JP6301924B2 - 水素化ホウ素マグネシウム、及びマグネシウム輸送媒体としてのその誘導体 - Google Patents
水素化ホウ素マグネシウム、及びマグネシウム輸送媒体としてのその誘導体 Download PDFInfo
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- JP6301924B2 JP6301924B2 JP2015525613A JP2015525613A JP6301924B2 JP 6301924 B2 JP6301924 B2 JP 6301924B2 JP 2015525613 A JP2015525613 A JP 2015525613A JP 2015525613 A JP2015525613 A JP 2015525613A JP 6301924 B2 JP6301924 B2 JP 6301924B2
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- Prior art keywords
- magnesium
- electrolyte
- solvent
- battery
- salt
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- 239000011777 magnesium Substances 0.000 title claims description 133
- 229910052749 magnesium Inorganic materials 0.000 title claims description 88
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims description 81
- 239000006163 transport media Substances 0.000 title 1
- 239000003792 electrolyte Substances 0.000 claims description 82
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 68
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 claims description 55
- 239000002904 solvent Substances 0.000 claims description 44
- 159000000003 magnesium salts Chemical class 0.000 claims description 43
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 40
- 239000000010 aprotic solvent Substances 0.000 claims description 23
- 230000002378 acidificating effect Effects 0.000 claims description 21
- 239000000654 additive Substances 0.000 claims description 21
- 150000001768 cations Chemical class 0.000 claims description 21
- 230000000996 additive effect Effects 0.000 claims description 18
- 239000002738 chelating agent Substances 0.000 claims description 16
- 150000003839 salts Chemical class 0.000 claims description 12
- 239000002608 ionic liquid Substances 0.000 claims description 11
- -1 magnesium cations Chemical class 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 8
- 239000012448 Lithium borohydride Substances 0.000 claims description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
- 239000011591 potassium Substances 0.000 claims description 5
- 229910052700 potassium Inorganic materials 0.000 claims description 5
- 239000012279 sodium borohydride Substances 0.000 claims description 5
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 5
- 150000001450 anions Chemical class 0.000 claims description 4
- 230000008021 deposition Effects 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 12
- 238000003795 desorption Methods 0.000 description 12
- 239000000463 material Substances 0.000 description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 238000002484 cyclic voltammetry Methods 0.000 description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 8
- 230000002441 reversible effect Effects 0.000 description 8
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 description 7
- 238000005481 NMR spectroscopy Methods 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 4
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 4
- 238000000840 electrochemical analysis Methods 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 4
- 241000894007 species Species 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000010494 dissociation reaction Methods 0.000 description 3
- 230000005593 dissociations Effects 0.000 description 3
- 239000002001 electrolyte material Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 230000032258 transport Effects 0.000 description 3
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 2
- 238000004607 11B NMR spectroscopy Methods 0.000 description 2
- 238000005160 1H NMR spectroscopy Methods 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
- 229910017267 Mo 6 S 8 Inorganic materials 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910000085 borane Inorganic materials 0.000 description 2
- QYHKLBKLFBZGAI-UHFFFAOYSA-N boron magnesium Chemical compound [B].[Mg] QYHKLBKLFBZGAI-UHFFFAOYSA-N 0.000 description 2
- 150000003983 crown ethers Chemical class 0.000 description 2
- 239000012043 crude product Substances 0.000 description 2
- 238000006056 electrooxidation reaction Methods 0.000 description 2
- 238000002329 infrared spectrum Methods 0.000 description 2
- 229910001416 lithium ion Inorganic materials 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000011877 solvent mixture Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 241001432959 Chernes Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910020366 ClO 4 Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000006182 cathode active material Substances 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 150000004673 fluoride salts Chemical class 0.000 description 1
