JP6247567B2 - Milky coffee drink containing fine powder of roasted coffee beans - Google Patents

Milky coffee drink containing fine powder of roasted coffee beans Download PDF

Info

Publication number
JP6247567B2
JP6247567B2 JP2014039929A JP2014039929A JP6247567B2 JP 6247567 B2 JP6247567 B2 JP 6247567B2 JP 2014039929 A JP2014039929 A JP 2014039929A JP 2014039929 A JP2014039929 A JP 2014039929A JP 6247567 B2 JP6247567 B2 JP 6247567B2
Authority
JP
Japan
Prior art keywords
coffee
milk
beverage
roasted
powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2014039929A
Other languages
Japanese (ja)
Other versions
JP2015164401A5 (en
JP2015164401A (en
Inventor
丈博 須藤
丈博 須藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suntory Holdings Ltd
Original Assignee
Suntory Holdings Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suntory Holdings Ltd filed Critical Suntory Holdings Ltd
Priority to JP2014039929A priority Critical patent/JP6247567B2/en
Priority to PCT/JP2015/055115 priority patent/WO2015129649A1/en
Priority to MYPI2016703138A priority patent/MY172323A/en
Publication of JP2015164401A publication Critical patent/JP2015164401A/en
Publication of JP2015164401A5 publication Critical patent/JP2015164401A5/ja
Application granted granted Critical
Publication of JP6247567B2 publication Critical patent/JP6247567B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23FCOFFEE; TEA; THEIR SUBSTITUTES; MANUFACTURE, PREPARATION, OR INFUSION THEREOF
    • A23F5/00Coffee; Coffee substitutes; Preparations thereof
    • A23F5/24Extraction of coffee; Coffee extracts; Making instant coffee
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23FCOFFEE; TEA; THEIR SUBSTITUTES; MANUFACTURE, PREPARATION, OR INFUSION THEREOF
    • A23F5/00Coffee; Coffee substitutes; Preparations thereof
    • A23F5/10Treating roasted coffee; Preparations produced thereby
    • A23F5/14Treating roasted coffee; Preparations produced thereby using additives, e.g. milk, sugar; Coating, e.g. for preserving

Description

本発明は、加熱臭が低減された乳入りコーヒー飲料に関する。   The present invention relates to a milk-containing coffee beverage with reduced heating odor.

乳入りコーヒー飲料は、一年を通して飲用される嗜好性の高い飲料であり、長期にわたって常温保存可能な容器詰め乳入りコーヒー飲料が多数流通されている。容器詰め乳入りコーヒー飲料は、通常、コーヒー豆抽出液、インスタントコーヒー等のコーヒー原料(本明細書中、コーヒー分とも表記する)に、牛乳、濃縮乳、全脂乳又は全脂粉乳、脱脂乳又は脱脂粉乳、練乳、クリーム、或いは乳タンパク質等のミルク成分を含有する乳原料(本明細書中、乳分とも表記する)などを混合溶解して調合液を得、保存容器に充填される前、または充填された後のいずれかに、高温殺菌をして製造されている。このように高温殺菌を経て製造される乳入りコーヒー飲料では、乳成分が熱変性し、乳加熱臭、具体的には、乳独特の劣化臭(すえ臭)や乳独特のむれっぽい味を発生させ、コク(クリーミー感)が消失して、乳入り飲料の品質を低下させることが知られている。   Milk coffee beverages are drinks with high palatability that are drunk throughout the year, and many bottled milk coffee beverages that can be stored at room temperature for a long period are in circulation. Coffee beverages with stuffed milk are usually used for coffee raw materials such as coffee bean extract and instant coffee (also referred to as coffee content in this specification), milk, concentrated milk, whole milk or whole milk powder, skim milk. Or before mixing the raw material containing milk components such as skim milk powder, condensed milk, cream, or milk protein (in this specification, also expressed as milk), etc. Or after being filled, it is manufactured by high temperature sterilization. In this way, in milk-containing coffee beverages manufactured through high-temperature sterilization, the milk components are heat-denatured, and the milk-heated odor, specifically, the milk's unique deterioration odor (natural odor) and the milk's peculiar taste It is known that the quality (creamy feeling) disappears and the quality of the milk-containing beverage is lowered.

そこで、乳入り飲料において、乳加熱臭を抑制する方法が種々開発されている。例えば、乳又は乳製品にα―グリコシルトレハロースを含有せしめ、加熱処理工程を経て製造することを特徴とする乳加熱臭の生成が抑制された乳又は乳製品の製造方法(特許文献1)や、糖分を含むコーヒー抽出液に、単糖およびアミノ酸からなる混合物ならびに乳成分を添加し、容器に充填後、レトルト殺菌することを特徴とする、加温状態でも長期間にわたり香味劣化のない乳入りコーヒー飲料(特許文献2)や、乳成分を配合したコーヒー抽出液に、クロロゲン酸またはクロロゲン酸類を添加することを特徴とする、加温状態でも長期間にわたり香味劣化のない乳入りコーヒー飲料(特許文献3)、飲料中の乳脂肪1重量%当たりに対し、植物油脂を0.15〜2の割合で配合することを特徴とする飲用後そう快な後味を有する容器詰めコーヒー(特許文献4)等が挙げられる。   Therefore, various methods for suppressing the heat odor of milk in a beverage containing milk have been developed. For example, a method for producing milk or dairy products in which the production of heated odor of milk is suppressed, characterized in that α-glycosyl trehalose is contained in milk or dairy products and is produced through a heat treatment step (Patent Document 1), A mixture of simple sugars and amino acids and a milk component are added to a coffee extract containing sugar, filled in a container, and then sterilized by retort. Beverages (Patent Document 2) and coffee extracts containing dairy ingredients are added with chlorogenic acid or chlorogenic acids, and milk-containing coffee beverages that do not deteriorate in flavor over a long period of time even in a heated state (Patent Document) 3) A container having a pleasant aftertaste after drinking, characterized by blending vegetable oils and fats in a ratio of 0.15 to 2 per 1% by weight of milk fat in beverages Because coffee (Patent Document 4), and the like.

一方、コーヒー飲料に対する消費者嗜好の多様化に伴い、コーヒー豆の微粉砕品を配合したコーヒー飲料が提案されている(特許文献5〜7)。   On the other hand, with the diversification of consumer preferences for coffee beverages, coffee beverages containing finely ground coffee beans have been proposed (Patent Documents 5 to 7).

特開2006−94856号公報JP 2006-94856 A 特開平11−9190号公報Japanese Patent Laid-Open No. 11-9190 特開平11−9189号公報Japanese Patent Laid-Open No. 11-9189 特開2009−291137号公報JP 2009-291137 A 特開2005−124486号公報JP 2005-124486 A 特開2007−289035号公報JP 2007-289035 A 特開2005−318812号公報JP 2005-318812 A

上記のとおり、容器詰め乳入りコーヒー飲料の高温殺菌時における香味劣化の抑制方法が種々開発されているが、未だ十分に満足できるものではなかった。本発明の目的は、乳入りコーヒー飲料の高温殺菌時に発生する乳加熱臭を抑制した、ドリンカビリティの高いコーヒー飲料を提供することにある。   As described above, various methods for suppressing flavor deterioration during high-temperature sterilization of coffee beverages containing packed milk have been developed, but they have not been fully satisfactory. An object of the present invention is to provide a coffee drink with high drinkability, which suppresses a heated odor of milk generated during high-temperature sterilization of a coffee drink containing milk.

本発明者らは、上記課題を解決するために鋭意検討を行った結果、植物油脂と特定の粒子径に微粉砕された焙煎コーヒー豆微粉末(不溶性コーヒー粉末)とを配合し、好ましくはコーヒー脂質量((A)パルミチン酸カーウェオール及び(B)パルミチン酸カフェストールの総量[(A)+(B)])が特定範囲に調整された乳入り飲料は、高温殺菌後の乳加熱臭が大きく低減されることを見出し、本発明を完成するに至った。   As a result of intensive studies to solve the above problems, the present inventors have blended vegetable oil and fat with roasted coffee bean fine powder (insoluble coffee powder) finely pulverized to a specific particle size, preferably A milk-containing beverage in which the amount of coffee lipids ((A) Carweol palmitate and (B) Total amount of palmitolic acid café stall [(A) + (B)]) is adjusted to a specific range is obtained by heating milk after pasteurization. The present inventors have found that the odor is greatly reduced and have completed the present invention.

