JP6382003B2 - Powdered seasoning - Google Patents

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JP6382003B2
JP6382003B2 JP2014143651A JP2014143651A JP6382003B2 JP 6382003 B2 JP6382003 B2 JP 6382003B2 JP 2014143651 A JP2014143651 A JP 2014143651A JP 2014143651 A JP2014143651 A JP 2014143651A JP 6382003 B2 JP6382003 B2 JP 6382003B2
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seasoning
drying
seasonings
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崇徳 印野
崇徳 印野
前田 和彦
和彦 前田
陽子 滝澤
陽子 滝澤
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Yamasa Corp
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Description

本発明は、つゆ等に有用な粉粒状調味料に関する。   The present invention relates to a granular seasoning useful for soup and the like.

たれ、つゆ等の調味料は通常液状の形態で使用されるが、食生活の多様化及び流通性の点から、粉末状や顆粒状で供給することが望まれている。そのような粉末又は顆粒調味料の例は、スープ、ソース、たれ、つゆ、インスタント食品用の粉末調味料等がある。   Seasonings such as sauce and soup are usually used in a liquid form, but it is desired to supply them in powder form or granule form from the viewpoint of diversification of diet and distribution. Examples of such powder or granule seasonings include soups, sauces, sauces, soups, powder seasonings for instant foods and the like.

これらの粉末又は顆粒状の調味料の製法としては、スプレードライ(噴霧乾燥)法、フリーズドライ(真空凍結乾燥)法、ドラムドライ法、バキュームドラムドライ法等が採用されている(特許文献1〜4)。   As a method for producing these powder or granular seasonings, a spray drying (spray drying) method, a freeze drying (vacuum freeze drying) method, a drum drying method, a vacuum drum drying method and the like are employed (Patent Documents 1 to 3). 4).

特開昭58−5162号公報JP 58-5162 A 特開平7−213250号公報JP 7-213250 A 特開2008−289418号公報JP 2008-289418 A 特開2013−188189号公報JP 2013-188189 A

前記乾燥法のうち、真空凍結乾燥法は、高温での加熱工程を含まないため風味が良好であり、また溶解性も良好であることから広く採用されている。
しかし、凍結乾燥調味料を製造するにあたり、Brixが一定の値よりも高い液体調味料を真空凍結乾燥すると気泡が生じやすく、その結果真空凍結乾燥過程で気泡がはじけて液が飛び散って歩留りが低下し、乾燥後に一部がアメ状になってしまい溶けにくくなるなどの弊害が生じることが判明した。
従って、本発明の課題は、風味が良好で、安定して製造できる粉粒状調味料を提供することにある。
Among the drying methods, the vacuum freeze-drying method is widely adopted because it does not include a heating step at a high temperature and has good flavor and good solubility.
However, in producing freeze-dried seasonings, liquid freeze-drying liquid liquid with a Brix higher than a certain value tends to generate bubbles, and as a result, bubbles are repelled in the process of vacuum freeze-drying, resulting in liquid scattering and reduced yield. In addition, it has been found that after drying, a part of the structure becomes candy-like and difficult to dissolve.
Therefore, the subject of this invention is providing the granular seasoning which has favorable flavor and can be manufactured stably.

そこで本発明者は、前記課題を解決すべく検討した結果、風味の強い原料は真空凍結乾燥した後に粉粒化し、一方、味の濃い原料は非凍結乾燥手段で粉粒化し、それらを混合すれば、風味が良好な粉粒状調味料が安定して得られることを見出し、本発明を完成した。   Therefore, as a result of studying the above-mentioned problems, the present inventor has found that a flavorful raw material is granulated after vacuum freeze-drying, while a high-taste raw material is granulated by non-freeze-drying means and mixed. Thus, the present inventors have found that a powdery seasoning having a good flavor can be stably obtained, thereby completing the present invention.

すなわち、本発明は、次の〔1〕〜〔3〕の発明を提供するものである。   That is, the present invention provides the following inventions [1] to [3].

