JP6190556B1 - Spiny cheese-like processed food - Google Patents

Spiny cheese-like processed food Download PDF

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JP6190556B1
JP6190556B1 JP2017073710A JP2017073710A JP6190556B1 JP 6190556 B1 JP6190556 B1 JP 6190556B1 JP 2017073710 A JP2017073710 A JP 2017073710A JP 2017073710 A JP2017073710 A JP 2017073710A JP 6190556 B1 JP6190556 B1 JP 6190556B1
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祐貴 武藤
祐貴 武藤
敦則 熊西
敦則 熊西
山本 浩志
浩志 山本
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Ueda Oils and Fats Manufacturing Co Ltd
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Abstract

【課題】実質的に乳タンパク質を含有しないにもかかわらず、チーズ特有の保形性及び食感を有し、裁断、切削等の加工適性を持ち、加熱時には良好な溶融性と曳糸性を示すチーズ様加工食品を提供する。更には乳成分をはじめとする食物アレルギーを引き起こす可能性のある原材料を含有しないチーズ様加工食品を提供する。【解決手段】特定の加工デンプンと油脂と水を含有させ、微細化された無数の油滴粒子の周りを水により膨潤したデンプンが覆う乳化構造を有する加工食品とした。更には該加工食品の構成成分である油脂に特定の物性を持たせることで乳化構造の安定性を高め、常温で良好な保形性を保持しつつ加熱により良好な溶融性が見られ、表面に艶のある見栄えの良いチーズ様加工食品とした。【選択図】なし[PROBLEMS] To have a shape retention and texture peculiar to cheese despite having substantially no milk protein, to have processing suitability such as cutting and cutting, and to have good meltability and stringiness upon heating. Provide the cheese-like processed food shown. Furthermore, the present invention provides a cheese-like processed food that does not contain raw materials that may cause food allergies, including milk components. A processed food having an emulsified structure containing a specific modified starch, fats and oils, and water and starch swollen by water around an infinite number of refined oil droplet particles. Furthermore, the stability of the emulsified structure is enhanced by imparting specific physical properties to the fats and oils that are constituents of the processed food, and good meltability is observed by heating while maintaining good shape retention at room temperature. This is a cheese-like processed food that is glossy and looks good. [Selection figure] None

Description

本発明は加熱時にチーズ様の曳糸性を有する実質的に乳タンパク質を含有しない加工食品に関するものである。 The present invention relates to a processed food having cheese-like spinnability when heated and substantially free of milk protein.

チーズは乳及び/または乳から得られる原料から造られている乳製品の一つであり、牛、水牛、山羊、羊等から得られる乳、中でも牛乳が最もよく使用されている。日本においてチーズとは法令上ナチュラルチーズ、プロセスチーズであり、チーズの文言が入るものとしてチーズフードがあるが、いずれも乳が成分として含まれており、製造方法や成分及びその量に厳格な制約がある。 Cheese is one of dairy products made from milk and / or raw materials obtained from milk, and milk obtained from cows, buffalo, goats, sheep, etc., among which milk is most often used. In Japan, cheese is a natural cheese or process cheese under the law, and there is cheese food that contains the wording of cheese, but all contain milk as an ingredient, and there are strict restrictions on the manufacturing method, ingredients and amount There is.

チーズの需要は年々増加しており、そのものを食するだけでなく様々な食品に使用され、調理には欠かせない原材料として定着している。使用する際の選択基準において、チーズの独特な風味の重要性はさることながら、硬さや弾力性、固形、半固形、流動状等の形状や切断、粉砕のし易さ、加熱時の溶け具合や焼き色等、用途が広がるほど種々要求される物性が多岐にわたっている。中でも加熱時に適度に溶けて、独特な粘性と曳糸性を持つというチーズ独特の性質が食する時の見た目と食感の点で好ましいものとしてとらえられている。これらの求められる性質に十分に対応するにはナチュラルチーズでは限界があるので、プロセスチーズやチーズフード、さらにはチーズに加えるための様々な食品原料や食品添加物の使用が検討され、チーズ風味食品と称するものが提案されている The demand for cheese is increasing year by year, and it is not only eaten, but also used in various foods. It has become an essential ingredient for cooking. In addition to the importance of the unique flavor of cheese in the selection criteria when using it, the shape and shape of hardness, elasticity, solid, semi-solid, fluid, etc., cutting, ease of crushing, melting condition during heating As the application spreads, such as baked and baked colors, various physical properties are required. Among them, the cheese has a unique property that it melts moderately when heated and has a unique viscosity and spinnability. Natural cheese has limits to fully meet these required properties, so processed cheeses, cheese foods, and the use of various food ingredients and food additives to add to cheese are being considered. Has been proposed

チーズ特有の曳糸性という物性は調理において食感と見た目で非常に魅力的であるが、この物性を発現させるにはたとえ少量であってもチーズを加えるか、乳タンパク質の代わりとなるタンパク質を利用する必要があった。一方、近年、食物アレルギーを持つ人への配慮も社会的使命の1つであり、アレルギーの心配なく食事を楽しめるようにするには、アレルギーの原因となる乳タンパク質あるいは更に拡大してタンパク質を含有していないにもかかわらず、チーズ様の風味や食感を味わうことができるような食品を提供してほしいとの要望が国内外で高まっている。 Cheese's unique property of stringiness is very attractive in terms of texture and appearance in cooking, but in order to express this physical property, even if it is a small amount, cheese is added or a protein that replaces milk protein is added. It was necessary to use. On the other hand, in recent years, consideration for people with food allergies is also a social mission, and in order to be able to enjoy meals without worrying about allergies, milk proteins that cause allergies or further expanded proteins are included. Despite not doing so, there is a growing demand in Japan and overseas to provide foods that can taste cheese-like flavor and texture.

タンパク質を低減しつつ、曳糸性を有するものとして特許文献1に増粘剤と酸処理デンプン、パーム油中融点画分、トータルミルクプロテイン等のタンパク質の使用が提案されている。タンパク質含量が10重量%以下である糸曳き性チーズ食品において、最もタンパク質含量の低いものとして本文中の実施例には2.0重量%の配合例しか記載されておらず、タンパク質を含有していない糸曳き性チーズ食品の品質の評価はされていない。また、特許文献2には馬鈴薯由来のデキストリンとカラギナン等の増粘多糖類、アラビアガム等の乳化剤を構成成分とし、実質的にタンパク質を含まないものが提示されているが、曳糸性を持ち合わせていない。チーズの多岐にわたる特性を発揮するには乳タンパク質が重要な役割を果たしており、乳タンパク質の機能を代替できるタンパク質も一切使用しないでチーズに期待される特性を全て満足させることは非常に困難であった。 Patent Document 1 proposes the use of a protein such as a thickener, acid-treated starch, a palm oil melting point fraction, and a total milk protein as having a spinnability while reducing protein. In a stringing cheese food product having a protein content of 10% by weight or less, only 2.0% by weight of the formulation example is described in the examples in the text as the one having the lowest protein content, and it contains protein. There is no evaluation of the quality of no stringing cheese food. Patent Document 2 proposes a potato-derived dextrin, a thickening polysaccharide such as carrageenan, and an emulsifier such as gum arabic, which is substantially free of protein. Not. Milk protein plays an important role in demonstrating the diverse characteristics of cheese, and it is very difficult to satisfy all the characteristics expected of cheese without using any protein that can replace the function of milk protein. It was.

