JP6310047B1 - Nano bubble generator - Google Patents

Abstract

PROBLEM TO BE SOLVED: To efficiently generate fine bubbles. A cylindrical outer cylinder having first and second bottom surfaces according to the present invention, an inner cylinder having a smaller diameter than the outer cylinder, and the first. A supply port formed in the vicinity of the second bottom surface or in the vicinity of the second bottom surface. A cylindrical portion having a first cylindrical portion to which the medium liquid is supplied, a third bottom surface and a fourth bottom surface, and the third bottom surface is opposed to the second bottom surface. An intermediate hole having a smaller area than the supply port is formed in the third bottom surface, and a second cylinder having a discharge port having a larger area than the intermediate hole in the fourth bottom surface or in the vicinity of the fourth bottom surface. Part. [Selection] FIG.

Description

  2. Description of the Related Art Conventionally, as a fine bubble generating device, a technique in which bubbles are included in a liquid by rotating a liquid mixed with a gas at high speed is widely known (see, for example, Patent Document 1).

Japanese Patent No. 4556396

  In the fine bubble generating apparatus having such a configuration, there has been a demand for generating fine bubbles more efficiently.

  The present invention has been made to solve such problems, and an object thereof is to provide a nanobubble generator capable of efficiently generating fine bubbles.

In order to solve such a problem, the nanobubble generator of the present invention,
A swirling unit that generates fine bubbles by a high-speed swirling method that swirls a medium liquid containing a mixed gas ;
A pressure release chamber to release pressure,
Provided in an intermediate flange part separating the swivel part and the pressure release chamber, and having a connection hole for connecting the swivel part and the pressure release chamber;
The swivel part is
A cylindrical outer cylinder having first and second planes , an inner cylinder having a smaller diameter than the outer cylinder, and a medium between the outer cylinder and the inner cylinder in the vicinity of the first plane and a space in which a gap portion to make the flow of liquid, a first cylindrical portion to which the liquid medium from the second plane or the second supply port formed in a plane near supplied, the The medium liquid supplied from the supply port to the outer cylinder part advances from the gap part toward the inner cylinder part toward the first plane while turning, and moves toward the second plane while turning the inner cylinder part. And proceed from the connection hole to the pressure release chamber,
The pressure release chamber is
Third becomes a cylindrical shape having a plane and a fourth plane, said relative second plane third plane are connected so as to face, in the fourth plane and the fourth plane near the A second cylindrical portion having a discharge port;
The connection hole is
A hole having a smaller area than the supply port formed in the third plane ;
The outlet is
The area is larger than the connection hole,
The intermediate flange portion is
The second plane and the third plane are configured, the supply port and the connection hole are formed, and a mortar-shaped recess is formed at the center of the second plane ,
The connection hole is
It was made to be provided at the center of the recess.

The present invention can realize a nanobubble generator that can efficiently generate fine bubbles.

It is a basic diagram which shows the structure of an electrolytic bubble water production | generation apparatus. It is a basic diagram which shows the structure of a gas-liquid delivery part. It is an approximate line figure used for explanation of a supply course. It is a flowchart with which it uses for description of bubble electrolyzed water production | generation processing. Outline diagram showing configuration of electrolysis section (1) It is a basic diagram which shows the structure (2) of an electrolysis part. It is a basic diagram with which it uses for description of the flow in an electrolyzed water production | generation process. It is an approximate line figure used for explanation of a flow in exchange processing. It is a basic diagram with which it uses for description of the flow in a washing process. It is a basic diagram with which it uses for description of a pressure adjustment mechanism. It is a basic diagram which shows the concept of the nanobubble generator of this invention. It is a basic diagram which shows the perspective view of a nano bubble production | generation part. It is a basic diagram which shows the disassembled perspective view of a nano bubble production | generation part. It is a basic diagram which shows the cross section of the center vicinity of a nano bubble production | generation part. It is a basic diagram which shows the structure of a flange surface. It is a basic diagram which shows the structure of the nano bubble production | generation part (1) by other embodiment. It is a basic diagram which shows the structure of the nano bubble production | generation part (2) by other embodiment. It is a basic diagram which shows the structure of the nano bubble production | generation part (3) by other embodiment.

  Next, modes for carrying out the present invention will be described with reference to the drawings.

<Configuration of electrolytic bubble water generator>
Next, an embodiment will be described with reference to FIGS. In FIG. 1, reference numeral 10 denotes an electrolytic bubble water generator as a whole. In the electrolyzed bubble water generating apparatus 10, electrolyzed bubble water that is electrolyzed water containing nanobubbles is generated using electrolyzed water generated by electrolysis as a medium liquid.

  In the electrolyzed bubble water generating device 10, both alkaline electrolyzed water and acidic electrolyzed water are generated by electrolysis, and the alkaline electrolyzed water is circulated and concentrated, while the acidic electrolyzed water contains nanobubbles, and the electrolyzed water is used as electrolyzed water. It is made to supply from the provision part 18. FIG.

  Although not shown, the electrolyzed bubble water generating apparatus 10 includes a control unit 20 (not shown) including an MPU (Micro Processing Unit), a ROM (Read Only Memory), and a RAM (Random Access Memory) (not shown). The entire water generator 10 is controlled in an integrated manner.

  In the electrolyzed bubble water generating device 10, the generated gas and the electrolyzed water generated by the electrolysis unit 13 are sent as they are to the gas-liquid delivery unit 15, the pump 16, and the nanobubble generation unit 17, thereby generating bubble electrolysis containing the generated gas as nanobubbles. Produce water. At this time, the entire system (electrolysis unit 13 to nanobubble generation unit 17) is a closed system, and the generated gas and electrolyzed water are mixed as they are without separation under a predetermined pressure, thereby efficiently generating the components of the generated gas. It can be dissolved and nanobubbled.

  The raw water supply unit 11 supplies the raw water to the electrolysis unit 13 only when electrolytic water is generated by the opening / closing control of the opening / closing mechanism by the control unit 20. The raw water supply unit 11 supplies raw water to the electrolysis unit 13 in a state where pressure is applied. Further, when the water pressure of the connected tap water or the like is too high, a pressure reducing mechanism such as a pressure reducing valve may be configured.

  Various raw materials such as tap water, electrolytic water, pure water, and purified water can be used as raw water. Moreover, you may use the water which removed unnecessary components, such as an impurity, by installing various filters in the front | former stage.

  The gas (mixed gas) to be contained as nanobubbles is not particularly limited and is appropriately selected depending on the application. For example, air, hydrogen, oxygen, carbon dioxide and the like are preferable.

  The electrolyte supply unit 12 supplies the electrolytic aqueous solution to the electrolysis unit 13 under the control of the control unit 20. It does not restrict | limit especially as electrolyte, The known compound which melt | dissolves in water, such as sodium chloride, sodium carbonate, sodium hydrogencarbonate, hydrochloric acid, potassium chloride, calcium chloride, and shows the characteristic as an electrolyte can be used suitably. In particular, an electrolyte capable of generating electrolyzed water of strong acidity (pH 4.0 or less) and strongly alkaline (pH 10.0 or more) by electrolysis is preferably used. For convenience, the case where sodium chloride is used as the electrolyte will be described, but the present invention is not limited thereto.

  The electrolyzer 13 may be configured to electrolyze raw water to generate electrolyzed water, and a two-tank electrolytic cell having an anode chamber 51 having an anode and a cathode chamber 52 having a cathode is used. The electrolysis unit 13 has a configuration in which acidic electrolyzed water is supplied to the gas-liquid delivery unit 15 while alkaline electrolyzed water is returned to the electrolyte supply unit 12 and circulated. The detailed configuration of the electrolysis unit 13 will be described later.

