JP6264735B2 - Adhesive tape base paper - Google Patents

Description

  The present invention relates to a base paper (base paper for adhesive tape) used as a support for an adhesive tape.

Although active use of plant-derived resources is a requirement of the times, plant fibers, which are green and sustainable materials, have many possibilities, but often fail in performance. For this reason, the actual situation is that development in the fields of automobiles, houses, home appliances, etc., in which the use of plant fibers is expected, has not progressed sufficiently.
Cellulose fiber-containing sheets are an example of effective use of an old green sustainable material, but in a long history, weight reduction and strength improvement have progressed, but the degree of improvement has never been large, and high strength Insufficient expansion to required applications. In many applications, there is a strong need for paper products based on higher strength plant fibers.

As a report example for improving the functionality of an adhesive tape, an adhesive tape has been proposed in which a nonwoven fabric derived from Manila hemp is impregnated with carboxymethyl cellulose to suppress the occurrence of shrinkage wrinkles (Patent Document 1).
As a method for producing an adhesive tape, a method in which an adhesive is applied to a sheet that has been peeled off, and then a base paper for an adhesive tape is pasted (transfer method), or a method in which an adhesive is directly applied to the base paper (direct method) Is mentioned. The transfer method has a complicated process, and requires a sheet that has been subjected to a peeling treatment, which is inferior in productivity. In contrast, the direct method allows efficient production.
In the adhesive tape, the adhesion between the adhesive layer and the base paper is important. The pressure-sensitive adhesive layer has a large dimensional change with respect to temperature and tends to extend. Therefore, if the adhesive tape base paper has a small dimensional change with respect to temperature change and high adhesiveness with the adhesive layer, an adhesive tape utilizing the dimensional stability of the adhesive tape base paper can be obtained. When the pressure-sensitive adhesive layer is formed by the direct method, if the pressure-sensitive adhesive easily penetrates into the pressure-sensitive adhesive tape base paper, the adhesiveness between the pressure-sensitive adhesive layer and the base paper increases, and a pressure-sensitive adhesive tape excellent in dimensional stability can be obtained.
It is also important that the adhesive tape base paper used as the adhesive tape base paper has high tensile strength. However, an adhesive tape base paper having excellent dimensional stability and adhesive impregnation property and high tensile strength has not been known.

JP 2008-44954 A

  The subject of this invention is providing the base paper (base paper for adhesive tapes) which is excellent in dimensional stability and the impregnation property of an adhesive, and is a support body of an adhesive tape with high tensile strength.

The present invention has the following aspects.
[1] Der tensile strength than 25MPa measured according to JIS P8113 of the base paper used as a support of the adhesive tape (base paper for adhesive tape) is, the density of the base paper is 0.50~0.85g / cm ³ , and the said base paper contains cellulose fibers, said cellulose fibers have an average fiber width of Ru less fine cellulose fibers der 1000 nm, the pressure-sensitive adhesive tape base paper.
[2] The adhesive tape base paper according to [1], wherein the linear thermal expansion coefficient in the measurement range at 50 to 150 ° C. of the base paper is 20 ppm / K or less.
[3] Wang Kenshiki air permeability of the base paper is less than 50,000 seconds, [1] or pressure-sensitive adhesive tape original sheet according to [2].

  The base paper used as the support of the pressure-sensitive adhesive tape of the present invention is excellent in dimensional stability and pressure-sensitive adhesive impregnation, and has high tensile strength.

The present invention will be described in detail below.
The base paper of the pressure-sensitive adhesive tape of the present invention has the following physical properties.
(Physical properties of base paper for adhesive tape)

[Tensile strength]
The tensile strength of the adhesive tape base paper is 25 MPa or more, more preferably 25 to 80 MPa, and further preferably 30 to 80 MPa. The tensile strength is a value measured according to JIS P8113.

[Linear thermal expansion coefficient]
The linear thermal expansion coefficient in the measurement range at 50 to 150 ° C. of the adhesive tape base paper is preferably 20 ppm / K or less, more preferably 15 ppm / K or less, further preferably 10 ppm / K or less, and particularly preferably 8 ppm / K or less. . When the linear thermal expansion coefficient of the fine cellulose fiber-containing sheet exceeds the upper limit, the dimensional stability is deteriorated.
The coefficient of linear thermal expansion is a value measured according to ASTM D696. An adhesive tape base paper having a linear thermal expansion coefficient equal to or less than the upper limit value is not easily deformed with respect to temperature change.

