JP6287371B2 - Optical film, optical film transfer body, and image display device - Google Patents

Description

  The present invention relates to an optical film having a retardation layer made of a liquid crystal material having reverse dispersion characteristics, a transfer member for an optical film, and an image display device.

  In recent years, an optical film applied to a flat panel display or the like has been provided that ensures a desired optical characteristic by imparting a desired retardation to transmitted light by a retardation layer (see, for example, Patent Document 1). . In this type of optical film, an alignment film is prepared on the surface of a substrate made of a transparent film or the like, and cured in a state where the liquid crystal material is aligned by the alignment regulating force of the alignment film, thereby forming a retardation layer. A liquid crystal material applied to such a retardation layer usually has a positive wavelength dispersion characteristic, but recently, a liquid crystal material having a reverse dispersion characteristic has been proposed (see, for example, Patent Documents 2 and 3). . Here, the reverse dispersion characteristic is a wavelength dispersion characteristic in which the phase difference in the transmitted light is smaller toward the shorter wavelength side, and more specifically, retardation at a wavelength of 450 nm (R450) and retardation at a wavelength of 550 nm (R550). The relationship is R450 <R550.

  In addition, in the image display panel, a method for improving various optical characteristics such as viewing angle characteristics and color using an A plate, a C plate, etc. has been proposed. A device for optical compensation of an ISP liquid crystal display device using a C plate has been proposed. Here, the optical compensation is a configuration that reduces light leakage in an oblique direction from the linear polarizing plate during black display. The C plate is represented by nx = ny <nz or nx = ny> nz, where nx = ny <nz is a positive C plate and nx = ny> nz is a negative C plate. The A plate is represented by nx> ny = nz or nz = nx> ny, where nx> ny = nz is a positive A plate and nz = nx> ny is a negative A plate. Note that nx and ny (nx ≧ ny) are refractive indexes in the in-plane direction, and nz is a refractive index in the thickness direction.

  Among these optical films, the positive A plate uses a liquid crystal material with a positive wavelength dispersion characteristic and a liquid crystal material with a reverse dispersion characteristic applied to the retardation layer, respectively, and has a positive wavelength dispersion characteristic and a reverse dispersion characteristic, respectively. Can be produced. Further, a positive C plate can be produced by applying a coating liquid made of a liquid crystal material for a so-called C plate and drying and curing it. In vertical alignment (VA) liquid crystal display devices and the like, a liquid crystal material is aligned in the vertical direction by a vertical alignment film, and various devices for the vertical alignment film for VA liquid crystal have been proposed.

  Such an optical film may be produced by a transfer method. Here, the transfer method refers to, for example, when a desired layer is formed on a predetermined base material, the desired layer is not directly formed on the base material, but once a releasable support. After the layer is formed on the (support substrate) in a peelable manner, the layer formed on the support is finally laminated according to the process, demand, etc. (the substrate to be transferred) ), And a desired layer is formed on a predetermined substrate by peeling and removing the support. It is considered that an optical film having a small overall thickness can be provided by producing an optical film by such a transfer method. In addition, the optical film produced by the transfer method is described in patent document 5 and patent document 6, for example.

  By the way, when producing a retardation layer using a liquid crystal material having a reverse dispersion characteristic, it has been found that the wavelength dispersion characteristic of the retardation layer changes with long-term use. As a result, it was found that the application to optical films and optical film transfer bodies provided with this type of retardation layer is still insufficient in terms of reliability.

JP-A-10-68816 U.S. Pat. No. 8,119,026 Japanese translation of PCT publication No. 2010-52892 JP-T 2006-520008 JP 2005-49865 A JP 2007-156234 A

  The present invention has been proposed in view of such circumstances, and relates to an optical film, a transfer member for an optical film, and an image display device that constitute a retardation layer using a liquid crystal material having reverse dispersion characteristics. The purpose is to reduce the change in characteristics.

  This inventor repeated earnest examination in order to solve the subject mentioned above. As a result, the reverse dispersion liquid crystal material has two kinds of mesogenic skeletons based on the positional relationship of twist, and the liquid crystal material is aligned by the alignment regulating force of the alignment film so as to correspond to this structure, thereby producing a retardation layer. In addition, the present invention has been completed by the idea that an orientation material that contributes to orientation in a direction orthogonal to the direction related to the orientation regulating force is added.

  Specifically, the present invention provides the following.

(1) An optical film including a retardation layer made of a liquid crystal material having reverse dispersion wavelength characteristics,
An alignment film for aligning the liquid crystal material in a vertical direction or a horizontal direction is provided in close contact with the retardation layer,
An alignment material that contributes to the alignment of the liquid crystal material in a direction orthogonal to the alignment direction due to the alignment regulating force of the alignment film was added to the material for forming the retardation layer.