  The gas-liquid delivery unit 15 mixes the generated gas and the electrolyzed water by high-speed agitation or rotates the gas at high speed to bring the generated gas and the electrolyzed water into contact with each other for a certain period of time. Are sent to the pump 16 at a substantially equal rate so that there is no bias. In addition, in the mixing by the gas-liquid delivery unit 15, the generation amount of nanobubbles is hardly or very small (less than 10% in terms of the number ratio as compared with the nanobubble generation unit 17).

  An example of the configuration of the gas-liquid delivery unit 15 is shown in FIGS. As shown in FIG. 2, the gas-liquid delivery unit 15 is sandwiched between plate members 71 and 72 having a rectangular shape on the upper side of a cylindrical member 70 and a plate member 73 having a lower rectangular shape. It has a shape.

  The plate-shaped members 71 to 73 constitute a bottom surface of the cylindrical member 70 and have a supply path for supplying electrolytic water and mixed gas to the cylindrical member 70. As shown in FIG. 3, the electrolyzed water (including the generated gas) is supplied to the cylindrical member 70 via supply paths 71 a to 71 d formed in the plate-like member 71. Further, supply paths 72a and 72b are formed in the plate-like member 72, and when a part of the bubble electrolyzed water generated by the nanobubble generating unit 17 overflows, it is supplied to the cylindrical member 70 via the pipe 17B. .

  The supply paths 71 a to 71 d and 72 to 72 b are provided substantially parallel (± 30 °) in the tangential direction with respect to the cylindrical member 70, and the flowing electrolytic water (electrolyzed water and bubble electrolytic water) flows into the cylindrical member 70. It is formed so as to circulate along the inner surface.

  In addition, a discharge path 73a that is a hole for discharging mixed water in which electrolyzed water and mixed gas (generated gas) are mixed is provided at the central portion of the plate-like member 73, and the mixed water passes through the pipe 15A. Discharged. Inside the pipe 15A, a low-speed swirling flow is generated, and it is considered that the electrolyzed water and the mixed gas are stirred up to the pump 16, and the formation of a large gas reservoir can be suppressed.

  As a result, the electrolyzed water and the mixed gas are mixed while being stirred at a high speed by the vertical force supplied from the upper side and discharged from the lower side, and the positional relationship between the electrolyzed water supplied along the cylindrical member 70 and the discharge path 73a. The inside of the member 70 is swung, and the mixed gas is supplied to the pump 16 via the pipe 15A in a state where the mixed gas is well mixed with each other.

  In this gas-liquid delivery unit 15, a large pressure is generated by, for example, a centrifugal effect by high-speed rotation, and the generated gas and the electrolyzed water are brought into contact with each other at the interface between the gas phase and the liquid layer under a large pressure, and particularly dissolved in water such as chlorine gas. In addition to facilitating the dissolution of highly gas, it also serves to prevent the influence of the pressure generated by the pump 16 from being transmitted to the electrolysis unit 13. In other words, the gas-liquid delivery unit 15 can cut off the transmission of pressure between the electrolysis unit 13, the gas-liquid delivery unit 15, and the pump 16 by high-speed turning.

  In addition, the pressure in the front | former stage (piping 14A and 15A) of the gas-liquid delivery part 15 is controlled so that it may become -15 kpa-+15 kpa, for example, More preferably, -10 kpa-+10 kpa. Thereby, it can suppress that a pressure is loaded with respect to the electrolysis part 13 of a front | former stage, and can prevent damage to the diaphragm 45 etc. beforehand. This control is performed by adjusting a solenoid valve provided in the pipe 17B. As a result of adjustment, if the pressure does not fall within the above pressure range, an emergency stop is performed to protect the device.

  The gas supply unit 14 supplies a mixed gas to be supplied to the gas-liquid delivery unit 15. For example, when air is mixed as a mixed gas, an air pump or compressed air is used as the gas supply unit 14. This gas supply part 14 is for supplementing the amount of gas that is insufficient with the generated gas, and is not necessarily essential. It is also possible to use only the generated gas as the mixed gas. In this embodiment, the chlorine gas contained in the generated gas is dissolved in the electrolyzed water at a high rate without being diluted. Therefore, the mixed gas is mixed in the pump 16 instead of the gas-liquid delivery unit 15. A mixed gas may be supplied to the unit 15. In this case, it is preferable that the mixed gas can be mixed at the center of the vortex by mixing the mixed gas from the upper surfaces of the plate-like members 71 and 72 and the vicinity of the center.

  The pump 16 (FIG. 2) is not particularly limited, and various known pumps can be used. For example, it is preferable to use a bubbling pump (for example, a SUS general-purpose vortex turbine pump 20NPD07Z (manufactured by Nikuni Co., Ltd.)) that rotates with blades because gas-liquid mixing proceeds before the nanobubble generator 17. The pump 16 applies pressure to the mixed water supplied via the pipe 15A, and supplies the mixed water to the nanobubble generating unit 17 via the pipe 16A at a fixed amount of, for example, 20 L / min. At this time, due to the effect of the gas-liquid delivery unit 15, there is almost no large gas reservoir in the mixed water, and the pump 16 is less likely to malfunction due to gas biting, and the mixed water is supplied to the nanobubble generating unit 17 at a stable flow rate. Can do.

  The nanobubble generating unit 17 is a high-speed swirling nanobubble generator in which medium bubbles (mixed water) are made to contain nanobubbles (fine bubbles) made of gas by high-speed swirling, and the configuration thereof is not limited. Although not shown, the nanobubble generator 17 has a configuration in which the angle is changed by a collision, for example, while turning inside a plurality of cylindrical members.

  The nano-bubble generating unit 17 creates a gas-liquid interface due to a difference in specific gravity in a state where the gas and the medium liquid are swirled to generate a velocity, and generates nano-bubbles by gas-liquid friction generated at the interface. Further, the nanobubble generation unit 17 collides the medium liquid with the wall surface and changes the traveling direction thereof, thereby disturbing the flow of the medium liquid and vigorously stirring and mixing the gas and the medium liquid. As a result, the bubbles become fine due to the physical collision action between the gas and the medium liquid, and more nanobubbles are formed.

  The nanobubble generator 17 rapidly changes the traveling direction of the medium liquid while rotating the medium liquid at high speed. Thereby, the nano bubble production | generation part 17 can apply a bigger acceleration with respect to a medium liquid, and can disperse | distribute a bubble and make it fine by the physical collision effect | action of gas and a medium liquid. It is preferable that the nanobubble generator 17 changes the turning direction of the medium liquid at a steep angle of 80 ° or more by causing the medium liquid that rotates at high speed to collide with the wall surface.

  The nanobubble generating unit 17 supplies the electrolytic bubble water in which the nanobubbles are generated by high-speed rotation under a predetermined pressure to the electrolytic bubble water providing unit 18. The electrolyzed bubble water providing unit 18 has an opening / closing mechanism, and opens / closes the opening / closing mechanism under the control of the control unit 20.

  According to Henry's Law, the solubility of a gas improves when the pressure applied to the liquid is large. Therefore, it is known that when a pressure is applied to a liquid in the presence of gas and the pressure is rapidly decreased, the dissolved gas becomes fine bubbles in the liquid.

  When the electrolyzed bubble water providing unit 18 supplies the bubble electrolyzed water to the user in a faucet manner, the pressure is released at the moment when the electrolyzed bubble water is discharged from the faucet. In addition, when a cleaning device or the like installed in the subsequent stage is connected, a pipe (not shown) is connected to the electrolytic bubble water providing unit 18, and the pressure is increased in the subsequent cleaning device or the storage tank. Is released to the atmospheric pressure all at once, a pressure release part (not shown) is provided outside the electrolytic bubble water generator 10. At this time, a part of the gas dissolved in the electrolytic bubble water becomes nanobubbles, and the nanobubbles in the electrolytic bubble water can be increased.