〔1〕(A)醤油、味噌、液体だし、柑橘成分及び食肉・魚介由来のエキスから選ばれる1種又は2種以上の調味料である賦香成分含有調味料を真空凍結乾燥後粉砕して得られた粉粒体及び(B)結晶化又は加熱を伴う手段で粉粒化された、食塩、砂糖、ぶどう糖、アミノ酸系調味料及び核酸系調味料から選ばれる1種又は2種以上の調味料である味の濃い調味料を含有する、粉粒状調味料。
〔2〕(A)賦香成分含有調味料を真空凍結乾燥後粉砕して得られた粉粒体が、Brix25以下の賦香成分含有調味料を真空凍結乾燥後粉砕して得られた粉粒体である、〔1〕記載の粉粒状調味料。
〔3〕鍋つゆ及びめんつゆから選ばれる調味料である〔1〕又は〔2〕に記載の粉粒状調味料。
[1] (A) Soy sauce, miso, liquid soup, citrus ingredients and flavoring ingredient-containing seasonings, which are one or more seasonings selected from meat and fish-derived extracts, are lyophilized after vacuum freeze-drying One or more seasonings selected from salt, sugar, glucose, amino acid-based seasonings and nucleic acid-based seasonings, which are granulated by means of the obtained granules and (B) crystallization or heating A powdery seasoning containing a seasoning with a strong taste.
[2] (A) A powder obtained by pulverizing a flavoring ingredient-containing seasoning after vacuum freeze-drying, and a powder obtained by grinding a flavoring ingredient-containing seasoning of Brix 25 or less after vacuum freeze-drying The granular seasoning according to [1], which is a body.
[3] The granular seasoning according to [1] or [2], which is a seasoning selected from hot pot soup and noodle soup.

本発明の粉粒状調味料は、風味が良好であり、溶けやすく、かつ形状・性状が安定して製造できる。   The granular seasoning of the present invention has a good flavor, is easily meltable, and can be manufactured with a stable shape and properties.

本発明の粉粒状調味料は、(A)賦香成分含有調味料を真空凍結乾燥後粉砕して得られた粉粒体と、(B)結晶化又は加熱を伴う手段で粉粒化された味の濃い調味料とを含有する。とくに醤油、味噌、液体だし、柑橘成分及び食肉・魚介由来のエキスから選ばれる1種又は2種以上の調味料である賦香成分含有調味料は、真空凍結乾燥によって得られたもののみを含有するものであることが好ましい。   The granular seasoning of the present invention was granulated by means of (A) a granule obtained by pulverizing a flavoring ingredient-containing seasoning after vacuum freeze-drying, and (B) crystallization or heating. Contains a flavoring seasoning. In particular, the flavoring ingredient-containing seasoning, which is one or more seasonings selected from soy sauce, miso, liquid dashi, citrus ingredients and meat and fish-derived extracts, contains only those obtained by vacuum freeze-drying It is preferable that

(A)賦香成分含有調味料は、風味の強い調味料であり、その例としては、ゆず、かぼす、すだち、レモン等の柑橘成分、醤油、味噌、液体だし、食肉・魚介由来のエキスから選ばれる1種又は2種以上が挙げられる。   (A) A flavoring ingredient-containing seasoning is a seasoning with a strong flavor. Examples thereof include citrus ingredients such as citron, kabosu, sudachi and lemon, soy sauce, miso, liquid soup, and extracts derived from meat and seafood. 1 type or 2 types or more selected are mentioned.

(A)賦香成分含有調味料は、真空凍結乾燥後粉砕する。真空凍結乾燥にあたっては、賦香成分含有調味料は、Brix25以下、特にBrix19以下の溶液とするのが望ましい。真空凍結乾燥に用いる機材や製造条件は、とくに限定されない。   (A) The flavoring ingredient-containing seasoning is pulverized after vacuum freeze-drying. In vacuum freeze-drying, the flavoring ingredient-containing seasoning is desirably a solution of Brix 25 or less, particularly Brix 19 or less. The equipment and manufacturing conditions used for vacuum freeze-drying are not particularly limited.