  According to (1), according to a liquid crystal material having reverse dispersion wavelength characteristics produced by fixing a liquid crystal monomer having two types of mesogenic skeletons in a molecule in an aligned state so that the optical axes of the mesogens are aligned. Regarding the retardation layer, the alignment of the liquid crystal monomer can be prevented from being disturbed, and as a result, the change in wavelength dispersion characteristics can be reduced.

(2) An optical film including a retardation layer made of a liquid crystal material having reverse dispersion wavelength characteristics,
An alignment film for aligning the liquid crystal material in a vertical direction or a horizontal direction is provided in close contact with the retardation layer,
An alignment material that contributes to the alignment of the liquid crystal material in the direction orthogonal to the alignment direction due to the alignment regulating force of the alignment film was added to the material for forming the alignment film.

  According to (2), it depends on the liquid crystal material having the reverse dispersion wavelength characteristic produced by fixing the liquid crystal monomer having two kinds of mesogenic skeletons in the molecule so that the optical axes of the mesogens are aligned. Regarding the retardation layer, the alignment of the liquid crystal monomer can be prevented from being disturbed, and as a result, the change in wavelength dispersion characteristics can be reduced.

(3) In (1) or (2),
The alignment material is a surfactant.

  According to (3), a change in chromatic dispersion characteristics can be reduced with a more specific configuration.

(4) In (1), (2), (3), or (4),
The retardation layer is
The phase difference (Re0 (λ)) at 0 ° incidence at a wavelength λ of 450 nm to 650 nm is 20 nm or less, and the phase difference (Re40 (λ)) at 40 ° incidence is larger than the phase difference at 0 ° incidence.

  According to (4), the viewing angle characteristic can be improved by applying to the positive C plate.

  (5) An image display device in which the optical film of (1), (2), or (3) is disposed on the panel surface of the image display panel.

  According to (5), the change in the color of the panel surface can be suppressed by reducing the change in the wavelength dispersion characteristic.

(6) An optical film transfer body having a transfer layer,
With a retardation layer made of liquid crystal material with reverse dispersion wavelength characteristics,
An alignment film for aligning the liquid crystal material in a vertical direction or a horizontal direction is provided in close contact with the retardation layer,
An alignment material that contributes to the alignment of the liquid crystal material in a direction orthogonal to the alignment direction due to the alignment regulating force of the alignment film was added to the material for forming the retardation layer.

  According to (6), the liquid crystal monomer having two kinds of mesogenic skeletons in the molecule is fixed by aligning the optical axes of the mesogens so that the optical axes of the mesogens are aligned. Regarding the retardation layer, the alignment of the liquid crystal monomer can be prevented from being disturbed, and as a result, the change in wavelength dispersion characteristics can be reduced.

(7) An optical film transfer body having a transfer layer,
With a retardation layer made of liquid crystal material with reverse dispersion wavelength characteristics,
An alignment film for aligning the liquid crystal material in a vertical direction or a horizontal direction is provided in close contact with the retardation layer,
An alignment material that contributes to the alignment of the liquid crystal material in the direction orthogonal to the alignment direction due to the alignment regulating force of the alignment film was added to the material for forming the alignment film.

  According to (7), according to the liquid crystal material having the reverse dispersion wavelength characteristic produced by fixing the liquid crystal monomer having two kinds of mesogenic skeletons in the molecule in an aligned state so that the optical axes of the mesogens are aligned. Regarding the retardation layer, the alignment of the liquid crystal monomer can be prevented from being disturbed, and as a result, the change in wavelength dispersion characteristics can be reduced.

  ADVANTAGE OF THE INVENTION According to this invention, the change of a wavelength dispersion characteristic can be reduced regarding the optical film which comprises a phase difference layer using the liquid crystal material by a reverse dispersion characteristic, and the transfer body for optical films.

It is a cross-sectional schematic diagram which shows the transfer body for optical films. It is sectional drawing which shows an optical film. It is a flowchart which shows the flow of the manufacturing process of the transfer body for optical films of FIG. It is a figure for demonstrating the flow which produces the optical film of FIG. It is a figure where it uses for description of the change of chromatic dispersion. It is a figure where it uses for description of reduction of the change of a wavelength dispersion characteristic.

  Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.

[First Embodiment]
[Transfer for optical film]
FIG. 1 is a cross-sectional view schematically showing an example of an optical film transfer body 1 according to the present embodiment. As shown in FIG. 1, a transfer body 1 for an optical film has a support substrate 11 made of polyethylene terephthalate (PET), an alignment film 12, and a retardation layer (liquid crystal layer) 13 laminated in this order. It will be.

