JP6381964B2 - Polyvinyl alcohol resin pellet manufacturing method - Google Patents

Description

  The present invention relates to a method for producing pellets made of polyvinyl alcohol resin (hereinafter referred to as “PVA”) that can be used as a molding material for various molded products.

  Conventionally, a hydrophobic thermoplastic resin can be pelletized by extruding the thermoplastic resin into a strand by melt-kneading, water contact cooling (water flow immersion), and then cutting into a pellet shape with a cutting device. The obtained pellets are used for various molding materials. As described above, the thermoplastic resin exhibiting hydrophobicity can be cooled by the water contact cooling method as described above, and pellets can be easily produced. However, PVA, which is a water-soluble resin, will be dissolved when trying to cool by water contact cooling after being extruded into a strand as described above, and cannot be cooled effectively. It was difficult to cut into a pellet shape.

  For this reason, pelletization of PVA, which is a water-soluble resin, has been studied. For example, after preparing PVA from which volatile components have been removed and extruding it into a strand shape on a belt, the PVA extruded onto the belt is air-cooled or air-cooled and pelletized by a cutting device such as a pelletizer. It has been proposed (see Patent Document 1).

JP 2012-149144 A

  However, in the production method of Patent Document 1 described above, a method for cooling a high-temperature strand extruded by melting and kneading is to cut a product cooled by air cooling or air cooling to produce a desired pellet. If it is attempted to cool to a temperature that can be cut by the cooling means, it requires a long cooling time, which is not realistic from the viewpoint of industrial production. For example, in a high-melting point PVA, the extruded strand has a higher temperature. There is a problem that cooling becomes more difficult. Thus, as for the manufacturing method of pelletizing the PVA which is a water-soluble resin as a raw material, the actual situation is that the actual manufacturing method has not yet been established.

  This invention is made | formed in view of such a situation, The objective is to provide the manufacturing method of the pellet made from PVA which enables the pelletization of PVA which is water-soluble resin.

  In view of the above circumstances, the present inventor conducted a series of studies in order to obtain PVA pellets, which are water-soluble resins that were conventionally difficult to produce industrially. Then, research was conducted focusing on the cooling method of this strand, how to cool the strand in a high temperature state obtained by melt-extruding PVA powder which is a water-soluble resin so that it can be cut into pellets. As a result, the melt-extruded strand is brought into contact with a metal belt cooled by itself, the contact surface is cooled, and fog is sprayed on the non-contact surface of the metal belt of the strand, and then the strand is dried. By injecting the gas, it becomes possible to effectively cool the strands in a high temperature state, and as a result, it is found that the cooled strands can be industrially efficiently cut into pellets, The present invention has been reached.

That is, in order to achieve the above object, the method for producing PVA pellets of the present invention includes a step of melt-extruding PVA to form a strand, and a step of cooling the strand and then cutting the strand into a pellet. A method for producing PVA pellets, wherein the strand cooling step is to bring the strand into contact with the metal belt surface that has been cooled per se, and spraying mist on the strand surface, and then supplying a dry gas to the strand. The step of cutting the strands into pellets is performed under conditions where the strand temperature is 35 to 95 ° C. and the water content is less than 0.1% by weight .

  PVA pellets, which are water-soluble resins that have conventionally been difficult to manufacture, can be industrially manufactured with high efficiency.

  And when the temperature of the strand at the time of cut | disconnecting the said strand to a pellet form is 95 degrees C or less, especially 35-95 degreeC, a strand itself does not wind around a pelletizer or the strands after a cutting | disconnection are not caught efficiently. It becomes possible to cut.

  Further, when the step of cutting the strand into pellets is performed under the conditions of a strand temperature of 35 to 95 ° C. and a moisture content of the strand of less than 0.1% by weight, the strand itself may be wound around the pelletizer or It is possible to cut efficiently without sticking between the pellets.

  The step of melt-extruding the polyvinyl alcohol-based resin to form a strand is performed by adding a powdered polyvinyl alcohol-based resin to a melt extruder to extrude the strand, and the charged polyvinyl alcohol-based resin is completely melted When it is carried out using a melt extruder in which a preliminary vent is formed in a region before the melt, melt kneading is performed without any trouble, and a uniform strand can be formed.

It is process drawing which shows typically an example of the manufacturing method of the pellet made from PVA of this invention.

  Next, embodiments of the present invention will be described in detail. However, the present invention is not limited to this embodiment.

The manufacturing method of the PVA pellets of the present invention is as follows:
(1) a step of melt-extruding PVA to form a strand;
(2) After cooling the said strand, it is a manufacturing method of the pellet made from PVA provided with the process of cut | disconnecting a strand to a pellet form. In the present invention, the strand cooling process is performed by a special cooling method and process that are not conventionally used, as described later.

First, in the manufacturing method of the PVA pellets of the present invention, PVA used as a raw material will be described, and the manufacturing method will be described later.
<< PVA >>
The PVA used in the method for producing the PVA pellets of the present invention is usually in the form of a powder and may be either unmodified PVA or modified PVA. Examples of the modified PVA include acetoacetylated PVA, oxyalkylene group-containing PVA, PVA having a 1,2-diol structural unit in the side chain, and carboxylic acid-modified PVA. Among them, PVA having a 1,2-diol structural unit in the side chain is particularly preferable because it has a low melting point and can be melted at a relatively low temperature when melt-molding.

  The saponification degree of the PVA is usually 72 to 100 mol%, preferably 78 to 98.5 mol%, particularly preferably 86 to 96 mol%. If the degree of saponification is too high, the molding temperature becomes high, the temperature range that can be melt-molded tends to be narrow, and melt molding tends to be difficult, and if it is too low, the flexibility becomes too high and the surface of the molded product Tend to be sticky.

  The average degree of polymerization of PVA (based on JIS K6726) is usually 300 to 1100, particularly 450 to 800, and more preferably 500 to 650. If the average degree of polymerization is too large, shear heat generation tends to occur during melt molding, and the resin tends to thermally decompose. Conversely, if the average degree of polymerization is too small, the strength of the resulting molded product tends to be low. Is seen.

