JP2005262195A - Electrolytic water generator provided with mechanism for removing gas generated in electrolysis - Google Patents

Electrolytic water generator provided with mechanism for removing gas generated in electrolysis Download PDF

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JP2005262195A
JP2005262195A JP2004119635A JP2004119635A JP2005262195A JP 2005262195 A JP2005262195 A JP 2005262195A JP 2004119635 A JP2004119635 A JP 2004119635A JP 2004119635 A JP2004119635 A JP 2004119635A JP 2005262195 A JP2005262195 A JP 2005262195A
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water
electrolysis
electrolytic
generated
electrolytic water
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Ichiro Shoda
一郎 庄田
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ALTECH CO Ltd
ARUTEKKU KK
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ALTECH CO Ltd
ARUTEKKU KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an electrolytic water generator capable of obtaining consistently stable electrolytic water with a gas removing valve by solving the following problem: hydrogen gas and oxygen gas generated in the electrolysis of water are fed together with discharge of the electrolytic water, and are accumulated in the midway of a water discharge pipe to produce a water passage resistance, which makes unstable the balance in the amount of water between acidic electrolytic water and alkaline electrolytic water, thereby making unstable the water quality of the electrolytic water. <P>SOLUTION: Check valves 13, 14 are installed in the midway of the water discharge pipe discharging the acidic electrolytic water and the alkaline electrolytic water generated in an electrolytic vessel 9, to provide such a function that gases generated by electrolysis are respectively discharged to the outside atmosphere. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

発明の詳細な説明Detailed Description of the Invention

本発明は、電解槽内に供給された原水が電気分解されて電解水が生成される電解水生成器に関する。  The present invention relates to an electrolyzed water generator that generates electrolyzed water by electrolyzing raw water supplied into an electrolyzer.

従来から、この種の電解水生成装置としては外部供給源からの原水を給水管を介して連続的に電解槽に供給するとともに、電解槽内の対を成した電極間に所定電圧を印加してこの原水を電気分解することにより電解水を生成している。この電気分解を促進させるために、ダイヤフラム式ポンプが電解補助液タンク内に蓄えられた濃塩水を塩水カプラを介して吸い込んで給水管に送出して原水に注入している。また電解水生成器は、電流センサーが電極間に流れる電流値を検知しており、生成の際には検出電流値が所望の電気量に相当する電流目標値より低ければ電解電圧を高くし、電流目標値より高ければ電解電圧を低く抑えることによって、検出電流値をほぼ電流目標値に保っている。  Conventionally, as this type of electrolyzed water generating device, raw water from an external source is continuously supplied to the electrolyzer through a water supply pipe, and a predetermined voltage is applied between the paired electrodes in the electrolyzer. Electrolyzed water is generated by electrolyzing the raw water of the lever. In order to promote this electrolysis, a diaphragm pump sucks concentrated salt water stored in the electrolytic auxiliary liquid tank through a salt water coupler, sends it to a water supply pipe, and injects it into raw water. In addition, the electrolyzed water generator detects the current value flowing between the electrodes by the current sensor, and at the time of generation, if the detected current value is lower than the current target value corresponding to the desired amount of electricity, the electrolysis voltage is increased, If it is higher than the current target value, the detected current value is kept substantially at the current target value by keeping the electrolysis voltage low.

このような電解水生成器では、電解生成中に陰極側で水素ガスが発生し、陽極側では酸素ガスが発生する。電解促進のために食塩を使用すると、陽極側では塩素ガスが発生する。電解水の生成能力を高めるために、電解補助剤として食塩や塩化カリウムなどの電解質を用いて電解電流を高い電流値に設定する使い方が多くなり、電解電流値に比例してガスの発生量が増加する。従来から、電解生成時に起こる化学反応は、電極板表面で反応をする為に電極板の保護として電解槽でこの発生したガスを取り除く構造を持ったものが大半をしめている。  In such an electrolyzed water generator, hydrogen gas is generated on the cathode side and oxygen gas is generated on the anode side during electrolysis generation. When salt is used to promote electrolysis, chlorine gas is generated on the anode side. In order to increase the ability to generate electrolyzed water, the use of electrolytes such as sodium chloride and potassium chloride as electrolysis aids increases the setting of the electrolysis current, and the amount of gas generated is proportional to the electrolysis current value. To increase. Conventionally, most chemical reactions that occur during electrolysis have a structure in which the generated gas is removed from the electrolytic cell as a protection of the electrode plate in order to react on the surface of the electrode plate.