  The optical film transfer body 1 is, for example, an optical functional layer of a linearly polarizing plate or an optical functional layer (for example, composed of a reverse dispersion stretched film) that imparts a phase difference corresponding to ¼ wavelength to transmitted light. A transfer body for an optical film provided with a transfer layer transferred by a transfer method, and a laminate of the retardation layer 13 and the alignment film 12 constitutes a transfer layer. In this optical film transfer body 1, for example, a transfer film is transferred onto the retardation layer 13 by bonding a polymer film such as a reverse dispersion stretched film via an adhesive, and a linear polarizing plate is further applied. By combining them, a predetermined optical film can be produced. At this time, when producing the optical film, after transferring the transfer layer to a substrate such as a reverse dispersion stretched film on the optical film transfer body 1, only the support substrate having releasability is peeled off.

  In the optical film transfer body 1 according to the present embodiment, the retardation layer 13 is a retardation layer that functions as a positive C plate. That is, the retardation layer 13 has nx = ny <nz or nx = ny> nz, nx = ny <nz, and has a phase difference (Re0 (λ0)) at 0 ° incidence (incident angle 0 °) at a wavelength λ of 450 nm to 650 nm. )) Is 20 nm or less, the phase difference (Re40 (λ)) at an oblique incidence of 40 degrees is larger than the phase difference at an incidence of 0 degree, and the phase difference Re40 (λ) increases as the wavelength λ increases. With increasing optical properties. Here, Re is an in-plane phase difference.

  The alignment film 12 is a vertical alignment film having an alignment regulating force in the vertical direction corresponding to the retardation layer 13, and the retardation layer 13 has a reverse dispersion characteristic depending on the state oriented to the alignment regulating force of the vertical alignment film. It is created by curing (solidifying) the liquid crystal material.

  In this embodiment, a material that contributes to alignment in a direction orthogonal to the direction related to the alignment regulating force of the alignment film 12 (hereinafter referred to as an alignment material) is added to the material of the retardation layer 13 to thereby add the retardation layer. 13 is produced, thereby reducing the change in wavelength dispersion characteristics. That is, the liquid crystal material having reverse dispersion wavelength characteristics includes two types of liquid crystal monomers having a mesogenic skeleton depending on the positional relationship of twist, and the retardation layer 13 is cured (solidified) in a state where the liquid crystal monomers are aligned in the vertical direction. Created. The reason why the change in the wavelength dispersion characteristic is reduced is that when the retardation layer 13 is formed by adding an alignment material, the alignment regulating force can be set so as to correspond to these two types of mesogenic skeletons. This is considered to be because the binding force of the liquid crystal monomer can be increased as compared with the case where no functional material is added.

<1-1. Support base material>
The support substrate 11 is a film material made of polyethylene terephthalate (PET), which has a function of indicating the alignment film 12 and is formed in a long shape.

  The support substrate 11 functions as a releasable support in the optical film transfer body 1 and supports the alignment film 12 and the retardation layer 13 forming a transfer layer.

  Although it does not specifically limit as thickness of the support base material 11, For example, it is preferable to set it as the range of 20 micrometers-200 micrometers. If the thickness of the support substrate 11 is less than 20 μm, it may not be possible to provide the minimum necessary self-supporting property as an optical film transfer body, which is not preferable. On the other hand, when the thickness exceeds 200 μm, when the optical film transfer body is long, the long optical film transfer body is cut into a single-wafer optical film transfer body. , Undesirably, processing scrap increases and wear of the cutting blade may be accelerated.

<1-2. Alignment film>
The alignment film 12 is obtained by coating and curing the alignment film composition (alignment film composition) on the support substrate 11 described above, and exhibits an alignment regulating force. Here, the alignment regulating force is a function of arranging (orienting) the liquid crystal compound in a specific direction when a layer (retardation layer 13) made of a polymerizable liquid crystal compound (liquid crystal material) is formed on the alignment film 12. Say. In this embodiment, a vertical alignment film in which the specific direction is the vertical direction (the thickness direction of the retardation layer) is applied.

  The alignment film 12 is not particularly limited, but various vertical alignment films applied to, for example, a VA liquid crystal display device can be applied. For example, a polyimide alignment film, an alignment film using an LB film, or the like is applied. can do.