特開2015−188387JP2015-188387 特開2010−142181JP2010-142181A

本発明は実質的に乳タンパク質を含有しないにもかかわらず、チーズ特有の保形性及び食感を有し、切断、裁断、切削等の加工適性を持ち、加熱時には良好な溶融性と曳糸性を示すチーズ様加工食品を提供することを目的とする。更には乳成分をはじめとする食物アレルギーを引き起こす可能性のある原材料やタンパク質を含有しないチーズ様加工食品を提供することである。 Although the present invention substantially does not contain milk protein, it has a shape retention and texture peculiar to cheese, has suitability for cutting, cutting, cutting, etc., and has good meltability and stringiness when heated It aims at providing the cheese-like processed food which shows property. Furthermore, it is providing the cheese-like processed food which does not contain the raw material and protein which may cause food allergy including a milk component.

本発明者は特定の加工デンプンの組み合わせとすること、及び油脂と水を含有させ、微細化された無数の油滴粒子の周りを水により膨潤したデンプンが覆う乳化構造を有する加工食品とすることにより前記課題を解決できることを見出し、本発明を完成させるに至った。更には該食品の構成成分である油脂を、特定の物性を持つ油脂とすることで乳化構造の安定性を高め、常温で良好な保形性を保持しつつ加熱により良好な溶融性が見られ、表面に艶のある見栄えの良いチーズ様加工食品としたのである。 The present inventor shall make a combination of a specific modified starch, and a processed food having an emulsified structure that contains oil and fat and water, and is covered with a starch swollen by water around innumerable fine oil droplet particles. Thus, the inventors have found that the above problems can be solved, and have completed the present invention. Furthermore, the stability of the emulsified structure is improved by making the fats and oils that are constituents of the food into fats and oils having specific physical properties, and good meltability is observed by heating while maintaining good shape retention at room temperature. The cheese-like processed food with a glossy surface and good appearance.

すなわち本発明は、
(1)乳由来タンパク質含量が0.1質量%以下であって、酸化デンプンを15〜30質量%、ヒドロキシプロピルデンプンを2〜8質量%含みそれらの総量は加工食品の総質量の20〜35質量%であり、酸化デンプンとヒドロキシプロピルデンプンの含有比が15:1〜2:1であり、上昇融点30℃以上の油脂を10〜40質量%、及び水を含有し、酸化デンプン総量中のアミロース含量が0.1〜23質量%で、実質的に乳由来タンパク質を含有せずとも加熱時に曳糸性を有するチーズ様加工食品、
(2)タンパク質含量が0.1%以下で実質的にタンパク質を含有しない(1)に記載のチーズ様加工食品、
(3)油脂のSFCが10℃で50〜95%、20℃で40〜85%である(1)または)に記載のチーズ様加工食品、
(4)実質的に乳由来原料を含有しない(1)〜()のいずれかに記載のチーズ様加工食品、
(5)形状がブロック状、スライス状、サイノメ状、短冊状、シュレッド状、粉状である(1)〜()のいずれかに記載のチーズ様加工食品を提供するものである。
That is, the present invention
(1) Milk- derived protein content is 0.1% by mass or less, containing 15-30% by mass of oxidized starch and 2-8% by mass of hydroxypropyl starch, the total amount of which is 20 to 20 % of the total mass of the processed food 35% by mass, the content ratio of oxidized starch and hydroxypropyl starch is 15: 1 to 2: 1, contains 10 to 40% by mass of fats and oils having a rising melting point of 30 ° C. or higher , and water, Cheese-like processed food having a amylose content of 0.1 to 23% by mass and having a stringiness upon heating without substantially containing milk- derived protein,
(2) The cheese-like processed food according to (1), having a protein content of 0.1% or less and substantially free of protein,
(3) The cheese-like processed food according to (1) or ( 2 ), wherein the SFC of the fat is 50 to 95% at 10 ° C and 40 to 85% at 20 ° C.
(4) The cheese-like processed food according to any one of (1) to ( 3 ), which contains substantially no milk-derived raw material.
(5) The cheese-like processed food according to any one of (1) to ( 4 ), wherein the shape is block, slice, sinome, strip, shred, or powder.

本発明の曳糸性チーズ様加工食品は、常温ではブロック状のものをサイノメ状、短冊状等への形状に自在にカットでき、シュレッド状への裁断や粉状への粉砕も可能となる等形状の加工適性に優れ、それらをオーブンやトースター等の調理器具内で加熱すると溶融して曳糸性を発現するといったチーズに類似した特有の物性を持つことに加えて、本発明の構成成分は、ほぼ無味無臭なため様々な呈味成分や香料を含有させることでチーズ風味にとどまらず、バター風味やチョコレート風味、マヨネーズ風味等任意の風味を付けることでき、使用できる調理食品の範囲が格段に広がる。しかも、本発明品は実質的に乳タンパク質や乳成分を含有していないので食物アレルギーを心配する人に配慮した加工食品であり、加える風味成分のアレルゲンに留意することで食物が原因となるアレルギーを引き起こさない加工食品とすることも可能となる。 The stringy cheese-like processed food of the present invention can freely cut a block-like food into a sinome shape, a strip shape, etc. at room temperature, and can be cut into a shred shape or pulverized into a powder shape, etc. In addition to having unique physical properties similar to cheese such as excellent shape processing suitability, melting them when they are heated in cooking utensils such as ovens and toasters, and exhibiting stringiness, the components of the present invention are Because it is almost tasteless and odorless, it can be added not only to cheese flavor but also to any flavor such as butter flavor, chocolate flavor, mayonnaise flavor by adding various flavoring ingredients and fragrances, and the range of cooked foods that can be used is marked spread. Moreover, since the product of the present invention is substantially free of milk protein and milk components, it is a processed food for those who are concerned about food allergies, and allergies caused by food by paying attention to the allergens of flavor components to be added It is also possible to make processed foods that do not cause odors.

本発明の曳糸性チーズ様加工食品は、乳タンパク質含量が0.1質量%以下であって、酸化デンプンとヒドロキシプロピルデンプン、上昇融点30℃以上の油脂及び水を含有し、酸化デンプン総量中のアミロース含量が0.1〜23質量%で、実質的に乳タンパク質を含有せずとも加熱時に曳糸性を有するチーズ様加工食品であり、酸化デンプンを含む水相部中に油脂が分散された構造を持つ食品である。 The spinnable cheese-like processed food of the present invention has a milk protein content of 0.1% by mass or less, and contains oxidized starch and hydroxypropyl starch, an oil and water having an ascending melting point of 30 ° C. or higher, and a total amount of oxidized starch. Is a cheese-like processed food that has a spinnability on heating without containing milk protein, and fats and oils are dispersed in the aqueous phase containing oxidized starch. It is a food with a special structure.

「実質的に」とは、タンパク質が含まれていないか、分析上、わずか痕跡程度である状態をいう。本発明においてはナチュラルチーズやプロセスチーズはもちろんのこと、脱脂粉乳やホエーパウダー等の乳タンパク質を含有する原料やあるいは大豆タンパク質や小麦タンパク質等の植物性タンパク質の使用を必要としない。 “Substantially” means a state in which a protein is not contained or is slightly traced in the analysis. In the present invention, not only natural cheese and processed cheese but also raw materials containing milk proteins such as skim milk powder and whey powder or vegetable proteins such as soybean protein and wheat protein are not required.

