JP6401912B2 - Solder composition and method for producing printed wiring board using the same - Google Patents

Description

The present invention relates to a solder composition (so-called solder paste) for mounting a component on a printed wiring board of an electronic device, and a method for manufacturing a printed wiring board for mounting an electronic component using this solder composition.

Generally, electronic components are mounted by thread solder using a soldering iron. However, in recent years, with the miniaturization of electronic products, the miniaturization of printed wiring boards has progressed, and there has been a problem that it is difficult to cope with soldering by a contact method such as a soldering iron.
In soldering to such a fine part that is difficult to solder with a soldering iron, a non-contact soldering method using laser light is used.
This technology irradiates the printed circuit board with laser light from the soldering head of the soldering device, absorbs the light energy of the irradiated laser light, causes heat generation, melts the solder, and solders This method is advantageous in that an electronic component can be mounted in a short portion of a printed wiring board in a short time (see Patent Documents 1 to 3).
In addition, since the laser light can be selectively irradiated to the part where solder connection is desired, when mounting electronic components, the entire component must be mounted without applying heat compared to the flow type or reflow type. Therefore, it is suitable for soldering to parts with high heat dissipation.

JP 60-182191 A JP-A-63-123593 Japanese Patent Laid-Open No. 4-137775

The method using laser light as a heat source has enabled non-contact soldering to fine parts. However, since rapid heating is performed, the generation of solder balls, scattering of flux, spreading of the flux residue, and the like has occurred remarkably. Therefore, when soldering with rapid heating, such as laser soldering, while maintaining the spread of solder during soldering, suppress the generation of solder balls, scattering of flux, spreading of flux residue, etc. Is required.
The generation of solder balls and the occurrence of flux scattering can be suppressed by preheating, but the effect is not sufficient.

Accordingly, the present invention provides a solder composition capable of suppressing the generation of solder balls, the scattering of flux and the spread of flux residue when soldering with rapid heating, and a method for producing a printed wiring board using the same. The purpose is to provide.
Here, the soldering with rapid heating means soldering such that the time required for heating from room temperature to the solder melting point is 3 seconds or less (preferably 1 second or less).

In order to solve the above problems, the present invention provides the following solder composition and a method for producing a printed wiring board using the same solder composition.
The solder composition of the present invention is a solder composition used for laser soldering, and the solder composition includes (A) a rosin resin, (B) an organic acid, (C) a solvent, and (D1) 25. A flux containing a solid iodine-based organic halogen compound at (° C. ) and (E) a solder powder, and the component (A) includes (A1) a high softening point rosin resin having a softening point of 130 ° C. or higher. and, wherein (A1) amount of component, wherein the total amount of 100 mass% of the component (a) state, and are more than 70 wt%, the component (D1) is 2-iodo benzoic acid, 3- It is at least one selected from the group consisting of iodobenzoic acid, 5-iodosalicylic acid, and 5-iodoanthranilic acid .

In the solder composition of the present invention, the flux further contains (D2) a bromine-based organic halogen compound that is solid at 25 ° C., and the component (D2) is 2,3-dibromobutanediol, tribromoneopentyl. It is preferably at least one selected from the group consisting of alcohol, 2,3-dibromopropionic acid, 2,3-dibromosuccinic acid, and 2-bromobenzoic acid .
In the solder composition of the present invention, the component (C) preferably contains (C1) isobornylcyclohexanol.
In the solder composition of the present invention, the blending amount of the component (D1) or the total blending amount of the component (D1) and the component (D2) is 1% by mass or more with respect to 100% by mass of the flux. It is preferable that it is 3 mass% or less .

The printed wiring board manufacturing method of the present invention is a method characterized in that an electronic component is mounted on a printed wiring board using the solder composition.

The reason why the solder composition of the present invention can suppress the generation of solder balls, the scattering of flux and the spread of flux residue when soldering with rapid heating is not necessarily clear, but the present inventors We infer as follows.
That is, the present inventors speculate that the reason for the generation of solder balls and the scattering of flux in laser soldering where rapid heating is performed is as follows. In other words, due to rapid heating such as by laser irradiation, the flux whose fluidity has increased rapidly flows out of the pad prior to melting of the solder powder, and at that time, unmelted solder powder flows out of the pad at the same time. The present inventors speculate that this is the case. On the other hand, the solder composition of the present invention contains a predetermined amount or more of (A1) a high softening point rosin resin and (D) an organic halogen compound that is solid at 25 ° C. In the present invention, during soldering with rapid heating, the components (A1) and (D) tend to be distributed so as to cover the surface of the solder composition, and temporarily become a film. . Such a film has a relatively low fluidity because the (D) component that is solid at room temperature is dissolved or dispersed in the (A1) component having a high melting point. Therefore, it can suppress that (B) organic acid and (C) solvent scatter and flow out of a pad by this membrane | film | coat. The present inventors speculate that the effects of the present invention are achieved by the action of the components (A1) and (D).

