JP6214164B2 - Hair cosmetic composition - Google Patents

Description

  The invention disclosed in the present application relates to a hair cosmetic composition. Specifically, the present invention relates to a hair cosmetic composition in which a plurality of agents are mixed and shaken to foam.

  Generally, as a hair cosmetic composition, an oxidation hair dye, a decoloring agent and a decoloring decoloring agent comprising a first agent containing an alkaline agent and a second agent containing an oxidizing agent are known. .

  Conventionally, liquid or cream-like hair cosmetic compositions have been used. However, there is little fear of dripping and the application property to the hair and the feeling of use are excellent. Things have increased.

  Various means for obtaining a foamed dosage form are known. For example, an aerosol type using a liquefied gas such as LPG, a type using a non-aerosol foamer container, a type using a container to shake and foam (a carbon dioxide gas) Including the case of stirring operation using generation).

  The following Patent Document 1 discloses a hair cosmetic composition in which a powdery agent and a liquid agent are mixed and shaken to obtain a foamy dosage form. The hair cosmetic composition disclosed in Patent Document 1 below is advantageous in that the disposal of the can body is unnecessary for the aerosol type. Further, since the foam formed by shaking is small, the foam homogenizing means is unnecessary, and the operation of mixing foaming is further simplified. Moreover, the foamy hair cosmetic composition obtained by shaking also had good holding power on the hair.

  The following Patent Document 2 discloses a hair dyeing or decoloring kit that can be made into a foamy dosage form without using a container having a complicated structure such as an aerosol container or a non-aerosol container.

  As described above, the foam-type hair cosmetic composition has various advantageous aspects. In particular, improvements in hair cosmetic compositions disclosed in the following Patent Document 1 and Patent Document 2 in which the foaming operation is simplified are progressing. And various prescriptions of the 1st agent which mix | blends the alkaline agent and the 2nd agent which mix | blends an oxidizing agent suitable for obtaining a foamy dosage form simply are disclosed.

  A typical oxidizing agent contained in the second agent is hydrogen peroxide. For example, the following Patent Document 1 (Table 3 etc.) and Patent Document 2 (Paragraph 0101) describe a second agent containing hydrogen peroxide.

JP 2011-105620 A JP 2011-184428 A

  The inventor of the present application observed a production test of a hair cosmetic composition with a simplified foaming operation. Unexpectedly, in the production of the second agent containing hydrogen peroxide, a production facility made of metal such as stainless steel was used. It has been found that rust may be generated. Therefore, the present inventor considered that there is some cause in the prescription of the second agent suitable for obtaining a foamy dosage form simply.

  The inventor of the present application first studied by paying attention to the viscosity of the second agent containing hydrogen peroxide. And when the viscosity was made high by mix | blending a higher alcohol with the 2nd agent which produces rust in metal manufacture facilities, such as stainless steel, it discovered that generation | occurrence | production of rust can be suppressed. From this result, it was thought that generation | occurrence | production of rust can be suppressed by the mixing | blending of the higher alcohol to a 2nd agent and / or the raise of the viscosity of a 2nd agent.

  Next, as a result of earnest research on the rust generated, the present inventor has found that amphoteric surfactants (coconut oil fatty acid amidopropyl betaine, etc.), cationic surfactants (stearyltrimethylammonium chloride, etc.), and cationic polymers (polydimethyl chloride). It came to be considered that halide ions which are counter ions of methylenepiperidinium and the like) increase the rust.

  On the other hand, as disclosed in Patent Document 1, the amphoteric surfactant is a useful component for improving the operability of mixed foaming, good foaming, and fine foam. In addition, both the cationic surfactant and the cationic polymer are useful components for improving the operability of mixed foaming, improving touch, and improving foaming.

  From the above, in order to suppress the rust generated in the production of the second agent containing hydrogen peroxide, increase the higher alcohol content of the second agent, increase the viscosity of the second agent, or amphoteric surfactant, It is only necessary to reduce the compounding amount of the cationic surfactant and the cationic polymer, and to reduce the compounding amount of the halide ion which is the counter ion. However, there is a concern that the defoaming action becomes apparent when the amount of the higher alcohol in the second agent is excessive. Further, it is considered that the higher the viscosity of the second agent, the more difficult it is to make the hair cosmetic composition foam. Also, if the amount of amphoteric surfactant, cationic surfactant, and cationic polymer is reduced, it will be difficult to obtain good foam with a simple operation of shaking, and there will also be a problem in touch. It is thought that it will end.

  As a result of earnest research to obtain good foaming and feel while suppressing the generation of rust in the production facility, the inventors of the present application have obtained a combination of specific surfactants, a chelating agent, and a cationic substance. The invention disclosed by the present application has been completed by finding that the identification and the like are effective.

  Therefore, it is an object to be solved by the present application to provide a hair cosmetic composition that can suppress the generation of rust in the production equipment for the second agent containing hydrogen peroxide and can obtain good foaming and feel. .

(First invention)
The first invention of the present application for solving the above-described problems is as follows.
A hair cosmetic composition selected from an oxidative hair dye, a decoloring agent and a decoloring decoloring agent, wherein a plurality of agents are mixed and foamed by shaking,
A plurality of agents, a first agent containing an alkaline agent;
Including a second agent containing hydrogen peroxide, a surfactant, and a chelating agent,
The second agent contains a nonionic surfactant and a cationic surfactant, and the mass ratio of the nonionic surfactant and the cationic surfactant in the second agent is 80% by mass or more of the total surfactant,
The amount of the higher alcohol of the second agent is 4% by mass or less,
The blending amount of the cationic substance which is at least one selected from the cationic surfactant of the second agent and the cationic polymer is 0.001 to 10% by mass,
It is a hair cosmetic composition.