本発明の構成成分であるデンプンは、化学処理を施された加工デンプンに属するものである。その加工デンプンの1つである酸化デンプンはデンプンを次亜塩素酸ナトリウムで酸化処理して得られるものであり、その酸化処理の程度はカルボキシル基量で規定することができ、カルボキシル基量が多いほど酸化処理程度が進んだことを意味する。未処理のデンプンはカルボキシル基がほぼない。起源原料としては馬鈴薯由来、タピオカ由来、コーン由来、ワキシーコーン由来、サゴヤシ由来、米由来、エンドウ由来、甘藷由来のデンプンから選ばれた1種類以上の酸化デンプンを用いることができる。本発明にはいずれの起源のデンプンであってもよいが、良好な曳糸性と加熱溶融性、成形加工適性の物性を兼ね備えるためには、用いた酸化デンプン総量中のアミロース含量を0.1〜23質量%とし、馬鈴薯由来、タピオカ由来、ワキシーコーン由来の酸化デンプンを1種類以上用いることがより好ましい。ただし、乳以外にもアレルギー疾患を心配する人を対象とする場合は、対象となるアレルゲンを有する可能性のある植物由来の加工デンプンを選択しないことが必要である。具体的には小麦由来、米由来、エンドウ由来を用いないことである。 The starch that is a constituent of the present invention belongs to a modified starch that has been subjected to chemical treatment. Oxidized starch, which is one of the modified starches, is obtained by oxidizing starch with sodium hypochlorite. The degree of oxidation treatment can be defined by the amount of carboxyl groups, and the amount of carboxyl groups is large. This means that the degree of oxidation treatment has progressed. Untreated starch has almost no carboxyl groups. As the source material, one or more kinds of oxidized starch selected from potato-derived, tapioca-derived, corn-derived, waxy-corn-derived, sago palm-derived, rice-derived, pea-derived and sweet potato-derived starches can be used. The starch of any origin may be used in the present invention, but in order to combine good spinnability, heat meltability, and molding processability, the amylose content in the total amount of oxidized starch used is 0.1. It is more preferable to use at least 23 kinds of oxidized starch derived from potato, tapioca and waxy corn. However, when targeting people who are concerned about allergic diseases other than milk, it is necessary not to select plant-derived modified starch that may have the target allergen. Specifically, wheat origin, rice origin, and pea origin are not used.

本発明に用いるヒドロキシプロピルデンプンはデンプンを酸化プロピレンでエーテル化して得られ、デンプンのいくつかの水酸基がヒドロキシプロピル基でエーテル化されたものである。馬鈴薯由来、タピオカ由来、コーン由来、ワキシーコーン由来、小麦由来、サゴヤシ由来、米由来、エンドウ由来、甘藷由来を起源とするデンプンから選ばれた1種類以上のヒドロキシプロピルデンプンを用いることができる。本発明にはいずれの起源のデンプンであってもよいが、タピオカ由来がより好ましい。酸化デンプン同様、アレルギー疾患を心配する人を対象とする場合は、小麦由来、米由来、エンドウ由来を用いないことである。 Hydroxypropyl starch used in the present invention is obtained by etherifying starch with propylene oxide, and some hydroxyl groups of starch are etherified with hydroxypropyl groups. One or more kinds of hydroxypropyl starch selected from starches derived from potato, tapioca, corn, waxy corn, wheat, sago, rice, pea, and sweet potato can be used. In the present invention, starch of any origin may be used, but tapioca is more preferable. As with oxidized starch, when targeting people who are allergic to allergic diseases, do not use wheat, rice or peas.

本発明に用いる酸化デンプン及びヒドロキシプロピルデンプンの添加量は目的とする物性に応じて適宜調整することが可能であり、例えば酸化デンプン含量を5〜50質量%、10〜40質量%、15〜35質量%とすることができる。好ましい酸化デンプン含量は15〜30質量%であり、さらに好ましくは20〜30質量%である。また、ヒドロキシプロピルデンプン含量を1〜15質量%、1〜10質量%、2〜10質量%とすることができる。ヒドロキシプロピルデンプンの好ましい含量は2〜8質量%であり、さらに好ましくは3〜7質量%である。 The addition amount of oxidized starch and hydroxypropyl starch used in the present invention can be appropriately adjusted according to the intended physical properties. For example, the oxidized starch content is 5 to 50% by mass, 10 to 40% by mass, and 15 to 35. It can be made into the mass%. A preferable oxidized starch content is 15 to 30% by mass, and more preferably 20 to 30% by mass. Moreover, hydroxypropyl starch content can be made into 1-15 mass%, 1-10 mass%, and 2-10 mass%. The preferred content of hydroxypropyl starch is 2-8% by weight, more preferably 3-7% by weight.

本発明に用いる酸化デンプンとヒドロキシプロピルデンプンの総量は加工食品の総質量の10〜50質量%がよく、酸化デンプンに対してヒドロキシプロピルデンプンの含量を少なくし、酸化デンプンとヒドロキシプロピルデンプンの含有比を質量比として15:1〜2:1とするのがよい。好ましくは酸化デンプンとヒドロキシプロピルデンプンの総質量が本発明の加工食品中の20〜35質量%で、酸化デンプンとヒドロキシプロピルデンプンの含有比が質量比として10:1〜4:1である。 The total amount of oxidized starch and hydroxypropyl starch used in the present invention is preferably 10 to 50% by mass of the total mass of the processed food, the content of hydroxypropyl starch is reduced relative to oxidized starch, and the content ratio of oxidized starch and hydroxypropyl starch The mass ratio is preferably 15: 1 to 2: 1. Preferably, the total mass of oxidized starch and hydroxypropyl starch is 20 to 35% by mass in the processed food of the present invention, and the content ratio of oxidized starch and hydroxypropyl starch is 10: 1 to 4: 1 as a mass ratio.

酸化デンプンと名称が類似している酸処理デンプンは、デンプンを塩酸や硫酸等の酸性水溶液に浸漬し、糊化温度以下で半日ないし数日間放置した後、中和、水洗、ろ過、乾燥を行って製造される加工デンプンであり、酸化デンプンと同様に低粘度で冷却によりゲル化能が増大する性質を持っているが、タンパク質を含有せず酸処理デンプン主体で構成したチーズ様加工食品では、ピザ用ナチュラルチーズのように良好な曳糸性や加熱溶融性等の物性を兼ね備えることは困難である。 Acid-treated starch, whose name is similar to oxidized starch, is soaked in an acidic aqueous solution such as hydrochloric acid or sulfuric acid, left for half a day or several days below the gelatinization temperature, and then neutralized, washed with water, filtered, and dried. As with oxidized starch, it has the properties of low viscosity and increased gelling ability upon cooling, but it does not contain protein, and it is processed with cheese-like processed food consisting mainly of acid-treated starch. It is difficult to combine physical properties such as good spinnability and heat meltability like natural cheese for pizza.

本発明に用いる油脂は食用に使用される油脂であり、上昇融点が30℃以上のものであれば特に制限はなく、パーム油、カカオ脂等の植物油脂や大豆硬化油、なたね硬化油等の植物硬化油、豚脂、牛脂等の動物油脂またはこれらの硬化油、魚油等水産動物油脂の硬化油等が例示でき、これら油脂の分別油やエステル交換油であってもよい。また、これらの油脂から選ばれた2種以上の油脂の混合油脂、さらにその分別油やエステル交換油であってもよい。より好ましい曳糸性チーズ様加工食品の物性のためには上昇融点が30℃以上で10℃のSFCが50〜95%、20℃のSFCが40〜85%である油脂とするのがよい。また、油脂添加量として本発明の加工食品に対して10〜40質量%がよく、好ましくは15〜35質量%、より好ましくは20〜30質量%である。 The fats and oils used in the present invention are edible fats and oils and are not particularly limited as long as the rising melting point is 30 ° C. or higher, such as vegetable oils such as palm oil and cocoa butter, hydrogenated soybean oil, rapeseed oil Examples of these oils include vegetable oils such as vegetable oils, pork fats, beef tallow, and the like, and oils such as these hardened oils, fish oils and other marine animal oils, and the like. Moreover, the mixed fats and oils of 2 or more types of fats selected from these fats and oils, the fractionated oil, and transesterified oil may be sufficient. For a more preferable physical property of a spiny cheese-like processed food, it is preferable to use an oil and fat having an elevated melting point of 30 ° C. or higher, an SFC of 10 ° C. of 50 to 95%, and an SFC of 20 ° C. of 40 to 85%. Moreover, 10-40 mass% is good with respect to the processed food of this invention as fat and oil addition amount, Preferably it is 15-35 mass%, More preferably, it is 20-30 mass%.