  Furthermore, the PVA is in the form of powder, and the average particle size is usually 50 to 2000 μm, preferably 100 to 1700 μm, and particularly preferably 150 to 1500 μm.

  Here, the average particle size means that the PVA particles are sieved with an opening of 1700 μm, 1000 μm, 850 μm, 500 μm, 250 μm, and 150 μm, and the particle size is 1700 μm or more, 1000 μm or more and less than 1700 μm, 850 μm using a sieve shaker. The particle size is classified into particles having a cumulative particle size distribution of 50% by weight, which is classified into those having a particle size distribution of less than 1000 μm, 500 μm or more and less than 850 μm, 250 μm or more and less than 500 μm, or 150 μm or more and less than 250 μm.

  The PVA is produced by polymerizing a vinyl ester monomer and further saponifying it. Examples of the vinyl ester monomers include vinyl formate, vinyl acetate, vinyl propionate, vinyl valelate, vinyl butyrate, vinyl isobutyrate, vinyl pivalate, vinyl caprate, vinyl laurate, vinyl stearate, vinyl versatate. , Aliphatic vinyl esters such as vinyl trifluoroacetate, and aromatic vinyl esters such as vinyl benzoate, etc., and usually have 3 to 20 carbon atoms, preferably 4 to 10 carbon atoms, particularly preferably 4 to 7 carbon atoms. Group vinyl ester. From the economical viewpoint, vinyl acetate is particularly preferably used. These are usually used alone, but a plurality of them may be used simultaneously as necessary.

  The modified PVA is produced by saponifying a polymer of a vinyl ester monomer and another unsaturated monomer, or by post-modifying polyvinyl alcohol.

  Examples of the other unsaturated monomer include olefins such as ethylene, propylene, isobutylene, α-octene, α-dodecene, α-octadecene, acrylic acid, methacrylic acid, crotonic acid, maleic acid, and maleic anhydride. , Unsaturated acids such as itaconic acid or salts thereof, mono- or dialkyl esters, nitriles such as acrylonitrile and methacrylonitrile, amides such as acrylamide and methacrylamide, ethylene sulfonic acid, allyl sulfonic acid, methallyl sulfonic acid, etc. Olefin sulfonic acids or salts thereof, alkyl vinyl ethers, N-acrylamidomethyltrimethylammonium chloride, allyltrimethylammonium chloride, dimethylallyl vinyl ketone, N-vinylpyrrolidone, vinyl chloride, vinyl chloride Polyoxyalkylene (meth) allyl ethers such as denene, polyoxyethylene (meth) allyl ether and polyoxypropylene (meth) allyl ether, polyoxyalkylenes such as polyoxyethylene (meth) acrylate and polyoxypropylene (meth) acrylate (Meth) acrylate, polyoxyethylene (meth) acrylamide, polyoxyalkylene (meth) acrylamide such as polyoxypropylene (meth) acrylamide, polyoxyethylene (1- (meth) acrylamide-1,1-dimethylpropyl) ester, Polyoxyethylene vinyl ether, polyoxypropylene vinyl ether, polyoxyethylene allylamine, polyoxypropylene allylamine, polyoxyethylene vinylamine, polyoxypropylene Nbiniruamin and the like.

  Examples of the post-modification method include acetoacetate esterification, acetalization, urethanization, etherification, grafting, phosphate esterification, and oxyalkyleneation.

  As described above, the PVA used in the present invention has a low melting point and can be melted at a relatively low temperature during melt molding, so that it has a 1,2-diol structural unit in the side chain. Is preferably used.

<PVA having a 1,2-diol structural unit in the side chain>
The PVA having a 1,2-diol structural unit in the side chain is specifically a PVA having a 1,2-diol structural unit in the side chain represented by the following general formula (1). In 1), R ¹ , R ² , and R ³ each independently represent a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, X represents a single bond or a bonded chain, R ⁴ , R ⁵ , and R ⁶ each independently represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms.

  The content of the 1,2-diol structural unit represented by the above formula (1) of the PVA having the 1,2-diol structural unit in the side chain is usually about 0.3 to 20 mol%, The remaining part is composed of a vinyl alcohol structural unit and a slight amount of vinyl acetate structural unit in the same manner as a normal PVA resin.

All of R ^{1 to} R ³ and R ^{4 to} R ⁶ in the 1,2-diol structural unit represented by the above formula (1) are preferably hydrogen atoms, but the resin properties are not significantly impaired. The amount may be substituted with an alkyl group having 1 to 4 carbon atoms, for example, methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, isobutyl group, tert-butyl group, etc. Preferably, it may have a substituent such as a halogen group, a hydroxyl group, an ester group, a carboxylic acid group, or a sulfonic acid group, if necessary.

Further, X in the 1,2-diol structural unit represented by the above formula (1) is typically a single bond, and is most preferably a single bond in terms of thermal stability. As long as it does not inhibit the above, a bond chain may be used, and the bond chain is not particularly limited, but hydrocarbons such as alkylene, alkenylene, alkynylene, phenylene, naphthylene (these hydrocarbons include fluorine, chlorine, bromine, etc.) other, -O of may be substituted by a _{halogen) -, - (CH 2 O} ) m -, - (OCH 2) m -, - (CH 2 O) m CH 2 -, - CO-, _{-COCO -, - CO (CH 2} ) m CO -, - CO (C 6 H 4) CO -, - S -, - CS -, - SO -, - SO 2 -, - NR -, - CONR-, -NRCO-, -CSNR-, -NRCS-, -NRNR-, -HPO _{4 -, - Si (OR)} 2 -, - OSi (OR) 2 -, - OSi (OR) 2 O -, - Ti (OR) 2 -, - OTi (OR) 2 -, - OTi (OR) 2 O-, -Al (OR)-, -OAl (OR)-, -OAl (OR) O-, etc. are mentioned (R is each independently an arbitrary substituent, preferably a hydrogen atom or an alkyl group, Of these, m is a natural number). Among them, an alkylene group having 6 or less carbon atoms, particularly a methylene group, or —CH ₂ OCH ₂ — is preferable from the viewpoint of stability during production or use.