  More specifically, as the vertical alignment film, for example, lecithin, silane-based surfactant, titanate-based surfactant, pyridinium salt-based polymer surfactant, and silane coupling-based vertical alignment such as n-octadecyltriethoxysilane. Composition for film, soluble polyimide having long chain alkyl group or alicyclic structure in side chain, composition for polyimide vertical alignment film such as polyamic acid having long chain alkyl group or alicyclic structure in side chain, etc. It can be formed using a material. In addition, as a composition for vertical alignment films, a composition for a polyimide-based vertical alignment film “JALS-2021” and “JALS-204” manufactured by JSR Co., Ltd., and “RN-1517” manufactured by Nissan Chemical Industries, Ltd. , "SE-1211", "EXPOA-018" and other commercial products can be applied.

  The solvent (dilution solvent) used in the alignment film composition is not particularly limited as long as it can dissolve the alignment material at a desired concentration. For example, hydrocarbon solvents such as benzene and hexane, methyl ethyl ketone, Ketone solvents such as methyl isobutyl ketone and cyclohexanone (CHN), ether solvents such as tetrahydrofuran, 1,2-dimethoxyethane, propylene glycol monoethyl ether (PGME), alkyl halide solvents such as chloroform and dichloromethane, methyl acetate Ester solvents such as ethyl acetate, butyl acetate, propylene glycol monomethyl ether acetate (PGMEA), amide solvents such as N, N-dimethylformamide, sulfoxide solvents such as dimethyl sulfoxide, anan solvents such as cyclohexane, Methanol, ethanol, isopropyl alcohol (hereinafter, referred to as. "IPA") can be exemplified an alcohol solvent such as. Moreover, one type of solvent may be sufficient and the mixed solvent of two or more types of solvents may be sufficient.

  Such an alignment film 12 made of a vertical alignment film or the like is produced by applying a coating liquid made of an alignment film composition containing the material as described above to the support substrate 11, drying, and heating. The The alignment film 12 is composed of the cured product thus produced.

<1-3. Retardation layer (liquid crystal layer)>
The retardation layer (liquid crystal layer) 13 contains a polymerizable liquid crystal composition. This polymerizable liquid crystal composition contains a liquid crystal compound exhibiting liquid crystallinity and having a polymerizable functional group in the molecule. The retardation layer 13 is obtained by adding an orientation material to a raw material.

  The liquid crystal compound has refractive index anisotropy and has a function of imparting a desired retardation by regularly arranging the liquid crystal compound. Examples of the liquid crystal compound include materials exhibiting a liquid crystal phase such as a nematic phase and a smectic phase, but the nematic phase is easier in order to arrange regularly than liquid crystal compounds exhibiting other liquid crystal phases. It is preferable to use a material exhibiting the above liquid crystallinity. The liquid crystal compound exhibiting a nematic phase is preferably a material having spacers at both ends of the mesogen. Since the liquid crystal compound having spacers at both ends of the mesogen is excellent in flexibility, the optical film can be excellent in transparency.

  In addition, when the alignment film 12 described above is made of a vertical alignment film and the liquid crystal compound is homeotropically aligned, there is no particular limitation as long as it is a homeotropic liquid crystal material capable of forming homeotropic alignment. Examples of the homeotropic liquid crystal material include materials that can form homeotropic alignment without using a vertical alignment film, and materials that can form homeotropic alignment by using a vertical alignment film. In the present embodiment, either can be suitably used.

  The liquid crystal compound is a polymerizable liquid crystal compound having a polymerizable functional group in the molecule as described above. By having a polymerizable functional group, it is possible to polymerize and fix the liquid crystal compound, so that the alignment stability is excellent and the phase change is less likely to occur over time. The polymerizable liquid crystal compound more preferably has a polymerizable functional group capable of three-dimensional crosslinking in the molecule. By having a polymerizable functional group capable of three-dimensional crosslinking, the sequence stability can be further enhanced. Note that “three-dimensional crosslinking” means that liquid crystal molecules are polymerized three-dimensionally to form a network structure.

  Examples of the polymerizable functional group include those that polymerize by the action of ionizing radiation such as ultraviolet rays and electron beams, or heat. Examples of these polymerizable functional groups include radical polymerizable functional groups and cationic polymerizable functional groups. Representative examples of radically polymerizable functional groups include functional groups having at least one addition-polymerizable ethylenically unsaturated double bond, such as vinyl groups having or without substituents, acrylate groups (acryloyl). Group, methacryloyl group, acryloyloxy group, generic name including methacryloyloxy group) and the like. Moreover, an epoxy group etc. are mentioned as a specific example of a cationically polymerizable functional group. In addition, examples of the polymerizable functional group include an isocyanate group and an unsaturated triple bond. Among them, a functional group having an ethylenically unsaturated double bond is preferably used from the viewpoint of the process.