(Second invention)
The second invention of the present application for solving the above-described problems is as follows.
The hair cosmetic composition according to the first invention, wherein the viscosity of the second agent is 3,000 mPa · s or less.

(Third invention)
The third invention of the present application for solving the above problem is
The hair cosmetic composition according to the first invention or the second invention, wherein the cationic surfactant is a cationic surfactant represented by the general formula shown in Chemical Formula 1.
(In the above chemical formula 1, R1 to R3 represent a saturated hydrocarbon group having 1 to 3 carbon atoms, and R1 to R3 may be the same or different from each other.
R4 represents a saturated or unsaturated hydrocarbon group having 12 to 16 carbon atoms.
A ⁻ represents an anion. )

(Fourth invention)
In order to solve the above problems, the fourth invention of the present application is:
The hair cosmetic composition according to any one of the first to third inventions, wherein an alkyl glucoside is blended as the nonionic surfactant.

(Fifth invention)
The fifth invention of the present application for solving the above-mentioned problems is
In the first invention, the second agent contains a cationic surfactant and a cationic polymer, and the mass ratio of the two components in the second agent is cationic surfactant / cationic polymer = 1.5-5. The hair cosmetic composition according to any one of the fourth invention.

(Sixth invention)
The sixth invention of the present application for solving the above-described problems is as follows.
Any one of the first to fifth inventions wherein the mass ratio of the anionic surfactant to the cationic surfactant in the mixture of the plural agents is anionic surfactant / cationic surfactant = 1.0 to 5 The hair cosmetic composition described.

(Seventh invention)
The seventh invention of the present application for solving the above-mentioned problems is
The hair cosmetic composition according to any one of the first to sixth inventions, wherein a compounding amount of the chelating agent in the second agent is 0.01 to 10% by mass.

(Eighth invention)
The eighth invention of the present application for solving the above-mentioned problems is
The operation of foaming by shaking includes at least one selected from an operation of foaming by shaking a container, an operation of mixing and foaming gas by stirring, and an operation of mixing and foaming gas released by stirring. A hair cosmetic composition according to any one of Inventions 1 to 7.

  The hair cosmetic composition disclosed in the present application can suppress the generation of rust in the production facility for the second agent containing hydrogen peroxide, and can obtain good foaming and feel.

  Hereinafter, embodiments of the invention disclosed in the present application will be described including the best mode.

[Hair cosmetic composition]
The hair cosmetic composition disclosed in the present application is a hair cosmetic composition selected from an oxidative hair dye, a decoloring agent and a decoloring decoloring agent, wherein a plurality of the agents are mixed and shaken to foam. A first agent compounded with an alkali agent, and a second agent compounded with hydrogen peroxide, a surfactant, and a chelating agent. The second agent contains a nonionic surfactant and a cationic surfactant, and is nonionic. The mass ratio of the surfactant and the cationic surfactant in the second agent is 80% by mass or more of the total surfactant, the blending amount of the higher alcohol of the second agent is 4% by mass or less, The compounding quantity of the cationic substance which is at least 1 sort (s) chosen from a cationic surfactant and a cationic polymer is 0.001-10 mass%.

  The hair cosmetic composition is a multi-drug formula. The multi-drug formula includes multi-drug formulas such as a 3-drug formula, a 4-drug formula, etc. in addition to a 2-drug formula. If it demonstrates concretely, when it is a 2 agent type, a hair-cosmetics composition is comprised by the 1st agent and the 2nd agent. In the case of a multi-agent type of three or more agents, in addition to the first agent compounding the alkali agent, the second agent compounding the oxidizing agent containing hydrogen peroxide, the third agent compounding the oxidation aid, the thickening The 3rd agent which mix | blends an agent, the 3rd agent which mix | blends an oil-based component, etc. may be contained in the structure of hair cosmetic composition. From the viewpoint of usability, a two-agent system is preferred.

  In the mixing of the plural agents, the mixing ratio of the first agent and the second agent is not particularly limited, but the first agent: second agent = 2: 1 to 1: 6 is preferable.

  The hair cosmetic composition corresponds to an oxidative hair dye, a decoloring agent, or a decoloring decoloring agent. The oxidative hair dye contains a dye component such as an oxidative dye for dyeing hair. In many cases, the depigmenting agent has the same structure as that of the oxidative hair dye except that it does not contain a dye component for dyeing hair. The decoloring decoloring agent usually does not contain a dye component for dyeing hair, and usually contains an oxidation aid. A decoloring agent and a decoloring decoloring agent may mix | blend a dye component in order to color the 2nd agent.

  The hair cosmetic composition is foamed by mixing and shaking multiple agents. The shaking method is not particularly limited as long as a mixture of plural agents can be foamed. From the viewpoint of foaming by a simple operation, one or more selected from an operation of foaming by shaking a container, an operation of mixing and foaming gas by stirring, and an operation of mixing and foaming gas released by stirring including. More preferably, foaming is performed by one operation selected from an operation of shaking a container to foam, an operation of mixing and foaming gas by stirring, and an operation of mixing and foaming gas released by stirring. From the viewpoint of ease of use, the operation of foaming by shaking the container is more preferable.

  In the operation of shaking and foaming the container, the direction of shaking the container is not particularly limited, but an operation of shaking the container up and down to foam is preferable. Moreover, although the frequency | count of shaking a container is not specifically limited, If it dares to illustrate, it will be about 10-40 times, Preferably it is about 15-30 times. Moreover, although the movement distance of a container is not specifically limited, About 20-30 cm is preferable.

  The foamed hair cosmetic composition is applied to the hair with a necessary amount of the mixture attached to a hand with a thin glove, a comb (comb) or a brush.