[density]
The density of pressure-sensitive adhesive tape base paper is preferably from ^{0.50~0.85g / cm 3, 0.50~0.80g / cm} 3 is more preferable. The density is a value measured according to JIS P8118: 1998. As the density of the base paper for pressure-sensitive adhesive tape of the present invention increases, the tensile strength increases.
The density of the base paper for the adhesive tape can be adjusted by adding an organic solvent and adjusting the amount of addition during paper making.
Examples of the organic solvent added during papermaking include methanol, ethanol, 2-propanol, ethylene glycol compounds, dipropylene glycol methyl ether, ethylene glycol monobutyl ether, ethylene glycol mono-t-butyl ether, diethylene glycol monoethyl ether, and the like. Glymes such as diethylene glycol dimethyl ether, diethylene glycol dibutyl ether, tetraethylene glycol dimethyl ether, triethylene glycol dimethyl ether, diethylene glycol diethyl ether, ethylene glycol diethyl ether, ethylene glycol dimethyl ether, diethylene glycol isopropyl methyl ether; 1,2-butanediol 1,6-he Dihydric alcohols such as Sanji ol; diethylene glycol monoethyl ether acetate, ethylene glycol monomethyl ether acetate.
Among these, ethylene glycol compounds, diethylene glycol dimethyl ether, and diethylene glycol isopropyl methyl ether are preferable because of their excellent solubility in water, a good balance of boiling point, surface tension, and molecular weight, and the ability to easily obtain a porous sheet. .
Two or more of the above organic solvents may be used in combination.

[Basis weight]
The basis weight of the pressure-sensitive adhesive tape base paper of the present invention is preferably 5 to 100 g / ^{m 2,} and more preferably 10 to 80 g / ^{m 2.} Here, the basis weight is a value measured according to JIS P8124: 1998.
If the basis weight of the base paper for the adhesive tape is less than the lower limit, the sheet rigidity is small and the handling property is poor, and the thickness is thin, so the tensile strength at break as a sheet is small, and the paper tends to break during processing. is there. On the other hand, if the basis weight of the adhesive tape base paper exceeds the upper limit, the dewaterability during papermaking is low, and thus the productivity tends to be insufficient.

[Air permeability]
The air permeability of the adhesive tape base paper is preferably 50000 seconds or less, more preferably 500 to 50000 seconds, further preferably 1000 to 50000 seconds, and particularly preferably 1500 to 50000 seconds. The air permeability is as follows: Oken Air Permeability: JAPAN TAPPI Paper Pulp Test Method No. It is the value measured according to 5-2: 2000 (Oken type).

[Specific surface area]
The specific surface area of the base paper for adhesive tape, is preferably ^{10 m} 2 / g or more, more preferably 30 to 200 m ² / g, more preferably from 50 to 200 m ² / g. The specific surface area is a BET specific surface area measured by a nitrogen gas adsorption method.

[Porosity]
The porosity of the adhesive tape base paper is preferably 30 to 70%, more preferably 30 to 60%. Here, the porosity is a value obtained by measuring the density of the sheet in accordance with JIS P8118 and calculating from the value.

  The base paper for wallpaper of the present invention may contain cellulose fibers or fine cellulose fibers.

(Fine cellulose fiber)
When fine cellulose fiber is contained in the base paper for the pressure-sensitive adhesive tape of the present invention, the average fiber width of the fine cellulose fiber is 1000 nm or less. The average fiber width of the fine cellulose fibers is preferably 1 nm to 1000 nm, and more preferably 20 nm to 500 nm.
When the average fiber width exceeds the upper limit, the specific surface area of the adhesive tape base paper becomes small, and the impregnation property of the adhesive becomes low.

The average fiber width of cellulose fibers is measured as follows. A cellulose fiber-containing slurry is prepared, and the slurry is cast on a carbon film-coated grid subjected to a hydrophilization treatment to obtain a transmission electron microscope (TEM) observation sample. When wide fibers are included, an operation electron microscope (SEM) image of the surface cast on glass may be observed. Observation by an electron microscope image is performed at any magnification of 1000 times, 5000 times, 10000 times, 20000 times, 50000 times or 100,000 times depending on the width of the constituent fibers. However, the sample, observation conditions, and magnification are adjusted to satisfy the following conditions.
(1) One straight line X is drawn at an arbitrary location in the observation image, and 20 or more single fibers intersect the straight line X.
(2) A straight line Y perpendicularly intersecting the straight line X is drawn in the same image, and 20 or more single fibers intersect the straight line Y.
For each of the single fibers intersecting with the straight line X and the single fibers intersecting with the straight line Y with respect to the electron microscope observation image as described above, the width (the short axis of the fiber) is at least 20 (ie, the total is at least 40). Read. In this way, at least three or more sets of electron microscope images as described above are observed, and the fiber width of at least 40 × 3 sets (that is, at least 120 sets) is read. The fiber widths thus read are averaged to obtain the average fiber width.