本発明の曳糸性チーズ様加工食品の含有する水分量は、含有させる水溶性成分を溶解することができる量であればよく、目的とする加工食品の物性に応じて適宜調整すればよい。水溶性成分の一部が不溶となれば曳糸性効果が十分に発揮できず、またザラついた食感となり好ましくない。含有する水分量が多すぎると流動物となってしまい、切断、裁断等の加工ができず、加熱時の曳糸性が非常に弱いものとなる。水分量は酸化デンプンとヒドロキシプロピルデンプンを合わせた質量の1.4〜1.8倍とすることが好ましく、その他に水溶性成分を含有させる場合にはそのものらを溶解できる水分量を余分に加えるとよい。 The amount of water contained in the spinnable cheese-like processed food of the present invention may be an amount that can dissolve the water-soluble component to be contained, and may be appropriately adjusted according to the physical properties of the intended processed food. If a part of the water-soluble component is insoluble, the spinnability effect cannot be sufficiently exhibited, and a rough texture is not preferable. If the amount of water contained is too large, it becomes a fluid, and processing such as cutting and cutting cannot be performed, and the spinnability during heating becomes very weak. The amount of water is preferably 1.4 to 1.8 times the total mass of oxidized starch and hydroxypropyl starch. In addition, when water-soluble components are contained, an extra amount of water that can dissolve them is added. Good.

本発明の曳糸性チーズ様加工食品には発明の効果に影響を与えない範囲内において、呈味成分や風味成分を加えることができる。例えば、塩や砂糖等の糖類や甘味料及び化学調味料、ココアパウダーやコーヒーパウダー、イチゴやマスカット等の各種果汁、チーズ香料やバター香料等の各種香料等が挙げられる。このような呈味成分や風味成分を加えることでチーズ様の食感や加熱時の曳糸性を持ちつつ、チーズ風味はもちろんのこと多岐にわたる風味を付与した加工食品とすることができる。また、着色料や日持ち向上剤も使用することができる。アレルギーに配慮した加工食品とするには、アレルゲンを含有しない原料を選択すればよい。 A taste ingredient and a flavor component can be added to the spinnable cheese-like processed food of the present invention within a range that does not affect the effects of the invention. Examples include sugars such as salt and sugar, sweeteners and chemical seasonings, cocoa powder and coffee powder, various fruit juices such as strawberry and muscat, and various flavors such as cheese flavor and butter flavor. By adding such a taste component and a flavor component, it can be set as the processed food which gave the cheese-like texture and the spine property at the time of a heating, and gave the flavor various as well as cheese flavor. Coloring agents and shelf life improvers can also be used. In order to make processed food in consideration of allergies, raw materials not containing allergens may be selected.

さらに、本発明の加工食品の物性に変化を加えるために増粘安定剤を使用してもよく、例えばグアーガム、キサンタンガム、アラビアガム、カラギナン、ローカストビーンガム、タマリンドシードガム、タラガム、デキストリン、ペクチン、寒天、セルロース、CMC、食物繊維、ポリアクリル酸ナトリウム等が挙げられる。また、本発明の加工食品中の油脂の分散を良くするために乳化剤を使用することも可能である。例えば、レシチンやグリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、プロピレングリコール脂肪酸エステル、ソルビタン脂肪酸エステル、酢酸モノグリセリド、酒石酸モノグリセリド、コハク酸モノグリセリド、クエン酸モノグリセリド、ジアセチル酒石酸モノグリセリド、乳酸モノグリセリド、ポリオキシエチレンソルビタン脂肪酸エステル等が挙げられる。いずれも発明の効果に影響をきたさない範囲内で使用ができる。 Further, a thickening stabilizer may be used to change the physical properties of the processed food of the present invention, such as guar gum, xanthan gum, gum arabic, carrageenan, locust bean gum, tamarind seed gum, tara gum, dextrin, pectin, Agar, cellulose, CMC, dietary fiber, sodium polyacrylate and the like can be mentioned. An emulsifier can also be used to improve the dispersion of fats and oils in the processed food of the present invention. For example, lecithin, glycerin fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, propylene glycol fatty acid ester, sorbitan fatty acid ester, acetic acid monoglyceride, tartaric acid monoglyceride, succinic acid monoglyceride, citric acid monoglyceride, diacetyltartaric acid monoglyceride, lactic acid monoglyceride, polyoxy And ethylene sorbitan fatty acid esters. Any of them can be used within a range that does not affect the effect of the invention.

本発明のチーズ様加工食品の製造としては、酸化デンプン、ヒドロキシプロピルデンプン、水を主原料として、必要に応じて食塩、風味成分、酸味料、乳化剤、日持ち向上剤等の副原料を混合溶解した水相部に油脂を添加し、混合乳化させる。乳化の温度は乳化の効率と殺菌の効果が発揮できることから80℃以上、望ましくは85〜95℃で混合物の粘度を下げた状態で行うのがよい。 For the production of the cheese-like processed food of the present invention, oxidized starch, hydroxypropyl starch, water as the main raw materials, and auxiliary ingredients such as salt, flavor components, acidulants, emulsifiers, shelf life improvers were mixed and dissolved as necessary. Add oils and fats to the water phase and mix and emulsify. The emulsification temperature is 80 ° C. or higher, preferably 85 to 95 ° C., since the emulsification efficiency and sterilization effect can be exhibited.

混合物の乳化機としては、ステファン型乳化機、表面掻取型乳化機、ケトル型乳化機またはスパイラル型乳化機等、通常のプロセスチーズの乳化に用いられる乳化機を使用することができる。また、乳化混合物の粘度が低い場合にはホモミキサーやプロペラミキサーを具備した混合乳化タンクであってもよい。加熱や温度の保持のためにジャケットタイプがよく、この時に直接蒸気の通気が可能な加圧耐用容器であれば短時間で加熱が行えるためより望ましい。乳化物の冷却方法としては、そのまま容器に移し替えて冷蔵庫等で保管することや容器をクーリングトンネルに通して連続式に行う方法が挙げられ、パーフェクターやオンレーター等の掻取式連続熱交換装置での冷却であってもよい。 As the emulsifier for the mixture, there can be used an emulsifier used for emulsification of ordinary process cheese, such as a stefan emulsifier, a surface scraping emulsifier, a kettle emulsifier or a spiral emulsifier. Further, when the viscosity of the emulsified mixture is low, it may be a mixed emulsification tank equipped with a homomixer or a propeller mixer. A jacket type is good for heating and maintaining temperature, and a pressurized container capable of direct vapor flow at this time is more desirable because it can be heated in a short time. Examples of the cooling method of the emulsion include a method of transferring it to a container as it is and storing it in a refrigerator or the like, and a method in which the container is continuously passed through a cooling tunnel. It may be cooling in the apparatus.