According to the present invention, when soldering with rapid heating, a solder composition capable of suppressing the generation of solder balls, the scattering of flux and the spread of flux residue, and a method of manufacturing a printed wiring board using the same Can be provided.

  The solder composition of the present invention contains a flux described below and (E) a solder powder described below.

[flux]
The flux used in the solder composition of the present invention is a component other than the component (E) in the solder composition, (A) a rosin resin, (B) an organic acid, (C) a solvent, and (D) 25 ° C. And containing a solid organic halogen compound.

  The blending amount of the flux is preferably 5% by mass or more and 35% by mass or less, more preferably 7% by mass or more and 15% by mass or less, and more preferably 8% by mass or more with respect to 100% by mass of the solder composition. It is particularly preferably 12% by mass or less. When the amount of the flux is less than 5% by mass (when the content of the solder powder exceeds 95% by mass), the flux as the binder is insufficient, and it tends to be difficult to mix the flux and the solder powder. On the other hand, when the flux content exceeds 35% by mass (when the solder powder content is less than 65% by mass), it is difficult to form a sufficient solder joint when the obtained solder composition is used. Tend to be.

[(A) component]
Examples of the (A) rosin resin used in the present invention include rosins and rosin modified resins. Examples of rosins include gum rosin, wood rosin, tall oil rosin, disproportionated rosin, polymerized rosin, hydrogenated rosin, and derivatives thereof. As rosin-based modified resins, unsaturated organic acid-modified resins of the above rosins that can be reactive components of Diels-Alder reactions (aliphatic unsaturated monobasic acids such as (meth) acrylic acid, fumaric acid, maleic acid, etc.) adietic acids such as aliphatic unsaturated dibasic acids such as α, β-unsaturated carboxylic acids, and unsaturated carboxylic acids having an aromatic ring such as cinnamic acid) and abietic acids such as modified products thereof, and these The thing which has a modified substance as a main component is mentioned. These rosin resins may be used alone or in combination of two or more.

In the present invention, the component (A) needs to contain (A1) a high softening point rosin resin having a softening point of 130 ° C. or higher. Examples of the component (A1) include a high softening point rosin resin having a softening point of 130 ° C. or higher among the components (A). Further, from the viewpoint of suppressing the scattering of the flux and the spread of the flux residue, the softening point of the high softening point rosin resin is preferably 140 ° C. or higher, and more preferably 145 ° C. or higher. The softening point can be measured by the ring and ball method.
In the present invention, the component (A) may contain (A2) a rosin resin having a softening point of less than 130 ° C. Examples of the component (A2) include rosin resins having a softening point of less than 130 ° C. among the components (A).
As means for adjusting the softening point of the component (A), the polymerization degree of rosin is adjusted (the higher the polymerization degree, the higher the softening point tends to be), and the modification method of rosin is changed. (For example, by modifying with acrylic acid or maleic acid, the softening point tends to increase), adjusting the molecular weight of rosin (the higher the molecular weight, the higher the softening point), Examples thereof include subjecting rosin to hydrogenation and subjecting rosin to esterification or transesterification.
The blending amount of the component (A1) needs to be 70% by mass or more with respect to 100% by mass of the total amount of the component (A1) and the component (A2), and is 85% by mass or more and 100% by mass. The following is more preferable. When the blending amount of the component (A1) is less than the lower limit, the suppression of the scattering of the flux and the spread of the flux residue becomes insufficient.

  The blending amount of the component (A) is preferably 30% by mass to 50% by mass and more preferably 40% by mass to 45% by mass with respect to 100% by mass of the flux. When the blending amount of the component (A) is less than the lower limit, oxidation of the copper foil surface of the soldering land is prevented and the molten solder is easily wetted on the surface, so-called solderability is lowered, and solder balls are easily generated. On the other hand, if the upper limit is exceeded, the amount of residual flux tends to increase.