  Although the fiber length of the fine cellulose fiber is not particularly limited, it is considered that when the fiber is shortened, the strength of paper strength may be lowered. Therefore, the average fiber length is preferably 10 times or more of the average fiber width, more preferably 50 times or more. 100 times or more is most preferable. In order to make the average fiber length within the above range, for example, it is effective to select softwood pulp having a long fiber length.

  The fiber length can be determined by analyzing the electron microscope observation image used when measuring the average fiber width. That is, at least 20 (that is, a total of at least 40) fiber lengths are read for each of the single fibers intersecting with the straight line X and the single fibers intersecting with the straight line Y with respect to the electron microscope observation image as described above. In this way, at least three or more sets of electron microscope images as described above are observed, and the fiber length of at least 40 × 3 sets (that is, at least 120 sets) is read. The average fiber length is obtained by averaging the fiber lengths thus read.

[Method for producing cellulose fiber]
Cellulose fibers can be obtained by refining a raw material containing lignocellulose (hereinafter referred to as “lignocellulose raw material”). For example, as a manufacturing method of a cellulose fiber, the method of refining lignocellulose raw material by the wet grinding using a mechanical action is mentioned. Examples of the wet pulverization method using a mechanical action include a method using a grinder (stone mortar pulverizer), a high-pressure homogenizer, an ultra-high pressure homogenizer, a high-pressure collision pulverizer, a disk refiner, a conical refiner, and the like.
Further, before the miniaturization, chemical treatment such as TEMPO (2,2,6,6-tetramethylpiperidine-1-oxy radical) oxidation, ozone treatment, enzyme treatment and the like may be performed.
It is also possible to obtain a lignocellulosic raw material by pulverizing wood and then performing a treatment such as delignification.
By any of the above methods, a cellulose fiber suspension having a solid concentration of about 0.01 to 20% by mass can be obtained.

  Although it does not specifically limit as a lignocellulose raw material, For example, it is preferable to use a woody plant (a conifer, a hardwood), and a herbaceous plant. More specifically, chemical pulp obtained by digesting woody plants by kraft method, sulfite method, soda method, polysulfide method, etc., mechanical pulp pulped by mechanical processing such as refiner, grinder, etc. Examples thereof include semi-chemical pulp pulped by mechanical processing, or waste paper pulp. These can be used in an unbleached (before bleaching) or bleached (after bleaching) state, respectively. Examples of non-wood pulp include fibers obtained by pulping cotton, manila hemp, flax, straw, bamboo, bagasse, kenaf and the like in the same manner as wood pulp.

(Pulp for general paper)
The base paper for pressure-sensitive adhesive tapes of the present invention may contain general paper pulp having an average fiber width exceeding 1000 nm.
General paper pulp is a pulp used for general paper and is the same as the above lignocellulose raw material.

When the base paper for pressure-sensitive adhesive tapes of the present invention contains pulp for general paper, the fine cellulose fibers also play a role of strengthening the interfiber bond of the pulp for general papermaking. When the pulp for general paper is included, the content of cellulose fiber in the base paper for adhesive tape is preferably 1 to 50% by weight, more preferably 5 to 40% by weight, and 10 to 30% by weight based on the total weight of the base paper for adhesive tape. Further preferred.
If content of a cellulose fiber is more than the said lower limit, the hydrogen bond between the pulp for general paper can fully be reinforced. However, when the content of cellulose fibers increases, the viscosity of the pulp slurry containing cellulose fibers increases, and it becomes necessary to lower the concentration of the pulp slurry containing cellulose fibers in order to enable papermaking. When the content of the cellulose fiber exceeds 50% by mass, it is necessary to greatly reduce the concentration of the pulp slurry containing the cellulose fiber, and the drainage at the time of paper making is remarkably lowered, making industrial production difficult.

(Other ingredients)
Moreover, the base paper for adhesive tapes of this invention may contain chemical additives, such as a filler, a sizing agent, a paper strength enhancer, and a yield improver, and glue other than the said cellulose fiber.

The base paper for pressure-sensitive adhesive tapes of the present invention may contain inorganic compound particles.
The inorganic compound particles are preferably nanoparticles having an average particle diameter of 1 to 2000 nm because the effect of the inorganic compound particles is increased. The average particle size of the inorganic compound nanoparticles is preferably 2 to 300 nm, more preferably 4 to 200 nm, and particularly preferably 6 to 100 nm. Here, the average particle diameter is an average particle diameter of primary particles by a dynamic light scattering method or an average particle diameter of primary particles by observation with a transmission electron microscope. The average particle diameter here is a mass average.
If the average particle diameter of the inorganic compound particles is equal to or larger than the lower limit value, it is readily available, and if the average particle diameter is equal to or smaller than the upper limit value, the antibacterial or deodorizing properties can be sufficiently exhibited.