すなわち、これに限定されるものではないが、本発明は以下を包含する。
(1)焙煎コーヒー豆を微粉砕して得られるメジアン径が50〜300μmの不溶性コーヒー粉末と、焙煎コーヒー豆の粉砕物に抽出処理を行って得られる焙煎コーヒー豆の抽出物と、植物油脂と、乳成分とを含有し、高温殺菌して製造される乳入りコーヒー飲料。
(2)飲料中の脂質量が、飲料100gあたり0.4〜3.0gである、(1)に記載の乳入りコーヒー飲料。
(3)飲料中のカフェイン含量が、飲料100gあたり10〜60mgである、(1)又は(2)に記載の乳入りコーヒー飲料。
(4)コーヒー脂質含量が0.5〜11.0mg/kgである、(1)〜(3)のいずれかに記載の乳入りコーヒー飲料。
(5)pHが5.5〜7.0である、(1)〜(4)のいずれかに記載の乳入りコーヒー飲料。
(6)植物油脂がヤシ油である、(1)〜(5)のいずれかに記載の乳入りコーヒー飲料。
That is, although not limited to this, this invention includes the following.
(1) An insoluble coffee powder having a median diameter of 50 to 300 μm obtained by finely pulverizing roasted coffee beans, and an extract of roasted coffee beans obtained by subjecting the pulverized roasted coffee beans to an extraction process, A milk-containing coffee beverage that contains vegetable oils and milk components and is manufactured by high-temperature sterilization.
(2) The milk-containing coffee beverage according to (1), wherein the amount of lipid in the beverage is 0.4 to 3.0 g per 100 g of beverage.
(3) The coffee coffee containing milk according to (1) or (2), wherein the caffeine content in the beverage is 10 to 60 mg per 100 g of beverage.
(4) The milk-containing coffee beverage according to any one of (1) to (3), wherein the coffee lipid content is 0.5 to 11.0 mg / kg.
(5) The milk-containing coffee drink according to any one of (1) to (4), wherein the pH is 5.5 to 7.0.
(6) The milk-containing coffee drink according to any one of (1) to (5), wherein the vegetable oil is coconut oil.

本発明により、高温殺菌および長期間の保存にも香味の観点から品質的に耐えうる、乳入りコーヒー飲料が得られる。本発明の乳入りコーヒー飲料は、乳入り飲料のオフフレーバー(乳加熱臭や酸化臭)が低減され、乳成分のコクが付与されたドリンカビリティの高い飲料である。   According to the present invention, it is possible to obtain a milky coffee beverage that can withstand quality sterilization from the viewpoint of flavor even under high-temperature sterilization and long-term storage. The milk-containing coffee beverage of the present invention is a beverage with high drinkability to which the off-flavor (milk heating odor and oxidation odor) of the milk beverage is reduced and the richness of the milk component is imparted.

本明細書でいう「コーヒー飲料」とは、コーヒー分を原料として使用し、加熱殺菌工程を経て製造される飲料製品のことをいう。製品の種類は特に限定されないが、1977年に認定された「コーヒー飲料等の表示に関する公正競争規約」の定義である「コーヒー」「コーヒー飲料」「コーヒー入り清涼飲料」が主に挙げられる。また、コーヒー分を原料とした飲料においても、乳固形分が3.0質量%以上のものは「飲用乳の表示に関する公正競争規約」の適用を受け、「乳飲料」として取り扱われるが、これは、本発明におけるコーヒー飲料に含まれるものとする。   The term “coffee beverage” as used herein refers to a beverage product produced using a coffee component as a raw material and subjected to a heat sterilization process. The type of product is not particularly limited, but “Coffee”, “Coffee drink”, and “Soft drink with coffee”, which are the definitions of “Fair competition rules regarding the display of coffee drinks” certified in 1977, are mainly cited. Also, in beverages made from coffee, those with a milk solid content of 3.0% by weight or more are treated as “milk beverages” under the “Fair Competition Rules for Labeling of Drinking Milk”. Is included in the coffee beverage of the present invention.

ここで、コーヒー分(本明細書中、焙煎コーヒー豆の抽出物とも表記する)とは、コーヒー豆由来の成分を含有する溶液のことをいい、例えば、コーヒー抽出液、すなわち、焙煎、粉砕されたコーヒー豆を水や温水などを用いて抽出した溶液が挙げられる。また、コーヒー抽出液を濃縮したコーヒーエキス、コーヒー抽出液を乾燥したインスタントコーヒーなどを、水や温水などで適量に調整した溶液も、コーヒー分として挙げられる。   Here, the coffee content (in the present specification, also referred to as an extract of roasted coffee beans) refers to a solution containing a component derived from coffee beans, for example, a coffee extract, that is, roasting, The solution which extracted the ground coffee bean using water, warm water, etc. is mentioned. Moreover, the solution which adjusted the coffee extract which concentrated the coffee extract, the instant coffee which dried the coffee extract, etc. to water and warm water etc. to an appropriate quantity is also mentioned as a coffee part.

本明細書中、乳成分を原料として使用し、加熱殺菌工程を経て製造されるコーヒー飲料を、「乳入りコーヒー飲料」と表す。ここで、乳成分とは、コーヒー飲料に乳風味や乳感を付与するために添加される成分を指し、少なくとも無脂乳固形成分を含む成分をいう。主に哺乳動物の乳、牛乳及び乳製品のことをいい、例えば、生乳、牛乳、特別牛乳、部分脱脂乳、脱脂乳、加工乳、乳飲料などが挙げられ、乳製品としては、クリーム、濃縮ホエイ、濃縮乳、脱脂濃縮乳、無糖れん乳、加糖脱脂れん乳、全粉乳、脱脂粉乳、クリームパウダー、ホエイパウダー、バターミルクパウダー、調整粉乳などが挙げられる。特に、本発明の効果は、乳成分として牛乳を用いたときに発生する加熱臭の抑制に効果的であるから、牛乳を含む飲料は本発明の好ましい態様の一つである。本発明の乳入り飲料における乳成分の含有量は、特に限定されないが、好ましくは固形分換算で0.1〜10質量%である。ここでいう固形分とは、乳成分を一般的な乾燥法(凍結乾燥、蒸発乾固等)を用いて乾燥させて水分を除いた後の、乾固物のことをいう。   In the present specification, a coffee beverage produced using a milk component as a raw material and subjected to a heat sterilization step is referred to as a “milk coffee beverage”. Here, a milk component refers to the component added in order to provide milk flavor and milky feeling to a coffee drink, and means the component which contains a non-fat milk solid component at least. Mainly refers to mammalian milk, milk and dairy products. Examples include raw milk, milk, special milk, partially skimmed milk, skimmed milk, processed milk, and milk beverages. Examples include whey, concentrated milk, defatted concentrated milk, sugar-free milk, sweetened defatted milk, whole milk powder, skimmed milk powder, cream powder, whey powder, butter milk powder, and adjusted powdered milk. In particular, since the effect of the present invention is effective in suppressing heated odor generated when milk is used as a milk component, a beverage containing milk is one of the preferred embodiments of the present invention. Although content of the milk component in the milk-containing drink of this invention is not specifically limited, Preferably it is 0.1-10 mass% in conversion of solid content. The term “solid content” as used herein refers to a dried product after the milk component is dried using a general drying method (freeze drying, evaporation to dryness, etc.) to remove moisture.