  The amount of the polymerizable liquid crystal compound is not particularly limited as long as the viscosity of the retardation layer forming coating liquid (liquid crystal composition) can be adjusted to a desired value according to the coating method applied on the alignment film 12. Although it does not specifically limit, For example, it can be in the range of about 5-40 mass parts as a quantity in a liquid-crystal composition. In addition, a polymeric liquid crystal compound can be used individually by 1 type or in mixture of 2 or more types.

  The liquid crystal compound described above is usually dissolved in a solvent (dilution solvent). The solvent is not particularly limited as long as it can uniformly disperse liquid crystal compounds and the like. For example, hydrocarbon solvents such as benzene and hexane, ketone solvents such as methyl ethyl ketone, methyl isobutyl ketone, and cyclohexanone (CHN). Solvent, ether solvents such as tetrahydrofuran, 1,2-dimethoxyethane, propylene glycol monoethyl ether (PGME), halogenated alkyl solvents such as chloroform and dichloromethane, methyl acetate, ethyl acetate, butyl acetate, propylene glycol monomethyl ether acetate Ester solvents such as (PGMEA), amide solvents such as N, N-dimethylformamide, sulfoxide solvents such as dimethyl sulfoxide, anone solvents such as cyclohexane, methanol, ethanol, isopropyl It can be exemplified an alcohol solvent such as alcohol, but is not limited thereto. Further, the solvent may be one kind or a mixed solvent of two or more kinds of solvents.

  The amount of the solvent is not particularly limited and can be, for example, about 66 to 900 parts by mass with respect to 100 parts by mass of the liquid crystal compound. If the amount of the solvent is less than 66 parts by mass, the liquid crystal compound may not be dissolved uniformly, which is not preferable. On the other hand, when the amount exceeds 900 parts by mass, a part of the solvent remains, which may reduce reliability and may not be uniformly applied.

  In addition, the liquid crystal composition may contain other compounds as necessary, as long as the alignment order of the liquid crystal compounds described above is not impaired. Examples thereof include a polymerization inhibitor, a plasticizer, a surfactant, and a silane coupling agent.

  The thickness of the retardation layer 13 formed by coating the liquid crystal composition as described above on the alignment film 12 is not particularly limited. It is preferably about 4000 nm.

  The alignment material is a material that contributes to alignment in the direction orthogonal to the direction related to the alignment regulating force of the alignment film 12, and more specifically, the liquid crystal of the retardation layer 13 applied to the support substrate 11. The material has a function of orienting the material in the in-plane direction of the coating layer. In this embodiment, by applying a surfactant that smoothes the surface of the coated coating liquid in the in-plane direction, the alignment regulating force that orients the liquid crystal material in the in-plane direction perpendicular to the vertical direction is phase-differenced. Apply to layer 13.

  Here, various materials such as a compound having an acrylic group, a compound having a fluorine group, and a compound having a siloxane bond can be applied to the surfactant. When the amount of the surfactant added is small, it cannot exhibit a sufficient function, and as a result, the change in wavelength dispersion characteristics cannot be sufficiently reduced. However, when the addition amount is too large, the alignment regulating force by the alignment film 12 is impaired. Therefore, in the solid component in the coating liquid of the retardation layer 13, the addition amount is 0.01 wt% or more and 5.0 wt% or less, more preferably 0.05 wt% or more and 1.0 wt% or less. Add by volume.

[Optical film]
FIG. 2 is a view showing an optical film produced by the optical film transfer body 1. In the optical film 1, a stretched film 22 that functions as a quarter-wave plate is laminated via a bonding layer 21 on a positive C plate composed of a transfer layer formed of a laminate of an alignment film 12 and a retardation layer 13. Further, a linearly polarizing plate (34, 33, 32) is laminated thereon via an adhesive layer 31.

  In the image display apparatus according to this embodiment, the optical film 1 is disposed on the panel surface of the image display panel. Thus, in this embodiment, extraneous light traveling toward the panel surface of the image display panel is converted into linearly polarized light by the linearly polarizing plates (34, 33, 32), and then converted into circularly polarized light by the ¼ wavelength plate (22). The light passes through the positive C plate and enters the panel surface of the image display panel. Here, the extraneous light by the circularly polarized light is reflected by the surface of the image display panel or the like, but the rotation direction of the polarization plane is reversed during the reflection. As a result, this reflected light is converted into linearly polarized light in the direction shielded by the linear polarizing plate by the ¼ wavelength plate, contrary to the arrival time, and then shielded by the subsequent linear polarizing plate. Outgoing emission is significantly suppressed. Thereby, in this embodiment, reflection of extraneous light is efficiently reduced.

  The positive C plate is configured such that the optical characteristics in the front direction of the image display panel (characteristics of the antireflection function) are extended in the viewing angle direction of the image display panel, thereby ensuring a wide viewing angle characteristic.