Specific examples of the inorganic compound fine particles include silicon dioxide (SiO ₂ ), aluminum oxide (Al ₂ O ₃ ), iron oxide (Fe ₂ O ₃ ), yttrium oxide (Y ₂ O ₃ ), indium oxide (InO), and oxide. Zinc (ZnO), magnesium oxide (MgO), titanium dioxide (TiO ₂ ), cerium dioxide (CeO ₂ ), trimanganese tetroxide (Mn ₃ O ₄ ), niobium pentoxide (Nb ₂ O ₅ ), silicon carbide (SiC) ), Boron carbide (B ₄ C), aluminum nitride (AlN), titanium boride (TiB ₂ ), and the like.
Metal nanoparticles can also be used as inorganic compound nanoparticles. Examples of the metal constituting the metal nanoparticles include gold, silver, copper, aluminum, nickel, cobalt, iron, platinum (platinum), ruthenium, zinc, vanadium, rhodium, palladium, osmium, iridium, and the like.
Moreover, the particle | grains which the said inorganic compound particle couple | bonded with zeolite, a hydroxyapatite, and a silica, for example, a nano platinum silica particle, can be used.
Moreover, a commercially available antibacterial agent or deodorant containing the inorganic compound particles can be used without particular limitation.

(Method for producing base paper for adhesive tape)
When making base paper for adhesive tape, in addition to continuous paper machines such as the long net type, circular net type, and inclined type used in normal paper making, a multi-layered paper machine combining these may be used. However, hand-drawing may be used.
Further, an organic solvent may be added during papermaking. The method for adding the organic solvent is not particularly limited, but a method in which the organic solvent is dropped from above in the running direction of the undried sheet (hydrous web) is preferable. The dropping angle is not particularly limited as long as the organic solvent can be uniformly added to the water-containing web, but it is preferable to drop the organic solvent vertically to the water-containing web.

(Function and effect)
As a result of investigations by the present inventors, the pressure-sensitive adhesive tape base paper of the present invention has excellent density stability and pressure-sensitive adhesive impregnation, and high tensile strength. I understood.

  Hereinafter, the present invention will be described more specifically with reference to examples and comparative examples. However, the present invention is not limited to these examples. Moreover, unless otherwise indicated, the part and% in an example show a mass part and mass%, respectively.

<Example 1>
Add water to conifer bleached kraft pulp (manufactured by Oji Holdings Co., Ltd., moisture 50%, Canadian standard freeness (CSF) 550 ml measured according to JIS P8121) to a concentration of 5.0%, disintegrator To obtain a pulp dispersion. This pulp dispersion liquid was refined by performing a defibrating process three times using a mass colander manufactured by Masuko Sangyo Co., Ltd. having a grinder portion having a major axis of 250 mm.
The supernatant concentration of the obtained defibrating solution was 3.25%. The width of fine cellulose fibers in the supernatant was in the range of 60 to 700 nm, and the average fiber width was 140 nm.
Water was added and diluted so that the concentration of the supernatant of the defibrated solution was about 3%, and the mixture was stirred with a homomixer to obtain a fine cellulose fiber dispersion A. The solid content concentration of the fine cellulose fiber dispersion A was measured and found to be 3.0%.
The surface of the dispersion containing fine cellulose fibers prepared by the above operation was made uniform with an applicator (clearance 1 mm) so that the thickness was uniform on a 508 nylon mesh sheet. Subsequently, it dehydrated by sucking from the lower side of the mesh sheet. Thereafter, diethylene glycol dimethyl ether (DEGDME, manufactured by Toho Chemical Co., Ltd., trade name: “Hisolv MDM”, molecular weight 134, boiling point 162 ° C., surface tension 28 N / m) was applied to the wet paper sheet on the mesh sheet, and the cellulose fiber solids. 1200 parts were added to 100 parts per minute. Next, suction was performed from the lower side of the mesh sheet, and the obtained wet paper was dried while being pressurized to 0.2 MPa using a cylinder dryer heated to 105 ° C. to obtain an adhesive tape base paper.

<Example 2>
In Example 1, an adhesive tape base paper was obtained in the same manner as Example 1 except that 600 parts of diethylene glycol dimethyl ether was added to 100 parts of the solid content of the wet paper sheet.