  The PVA having a 1,2-diol structural unit in the side chain is, for example, (i) a vinyl ester monomer and a compound represented by the following general formula (2) (for example, 3,4-diacetoxy-1-butene) And (ii) a method of saponifying and decarboxylating a copolymer of a vinyl ester monomer and a compound represented by the following general formula (3) (for example, vinyl ethylene carbonate) (Iii) Saponification and deketalization of a copolymer of a vinyl ester monomer and a compound represented by the following general formula (4) (for example, 2,2-dialkyl-4-vinyl-1,3-dioxolane) And (iv) a method of saponifying a copolymer of a vinyl ester monomer and glyceryl monoallyl ether, and the like. Among these, a method of saponifying a copolymer of the above (i) vinyl ester monomer and a compound represented by the following general formula (2) is preferably used.

The vinyl ester monomers used in the above methods include vinyl formate, vinyl acetate, vinyl propionate, vinyl valelate, vinyl butyrate, vinyl isobutyrate, vinyl pivalate, vinyl caprate, vinyl laurate, stearic acid. Vinyl, vinyl benzoate, vinyl versatate and the like can be mentioned, but vinyl acetate is preferably used from the economical viewpoint.
Hereinafter, each of the methods (i), (ii), and (iii) will be described in detail.

[Method (i)]
In the method (i), a vinyl ester monomer and a compound represented by the general formula (2) are copolymerized and then saponified to obtain a 1,2-diol structural unit represented by the general formula (1). It is the method of manufacturing PVA which has.

In the compound represented by the general formula (2), R ^{1 to} R ³ , R ^{4 to} R ⁶ and X are the same as those in the general formula (1), and R ⁷ and R ⁸ are each independently A hydrogen atom or R ⁹ —CO— (wherein R ⁹ is an alkyl group, preferably a methyl group, a propyl group, a butyl group, a hexyl group or an octyl group. It may have a substituent such as a halogen group, a hydroxyl group, an ester group, a carboxylic acid group, or a sulfonic acid group as long as it does not adversely affect the process.

Specific examples of the compound represented by the general formula (2) include 3,4-dihydroxy-1-butene, 3,4-diasiloxy-1-butene, and 3-acyloxy-4-hydroxy-, where X is a single bond. 1-butene, 4-acyloxy-3-hydroxy-1-butene, 3,4-diacyloxy-2-methyl-1-butene, 4,5-dihydroxy-1-pentene, wherein X is an alkylene group, 4,5- Diacyloxy-1-pentene, 4,5-dihydroxy-3-methyl-1-pentene, 4,5-diacyloxy-3-methyl-1-pentene, 5,6-dihydroxy-1-hexene, 5,6-diacyloxy- 1-hexene, X is -CH ₂ OCH ₂ - or -OCH ₂ - in which glycerol monoallyl ether, 2,3-diacetoxy-1-allyloxypropane, 2-aceto Shi-1-allyloxy-3-hydroxypropane, 3-acetoxy-1-allyloxy-2-hydroxypropane, glycerin monovinyl ether, glycerin monomethyl isopropenyl ether, and the like.

Among them, R ¹ , R ² , R ³ , R ⁴ , R ⁵ and R ⁶ are hydrogen, X is a single bond, R ⁷ and R ⁸ are R ^{9 in} terms of excellent copolymerization reactivity and industrial handling. 3,4-diasiloxy-1-butene in which —CO— and R ⁹ is an alkyl group is preferable, and 3,4-diacetoxy-1-butene in which R ⁹ is a methyl group is particularly preferable. The reactivity ratio of each monomer when vinyl acetate and 3,4-diacetoxy-1-butene were copolymerized was r (vinyl acetate) = 0.710, r (3,4-diacetoxy-1-butene) = 0.701, which is compared to r (vinyl acetate) = 0.85 and r (vinyl ethylene carbonate) = 5.4 in the case of vinyl ethylene carbonate, which will be described later. This shows that 1-butene is excellent in copolymerization reactivity with vinyl acetate.

  The 3,4-diacetoxy-1-butene can be obtained from the market as a product of Eastman Chemical Co. for industrial production and Acros Co. at the reagent level. Further, 3,4-diacetoxy-1-butene obtained as a by-product during the production process of 1,4-butanediol can also be used.

  Also, it can be obtained by using a known technique such as a method of converting 1,4-diacetoxy-2-butene into 3,4-diacetoxy-1-butene described in JP-A-10-212264.

  In copolymerizing the vinyl ester monomer and the compound represented by the general formula (2), a known method such as bulk polymerization, solution polymerization, suspension polymerization, dispersion polymerization, or emulsion polymerization is employed. However, solution polymerization is usually performed.

  As a method for charging the monomer component at the time of copolymerization, for example, any method such as batch charging, split charging, continuous charging, etc. is adopted. Among them, 1,2-derived from the compound represented by the general formula (2) Drop polymerization is preferred from the viewpoint that the diol structural units are uniformly distributed in the molecular chain of the polyvinyl ester polymer, and a polymerization method based on the HANNA method using a reactivity ratio with vinyl acetate is particularly preferred.

  The above dropping polymerization is a polymerization in which either one or both monomers are dropped continuously or discontinuously in order to keep the monomer ratio in the reaction system within a certain range during the copolymerization. In particular, dripping polymerization by the HANNA method was performed by dropping the monomer at a rate commensurate with the monomer consumption rate calculated based on the reactivity ratio of the two monomers, and keeping the monomer ratio in the system almost constant. .

Examples of the solvent used in the copolymerization include lower alcohols such as methanol, ethanol, isopropyl alcohol, n-propanol and butanol, and ketones such as acetone and methyl ethyl ketone, and industrially preferred is methanol. used.
The amount of the solvent used may be appropriately selected in consideration of the chain transfer constant of the solvent in accordance with the degree of polymerization of the target copolymer. For example, when the solvent is methanol, S (solvent) / M (Monomer) = 0.01 to 10 (weight ratio), preferably selected from the range of about 0.04 to 3 (weight ratio).