このような電解水生成器では、電解槽の電極保護が可能となるが、水の弱電解においては水中に水素ガスや酸素ガスが微細粒子として存在しているため、生成された電解水は吐水される配管途中で微細粒子ガスが核形成し、大きな気泡となって配管内部を存在することになる。そのため、殺菌用として使用されている強酸性電解水や強アルカリ性電解水が吐水される時などは電解水とガスが交互に排出される。  In such an electrolyzed water generator, it is possible to protect the electrode of the electrolyzer, but in weak electrolysis of water, hydrogen gas and oxygen gas are present as fine particles in the water, so the generated electrolyzed water is discharged from the water. The fine particle gas nucleates in the middle of the pipe, and becomes a large bubble and exists inside the pipe. Therefore, when strong acidic electrolyzed water or strong alkaline electrolyzed water used for sterilization is discharged, electrolyzed water and gas are alternately discharged.

発明が解決しようとする課題Problems to be solved by the invention

しかしながら、このような電解水生成装置においては、電解水とガスが交互に排出されるため、それぞれの配管内部の圧力が不均一となり、水量の比率が不安定となる。水量比率が不安定なまま電解電流値が一定に制御されていると電解水の水質が不安定となり、電解水を使用する際には問題があった。  However, in such an electrolyzed water generating apparatus, since electrolyzed water and gas are alternately discharged, the pressure inside each pipe becomes non-uniform, and the ratio of the amount of water becomes unstable. If the electrolysis current value is controlled to be constant while the water amount ratio is unstable, the quality of the electrolyzed water becomes unstable, which causes a problem when using electrolyzed water.

本発明は、上記問題に対処するためになされたものであり、その目的は電解水生成後の吐水された配管途中にガス抜きの手段を講じることによって、水量の不安定が解消され、生成水質の不安定を確実に防止することができる電解水生成器を提供することにある。  The present invention has been made in order to cope with the above-mentioned problem, and the purpose thereof is to eliminate the instability of the water volume by providing a means for degassing in the middle of the discharged water after the generation of electrolyzed water. It is an object of the present invention to provide an electrolyzed water generator that can reliably prevent instability.

課題を解決するための手段Means for solving the problem

上記目的を達成するために、本発明の構成上の特徴は、収容した一対または二対以上の電極間に印加した所定電圧により外部供給源から供給される原水を電気分解して電解水を生成する電解槽を具備した電解水生成装置において、陰極側で生成された陰極水と陽極側で生成された陽極水の吐水配管途中にガス抜き弁を、それぞれの配管に備えることによって微細粒子ガスが核形成し大きな気泡をガス抜き弁によって放出し、配管内部の圧力を均一に保つことにある。  In order to achieve the above object, the constitutional feature of the present invention is to generate electrolyzed water by electrolyzing raw water supplied from an external supply source with a predetermined voltage applied between a pair of accommodated electrodes or two or more pairs of electrodes. In the electrolyzed water generating apparatus equipped with an electrolyzing tank, fine particle gas is generated by providing a gas vent valve in the water discharge piping in the water of the cathode water generated on the cathode side and the anode water generated on the anode side. It is intended to keep the pressure inside the pipe uniform by nucleating and releasing large bubbles with a vent valve.

また、上記ガス抜き弁を2箇所以上設けて長い配管に対応しても良い。  Moreover, you may respond | correspond to long piping by providing the said gas vent valve two or more places.