[Component (B)]
Examples of the organic acid used in the present invention include other organic acids in addition to monocarboxylic acid and dicarboxylic acid. These organic acids may be used alone or in combination of two or more. These organic acids act as activators in the flux.
Monocarboxylic acids include formic acid, acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, enanthic acid, capric acid, lauric acid, myristic acid, pentadecylic acid, palmitic acid, margaric acid, stearic acid, tuberculostearic acid Arachidic acid, behenic acid, lignoceric acid, glycolic acid and the like.
Examples of the dicarboxylic acid include oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, fumaric acid, maleic acid, tartaric acid, diglycolic acid and the like.
Examples of other organic acids include dimer acid, levulinic acid, lactic acid, acrylic acid, benzoic acid, salicylic acid, anisic acid, citric acid, and picolinic acid.

  The blending amount of the component (B) is preferably 1% by mass to 15% by mass, more preferably 3% by mass to 12% by mass, and more preferably 5% by mass with respect to 100% by mass of the flux. The content is particularly preferably 10% by mass or less. When the blending amount of the component (B) is less than the lower limit, solder balls tend to be generated, and when the upper limit is exceeded, the insulating properties of the flux tend to decrease.

[Component (C)]
As the (C) solvent used in the present invention, a known solvent can be used as appropriate. (C1) The boiling point is 280 ° C. or more and 321 ° C. or less, and the viscosity is 12 Pa · s or more and 80 Pa · s or less at 30 ° C. It is preferable to contain a certain solvent. Among these, the viscosity at 30 ° C. of the component (C1) is preferably 20 Pa · s to 75 Pa · s, more preferably 30 Pa · s to 70 Pa · s, and particularly preferably 55 Pa · s to 67 Pa · s. The viscosity can be measured using a B-type viscometer (programmable rheometer DV-III, manufactured by Brookfield).
In soldering with rapid heating, conventionally, generation of solder balls and scattering of flux have occurred. This is presumed to be caused by the flux with reduced viscosity flowing out of the pad prior to the melting of the solder powder due to rapid heating by laser irradiation or the like. In addition, when the flux flows out of the pad, unmelted solder powder flows together. By using the high viscosity and high boiling point solvent as the component (C1), the generation of solder balls and the occurrence of flux scattering can be more reliably suppressed.
The reason is presumed that the use of a solvent having a high viscosity makes it easier for the solder composition to remain on the pad during heating by laser irradiation or the like. In addition, the use of a solvent with a high boiling point increases the temperature at which the flux has fluidity, and the solder alloy melts more than the solder composition using a solvent with a low boiling point, thus suppressing solder balls. In addition, since the bumping of the solvent is further suppressed, it is assumed that the scattering of the flux is suppressed.

The component (C1) is preferably a cyclic alkane type alcohol having 5 or more carbon atoms having a terpene skeleton. Of these, the component (C1) is particularly preferably isobornylcyclohexanol. An example is Tersolve MTPH manufactured by Nippon Terpene Chemical Co., Ltd.
The blending amount of the component (C1) is preferably 2% by mass or more and 40% by mass or less, more preferably 7% by mass or more and 35% by mass or less, and 12% by mass with respect to 100% by mass of the flux. The content is particularly preferably 25% by mass or less.

In the component (C), the component (C1) and the component (C2) that is a solvent other than this may be used in combination. As such component (C2), known solvents such as alcohol solvents can be used as appropriate.
Specifically, diethylene glycol, dipropylene glycol, triethylene glycol, hexylene glycol, hexyl diglycol, 1,5-pentanediol, methyl carbitol, butyl carbitol, 2-ethylhexyl diglycol, octanediol, phenyl glycol, Examples include diethylene glycol monohexyl ether. These solvents may be used alone or in combination of two or more.

  The total amount of the component (C) is preferably 30% by mass or more and 65% by mass or less, more preferably 35% by mass or more and 50% by mass or less, and 40% by mass with respect to 100% by mass of the flux. % To 45% by mass is particularly preferable. (C) If the total compounding quantity of a solvent exists in the said range, the viscosity of the solder composition obtained can be suitably adjusted to an appropriate range.

[(D) component]
Examples of (D) the organic halogen compound that is solid at 25 ° C. used in the present invention include non-salt organic compounds in which halogen atoms are bonded by a covalent bond. This halogenated compound may be a compound formed by covalent bonding of single elements of chlorine, bromine, iodine and fluorine, such as chlorinated, brominated, iodinated and fluoride, but any of chlorine, bromine, iodine and fluorine may be used. The compound which has each two or all of these covalent bonds may be sufficient. In order to improve the solubility in an aqueous solvent, these compounds preferably have a polar group such as a hydroxyl group or a carboxyl group such as a halogenated alcohol or a halogenated carboxyl.