  In the image display device and the optical film 15 thus configured, as described above with respect to the optical film transfer body 1, the change in wavelength dispersion characteristics is achieved by adding an orientation material to the retardation layer 13. As a result, a change in the color of the image display panel can be effectively avoided.

[Method for producing optical film transfer body]
Next, the manufacturing method of the transfer body for optical films is demonstrated. FIG. 3 is a flowchart showing the flow of the manufacturing process of the optical film transfer body 1.

  As shown in FIG. 3, in the production of the optical film transfer body 1, first, a support substrate 11 made of a PET film is provided from a long film wound around a roll.

  Next, in the alignment film forming step, a coating liquid (alignment film composition) for the vertical alignment film is applied on the support substrate 11 drawn out from the roll, and subjected to a heat curing process using a dryer or the like. . Thereby, the alignment film 12 by the vertical alignment film is formed on the support substrate 11.

  Next, in the retardation layer forming step, a liquid crystal composition coating liquid containing a liquid crystal compound (a retardation layer forming coating liquid) is applied onto the alignment film 12. In this embodiment, a surfactant is added to this coating solution. Thereafter, the coated coating liquid is dried and cured by irradiation with ultraviolet rays or the like, thereby forming a retardation layer (liquid crystal layer) 13. Prior to drying, a leveling process may be performed by leaving the retardation layer 13 for a certain period of time to make the thickness of the retardation layer 13 uniform.

  In this way, a laminate film in which the support substrate 11 / alignment film 12 / retardation layer 13 are laminated in this order is produced, and the obtained film is wound up by a take-up reel or the like. Through such steps, the optical film transfer body 1 is produced.

  The coating method of the alignment film composition on the support substrate 11 and the coating method of the retardation layer forming coating liquid on the alignment film 12 are not particularly limited. For example, , Die coating method, gravure coating method, reverse coating method, knife coating method, dip coating method, spray coating method, air knife coating method, spin coating method, roll coating method, printing method, dipping and lifting method, curtain coating method, casting method , Bar coating method, extrusion coating method, E-type coating method and the like can be used.

[Method for producing optical film]
Next, a method for producing an optical film by the transfer method using the optical film transfer body described above will be described. FIG. 4 shows an optical film transfer body that is formed of a reverse dispersion stretched film using an optical film transfer body 1 according to the present embodiment and that imparts a phase difference corresponding to 1/4 wavelength to transmitted light. It is a figure which shows the flow of the process at the time of transferring the transfer layer of 1 and producing an optical film. In addition, this FIG. 4 is a figure which shows the cross section of a film, and is a figure which shows the flow of a process, showing the layer structure of the film in each process. Further, the layer structure of the film is not limited to this.

  Here, as shown in FIG. 4A, in this embodiment, the optical film transfer body 1 is formed by the process described above with reference to FIG. Next, as shown in FIG. 4B, an adhesive layer 21 containing, for example, a UV adhesive is formed on the retardation layer 13 of the produced optical film transfer body 1, and the adhesive layer 21 is formed on the adhesive layer 21. The polymer film 22 is formed, and the optical film transfer body 1 is transferred.

  Various adhesives such as an ultraviolet curable resin, a thermosetting resin, and a pressure sensitive adhesive can be widely applied as the adhesive layer 21. Among them, ultraviolet (UV) is used from the viewpoint of reducing the overall thickness. It is preferable to apply a curable resin to form a UV adhesive layer. In this case, an adhesive layer having a thickness of about 1 μm can be produced. An adhesive layer may be applied to the adhesive layer 21.

  The polymer film is not particularly limited, and for example, a stretched film having reverse dispersion characteristics (hereinafter also referred to as “reverse dispersion stretched film 22”) can be used. The reverse dispersion stretched film 22 is formed of, for example, a COP (cycloolefin polymer) film that is stretched in one axial direction or obliquely stretched in a desired direction, and the slow axis is relative to the absorption axis of the linearly polarizing plate. Thus, it is arranged so as to form an angle of 45 degrees counterclockwise, and plays a role as a retardation layer for a quarter wavelength plate that imparts a phase difference corresponding to a quarter wavelength to transmitted light. By using such a reverse dispersion stretched film 22, for example, the configuration of the base material, the resin layer for a quarter wavelength plate, and the alignment film for a quarter wavelength plate can be omitted. The layer thickness can be reduced.

  A polymer film 22 such as a reverse dispersion stretched film is laminated on the optical film transfer body 1, and then the support substrate 11 of the optical film transfer body 1 is peeled as shown in FIG. 4 (c). The optical film transfer body 1 plays a role as a releasable support in order to transfer the transfer layer (retardation layer 13 and alignment film 12) to another base material (polymer film or the like) in this way. The support substrate 11 is peeled off. In addition, you may make it perform peeling of the support body base material 11 after laminating | stacking the linear polarizing plate mentioned later.