真空凍結乾燥後の賦香成分含有調味料は容器の形状のブロック状であるが、これを必要により粉砕する。粉砕手段は、特に限定されず、ミル、ミキサー等を利用した粉砕方法が採用できる。また、粉砕した粉粒体は、適宜ふるいにかけるなどして粒子径を均一化してもよい。   The flavoring ingredient-containing seasoning after vacuum freeze-drying is a block shape in the shape of a container, which is pulverized if necessary. The pulverizing means is not particularly limited, and a pulverizing method using a mill, a mixer or the like can be employed. The pulverized powder may be made uniform by sieving it appropriately.

(B)味の濃い調味料は、結晶化又は加熱を伴う手段で粉粒化されたものを用いる。味の濃い調味料は、通常塩味、甘味、旨味等を付与するための主成分であり、食塩、砂糖、ぶどう糖、グルタミン酸ナトリウム等のアミノ酸系調味料、及びグアニル酸ナトリウムやイノシン酸ナトリウム等の核酸系調味料から選ばれる1種又は2種以上が挙げられる。   (B) The seasoning with a strong taste uses what was granulated by the means accompanied by crystallization or a heating. A seasoning with a strong taste is usually the main ingredient for imparting a salty taste, sweet taste, umami, etc., and an amino acid seasoning such as salt, sugar, glucose, sodium glutamate, and a nucleic acid such as sodium guanylate or sodium inosinate. The 1 type (s) or 2 or more types chosen from a system seasoning are mentioned.

これらの味の濃い調味料は、凍結乾燥以外の粉粒化手段により粉粒化されたものを用いる。その粉粒化手段は、加熱によっても風味を損なうことが少ないため、結晶化又は加熱を伴う粉粒化手段でよい。   As these seasonings having a strong taste, those seasoned by powdering means other than freeze-drying are used. The powdering means may be a powdering means that accompanies crystallization or heating because the flavor is hardly impaired by heating.

加熱を伴う粉粒化手段としては、噴霧乾燥法、ドラム乾燥法、減圧乾燥法、自然乾燥等が挙げられる。また、必要により粉砕することができ、粉砕手段としては、ミル、ミキサー等による粉砕が挙げられる。   Examples of the granulating means with heating include spray drying, drum drying, reduced pressure drying, and natural drying. Moreover, it can grind | pulverize as needed and the grinding | pulverization means includes the grinding | pulverization by a mill, a mixer, etc.

本発明の粉粒状調味料における(A)成分と(B)成分の含有質量比(A/B)は、その用途によって相違するが、0.1〜10が好ましく、1.0〜8.0がより好ましく、1.0〜5.0がさらに好ましい。   The mass ratio (A / B) of the component (A) and the component (B) in the granular seasoning of the present invention varies depending on the use, but is preferably 0.1 to 10, and preferably 1.0 to 8.0. Is more preferable, and 1.0 to 5.0 is more preferable.

本発明の粉粒状調味料には、上記に挙げた賦香成分含有調味料や味の濃い調味料のほかに、他の原材料として、人工甘味料、香辛料、みりん、酢等の調味成分や、デキストリン、でんぷん等の賦形剤等を適宜添加することができる。当該他の原材料は、添加することによってBrixを25より大きく上昇せしめない限り、(A)賦香成分含有調味料と共に混合し、真空凍結乾燥させることができるが、真空凍結乾燥することは必須ではない。   In addition to the flavoring ingredient-containing seasonings and rich flavors listed above, the powdered granular seasoning of the present invention includes other ingredients such as artificial sweeteners, spices, mirin, vinegar and other seasoning ingredients, Excipients such as dextrin and starch can be appropriately added. The other raw materials can be mixed with (A) the flavoring ingredient-containing seasoning and vacuum lyophilized unless added to increase Brix to more than 25. However, vacuum lyophilization is not essential. Absent.

本発明の粉粒状調味料の用途としては、鍋つゆ、うどんつゆ、そばつゆ等のめんつゆ類;ソース類、たれ類等が挙げられる。また、野菜炒め等の炒め物、炒飯、焼きそば等の調味料として用いることも可能である。   Examples of the use of the granular seasoning of the present invention include noodle soup such as hot pot soup, udon soup and soba soup; sauces and sauces. Moreover, it can also be used as a seasoning such as stir-fried vegetables such as stir-fried vegetables, fried rice, and fried noodles.