本発明の飲料は、無脂乳固形成分を配合して得られる乳入りコーヒー飲料であるが、好ましい態様において、飲料中の水溶性タンパク質が、飲料100gあたり0.4〜2.0gとなるように調製する。水溶性タンパク質の量は、より好ましくは飲料100gあたり0.5〜1.8gであり、さらに好ましくは0.6〜1.6gである。ここで、飲料中の水溶性タンパク質含量は、栄養改善法の栄養表示基準(ケルダール法)に基づく飲料中のたんぱく質量の測定に基づき分析される。   The beverage of the present invention is a milk-containing coffee beverage obtained by blending non-fat milk solid components. In a preferred embodiment, the water-soluble protein in the beverage is 0.4 to 2.0 g per 100 g of beverage. Prepare to. The amount of the water-soluble protein is more preferably 0.5 to 1.8 g per 100 g of beverage, and further preferably 0.6 to 1.6 g. Here, the water-soluble protein content in the beverage is analyzed based on the measurement of the protein mass in the beverage based on the nutrition labeling standard (Kjeldahl method) of the nutrition improvement method.

本発明のコーヒー飲料は、上記のコーヒー分及び乳成分を含有する乳入りコーヒー飲料に、さらに特定の粒子径に微粉砕された焙煎コーヒー豆微粉末(不溶性コーヒー粉末)と、植物油脂とを配合することを特徴とする。以下、これらについて詳述する。
(不溶性コーヒー粉末)
本発明の「不溶性コーヒー粉末」とは、焙煎コーヒー豆を微粉砕して得られるもの(焙煎コーヒー豆微粉末)をいう。ここで、「焙煎コーヒー豆」とは、コーヒーの生豆に対して焙煎と呼ばれる加熱処理を施したものである。焙煎によって生豆に含まれている成分が化学変化してコーヒーの風味(強い芳香性やフレーバー)が醸し出されており、また、空隙含有構造体が形成されている。
The coffee beverage of the present invention comprises the above-described milk-containing coffee beverage containing a coffee component and a milk component, further roasted coffee bean fine powder (insoluble coffee powder) finely pulverized to a specific particle size, and vegetable oil and fat. It is characterized by blending. These will be described in detail below.
(Insoluble coffee powder)
The “insoluble coffee powder” of the present invention refers to a product obtained by pulverizing roasted coffee beans (roasted coffee bean fine powder). Here, “roasted coffee beans” are obtained by subjecting green coffee beans to a heat treatment called roasting. The ingredients contained in the green beans are chemically changed by roasting to create a coffee flavor (strong fragrance and flavor), and a void-containing structure is formed.

本発明の不溶性コーヒー粉末の原料となる焙煎コーヒー豆は、特に限定されない。直火式、熱風式、半熱風式、炭火式、遠赤外線式、マイクロ波式、過熱水蒸気式などの方法で、水平(横)ドラム型、垂直(縦)ドラム型、垂直回転ボール型、流動床型、加圧型などの装置を用い、コーヒー豆の種別に対応して、所定の目的に応じた焙煎度に仕上げればよい。ただし、焙煎度が高いと油脂成分がコーヒー豆表面に析出しやすくなり、粉砕が困難になったり、粉砕処理して得られる微粉末がケーキングを起こし易くなったりする。この観点から、アグトロンカラーメーターで測定した値(アグトロン値)を指標として、45〜70程度、好ましくは50〜60程度となるように焙煎された焙煎コーヒー豆が好適に用いられる。なお、コーヒー豆の種別についても、限定されるものではなく、アラビカ種、ロブスタ種のいずれも使用できるが、ロブスタ種は本発明のコーヒー特有のジテルペン化合物(カフェストール及びカーウェオール)の濃度を特定範囲に調整しやすいことから、好ましい態様の一例である。   The roasted coffee beans that are the raw material for the insoluble coffee powder of the present invention are not particularly limited. Direct fire type, hot air type, semi-hot air type, charcoal fire type, far infrared type, microwave type, superheated steam type, etc., horizontal (horizontal) drum type, vertical (vertical) drum type, vertical rotating ball type, flow Using a floor-type or pressure-type device, the roasting degree according to a predetermined purpose may be finished in accordance with the type of coffee beans. However, when the roasting degree is high, the oil and fat components are likely to be deposited on the surface of the coffee beans, and it becomes difficult to grind, or the fine powder obtained by the grinding treatment tends to cause caking. From this viewpoint, roasted coffee beans roasted to be about 45 to 70, preferably about 50 to 60, using the value (Agtron value) measured with an Agtron color meter as an index is suitably used. The type of coffee beans is not limited, and either Arabica or Robusta can be used, but Robusta has the concentration of diterpene compounds (cafe stall and carweol) specific to the coffee of the present invention. Since it is easy to adjust to a specific range, it is an example of a preferable aspect.

この焙煎コーヒー豆を粉砕処理して、本発明の不溶性コーヒー粉末を得る。粉砕処理は、焙煎後、24時間以内、好ましくは20時間以内、より好ましくは15時間以内、特に好ましくは10時間に行うことが好ましい。焙煎後の放置時間が長いと、油脂成分がコーヒー豆表面に析出しやすくなる。   The roasted coffee beans are pulverized to obtain the insoluble coffee powder of the present invention. The pulverization treatment is preferably performed within 24 hours, preferably within 20 hours, more preferably within 15 hours, and particularly preferably within 10 hours after roasting. If the standing time after roasting is long, the oil and fat component tends to precipitate on the surface of the coffee beans.

乾式での粉砕処理は、メジアン径で1mm以下に粗粉砕した後、微粉砕することが好ましい。微粉砕をする前に、予め粗粉砕することにより、一層効率よく短時間に微粉砕することができ、コーヒーの香り(フレーバー)の飛散を最小限に抑えることができる。また、粒度分布を狭くできるという利点もある。粗粉砕は、メジアン径で約1mm以下、好ましくは0.5mm以下になるように粉砕するが、その方法は特に制限されない。ロール式ミル、ボール式ミル、石臼式ミル等、種々の形式の粉砕機を使用することができる。   In the dry pulverization treatment, it is preferable to coarsely pulverize to a median diameter of 1 mm or less and then finely pulverize. By coarsely pulverizing in advance before fine pulverization, fine pulverization can be performed more efficiently in a short time, and scattering of coffee aroma (flavor) can be minimized. There is also an advantage that the particle size distribution can be narrowed. The coarse pulverization is performed so that the median diameter is about 1 mm or less, preferably 0.5 mm or less, but the method is not particularly limited. Various types of pulverizers such as a roll mill, a ball mill, and a stone mill can be used.

不溶性コーヒー粉末は、メジアン径で50〜300μmとなるように粉砕する。メジアン径で300μmを超える粉末は、飲料に配合した場合に食感や舌触りなどのテクスチャーに違和感を与えることがある。より好ましい微粉砕の程度の上限はメジアン径で250μm以下、さらに好ましくは200μm以下である。また、メジアン径で50μm未満となるまで微粉砕処理した場合には、保存安定効果が得られない傾向がある。より好ましい微粉砕の程度の下限はメジアン径で70μm以上、さらに好ましくは80μm以上、特に好ましくは90μm以上である。微粉砕の方法も特に制限されず、ロール式粉砕機、バーハンマー式やピンハンマー式等の衝撃式粉砕機、気流式粉砕機など、種々の形式の粉砕機を使用することができるが、ロール式粉砕機が好ましく用いられる。   The insoluble coffee powder is pulverized so as to have a median diameter of 50 to 300 μm. A powder having a median diameter of more than 300 μm may give an uncomfortable feeling to the texture such as texture and touch when blended in a beverage. A more preferable upper limit of the degree of fine grinding is a median diameter of 250 μm or less, and more preferably 200 μm or less. In addition, when the pulverization is performed until the median diameter is less than 50 μm, the storage stability effect tends to be not obtained. A more preferable lower limit of the degree of pulverization is a median diameter of 70 μm or more, more preferably 80 μm or more, and particularly preferably 90 μm or more. The method of fine pulverization is not particularly limited, and various types of pulverizers such as a roll pulverizer, an impact pulverizer such as a bar hammer type and a pin hammer type, and an airflow pulverizer can be used. A type pulverizer is preferably used.