  As described above, in the electrolyzed bubble water generating apparatus 10, the gas-liquid delivery unit 15 is provided before the nanobubble generating unit 17, and the contact time between the mixed gas and the electrolyzed water is set longer by using the transmission path of the pump 16. I made it. As a result, the mixed gas can be adapted to the electrolyzed water, the bubbles can be easily reduced, and the generation of nanobubbles by the nanobubble generating unit 17 can be increased, and the solubility of the mixed gas in the electrolyzed water is improved and generated when the pressure is released. Nanobubbles that are generated can be increased.

  Further, when chlorine gas is generated as a part of the generated gas (that is, chlorine is contained in the electrolyte), chlorine having high solubility in water is preferentially dissolved in the electrolyzed water due to the gas dissolution characteristics. This phenomenon becomes more prominent as the contact time between the gas and the liquid is longer. Therefore, in the mixed water supplied to the nanobubble generator 17, the mixed gas and oxygen gas (including ozone gas) remain as gases, but most of the chlorine gas is dissolved in the mixed water.

  When mixed water is supplied to the nanobubble generating unit 17 in this state, chlorine gas is hardly contained in the nanobubbles generated by the high-speed swirling method. Of course, some of the chlorine is thought to be nanobubbled when the pressure is released, but because of the high solubility, other gases are preferentially nanobubbled, so much of the chlorine may exist in a state of being dissolved in the electrolytic bubble water. it can.

  When electrolytic water is used as a sterilizing / disinfecting agent, the concentration of dissolved chlorine is very important. In the electrolytic bubble water generating device 10, when generating chlorine gas as a part of the generated gas, it is possible to make most of the chlorine components generated by electrolysis exist in a state dissolved in the electrolytic bubble water. The chlorine concentration can be improved, and the effect of sterilization and sterilization can be enhanced.

  That is, as shown in FIG. 4, in the bubble electrolyzed water generation process RT1 of the present invention, raw water is pressurized and supplied in step SP101, and electrolyzed water is generated by electrolyzing the raw water in step SP102.

  In step SP103, the electrolyzed water and the generated gas are conveyed, and in step SP104, the electrolyzed water and the generated gas are mixed by high-speed stirring to generate mixed water. In step SP105, the mixed water is pumped through a pump, and in step SP106, nanobubbles are generated by a high-speed swirling method.

  In step SP107, the pressure is released, and nanobubbles are generated by the pressure release method.

  In this way, nano bubbles are generated by the high-speed swirling method under pressure using a sealed system between step SP101 and step SP106, and then the nano bubbles are generated by the pressure release method, and electrolyzed water and generated gas (and mixed gas). Therefore, it is possible to further increase the nanobubbles.

<Configuration of electrolysis unit>
Next, the configuration of the electrolysis unit 13 will be described.

  As shown in the sectional view of FIG. 5, a two-cell type electrolytic cell in which a diaphragm 45 is provided between a water-permeable cathode 44 and an anode 43 can be used. In the electrolysis unit 13, raw water is supplied to the anode chamber 51 and an aqueous electrolyte solution is supplied to the cathode chamber 52, thereby allowing the electrolyte (anion) to move from the cathode chamber 52 to the anode chamber 51 through the diaphragm 45. Thus, the electrolysis is performed.

  Here, in the electrolysis part 13, the space | interval of the cathode 44, the diaphragm 45, and the anode 43 is adjusted so that electrolysis efficiency may be in the state close | similar to the highest. Specifically, the gap between the cathode 44 and the diaphragm 45 is 1.0 to 3.0 cm, more preferably 1.5 to 2.0 cm, and the gap between the anode 43 and the diaphragm 45 is 0.01 to 1.0 cm. More preferably, it is set to 0.01 to 0.5 cm.

  If the distance between the anode 43 and the diaphragm 45 is small, the diaphragm 45 may come into contact with the anode 43 to cause damage to the diaphragm 45 or the electrolytic efficiency may be reduced. If the distance between the anode 43 and the diaphragm 45 is large, There is a possibility that the attractive force of the anode 43 to the electrolyte is insufficient, and a sufficient amount of electrolyte is not supplied to the anode chamber 51, resulting in a decrease in electrolysis efficiency. Therefore, it is preferable to maintain the distance between the electrode (anode 43) and the diaphragm 45 within a designed fixed range.

  Further, when the pressure in the anode chamber 51 is higher than that in the cathode chamber 52, the electrolyte is less likely to move to the anode chamber 51 due to the pressure difference, and the electrolysis efficiency may be reduced. For this reason as well, it is required that the distance between the electrode (anode 43) and the diaphragm 45 be maintained within a designed fixed range.

  In addition, when providing electrodes (anode 43 and cathode 44) on the entire surface of the electrolytic cell, it is preferable to provide holes in the electrodes and pass raw water or an aqueous electrolyte solution between the electrodes. There is no limitation on the size and ratio of the holes, but in order to prevent the diaphragm from extending due to the pressure difference, the size of the holes is as small as possible (for example, a diameter of 1 cm or less, more preferably 0.7 cm or less). It is preferable to use a circular shape where no stress is applied to the location. Further, by utilizing the thickness of the cathode 44, the shape of the hole may be a mortar shape with a diameter increasing toward the anode chamber 51, or the corner may be rounded so that stress is not easily applied to a specific portion of the diaphragm. preferable.

  As shown in FIGS. 5 and 6, in the electrolysis unit 13, a first raw water supply port 41 through which raw water is supplied to the anode chamber 51 is provided near the bottom surface of the electrolytic cell. Moreover, the acidic electrolyzed water discharge port 48 for discharging acidic electrolyzed water is provided on the top surface of the electrolytic cell. The top surface of the electrolytic cell refers to the top surface of the inner surface of the anode chamber 51. The same applies hereinafter.

  For this reason, raw | natural water advances toward the top from the bottom, and is discharged | emitted from the acidic electrolyzed water discharge port 48 of the upper part as acidic electrolyzed water. At this time, the generated gas generated by electrolysis moves upward by buoyancy and is efficiently discharged from the acidic electrolyzed water discharge port 48.

  Accordingly, the acidic electrolyzed water discharged from the electrolysis unit 13 includes a generated gas (chlorine gas and oxygen gas). The electrolysis unit 13 supplies the generated generated gas and electrolyzed water to the gas-liquid delivery unit 15 via the pipe 13A.

  On the other hand, an electrolyte supply port 42 to which an aqueous electrolyte solution in which an electrolyte (sodium chloride) is dissolved is supplied to the anode chamber 51 is provided near the bottom surface of the electrolytic cell. Further, an alkaline electrolyzed water discharge port 49 for discharging alkaline electrolyzed water is provided on the top surface of the electrolytic cell.

  For this reason, the aqueous electrolyte solution proceeds from bottom to top and is discharged from the alkaline electrolyzed water discharge port 49. At this time, the generated gas generated by electrolysis moves upward due to buoyancy and is efficiently discharged from the alkaline electrolyzed water outlet 49.

  As shown in FIG. 7, a circulation tank 63 is connected to the alkaline electrolyzed water discharge port 49 and the electrolyte supply port 42 via pipes 61 and 62. The circulation tank 63 is connected to the electrolyte supply tank 65 and the raw water supply unit 11 via pipes 64 and 67, respectively. The circulation tank 63 has a discharge pipe 66. The pipes 61, 62, 64, 66 and 67 are all provided with an opening / closing mechanism, and are opened and closed under the control of the control unit 20.

  The control unit 20 supplies the raw water from the raw water supply unit 11 to the anode chamber 51 while supplying the electrolytic aqueous solution from the circulation tank 63 to the cathode chamber 52 when supplying the electrolytic water.