また、上記の電解水生成器において電解促進のための添加剤を混入し高い電解電流で使用するものと、添加剤を使用しない低い電解電流において使用する場合は、発生する気泡量が等量ではなく、配管の長さや設置状況によってガス抜きの設置箇所や数量を調整することにある。  In addition, when the above electrolyzed water generator is mixed with an additive for promoting electrolysis and used at a high electrolysis current, and when used at a low electrolysis current without using an additive, the amount of generated bubbles is equal. Rather, the installation location and quantity of the gas vent are adjusted according to the length of the pipe and the installation status.

以下、本発明の実施の形態を図面を参照して詳細に説明する。
図1は本発明の実施の形態を示す図であって、この形態では電解水生成器について概略的に示している。
Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.
FIG. 1 is a diagram showing an embodiment of the present invention. In this embodiment, an electrolyzed water generator is schematically shown.

この電解水生成器の構成は電解槽9を含む水路系部品と電解電源18を含む電気系部品からなっている。また、外部には電解補助液タンク12を備えている。  The configuration of the electrolyzed water generator is composed of a water channel system component including the electrolyzer 9 and an electrical system component including the electrolysis power source 18. In addition, an electrolytic auxiliary liquid tank 12 is provided outside.

前記の電解槽9の内部は隔膜板11によって一対の電極室に区画されており、両電極室はそれぞれ給水管1を介して外部の原水供給源(例えば水道)に接続され、給水管1の途中には後述するように前記の電解補助液タンク12に接続された塩水カプラ17が接続されている。これにより前記の給水管1からの原水(水道水)は前記の塩水カプラ17からの濃塩水が注入された希塩水となって両電極室に供給される。各電極室には一対の電極10a、10bが互いに対向するように収容され、これら両電極10a、10b間には電解電源18からの直流電圧が印加されて、前述のように供給された希塩水が電気分解されて電解水が生成される。前記の電解槽9の各電極室には酸性電解水吐水口15とアルカリ性電解水吐水口16がそれぞれ接続されており、生成された電解水はその先端部である酸性電解水吐水口15とアルカリ性電解水吐水口16から外部へ吐出される。  The inside of the electrolytic cell 9 is partitioned into a pair of electrode chambers by a diaphragm plate 11, and both electrode chambers are respectively connected to an external raw water supply source (for example, water supply) via a water supply pipe 1. On the way, a salt water coupler 17 connected to the electrolytic auxiliary liquid tank 12 is connected as will be described later. Thereby, the raw water (tap water) from the water supply pipe 1 is supplied to both electrode chambers as diluted salt water into which the concentrated salt water from the salt water coupler 17 is injected. A pair of electrodes 10a and 10b are accommodated in each electrode chamber so as to face each other, and a DC voltage from the electrolytic power source 18 is applied between the electrodes 10a and 10b so that the diluted salt water supplied as described above is supplied. Is electrolyzed to generate electrolyzed water. An acidic electrolyzed water outlet 15 and an alkaline electrolyzed water outlet 16 are connected to each electrode chamber of the electrolytic cell 9, and the generated electrolyzed water has an acidic electrolyzed water outlet 15, which is the tip thereof, and alkaline water. It is discharged from the electrolyzed water outlet 16 to the outside.

前記の給水管1には、減圧弁4および開閉弁である給水電磁弁3が設けられている。前記の減圧弁4は外部供給源から圧送される原水の圧力を減圧し、所定圧力範囲内に保つ。前記の給水電磁弁3は電気制御回路により開閉(オン・オフ)制御され、開状態にて外部供給源からの原水を前記の給水管1を介して前記の電解槽9へ供給する。  The water supply pipe 1 is provided with a pressure reducing valve 4 and a water supply electromagnetic valve 3 which is an on-off valve. The pressure reducing valve 4 reduces the pressure of raw water pumped from an external supply source and keeps it within a predetermined pressure range. The water supply electromagnetic valve 3 is controlled to be opened and closed (on / off) by an electric control circuit, and supplies raw water from an external supply source to the electrolytic cell 9 through the water supply pipe 1 in an open state.