  The container used for mixing and foaming by mixing a plurality of agents is not particularly limited. From the viewpoint of performing foaming by a simple operation, the containers disclosed in Patent Document 1 and Patent Document 2, and the mixing container and mixing tool disclosed in JP 2012-106954 A are preferable. It is also preferable to make a set including a hair cosmetic composition and a container.

[Description of ingredients blended in hair cosmetic composition]
The first agent of the hair cosmetic composition contains an alkaline agent. The alkaline agent improves the hair dyeing property and decoloring property by promoting the action of hydrogen peroxide blended in the second agent.

  Examples of alkali agents include ammonia, alkanolamines, organic amines (2-amino-2-methyl-1,3-propanediol, guanidine, etc.), inorganic alkalis (sodium hydroxide, potassium hydroxide, etc.), carbonates ( Sodium carbonate, sodium hydrogen carbonate, potassium carbonate, ammonium carbonate, ammonium hydrogen carbonate, etc.), silicates (sodium silicate, potassium silicate, magnesium silicate, etc.), metasilicates (sodium metasilicate, and potassium metasilicate) Etc.), sulfates (such as ammonium sulfate), chlorides (such as ammonium chloride), phosphates (such as primary ammonium phosphate and secondary ammonium phosphate), basic amino acids (such as arginine and lysine) and salts thereof Can be mentioned. Specific examples of the alkanolamine include monoethanolamine, diethanolamine, triethanolamine, monopropanolamine, isopropanolamine, dipropanolamine, tripropanolamine, 2-amino-2-methyl-1,3-propanediol, 2- Examples include amino-2-methyl-1-propanol and 2-amino-2-hydroxymethyl-1,3-propanediol. The alkali agent can use the 1 type (s) or 2 or more types.

  When the first agent is powdered, the alkaline agent is solid. Examples of the solid alkaline agent include the silicates, metasilicates, carbonates, sulfates, chlorides, and phosphates described above.

  From the viewpoint of improving the operability of mixed foaming and the retention of foam to hair, it is preferable to blend the carbonate as an alkaline agent.

  Although the compounding quantity of the alkaline agent in the mixture of multiple agents is not particularly limited, it is preferably an amount that makes the pH of the mixture be in the range of 7-12. If the pH of the mixture is 7 or more, it is considered that the action of hydrogen peroxide is promoted. Moreover, it is preferable to make pH of a mixture into the range of 7-12 also from the surface of the feel of hair. More preferably, the pH is 9-11.

  The second agent contains hydrogen peroxide as an oxidizing agent. Hydrogen peroxide is blended in order to oxidize an oxidative dye to develop a color and to decolorize melanin contained in hair. The blending amount of hydrogen peroxide in the mixture of plural agents is not particularly limited, but is preferably 0.05 to 9% by mass from the viewpoint of obtaining a good feel. More preferably, it is 0.3-7 mass%.

  The second agent may contain an appropriate oxidizing agent other than hydrogen peroxide. Examples of oxidizing agents other than hydrogen peroxide include urea peroxide, melamine peroxide, sodium percarbonate, potassium percarbonate, sodium perborate, potassium perborate, sodium peroxide, potassium peroxide, magnesium peroxide, Examples thereof include barium oxide, calcium peroxide, strontium peroxide, sulfate hydrogen peroxide adduct, phosphate hydrogen peroxide adduct, pyrophosphate hydrogen peroxide adduct, and the like. These 1 type (s) or 2 or more types can be used suitably.

  The surfactant that can be blended in the hair cosmetic composition is not particularly limited. Examples of the surfactant include a cationic surfactant, a nonionic surfactant, an anionic surfactant, and an amphoteric surfactant. These surfactants may be used alone or in combination of two or more thereof.

  The cationic surfactant is an important component in the invention disclosed in the present application, having both a side surface as a surfactant and a side surface as a cationic substance. Examples of the cationic surfactant include alkyl trimethyl ammonium salts, alkenyl trimethyl ammonium salts, dialkyl dimethyl ammonium salts, and dialkenyl dimethyl ammonium salts.

  Specific examples include cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, isostearyltrimethylammonium chloride, lauryltrimethylammonium chloride, behenyltrimethylammonium chloride, octadecyltrimethylammonium chloride, cocoyltrimethylammonium chloride, cetyltrimethylammonium bromide, bromide Examples include stearyl trimethyl ammonium, lauryl trimethyl ammonium bromide, isostearyl lauryl dimethyl ammonium chloride, dicetyl dimethyl ammonium chloride, distearyl dimethyl ammonium chloride, and dicocoyl dimethyl ammonium chloride. Preferably, a lauryltrimethylammonium salt is blended in the hair cosmetic composition.

  The second agent is preferably formulated with a cationic surfactant represented by the general formula shown in Chemical Formula 1 above. More preferably, the second agent contains only the cationic surfactant represented by the general formula shown in Chemical Formula 1 as the cationic surfactant.

From the viewpoint of reducing the viscosity of the second agent in liquid form and from the viewpoint of foaming, in the general formula shown in Chemical Formula 1, R1 to R3 are preferably methyl groups. R4 is preferably a linear saturated hydrocarbon group having 12 to 16 carbon atoms. A ⁻ is not particularly limited, but may be chloride ion, bromide ion, iodide ion, acetate ion or phosphate ion. Since it is easily available, A ⁻ can be a chloride ion or a bromide ion.

  The blending amount of the cationic surfactant in the mixture of plural agents is not particularly limited. It is preferable to set it as 0.0005-10 mass% from a viewpoint of foaming and a touch improvement. More preferably, it is 0.5-9 mass%.