- 229910021397 glassy carbon Inorganic materials 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910001510 metal chloride Inorganic materials 0.000 description 1
- 229910001512 metal fluoride Inorganic materials 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000002734 organomagnesium group Chemical group 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 235000021018 plums Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0568—Liquid materials characterised by the solutes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
- C01B6/06—Hydrides of aluminium, gallium, indium, thallium, germanium, tin, lead, arsenic, antimony, bismuth or polonium; Monoborane; Diborane; Addition complexes thereof
- C01B6/10—Monoborane; Diborane; Addition complexes thereof
- C01B6/13—Addition complexes of monoborane or diborane, e.g. with phosphine, arsine or hydrazine
- C01B6/15—Metal borohydrides; Addition complexes thereof
- C01B6/19—Preparation from other compounds of boron
- C01B6/21—Preparation of borohydrides of alkali metals, alkaline earth metals, magnesium or beryllium; Addition complexes thereof, e.g. LiBH4.2N2H4, NaB2H7
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0569—Liquid materials characterised by the solvents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0567—Liquid materials characterised by the additives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
- H01M2300/0028—Organic electrolyte characterised by the solvent
- H01M2300/0037—Mixture of solvents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
- H01M2300/0045—Room temperature molten salts comprising at least one organic ion
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261678672P | 2012-08-02 | 2012-08-02 | |
| US61/678,672 | 2012-08-02 | ||
| US13/720,522 US9312566B2 (en) | 2012-08-02 | 2012-12-19 | Magnesium borohydride and its derivatives as magnesium ion transfer media |
| US13/720,522 | 2012-12-19 | ||
| US13/839,003 | 2013-03-15 | ||
| US13/839,003 US9318775B2 (en) | 2012-08-02 | 2013-03-15 | Magnesium borohydride and its derivatives as magnesium ion transfer media |
| US13/956,993 | 2013-08-01 | ||
| US13/956,993 US20140038037A1 (en) | 2012-08-02 | 2013-08-01 | Magnesium borohydride and its derivatives as magnesium ion transfer media |
| PCT/US2013/053331 WO2014022729A1 (en) | 2012-08-02 | 2013-08-02 | Magnesium borohydride and its derivatives as magnesium ion transfer media |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015523703A JP2015523703A (ja) | 2015-08-13 |
| JP2015523703A5 JP2015523703A5 (OSRAM) | 2016-09-23 |
| JP6301924B2 true JP6301924B2 (ja) | 2018-03-28 |
Family
ID=50025791
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015525613A Active JP6301924B2 (ja) | 2012-08-02 | 2013-08-02 | 水素化ホウ素マグネシウム、及びマグネシウム輸送媒体としてのその誘導体 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20140038037A1 (OSRAM) |
| EP (1) | EP2880706A4 (OSRAM) |
| JP (1) | JP6301924B2 (OSRAM) |
| KR (2) | KR102109796B1 (OSRAM) |
| CN (1) | CN104428940B (OSRAM) |
| WO (1) | WO2014022729A1 (OSRAM) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9362593B2 (en) | 2012-12-19 | 2016-06-07 | Toyota Motor Engineering & Manufacturing North America, Inc. | Borohydride solvo-ionic liquid family for magnesium battery |
| US9843080B2 (en) | 2014-04-11 | 2017-12-12 | Alliance For Sustainable Energy, Llc | Magnesium-based methods, systems, and devices |
| JP6287649B2 (ja) | 2014-07-08 | 2018-03-07 | 株式会社村田製作所 | 電解液及び電気化学デバイス |
| WO2016049309A1 (en) * | 2014-09-25 | 2016-03-31 | Virginia Commonwealth University | Halogen-free electrolytes |
| CN104538669B (zh) * | 2014-12-16 | 2017-11-10 | 上海交通大学 | 一种可充镁电池 |
| US20160181662A1 (en) * | 2014-12-23 | 2016-06-23 | Toyota Motor Engineering & Manufacturing North America, Inc. | Functionalized carboranyl magnesium electrolyte for magnesium battery |
| US9455473B1 (en) | 2015-05-12 | 2016-09-27 | Toyota Motor Engineering & Manufacturing North America, Inc. | Ionic liquids for rechargeable magnesium battery |
| US9716289B1 (en) | 2016-01-12 | 2017-07-25 | Toyota Motor Engineering & Manufacturing North America, Inc. | Solid-phase magnesium boranyl electrolytes for a magnesium battery |
| KR101864812B1 (ko) * | 2016-02-15 | 2018-06-05 | 다이슨 테크놀러지 리미티드 | 마그네슘 염 |
| US9997815B2 (en) * | 2016-08-05 | 2018-06-12 | Toyota Motor Engineering & Manufacturing North America, Inc. | Non-aqueous magnesium-air battery |