  That is, in the electrolytic bubble water generator 10, the electrolytic aqueous solution is supplied from the circulation tank 63 to the cathode chamber 52 to be electrolyzed, and the alkaline electrolyzed water generated by the electrolysis is returned to the circulation tank 63 and reused as the electrolytic aqueous solution. To do.

  However, when the electrolyte aqueous solution is circulated for a long time, the anion (chlorine ion) concentration in the circulation tank 63 decreases.

  Therefore, as shown in FIG. 8, the control unit 20 removes only a small amount of the aqueous electrolyte solution (for example, 1/20 to 1/5 of the tank capacity) through the pipe 66 every predetermined replenishment time (for example, it operates for 15 to 120 minutes). About) Discard and replenish the circulation tank 63 with the same amount of electrolyte aqueous solution.

  In addition, when the electrolyte aqueous solution is circulated for a long time, the pH value of the electrolyte aqueous solution increases. In addition, the control unit 20 discards the entire electrolyte aqueous solution in the circulation tank 63 via the pipe 66 every predetermined replacement time (for example, 5 to 25 hours), and fills the circulation tank 63 with the electrolyte aqueous solution for the tank capacity. To do.

  Furthermore, as shown in FIG. 9, the control unit 20 executes a cleaning process for the circulation tank 63 and the cathode chamber 52 when a preset cleaning time is reached.

  Specifically, the control unit 20 discards the entire electrolyte aqueous solution in the circulation tank 63 from the pipe 66 and then supplies the raw water from the raw water supply unit 11 to the circulation tank 63. Then, the control unit 20 circulates raw water to the circulation tank 63 and the cathode chamber 52 via the pipes 62 and 61. This process is executed for about 10 minutes to 1 hour, for example. The supply of raw water may be continued and the raw water may be washed continuously while discarding some raw water as needed. Processing may be performed. Further, the cleaning process may be performed only once or a plurality of times.

  In addition, it is preferable to provide a neutralizing device for neutralizing the alkali on the pipe 66. Thereby, it can be discarded after adjusting the pH of the concentrated alkaline electrolyzed water to an appropriate value.

  As described above, in the electrolytic bubble water generating apparatus 10, the electrolytic aqueous solution supplied to the cathode chamber 52 is supplied to the cathode chamber 52 by the electrolyzing unit 13 having a two-tank electrolytic cell configuration separated by the diaphragm 45, and the alkaline electrolyzed water generated as it is is used as an electrolyte. While being circulated through the circulation tank 63 as an aqueous solution, only acidic electrolyzed water is supplied from the electrolyzed water supply unit 18 as electrolyzed water.

  The electrolytic bubble water generator 10 can automatically replace the aqueous electrolyte solution by the discharge mechanism (pipe 66) and the filling mechanism (pipe 64 and the electrolyte supply tank 65) for discharging the electrolyte aqueous solution in the circulation tank 63. did. Furthermore, the electrolyzed bubble water generating apparatus 10 can automatically wash the circulation tank 63 by connecting the raw water supply unit 11 and the circulation tank 63.

  Thereby, the alkaline electrolyzed water that is not used can be reused, the amount of water used can be saved, and the alkaline electrolyzed water is concentrated, so that the amount of alkaline electrolyzed water to be discarded can be greatly reduced. In addition, since the cathode chamber 52, the circulation tank 63, and the pipes 61 and 62 generated with the concentration of the alkaline electrolyzed water can be cleaned using raw water, adhesion of mineral components and the like can be eliminated.

  Next, pressure adjustment will be described. In the conventional configuration, in order to prevent damage to the electrolytic cell, by providing a discharge line from the circulation tank 63 and installing a relief valve there, the electrolyte solution from the anode chamber 51 is discharged when the pressure increases, It was the structure which performs washing | cleaning. However, there is a problem that clogging is fast, cleaning must be performed frequently, and work is complicated.

  As described above, in the electrolysis unit 13 of the electrolytic bubble water generating apparatus 10, the electrolyte aqueous solution is supplied to the cathode chamber separating the anode chamber 51 and the cathode chamber 52 by the diaphragm 45, and passes through the diaphragm 45. Chlorine ions are supplied to the anode chamber 51. The position of the diaphragm 45 and the anode 43 is determined so that chlorine ions can be appropriately supplied to the anode chamber 51. Further, the diaphragm 45 is disposed at a position close to the cathode 44. However, when the diaphragm 45 is pulled toward the cathode 44, the diaphragm 45 is sucked into a hole formed in the cathode 44, and the diaphragm 45 is stretched and damaged. There is a risk that the cathode 44 may be burnt due to heat generation.

  Therefore, it was considered that the above-described problems could be solved by making the pressures in the anode chamber 51 and the cathode chamber 52 as uniform as possible. Therefore, in the present invention, the pressure adjusting valve 88 for adjusting the pressure is provided between the circulation tank 63 and the cathode chamber 52 which is the electrolyte supply chamber.

  As shown in FIG. 10, a pressure reducing valve 81 is provided on a pipe 11 </ b> A extending from the raw water supply unit 11, and the pipe 11 </ b> A branched to the back of the pressure reducing valve 81 and connected to the anode chamber 51 is circulated. Branches to a pipe 67 connected to the tank 63. The pipes 11A and 65 are provided with opening / closing valves 82 and 85, respectively, and raw water is supplied to the anode chamber 51 and the circulation tank 63 in accordance with the opening / closing of the opening / closing valves 82 and 85.

  When the open / close valve 82 is opened, the raw water supplied from the raw water supply unit 11 is supplied to the anode chamber 51 through the pipe 11A. At this time, the flow rate of the raw water is adjusted by the flow rate adjusting valve 83 and is prevented from flowing back by the check valve 84.

  An open / close valve 87 and a pressure adjustment valve 88 are provided on the pipe 61 connected from the cathode chamber 52 to the circulation tank 63. In normal times, the opening / closing valve 87 is in an open state.

  The pressure adjusting valve 88 is preferably a so-called diaphragm valve that adjusts the pressure by closing a part or all of the flow path by deforming an elastic diaphragm using a spring or a screw. As the diaphragm valve, a relief valve or a back pressure valve is preferably used. A so-called primary pressure regulating valve or secondary pressure regulating valve that opens and closes the valve according to the pressure on the primary side or the secondary side that is the fluid inlet may be used. It is more preferable to have a configuration that has a joint flow path portion that is located on and connected to one surface, and that can block both the primary flow path and the secondary flow path on the single surface by the diaphragm. . As a result, it is possible to appropriately adjust the pressure on both the primary side and the secondary side. Such a configuration is described in, for example, the following website (http://www.iwakipumps.jp/blog/naruhodo/12).

Since the aqueous electrolyte solution has a relatively high electrolyte concentration, when it is left standing for a certain period of time, salt is likely to precipitate particularly in the vicinity of the valve, causing clogging. When a diaphragm valve having elasticity is used as the pressure regulating valve 88, the diaphragm always swings and repeats deformation due to its easily deformable characteristics, so that the salt adhering to the diaphragm due to precipitation is easily removed by deformation during operation. It is possible to pass a lump of salt or the like by temporary deformation of the diaphragm, and the possibility of clogging even during long-time operation can be extremely reduced. Note that having elasticity means that the elastic modulus is 10 ⁵ Pa to 10 ⁸ Pa, more preferably 10 ⁶ Pa to 10 ⁷ Pa. Although there is no restriction | limiting in the structure of a diaphragm, In order to obtain sufficient deformation, it is preferable that the thickness of a diaphragm is 1.0-3.0 mm (1.0 mm or more, 3.0 mm or less) on average.