次に実施例を挙げて本発明を更に詳細に説明する。   EXAMPLES Next, an Example is given and this invention is demonstrated still in detail.

試験例1:Brixによる凍結乾燥の検討
真空凍結乾燥調味料を製造するにあたり、真空凍結乾燥開始時の液体調味料のBrixの値と、乾燥後の性状等の比較を行った。
まず、下記表1に示す配合割合(%(w/w))で原料を混合した液体調味料をそれぞれ調製し、それぞれの液のBrixを測定した。その後、調製した液体調味料30mLを常法により真空凍結乾燥した。測定値についても表1に示す。
Test Example 1: Examination of freeze-drying with Brix In producing a vacuum freeze-dried seasoning, the Brix value of the liquid seasoning at the start of vacuum freeze-drying was compared with the properties after drying.
First, the liquid seasoning which mixed the raw material with the mixture ratio (% (w / w)) shown in following Table 1 was prepared, respectively, and Brix of each liquid was measured. Thereafter, 30 mL of the prepared liquid seasoning was freeze-dried by a conventional method. The measured values are also shown in Table 1.

Figure 0006382003
Figure 0006382003

調製した真空凍結乾燥したブロック状態の調味料について、その性状(外見)を下記1〜5点の評点によって評価した。
1点:気泡がきわめて多く発生し、ブロックの外見が崩れ、著しいアメ状化がみられるなど、きわめて好ましくない性状
3点:気泡やアメ状化は多くなく、おおむね好ましい性状
5点:気泡の発生やアメ状化はほとんどみられず、きわめて好ましい性状
About the prepared vacuum freeze-dried seasoning of the block state, the property (appearance) was evaluated by the following 1-5 grades.
1 point: Very unfavorable properties such as the generation of extremely large bubbles, the appearance of the block is broken, and significant candy formation, etc. 3 points: There are not many bubbles and candy formation, generally favorable properties 5 points: Generation of bubbles And almost no candy-like appearance, very favorable properties

評価結果を下記表2に示す。   The evaluation results are shown in Table 2 below.

Figure 0006382003
Figure 0006382003

以上の結果から、Brixの値が25より大きい液体調味料を真空凍結乾燥したときには、激しい気泡の発生やアメ状化を招き、好ましい凍結乾燥調味料は得られなかった。また、アメ状化した部分は水への溶解性も著しく低く、実用には全く適さないものであった(参考例5)。
一方、Brixの値が21以上25以下の液体調味料を真空凍結乾燥したときには、気泡の発生やアメ状化は観察されず、おおむね好ましい性状の調味料を得られた(参考例3、4)。
Brixの値が21未満の液体調味料を凍結乾燥したときには、真空凍結乾燥時に気泡の発生がほとんどみられず、良好な形態の固形調味料を得られた(参考例1、2)。
From the above results, when a liquid seasoning having a Brix value greater than 25 was freeze-dried in vacuo, severe bubble formation and candy formation were caused, and a preferred freeze-dried seasoning could not be obtained. Further, the candy-like portion was remarkably low in water solubility and was not suitable for practical use (Reference Example 5).
On the other hand, when a liquid seasoning having a Brix value of 21 or more and 25 or less was vacuum freeze-dried, no bubble formation or candy-like formation was observed, and a seasoning with generally preferable properties was obtained (Reference Examples 3 and 4). .
When a liquid seasoning having a Brix value of less than 21 was freeze-dried, almost no bubbles were observed during vacuum freeze-drying, and a solid seasoning in a favorable form was obtained (Reference Examples 1 and 2).

これらの検討から、Brixの値が25より大きな液体調味料を従来の方法で真空凍結乾燥して固形調味料を得ることは困難であることが判明した。   From these examinations, it has been found that it is difficult to obtain a solid seasoning by vacuum lyophilizing a liquid seasoning having a Brix value greater than 25 by a conventional method.