粒子径は、多数個の測定結果を粒子径毎の存在比率の分布として表すのが一般的であり、これを粒子径分布という。存在比率の基準としては体積基準と個数基準などがあるが、本明細書では体積基準での存在比率で表わし、レーザー回折・散乱法に基づいた測定装置にて測定することができる。測定装置の例としては、マイクロトラック粒度分布測定装置(日機装株式会社製)である。そして、本明細書において焙煎コーヒー豆の微粉砕物の粒子径をメジアン径で表わしているが、メジアン径とは粒子径の累積データの50%径であり、粉体をある粒子径から2つに分けたとき、大きい側と小さい側が等量となる径のことである。   The particle size is generally expressed as a distribution of abundance ratios for each particle size, which is called a particle size distribution. The reference of the existence ratio includes a volume reference and a number reference. In this specification, the existence ratio is represented by a volume reference, and can be measured by a measuring device based on a laser diffraction / scattering method. An example of the measuring device is a microtrack particle size distribution measuring device (manufactured by Nikkiso Co., Ltd.). In the present specification, the particle size of the finely pulverized roasted coffee beans is expressed as a median size. The median size is 50% of the cumulative data of the particle size. When divided into two, it is a diameter in which the larger side and the smaller side are equal.

本発明における不溶性コーヒー粉末は、コーヒー飲料100mLあたりの水不溶性固形分が0.01〜1g、好ましくは0.1〜0.5gとなるように配合する。ここで、水不溶性固形分とは、飲料中の不溶性固形分を濾紙上に集めて乾燥して得られる固形分(重量)をいう。飲料100mLあたりの水不溶性固形分が0.01g未満であると、乳加熱臭を低減するのに十分な効果が得られないことがあり、飲料100mLあたりの水不溶性固形分が1gを超えると、飲用時にザラツキを感じたり、焙煎コーヒー豆に起因する好ましくない加熱臭を感じることがある。   The insoluble coffee powder in the present invention is blended so that the water-insoluble solid content per 100 mL of coffee beverage is 0.01 to 1 g, preferably 0.1 to 0.5 g. Here, the water-insoluble solid content refers to a solid content (weight) obtained by collecting the insoluble solid content in the beverage on a filter paper and drying it. When the water-insoluble solid content per 100 mL of beverage is less than 0.01 g, a sufficient effect may not be obtained to reduce the heat odor of milk, and when the water-insoluble solid content per 100 mL of beverage exceeds 1 g, When drinking, it may feel rough or unpleasant heated odor due to roasted coffee beans.

一般に脂質は、コーヒーの胃に対する刺激を和らげるとともに、口当たりをマイルドにする、飲料に乳風味、コク感を付与するなど風味上の大切な役割をもっているが、本発明者は、UHT殺菌やレトルト殺菌等の高温加熱を伴う容器詰めコーヒー飲料の場合、コーヒー脂質とタンパク質とを混合して高温加熱を行うと、加熱臭が増大する傾向にあることを見出している。これより、コーヒー原料(不溶性コーヒー粉末及び焙煎コーヒー豆の抽出物)は、コーヒー脂質が少ないものを用いることが好ましい。ここで、本明細書でいう「コーヒー脂質」とは、後述する実施例に記載の方法で測定されるカーウェオール(kahweol)とカフェストール(cafestol)にパルミチン酸がエステル結合した、(A)パルミチン酸カーウェオール(略記:KwO-pal)と(B)パルミチン酸カフェストール(略記:CfO-pal)の総量[(A)+(B)]をいう。   In general, lipids have important roles in flavor such as mildness of coffee stomach, mild taste, milk flavor and richness in beverages. In the case of container-packed coffee beverages with high-temperature heating such as the above, it has been found that heating odor tends to increase when coffee lipids and proteins are mixed and heated at high temperatures. From this, it is preferable to use a coffee raw material (insoluble coffee powder and roasted coffee bean extract) having less coffee lipid. Here, “coffee lipid” as used herein refers to esterification of palmitic acid to carhweol and cafestol measured by the method described in the examples described later. (A) This refers to the total amount [(A) + (B)] of carweol palmitate (abbreviation: KwO-pal) and (B) palmitate café stall (abbreviation: CfO-pal).

不溶性コーヒー粉末のコーヒー脂質は、ロブスタ種を用いることで同じ量のアラビカ種のコーヒー豆を用いた場合よりも低い濃度とすることができる。焙煎コーヒー豆の抽出物のコーヒー脂質は、コーヒー抽出液にコーヒー脂質の吸着能を有する吸着剤処理を行う方法を用いるのが簡便である。コーヒー脂質の吸着能を有する吸着剤としては、例えば、ペーパーフィルター、ネル(綿)フィルター、珪藻土、ポリプロピレン製不織布を用いたフィルターカートリッジ等の多孔質ろ材が例示される。また、三相遠心分離を用いて、油分、抽出液、粕の三相に分け、油分を適量除去することによりコーヒー脂質を低減してもよい。多孔質ろ材には、焙煎コーヒー豆又はその粉砕物も使用することができる。具体的には、焙煎コーヒー豆(抽出後のコーヒー滓を含む)をカラム状に積層させ、これに溶液状のコーヒー原料を通液することによりコーヒー脂質を選択的に吸着除去できる。通液は、ダウンフローであってもアップフローであってもよいが、アップフローはよりコーヒー脂質が除去されやすい傾向にある。   The coffee lipid of the insoluble coffee powder can be made lower by using Robusta seed than when using the same amount of Arabica coffee beans. For the coffee lipid of the roasted coffee bean extract, it is convenient to use a method in which the coffee extract is treated with an adsorbent having the ability to adsorb coffee lipid. Examples of the adsorbent having the ability to adsorb coffee lipids include porous filter media such as filter cartridges using paper filters, flannel (cotton) filters, diatomaceous earth, and polypropylene nonwoven fabrics. Further, coffee lipid may be reduced by separating into three phases of oil, extract, and koji using three-phase centrifugation and removing an appropriate amount of oil. As the porous filter medium, roasted coffee beans or a pulverized product thereof can also be used. Specifically, roasted coffee beans (including the coffee grounds after extraction) are stacked in a column shape, and the coffee lipid can be selectively adsorbed and removed by passing a solution-like coffee raw material therethrough. The liquid flow may be a down flow or an up flow, but the up flow tends to remove coffee lipid more easily.

不溶性コーヒー粉末及び焙煎コーヒー豆の抽出物を含有する本発明のコーヒー飲料中の好ましいコーヒー脂質含量[(A)+(B)]は、0.5〜11.0mg/kg、より好ましくは0.6〜8.0mg/kg、さらに好ましくは0.8〜6.0mg/kg、特に好ましくは1.0〜5.0mg/kg程度である。   The preferred coffee lipid content [(A) + (B)] in the coffee beverage of the present invention containing insoluble coffee powder and roasted coffee bean extract is 0.5-11.0 mg / kg, more preferably 0. It is about 0.6 to 8.0 mg / kg, more preferably about 0.8 to 6.0 mg / kg, and particularly preferably about 1.0 to 5.0 mg / kg.

(植物油脂)
本発明のコーヒー飲料は、植物油脂を必須成分として含有する。植物油脂としては、例えは、ナタネ油、ナタネ硬化油、コメ油、大豆油、コーン油、サフラワー油、ヒマワリ油、綿実油、ゴマ油、オリーブ油、パーム油、パーム核油、ヤシ油、ヤシ硬化油等の植物油脂と、それらの水素添加油、それらの1種以上の混合物によるエステル交換油等が挙げられる。これらの植物油脂のうち、特にヤシ油、パーム核油が、本発明の効果がより顕著になるため好ましい。さらに好ましい植物油脂はヤシ油である。
(vegetable oil)
The coffee beverage of the present invention contains vegetable oil as an essential component. Examples of vegetable oils include rapeseed oil, rapeseed oil, rice oil, soybean oil, corn oil, safflower oil, sunflower oil, cottonseed oil, sesame oil, olive oil, palm oil, palm kernel oil, coconut oil, and coconut oil. And the like, vegetable oils and fats thereof, hydrogenated oils thereof, and transesterified oils of a mixture of one or more thereof. Among these vegetable oils and fats, coconut oil and palm kernel oil are particularly preferable because the effects of the present invention become more remarkable. A more preferred vegetable oil is coconut oil.