  The inventor of the present application tried to use a pressure regulating valve made of hard plastic as the pressure regulating valve 88, but the pressure when the valve was opened was larger than the set value. When the inside was confirmed, it was confirmed that the electrolyte salt adhered to the O-ring part. If a hard material is used as a material for blocking the flow path, a so-called packing is required to prevent leakage like an O-ring. If even a small amount of salt adheres to this part, leakage will occur and the function as a pressure regulating valve will be distorted. This is thought to occur.

  On the other hand, due to the above-described effects, the diaphragm valve maintained the pressure when exchanging even after a long period of use within a certain range. And when the inside was confirmed, adhesion of electrolyte was hardly seen.

  A pump 89 is installed on the pipe 62 connected to the cathode chamber 52 from the circulation tank 63, and the electrolyte aqueous solution in the circulation tank 63 is pumped and pumped to the cathode chamber 52. There is no restriction | limiting in particular in the structure of the pump 89, Although it selects suitably according to specifications, such as flow volume, a housing | casing can be made small by using a tube pump, and it is preferable. The pump 89 is provided not on the pipe 61 but on the pipe 62, and is distributed separately to the two pipes connecting the circulation tank 63 and the cathode chamber 52, thereby adjusting the flow rate. The influence of pulsation caused by the pump 89 at the time of pumping in the valve 88 can be reduced. In particular, when a tube pump is used as the pump 89, the pulsation can be effectively reduced and the diaphragm valve can be effectively exhibited.

  The pressure regulating valve 88 may be a fixed type that determines the position of the diaphragm by a screw, and the flow rate is adjusted according to the pressure value of the cathode chamber 52 and the current value of the electrolysis unit 13 by the control of the control unit 20. It may be an automatic adjustment type.

  In the case of the fixed type, for example, when the electrolytic bubble water generator 10 is installed, the flow rate adjusting valve 83 is configured so that an appropriate supply amount of raw water is supplied according to the supply amount of the raw water supplied by the raw water supply unit 11. It is preferable that the pressure of the electrolysis unit 13 is adjusted to be optimal by measuring the current value in the electrolysis unit 13 and the pressure value inside the cathode chamber 52.

  By supplying an electrolyte solution at an appropriate flow rate to the cathode chamber 52, the pressures in the cathode chamber 52 and the anode chamber 51 can be adjusted to appropriate values. As a result, the diaphragm 45 is moved closer to one electrode due to the pressure difference, and the distance from the electrode changes to change the amount of electrolyte passing therethrough. As a result, the electrolytic efficiency is prevented from being lowered. Can be prevented from being damaged or the diaphragm 45 can be stretched.

  As described above, the electrolytic bubble water generator 10 is provided with the flow rate adjustment valve 83 and the pressure adjustment valve 88, and adjusts the flow rates of the raw water and the electrolyte aqueous solution supplied to the cathode chamber 52 and the anode chamber 51, thereby performing electrolysis. The internal pressure of the portion 13 can be kept appropriate.

<Configuration of nanobubble generator>
Next, the configuration of the nanobubble generator 17 will be described.

  In FIG. 11, the conceptual diagram of the nano bubble production | generation part 17 of this invention is shown. The nanobubble generating unit 17 includes a first cylindrical portion 101 having a first bottom surface 103 and a second bottom surface 104, and a second cylindrical portion 102 having a third bottom surface 105 and a fourth bottom surface 106, and the second bottom surface. 104 and the third bottom surface 105 are arranged facing each other. The first cylindrical portion 101 includes an outer cylindrical portion 101A and an inner cylindrical portion 101B, and a passage through which fluid can pass between the outer cylindrical portion 101A and the inner cylindrical portion 101B at or near the first bottom surface 103. On the other hand, such a gap 112 is not provided in the second bottom surface 104 and the vicinity thereof, and fluid cannot flow between the outer cylinder portion 101A and the inner cylinder portion 101B. In addition, the second bottom surface 104 and the third bottom surface 105 are provided with an intermediate hole 113 to allow the fluid to pass between the first cylindrical portion 101 and the second cylindrical portion 102.

  Therefore, when the medium liquid is supplied from the second bottom surface 104 of the first cylindrical portion 101 or the supply port 111 provided in the vicinity thereof, the medium liquid turns toward the first bottom surface 103 while turning, and the first bottom surface 103 is rotated. And travels from the gap 112 to the inner cylinder portion 101B. The medium liquid advances toward the second bottom surface 104 while turning the inner cylinder portion 101B, collides with the second bottom surface 104, and advances from the intermediate hole 113 to the second cylindrical portion 102. The medium liquid travels from the third bottom surface 105 to the fourth bottom surface 106 in the second cylindrical portion 102 and is discharged from the discharge port 114 provided at or near the fourth bottom surface 106.

  Here, the cross-sectional area of the intermediate hole 113 is formed smaller than the cross-sectional areas of the supply port 111 and the discharge port 114. For this reason, the internal pressure of the 1st cylindrical part 101 becomes larger than the internal pressure of the 2nd cylindrical part 102. FIG. That is, in the nanobubble generating unit 17, the medium liquid is swirled under high pressure and collided with the first bottom surface 103 and the second bottom surface 104 to generate nanobubbles by a high-speed swirling method, and through the intermediate hole 113 having a small cross-sectional area. In addition, it has a two-stage nanobubble generation mechanism that releases the pressure by transferring the medium liquid to the lower pressure second cylindrical portion 102 and generates nanobubbles by the pressure release method.

  A specific configuration of the nanobubble generator 17 is shown in FIG. 12, an exploded perspective view is shown in FIG. 13, a cross-sectional view cut near the center is shown in FIG. 14, and a size relationship is shown in FIG. In addition, the code | symbol used in FIG. 11 is also displayed in the location corresponding to FIG. The description will be made assuming that the vertical direction on the paper is the vertical direction and the horizontal direction is the horizontal direction.

  The nanobubble generating unit 17 includes a first cylindrical part 121, a second cylindrical part 122, and three flange parts 123 to 125 that sandwich them. In any case, the material is not limited, and is formed of a hard and strong material such as hard plastic, metal, or glass.

  The first cylindrical portion 121 includes an outer cylindrical portion 121A that is a cylindrical member having a large diameter and an inner cylindrical portion 121B that is a cylindrical member having a small diameter, and the inner cylindrical portion 121B is disposed inside the outer cylindrical portion 121A. The outer cylinder part 121A and the inner cylinder part 121B have substantially the same height in the vertical direction, and the size thereof is not limited. For example, the outer diameter of the outer cylinder part 121A is 50 to 100 mm, and the outer diameter of the inner cylinder part 121B. Is 25 to 50 mm, and the height is 100 to 175 mm.

  The flange portion 123 located at the uppermost portion of the first cylindrical portion 121 has a rectangular parallelepiped shape as a whole, and has a flange surface 123A constituting the upper surface and a flange surface 123B constituting the lower surface. The flange surface 123B has a disk-shaped groove 123E that is slightly shallower (for example, 5 to 10 mm) than the wall thickness of the outer cylinder portion 121A so that the outer cylinder portion 121A can be fitted, and the inner cylinder portion 121B. A circular recess 123C that is larger by about 5 to 30 mm than the outer diameter and deeper than the groove 123E is formed.

  Further, the flange portion 124 positioned between the first cylindrical portion 121 and the second cylindrical portion 122 has a rectangular parallelepiped shape as a whole, and the flange surface 124A which is the upper surface thereof has an outer cylindrical portion 121A and an inner cylindrical portion. Disk-shaped grooves 124E and 124F formed with a width slightly larger than the wall thickness of the outer cylindrical portion 121A and the inner cylindrical portion 121B (for example, 1 to 10 mm) and substantially the same depth so that 121B can be fitted. Is formed.

  Therefore, as shown in FIG. 14, the outer cylinder part 121A and the inner cylinder part 121B sandwiched between the flange surface 124A and the flange surface 123B have substantially the same upper end, and there is a gap between the recess 123C and the inner cylinder part 121B. 112 is formed.