In the copolymerization, a polymerization catalyst is used. Examples of the polymerization catalyst include known radical polymerization catalysts such as azobisisobutyronitrile, acetyl peroxide, benzoyl peroxide, lauryl peroxide, azobisdimethylvaleronitrile, azo Examples include low-temperature active radical polymerization catalysts such as bismethoxydimethylvaleronitrile and t-butylperoxyneodecanoate. The amount of polymerization catalyst used varies depending on the type of comonomer and the type of catalyst, but cannot be determined unconditionally. , Arbitrarily selected according to the polymerization rate. For example, when azoisobutyronitrile or acetyl peroxide is used, 0.002 to 0.7 mol% is preferable with respect to the vinyl ester monomer, and 0.004 to 0.5 mol% is particularly preferable.
The reaction temperature of the copolymerization reaction is about 30 ° C. to the boiling point depending on the solvent and pressure used, more specifically 35 to 90 ° C., preferably 40 to 75 ° C.

  The obtained copolymer is further saponified. In the saponification, the copolymer obtained as described above is dissolved in a solvent such as alcohol, and an alkali catalyst or an acid catalyst is used. Done. Typical solvents include methanol, ethanol, propanol, tert-butanol and the like, with methanol being particularly preferred. The concentration of the copolymer in the alcohol is appropriately selected depending on the viscosity of the system, but is usually selected from the range of 10 to 60% by weight. Catalysts used for saponification include alkali catalysts such as alkali metal hydroxides and alcoholates such as sodium hydroxide, potassium hydroxide, sodium methylate, sodium ethylate, potassium methylate, lithium methylate, etc., sulfuric acid, Examples include acid catalysts such as hydrochloric acid, nitric acid, metasulfonic acid, zeolite, and cation exchange resin.

The amount of the saponification catalyst used is appropriately selected depending on the saponification method, the target degree of saponification, and the like. Usually, when an alkali catalyst is used, the vinyl ester monomer and the general formulas (2) to ( A ratio of 0.1 to 30 mmol, preferably 2 to 17 mmol, is appropriate with respect to 1 mol of the total amount of 1,2-diol structural units derived from the compound represented by 4).
Moreover, 10-60 degreeC is preferable, for example, as for the reaction temperature of saponification reaction, More preferably, it is 20-50 degreeC.

  The PVA having a 1,2-diol structural unit in the side chain obtained by the method (i) is different from the method (ii) or the method (iii), depending on the degree of saponification. The acetoxy group remains in the chain. Since the side chain acetoxy group is larger than the side chain hydroxyl group and has a higher degree of freedom than the main chain acetoxy group, it has an effect on the crystallinity inhibition of PVA, interfacial properties when used in aqueous solution, or affinity with other materials. Is a big one.

  Also, PVA having a 1,2-diol structural unit in the side chain obtained by the method (ii) or (iii) has a low degree of saponification, or is insufficiently decarboxylated or deacetalized. In such a case, a carbonate ring or an acetal ring may remain in the side chain. On the other hand, the PVA having a 1,2-diol structural unit in the side chain obtained by the method (i) has no such problems as described above, and is excellent in terms of stability at the time of production and after becoming a product. ing.

[Method (ii)]
In the method (ii), a vinyl ester monomer and a compound represented by the above general formula (3) are copolymerized, then saponified and decarboxylated, and then 1,2-diol represented by the above general formula (1). It is a method for producing PVA having a structural unit.

In the compound represented by the general formula (3), R ^{1 to} R ³ , R ^{4 to} R ⁶ and X are the same as those in the general formula (1). Among them, vinyl ethylene carbonate in which R ¹ , R ² , R ³ , R ⁴ , R ⁵ , R ⁶ are hydrogen and X is a single bond is preferably used because it is easily available and has good copolymerizability. It is done.

Copolymerization and saponification of the vinyl ester monomer and the compound represented by the general formula (3) are performed in the same manner as in the method (i).
In addition, about decarboxylation, without performing a special process, decarboxylation is performed with saponification, and it transform | converts into a 1, 2- diol structure by opening an ethylene carbonate ring.
Further, it is possible to perform decarboxylation without saponifying the vinyl ester part under a constant pressure (normal pressure to 1 × 10 ⁷ Pa) and at a high temperature (50 to 200 ° C.). The saponification can also be performed after decarboxylation.

[Method (iii)]
In the method (iii), a vinyl ester monomer and a compound represented by the above general formula (4) are copolymerized, then saponified and deketalized, and the side chain represented by the above general formula (1) has 1 , 2-diol structural unit.

In the compound represented by the general formula (4), R ^{1 to} R ³ , R ^{4 to} R ⁶ and X are the same as those in the general formula (1), and R ¹⁰ and R ¹¹ are each independently It is hydrogen or an alkyl group. Examples of the alkyl group include alkyl groups having 1 to 4 carbon atoms such as a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, an isobutyl group, and a tert-butyl group. Is preferred. The alkyl group may have a substituent such as a halogen group, a hydroxyl group, an ester group, a carboxylic acid group, or a sulfonic acid group as long as the copolymerization reactivity and the like are not inhibited. Among them, R ¹ , R ² , R ³ , R ⁴ , R ⁵ , R ⁶ are hydrogen and R ¹⁰ , R ¹¹ are methyl groups in terms of easy availability and good copolymerizability -Dimethyl-4-vinyl-1,3-dioxolane is preferred.

Copolymerization and saponification of the vinyl ester monomer and the compound represented by the general formula (4) are performed in the same manner as in the method (i).
For deketalization, when the saponification reaction is performed using an alkali catalyst, an aqueous solvent (a mixed solvent of lower alcohol such as water, water / acetone, water / methanol, etc.) is further used after the saponification using an acid catalyst. Etc.) is deketalized and converted to a 1,2-diol structure. In this case, examples of the acid catalyst include acetic acid, hydrochloric acid, sulfuric acid, nitric acid, metasulfonic acid, zeolite, and cation exchange resin.
When the saponification reaction is carried out using an acid catalyst, saponification and deketalization are performed without any special treatment, and the saponification reaction is converted into a 1,2-diol structure.