植物油脂は、栄養改善法の栄養表示基準(レーゼゴットリーブ法)に基づく飲料中の脂質量、すなわち飲料中のコーヒー脂質含量、乳脂質含量および植物油脂由来の脂質含量の合計が、飲料100gあたり0.4〜3.0gとなるように配合する。飲料100gあたりの脂質量が0.5〜2.5gであるとより好ましく、0.5〜2.0gであるとさらに好ましい。通常、植物油脂の配合量は、コーヒー飲料100mLあたり0.5〜2.5g、好ましくは0.5〜2.0g程度である。   Vegetable fats and oils have a fat content in beverages based on the nutrition labeling standard of the nutritional improvement method (Lases Gottlieb method), that is, the total of lipid content derived from coffee fats, milk lipids and vegetable fats and oils in beverages is 0 It mix | blends so that it may become 4-3.0g. The amount of lipid per 100 g of beverage is more preferably 0.5 to 2.5 g, and further preferably 0.5 to 2.0 g. Usually, the compounding quantity of vegetable oil is 0.5-2.5g per 100 mL of coffee drinks, Preferably it is about 0.5-2.0g.

(その他成分)
通常、コーヒー原料は弱酸性であるが、乳成分の安定性を保つために、容器詰めされる乳入りコーヒー飲料では、通常、pH調整剤が添加され、pHが5.5〜7.0程度、好ましくはpH6.0〜7.0の中性領域になるようにpH調整が行われている。しかし、このpH調整の段階では、コーヒー原料が本来有する風味(例えば、ほのかな酸味)や味わいが失われるという問題があった。しかし、本発明のコーヒー脂質を低減した乳入りコーヒー飲料は、pHが5.5〜7.0程度、好ましくはpH6.0〜7.0の中性領域であっても、コーヒーの味わいが十分に付与されており、また乳成分のコクも増強されるので、コーヒーと乳とがそれぞれの良さを引き立てあい、広がりがありかつメリハリのある味わいを愉しむことができるコーヒー飲料となる。ここで、用いられるpH調整剤としては、水に溶解した時にアルカリ性を示す物質であれば限定されず、具体的には、重曹(炭酸水素ナトリウム)、炭酸ナトリウム、炭酸カリウム、水酸化ナトリウム、水酸化カリウム、リン酸三ナトリウム、リン酸三カリウムなどが挙げられる。
本発明のコーヒー飲料は、コーヒーと乳とがそれぞれの良さを引き立てあう飲料であり、特に繊細なコーヒーの香りを維持(保持)した嗜好性(ドリンカビリティ;飲料の性質を指し、ある飲料を一定量飲用した後も、なおおいしく飲み続けられる場合には、その飲料はドリンカビリティがあるといえる。ドリンカビリティは「飲みたいかどうか」と表現されることもある。)の高い飲料である。より詳述すると、一般に、コーヒーの香りは、とても繊細、不安定なものであり、抽出直後の香り、風味は時間の経過とともに変化していき、長時間保持できるものではないことが知られている。高温殺菌される容器詰め飲料では、特に、コーヒーの香りや風味の消失、変性が著しいが、コーヒー脂質を低減し、かつ脂質中のカーウェオール及びカフェストールの割合が特定範囲に調整されたコーヒー飲料は、不安定なコーヒーの香りを効果的に維持(保持)する。
(Other ingredients)
Usually, the coffee raw material is weakly acidic, but in order to maintain the stability of the milk component, in the case of a milk-filled coffee beverage packed in a container, a pH adjuster is usually added, and the pH is about 5.5 to 7.0. The pH is preferably adjusted to be in the neutral range of pH 6.0 to 7.0. However, at the stage of pH adjustment, there is a problem that the flavor (for example, faint acidity) and taste inherent to the coffee raw material are lost. However, the milk coffee beverage with reduced coffee lipid according to the present invention has a sufficient coffee taste even when the pH is about 5.5 to 7.0, preferably in the neutral region of pH 6.0 to 7.0. In addition, the richness of the milk component is enhanced, so that coffee and milk complement each other's goodness, and the coffee beverage can be enjoyed with a wide and sharp taste. Here, the pH adjuster used is not limited as long as it is an alkaline substance when dissolved in water. Specifically, sodium bicarbonate (sodium hydrogen carbonate), sodium carbonate, potassium carbonate, sodium hydroxide, water Examples include potassium oxide, trisodium phosphate, and tripotassium phosphate.
The coffee beverage of the present invention is a beverage in which coffee and milk complement each other's goodness, and in particular, the preference (drinkability; the nature of the beverage) that maintains (holds) the fragrance of delicate coffee. If a drink is still delicious after a certain amount of drink, it can be said that the drink is drinkable, which is sometimes expressed as “whether or not you want to drink.”) is there. More specifically, it is generally known that the aroma of coffee is very delicate and unstable, and the aroma and flavor immediately after extraction change over time and cannot be held for a long time. Yes. In the case of container-packed beverages that are pasteurized, coffee that has lost its coffee aroma, flavor, and denaturation, but has reduced coffee lipids and the ratio of carweol and caffe stall in the lipids has been adjusted to a specific range. The beverage effectively maintains (holds) the unstable coffee scent.

なお、コーヒー風味を良好に発現、維持させるために、本発明のコーヒー飲料には、カフェインを含有させることが好ましいが、カフェイン含有量が高いと、本発明の効果を低下させ、かえって加熱臭が強く感じられることがある。カフェインの含有量は、飲料100mLに対して10〜60mgが好ましく、15〜50mgがより好ましく、20〜40mgがさらに好ましい。   In order to express and maintain the coffee flavor well, the coffee beverage of the present invention preferably contains caffeine. However, if the content of caffeine is high, the effect of the present invention is lowered and heated instead. Odor may be felt strongly. The content of caffeine is preferably 10 to 60 mg, more preferably 15 to 50 mg, and still more preferably 20 to 40 mg with respect to 100 mL of beverage.

さらに、必要に応じて、本発明のコーヒー飲料には、甘味料、安定剤等を添加することもできる。   Furthermore, a sweetener, a stabilizer, etc. can also be added to the coffee drink of this invention as needed.

(容器詰め飲料)
本発明の乳入りコーヒー飲料は、上記したとおり、高温殺菌及び長期間の保存による不快な香りや風味を改善した容器詰め飲料である。本発明のコーヒー飲料が充填される容器としては、殺菌方法や保存方法に合わせて適宜選択すればよく、アルミ缶、スチール缶、PETボトル、ガラス瓶、紙容器など、通常用いられる容器のいずれも用いることができる。
(Packed beverage)
As described above, the milk-containing coffee beverage of the present invention is a container-packed beverage that has improved an unpleasant scent and flavor due to high-temperature sterilization and long-term storage. The container filled with the coffee beverage of the present invention may be appropriately selected according to the sterilization method and storage method, and any of the commonly used containers such as aluminum cans, steel cans, PET bottles, glass bottles, and paper containers are used. be able to.