前記の塩水カプラ17は、前記の給水電磁弁3下流の流量調整弁7に接続された定量ポンプ8の吐出口(吐出側)に接続している。前記の定量ポンプ8の吸い込み口は前記の塩水カプラ17を中継して、前記の電解補助液タンク12の上部から挿入されている。  The salt water coupler 17 is connected to the discharge port (discharge side) of the metering pump 8 connected to the flow rate adjusting valve 7 downstream of the water supply electromagnetic valve 3. The suction port of the metering pump 8 is inserted from the upper part of the electrolytic auxiliary liquid tank 12 through the salt water coupler 17.

前記の定量ポンプ8は、チューブ式のものであり、チューブを押しつぶしながら吸い込んだ流体を吐出するものであり、その吐出量は電気制御回路によりポンプモーターの電圧を変化させることにより制御されている。電解水生成中には、前記の定量ポンプ8は前記の電解補助液タンク12から濃塩水を吸い込んで前記の流量調整弁7に吐出して原水に注入し、これにより希塩水となった原水が前記の電解槽9に供給される。  The metering pump 8 is of a tube type and discharges the sucked fluid while crushing the tube, and the discharge amount is controlled by changing the voltage of the pump motor by an electric control circuit. During the generation of the electrolyzed water, the metering pump 8 sucks concentrated salt water from the electrolysis auxiliary liquid tank 12 and discharges the concentrated salt water to the flow rate adjusting valve 7 and injects it into the raw water. It is supplied to the electrolytic cell 9.

通水配管途中には流量センサー6が設けられており、前記の流量センサー6は原水の流量を検出して、水量が少ない場合には前記の電解電源18の出力を停止し、通水量の異常状態を表示する。  A flow rate sensor 6 is provided in the middle of the water flow pipe. The flow rate sensor 6 detects the flow rate of the raw water, and when the amount of water is small, the output of the electrolysis power supply 18 is stopped and the flow rate is abnormal. Display status.

前記の電解槽9によって生成された酸性電解水とアルカリ性電解水を吐出する吐水配管途中には逆止弁13、14が設けており、電気分解によって発生したガスをそれぞれ外気へ放出する機能を備えている。  The check valves 13 and 14 are provided in the middle of the water discharge pipe for discharging the acidic electrolyzed water and alkaline electrolyzed water generated by the electrolyzer 9, and each has a function of releasing gas generated by electrolysis to the outside air. ing.