  Furthermore, PVA which has a 1, 2- diol structural unit in a side chain can use what copolymerized the unsaturated monomer. The introduction amount of the unsaturated monomer cannot be generally specified, but if the introduction amount is too large, the water solubility may be impaired, which is not preferable.

  Examples of the unsaturated monomer include olefins such as ethylene, propylene, isobutylene, α-octene, α-dodecene, α-octadecene, acrylic acid, methacrylic acid, crotonic acid, maleic acid, maleic anhydride, itaconic acid, and the like. Unsaturated acids, their salts, monoesters or dialkyl esters, nitriles such as acrylonitrile and methacrylonitrile, amides such as diacetone acrylamide, acrylamide and methacrylamide, ethylene sulfonic acid, allyl sulfonic acid, methallyl sulfonic acid, etc. Olefin sulfonic acids or salts thereof, alkyl vinyl ethers, dimethylallyl vinyl ketone, N-vinyl pyrrolidone, vinyl compounds such as vinyl chloride, substituted vinyl acetates such as isopropenyl acetate and 1-methoxyvinyl acetate. Le ethers, vinylidene chloride, 1,4-diacetoxy-2-butene, vinylene carbonate, acetoacetyl group-containing monomers, and the like.

Furthermore, polyoxyethylene (meth) allyl ether, polyoxyethylene (meth) acrylamide, polyoxypropylene (meth) acrylamide, polyoxyethylene (meth) acrylate, polyoxypropylene (meth) acrylate, polyoxyethylene (1- ( Poly) alkylene groups such as (meth) acrylamide-1,1-dimethylpropyl) ester, polyoxyethylene vinyl ether, polyoxypropylene vinyl ether, polyoxyethylene allylamine, polyoxypropylene allylamine, polyoxyethylene vinylamine, polyoxypropylene vinylamine Containing monomer, N-acrylamidomethyltrimethylammonium chloride, N-acrylamidoethyltrimethylammonium chloride, N-acrylic Luamidopropyltrimethylammonium chloride, 2-acryloxyethyltrimethylammonium chloride, 2-methacryloxyethyltrimethylammonium chloride, 2-hydroxy-3-methacryloyloxypropyltrimethylammonium chloride, allyltrimethylammonium chloride, methallyltrimethylammonium chloride, 3 Examples thereof include cationic group-containing monomers such as butenetrimethylammonium chloride, dimethyldiallylammonium chloride, and diethyldiallylammonium chloride.
Moreover, it is possible to use what introduce | transduced about 1.6-3.5 mol% of 1, 2-diol bond in the PVA main chain by making superposition | polymerization temperature into 100 degreeC or more.

<< PVA pellet manufacturing method >>
The method for producing the PVA pellets of the present invention is carried out as follows using the powdery PVA.
As described above, the method for producing the PVA pellets of the present invention is as follows.
(1) a step of melt-extruding PVA to form a strand;
(2) After cooling the said strand, it is a manufacturing method of the pellet made from PVA provided with the process of cut | disconnecting a strand to a pellet form. The strand cooling process is conventionally performed by bringing the surface of the strand into contact with the cooled metal belt surface, spraying mist on the surface of the strand, and then spraying the strand with dry gas. There is no special cooling method.

  An example of the process for producing the PVA pellets of the present invention will be described step by step based on the process diagram shown in FIG. However, the process in the manufacturing method of the PVA pellets of the present invention is not limited to the process shown in FIG. 1 as long as the strand cooling process has the above characteristics.

<Melt extrusion process>
A powdery PVA is charged into the charging port 2 of the melt extruder 1 shown in FIG. 1, melt-kneaded, and extruded into one or a plurality of substantially rod-shaped strands 5. The diameter of the strand 5 extruded at this time is appropriately set according to the size of the hole of the mold attached to the extrusion port of the melt extruder 1, but is usually 0.5 to 4.0 mm, preferably 1 0.0-3.0 mm, particularly preferably 1.5-2.5 mm.

  The temperature condition for the melt kneading is preferably set to 250 ° C. or less, more preferably 150 to 240 ° C., and particularly preferably 180 to 230 ° C. If the melt kneading temperature is too high, the PVA will be thermally decomposed, making it difficult to extrude the desired strand 5.

  The melt extruder 1 is not particularly limited in appearance and the like, and even if it is a twin screw type, the bottom of the hopper is a biaxial screw, and thereafter, it is a single screw type toward the tip. Although an extruder referred to as a 5-axis may be used, a twin-screw type melt extruder is usually used.

  And as the said melt extruder 1, it is preferable to use the melt extruder by which the vent 3 (refer FIG. 1) was provided in the area | region before the input powdery PVA begins to melt | dissolve and completely melts. By providing the vent 3, the volatile component contained in the raw material PVA can be degassed outside the melt extruder 1, and the volatile component stays in the melt extruder 1, and serves as a back pressure on the hopper side. Thus, the strand 5 can be continuously extruded by maintaining a stable supply of the powder raw material and a uniform kneading state.

  Further, the number of the vents 3 is not limited as long as it is possible to degas the generated volatile components provided in the region after the PVA starts to melt and before the complete melting, and at least one of them is not limited. It is sufficient if it is provided, and preferably one. The shape of the mouth of the vent 3 is usually a circle, an ellipse, a triangle, a quadrangle, or a polygon such as a pentagon, and is preferably a circle or a quadrangle. The size (bore diameter) of the vent 3 is appropriately set depending on the amount of PVA that is a raw material, the size of the melt extruder 1, and the like. For example, in the case of a circular shape, the diameter is set to about 20 to 150 mm. . If the aperture is too large, the unmelted powder PVA material tends to be ejected, and if it is too small, the unmelted powder PVA material tends to be clogged.

  The volatile component in the PVA as the raw material is derived from a reaction product produced in the production process of PVA, or a residue of the raw material used in the production of PVA. For example, water, methyl alcohol, And methyl acetate. Content of the said volatile component is about 3 to 5 weight% normally in PVA which is a raw material.