本明細書における高温殺菌とは、高温で短時間殺菌した後、無菌条件下で殺菌処理された保存容器に充填する方法(UHT殺菌法)と、調合液を缶等の保存容器に充填した後、レトルト処理を行うレトルト殺菌法とをいう。高温殺菌の条件は、乳入り飲料の調合液の特性や使用する保存容器に応じて適宜選択すればよいが、UHT殺菌法の場合、通常120〜150℃で1〜120秒間程度、好ましくは130〜145℃で30〜120秒間程度の条件であり、レトルト殺菌法の場合、通常110〜130℃で10〜30分程度、好ましくは120〜125℃で10〜20分間程度の条件である。
コーヒー飲料の香りや風味の評価は、官能評価によって行うことができる。例えば、加熱殺菌処理後および長期間保存後のコーヒー飲料を、繊細なコーヒーの香りの強さや不快臭の強さ、乳成分のコク、ドリンカビリティーなどを指標に評価する。
High temperature sterilization in this specification is a method of filling a storage container that has been sterilized under aseptic conditions after being sterilized for a short time at high temperature (UHT sterilization method), and after filling a storage container such as a can with the preparation liquid The retort sterilization method which performs a retort process is said. The conditions for the high temperature sterilization may be appropriately selected according to the characteristics of the preparation solution of the milk-containing beverage and the storage container to be used, but in the case of the UHT sterilization method, usually at 120 to 150 ° C. for about 1 to 120 seconds, preferably 130. It is the conditions for about 30 to 120 seconds at ˜145 ° C., and in the case of the retort sterilization method, it is usually about 10 to 30 minutes at 110 to 130 ° C., preferably about 10 to 20 minutes at 120 to 125 ° C.
Evaluation of the aroma and flavor of a coffee drink can be performed by sensory evaluation. For example, coffee beverages after heat sterilization treatment and after long-term storage are evaluated by using as an index the strength of delicate coffee aroma, the strength of unpleasant odor, the richness of milk components, and the drinkability.

以下、実施例を示して本発明の詳細を具体的に説明するが、本発明はこれに限定されるものではない。   EXAMPLES Hereinafter, although an Example is shown and the detail of this invention is demonstrated concretely, this invention is not limited to this.

[実施例1]
(1)不溶性コーヒー粉末の調製
ロブスタ種のコーヒー豆を定法にてアグトロン値が50〜60(55程度)になるまで焙煎して、焙煎コーヒー豆を得た。この焙煎コーヒー豆をロール式粉砕機にて粒子径がメジアン径で105μm程度となるまで微粉砕して、焙煎コーヒー豆微粉末(不溶性コーヒー粉末)を得た。なお、本実施例中、粒子径の測定には、マイクロトラック粒度分布測定装置(日機装株式会社製、型式:MT3300EXII)を用いた。測定は、粉体の試料をエアーで分散させながら、レーザー光を試料に照射し、回折散乱パターンから粒子径分布の測定(乾式レーザー回折散乱法)を行い、粒子径の累積データの50%径をメジアン径とした。
(2)焙煎コーヒー豆の抽出物の調製
ロブスタ種のコーヒー豆を定法にてアグトロン値が45〜49になるまで焙煎して、焙煎コーヒー豆を得た。この焙煎コーヒー豆を原料とし、湯による抽出処理を行ってコーヒー抽出液を得、これを噴霧乾燥処理して粒子径がメジアン径で270μm程度の可溶性コーヒー粉末(焙煎コーヒー豆の抽出物)を得た。
(3)コーヒー飲料の調製
上記(1)で調製した不溶性コーヒー粉末(焙煎コーヒー豆微粉末)と、上記(2)で調製した焙煎コーヒー豆の抽出物を用い、表1の処方で混合し、さらに炭酸水素ナトリウムを用いてpHを6.5調整して、コーヒー調合液を得た。
[Example 1]
(1) Preparation of insoluble coffee powder Robusta coffee beans were roasted by a conventional method until the Agtron value reached 50-60 (about 55) to obtain roasted coffee beans. This roasted coffee bean was finely pulverized with a roll-type pulverizer until the particle size became about 105 μm in median size to obtain roasted coffee bean fine powder (insoluble coffee powder). In this example, a microtrac particle size distribution measuring device (manufactured by Nikkiso Co., Ltd., model: MT3300EXII) was used for measuring the particle size. The measurement is performed by irradiating the sample with laser light while dispersing the powder sample with air, measuring the particle size distribution from the diffraction scattering pattern (dry laser diffraction scattering method), and measuring 50% of the cumulative particle size data. Was the median diameter.
(2) Preparation of roasted coffee bean extract Robusta coffee beans were roasted by an ordinary method until the Agtron value was 45 to 49, to obtain roasted coffee beans. Using this roasted coffee bean as a raw material, extraction with hot water is performed to obtain a coffee extract, which is then spray-dried to obtain a soluble coffee powder having a median diameter of about 270 μm (an extract of roasted coffee beans) Got.
(3) Preparation of coffee beverage Using the insoluble coffee powder (roasted coffee bean fine powder) prepared in (1) above and the roasted coffee bean extract prepared in (2) above, mixing in the formulation of Table 1 Further, the pH was adjusted to 6.5 using sodium hydrogen carbonate to obtain a coffee blended liquid.

このコーヒー調合液を食品衛生法に従った殺菌条件で加熱殺菌後、熱可塑性樹脂の容器に150gずつ充填し、容器蓋をヒートシールして密封して容器詰めコーヒー飲料を製造した。また、比較として、不溶性コーヒー粉末を配合せずに焙煎コーヒー豆の抽出物の配合量を1.5重量%とする以外は同様に製造したもの(比較例1)、植物油脂パウダーを配合せずに乳脂肪で置換する以外は同様に製造したもの(比較例2)を製造した。
(4)分析
得られた飲料中の栄養改善法の栄養表示基準(レーゼゴットリーブ法)に基づく脂質量および栄養改善法の栄養表示基準(ケルダール法)に基づく飲料中のたんぱく質量を分析した。また、以下の方法によりコーヒー脂質濃度を求めた。まず、飲料をBrix1.5となるように水で希釈し、(A)パルミチン酸カーウェオール(KwO-pal)及び(B)パルミチン酸カフェストール(CfO-pal)の含量を、LC−MS/MSを使用し、MRMモードにて測定した。以下に測定方法の詳細を示す。
The coffee mixture was heat-sterilized under sterilization conditions in accordance with the Food Sanitation Law, and 150 g each was filled into a thermoplastic resin container, and the container lid was heat-sealed and sealed to produce a container-packed coffee beverage. In addition, for comparison, a product manufactured in the same manner except that the amount of roasted coffee bean extract is 1.5% by weight without adding insoluble coffee powder (Comparative Example 1), vegetable fat powder is added. The same product (Comparative Example 2) was produced except that the fat was replaced with milk fat.
(4) Analysis The amount of lipid based on the nutrition labeling standard (Lases Gottlieb method) of the nutrition improvement method in the obtained beverage and the protein mass in the beverage based on the nutrition labeling standard (Kjeldahl method) of the nutrition improvement method were analyzed. Further, the coffee lipid concentration was determined by the following method. First, the beverage was diluted with water to a Brix of 1.5, and the contents of (A) carwalol palmitate (KwO-pal) and (B) palmitate caffeol (CfO-pal) were measured using LC-MS / Measurement was performed in MRM mode using MS. Details of the measurement method are shown below.

(分析試料の調製)
まず、希釈試料2gをガラス製遠沈管にとり、アセトニトリル4mlを加えて、ボルテックスミキサーで1分間攪拌した。これを遠心機で遠心(1680×g、30分、20℃)し、上清を10mlメスフラスコに移した。遠沈管にエタノール2mlを加え、沈殿物をピペット先端で潰して拡散させた。これを超音波洗浄機に15分かけて不溶物をさらに拡散させ、ボルテックスミキサーで1分間攪拌し、遠心機で遠心(1680×g、30分、20℃)して、上清を10mlメスフラスコに移した。同様のエタノールによる抽出作業を、さらに1回行った。抽出液を回収した10mlメスフラスコをエタノールでメスアップし、よく混ぜた液をPTFE製メンブレンフィルター(東洋濾紙社製、孔径0.2μm、直径25mm)で濾過し、分析試料とした。LC−MS/MSの測定方法は以下のとおり。
(Preparation of analysis sample)
First, 2 g of the diluted sample was placed in a glass centrifuge tube, 4 ml of acetonitrile was added, and the mixture was stirred for 1 minute with a vortex mixer. This was centrifuged with a centrifuge (1680 × g, 30 minutes, 20 ° C.), and the supernatant was transferred to a 10 ml volumetric flask. 2 ml of ethanol was added to the centrifuge tube, and the precipitate was crushed with a pipette tip to diffuse. The insoluble matter was further diffused in an ultrasonic cleaner over 15 minutes, stirred with a vortex mixer for 1 minute, centrifuged with a centrifuge (1680 × g, 30 minutes, 20 ° C.), and the supernatant was added to a 10 ml volumetric flask. Moved to. The same extraction with ethanol was performed once more. The 10 ml volumetric flask from which the extract was collected was diluted with ethanol, and the well mixed liquid was filtered through a PTFE membrane filter (Toyo Roshi Kaisha, pore size 0.2 μm, diameter 25 mm) to obtain an analytical sample. The measuring method of LC-MS / MS is as follows.