The component (D) preferably contains (D1) an iodine organic halogen compound that is solid at 25 ° C. from the viewpoint of suppressing solder balls and suppressing the scattering of flux and the spread of flux residue.
Examples of the component (D1) include carboxyl iodides such as 2-iodobenzoic acid, 3-iodobenzoic acid, 2-iodopropionic acid, 5-iodosalicylic acid, and 5-iodoanthranilic acid. These may be used alone or in combination of two or more.
The blending amount of the component (D1) is preferably 0.01% by mass or more and 10% by mass or less, and more preferably 0.1% by mass or more and 5% by mass or less with respect to 100% by mass of the flux. It is particularly preferably 0.2% by mass or more and 1% by mass or less.

The component (D) preferably further contains (D2) a bromine-based organic halogen compound that is solid at 25 ° C. from the viewpoint of suppressing solder balls, suppressing the scattering of flux and the spread of flux residue.
Examples of the component (D 2 ) include brominated alcohols such as 2,3-dibromopropanol, 2,3-dibromobutanediol, 1,4-dibromo-2-butanol and tribromoneopentyl alcohol, 2,3-dibromo Examples thereof include brominated carboxyl such as propionic acid, 2,3-dibromosuccinic acid and 2-bromobenzoic acid. These may be used alone or in combination of two or more.

  As the component (D), the component (D1) and the component (D2) may be used in combination with the component (D3) which is an organic halogen compound other than these. Examples of such component (D3) include chlorinated alcohols such as 1,3-dichloro-2-propanol and 1,4-dichloro-2-butanol, fluorinated alcohols such as 3-fluorocatechol, and 2-chlorobenzoic acid. And carboxyl chloride such as 3-chloropropionic acid.

  The total compounding amount of the component (D) is preferably 0.05% by mass or more and 10% by mass or less, and more preferably 0.1% by mass or more and 5% by mass or less with respect to 100% by mass of the flux. It is preferably 1% by mass or more and 3% by mass or less. When the blending amount of the component (D) is less than the lower limit, solder balls tend to be generated, and when the upper limit is exceeded, the insulating property of the flux tends to be lowered.

  In addition to the component (A), the component (B), the component (C), and the component (D), the flux used in the present invention, if necessary, other active agents and other additives Furthermore, other resins can be added. Examples of other additives include thixotropic agents (cured castor oil, amides, kaolin, colloidal silica, organic bentonite, glass frit, etc.), antioxidants, matting agents, foaming agents, antifoaming agents, and the like. Examples of other resins include acrylic resins. The amount of these additives and the like is preferably 0.1% by mass or more and 10% by mass or less, and more preferably 0.5% by mass or more and 5% by mass or less with respect to 100% by mass of the flux. .

[(E) component]
The solder powder (E) used in the present invention is preferably composed of only lead-free solder powder, but may be lead-lead solder powder. As the solder alloy in the solder powder, an alloy containing tin as a main component is preferable. Examples of the second element of the alloy include silver, copper, zinc, bismuth, and antimony. Furthermore, you may add another element (after 3rd element) to this alloy as needed. Examples of other elements include copper, silver, bismuth, antimony, aluminum, and indium.
Specific examples of the lead-free solder powder include Sn / Ag, Sn / Ag / Cu, Sn / Cu, Sn / Ag / Bi, Sn / Bi, Sn / Ag / Cu / Bi, Sn / Sb, Sn / Zn / Bi, Sn / Zn, Sn / Zn / Al, Sn / Ag / Bi / In, Sn / Ag / Cu / Bi / In / Sb, In / Ag, and the like.

  The average particle size of the solder powder is preferably 1 μm or more and 40 μm or less, more preferably 10 μm or more and 35 μm or less, and particularly preferably 15 μm or more and 25 μm or less. If the average particle diameter is within the above range, it can be applied to the recent printed wiring board in which the pitch of the soldering lands is narrow. The average particle size can be measured with a dynamic light scattering type particle size measuring device.

[Manufacture of solder composition]
In order to produce the solder composition of the present invention, the above-described flux and the above-described (E) solder powder may be blended at the predetermined ratio and mixed with stirring.