  The flange portion 124 is formed with an introduction hole 131 that is bent upward from an introduction inlet 131A provided in the side surface 124C. The flange portion 124A has an inner side of the outer cylinder portion 121A and an outer side of the inner cylinder portion 121B. An introduction outlet 131B that is an outlet of the introduction hole 131 is provided in the region.

  In addition, a circular recess 136 is provided at the center of the flange portion 124, and has a diameter (cross-sectional area) smaller than that of the introduction hole 131 at the center of the recess 136. 133 is provided. The cross-sectional area ratio between the introduction hole 131 and the intermediate hole 133 is preferably set to 1: 0.1 to 1: 0.5, more preferably 1: 0.2 to 1: 0.3. A metal reinforcing member 137 having a hole having a diameter that is the same as or slightly larger than the intermediate hole 133 (about 1 to 3 mm) is fitted into the recess 136. The reinforcing member 137 has a flat lower surface than the intermediate hole 133, whereas the upper surface is recessed in a mortar shape. Although there is no restriction | limiting in the size of the intermediate hole 133, For example, an intermediate hole is formed in about 5 mm and the hole of a reinforcement member is formed in about 7 mm. The cross-sectional area ratio between the introduction hole 131 and the intermediate hole 133 is important in setting the pressure inside the first cylindrical portion 121, and the pressure from the pump 16 to the intermediate hole 133 is preferably 200 to 1000 kPa, more preferably. Is maintained at about 440 to 700 kPa, so that the high-speed turning method and the pressure releasing method can be advanced simultaneously.

  A lateral hole 135 connected to the intermediate hole 133 is provided on the side surface of the flange portion 124. Although there is no restriction | limiting in the size of this horizontal hole 135, For example, it is preferable to form in the same diameter (for example, about 2-8 mm) as the intermediate hole 133, for example.

  The second cylindrical portion 122 is a cylindrical member that is substantially the same as the outer cylindrical portion 121 </ b> A of the first cylindrical portion 121. The flange surface 124B, which is the lower surface of the flange portion 124, and the flange surface 125A, which is the upper surface of the flange portion 125, are shallow with a width slightly larger than the wall thickness of the outer cylinder portion 121A so that the second cylindrical portion 122 fits (for example, 1 to 10 mm) formed disk-shaped grooves 124G and 125E are formed.

  Near the center of the flange portion 125, four discharge ports 134 that connect the upper and lower surfaces of the flange portion 125 are formed. The discharge port 134 is formed so as to fit within the inner diameter of the pipe 17A to be connected (see FIG. 15).

  Therefore, by connecting the pipe 16A to the inlet of the introduction hole 131, the mixed gas and the acidic electrolyzed water (hereinafter referred to as mixing target water) from the gas-liquid delivery part 15 to the inner cylinder part 121B and the inner cylinder part 121B. Is supplied. The mixing target water turns upward while turning, enters the inner cylinder portion 121B through the gap 112, and advances downward while turning. Further, the water to be mixed proceeds through the intermediate hole 133 to the second cylindrical portion 122.

  At this time, since the reinforcing member 137 is formed in a mortar shape, the water to be mixed is smoothly guided to the intermediate hole 133 while turning, and the stress applied to the vicinity of the intermediate hole 133 can be reduced.

  Further, since the cross-sectional areas of the pipe 16A and the discharge port 134 are substantially the same, and the cross-sectional area of the intermediate hole 133 is smaller than that of the pipe 16A and the discharge port 134, the pressure in the first cylindrical part 121 is set to the second cylindrical part 122. In addition to the generation of fine bubbles by the high-speed swirling method while maintaining a high state compared to the pressure, the pressure is released at once as the mixing target water enters the second cylindrical portion 122. Fine bubbles are generated.

  Furthermore, by taking in air from the lateral hole 135, fine bubbles can be generated by the venturi method, fine bubbles can be additionally generated, and the fine bubbles in the mixing target water can be increased. By changing the diameter of the horizontal hole 135, the size of the additionally generated fine bubbles can be adjusted. For example, when the diameter of the lateral hole 135 is about 4.5 to 7 mm, the amount of bubbles can be increased centering on micro-order (1 to 1000 μm) micro bubbles. Further, when the diameter of the lateral hole 135 is about 2 to 4.5 mm, it is possible to increase mainly nano-sized (1 to 1000 nm) fine bubbles. In addition, it is also possible to mix arbitrary gas by connecting a gas cylinder to the horizontal hole 135.

  The mixing target water that has entered the second cylindrical portion 122 is discharged from the discharge port 134 while turning, and proceeds to the pipe 17A. Here, by forming the discharge port 134 as four through holes, it is possible to disperse the energy of swirl in the second cylindrical portion 122 and disperse the stress applied to the pipe 17A.

  As described above, in the nanobubble generation unit 17, by connecting the double cylinder (first cylinder part 121) and the single cylinder (second cylinder part 122) that rapidly change the turning direction by the intermediate hole 133 having a small diameter, Release pressure after high-speed turning under high pressure. Thereby, a fine bubble can be efficiently generated using both a high-speed turning system and a pressure release system. Moreover, the horizontal hole 135 is connected with respect to the intermediate hole 133, and a fine bubble is generated by a venturi system.

  In other words, by forming cylindrical holes on top of each other and forming a horizontal hole between them, it is possible to generate microbubbles using three types of systems in a compact shape, increasing the number of microbubbles in the generated microbubble water Can be made.

<Operation and effect>
Hereinafter, the characteristics of the invention group extracted from the above-described embodiment will be described while showing problems and effects as necessary. In the following, for easy understanding, the corresponding configuration in each of the above embodiments is appropriately shown in parentheses, but is not limited to the specific configuration shown in parentheses. In addition, the meanings and examples of terms described in each feature may be applied as the meanings and examples of terms described in other features described in the same wording.

According to the above configuration, the nanobubble generator (nanobubble generator 17) of the present invention includes a cylindrical outer cylinder (outer cylinder 121A) having first and second bottom surfaces (flange surfaces 123B and 124A) and The medium liquid (mixing target water) flows between the outer cylinder part and the inner cylinder part in the vicinity of the first bottom surface and the inner cylinder part (inner cylinder part 121B) having a smaller diameter than the outer cylinder part. A first cylindrical portion having a gap portion (gap 112) which is a space and to which the medium liquid is supplied from a supply port (introduction outlet 131B) formed near the second bottom surface or the second bottom surface. (First cylindrical portion 121);
It has a cylindrical shape having third and fourth bottom surfaces (flange surfaces 124B and 125A), is connected with the third bottom surface facing the second bottom surface, and is supplied to the third bottom surface. An intermediate hole (intermediate hole 133) having a smaller area than the mouth is formed, and a second cylinder having a discharge port (discharge port 134) having a larger area than the intermediate hole in the fourth bottom surface or in the vicinity of the fourth bottom surface. Part (2nd cylindrical part 122).

  As a result, the first cylindrical part can be brought into a high pressure state to generate fine bubbles by the high-speed swirling method, and the pressure can be released from the second cylindrical part to generate the fine bubbles by the pressure releasing method. Thus, fine bubbles can be efficiently generated using the two methods.

  The medium liquid flow between the outer cylinder part and the inner cylinder part is a medium liquid flow from the outer cylinder part toward the inner cylinder part. Accordingly, an even swirl flow can be formed using the pulling pressure from the intermediate hole 133 formed at the center of the inner cylinder portion.

  A medium liquid containing a mixed gas is supplied to the supply hole. Thereby, since the mixed gas is mixed with the medium liquid in advance, the contact time between the mixed gas and the medium liquid can be extended, and fine bubbles can be easily generated.