(LC−MS/MS分析条件)
〔使用機種〕
・MS:4000QTRAP(AB Sciex社製)
・LC:1290Infinity(Agilent Technologies社製)
〔LC条件〕
・移動相:(A)0.1%ギ酸水溶液、(B)エタノール
・流速:0.4ml/分
・グラジエント条件:0−1分(80%B)、1−5分(80−100%B)、5−7.5分(100%B)、初期移動相による平衡化2.5分
・カラム:Agilent Technologies社製 Zorbax Eclipse Plus RRHD C18 1.8μm 2.1×150mm
・カラム温度:45℃
・導入量:1μl
〔MS条件〕
・イオン源:Heated Nebulizer
・CUR:20
・CAD:Medium
・NC:5
・TEM:400
・GS1:40
・ihe:ON
・切り替えバルブ条件:カラムを通過した移動相のうち、4.5〜5.8分のみをMSに導入した
〔MRM条件〕
・パルミチン酸カーウェオール:535.41→279.17(Q1→Q3)
・パルミチン酸カフェストール:537.43→281.19(Q1→Q3)
・DP:95
・EP:10
・CE:21
・CXP:12
本実施例においては、上記条件でパルミチン酸カーウェオール標準品(MP Biomedicals社製)およびパルミチン酸カフェストール標準品(LKT Labs社製)を分析して検量線をあらかじめ作成し、試料中のパルミチン酸カーウェオールおよびパルミチン酸カフェストールを定量した。上記条件におけるパルミチン酸カーウェオールの溶出時間は5.1分、パルミチン酸カフェストールの溶出時間は5.2分であった。
(LC-MS / MS analysis conditions)
[Models used]
MS: 4000QTRAP (manufactured by AB Sciex)
LC: 1290 Infinity (manufactured by Agilent Technologies)
[LC conditions]
Mobile phase: (A) 0.1% formic acid aqueous solution, (B) ethanol Flow rate: 0.4 ml / min Gradient conditions: 0-1 min (80% B), 1-5 min (80-100% B ), 5-7.5 min (100% B), equilibrated with initial mobile phase 2.5 min. Column: Zorbax Eclipse Plus RRHD C18 1.8 μm 2.1 × 150 mm manufactured by Agilent Technologies
-Column temperature: 45 ° C
・ Introduction volume: 1 μl
[MS conditions]
・ Ion source: Heated Nebulizer
・ CUR: 20
・ CAD: Medium
・ NC: 5
-TEM: 400
・ GS1: 40
・ Ihe: ON
Switching valve condition: Of the mobile phase that passed through the column, only 4.5 to 5.8 minutes was introduced into the MS [MRM condition]
-Carmitol palmitate: 535.41 → 279.17 (Q1 → Q3)
・ Calm Stall Palmitate: 537.43 → 281.19 (Q1 → Q3)
・ DP: 95
・ EP: 10
・ CE: 21
・ CXP: 12
In this example, a calibration curve was prepared in advance by analyzing a standard product of carmitol palmitate (manufactured by MP Biomedicals) and a standard product of cafetall palmitate (manufactured by LKT Labs) under the above conditions, and palmitic acid contained in the sample. Acid carweol and palmitate caffeate were quantified. The elution time of carwalol palmitate under the above conditions was 5.1 minutes, and the elution time of caffeate palmitate was 5.2 minutes.

さらに、飲料中の水不溶性固形分量を以下の方法により求めた。   Further, the water-insoluble solid content in the beverage was determined by the following method.

(水不溶性固形分量の測定)
25℃に恒温したサンプル(コーヒー飲料)をよく攪拌し均一な状態にし、10gを遠沈管に定量し、卓上本架遠心機(KOKVSAN H-28F)を用いて、処理温度20℃、回転数3000rpmで10分間遠心した。保留粒子径が5μmの濾紙の乾燥質量を測定した後、遠沈管内の遠心後の上清固形分を減圧濾過により集めた。次に遠沈管中にイオン交換水を加えて攪拌し、再び同条件で10分間遠心した。遠沈管内の遠心後の上清固形分を該濾紙上に減圧濾過により集めた。残った固形分も該濾紙上に集めて水洗し、減圧濾過した。水洗に用いたイオン交換水は全量で100mLとした。該濾紙を乾燥後に質量を測定し、以下の式により水不溶性固形分量(質量%)を算出した。
(Measurement of water-insoluble solid content)
Stir the sample (coffee beverage) at a constant temperature of 25 ° C to a uniform state, and 10 g is quantified in a centrifuge tube. Using a tabletop centrifuge (KOKVSAN H-28F), the processing temperature is 20 ° C and the rotation speed is 3000 rpm. And centrifuged for 10 minutes. After measuring the dry mass of the filter paper having a retained particle diameter of 5 μm, the supernatant solid content after centrifugation in the centrifuge tube was collected by vacuum filtration. Next, ion-exchanged water was added to the centrifuge tube, and the mixture was stirred and centrifuged again under the same conditions for 10 minutes. The supernatant solid content after centrifugation in the centrifuge tube was collected on the filter paper by vacuum filtration. The remaining solid was also collected on the filter paper, washed with water, and filtered under reduced pressure. The total amount of ion-exchanged water used for washing was 100 mL. After the filter paper was dried, the mass was measured, and the water-insoluble solid content (mass%) was calculated by the following formula.

[水不溶性固形分量(質量%)]=[(乾燥後の濾紙質量(g))−(濾紙の初期乾燥質量(g))]/10(g)×100   [Water-insoluble solid content (mass%)] = [(filter paper weight after drying (g)) − (initial dry weight of filter paper (g))] / 10 (g) × 100

(5)官能評価
3種類の容器詰めコーヒー飲料を1ヶ月間常温で保存した後、冷蔵温度(5〜10℃)に冷却したものを官能評価した。官能評価は5名の専門パネラーにより、加熱臭について、+:強い、±:普通、−:弱いとし、最も多い評価で表わした。
(6)結果
結果を表2に示す。不溶性コーヒー粉末と焙煎コーヒー豆の抽出物と植物油脂とを含有する本発明の乳入りコーヒー飲料は、顕著に加熱臭が低減されていた。
(5) Sensory evaluation After three kinds of container-packed coffee drinks were stored at room temperature for one month, the ones cooled to a refrigeration temperature (5 to 10 ° C.) were subjected to sensory evaluation. The sensory evaluation was expressed by the most frequent evaluations by a panel of five experts regarding the heated odor as +: strong, ±: normal,-: weak.
(6) Results Table 2 shows the results. The milky coffee beverage of the present invention containing the insoluble coffee powder, the roasted coffee bean extract and the vegetable oil / fat has a significantly reduced heating odor.

[実施例2]
実施例1で調製した不溶性コーヒー粉末と焙煎コーヒー豆の抽出物を用い、表3の処方で混合し、さらに炭酸水素ナトリウムを用いてpHを6.5調整してコーヒー調合液を得、実施例1と同様にして容器詰めコーヒー飲料を製造した。また、不溶性コーヒー粉末を配合せずに焙煎コーヒー豆の抽出物の配合量を1.0重量%とする以外は同様に製造したもの(比較例3)、植物油脂パウダーを配合せずに乳脂肪水で置換する以外は同様に製造したもの(比較例4)を製造し、実施例1と同様に分析、評価した。
[Example 2]
Using the insoluble coffee powder and roasted coffee bean extract prepared in Example 1 and mixing in accordance with the formulation shown in Table 3, the pH was adjusted to 6.5 using sodium bicarbonate to obtain a coffee blended solution. A container-packed coffee drink was produced in the same manner as in Example 1. Also, a non-insoluble coffee powder was prepared in the same manner except that the amount of roasted coffee bean extract was 1.0% by weight (Comparative Example 3), milk without vegetable oil powder. A similar product (Comparative Example 4) was produced except that it was replaced with fatty water, and analyzed and evaluated in the same manner as in Example 1.