[Printed wiring board]
Next, the printed wiring board of the present invention will be described. The printed wiring board of the present invention is characterized in that an electronic component is mounted on a printed wiring board using the solder composition described above. Therefore, the printed wiring board of the present invention can sufficiently suppress the scattering of solder balls and flux when soldering with rapid heating (for example, during laser irradiation).

Examples of the coating apparatus used here include a dispenser, a jet dispenser, a screen printer, and a metal mask printer.
The coating thickness is not particularly limited, but is preferably 0.05 mm or more and 2 mm or less.
As a soldering method, a known method is appropriately used as long as soldering accompanied by rapid heating (soldering for which the time required for heating from room temperature to the solder melting point is 3 seconds or less (preferably 1 second or less)). Can be adopted. Examples of soldering with rapid heating include laser soldering and soldering with a soldering iron.
The type of laser light source of the laser light used for soldering is not particularly limited, and can be appropriately employed according to the wavelength matched to the metal absorption band. Examples of the laser light source include a solid-state laser (ruby, glass, YAG, etc.), a semiconductor laser (GaAs, InGaAsP, organic matter, etc.), a liquid laser (pigment, etc.), a gas laser (He—Ne, Ar, CO ₂ , excimer, etc.) ).
The laser irradiation conditions are not particularly limited. For example, the spot diameter φ is preferably 0.1 mm or more and 2 mm or less. Moreover, it is preferable that irradiation time is 0.1 second or more and 5 seconds or less.

  In the solder composition of the present invention, the remaining film may be left coated on the wiring board on which the electronic component is mounted without being washed. In this invention, the printed wiring board after electronic components mounting | wearing with the residual film | membrane of such a solder composition can be provided.

EXAMPLES Next, although an Example and a comparative example demonstrate this invention further in detail, this invention is not limited at all by these examples. In addition, the material used in the Example and the comparative example is shown below.
((A1) component)
Rosin resin A: hydrogenated acid modified rosin (softening point: 130 ° C.), trade name “KE-604”, Arakawa Chemical Industries rosin resin B: maleic acid modified rosin (softening point: 148 ° C.), trade name “Marquide No. 33”, manufactured by Arakawa Chemical Industries, Ltd. (component (A2))
Rosin resin C: hydrogenated rosin ester (softening point: 85 ° C.), trade name “Likatak F-85”, Rica Finetech rosin resin D: fully hydrogenated rosin (softening point: 80 ° C.), trade name "Foral AX", manufactured by Eastman Chemical (component (B))
Organic acid A: Succinic acid Organic acid B: Glutaric acid Organic acid C: Picolinic acid Organic acid D: Dimer acid (component (C1))
Solvent A: Isobornylcyclohexanol (boiling point: 308-318 ° C., viscosity: 65.5 Pa · s (30 ° C.)), trade name “MTPH”, manufactured by Nippon Terpene Chemical Co., Ltd. (component (C2))
Solvent B: 2-ethylhexyl diglycol Solvent C: Phenyl glycol (component (D1))
Organohalogen compound A: 2-iodobenzoic acid (component (D2))
Organohalogen compound B:
((E) component)
Solder powder: particle size 20-36 μm, solder melting point 200-230 ° C., solder composition Sn / Ag3.0 / Cu0.5
(Other ingredients)
Thixo Agent A: Trade name “Sripac ZHH”, Nippon Kasei Co., Ltd. Thixo Agent B: Trade name “Diamid Y”, Nippon Kasei Co., Ltd. Antioxidant: Trade name “Sumilyzer TPD”, manufactured by Sumitomo Chemical Co., Ltd.

[Example 1]
Rosin resin A 36% by weight, organic acid A 0.5% by weight, organic acid B 3% by weight, organic acid C 0.5% by weight, organic acid D 6% by weight, solvent A 12.5% by weight, solvent B 21.07% by weight, solvent C8% by mass, organohalogen compound A 0.06% by mass, organohalogen compound B 0.07% by mass, thixotropic agent A 6% by mass, thixotropic agent B 5.8% by mass, and antioxidant 0.5% by mass are charged into a container. Then, a flux was obtained by mixing using a rough machine.
Thereafter, 11% by mass of the obtained flux and 89% by mass of the solder powder (100% by mass in total) are put into a container and mixed in a kneader to prepare a solder composition having the composition shown in Table 1 below. did.

[Examples 2 to 4]
A solder composition was obtained in the same manner as in Example 1 except that each material was blended according to the composition shown in Table 1 below.
[Comparative Examples 1-4]
A solder composition was obtained in the same manner as in Example 1 except that each material was blended according to the composition shown in Table 2 below.