  In the vicinity of the third bottom surface, there is provided an intake hole (horizontal hole 135) for taking in gas. Thereby, a fine bubble can be produced | generated by a venturi system, and the whole quantity of a fine bubble can be increased.

  The second bottom surface and the third bottom surface are formed, and an intermediate flange portion having the supply port and the intermediate hole is provided. Thereby, since two bottom surfaces, a supply port, and an intermediate hole can be formed by one flange part, a number of parts can be reduced and a structure can be simplified.

  It has the 1st bottom face plate which constitutes the 1st bottom face and has a dent facing the inner cylinder part as the gap part. Thereby, since the medium liquid can be drawn to the vicinity of the center using the dent, the flow of the medium liquid can be made smooth.

  It has the 2nd bottom face plate which constitutes the 4th bottom face and has the discharge mouth in the center of the 4th bottom face, or near the center. Thereby, for example, the entrance of the discharge port can be provided at an arbitrary position of the bottom plate such as the vicinity of the center, and the degree of freedom in design is improved.

  The discharge port is connected to a discharge pipe, and is formed as a plurality of holes that fit inside a cross section of the discharge pipe. Thereby, since a turbulent flow can be formed in front of the discharge pipe, concentration of stress on a specific portion of the discharge pipe can be prevented.

  The nanobubble generator of the present invention includes a cylindrical outer cylinder portion having first and second bottom surfaces, an inner cylinder portion having a smaller diameter than the outer cylinder portion, and the outer cylinder portion in the vicinity of the first bottom surface. And a gap that is a space for creating a medium liquid flow between the inner cylindrical portions, and a rod-shaped member (bar-shaped member 141) that protrudes from the second bottom surface to the center of the inner cylindrical portion, and the second And a first cylindrical portion to which the medium liquid is supplied from a supply port formed in the vicinity of the second bottom surface or the second bottom surface.

  Thereby, it is possible to easily form a swirling flow centering on the rod-shaped member existing at the center of the inner cylinder portion, and it is possible to increase fine bubbles.

  The rod-like member is characterized in that a spiral groove is formed on at least a part of the surface. As a result, it is possible to prevent the generation of turbulent flow that occurs when the traveling direction is changed by colliding with the first bottom surface in the flow of the swirling flow, and the turbulent flow is generated around the rod-shaped member while smoothing the flow. It is possible to generate fine bubbles in a smooth flow.

  The rod-shaped member is a screw fixed to the first bottom surface. Thereby, it becomes possible to fix a rod-shaped member to an inner cylinder part by the simple structure which forms a female screw (hole) in a bottom face, and inserts a screw | thread.

  In the nanobubble generating method of the present invention, the medium liquid is swirled in a plurality of swirling directions under a pressure of 200 to 1000 kPa, and the pressure is released while continuing swirling. The phrase “the pressure is released while continuing the turning” is executed by releasing the pressure at a position less than a position (for example, 20 cm to 10 cm) close to the turning unit that performs the turning.

  As a result, the pressure can be released immediately after the generation of nanobubbles by the high-speed swirling method, and nanobubbles can be generated by the two methods in a short time.

A swivel portion (first cylindrical portion 121) for swirling the medium liquid in a plurality of swiveling directions;
A pressure release chamber (second cylindrical portion 122) for releasing pressure;
It is a nano bubble generator which has a connection hole (intermediate hole 133) which connects the revolving part and the pressure release chamber.

  As a result, the pressure can be released immediately after the generation of nanobubbles by the high-speed swirling method, and nanobubbles can be generated by the two methods in a short time. In addition, it is preferable that a connection hole is less than 20 cm, for example, and also less than 10 cm. For example, in the embodiment, the swivel unit and the pressure release chamber are separated by a flange having a thickness of less than 10 cm, and a through hole provided in the flange is connected as a connection hole.

In the connection hole,
A gas supply port (horizontal hole 135) through which gas is supplied is provided.

  Thereby, it is possible to generate the nanobubbles by the venturi method immediately after the generation of the nanobubbles by the high-speed swirling method, and to release the pressure immediately after that, and to generate the nanobubbles by the three methods in a short time.

<Other embodiments>
In the above-described embodiment, the fine bubbles are generated by using the nanobubble generating unit 17 shown in FIG. 14, but the present invention is not limited to this. For example, the nanobubble generating unit 17X having the configuration shown in FIGS. ~ 17Z can be used. 16 to 18, the same reference numerals are assigned to the same portions as those shown in FIGS. 12 to 15. Only the differences will be described below.

  In the nanobubble generating unit 17X illustrated in FIG. 16, a rod-shaped member 141 that protrudes from the center of the flange portion 123 toward the inner cylindrical portion 121B of the first cylindrical portion 121 is provided. The bar-shaped member may have a smooth surface, and a spiral groove like a screw may be formed on at least a part of the surface.

  In the drawing, a long screw is fitted or screwed into the hole (or female screw) provided in the center of the flange portion 123 from the flange surface 123B surface, and is fixed using a washer and a nut, thereby fixing the flange surface 123B. The state which protruded the rod-shaped member 141 is shown. Although there is no restriction | limiting in the length of the rod-shaped member 141, When the height of the 1st cylindrical part 121 is set to 1, it is preferable that it is about 00.1-0.9 length. Due to the presence of the rod-shaped member 141, the turning is promoted and the fine bubbles can be increased.

  In the nanobubble generating part 17Y shown in FIG. 17, the two first cylindrical parts 121 having the double cylindrical configuration and the rod-shaped member 141 are arranged in the horizontal direction, and the diameter of the intermediate hole 133Y is formed almost the same as the diameter of the introduction hole 131. Has been. Accordingly, the nanobubble generator 17Y has a configuration that generates fine bubbles only by the high-speed turning method. That is, the configuration using the rod-shaped member 141 can be applied to a nanobubble generating unit only for the high-speed turning method or a method combining the high-speed turning method and the venturi method.

  In the nanobubble generator 17Z shown in FIG. 18, two first cylinders 121 having a double cylinder configuration and a rod-shaped member 141 are arranged in the vertical direction, and the mixing target water flows from the inside to the outside in the lower first cylinder 121Z. The clearance 112 is formed by the point which advances and the flange 123Z does not have the recessed part 123C, and the inner cylinder part 121B is slightly smaller than the height of the outer cylinder part 121A. That is, the high-speed turning method can make a flow from the inside to the outside. This configuration can also be applied to the first cylindrical portion without the rod-shaped member 141.

  In the above-described embodiment, the introduction hole 131 is bent from the side surface 124C of the flange portion 124 toward the flange surface 124A. However, the present invention is not limited to this. For example, two flanges are combined and the upper flange is the outer cylinder portion 121A. In addition to a hole having the same diameter as the inner diameter (hereinafter referred to as an outer cylinder hole), a linear introduction hole penetrating from the side surface toward the outer cylinder hole may be provided. In this case, the upper flange constitutes a part of the outer cylinder portion 101A, and an introduction outlet is provided in the vicinity of the bottom surface of the outer cylinder portion 101A.

  In the above-described embodiment, the alkaline electrolyzed water is circulated using the cathode chamber as the electrolyte supply chamber. However, the present invention is not limited to this, and the acidic electrolyzed water may be circulated using the anode chamber as the electrolyte supply chamber.

  Furthermore, in the above-described embodiment, one electrolytic cell is provided as the electrolyzing unit 13, but two or more electrolytic cells may be provided. In this case, the mixed liquid (generated gas and electrolyzed water) is supplied to the gas-liquid delivery unit 15 via a plurality of paths (pipes). At this time, the gas-liquid delivery part 15 also plays the role which mixes the liquid mixture manufactured with the some electrolytic vessel equally.