以下ガス抜きのメカニズムの詳細を図2及び図3の部分図にて説明する。前記の電解槽9の下部には電解槽入水口20を具備し、上部には電解槽酸性水出水口21と電解槽アルカリ水出水口22を具備している。前記の電解槽酸性水出水口21はチーズ23にて前記の酸性電解水吐水口15と前記の逆止弁14に分岐している。同様に前記の電解槽アルカリ水出水口22はチーズ23にて前記のアルカリ性電解水吐水口16と前記の逆止弁13に分岐している。入水すると流量センサー6が作動して、電解槽では前記の電解槽入水口20から入水し電気分解を開始し、ガスが発生する、発生したガスは前記の電解槽酸性水出水口21及び、電解槽アルカリ水出水口22から電解水と共に出てゆく。「前記の電解槽酸性水出水口21及び電解槽アルカリ水出水口22以降は共通機能なので図3で示す一方で説明する。」さらに、ガスを含んだ電解水は前記のチーズ23に到達する。前記のアルカリ性電解水吐水口16は前記のチーズ23より構造的に下方に配置してあり、前記の逆止弁13は上方に配置してある。アルカリ性電解水は下方へ出力し、ガスは上方へ放出されて気水分離することができ、ガス抜きしている。  Details of the degassing mechanism will be described below with reference to the partial views of FIGS. An electrolytic tank water inlet 20 is provided in the lower part of the electrolytic tank 9, and an acidic water acidic water outlet 21 and an electrolytic tank alkaline water outlet 22 are provided in the upper part. The electrolytic cell acidic water outlet 21 is branched into the acidic electrolytic water outlet 15 and the check valve 14 by cheese 23. Similarly, the alkaline water outlet 22 of the electrolytic cell branches into the alkaline electrolytic water outlet 16 and the check valve 13 at the cheese 23. When the water enters, the flow sensor 6 is activated, and in the electrolytic cell, water enters from the electrolytic cell inlet 20 to start electrolysis, and gas is generated. The generated gas is the electrolytic cell acidic water outlet 21 and the electrolytic cell. It goes out together with the electrolyzed water from the tank alkaline water outlet 22. “Since the electrolytic cell acidic water outlet 21 and the electrolytic cell alkaline water outlet 22 are common functions, they will be described with reference to FIG. 3.” Furthermore, the electrolytic water containing gas reaches the cheese 23. The alkaline electrolyzed water outlet 16 is structurally disposed below the cheese 23, and the check valve 13 is disposed above. The alkaline electrolyzed water is output downward, and the gas is released upward to be separated into steam and gas, and is degassed.

発明の効果The invention's effect

本発明は、以上説明したように構成されているので、以下に記載されるような効果を奏する。
電解槽9によって生成された酸性電解水とアルカリ性電解水の吐水配管途中に設けた逆止弁13、14によって、電気分解により発生した水中の溶存ガス成分を吐水配管途中から外気へ放出することができる。
Since the present invention is configured as described above, the following effects can be obtained.
It is possible to release dissolved gas components in water generated by electrolysis from the midway of the water discharge pipe to the outside air by the check valves 13 and 14 provided in the midway of the water discharge pipe of the acidic electrolyzed water and alkaline electrolyzed water generated by the electrolyzer 9. it can.

吐水配管途中の溶存ガスが外気へ放出できることにより、配管内部に生じる圧力が酸性電解水(陽極側)とアルカリ性電解水(陰極側)で均一化され、お互いの水量比率が崩れることがない。そのため通水流量に合わせた電気量の確保ができ、生成された水質の安定が向上することができる。  Since the dissolved gas in the middle of the water discharge pipe can be released to the outside air, the pressure generated in the pipe is made uniform between the acidic electrolyzed water (anode side) and the alkaline electrolyzed water (cathode side), and the water volume ratio of each other does not collapse. Therefore, it is possible to ensure the amount of electricity that matches the water flow rate, and to improve the stability of the generated water quality.

また電解促進剤添加によって生じる電気量の大小の違いにおいて、電解で発生するガス量の違いにおいても、吐水配管途中に逆止弁などのガス抜き弁を1つまたは2つ以上設けることによって、ガスを外気へ放出できることができる。  In addition, even in the difference in the amount of electricity generated by the addition of an electrolysis accelerator, even in the difference in the amount of gas generated by electrolysis, by providing one or more degassing valves such as check valves in the middle of the water discharge pipe, Can be released to the outside air.

本発明の実施形態に係る電解水生成装置のフロー図である。It is a flowchart of the electrolyzed water generating apparatus which concerns on embodiment of this invention. 本発明のガス抜き構造の部分図の正面図である。It is a front view of the fragmentary figure of the degassing structure of this invention. 本発明のガス抜き構造の部分図の側面図である。It is a side view of the fragmentary figure of the degassing structure of this invention.