  Examples of nonionic surfactants include alkyl glucosides, ether type nonionic surfactants, ester type nonionic surfactants, and fatty acid alkanolamides (polyoxyethylene coconut oil ethanolamide and the like).

  The alkyl group of the alkyl glucoside is bonded to the sugar moiety by a glucoside bond. The number of alkyl groups bonded to the sugar moiety is not limited, but is preferably 1 to 2. The structure of the alkyl group is not particularly limited as long as the effect of the present invention is not impaired. The alkyl group may be linear, branched, cyclic, or a combination thereof, and there is no limitation on whether it is saturated or unsaturated. It is preferably a linear or branched saturated alkyl group, and more preferably a linear saturated alkyl group. Although carbon number of the said alkyl group is not specifically limited, It is preferable that it is 6-24, It is more preferable that it is 6-18, It is still more preferable that it is 8-16. From the viewpoint of improving foaming, alkyl (8-16) glucoside is preferred. The alkyl (8-16) glucoside is a mixture of alkyl glucosides having different carbon numbers, wherein the linear alkyl group has 8 to 16 carbon atoms.

  Examples of ether type nonionic surfactants include polyoxyalkylene alkyl ethers. As the polyoxyalkylene alkyl ether, polyoxyethylene (hereinafter also referred to as POE) alkyl ether is preferable. The number of polymerizations of the POE is not particularly limited, but is preferably 2 to 50, more preferably 5 to 40, and still more preferably 10 to 40. The length of the alkyl group is not particularly limited, but preferably has 10 to 14 carbon atoms.

  Specific examples of POE alkyl ethers include POE cetyl ether, POE stearyl ether, POE behenyl ether, POE oleyl ether, POE lauryl ether, POE octyl decyl ether, POE hexyl decyl ether, POE isostearyl ether, POE nonyl phenyl ether, POE octyl Examples thereof include phenyl ether and POE polyoxypropylene cetyl ether. Preferably, POE lauryl ether is blended in the hair cosmetic composition.

  Examples of ester type nonionic surfactants include POE sorbitan monooleate, POE sorbitan monostearate, POE sorbitan monopalmitate, POE sorbitan monolaurate, POE sorbitan trioleate, POE glycerine monostearate, monomyristic acid POE glycerin, tetraoleic acid POE sorbit, hexastearic acid POE sorbit, monolauric acid POE sorbit, POE sorbite beeswax, monooleic acid polyethylene glycol, monostearic acid polyethylene glycol, monolauric acid polyethylene glycol, lipophilic monooleic acid glycerin, mono Glyceryl stearate, sorbitan monooleate, sorbitan sesquioleate, sorbitan trioleate, mono Examples include sorbitan teatate, sorbitan monopalmitate, sorbitan monolaurate, sucrose fatty acid ester, decaglyceryl monolaurate, decaglyceryl monostearate, decaglyceryl monooleate, decaglyceryl monomyristate, jojoba wax PEG-80, etc. .

  It is preferable that the mixture of multiple agents contains at least one selected from alkyl glucosides and ether type nonionic surfactants as nonionic surfactants. The mixture of multiple agents may comprise an alkyl glucoside and an ether type nonionic surfactant.

  The blending amount of the nonionic surfactant in the mixture of plural agents is not particularly limited. From the viewpoint of improving foaming and improving the stability of hydrogen peroxide, the amount of the nonionic surfactant in the mixture of plural agents is preferably 0.005 to 12.5% by mass. More preferably, it is 0.25-10 mass%.

  Examples of the anionic surfactant include alkyl ether sulfates such as POE lauryl ether sulfate, alkyl sulfates, alkenyl ether sulfates, alkenyl sulfates, olefin sulfonates, alkane sulfonates, α-sulfone fatty acid salts, There are N-acyl amino acid type surfactants, phosphate mono- or diester type surfactants, sulfosuccinic acid esters and the like. Examples of the sulfosuccinic acid ester include sulfolauric acid lauryl salt. Fatty acids do not fall under anionic surfactants.

  Examples of the counter ion of the anionic group of these anionic surfactants include sodium ion, potassium ion and triethanolamine.

  Examples of amphoteric surfactants include carbobetaine type, amide betaine type, sulfobetaine type, hydroxysulfobetaine type, amide sulfobetaine type, phosphobetaine type, imidazolinium type, alkylbetaine type, alkylamide betaine type, amino acid type There are amphoteric surfactant type and amine oxide type. Examples of the amide betaine type include coconut oil fatty acid amidopropyl betaine.

  The total surfactant content in the mixture of plural agents is preferably 0.5% by mass or more, more preferably 1% by mass or more, from the viewpoint of foaming the mixture by shaking.

  The mixture of plural agents preferably contains an anionic surfactant and a cationic surfactant. Moreover, it is preferable that an anionic surfactant is mix | blended with a 1st agent. From the viewpoint of improving the mixing property and the foaming improvement by the complex with the cationic surfactant compounded in the second agent, the mass ratio of the anionic surfactant to the cationic surfactant in the mixture of the plural agents is the anionic interface. Activating agent / cationic surfactant = 1.0 to 5 is preferable, and 1.1 to 3 is more preferable.

  The second agent of the hair cosmetic composition contains a chelating agent. A chelating agent contributes to suppression of generation | occurrence | production of the rust in the manufacturing equipment of a 2nd agent. In some cases, other agents constituting the hair cosmetic composition may also contain a chelating agent. The chelating agent can use the 1 type (s) or 2 or more types. The compounding amount of the chelating agent in the mixture of plural agents is not particularly limited. From the viewpoint of suppressing rust, improving the feel, and improving the stability of hydrogen peroxide, the blending amount of the chelating agent in the mixture of plural agents is preferably 0.01 to 10% by mass.