  In addition to the vent 3 described above, the vent 4 may be provided after being completely melted, and the number thereof may be one or may be provided in a plurality of multiple stages of two or more.

<Strand cooling process>
In the strand cooling process of the present invention, as shown in FIG. 1, the melt-extruded strand 5 is placed on the surface of a water-cooled metal endless belt 6, and the strand 5 is driven by rotation of the metal endless belt 6. The lower side of the strand 5 is cooled by moving. At the same time, after spraying mist on the surface of the strand 5, spraying a dry gas removes latent heat of vaporization and efficiently cools the entire strand 5.

  As the water-cooled metal endless belt 6, a stainless steel belt employing a conventionally known water-cooled cooling method can be used. For example, in a state where no strand is placed, a shower or the like can be used. A water cooling method is preferably used. In the drawing, the cooling process using the metal endless belt 6 is provided in one place, but the present invention is not limited to this, and the cooling process using the metal endless belt 6 may be provided in two or more places in a continuous manner. Good.

  The surface temperature of the water-cooled metal endless belt 6 is preferably 2 to 80 ° C, more preferably 5 to 60 ° C, and particularly preferably 20 to 40 ° C. If the surface temperature is too high, it is difficult to cool the strand 5 in a short time and effectively.

  On the other hand, as a method for cooling the entire strand 5 by spraying mist on the surface of the strand 5, for example, as shown in FIG. In addition, a spraying device 7 for spraying mist is provided, mist is sprayed on the surface of the strand 5 to attach moisture to the surface of the strand 5, it evaporates with the heat of the strand, and cooling is performed by efficiently taking away latent heat of evaporation. How to do. When the apparatus 7 is used, the amount of water spray varies depending on the speed of the cooling belt, but is usually 0.5 to 9.6 L / hr, preferably 1.0 to 4.0 L / hr, particularly preferably 2. 0.0 to 3.0 L / hr.

Moreover, the average water droplet particle diameter of the water to spray is 0.1-30 micrometers normally, Preferably it is 0.5-20 micrometers, Most preferably, it is 1-10 micrometers. If the particle size is too large, the strands may get wet and the PVA may melt.
The mist as described above can be sprayed by using, for example, a two-fluid spray nozzle (for example, AKIJET manufactured by Ikeuchi Co., Ltd.) that sprays compressed air and water simultaneously.

Next, it is preferable to cool the surface of the strand 5 based on latent heat of vaporization by injecting a dry gas 8 onto the strand 5 that has passed through the cooling step. Examples of the dry gas 8 include air and inert gas (for example, nitrogen gas, carbon dioxide gas, etc.). Preferably, an air cooling system by injecting air is employed. The gas volume of the drying gas 8, typically, 5 to 50 m ³ / min, preferably 10 to 40 m ³ / min, particularly preferably 20 to 30 m ³ / min. Moreover, as temperature of the dry gas 8 to be used, it is 5-40 degreeC normally, Preferably it is 10-30 degreeC, Most preferably, it is 15-25 degreeC.

  In the strand cooling step, the cooling distance is usually 4 to 20 m, preferably 6 to 15 m, particularly preferably 8 to 10 m. If the distance is too short, the cooling tends to be insufficient, and the strand tends to be unable to be cut with a pelletizer. If it is too long, the workability during production tends to deteriorate.

Temperature of the strands 5 consisting via the cooling step and the drying gas injection step is 3 5 to 95 ° C., particularly preferably from 60 to 90 ° C.. If the temperature of the strand 5 is too high, it is difficult to cut the strand 5 in the next step and efficiently pelletize it. Specifically, if the temperature of the strand 5 is too high, it becomes difficult to obtain a pellet having a uniform cut surface because the strand 5 is too soft when cut into pellets in the next step. On the other hand, if the temperature of the strand 5 is too low, the strand 5 is too hard and fine powder is generated at the time of cutting or there is a tendency for defects to occur on the cut surface.

Further, the water content of the strand 5 formed through the cooling step and the dry gas injection step is 0 . It is less than 1% by weight, more preferably 0.08% by weight or less, and particularly preferably 0.05% by weight or less. Usually, the lower limit of the water content is 0.02% by weight. When the water content is too large, it is difficult to obtain pellets having a uniform cut surface because the strands 5 are too soft when the strands 5 are cut into pellets.

<Strand cutting (pelletizing) process>
By supplying the strand 5 cooled by the said process to the cutting device 9 for cut | disconnecting in a pellet form, the strand 5 is cut and formed into a pellet form (pelletizing process). Examples of the cutting device 9 include a device that continuously cuts the strand 5 into a pellet shape with a rotary blade, such as a pelletizer. And in this cutting | disconnection, in order to suppress the temperature rise of the strand 5 resulting from the frictional heat at the time of a cutting | disconnection, and to cool to an appropriate temperature, the cooling gas 10 is supplied to a cutting part. Examples of the cooling gas 10 include air and inert gas (for example, nitrogen gas, carbon dioxide gas, etc.), for example, as in the case of the dry gas described above. Preferably, an air cooling method by injecting air is employed. The The supply gas amount of the cooling gas 10 is usually 150 to 1200 NL / min, preferably 300 to 1000 NL / min, and particularly preferably 500 to 800 NL / min. Further, the temperature of the cooling gas 10 to be supplied is usually 5 to 30 ° C, preferably 8 to 20 ° C, and particularly preferably 10 to 15 ° C.