<Example 3>
A base paper for adhesive tape was obtained in the same manner as in Example 1 except that 600 parts of diethylene glycol dimethyl ether diluted twice with water was added to 100 parts of the solid content of the wet paper sheet in Example 1. It was.

<Example 4>
In Example 1, an adhesive tape base paper was obtained in the same manner as in Example 1 except that the number of treatments of the mass collider was 1 and the average fiber width was 400 nm.

<Comparative Example 1>
In Example 1, an adhesive tape base paper was obtained in the same manner as in Example 1 except that diethylene glycol dimethyl ether was not added.

<Comparative example 2>
A base paper for pressure-sensitive adhesive tape was obtained in the same manner as in Example 1 except that 10000 parts of diethylene glycol dimethyl ether was added in Example 1 to 100 parts of the solid content of the wet paper sheet.

<Comparative Example 3>
In Example 1, an adhesive tape base paper was obtained in the same manner as in Example 1 except that the treatment with the mass colloider was not performed and the average fiber width was 20000 nm.

(Evaluation)
The density, air permeability, tensile strength, and linear thermal expansion coefficient of the obtained base paper for pressure-sensitive adhesive tape were measured by the following methods, and the impregnation properties of the pressure-sensitive adhesive were evaluated by the following methods. The measurement results and evaluation results are shown in Table 1.

[density]
The density was measured according to JIS P8118: 1998.
[Air permeability]
The air permeability is as follows: Oken Air Permeability: JAPAN TAPPI Paper Pulp Test Method No. It was measured according to 5-2: 2000 (Oken type).
[Tensile strength]
The tensile strength was measured according to JIS P8113.
[Measurement of linear thermal expansion coefficient]
The linear thermal expansion coefficient was measured according to ASTM D696.

[Impregnation of adhesive]
The pressure-sensitive adhesive whose B-type viscosity was adjusted to about 2000 cps was put in the container, the base paper for the pressure-sensitive adhesive tape was floated on the surface of the pressure-sensitive adhesive, and the impregnation property of the pressure-sensitive adhesive was visually evaluated according to the following evaluation criteria.
◎: Adhesive soaks considerably up to the upper surface of the adhesive tape base paper (the amount of adhesive penetrating into the adhesive base tape is considerably large)
○: Adhesive soaks up to the upper surface of the adhesive tape base paper (the amount of adhesive penetrating into the adhesive tape base paper is large)
×: It is difficult for the adhesive to penetrate up to the upper surface of the adhesive tape base paper (the amount of adhesive penetrating the adhesive tape base paper is small)

[Comprehensive evaluation as base paper for adhesive tape]
Based on the measurement results of the tensile strength and the linear thermal expansion coefficient and the evaluation results of the impregnation property of the pressure-sensitive adhesive, whether or not it is suitable as the characteristics of the base paper for pressure-sensitive adhesive tape was comprehensively evaluated according to the following criteria. The results are shown in Table 1.
A: All of the following (a) to (c) are satisfied, and it is suitable as an adhesive tape base paper.
X: One of the following (a) to (c) is not satisfied, and it is not suitable as an adhesive tape base paper.
(A) Tensile strength 25 MPa or more (b) Linear thermal expansion coefficient 20 ppm / K or less (c) Impregnating property of adhesive is ◎ or ○

As shown in Table 1, the adhesive tape base papers of Examples 1 to 4 had high tensile strength and linear thermal expansion coefficient, excellent adhesive impregnation properties, and excellent properties as the adhesive tape base paper.
The base paper for pressure-sensitive adhesive tapes of Comparative Example 1 having a density of 0.90 g / cm ³ had low pressure-sensitive adhesive impregnation properties.
The base paper for adhesive tape of Comparative Example 2 having a density of 0.42 g / cm ³ had low tensile strength.
The base paper for pressure-sensitive adhesive tape of Comparative Example 3 having an average fiber width of 20000 nm had a large coefficient of linear thermal expansion and low dimensional stability.

Claims (3)

Der tensile strength than 25MPa measured according to JIS P8113 of the base paper used as a support of the adhesive tape (base paper for adhesive tape) is,
The density of the base paper is 0.50 to 0.85 g / cm ³ ,
The base paper contains cellulose fibers;
The cellulose fibers have an average fiber width of Ru less fine cellulose fibers der 1000 nm, the pressure-sensitive adhesive tape base paper.   The base paper for adhesive tapes of Claim 1 whose linear thermal expansion coefficient in the measurement range in 50-150 degreeC of the said base paper is 20 ppm / K or less. Wang Kenshiki air permeability of the base paper is less than 50,000 seconds, the pressure-sensitive adhesive tape base paper according to claim 1 or 2.