(パーム核極度硬化油の調製)
1リットルのオートクレーブにパーム核油(ヨウ素価18.0)100質量部、ニッケル触媒(堺化学工業株式会社製 SO−750R)0.3質量部を添加し、水素圧0.2MPa、回転数750rpmで攪拌しながら、180℃で水素添加反応を行い、油脂のヨウ素価が0.5に低下するまで反応を続けた。その後、活性白土を対油0.3質量部添加して脱色、脱臭をして表1に示す分析値を有する油脂1を得た。
(Preparation of palm kernel extremely hardened oil)
100 parts by mass of palm kernel oil (iodine value 18.0) and 0.3 parts by mass of nickel catalyst (SO-750R manufactured by Sakai Chemical Industry Co., Ltd.) are added to a 1 liter autoclave, hydrogen pressure 0.2 MPa, rotation speed 750 rpm. While stirring, the hydrogenation reaction was performed at 180 ° C., and the reaction was continued until the iodine value of the fat decreased to 0.5. Then, 0.3 parts by weight of activated clay was added to the oil to decolorize and deodorize to obtain an oil 1 having the analytical values shown in Table 1.

(エステル交換油の調製)
パーム核極度硬化油60質量部とパームオレイン40質量部を混合した油脂に、0.2質量部のナトリウムメトキシドを加え、80℃で60分混合攪拌してランダムエステル交換反応を行い、反応後、水洗して触媒を除去した。次に脱色、脱臭して表1に示す分析値を有する油脂2を得た。
(Preparation of transesterified oil)
After adding 0.2 parts by mass of sodium methoxide to the oil and fat in which 60 parts by mass of palm kernel extremely hardened oil and 40 parts by mass of palm olein are mixed, the mixture is stirred at 80 ° C. for 60 minutes to conduct a random transesterification reaction. The catalyst was removed by washing with water. Next, decolorization and deodorization were performed to obtain an oil 2 having the analytical values shown in Table 1.

(その他油脂)
その他油脂として、パーム油(ヨウ素価51.2、油脂3)、パームステアリン(ヨウ素価31.5、油脂4)、大豆油(ヨウ素価130.8、油脂5)、パームオレイン(ヨウ素価57.5、油脂6)、パーム核極度硬化油70質量部とパームオレイン30質量部を混合した油脂(ヨウ素価17.6、油脂7)、バターから抽出したバターオイル(ヨウ素価31.7、油脂8)を用いて実施例、比較例を行った。実施例、比較例に使用した油脂1〜8の詳細な情報は表1に示した。
(Other oils and fats)
Other oils and fats include palm oil (iodine value 51.2, oil 3), palm stearin (iodine value 31.5, oil 4), soybean oil (iodine value 130.8, oil 5), and palm olein (iodine value 57. 5, fats and oils 6), fats and oils (iodine value 17.6, fats and oils 7) mixed with 70 parts by weight of palm kernel extremely hardened oil and 30 parts by weight of palm olein, butter oil extracted from butter (iodine value 31.7, fats and oils 8) ) Were used to carry out examples and comparative examples. Detailed information of the fats and oils 1 to 8 used in Examples and Comparative Examples is shown in Table 1.

実施例、比較例に使用した酸化デンプン及びヒドロキシプロピルデンプン、酸処理デンプン、ヒドロキシプロピルリン酸架橋デンプン、未加工デンプンの由来原料は以下の通りである。酸化デンプン1:馬鈴薯、酸化デンプン2:サゴヤシ、酸化デンプン3:ワキシーコーン、酸化デンプン4:タピオカ、酸化デンプン5:コーン、ヒドロキシプロピルデンプン1:タピオカ、ヒドロキシプロピルデンプン2:馬鈴薯、酸処理デンプン:サゴヤシ、ヒドロキシプロピリン酸架橋デンプン:コーン、未加工デンプン:サゴヤシ。
本発明に使用した酸化デンプンのアミロース含量及びカルボキシル基量は由来原料ごとに分類して表2に示し、表3〜表5に示した酸化デンプンの中のアミロース含量は表2の値をもとに算出した。
The raw materials derived from oxidized starch and hydroxypropyl starch, acid-treated starch, hydroxypropyl phosphate cross-linked starch and raw starch used in Examples and Comparative Examples are as follows. Oxidized starch 1: potato, oxidized starch 2: sago palm, oxidized starch 3: waxy corn, oxidized starch 4: tapioca, oxidized starch 5: corn, hydroxypropyl starch 1: tapioca, hydroxypropyl starch 2: potato, acid-treated starch: sago palm Hydroxypropyric acid crosslinked starch: corn, raw starch: sago.
The amylose content and carboxyl group content of the oxidized starch used in the present invention are shown in Table 2 classified according to the starting material, and the amylose content in the oxidized starch shown in Tables 3 to 5 is based on the values in Table 2. Was calculated.

以下に実施例を挙げ、本発明をさらに詳しく説明するが、本発明は、これらに限定されるものではない。尚、本発明の実施例における評価方法は下記の通りである。上昇融点については、基準油脂分析試験法2.2.4.2−1996にて、SFCについては、基準油脂分析試験法2.2.9−2013固体脂含量(NMR法)にて分析を行った。 EXAMPLES The present invention will be described in more detail with reference to examples below, but the present invention is not limited to these examples. In addition, the evaluation method in the Example of this invention is as follows. The rising melting point is analyzed by the standard fat analysis method 2.2.4.2-1996, and the SFC is analyzed by the standard fat analysis test method 2.2.9-2013 solid fat content (NMR method). It was.