符号の説明Explanation of symbols

1 給水管 2 ストレーナ
3 給水電磁弁 4 減圧弁
5 フィルター 6 流量センサー
7 流量調整弁 8 定量ポンプ
9 電解槽 10a、10b 電極板
11 隔膜板 12 電解補助液タンク
13、14 逆止弁 15 酸性電解水吐水口
16 アルカリ性電解水吐水口 17 塩水カプラ
18 電解電源 19 排気口
20 電解槽入水口 21 電解槽酸性水出水口
22 電解槽アルカリ水出水水口 24 チーズ
DESCRIPTION OF SYMBOLS 1 Water supply pipe 2 Strainer 3 Water supply solenoid valve 4 Pressure reducing valve 5 Filter 6 Flow rate sensor 7 Flow rate adjustment valve 8 Metering pump 9 Electrolyzer 10a, 10b Electrode plate 11 Diaphragm plate 12 Electrolysis auxiliary liquid tank 13, 14 Check valve 15 Acidic electrolyzed water Water outlet 16 Alkaline electrolyzed water spout 17 Salt water coupler 18 Electrolytic power source 19 Exhaust port 20 Electrolyzer water inlet 21 Electrolyzer acid water outlet 22 Electrolyzer alkaline water outlet 24 Cheese

Claims (3)

収容した一対または二対以上の電極間に印加した所定電圧により外部供給源から供給される原水を電気分解して電解水を生成する電解槽を具備した電解水生成器において、陰極側で生成された陰極水と陽極側で生成された陽極水の吐水配管途中にガス抜き弁を、それぞれの配管に備えたことを特徴とする電解生成器。In an electrolyzed water generator comprising an electrolyzer that electrolyzes raw water supplied from an external supply source by a predetermined voltage applied between a pair of housed electrodes or two or more pairs of electrodes and generates electrolyzed water, the electrolyzed water generator is generated on the cathode side. An electrolysis generator, characterized in that a degassing valve is provided in each of the pipes in the middle of a water discharge pipe for the cathodic water and the anode water generated on the anode side. 請求項1に記載の電解水生成器において、ガス抜き弁が1箇所または2箇所以上備えたことを特徴とする電解水生成器。2. The electrolyzed water generator according to claim 1, wherein the degassing valve includes one or more degassing valves. 請求項1に記載の電解水生成器において、電解促進補助剤添加用のポンプを備えたことを特徴とする電解水生成器。2. The electrolyzed water generator according to claim 1, further comprising a pump for adding an electrolysis promoting auxiliary agent.
JP2004119635A 2004-03-19 2004-03-19 Electrolytic water generator provided with mechanism for removing gas generated in electrolysis Pending JP2005262195A (en)

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Cited By (4)

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JP2008126212A (en) * 2006-11-24 2008-06-05 Hoshizaki Electric Co Ltd Apparatus for producing electrolyzed water
JP2009112981A (en) * 2007-11-08 2009-05-28 Hoshizaki Electric Co Ltd Method for electrolysis operation of electrolytic water producing apparatus
JP5572734B1 (en) * 2013-05-21 2014-08-13 株式会社日本トリム ELECTROLYTIC CELL AND ELECTROLYTIC WATER GENERATOR HAVING THE SAME
CN115231633A (en) * 2022-06-27 2022-10-25 广东邦普循环科技有限公司 Waste storage battery electrolyte collecting and processing device and using method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008126212A (en) * 2006-11-24 2008-06-05 Hoshizaki Electric Co Ltd Apparatus for producing electrolyzed water
JP2009112981A (en) * 2007-11-08 2009-05-28 Hoshizaki Electric Co Ltd Method for electrolysis operation of electrolytic water producing apparatus
JP5572734B1 (en) * 2013-05-21 2014-08-13 株式会社日本トリム ELECTROLYTIC CELL AND ELECTROLYTIC WATER GENERATOR HAVING THE SAME
CN115231633A (en) * 2022-06-27 2022-10-25 广东邦普循环科技有限公司 Waste storage battery electrolyte collecting and processing device and using method thereof
CN115231633B (en) * 2022-06-27 2023-09-08 广东邦普循环科技有限公司 Waste storage battery electrolyte collecting and processing device and application method thereof

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