  Examples of chelating agents include edetic acid (ethylenediaminetetraacetic acid (EDTA)), ethylenediaminehydroxyethyltriacetic acid, dihydroxyethylethylenediaminediacetic acid, 1,3-propanediaminetetraacetic acid, diethylenetriaminepentaacetic acid (DTPA), and triethylenetetraminehexaacetic acid. Nitrilotriacetic acid, hydroxyethyliminodiacetic acid, L-aspartic acid-N, N-diacetic acid, aminotrimethylenephosphonic acid, hydroxyethanediphosphonic acid, salts thereof, derivatives thereof, and salts of these derivatives Can be mentioned. Among these, edetic acid (ethylenediaminetetraacetic acid (EDTA)), ethylenediaminehydroxyethyltriacetic acid, dihydroxyethylethylenediaminediacetic acid, diethylenetriaminepentaacetic acid (DTPA), hydroxyethanediphosphonic acid, and salts thereof are preferable.

  The hair cosmetic composition may contain a higher alcohol. The higher alcohol is a monohydric alcohol having 6 or more carbon atoms. The higher alcohol can use the 1 type (s) or 2 or more types.

  The carbon chain of the higher alcohol is preferably saturated. The carbon chain of the higher alcohol is preferably linear or branched, and more preferably linear.

  As higher alcohols, lauryl alcohol, myristyl alcohol, cetyl alcohol (cetanol), 2-hexyl decanol, cetostearyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, aralkyl alcohol, 2-octyldodecanol, behenyl alcohol, decyltetradecanol Can be illustrated. Preferably, lauryl alcohol is blended in the hair cosmetic composition.

  The blending amount of the higher alcohol in the mixture of plural agents is not particularly limited. From the viewpoint of improving foam retention and operability, the blending amount of the higher alcohol in the mixture of the plural agents is preferably 0.01 to 5% by mass. If the blending amount of the higher alcohol in the mixture of plural agents exceeds 5% by mass, defoaming is likely to occur, and sufficient foaming may not be obtained.

  The hair cosmetic composition may contain a cationic polymer. As described above, the cationic polymer contributes to improvement of foaming and touch. One or two or more of the cationic polymers can be used.

  The cationic polymer is, for example, one containing an amino group or ammonium group in the polymer chain, or one containing diallyl quaternary ammonium salt as a structural unit, such as a cationized cellulose derivative, a cationic starch, a cationized guar gum derivative, Examples include diallyl quaternary ammonium salts / acrylamide copolymers and quaternized polyvinylpyrrolidone derivatives. From the viewpoint of easy availability, for example, dimethyldiallylammonium chloride / acrylamide copolymer, dimethyldiallylammonium chloride / acrylic acid copolymer, polydimethylmethylenepiperidium chloride, hydroxyethylcellulose dimethyldiallylammonium chloride, O- [2-hydroxychloride] -3- (Trimethylammonio) propyl] hydroxyethylcellulose.

  From the viewpoint of improving the feel of hair and reducing the viscosity of the second agent, the cationic polymer is preferably a product prepared in a liquid form at 25 ° C. as a raw material. Examples of products prepared in a liquid state at 25 ° C. include, for example, Marquat 550 (dimethyldiallylammonium chloride / acrylamide copolymer), Marquat 280, 295 (dimethyldiallylammonium chloride / acrylic acid copolymer), and Marquat 100 (polyethylene). And dimethylmethylenepiperidinium chloride) and O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride.

  The compounding quantity of the cationic polymer in the mixture of multiple agents is not particularly limited. From the viewpoint of improving the feel, the blending amount of the cationic polymer in the mixture of the plural agents is preferably 0.0005 to 4.5% by mass, and more preferably 0.05 to 2% by mass.

  The cationic substance refers to the above-described cationic surfactant and cationic polymer. One type or two or more types of cationic substances may be used.

  When the hair cosmetic composition is an oxidative hair dye, a dye component is blended. The dye component is preferably blended with the first agent.

  An oxidation dye is mix | blended with an oxidation hair dye. Oxidative dyes are compounds that can develop color by oxidative polymerization. The oxidation dye is not particularly limited, and examples thereof include dye intermediates, couplers, and melanin precursors. One or more oxidation dyes may be used.

  More specifically, for example, as oxidative dyes, phenylenediamine and derivatives thereof, phenol derivatives, aminophenol and derivatives thereof, diphenylamine and derivatives thereof, pyridine derivatives, pyrimidine derivatives, pyrazole derivatives, pyrrolidine derivatives, toluene derivatives, indole derivatives, Examples include pyrrole derivatives and imidazole derivatives.

  More specifically, for example, as a dye intermediate, phenylenediamines (excluding metaphenylenediamine), aminophenols (however, metaaminophenol, 2,4-diaminophenol and paramethylaminophenol are included. Toluylenediamines such as toluene-2,5-diamine (excluding toluene-3,4-diamine and toluene-2,4-diamine), diphenylamines, diaminophenylamines, N- And phenylphenylenediamines, diaminopyridines (excluding 2,6-diaminopyridine) and the like.

  As couplers, pyrogallol, resorcin, catechol, metaaminophenol, metaphenylenediamine, 2,4-diaminophenol, 1,2,4-benzenetriol, toluene-3,4-diamine, toluene-2,4-diamine, Hydroquinone, α-naphthol, 2,6-diaminopyridine, 1,5-dihydroxynaphthalene, 5-aminoorthocresol, paramethylaminophenol, 2,4-diaminophenoxyethanol, gallic acid, tannic acid, ethyl gallate, gallic acid Examples include methyl, propyl gallate, pentaploid, 5- (2-hydroxyethylamino) -2-methylphenol, and the like.