実施例1:賦香成分を凍結乾燥したとき/噴霧乾燥したときの違いの検討
賦香成分含有調味料を真空凍結乾燥した場合と、噴霧乾燥した場合における、乾燥調味料の食味の違いについて検討した。
まず、下記表3に示すような配合割合(%(w/w))で原料を混合することにより賦香成分含有調味料を含有する液体調味料を調製し、調製した液体調味料30mLを冷凍し、真空凍結乾燥した。実施例1における当該調製した液体調味料のBrixは19であり、気泡やアメ状化は全くみられず良好な性状の凍結乾燥調味料が得られた。
Example 1: Examination of the difference when the flavoring ingredient is freeze-dried / spray-dried Examination of the difference in the taste of the dried seasoning when the flavor-containing seasoning is freeze-dried and when it is spray-dried did.
First, a liquid seasoning containing a flavoring ingredient-containing seasoning is prepared by mixing raw materials at a blending ratio (% (w / w)) as shown in Table 3 below, and 30 mL of the prepared liquid seasoning is frozen. And vacuum lyophilized. The Brix of the liquid seasoning prepared in Example 1 was 19, and no freeze bubbles or candy-like formation was observed, and a freeze-dried seasoning with good properties was obtained.

真空凍結乾燥した賦香成分含有調味料は、ミルによって粉砕し、径5mmのストレーナーを通すことで粒度の粗いものを取り除いた。   The flavor-containing seasoning containing freeze-dried powder was pulverized by a mill and passed through a strainer with a diameter of 5 mm to remove coarse particles.

Figure 0006382003
Figure 0006382003

上記真空凍結乾燥後に粉砕した賦香成分含有調味料10gに対し、本願発明では、食塩1.2gを添加した。対照では食塩1.2gに加えて、通常の噴霧乾燥によって得られた粉末醤油2gをさらに添加した。本願発明及び対照では、含有窒素の値及び食塩値が同等となるように調整した。   In this invention, 1.2g of salt was added with respect to 10g of flavoring ingredient containing seasonings grind | pulverized after the said vacuum freeze-drying. In the control, in addition to 1.2 g of sodium chloride, 2 g of powdered soy sauce obtained by ordinary spray drying was further added. In the present invention and the control, the nitrogen content and the salt value were adjusted to be equivalent.

調製した粉粒調味料10gを、100mLの温水に溶解させ、官能評価を実施した。評価では醤油の劣化臭・加熱臭という項目について、以下のように評点を設定した。
1点:醤油の劣化臭・こげ臭を強く感じる
3点:醤油の劣化臭・こげ臭をやや感じる
5点:醤油の劣化臭・こげ臭を感じない
10 g of the prepared powder seasoning was dissolved in 100 mL of warm water, and sensory evaluation was performed. In the evaluation, the following points were set for the items of soy sauce deterioration odor and heating odor.
1 point: Strongly felt the soy sauce deterioration odor / burnt odor 3 points: Soy sauce deterioration odor / burnt odor slightly 5 points: Soy sauce deterioration odor / burnt odor not felt

結果を下記表4に示す。   The results are shown in Table 4 below.

Figure 0006382003
Figure 0006382003

以上の結果から、賦香成分含有調味料を真空凍結乾燥した場合と、噴霧乾燥した場合における、乾燥調味料の食味の違いについて、賦香成分含有調味料を真空凍結乾燥した場合(本願発明)は劣化臭・こげ臭はほとんどなく良好な風味であったが、賦香成分含有調味料を噴霧乾燥した場合(対照)は劣化臭・こげ臭が強く感じられ、風味として好ましくないという結果が得られた。   From the above results, when the flavoring ingredient-containing seasoning is vacuum freeze-dried and when it is spray-dried, the flavoring ingredient-containing seasoning is vacuum freeze-dried (the invention of the present application). However, when the seasoning containing a flavoring ingredient was spray-dried (contrast), it was strongly felt that the odor and burnt odor were not good. It was.

