolamide 2.28
Edetate disodium 0.10
Sodium benzoate 0.50
Oxybenzone 0.03
Phosphoric acid (75 mass% aqueous solution) 0.10
Dibutylhydroxytoluene 0.01
Sodium chloride 0.80
Red No. 106 0.00012
Fragrance 0.26
Purified water balance

<Familiarity with hair>
Seven panelists pushed the pump twice, and then the third foam was discharged onto the palm, and 1.0 g of foam was spread on the evaluation hair bundle. At this time, the effect of foam on hair is uniformly applied to each panel, “whether the foam quickly and evenly fits” / “can't say either” / “foam is hard to adapt and cannot be applied evenly” Was selected alternatively. Table 1 shows the number of people selected for each option.

<Wave reproducibility>
Seven panelists pushed the pump twice, and then the third foam was discharged onto the palm, and 1.0 g of foam was spread on the evaluation hair bundle. At this time, each panel was told about the good reproducibility of the wave after finishing (the effect of reducing the wave diameter from the state where the wave diameter increased during the drying process). It was alternatively selected whether it corresponds to “Yes” / “Slightly larger than the wave diameter during natural drying” / “Significantly larger than the wave diameter during natural drying”. Table 1 shows the number of people selected for each option. The evaluation was made by comparing with a hair bundle after 6 hours of natural drying after shampoo / towel drying.

* 1: Plus size L-188K (manufactured by Reciprocal Chemical Industries)
* 2: PVP-K30 (Ashland)
* 3: Organopolysiloxane obtained in Synthesis Example 1 of JP 2013-253045 A
* 4: Unilube 50MB-26 (manufactured by NOF Corporation)
* 5: Unilube 50MB-72 (manufactured by NOF Corporation)
* 6: Unilube 50MB-168 (manufactured by NOF Corporation)
* 7: Macbiobride MG-10P (manufactured by NOF Corporation)
* 8: Softanol 90 (made by Nippon Shokubai Co., Ltd.)
* 9: Cotamin 86W (Kao Corporation)

Formulation example
(mass%)
Polysilicone-9 0.65
(Acrylates / Methoxymethacrylate PEG-23) Copolymer (* 1) 0.12
PPG-10 methyl glucose (* 7) 2.0
PPG-17 Butes-17 (* 4) 1.0
Glycerin 1.2
Polyethylene glycol 600 1.5
Lanolin fatty acid 0.01
(C12-14) -s-Palace-9 (* 8) 2.0
Steartrimonium chloride 0.24
Perfume 0.09
Ethanol 11.0
Water (balance)

Claims (4)

A hair styling agent in a non-aerosol foamer container containing the following components (A) to (C).
(A) Polymer obtained by copolymerizing monomer components comprising monomer (a) and monomer (b)
(a) (meth) acrylate monomer represented by the general formula (1); 38 to 47 % by mass

[Wherein, R ¹ represents a hydrogen atom or a methyl group, and R ² represents an alkyl group having 1 to 4 carbon atoms. ]
(b) an ethylene oxide group-containing (meth) acrylate monomer represented by the general formula (2); 53 to 62 % by mass

[Wherein, R ³ represents a hydrogen atom or a methyl group, R ⁴ represents an alkyl group having 1 to ⁴ carbon atoms, and p represents an integer of 23 to 90. ]
(B) an alkylene oxide addition polymer represented by the general formula (3)

[Wherein, R ⁵ and R ⁶ each represent a hydrogen atom or a linear or branched alkyl or alkenyl group having 1 to 24 carbon atoms, m represents an integer of 1 or more, and n represents an integer of 0 or more. . However, R ⁵ and R ⁶ are not simultaneously hydrogen atoms. ]
(C) Surfactant other than component (B)   The hair styling agent in a non-aerosol foamer container according to claim 1, wherein the mass ratio (B) / (A) of the component (B) to the component (A) is from 0.05 to 25.   The non-aerosol foam according to claim 1 or 2, wherein the component (C) contains one or more surfactants selected from the group consisting of a nonionic surfactant and a cationic surfactant. Hair conditioner in a mer container.   The non-aerosol foamer-containing hair styling agent according to any one of claims 1 to 3, wherein the content of the component (A) is 0.01 mass% or more and 6 mass% or less.