  And if the support base material 11 of the transfer body 1 for optical films is peeled, next, as shown in FIG.4 (d), the linearly polarizing plate provided with the adhesive layer 31 is laminated | stacked.

  As the linear polarizing plate, the optical functional layer is disposed after the lower surface side of the base material 34 made of a transparent film such as TAC (triacetyl cellulose) is saponified. In addition, the base material 34 is poly (meth) methyl acrylate, poly (meth) butyl acrylate, (meth) methyl acrylate- (meth) butyl acrylate copolymer, (meth) methyl acrylate-styrene copolymer. Resins such as acrylic resin such as coalescence, glass such as soda glass, potassium glass, lead glass, and quartz glass can also be applied.

  The optical functional layer is a part responsible for the optical function as a linear polarizing plate, and for example, a layer in which a polarizer 33 and a transparent protective film (base material) 32 made of an acrylic resin or the like are sequentially laminated are used. Can do. Such a linearly polarizing plate is bonded to a polymer film 22 such as a reverse dispersion stretched film via an adhesive layer 31.

  Based on the above processes, an optical film can be produced by a transfer method using the optical film transfer body 1.

〔Study results〕
5 and 6 are diagrams showing the examination results. FIG. 5 is a diagram showing a measurement result of the change over time of the retardation layer when no alignment material is added. The sample to be used for the measurement was coated with a coating solution for a vertical alignment film on a transparent film material (PET film) having a thickness of 100 μm, dried and cured, and then coated with a coating solution for a retardation layer and dried and cured. It has been made.

  For the coating of the vertical alignment film, EXPOA-018, one of the inorganic vertical alignment film materials, was dissolved in an ethanol / butyl cellosolve solvent at a concentration of 4% and used in a dilute solution state. The vertical alignment film was prepared by coating EXPOA-018 on a base material made of PET film (Toyobo E5100) by a die head coating method (film thickness: 100 nm) and drying at a drying temperature of 120 ° C. for 5 minutes.

(Retardation layer coating solution)
A mixture of compound (1), RM (1), and RM (3) described in JP-T-2010-528992 is added to the vertical alignment film on the PET substrate thus prepared in a mixing ratio of 5: 3: 2. Then, an ink (coating liquid) was prepared by dissolving in a 7: 3 mixed solvent of toluene / cyclohexanone and adjusting the solid content concentration to 21.5%, and this coating liquid was measured at a wavelength of 552 nm. The flow rate was adjusted during coating so that the thickness retardation Rth (552) at -80 nm was -80 nm. Thereafter, the film was dried at a drying temperature of 65 ° C. for 5 minutes, and then fixed by being cured by irradiating with an ultraviolet ray so that the irradiation amount was 380 mJ / cm ² with an H bulb manufactured by Fusion. In order to cancel the phase difference of the PET film as the substrate, the liquid crystal layer was transferred to glass with adhesive, and the phase difference at 0 degree incidence of each wavelength using KOBRA-WR manufactured by Oji Scientific Instruments Co., Ltd. The thickness phase difference Rth at each wavelength was calculated from the measured values of Re0 (λ)) and the phase difference (Re40 (λ)) at an oblique incidence of 40 degrees. It was confirmed that the prepared sample had Re0 (590) of 2 nm or less and was a positive C plate.

  The vertical axis in FIG. 5 is a division value obtained by dividing the thickness phase difference Rth at a wavelength of 450 nm by the thickness phase difference Rth at a wavelength of 550 nm, and the horizontal axis is a standing time in each environment. The subscript L is the temperature of each environment, L100 is a change over time in an environment at a temperature of 100 degrees, and L85 and LN are changes over time at a temperature of 85 degrees and room temperature, respectively. L-40 is a change with time at a temperature of -40, and L60 is a change with time at a temperature of 60 degrees and a humidity of 95%.

  According to this measurement result, it can be seen that the chromatic dispersion changes abruptly when the ambient temperature is high.

  FIG. 6 is a diagram showing the characteristics when an alignment material is added to the retardation layer in the measurement sample that is in the state of FIG. Here, the orientation material is Megafac Series F470 manufactured by DIC, and the amount added is 0.2% by weight.

  Symbols L1 and L2 are division values obtained by dividing the thickness phase difference Rth at a wavelength of 630 nm by the thickness phase difference Rth at a wavelength of 550 nm, the symbol L3 is a change over time at a temperature of 85 degrees, and L4 is a temperature of 60 degrees and humidity. Change over time at 95%. Symbols L1 and L2 are division values obtained by dividing the thickness phase difference Rth at a wavelength of 450 nm by the thickness phase difference Rth at a wavelength of 550 nm, the symbol L1 is a change over time at a temperature of 85 degrees, and L2 is a temperature of 60 degrees and humidity Change over time at 95%.