したがって、(A)醤油、味噌、液体だし又は柑橘成分から選ばれる1種又は2種以上の調味料である賦香成分含有調味料を真空凍結乾燥後粉砕して得られた粉粒体及び(B)結晶化又は加熱を伴う手段で粉粒化された、食塩、砂糖、グルタミン酸ナトリウムから選ばれる1種又は2種以上の調味料である味の濃い調味料を含有する、粉粒状調味料は、賦香成分含有調味料に不要な焦げ臭や劣化臭を付与させることなく、風味の良好な粉粒調味料となることが明らかになった。   Accordingly, (A) a granular material obtained by vacuum freeze-drying and pulverizing a flavoring ingredient-containing seasoning which is one or more seasonings selected from soy sauce, miso, liquid soup or citrus ingredients and ( B) A granular seasoning containing a seasoning having a strong taste, which is one or more seasonings selected from salt, sugar and sodium glutamate, which has been granulated by means of crystallization or heating. Thus, it has been clarified that it becomes a powdery seasoning with a good flavor without imparting an unnecessary burning odor or deteriorated odor to the flavoring ingredient-containing seasoning.

実施例2:製造例
味噌、昆布だし、鰹だしを含有する液体調味料を作製した。当該液体調味料を冷凍し、その後真空凍結乾燥した。ミルによって粉砕し、径5mmのストレーナーを通すことで粒度の粗いものを取り除いた。当該粉粒調味料に結晶化又は噴霧乾燥によって粉粒化された食塩及びグルタミン酸ナトリウムを添加した。
得られた粉粒調味料を温水に溶解させ、鍋つゆを作製したところ、味噌の良好な風味を感じられ、焦げ臭や劣化臭は感じられなかった。
Example 2: Production Example A liquid seasoning containing miso, kelp dashi and koji dashi was prepared. The liquid seasoning was frozen and then vacuum lyophilized. Crude particles were removed by grinding with a mill and passing through a strainer with a diameter of 5 mm. Sodium chloride and sodium glutamate pulverized by crystallization or spray drying were added to the powder seasoning.
When the obtained granule seasoning was dissolved in warm water to make a hot pot soup, a good taste of miso was felt, and neither a burnt odor nor a deteriorated odor was felt.

実施例3:製造例
醤油、ゆず果汁、鶏だし、鰹だしを含有する液体調味料を作製した。当該液体調味料を冷凍し、その後真空凍結乾燥した。ミルによって粉砕し、径5mmのストレーナーを通すことで粒度の粗いものを取り除いた。当該粉粒調味料に結晶化又は噴霧乾燥によって粉粒化された食塩及びグルタミン酸ナトリウムを添加した。
得られた粉粒調味料を温水に溶解させ、鍋つゆを作製したところ、ゆずや醤油の良好な風味を感じられ、焦げ臭や劣化臭は感じられなかった。
Example 3: Production Example A liquid seasoning containing soy sauce, yuzu juice, chicken stock, and broth was prepared. The liquid seasoning was frozen and then vacuum lyophilized. Crude particles were removed by grinding with a mill and passing through a strainer with a diameter of 5 mm. Sodium chloride and sodium glutamate pulverized by crystallization or spray drying were added to the powder seasoning.
When the obtained powdered seasoning was dissolved in warm water to make a hot pot soy sauce, a good flavor of yuzu and soy sauce was felt, and neither a burnt odor nor a deteriorated odor was felt.

Claims (2)

(A)醤油、味噌、液体だし、柑橘成分及び食肉・魚介由来のエキスから選ばれる1種又は2種以上の調味料であるBrix25以下の賦香成分含有調味料を真空凍結乾燥後粉砕して得られた粉粒体及び(B)結晶化又は加熱を伴う手段で粉粒化された、食塩、砂糖、ぶどう糖、アミノ酸系調味料及び核酸系調味料から選ばれる1種又は2種以上の調味料である味の濃い調味料を含有する粉粒状調味料。 (A) Soy sauce, miso, liquid soup, citrus ingredients and one or two or more kinds of seasonings selected from essences derived from meat and seafood are vacuum freeze-dried and then ground. One or more seasonings selected from salt, sugar, glucose, amino acid-based seasonings and nucleic acid-based seasonings, which are granulated by means of the obtained granules and (B) crystallization or heating A granular seasoning containing a seasoning with a strong taste. 鍋つゆ及びめんつゆから選ばれる調味料である請求項1に記載の粉粒状調味料。 The granular seasoning according to claim 1, which is a seasoning selected from hot pot soup and noodle soup.
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