<Pellet cooling process>
The PVA pellets cut and formed by going through the strand cutting (pelletizing) step (hereinafter sometimes simply referred to as “pellet”) 11 are subjected to a pellet cooling step in order to fix the pelletized shape. It is preferable to pass through. As the pellet cooling step, for example, as shown in FIG. 1, the pellet 11 cut and formed in the pellet cooling device 14 is placed on the metal mesh 12 and moved in the direction of the arrow while moving the metal mesh 12. The mode of vibrating itself is preferable from the viewpoint of preventing adhesion of the pellet 11 to the surface of the metal net 12 and effective cooling. In addition, as a cooling method, the cooling gas 13 is supplied to the pellet 11 through the metal mesh 12 from below the metal mesh 12, and the cooling gas 13 is circulated outside the device from above the pellet cooling device 14. Accordingly, it is preferable from the viewpoint of cooling the pellet 11 that the cooling gas 13 is not retained in the pellet cooling device 14. Examples of the cooling gas 13 include air and an inert gas (for example, nitrogen gas, carbon dioxide gas, etc.), for example, similar to the above-mentioned dry gas, and preferably air. The gas volume of the cooling gas 13, typically, 5~60m ³ / min, preferably 20 to 50 m ³ / min, particularly preferably 30 to 40 m ³ / min. Moreover, as cooling gas 13 temperature to supply, it is 5-35 degreeC normally, Preferably it is 10-30 degreeC, Most preferably, it is 15-25 degreeC.

  The pellet 11 cooled via the pellet cooling device 14 is preferably, for example, less than 35 ° C., more preferably 10 to 30 ° C., and particularly preferably 20 to 25 ° C. If the temperature of the cooled pellet 11 is too high, it is difficult to efficiently classify the pellet 11 in the next step, and the accuracy of classification tends to be reduced.

<Classification process>
The cooled pellets 11 are usually sorted into a desired shape and size through a classification process. In this way, a pellet 11 as a final product is obtained.

  The finally obtained pellet 11 is generally a substantially cylindrical shape. Moreover, although the magnitude | size of the pellet 11 is suitably set according to a use etc., it is 0.5-4 mm in diameter normally, Preferably it is 1-3 mm, Most preferably, it is 1.5-2.5 mm, and the pellet 11 The length is usually 0.5 to 4 mm, preferably 1 to 3 mm, particularly preferably 1.5 to 2.5 mm.

  PVA pellets obtained by the method for producing PVA pellets of the present invention are used for various molding materials, but have not been industrially produced as PVA pellets. Injection molding, extrusion molding, film molding (inflation film / T-die cast film), profile molding, melt coating, blow molding, melt spinning, nonwoven fabric molding (spunbond, meltblown), etc. that could not be used as material applications Used for various molding materials.

  EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited to the following examples unless it exceeds the gist. In the examples, “parts” and “%” mean weight basis unless otherwise specified.

[Example 1]
<Manufacture of PVA>
In a reaction vessel equipped with a reflux condenser and a stirrer, 76.6 parts of vinyl acetate (initial charge rate is 40%), 14.2 parts of methanol, 9.2 parts of 3,4-diacetoxy-1-butene (initial stage) The charging rate is 40%), azobisisobutyronitrile is added (0.068 mol% of vinyl acetate charged), and the temperature is raised under a nitrogen stream while stirring, and vinyl acetate and 3,4-diacetoxy are added. Polymerization was started while dropwise addition of -1-butene at a constant rate of 13.5 hours. When the polymerization rate of vinyl acetate reached 91%, m-dinitrobenzene was added to complete the polymerization, and then unreacted vinyl acetate monomer was removed from the system by blowing methanol vapor. A combined methanol solution was obtained.

  Next, the methanol solution was further diluted with methanol, adjusted to a concentration of 50%, charged into a kneader, and a 2% methanol solution of sodium hydroxide was added to the vinyl acetate structural unit in the copolymer while maintaining the solution temperature at 35 ° C. Further, saponification was performed by adding 4.5 mmol with respect to 1 mol of the total amount of 3,4-diacetoxy-1-butene structural units. As saponification progressed, when saponified substances were precipitated and formed into particles, they were separated by filtration, washed well with methanol, and dried in a hot air dryer to prepare the target PVA.

The saponification degree of the obtained PVA was 87 mol% when analyzed by the alkali consumption required for hydrolysis of residual vinyl acetate and 3,4-diacetoxy-1-butene. The average degree of polymerization was 470 when analyzed according to JIS K 6726. The content of the 1,2-diol structural unit in the side chain is calculated from the integral value measured by ¹ H-NMR (300 MHz proton NMR, d6-DMSO solution, internal standard substance: tetramethylsilane, 50 ° C.). As a result, it was 6 mol%.

<Melt extrusion process>
The powdery 1,2-diol PVA obtained above is introduced into the inlet 2 of a melt extruder (Twin screw type: TEM-58BS manufactured by Toshiba Machine Co., Ltd.), melt-kneaded, and a single substantially rod-like shape. The strand 5 (diameter 58 mm) was extruded under the following conditions.
Diameter (D) 58mm, L / D = 45
Screw rotation speed: 150rpm
Set temperature: C1 / C2 / C3 / C4 / C5 / C6 / C7 / C8 / A / D = 90/120/150/180/200/205/210/210/210/210 ° C.
Screw pattern: 2 kneaded screws Screen mesh: 90/120/90 mesh
Discharge rate: 200kg / hr
Vent 3 position: C4 (caliber 100mm)
Vent 4 position: C8 (caliber 100mm)
The temperature condition for the melt kneading was 230 ° C.

<Strand cooling process>
The melt-extruded strand 5 of about 230 ° C. was placed on the surface of a water-cooled stainless steel belt 6, and the strand 5 was moved by the rotational driving of the stainless steel belt 6, thereby cooling the lower side of the strand 5. At the same time, as shown in FIG. 1, a spraying device 7 (AKIJET AKIJET nozzle manufactured by Ikeuchi Co., Ltd.) for spraying water is provided above the strand 5 that is moved by the rotational driving of the stainless steel belt 6. Then, water was adhered to the surface of the strand 5 to cool the entire strand 5. The surface temperature of the water-cooled stainless steel belt 6 was 21 ° C. Further, when the spray device 7 was used, the water spray amount was 3 L / hr.

Next, the surface of the strand 5 was cooled by injecting air as the dry gas 8 to the strand 5 that passed through the cooling step. The gas amount of the dry gas 8 was set to 30 m ³ / min, and the temperature of the dry gas 8 was set to 20 ° C.
The cooling distance of all steps of the strand cooling step was 10 m.