  An oxidative dye is a concept that includes a salt of a compound that can develop color by oxidative polymerization. For example, acid addition salts of the above-mentioned compounds can be mentioned. Preferable examples include addition salts of organic acids, addition salts of inorganic acids such as sulfates, and the like.

  Furthermore, you may mix | blend a direct dye. Examples of direct dyes include acid dyes, basic dyes, natural dyes, nitro dyes, and disperse dyes. A direct dye may mix | blend the 1 type (s) or 2 or more types.

  The hair cosmetic composition may contain any component. For example, water, water-soluble polymers other than the above-mentioned cationic polymers such as hydroxyethylcellulose, carboxyvinyl polymer, solvents such as propylene glycol, amino acids other than basic amino acids, fatty acids other than fatty acids and higher alcohols, sorbitol, maltose, etc. Preservatives such as saccharides, parabens, sodium benzoate, phenacetin, 8-hydroxyquinoline, acetanilide, phenoxyethanol, sodium pyrophosphate, barbituric acid, uric acid, tannic acid and other stable ingredients, phosphoric acid, disodium hydrogen phosphate, etc. 1 or more selected from pH adjusting components, antioxidants such as sodium sulfite, plant or herbal extracts, vitamins containing ascorbic acids, fragrances, non-silicas such as sodium sulfate, and dispersing agents such as magnesium stearate Even if you mix There. In addition, for example, at least one selected from those listed in “Quasi-drug raw material standards 2006” (Pharmaceutical Daily) may be blended.

[Description of the second agent]
The second agent contains at least hydrogen peroxide, a surfactant and a chelating agent. In addition, the above-described components may be appropriately blended on the condition that the generation of rust in the second agent production facility is suppressed. If the step of heating is included in the production of the second agent, rust in the production facility is likely to be generated, so it is also preferable to preferentially blend a water-soluble component or a liquid component at 25 ° C. However, usually an alkali agent and an oxidation dye are not blended in the second agent.

  Although the compounding quantity of the hydrogen peroxide in a 2nd agent is not specifically limited, It is preferable to set it as 0.1-10 mass% from a viewpoint of suppressing generation | occurrence | production of the rust in the manufacturing equipment of a 2nd agent, and a viewpoint of coloring improvement. More preferably, it is 0.5-8 mass%.

  The compounding amount of the chelating agent in the second agent is not particularly limited. From the viewpoint of suppressing the occurrence of rust in the production equipment for the second agent and improving the feel, it is preferably 0.01 to 10% by mass, more preferably 0.1 to 10% by mass, and 0 More preferably, it is 25-8 mass%.

The second agent contains a nonionic surfactant and a cationic surfactant. In order to obtain the effects of the invention disclosed in the present application, the mass ratio of the nonionic surfactant and the cationic surfactant (nonionic surfactant and cationic surfactant / total surfactant) is added to the second agent. 80% by mass or more of the total surfactant to be produced. Preferably it is 90 mass% or more. More preferably, the surfactant added to the second agent is only a nonionic surfactant and a cationic surfactant. In other words, the anionic surfactant and the amphoteric surfactant are much less in the second agent than the nonionic surfactant and the cationic surfactant. If the mass ratio is less than 80% by mass, there is a possibility that the problem of increased rust generation or reduced touch occurs.

  From the viewpoint of improving foaming, the second agent preferably contains an alkyl glucoside as a nonionic surfactant. Although the compounding quantity of the alkyl glucoside in a 2nd agent is not specifically limited, 0.01-15 mass% is preferable and 0.3-10 mass% is more preferable. More preferably, the second agent contains only alkyl glucoside as a nonionic surfactant. From the viewpoint of improving foaming, the blending amount of the nonionic surfactant in the second agent is preferably 0.01 to 15% by mass, and more preferably 0.3 to 10% by mass.

  It is preferable that a 2nd agent contains 1 or more types chosen from alkyl glucoside and an ether type nonionic surfactant as a nonionic surfactant. The mixture of multiple agents may comprise an alkyl glucoside and an ether type nonionic surfactant.

  The second agent contains a cationic substance. In the second agent, the cationic polymer is an optional component among the cationic substances, but preferably, the second agent contains a cationic surfactant and a cationic polymer.

  In order to acquire the effect of the invention which this application discloses, the compounding quantity of the cationic substance in a 2nd agent is 0.001-10 mass%. If the blending amount of the cationic substance in the second agent is less than 0.001% by mass, there is a problem that the touch is lowered, and there is a problem that foaming is lowered depending on circumstances. When the blending amount of the cationic substance in the second agent exceeds 10% by mass, there is a problem that the generation of rust in the production facility for the second agent is increased. 0.1-10 mass% is preferable and the compounding quantity of the cationic substance in a 2nd agent has more preferable 0.1-5 mass%.

  From the viewpoint of suppressing rust in the production equipment for the second agent, the blending amount of the cationic surfactant in the second agent is preferably 0.001 to 10% by mass, more preferably 0.1 to 10% by mass, and 4-7 mass% is further more preferable.

  From the viewpoint of suppressing rust in the production equipment for the second agent, the blending amount of the cationic polymer in the second agent is preferably 0.001 to 7 mass%, more preferably 0.01 to 3 mass%, 2% by mass is more preferable.

  When the second agent mixes the cationic surfactant and the cationic polymer, the mass ratio is not particularly limited. From the viewpoint of suppressing the occurrence of rust in the production facility for the second agent and improving the feel, it is preferable that the cationic surfactant / cationic polymer = 1.5 to 5 in the second agent. More preferably, it is 7-5.