結果を表4に示す。脂質濃度が高い実施例2においても、不溶性コーヒー粉末と焙煎コーヒー豆の抽出物と植物油脂とを含有する本発明の乳入りコーヒー飲料は、顕著に加熱臭が低減されていた。   The results are shown in Table 4. Also in Example 2 where the lipid concentration is high, the milky coffee beverage of the present invention containing the insoluble coffee powder, the roasted coffee bean extract, and the vegetable oil / fat has a significantly reduced heating odor.

Claims (4)

焙煎コーヒー豆を微粉砕して得られるメジアン径が90〜200μmの不溶性コーヒー粉末と、焙煎コーヒー豆の粉砕物に抽出処理を行って得られる焙煎コーヒー豆の抽出物と、植物油脂と、乳成分とを含有し、高温殺菌して製造される乳入りコーヒー飲料であって、
飲料中の脂質量が、飲料100gあたり0.5〜2.5gであり、
飲料中のコーヒー脂質含量が1.0〜5.0mg/kgである、
前記乳入りコーヒー飲料。
An insoluble coffee powder having a median diameter of 90 to 200 μm obtained by finely pulverizing roasted coffee beans, an extract of roasted coffee beans obtained by subjecting the pulverized roasted coffee beans to an extraction process, and vegetable oils and fats And a milk-containing coffee drink that contains a milk component and is manufactured by high-temperature sterilization,
The amount of lipid in the beverage is 0.5 to 2.5 g per 100 g of beverage,
The coffee lipid content in the beverage is 1.0-5.0 mg / kg,
The milky coffee drink.
飲料中のカフェイン含量が、飲料100gあたり10〜60mgである、請求項1に記載の乳入りコーヒー飲料。   The coffee drink with milk of Claim 1 whose caffeine content in a drink is 10-60 mg per 100g of drinks. pHが5.5〜7.0である、請求項1又は2に記載の乳入りコーヒー飲料。   The milk-containing coffee drink according to claim 1 or 2, wherein the pH is 5.5 to 7.0. 植物油脂がヤシ油である、請求項1〜3のいずれか一項に記載の乳入りコーヒー飲料。   The milk-containing coffee drink according to any one of claims 1 to 3, wherein the vegetable oil is coconut oil.
JP2014039929A 2014-02-28 2014-02-28 Milky coffee drink containing fine powder of roasted coffee beans Active JP6247567B2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2014039929A JP6247567B2 (en) 2014-02-28 2014-02-28 Milky coffee drink containing fine powder of roasted coffee beans
PCT/JP2015/055115 WO2015129649A1 (en) 2014-02-28 2015-02-24 Milk-containing coffee beverage including finely powdered roasted coffee beans
MYPI2016703138A MY172323A (en) 2014-02-28 2015-02-24 Milk-containing coffee beverage that contain particulates of roasted coffee beans

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2014039929A JP6247567B2 (en) 2014-02-28 2014-02-28 Milky coffee drink containing fine powder of roasted coffee beans

Publications (3)

Publication Number Publication Date
JP2015164401A JP2015164401A (en) 2015-09-17
JP2015164401A5 JP2015164401A5 (en) 2017-04-06
JP6247567B2 true JP6247567B2 (en) 2017-12-13

Family

ID=54008967

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2014039929A Active JP6247567B2 (en) 2014-02-28 2014-02-28 Milky coffee drink containing fine powder of roasted coffee beans

Country Status (3)

Country Link
JP (1) JP6247567B2 (en)
MY (1) MY172323A (en)
WO (1) WO2015129649A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102441166B1 (en) * 2017-11-29 2022-09-08 곽태일 Manufacturing method of coffee bean and coffee composition using whey
JP7117853B2 (en) * 2018-01-17 2022-08-15 アサヒ飲料株式会社 Packaged Coffee Beverage and Method for Improving Taste Quality of Packaged Coffee Beverage
CN108308348A (en) * 2018-01-26 2018-07-24 北京旧石器餐饮管理有限公司 Coffee high in fat and preparation method thereof
JP7424775B2 (en) * 2019-09-03 2024-01-30 サントリーホールディングス株式会社 Heat-sterilized packaged beverage containing a high concentration of medium-chain fatty acid triglycerides
WO2023223967A1 (en) * 2022-05-16 2023-11-23 サントリーホールディングス株式会社 Container-packed coffee beverage

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3965267A (en) * 1974-09-17 1976-06-22 Union Carbide Corporation Cryopulverizing and post-treatment of flavoring materials
JP4508729B2 (en) * 2004-06-07 2010-07-21 キリンビバレッジ株式会社 Vegetable oil composition and beverage containing the same
JP4535810B2 (en) * 2004-09-03 2010-09-01 太陽化学株式会社 Composition for enhancing coffee flavor
JP4387440B1 (en) * 2008-06-06 2009-12-16 キリンビバレッジ株式会社 Method for producing containerized coffee

Also Published As

Publication number Publication date
MY172323A (en) 2019-11-21
WO2015129649A1 (en) 2015-09-03
JP2015164401A (en) 2015-09-17

Similar Documents

Publication Publication Date Title
TWI375520B (en) Enriched coffee extract and manufacturing method
JP6247567B2 (en) Milky coffee drink containing fine powder of roasted coffee beans
TW201012397A (en) Beverages with enhanced flavors and aromas and method of making same
TWI544873B (en) Coffee beverage in container and its manufacturing method
AU2009287839B2 (en) Milk composition and milk-added beverage, both having lower whey protein content
JP4387440B1 (en) Method for producing containerized coffee
JP6124817B2 (en) Method for producing container-packed coffee beverage
JP2024024078A (en) Packaged coffee beverage containing γ-aminobutyric acid
JP2014147333A (en) Coffee drink composition, coffee drink containing the same, method for manufacturing container-packed coffee drink, and method for improving taste of container-packed coffee drink
JP6141141B2 (en) Containerized coffee drink with finely ground coffee beans
JP6238634B2 (en) Coffee powder composition
JP6393381B1 (en) Coffee drink
JP2015112033A (en) Coffee beverage and manufacturing method thereof
WO2015019870A1 (en) Coffee powder composition and coffee beverage
JP6329551B2 (en) Milk coffee drink with low coffee fat content
JP7334506B2 (en) Method for producing instant coffee beverage composition
JP6482450B2 (en) Containerized coffee beverage and method for producing the same
JP6218035B2 (en) Coffee beverage containing fine powder of roasted coffee beans and malt extract
JP6789618B2 (en) Packaged coffee beverage with suppressed sourness deterioration
JP2015065918A (en) Coffee drink including coffee lipid
JP7412627B1 (en) Packaged beverages containing soybean ingredients
JP2015065917A (en) Coffee drink including grease component
JP6415766B2 (en) Containerized coffee beverage and method for producing the same
JP6415767B2 (en) Containerized coffee beverage and method for producing the same
WO2020100898A1 (en) Coffee beverage packed in container, and method for producing same

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20170228

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20170228

A871 Explanation of circumstances concerning accelerated examination

Free format text: JAPANESE INTERMEDIATE CODE: A871

Effective date: 20170228

A975 Report on accelerated examination

Free format text: JAPANESE INTERMEDIATE CODE: A971005

Effective date: 20170309

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20170316

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20170511

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20170718

A711 Notification of change in applicant

Free format text: JAPANESE INTERMEDIATE CODE: A711

Effective date: 20170905

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20171020

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20171117

R150 Certificate of patent or registration of utility model

Ref document number: 6247567

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250