Figure 0006190556
Figure 0006190556

Figure 0006190556
Figure 0006190556

曳糸性チーズ様加工食品の品質評価
(曳糸性)
曳糸性の評価方法は、シュレッド状(縦35mm×横5mm×厚さ2mm)に成形した曳糸性チーズ様加工食品10g分をアルミ箔の上に乗せ、100V、810Wのオーブンで3分間加熱した後、測定装置として、株式会社山電製「クリープメータ レオナー(RE−3305S)」、測定プランジャーとして、同社規定の円盤型プランジャーNo.37(直径11.3mm、厚さ1mm)を使用して下記の条件で測定した。
円盤型プランジャーの先端が曳糸性チーズ様加工食品と接触するようにセットし、曳糸性チーズ様加工食品を10mm/secのテーブルスピードで下方向に移動させ、プランジャーの先端から曳糸性チーズ様加工食品が剥離した時点で移動を停止した。アルミ箔上の曳糸性チーズ様加工食品の表面とプランジャーの先端との距離を測定し、3回測定した平均を曳糸性の長さとした。プランジャーから剥離せずに装置の測定限界(77mm)に達した場合は77mm以上とした。なお曳糸性評価判定は下記に示す基準とした。
◎:60mm以上 ○:20mm以上60mm未満 ×:20mm未満
(加熱溶融性)
加熱溶融性の評価方法は以下の条件で評価した。シュレッド状(縦35mm×横5mm×厚さ2mm)に成形した曳糸性チーズ様加工食品10g分をアルミ箔の上に乗せ、100V、810Wのオーブンで加熱し、溶融性が良好なものから以下の基準にて3段階で評価した。
◎:3〜5分で溶融し、かつ程よい流動性が見られる
○:3〜5分で溶融するが、流動性は見られない
×:5分経過して加熱してもほとんど溶融しない
(成形加工適性)
成形加工適性は以下の2つの方法によって評価した。
(1) カット適性
5℃で3日間冷蔵保管した曳糸性チーズ様加工食品を室温下、ナイフで切断した時の切り易さについて以下の基準で評価した。
◎:曳糸性チーズ様加工食品がナイフに付着することなく切れ、ナイフがほとんど汚れない
○:曳糸性チーズ様加工食品がナイフに付着するが、ナイフとチーズ様食品は容易に分離する
×:曳糸性チーズ様加工食品がナイフに付着し、ナイフとチーズ様食品が容易に分離しない
(2) 硬度
直径50mm、深さ25mmのカップに曳糸性チーズ様加工食品を30g入れ、5℃で3日間冷蔵保管した。株式会社山電製「クリープメータ レオナー(RE−3305S)」に該サンプルをセットし、プランジャーNo.5(5mm×22mm)、試料台速度を5mm/secに設定し、プランジャーを挿入した時の応力(gf)を読みとった。硬度は以下の基準で評価した。
◎:1000gf以上
○:500gf以上1000gf未満
×:500gf未満
(30℃での油脂の分離)
シュレッド状(縦35mm×横5mm×厚さ2mm)に成形した曳糸性チーズ様加工食品5g分を30℃に静置させ、以下の基準で評価した。
〇:4時間経過しても曳糸性チーズ様加工食品の表面に油滴(=オイルオフ)が見られない
×:1時間以上4時間未満で曳糸性チーズ様加工食品の表面に油滴が見られる
(食感の評価)
ダイス状(縦20mm×横20mm×厚さ20mm)に成形した20℃の曳糸性チーズ様加工食品を食べた時の感触を、以下の基準で評価した。
○:チーズ特有の弾力感、粘りを感じる
×:チーズ特有の弾力感、粘りを感じない
Quality evaluation of processed foods like spinnable cheese
The evaluation method of spinnability is to place 10g of spine-type cheese-like processed food shaped into a shred (length 35mm x width 5mm x thickness 2mm) on aluminum foil and heat in an oven at 100V, 810W for 3 minutes. After that, Yamaden Co., Ltd. “Creep Meter Leonor (RE-3305S)” was used as the measuring device, and the company's disc-shaped plunger No. 37 (diameter 11.3 mm, thickness 1 mm) was used as the measuring plunger. And measured under the following conditions.
Set so that the tip of the disc-shaped plunger is in contact with the processed cheese-like processed food, and move the processed cheese-like processed food downward at a table speed of 10 mm / sec. The movement was stopped when the processed cheese-like processed food peeled. The distance between the surface of the spinnable cheese-like processed food on the aluminum foil and the tip of the plunger was measured, and the average of three measurements was taken as the spinnable length. When the measurement limit (77 mm) of the apparatus was reached without peeling from the plunger, it was set to 77 mm or more. In addition, the evaluation as shown below was used for the evaluation of spinnability.
◎: 60 mm or more ○: 20 mm or more and less than 60 mm ×: less than 20 mm (heat melting property)
The evaluation method for heat melting property was evaluated under the following conditions. 10g of spiny cheese-like processed food molded into a shred shape (length 35mm x width 5mm x thickness 2mm) is placed on an aluminum foil and heated in an oven of 100V, 810W. The evaluation was made in three stages according to the criteria.
A: Melted in 3 to 5 minutes and moderate fluidity is observed. ○: Melted in 3 to 5 minutes, but no fluidity is observed. X: Almost no melting even when heated after 5 minutes (molding) Processing suitability)
The moldability was evaluated by the following two methods.
(1) Cutting suitability The ease with which a spinnable cheese-like processed food that had been refrigerated at 5 ° C. for 3 days was cut at room temperature with a knife was evaluated according to the following criteria.
◎: Spun cheese-like processed food is cut without sticking to the knife, and the knife is hardly soiled ○: Spun cheese-like processed food is attached to the knife, but the knife and cheese-like processed food are easily separated × : Spinnable cheese-like processed food adheres to the knife, and the knife and cheese-like food do not easily separate (2) 30 g of the spinnable cheese-like processed food is put in a cup having a hardness diameter of 50 mm and a depth of 25 mm, and 5 ° C. And refrigerated for 3 days. When the sample is set in “Creep Meter Leonor (RE-3305S)” manufactured by Yamaden Co., Ltd., plunger No. 5 (5 mm × 22 mm), sample stage speed is set to 5 mm / sec, and the plunger is inserted The stress (gf) was read. Hardness was evaluated according to the following criteria.
A: 1000 gf or more
○: 500 gf or more and less than 1000 gf
X: Less than 500 gf (separation of fats and oils at 30 ° C.)
A portion of 5 g of spine cheese-like processed food molded into a shred shape (length 35 mm × width 5 mm × thickness 2 mm) was allowed to stand at 30 ° C. and evaluated according to the following criteria.
○: No oil drop (= oil off) is observed on the surface of the spiny cheese-like processed food even after 4 hours. X: Oil drop on the surface of the spinnable cheese-like processed food in 1 hour or more and less than 4 hours Can be seen (Evaluation of texture)
The feeling when eating a 20 ° C. spinnable cheese-like processed food molded into a die shape (vertical 20 mm × horizontal 20 mm × thickness 20 mm) was evaluated according to the following criteria.
○: Cheese-specific elasticity and stickiness x: Cheese-specific elasticity, stickiness not felt

(実施例1)ヒドロキシプロピルデンプン:タピオカ
水相部として食塩を1.5質量部、水を45.5質量部添加して昇温し、50℃に達した後、酸化デンプン1(アミロース含量:21質量%、カルボキシル基量:1.1質量%)を26.0質量部、ヒドロキシプロピルデンプン1を5.0質量部添加し、プロペラミキサー(1,300rpm)で混合攪拌して溶解させた。デンプンがしっかり膨潤糊化した後、油脂1を22.0質量部添加し乳化させ85℃まで混合攪拌した。85℃に到達後、そのままの回転数で1分間攪拌保持した。加熱乳化したチーズ様乳化物を容器に充填し、5℃の冷蔵庫で3日間冷却して曳糸性チーズ様加工食品を得た。このものについて曳糸性や加熱溶融性、成形加工適性等を評価した。
該曳糸性チーズ様加工食品のタンパク質含量は0.0質量%、酸化デンプンの中のアミロース含量は21.0質量%、酸化デンプン/ヒドロキシプロピルデンプン比は5.2、5℃における硬度は1,800gfであり、曳糸性及び810W、3分間加熱した際の加熱溶融性、成形加工適性とも良好な物性であった。品質評価結果は表3に示した。
(Example 1) Hydroxypropyl starch: 1.5 parts by mass of sodium chloride and 45.5 parts by mass of water as tapioca aqueous phase were added and heated to 50 ° C., and then oxidized starch 1 (amylose content: 21 mass%, carboxyl group amount: 1.1 mass%) was added to 26.0 mass parts and hydroxypropyl starch 1 was added 5.0 mass parts, and the mixture was mixed and stirred with a propeller mixer (1,300 rpm) to dissolve. After the starch was firmly swollen and gelatinized, 22.0 parts by weight of fat 1 was added, emulsified, and mixed and stirred to 85 ° C. After reaching 85 ° C., the mixture was stirred and held at the same rotational speed for 1 minute. The heat-emulsified cheese-like emulsion was filled into a container and cooled in a refrigerator at 5 ° C. for 3 days to obtain a spinnable cheese-like processed food. This was evaluated for spinnability, heat meltability, moldability and the like.
The silky cheese-like processed food has a protein content of 0.0% by mass, an amylose content in oxidized starch of 21.0% by mass, an oxidized starch / hydroxypropyl starch ratio of 5.2, and a hardness at 5 ° C. of 1 800gf, good physical properties in terms of spinnability, 810W, heat melting property when heated for 3 minutes, and molding processability. The quality evaluation results are shown in Table 3.