  From the viewpoint of keeping the viscosity of the second agent low and from the viewpoint of foaming of the hair cosmetic composition (mixture), the blending amount of the higher alcohol in the second agent is 4% by mass or less. That is, the second agent may not contain a higher alcohol. When the blending amount of the higher alcohol in the second agent exceeds 4% by mass, there is also a problem that it is difficult to mix with the first agent. The amount of higher alcohol in the second agent is preferably 3% by mass or less, more preferably 1% by mass or less, more preferably 0.5% by mass or less, and 0.25% by mass or less. More preferably.

  Further, from the viewpoint of keeping the viscosity of the second agent low, it is preferable that the higher alcohol blended in the second agent has 10 to 14 carbon atoms.

  The dosage form of the second agent can be appropriately selected. A preferable dosage form is liquid (liquid, emulsion).

  The viscosity of the second agent is not particularly limited. In order to obtain good bubbles by a simple operation of shaking the mixture, the viscosity of the second agent is preferably 3,000 mPa · s or less, and more preferably 2500 mPa · s or less.

  As described above, the present application also discloses the production of the second agent that suppresses the occurrence of rust in the production facility.

[Description of the first agent]
The first agent contains at least an alkaline agent. In addition, you may mix | blend the component mentioned above suitably. However, normally hydrogen peroxide is not blended with the first agent.

  The first agent is preferably blended with at least one selected from anionic surfactants and amphoteric surfactants in order to obtain good foam by a simple operation of shaking the mixture. In particular, the first agent preferably contains an anionic surfactant.

  In addition, from the viewpoint of improving the feel by adding a cationic polymer that cannot be added to the second agent, it is also preferable that the first agent contains a cationic polymer. In addition, when a 1st agent is a powder form, it is preferable to mix | blend a powdered cationic polymer.

  The dosage form of the first agent can be appropriately selected. Examples of preferable dosage forms include powder, liquid (liquid, emulsion), and emulsion (cream). More preferably, it is a powder or an emulsion.

  Examples of the invention disclosed in the present application will be described below. The technical scope of the invention disclosed in the present application is not limited to the following examples.

  The 1st agent and 2nd agent which concern on each Example and comparative example of following Table 1-14 were prepared by the conventional method. Next, how to read the table will be explained.

The unit of the numerical value indicating the blending amount of each component in the table is% by mass.
The dosage forms of the first agent and the second agent are also shown in the table.
In the column of “1 agent: 2 agents” in the table, the mixing ratio of the first agent and the second agent according to each example and comparative example is described.
In the “Viscosity” column in the table, the viscosity (unit: mPa · s) of the first agent and the second agent is described. When simply indicated as “viscosity” in the table, it refers to the viscosity of the second agent. In the case where “viscosity of one agent” or “viscosity of two agents” is indicated, it indicates the viscosity of the first agent and the viscosity of the second agent.
In the “Kachi Active + Kachi Poly” column in the table, the total amount of the cationic surfactant and the cationic polymer in the second agent is described.
In the “Kachi Active / Kachi Poly” column in the table, the mass ratio of the cationic surfactant to the cationic polymer in the second agent (cationic surfactant / cationic polymer) is described.
In the “Anion / Cation” column in the table, the mass ratio of the anionic surfactant to the cationic surfactant (anionic surfactant / cationic surfactant) in the mixture was described.

[Explanation of evaluation]
First, evaluation items and evaluation criteria in each example and comparative example will be described. In each example and comparative example, the items “rust”, “foaming”, and “feel” were evaluated. The evaluation results are shown in the table.

〔rust〕
Half of the JIS standard SUS test piece was submerged in the second agent according to each Example and Comparative Example, and the presence or absence of rust on the test piece was evaluated. The evaluation criteria are as follows. The evaluation was performed by three people, and the average value was rounded to the nearest whole number and listed in the table.

5: The test piece does not rust even if it is submerged for 1 week at 30 ° C.
4: Rust occurs on the test piece submerged for 3 days to less than 1 week under the condition of 30 ° C.
3: Rust occurs on the test piece submerged in 1 day to less than 3 days under the condition of 30 ° C.
2: Rust occurs on the test piece submerged in less than one day under the condition of 30 ° C.
Under the condition of 1-30 ° C., rust is generated on the test piece submerged in less than one day, and rust grows with time.

[Bubbling]
The amount of foam in the container after foaming the mixture of the first agent and the second agent according to each Example and Comparative Example was visually evaluated. The evaluation criteria are as follows. The evaluation was performed by three people, and the average value was rounded to the nearest whole number and listed in the table. The standard “bubbles leak” is applied in Test Examples 4 and 5.

5: Foam occupies 80% or more of the container, and the foam does not leak from the container.
4: Foam occupies 60% to less than 80% of the container, or the foam is slightly coarse and leaks a little from the container.
3: Foam occupies 40% to less than 60% of the container, or the foam is slightly coarse and leaks somewhat from the container.
2: Foam occupies 20% to less than 40% of the container, or there are many leaks of coarse foam from the container.
1: Foam accounts for less than 20% of the container, or very coarse foam leaks from the container.

[Feel]
The mixture according to each example and comparative example is foamed, a hair bundle having a length of 30 cm and a weight of 3 g is hair-dyed with 30 g of the foamy oxidative hair dye, and the finger in the middle of flowing with hot water is passed. Panelists evaluated. The evaluation criteria are as follows. The evaluation was performed by three people, and the average value was rounded to the nearest whole number and listed in the table.

5: Very smooth and does not entangle with fingers.
4: Smooth and almost entangled with fingers.
3: Smooth and less tangled with fingers.
2: There is a squeak and the entanglement with a finger is conspicuous
1: Very squeaky and tangled on fingers.