<Evaluation of solder composition>
Evaluation of the solder composition (flux residue spreading test, flux scattering test, solder ball test) was performed by the following method. The results obtained for the examples are shown in Table 1, and the results obtained for the comparative examples are shown in Table 2.

<Printing conditions>
Metal mask thickness: 0.2mm
Squeegee: metal squeegee squeegee speed: 30 mm / second plate separation speed: 0.2 mm / second printing pressure: 100 kPa
Printing site: Cu land 2.1 x 2.5 mm

<Laser irradiation conditions>
Laser wavelength: 808nm
Spot diameter: Φ1.6mm
Irradiation time: 0.5 seconds

<Test method>
(1) Flux residue spread test The test piece after laser irradiation was observed, and the spread width of the flux residue from the land was measured. And the spread of the flux residue was evaluated according to the following criteria.
A: The spread width of the flux residue from the land is 0.5 mm or less.
○: The spread width of the flux residue from the land is more than 0.5 mm and 1 mm or less.
Δ: The spread width of the flux residue from the land is more than 1 mm and 1.5 mm or less.
X: The spreading width of the flux residue from the land is more than 1.5 mm.

(2) Flux scattering test In order to investigate the flux scattering situation that occurs during laser irradiation of the solder composition, flux scattering per 25 cm ² was observed (pieces / 25 cm ² ). And the scattering of the flux was evaluated according to the following criteria.
A: Flux scattering is 0/25 cm ² .
◯: Flux scattering is 1 piece / 25 cm ² or more and 10 pieces / 25 cm ² or less.
△: scattering of the flux is 11/25 cm ² or more to 25/25 cm ² or less.
X: Scattering of flux exceeds 25 pieces / 25 cm ² .

(3) Solder ball test A solder ball test was performed in accordance with JIS Z 3284 (1994) in order to examine the occurrence of solder balls that occur during laser irradiation of the solder composition. The solder balls were evaluated according to the following criteria.
A: There are no solder balls.
○: There are 1 or more and less than 5 solder balls.
Δ: There are 5 or more and less than 10 solder balls.
X: There are 10 or more solder balls.

As is clear from the results shown in Tables 1 and 2, when the solder composition of the present invention was used (Examples 1 to 4), the spread of the flux residue was sufficiently suppressed, and laser irradiation was used. It was confirmed that the generation of solder balls and flux scattering that occur when the soldering method is performed are suppressed.
On the other hand, when the blending amount of the component (A1) in the present invention is a predetermined value or less, or when a solder composition not containing the component (D) is used (Comparative Examples 1 to 4), the spread of the flux residue and It was found that the flux scattering could not be suppressed.

  The solder composition of the present invention can be particularly suitably used as a technique for mounting a component on a printed wiring board of an electronic device using a laser beam.

Claims (5)

A solder composition used for laser soldering,
The solder composition includes: (A) a rosin resin, (B) an organic acid, (C) a solvent, and (D1) a flux containing an iodine organic halogen compound that is solid at 25 ° C., and (E) a solder powder. Containing
The component (A) contains (A1) a high softening point rosin resin having a softening point of 130 ° C. or higher,
Wherein (A1) amount of component, wherein the total amount of 100 mass% of the component (A) state, and are more than 70 wt%,
The component (D1) is at least one selected from the group consisting of 2-iodobenzoic acid, 3-iodobenzoic acid, 5-iodosalicylic acid, and 5-iodoanthranilic acid . . The solder composition according to claim 1,
The flux further contains a brominated organic halogen compound which is solid at (D2) 25 ° C.,
The component (D2) is selected from the group consisting of 2,3-dibromobutanediol, tribromoneopentyl alcohol, 2,3-dibromopropionic acid, 2,3-dibromosuccinic acid, and 2-bromobenzoic acid. A solder composition comprising at least one . In the solder composition according to claim 1 or 2,
The component (C) contains (C1) isobornylcyclohexanol.
The solder composition characterized by the above-mentioned. In the solder composition according to any one of claims 1 to 3,
The blending amount of the component (D1) or the total blending amount of the component (D1) and the component (D2) is 1% by mass to 3% by mass with respect to 100% by mass of the flux. A solder composition. An electronic component is mounted on a printed wiring board using the solder composition of any one of Claims 1-4 , The manufacturing method of a printed wiring board characterized by the above-mentioned.