  The temperature of the strand 5 which passed through the said cooling process and dry gas injection process was 93 degreeC. Moreover, the moisture content of the strand 5 which passed through the said cooling process and dry gas injection process was 0.05%. The temperature of the strand 5 was measured using a non-contact type laser thermometer. On the other hand, the water content of the strand 5 was measured with a Karl Fischer moisture meter.

<Strand cutting (pelletizing) process>
In order to cut the strand 5 having a water content of 0.05% at 93 ° C. cooled by the above process into pellets, the strand 5 is supplied to pelletizer 9 (TSL-450 type manufactured by Tanaka Co., Ltd.) and cut into pellets. (Pelletizing step). At the same time, when cutting into the pellets, air was injected and supplied as a cooling gas 10 to the cut portion. The supply amount of the cooling gas (air) 10 was set to 800 Nl / min, and the temperature of the supplied cooling gas 10 was set to 10 ° C.

<Pellet cooling process>
Next, the pellet 11 formed by going through the strand cutting (pelletizing) step was passed through the pellet cooling step. In the pellet cooling step, as shown in FIG. 1, the pellet 11 cut and molded in a pellet cooling device (Mistral ASC type manufactured by Tanaka) 14 is placed on a stainless steel mesh 12, and the stainless steel mesh 12 itself. The pellet 11 was sequentially moved in the direction of the arrow while vibrating. In addition, the cooling gas 13 is supplied from below the stainless steel mesh 12 through the stainless steel mesh 12 and supplied to the pellet 11, and the cooling gas 13 is supplied from above the pellet cooling device 14 to the outside of the device so that the cooling gas 13 is not retained. 13 was distributed. The cooling gas 13 was normal air, the gas amount of the cooling gas 13 was set to 30 m ³ / min, and the temperature of the cooling gas 13 to be supplied was set to 15 ° C.

  The temperature of the pellet 11 cooled via the pellet cooling device 14 was 23 ° C. The temperature of the pellet 11 was measured using a non-contact laser thermometer as described above.

<Classification process>
Next, the cooled pellets 11 were classified using a vibration type pellet sorter (PSL-300A manufactured by Tanaka). The finally obtained pellet 11 was substantially cylindrical, and the size was 2.0 mm diameter × 2.0 mm length.

<Production speed>
The production rate of the pellet 11 was measured as follows. That is, the weight of the pellet which comes out within a fixed time from the pellet sorter was measured and confirmed to be 200 kg / hr.

[Example 2]
In Example 1, pellets were produced in the same manner as in Example 1 except that the cooling distance of the strand 5 was changed to 5 m. The obtained pellet 11 was substantially cylindrical, and the size was 2.0 mm diameter × 2.0 mm thickness.
When the production rate was measured in the same manner as in Example 1, it was 50 kg / hr.

[Comparative Example 1]
In Example 1, the strand 5 that was extruded without passing through the strand 5 cooling step was directly subjected to a strand cutting (pelletizing) step. Otherwise, the production of pellets was attempted in the same manner as in Example 1. However, since the melted strand has no tension at all without cooling, it cannot be conveyed to the pelletizer and cannot be pelletized.

[Comparative Example 2]
The strand 5 cooling process performed in Example 1 was changed as follows. That is, a cooling method of immersing in a water bath was adopted. As a result, when the molten strand enters the water bath, it is cooled rapidly, but the surface dissolves in water and exhibits strong adhesiveness. The strands adhere to each other, and the strands adhere to the devices. Ran out of control at a constant speed and quantitatively. Therefore, pelletization was impossible at all.

  As is clear from the above results, in the examples, the desired PVA pellets could be efficiently manufactured through the manufacturing process of the PVA pellets. On the other hand, in the manufacturing method of the PVA pellets described in Comparative Examples 1 and 2, the above-mentioned problems occurred, so that the PVA pellets could not be manufactured.

  PVA pellets obtained by the PVA pellet manufacturing method of the present invention include, for example, extrusion molding, injection molding, film molding (inflation film / T-die cast film), profile molding, melt coating, blow molding, melt spinning, and nonwoven fabric molding. (Spunbond, meltblown) and the like can be used for molding material applications.

DESCRIPTION OF SYMBOLS 1 Melt extruder 3 Vent 5 Strand 6 Metal endless belt 7 Spraying device 9 Cutting device 11 PVA pellet (pellet)
12 Metal mesh 14 Pellet cooling device

Claims (3)

A method for producing a polyvinyl alcohol-based resin pellet comprising a step of melt-extruding a polyvinyl alcohol-based resin to form a strand, and a step of cooling the strand and then cutting the strand into a pellet, wherein the strand is cooled step, the lower surface of the strand, together with itself into contact with the cooled metal belt surface, after spraying the mist to the strand surface, is to be injected dry gas into strands, pellets the strands The method of producing pellets made of polyvinyl alcohol resin, characterized in that the step of cutting into a shape is performed under the condition that the strand temperature is 35 to 95 ° C. and the water content is less than 0.1% by weight . The step of melt-extruding the polyvinyl alcohol-based resin to form a strand is performed by adding a powdered polyvinyl alcohol-based resin to a melt extruder to extrude the strand, and the charged polyvinyl alcohol-based resin is completely melted claim 1 Symbol placement of polyvinyl alcohol production method of the resin pellets is carried out using a melt extruder pre vent is formed in front of the area to be. A step of feeding a powdery polyvinyl alcohol resin into the following melt extruder (x) to extrude the strand, and bringing the lower surface of the strand into contact with the cooled metal belt surface itself In addition, after exposing the strand surface to an aqueous atmosphere, the step of cooling the strand to 95 ° C. or less by spraying a cooling gas onto the strand, and the temperature of the strand at 35 to 95 ° C. The pellet made of polyvinyl alcohol resin according to claim 1, comprising a step of cutting into pellets when the water content is less than 0.1% by weight, and a step of cooling the pellets to 35 ° C. or less with a cooling gas. The manufacturing method.
[(X) A melt extruder in which a preliminary vent is formed in a region before the charged polyvinyl alcohol resin is completely melted. ]

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