  According to FIG. 6, it can be seen that the change in chromatic dispersion is significantly suppressed as compared with the conventional case.

[Second Embodiment]
In this embodiment, an alignment material is added to the alignment film 12 instead of or in addition to the retardation layer 13 (see FIG. 1). This embodiment has the same configuration as that of the first embodiment except that the added portion is different.

  Here, as in this embodiment, even if an alignment material is added to the alignment film 12 related to the alignment regulating force in the vertical direction, the same effect as in the first embodiment can be obtained.

[Third Embodiment]
In this embodiment, the normal A plate is made of a liquid crystal material having reverse dispersion characteristics to make an optical film and an optical film transfer body. Such an optical film is, for example, an optical film used for optical compensation.

  More specifically, in this embodiment, an alignment film having an alignment regulating force in the horizontal direction is formed on a substrate made of a transparent film material, and a retardation layer is formed on the alignment film by a reverse dispersion liquid crystal material. Create In this alignment film, various configurations such as a photo-alignment film and a line-shaped fine uneven shape can be widely applied. In this optical film, a retardation layer is prepared by applying a coating solution for the retardation layer on the alignment film and drying and curing the coating film.

  Here, in this embodiment, since the alignment film has a horizontal alignment regulating force, the alignment material contributing to the alignment of the liquid crystal material in the direction orthogonal to the direction of the alignment regulating force is the retardation layer and / or It is added to the material for forming the alignment layer. More specifically, an alignment material that contributes to the alignment of the liquid crystal material in the vertical direction is applied. For example, a material that is used for forming a vertical alignment film is added.

  In this embodiment, even when an optical film transfer body and an optical film having an A plate are produced, the same effects as those of the first embodiment or the second embodiment can be obtained.

[Other Embodiments]
The specific configuration suitable for the implementation of the present invention has been described in detail above. However, the present invention is not limited to the scope of the present invention, and various combinations of the above-described embodiments, and further the configuration of the above-described embodiments. Can be variously changed.

  That is, in the above-described embodiment, the case where an optical film is formed using the optical film transfer body is described. However, the present invention is not limited to this, and the optical film is formed by directly forming a retardation layer on a transparent film material. The present invention can also be widely applied when creating a film.

DESCRIPTION OF SYMBOLS 1 Transfer body for optical films 11 Support base material 12 Alignment film 13 Phase difference layer (liquid crystal layer)
DESCRIPTION OF SYMBOLS 15 Optical film 21 Adhesive layer 22 Stretched film 31 Adhesive layer 32 Protective film 33 Polarizer 34 Base material

Claims (4)

An optical film having a retardation layer made of a liquid crystal material with reverse dispersion wavelength characteristics,
An alignment film for aligning the liquid crystal material in the vertical direction is provided in close contact with the retardation layer,
An alignment material that contributes to the alignment of the liquid crystal material in a direction orthogonal to the alignment direction due to the alignment regulating force of the alignment film is added to the material for forming the retardation layer,
The liquid crystal material is a liquid crystal material having two types of mesogenic skeletons due to the positional relationship of twisting,
The alignment material is, Ri surfactant der,
The optical film whose content of the said surfactant is 0.01 weight% or more and 1.0 weight% or less in the solid component of the material which produces the said phase difference layer . The retardation layer is
The phase difference (Re0 (λ)) at 0 ° incidence at a wavelength λ of 450 nm to 650 nm is 20 nm or less, and the phase difference at 40 ° incidence (Re40 (λ)) is larger than the phase difference at 0 ° incidence.
The optical film according to claim 1. An image display device in which the optical film according to claim 1 or 2 is disposed on a panel surface of an image display panel. A transfer body for an optical film having a transfer layer,
With a retardation layer made of liquid crystal material with reverse dispersion wavelength characteristics,
An alignment film for aligning the liquid crystal material in the vertical direction is provided in close contact with the retardation layer,
An alignment material that contributes to the alignment of the liquid crystal material in a direction orthogonal to the alignment direction due to the alignment regulating force of the alignment film is added to the material for forming the retardation layer,
The liquid crystal material is a liquid crystal material having two types of mesogenic skeletons due to the positional relationship of twisting,
The alignment material is, Ri surfactant der,
The transfer body for optical films whose solid component of the material which produces the said phase difference layer WHEREIN: Content of the said surfactant is 0.01 weight% or more and 1.0 weight% or less .

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