(実施例2) ヒドロキシプロピルデンプン:馬鈴薯
表3に示した配合により、実施例1と同様の手順で曳糸性チーズ様加工食品を製造した。実施例1と同様の評価を行ったところ、曳糸性及び加熱溶融性、成形加工適性とも良好な物性であった。品質評価結果は表3に示した。
(Example 2) Hydroxypropyl starch: Potato A spiny cheese-like processed food was produced by the same procedure as in Example 1 with the formulation shown in Table 3. When the same evaluation as in Example 1 was performed, the physical properties were good in terms of stringiness, heat melting property, and molding processability. The quality evaluation results are shown in Table 3.

(実施例3〜10) 酸化デンプンの組み合わせ
表3に示した配合により、実施例1〜2において酸化デンプンの由来や、酸化デンプンの組み合わせを変えた以外は同様の手順で製造し、曳糸性チーズ様加工食品を得た。品質評価結果は表3に示した。
(Examples 3 to 10) Combinations of oxidized starches According to the formulation shown in Table 3, the production of the oxidized starches in Examples 1 and 2 and the combinations of oxidized starches were changed in the same procedure, and the spinnability A cheese-like processed food was obtained. The quality evaluation results are shown in Table 3.

(実施例11) 酸化デンプン/ヒドロキシプロピルデンプン比:3.1
水相部として食塩を2.5質量部、クエン酸を0.15質量部、アミノ酸を0.2質量部、酵母エキスを0.15質量部、水を46.8質量部添加して昇温し、50℃に達した後、酸化デンプン1(アミロース含量:21質量%、カルボキシル基量:1.1質量%)を22.0質量部、ヒドロキシプロピルデンプン1を7.0質量部添加し、プロペラミキサー(1,300rpm)で混合攪拌して溶解させた。デンプンがしっかり膨潤糊化した後、油脂2を21.0質量部添加し、乳化させ85℃まで混合攪拌した。85℃に到達後、チーズ香料を0.2質量部添加してそのままの回転数で1分間攪拌保持した。加熱乳化したチーズ様乳化物を容器に充填し、5℃の冷蔵庫で3日間冷却して曳糸性チーズ様加工食品を得た。品質評価結果は表4に示した。
Example 11 Oxidized starch / hydroxypropyl starch ratio: 3.1
As an aqueous phase, 2.5 parts by mass of sodium chloride, 0.15 parts by mass of citric acid, 0.2 parts by mass of amino acids, 0.15 parts by mass of yeast extract, and 46.8 parts by mass of water were added to raise the temperature. Then, after reaching 50 ° C., 22.0 parts by mass of oxidized starch 1 (amylose content: 21% by mass, carboxyl group content: 1.1% by mass) and 7.0 parts by mass of hydroxypropyl starch 1 were added, The mixture was stirred and dissolved with a propeller mixer (1,300 rpm). After the starch was firmly swollen and gelatinized, 21.0 parts by weight of fat 2 was added, emulsified and mixed and stirred to 85 ° C. After reaching 85 ° C., 0.2 part by mass of cheese flavor was added and stirred and held for 1 minute at the same rotation speed. The heat-emulsified cheese-like emulsion was filled into a container and cooled in a refrigerator at 5 ° C. for 3 days to obtain a spinnable cheese-like processed food. The quality evaluation results are shown in Table 4.

(実施例12) 酸化デンプン/ヒドロキシプロピルデンプン比:13.0
表4に示した配合により、実施例11と同様の手順で曳糸性チーズ様加工食品を製造した。品質評価結果は表4に示した。
Example 12 Oxidized starch / hydroxypropyl starch ratio: 13.0
With the formulation shown in Table 4, a spinnable cheese-like processed food was produced in the same procedure as in Example 11. The quality evaluation results are shown in Table 4.

(実施例13〜16)他の油脂の使用:パーム油、パームステアリン、配合油脂、バターオイル
表4に示した配合により、実施例11と同様の手順で曳糸性チーズ様加工食品を製造した。品質評価結果は表4に示した。
(Examples 13 to 16) Use of other fats and oils: Palm oil, palm stearin, blended fats and oils, butter oil According to the blending shown in Table 4, a spinnable cheese-like processed food was produced in the same procedure as in Example 11. . The quality evaluation results are shown in Table 4.

(実施例17)乳以外のタンパク質使用:大豆タンパク質
表4に示した配合により、実施例11と同様の手順で曳糸性チーズ様加工食品を製造した。品質評価結果は表4に示した。
(Example 17) Use of proteins other than milk: Soy protein A spiny cheese-like processed food was produced by the same procedure as in Example 11 with the formulation shown in Table 4. The quality evaluation results are shown in Table 4.

(実施例18)増粘剤使用:アラビアガム
表4に示した配合により、実施例11と同様の手順で曳糸性チーズ様加工食品を製造した。品質評価結果は表4に示した。
(Example 18) Use of thickener: Arabic gum According to the formulation shown in Table 4, a spinnable cheese-like processed food was produced in the same procedure as in Example 11. The quality evaluation results are shown in Table 4.

(実施例19)チーズ風味以外の加工食品:チョコレート風味
水相部として砂糖を6.0質量部、水を44.3質量部添加して昇温し、50℃に達した後、酸化デンプン1(アミロース含量:21質量%、カルボキシル基量:1.1質量%)を19.0質量部、酸化デンプン2(アミロース含量:25質量%、カルボキシル基量:0.4質量%)を4.0%、ヒドロキシプロピルデンプン1を4.0質量部添加し、プロペラミキサー(1,300rpm)で混合攪拌して溶解させた。デンプンがしっかり膨潤糊化した後、ココアパウダーを10.0質量部添加し、デンプンとよく馴染むように混合攪拌した。そこに油脂1を12.5質量部添加し、乳化させ85℃まで混合攪拌した。85℃に到達後、チョコレート香料を0.2質量部添加してそのままの回転数で1分間攪拌保持した。加熱乳化したチョコレート様乳化物を容器に充填し、5℃の冷蔵庫で3日間冷却して曳糸性チョコレート様加工食品を得た。品質評価結果は表4に示した。
(Example 19) Processed foods other than cheese flavor: 6.0 parts by weight of sugar and 44.3 parts by weight of water were added as a chocolate-flavored water phase, and the temperature was raised to 50 ° C. (Amulose content: 21% by mass, carboxyl group content: 1.1% by mass) 19.0 parts by mass, oxidized starch 2 (amylose content: 25% by mass, carboxyl group content: 0.4% by mass) 4.0 %, Hydroxypropyl starch 1 was added in an amount of 4.0 parts by mass, and dissolved by mixing and stirring with a propeller mixer (1,300 rpm). After the starch was firmly swollen and gelatinized, 10.0 parts by mass of cocoa powder was added and mixed and stirred so as to be well blended with the starch. 12.5 mass parts of fats and oils 1 were added there, it was made to emulsify, and it mixed and stirred to 85 degreeC. After reaching 85 ° C., 0.2 part by mass of chocolate flavor was added, and the mixture was stirred and held for 1 minute at the same rotational speed. A chocolate-like emulsion emulsified by heating was filled into a container and cooled in a refrigerator at 5 ° C. for 3 days to obtain a stringy chocolate-like processed food. The quality evaluation results are shown in Table 4.