  In the above-described embodiment, the fine water bubbles are contained in the electrolyzed water. However, the present invention is not limited to this, and the present invention can be applied to an electrolyzed water generating apparatus that provides generated electrolyzed water as it is. In this case, since a pressure difference does not occur between the anode chamber and the cathode chamber, it is not necessary to provide electrodes so as to partition the anode chamber and the cathode chamber.

  Furthermore, in the above-described embodiment, the electrolyte aqueous solution is supplied from the electrolyte supply tank 65 to the circulation tank 63, but the electrolyte and raw water may be supplied. In this case, the circulation tank 63 preferably has a stirring mechanism such as a stirring blade.

  In the above-described embodiment, a high concentration electrolyte aqueous solution can also be supplied to the electrolyte supply tank 65. In this case, the replacement process is not performed, and the aqueous electrolyte solution is replenished sequentially (for example, every 15 to 60 minutes) (or the electrolyte aqueous solution in the circulation tank 63 is partially replaced), and the cleaning process is executed once a day, for example. Thereby, the processing time accompanying replenishment (exchange process) of electrolyte aqueous solution can be shortened. In this case, the control unit 20 causes the electrolyte aqueous solution to be supplied from the electrolyte supply tank 65 to the circulation tank 63, and discharges the amount overflowed beyond the capacity of the circulation tank 63. The amount of the aqueous electrolyte solution supplied from the electrolyte supply tank 65 is set to be smaller than the amount of the aqueous electrolyte solution supplied from the circulation tank 63 (for example, about 1/10 to 1/30).

  In the above-described embodiment, the case where nanobubbles are generated by high-speed turning has been described. The present invention is not limited to this, and it is not always necessary to rotate at high speed. For example, fine bubbles may be generated by causing a physical collision action by meandering the medium liquid a plurality of times.

  Furthermore, in the above-described embodiment, the medium liquid is supplied to the nanobubble generation unit 17 and is discharged as it is from the electrolytic bubble water providing unit 18 so as to generate a so-called continuous type fine bubble liquid. You may produce | generate a fine bubble liquid by what is called a batch type system which stores a medium liquid and a fine bubble liquid in a tank, and circulates the nanobubble production | generation part 17 over fixed time. Further, a storage tank for storing fine bubble water may be provided at the subsequent stage of the electrolytic bubble water providing unit 18.

  In the above-described embodiment, the high-speed stirring is performed by the high-speed turning in which the gas-liquid delivery unit 15 travels in one direction, but the present invention is not limited to this. For example, high-speed stirring may be performed by generating turbulent flow or swirling blades.

  Moreover, in the above-mentioned embodiment, the case where generation of nanobubbles was performed at room temperature and adjustment for water temperature was not performed was described. The solubility of gas increases as the liquid temperature decreases. For this reason, a cooling function for lowering the liquid temperature can be added.

  In the above-described embodiment, the circulation tank 63 is connected to the two-tank electrolysis unit 13, but the circulation tank 63 may be connected to an intermediate chamber of the three-tank electrolysis unit. Further, instead of the circulation tank 63, an electrolyte supply unit that simply supplies an aqueous electrolyte solution (is configured to discard those not used) can be provided. Alternatively, an aqueous electrolyte solution may be supplied to each chamber of the two-tank electrolysis unit 13 separated by a diaphragm.

  Furthermore, in the above-described embodiment, the electrolyzed bubble water generating device 10 as the electrolyzed water generating device, the anode chamber 51 as the raw water supply unit, the circulation tank 63 as the circulation tank, and the piping 66 as the electrolyte discharge unit The case where the electrolyte supply tank 65 as the electrolyte supply unit and the control unit 20 as the control unit are configured has been described. The present invention is not limited to this, and the electrolyzed water generating apparatus of the present invention may be configured by the raw water supply unit, the circulation tank, the electrolyte discharge unit, the electrolyte supply unit, and the control unit having various configurations. .

  The present invention can be used for, for example, a nanobubble generating device that generates nanobubble water containing nanobubbles, an electrolytic bubble water generating device that generates electrolytic bubble water, and the like.

7: Nanobubble generating unit 10: Electrolytic bubble water generating device 101: First cylindrical portion 101A: Outer cylindrical portion 101B: Inner cylindrical portion 102: Second cylindrical portion 103: First bottom surface 104: Second bottom surface 105: Third bottom surface 106 : Fourth bottom surface 111: supply port 112: gap 113: intermediate hole 114: discharge port 121: first cylindrical part 121A: outer cylinder part 121B: inner cylinder part 122: second cylindrical parts 123, 124, 125: flange part 123C 136: Recessed portion 123Z: Flange 124C: Side surface 131: Introduction hole 131B: Introduction outlet 133: Intermediate hole 134: Discharge port 135: Horizontal hole 141: Bar-shaped member

Claims (11)

A swirl unit that generates fine bubbles in the medium liquid by a high-speed swirling method that swirls the medium liquid containing the mixed gas ;
A pressure release chamber to release pressure,
Provided in an intermediate flange portion that separates the swirling portion and the pressure release chamber, and has a connection hole that connects the swirling portion and the pressure release chamber and forms a swirling flow in the swirling portion using a pulling pressure. And
The swivel part is
A cylindrical outer tube portion having first and second planes , an inner tube portion having a diameter smaller than that of the outer tube portion, and between the outer tube portion and the inner tube portion in the vicinity of the first plane. A first cylindrical portion to which the medium liquid is supplied from a supply port formed in the second plane or in the vicinity of the second plane . The medium liquid supplied from the supply port to the outer cylinder part advances from the gap part to the inner cylinder part toward the first plane while turning, and moves to the second plane while turning the inner cylinder part. Proceed from the connection hole toward the pressure release chamber,
The pressure release chamber is
Third becomes a cylindrical shape having a plane and a fourth plane, said relative second plane third plane are connected so as to face, in the fourth plane and the fourth plane near the A second cylindrical portion having a discharge port;
The connection hole is
A hole having a smaller area than the supply port formed in the third plane ;
The outlet is
The area is larger than the connection hole,
The intermediate flange portion is
The second plane and the third plane are configured, the supply port and the connection hole are formed, and a mortar-shaped recess is formed at the center of the second plane ,
The connection hole is
A nanobubble generator characterized by being provided at the center of the recess. A metal reinforcing member formed in a mortar having a hole forming a part of the connection hole and recessed in the center is fitted in the center of the second plane of the intermediate flange portion. The nanobubble generator according to claim 1. The outlet is
The nanobubble generator according to claim 1 or 2, wherein the nanobubble generator is connected to a discharge pipe and is formed as a plurality of holes that fit inside a cross section of the discharge pipe. The intermediate flange portion is
The nanobubble generator according to claim 1 , wherein a supply port connected to the first cylindrical portion is provided . The nanobubble generator according to any one of claims 2 to 4, further comprising: a first flat plate that constitutes the first flat surface and has a recess facing the inner tube portion as the gap portion. Constitute the fourth flat, nanobubbles produced according to any one of claims 2-5, characterized in that it comprises a second flat plate having said discharge port in the center or near the center of the fourth plane vessel. The outlet is
The nanobubble generator according to claim 1, wherein the nanobubble generator is formed as four holes. The intermediate flange portion is
The nanobubble generator according to any one of claims 1 to 7, wherein an air inlet connected in a lateral direction with respect to the connection hole is formed. The nanobubble generator according to any one of claims 1 to 8, wherein the first and second cylindrical portions have substantially the same volume. The nanobubble generator according to any one of claims 2 to 9, further comprising: a rod-like member protruding from the first plane to the center of the inner cylinder portion. The nanobubble generator according to any one of claims 1 to 10, wherein the medium liquid is swirled in a plurality of swirling directions under a pressure of 200 to 1000 kPa, and the pressure is released while swirling is continued.

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