[Test Example 1]
In Test Example 1, a liquid second agent and a powdery first agent were used. As a container, the height is 14 cm, the inner diameter is 7-8 cm with the diameter expanded upward, the container itself has a capacity of 600 ml, the lid is 5 cm high, a convex dome shape, the height is 17 cm with the lid on, and the dose is 770 ml. The container was used. The shape of the container is the same as that in FIGS.

  The 1st agent shown in Examples 1-44 shown in Table 1-Table 8, the 2nd agent of Comparative Examples 1-10, and Table 9 was used. (Note that Table 9 also shows the case where the second agent according to Example 1 is used for the sake of convenience.) The first agent and the second agent are placed in a container at the mixing ratio shown in the table (the first agent and The total amount (total) of the second agent was 120 g), covered, and shaken up and down 30 cm and 20 times to obtain a foamy oxidative hair dye. After the shaking operation, the above-mentioned “foaming” was evaluated, and the above-mentioned “feel” was evaluated using the resulting foamy oxidative hair dye. The evaluation of the “rust” was separately performed using the second agent according to each example and comparative example.

[Table 1]

[Table 2]

[Table 3]

[Table 4]

[Table 5]

[Table 6]

[Table 7]

[Table 8]

[Table 9]

[Test Example 2]
In Test Example 2, the powdery first agent and the liquid second agent shown in Example 1 were used. In Test Example 2, the first agents of Examples 51 to 56 shown in Table 10 were used. The specific test operation and evaluation were the same as in Test Example 1 above. In addition, since the 2nd agent is what is shown in Example 1, the test of rust itself was abbreviate | omitted and the evaluation of the same rust as Example 1 was described in the table | surface.

[Table 10]

[Test Example 3]
In Test Example 3, the liquid or creamy first agent and the liquid second agent shown in Example 1 were used. The container is the same as in Test Example 1.

  About Examples 61-62 shown in Tables 11-12, the 1st agent and the 2nd agent are put in a container with the mixing ratio shown in the table (the total amount (total) of the 1st agent and the 2nd agent is 140g), and a lid The mixture was shaken up and down 30 cm and 20 times to obtain a foamy oxidative hair dye. After the shaking operation, the above-mentioned “foaming” was evaluated, and the above-mentioned “feel” was evaluated using the resulting foamy oxidative hair dye. In addition, since the 2nd agent is what is shown in Example 1, the test of rust itself was abbreviate | omitted and the evaluation of the same rust as Example 1 was described in the table | surface.

[Table 11]

[Table 12]

[Test Example 4]
In Test Example 4, the powdery first agent shown in Table 9 and the liquid second agent shown in Example 1 were used. As the container, an upper open container having a capacity of 600 ml was used. A spatula was used as a foaming tool.

  About Example 71 shown in Table 13, the 1st agent and the 2nd agent are put in a container with the mixing ratio shown in the table (the total amount of the first agent and the second agent (total) is 120 g), and manually using a foaming tool. To obtain a foamy oxidative hair dye. After the stirring operation, the above-mentioned “foaming” was evaluated, and the above-mentioned “feel” was evaluated using the obtained foamy oxidative hair dye. In addition, since the 2nd agent is what is shown in Example 1, the test of rust itself was abbreviate | omitted and the evaluation of the same rust as Example 1 was described in the table | surface.

[Table 13]

[Test Example 5]
In Test Example 5, a creamy first agent and a liquid second agent were used. As the container, an upper open container having a capacity of 600 ml was used. A spatula was used as a foaming tool. Carbon dioxide released from the first agent was also used for foaming.

  About Example 81 shown in Table 14, the 1st agent and the 2nd agent are put in a container with the mixing ratio shown in the table (total amount of the first agent and the second agent (total) is 120 g), and manually using a foaming tool And the foamed oxidative hair dye was obtained using the liberated carbon dioxide gas. After the foaming operation, the above-mentioned “foaming” was evaluated, and the above-mentioned “feel” was evaluated using the resulting foamy oxidative hair dye. Evaluation of the above “rust” was separately performed using the second agent according to Example 81.

[Table 14]

[Test Example 6]
Cetyl alcohol and stearyl alcohol were added to the second agent according to Comparative Example 9 until the viscosity reached 5,000 mPa · s, and the “rust” item was tested. As a result, the rating was improved to 4. From the above, although the reason is not necessarily clear, the evaluation of the “rust” item has been improved by blending higher alcohol and / or increasing the viscosity. However, the evaluation of foaming was inferior to the evaluation result of Comparative Example 9.

  According to the present application, there is provided a hair cosmetic composition capable of suppressing the generation of rust in the production equipment for the second agent containing hydrogen peroxide and obtaining good foaming and feel.

Claims (1)

A hair cosmetic composition (excluding a composition containing a keratose hydrolyzate or a derivative thereof) selected from an oxidative hair dye, a decoloring agent, and a decoloring decoloring agent, which is foamed by mixing a plurality of agents. And
A plurality of agents, a first agent containing an alkaline agent (excluding a powdery first agent containing starch and a first agent containing a carboxylic acid anionic surfactant);
Includes a second agent containing hydrogen peroxide, a surfactant, and a chelating agent (excluding hair cosmetic compositions containing a thickening composition containing a thickener in addition to the first and second agents) ), The second agent contains a nonionic surfactant and a cationic surfactant, and the mass ratio of the nonionic surfactant and the cationic surfactant in the second agent is 80% by mass or more of the total surfactant. ,
The amount of the higher alcohol of the second agent is 0.5 % by mass or less,
The blending amount of the cationic substance which is at least one selected from the cationic surfactant of the second agent and the cationic polymer is 0.001 to 10% by mass,
A hair cosmetic composition characterized by the above.