(実施例20)乳化剤使用:ポリグリセリン脂肪酸エステル
表4に示した配合により、実施例11と同様の手順でチーズ様加工食品を製造した。品質評価結果は表4に示した。
(Example 20) Use of emulsifier: Polyglycerin fatty acid ester A cheese-like processed food was produced in the same procedure as in Example 11 by the formulation shown in Table 4. The quality evaluation results are shown in Table 4.

Figure 0006190556
Figure 0006190556

Figure 0006190556
Figure 0006190556

(比較例1)酸化デンプン以外のデンプン:酸処理デンプン
水相部として食塩を1.5質量部、水を45.5質量部添加して昇温し、50℃に達した後、酸処理デンプンを26.0質量部、ヒドロキシプロピルデンプン1を5.0質量部添加し、プロペラミキサー(1,300rpm)で混合攪拌して溶解させた。デンプンがしっかり膨潤糊化した後、油脂1を22.0質量部添加し乳化させ85℃まで混合攪拌した。85℃に到達後、そのままの回転数で1分間攪拌保持した。加熱乳化したチーズ様乳化物を容器に充填し、5℃の冷蔵庫で3日間冷却して曳糸性チーズ様加工食品を得た。品質評価結果は表5に示した。
(Comparative Example 1) Starch other than oxidized starch: 1.5 parts by mass of sodium chloride and 45.5 parts by mass of water as an acid-treated starch aqueous phase, and the temperature was raised to 50 ° C. 26.0 parts by mass and 5.0 parts by mass of hydroxypropyl starch 1 were mixed and stirred with a propeller mixer (1,300 rpm) to dissolve. After the starch was firmly swollen and gelatinized, 22.0 parts by mass of fat 1 was added, emulsified, and mixed and stirred to 85 ° C. After reaching 85 ° C., the mixture was stirred and held at the same rotational speed for 1 minute. The heat-emulsified cheese-like emulsion was filled into a container and cooled in a refrigerator at 5 ° C. for 3 days to obtain a spinnable cheese-like processed food. The quality evaluation results are shown in Table 5.

(比較例2)酸化デンプン以外のデンプン:ヒドロキシプロピルリン酸架橋デンプン
表5に示した配合により、酸処理デンプンをヒドロキシプロピルリン酸架橋デンプンに代えた以外は比較例1と同様の手順で曳糸性チーズ様加工食品を製造しようとしたが、水相部が高粘度となり、油相部と乳化せずチーズ様加工食品は得られなかった。品質評価結果は表5に示した。
(Comparative Example 2) Starch other than oxidized starch: hydroxypropyl phosphate crosslinked starch According to the formulation shown in Table 5, the acid-treated starch was replaced with hydroxypropyl phosphate crosslinked starch in the same procedure as in Comparative Example 1 An attempt was made to produce a processed cheese-like processed food, but the water phase portion became highly viscous, and the oil phase portion was not emulsified, and a cheese-like processed food was not obtained. The quality evaluation results are shown in Table 5.

(比較例3)酸化デンプン以外のデンプン:酸化デンプン+未加工デンプン
表5に示した配合により、比較例1と同様の手順で曳糸性チーズ様加工食品を製造した。品質評価結果は表5に示した。
(Comparative Example 3) Starch other than oxidized starch: oxidized starch + unprocessed starch A spiny cheese-like processed food was produced by the same procedure as in Comparative Example 1 with the formulation shown in Table 5. The quality evaluation results are shown in Table 5.

(比較例4)アミロース含量:23.0質量%以上
表5に示した配合により、比較例1と同様の手順で曳糸性チーズ様加工食品を製造した。品質評価結果は表5に示した。
(Comparative Example 4) Amylose content: 23.0% by mass or more By the combination shown in Table 5, a spinnable cheese-like processed food was produced in the same procedure as in Comparative Example 1. The quality evaluation results are shown in Table 5.

(比較例5〜6)油脂の変更:大豆油、パームオレイン
表5に示した配合により、比較例1と同様の手順で曳糸性チーズ様加工食品を製造した。品質評価結果は表5に示した。
(Comparative examples 5-6) Change of fats and oils: Soybean oil, palm olein By the mixing | blending shown in Table 5, the spinnable cheese-like processed food was manufactured in the same procedure as the comparative example 1. The quality evaluation results are shown in Table 5.

(比較例7)酸化デンプン/ヒドロキシプロピルデンプン含有比:下限以下(1.0)
表5に示した配合により、比較例1と同様の手順で曳糸性チーズ様加工食品を製造した。品質評価結果は表5に示した。
(Comparative Example 7) Oxidized starch / hydroxypropyl starch content ratio: below the lower limit (1.0)
With the formulation shown in Table 5, a spinnable cheese-like processed food was produced in the same procedure as in Comparative Example 1. The quality evaluation results are shown in Table 5.

(比較例8)酸化デンプン/ヒドロキシプロピルデンプン含有比:上限以上(26.0)
表5に示した配合により、比較例1と同様の手順で曳糸性チーズ様加工食品を製造した。品質評価結果は表5に示した。
(Comparative Example 8) Oxidized starch / hydroxypropyl starch content ratio: above the upper limit (26.0)
With the formulation shown in Table 5, a spinnable cheese-like processed food was produced in the same procedure as in Comparative Example 1. The quality evaluation results are shown in Table 5.

Figure 0006190556
Figure 0006190556

Claims (5)

由来タンパク質含量が0.1質量%以下であって、酸化デンプンを15〜30質量%、ヒドロキシプロピルデンプンを2〜8質量%含みそれらの総量は加工食品の総質量の20〜35質量%であり、酸化デンプンとヒドロキシプロピルデンプンの含有比が15:1〜2:1であり、上昇融点30℃以上の油脂を10〜40質量%、及び水を含有し、酸化デンプン総量中のアミロース含量が0.1〜23質量%で、実質的に乳由来タンパク質を含有せずとも加熱時に曳糸性を有するチーズ様加工食品。 Milk- derived protein content is 0.1% by mass or less, containing 15-30% by mass of oxidized starch and 2-8% by mass of hydroxypropyl starch, the total amount of which is 20-35% by mass of the total mass of processed food The content ratio of oxidized starch and hydroxypropyl starch is 15: 1 to 2: 1, containing 10 to 40% by mass of fats and oils having an elevated melting point of 30 ° C. or higher , and water , and the amylose content in the total amount of oxidized starch Is a cheese-like processed food that has a spinnability when heated even if it contains 0.1 to 23% by mass and does not substantially contain milk- derived protein. タンパク質含量が0.1%以下で実質的にタンパク質を含有しない請求項1に記載のチーズ様加工食品。 The cheese-like processed food according to claim 1, wherein the protein content is 0.1% or less and substantially no protein is contained. 油脂のSFCが10℃で50〜95%、20℃で40〜85%である請求項1または2に記載のチーズ様加工食品。 The cheese-like processed food according to claim 1 or 2 , wherein the SFC of the fat is 50 to 95% at 10 ° C and 40 to 85% at 20 ° C. 実質的に乳由来原料を含有しない請求項1〜のいずれかに記載のチーズ様加工食品。 The cheese-like processed food according to any one of claims 1 to 3 , which contains substantially no milk-derived raw material. 形状がブロック状、スライス状、サイノメ状、短冊状、シュレッド状、粉状である請求項1〜のいずれかに記載のチーズ様加工食品。
The cheese-like processed food according to any one of claims 1 to 4 , wherein the shape is block, slice, sinome, strip, shred, and powder.
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