| US10910672B2 (en) | 2016-11-28 | 2021-02-02 | Toyota Motor Engineering & Manufacturing North America, Inc. | High concentration electrolyte for magnesium battery having carboranyl magnesium salt in mixed ether solvent |
| US10673095B2 (en) | 2017-09-13 | 2020-06-02 | Toyota Motor Engineering & Manufacturing North America, Inc. | Electrochemical cells having ionic liquid-containing electrolytes |
| US10680280B2 (en) | 2017-09-26 | 2020-06-09 | Toyota Jidosha Kabushiki Kaisha | 3D magnesium battery and method of making the same |
| CN108285130A (zh) * | 2018-02-11 | 2018-07-17 | 庄英俊 | 一种硼氢化锂的制备方法及检测方法 |
| CN110336079B (zh) * | 2019-06-24 | 2020-11-10 | 清华大学 | 镁电池电解液、其制备方法以及镁电池 |
| JP7384346B2 (ja) * | 2019-11-05 | 2023-11-21 | 国立大学法人山口大学 | マグネシウム二次電池用の絶縁抑制電解液及び絶縁抑制方法 |
| CN111370759B (zh) * | 2020-03-17 | 2023-03-17 | 清华大学 | 镁电池电解液及其制备方法和镁电池 |
| CN115000513B (zh) * | 2022-07-13 | 2025-06-10 | 广东省国研科技研究中心有限公司 | 一种宽电位窗口可充镁电池电解液及其制备方法 |
| CN116154295B (zh) * | 2023-04-04 | 2025-11-28 | 江西思远再生资源有限公司 | 一种用于镁电池的两性离子液体电解质 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL269399A (OSRAM) * | 1960-05-20 | 1900-01-01 | ||
| US3458531A (en) * | 1962-12-18 | 1969-07-29 | Du Pont | Salts of the b11h14- anion |
| US3355261A (en) * | 1963-04-29 | 1967-11-28 | Du Pont | Chemical process |
| US4020240A (en) * | 1975-09-03 | 1977-04-26 | P. R. Mallory & Co., Inc. | Electrochemical cell with clovoborate salt in electrolyte and method of operation and composition of matter |
| US4132837A (en) * | 1978-03-30 | 1979-01-02 | University Patents, Inc. | Electrochemical cells with non-aqueous electrolytes containing macroheterocyclic compounds |
| US4397925A (en) * | 1981-10-15 | 1983-08-09 | Ray-O-Vac Corporation | Alkaline battery with reducing agents in the electrolyte |
| US4894302A (en) * | 1985-06-14 | 1990-01-16 | The Dow Chemical Company | Alkaline earth metal anode-containing cell having electrolyte of organometallic alkaline earth metal salt and organic solvent |
| US4808282A (en) * | 1987-01-05 | 1989-02-28 | The Dow Chemical Company | Alkaline earth metal compounds and alkali metal substances via electrochemical process |
| CN1283315A (zh) * | 1997-12-26 | 2001-02-07 | 东燃珍宝石油株式会社 | 锂电池用电解液及其制造方法 |
| US6316141B1 (en) * | 1999-10-18 | 2001-11-13 | Bar Ilan University | High-energy, rechargeable, electrochemical cells with non-aqueous electrolytes |
| WO2001093363A2 (en) * | 2000-05-26 | 2001-12-06 | Covalent Associates, Inc. | Non-flammable electrolytes |
| US20040137324A1 (en) * | 2002-12-27 | 2004-07-15 | Masaharu Itaya | Electrolyte for nanaqueous battery, method for producing the same, and electrolytic solution for nonaqueous battery |
| US7785740B2 (en) * | 2004-04-09 | 2010-08-31 | Air Products And Chemicals, Inc. | Overcharge protection for electrochemical cells |
| US20060204843A1 (en) * | 2005-03-10 | 2006-09-14 | Ivanov Sergei V | Polyfluorinated boron cluster anions for lithium electrolytes |
| US20070048605A1 (en) | 2005-08-23 | 2007-03-01 | Pez Guido P | Stable electrolyte counteranions for electrochemical devices |
| US9722276B2 (en) * | 2008-05-13 | 2017-08-01 | Tohoku University | Solid electrolyte, method for producing the same, and secondary battery comprising solid electrolyte |
| US20110076572A1 (en) * | 2009-09-25 | 2011-03-31 | Khalil Amine | Non-aqueous electrolytes for electrochemical cells |
| US8354193B2 (en) * | 2010-04-12 | 2013-01-15 | Toyota Motor Engineering & Manufacturing North America | Electrolyte for a magnesium sulfur battery |
| US9112243B2 (en) * | 2013-04-08 | 2015-08-18 | Battelle Memorial Institute | Energy storage devices having anodes containing Mg and electrolytes utilized therein |
-
2013
- 2013-08-01 US US13/956,993 patent/US20140038037A1/en not_active Abandoned
- 2013-08-02 KR KR1020197005570A patent/KR102109796B1/ko active Active
- 2013-08-02 KR KR20157002865A patent/KR20150040900A/ko not_active Ceased
- 2013-08-02 WO PCT/US2013/053331 patent/WO2014022729A1/en not_active Ceased
- 2013-08-02 EP EP13826315.7A patent/EP2880706A4/en not_active Withdrawn
- 2013-08-02 JP JP2015525613A patent/JP6301924B2/ja active Active
- 2013-08-02 CN CN201380037003.6A patent/CN104428940B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP2880706A1 (en) | 2015-06-10 |
| EP2880706A4 (en) | 2016-09-14 |
| JP2015523703A (ja) | 2015-08-13 |
| WO2014022729A1 (en) | 2014-02-06 |
| CN104428940B (zh) | 2017-07-28 |
| US20140038037A1 (en) | 2014-02-06 |
| CN104428940A (zh) | 2015-03-18 |
| KR20150040900A (ko) | 2015-04-15 |
| KR102109796B1 (ko) | 2020-05-12 |
| KR20190021498A (ko) | 2019-03-05 |
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